Material Safety Data Sheet

Bardac 2250
Version 1.14 Revision Date 2011.02.18 Print Date 2011.02.19

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name Product Use Description : : Bardac 2250 Cleaning/washing agents and disinfectants

Company

Lonza Inc. 90 Boroline Road Allendale, NJ 07401 1-201-316-9200 CHEMTREC 1-800-424-9300

Telephone Emergency telephone number

: :

SECTION 2. HAZARDS IDENTIFICATION Emergency Overview

Danger
Colour: light yellow, Odour: alcohol-like Hazard Summary : Harmful in contact with skin. Causes burns. Irritating to eyes. OSHA Hazards : CORROSIVE Potential Health Effects Primary Routes of Entry : Inhalation Ingestion Eyes Skin : May be harmful if inhaled. : Causes skin burns. : Causes eye irritation. : Harmful if swallowed.

Inhalation Skin Eyes Ingestion

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Material Safety Data Sheet

Bardac 2250
Version 1.14 Revision Date 2011.02.18 Print Date 2011.02.19

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Didecyldimethylammonium chloride Ethanol Water CAS-No. 7173-51-5 64-17-5 7732-18-5 Weight percent 50,00 10,00 40,00

SECTION 4. FIRST AID MEASURES First aid procedures Inhalation : Move to fresh air. Call a physician immediately. If breathing is irregular or stopped, administer artificial respiration. : After contact with skin, wash immediately with plenty of soap and water. Call a physician immediately. Take off all contaminated clothing immediately. : Immediately flush eye(s) with plenty of water. Call a physician immediately. : Call a physician immediately. Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person.

Skin contact

Eye contact

Ingestion

SECTION 5. FIRE-FIGHTING MEASURES Flammable properties Flash point : 109 F (43 C)

Fire fighting Suitable extinguishing media : Dry powder Water spray Foam : Use water spray to cool unopened containers.

Further information

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Material Safety Data Sheet

Bardac 2250
Version 1.14 Revision Date 2011.02.18 Print Date 2011.02.19

Protective equipment and precautions for firefighters Specific hazards during fire fighting Special protective equipment for fire-fighters : Heating or fire can release toxic gas. : In the event of fire, wear self-contained breathing apparatus.

SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Use respirator when performing operations involving potential exposure to vapour of the product. : Do not flush into surface water or sanitary sewer system. : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).

Environmental precautions Methods for containment / Methods for cleaning up

SECTION 7. HANDLING AND STORAGE Handling Handling : Avoid contact with skin and eyes. Provide sufficient air exchange and/or exhaust in work rooms. : Highly flammable. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges.

Advice on protection against fire and explosion

Storage Requirements for storage areas and containers : Keep container tightly closed. To maintain product quality, do not store in heat or direct sunlight. Keep in a dry, cool and well-ventilated place. : Store containers in compliance with the most recent NFPA Code (NFPA 30). Ground all containers prior to pouring. : < 140 F (< 60 C) : Storage temperature

Further information on storage conditions Storage temperature Other data

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Material Safety Data Sheet

Bardac 2250
Version 1.14 Revision Date 2011.02.18 Print Date 2011.02.19

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Components Ethanol CAS-No. 64-17-5 Value TWA Control parameters 1 000 ppm Update 2008 Basis ACGIH

REL

1 000 ppm 1 900 mg/m3 1 000 ppm

2005

NIOSH/GUIDE

STEL

2009

ACGIH

Engineering measures

Personal protective equipment Eye protection : Tightly fitting safety goggles Face-shield Hand protection : Suitable material : Nitrile rubber Break through time : > 480 min Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place. Rubber or plastic apron Rubber or plastic boots : In the case of vapour formation use a respirator with an approved filter. : Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Respiratory protection

Hygiene measures

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance 1043.6 / CO00001534 Page 4 / 10

Material Safety Data Sheet

Bardac 2250
Version 1.14 Physical state Colour Odour Revision Date 2011.02.18 : liquid : light yellow : alcohol-like Print Date 2011.02.19

Safety data Flash point pH : : 109 F (43 C) 6,5 - 9 at 100,00 g/l 77 F (25 C) Stock Point Density : -4 F (-20 C)

: 0,93 g/cm3 at 77 F (25 C) : Note: completely soluble : <100 mPa.s at 77 F (25 C)

Water solubility Viscosity, dynamic

SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid : Remarks: no data available : Remarks: Reducing agents Strong oxidizing agents : Note: nitrogen oxides (NOx) hydrochloric acid Carbon oxides

Hazardous decomposition products

SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 rat Dose: 450 mg/kg : LD50 rabbit Dose: 4 300 mg/kg : rabbit Result: Corrosive Method: OECD Test Guideline 404 Exposure time: 4 h Page 5 / 10

Acute dermal toxicity

Skin irritation

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Material Safety Data Sheet

Bardac 2250
Version 1.14 Revision Date 2011.02.18 Print Date 2011.02.19

Eye irritation

: rabbit Result: severe irritant : Buehler Test guinea pig Result: not sensitizing

Sensitisation

SECTION 12. ECOLOGICAL INFORMATION Toxicity to daphnia and other aquatic invertebrates. : EC50 Species: Daphnia magna (Water flea) Concentration: 0,94 mg/l Exposure time: 48 h

The following ecotoxicological data refer to:

Didecyldimethylammonium chloride (CAS-No.: 7173-51-5) Biodegradability : Modified Sturm Test Concentration: 10 mg/l Exposure time: 28 d Result: Readily biodegradable. 72 % Method: OECD 301 B Die-Away Test Concentration: 0,016 mg/l Exposure time: 28 d 93,3 % OECD Confirmatory Test Exposure time: 24 - 70 d 91 % Method: OECD 303 A Remarks: The surfactant(s) contained in this mixture complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Bioaccumulation 1043.6 / CO00001534 : Species: Lepomis macrochirus (Bluegill sunfish) Page 6 / 10

Material Safety Data Sheet

Bardac 2250
Version 1.14 Revision Date 2011.02.18 Exposure time: 46 d Bioconcentration factor (BCF): 81 Method: EPA-FIFRA Acute Fish toxicity : Acute toxicity LC50 Species: Pimephales promelas (fathead minnow) Concentration: 0,19 mg/l Exposure time: 96 h Analytical monitoring: yes Method: US-EPA Chronic toxicity NOEC Species: Danio rerio (zebra fish) Concentration: 0,03 mg/l Exposure time: 34 d Analytical monitoring: yes Method: OECD 210 Toxicity to daphnia and other aquatic invertebrates. : Immobilization EC50 Species: Daphnia magna (Water flea) Concentration: 0,06 mg/l Exposure time: 48 h Analytical monitoring: yes Method: EPA-FIFRA Reproduction Test NOEC Species: Daphnia magna (Water flea) Concentration: 0,01 mg/l Exposure time: 21 d Analytical monitoring: yes Method: OECD 211 Chronic toxicity NOEC Species: Chironomus sp. Concentration: 530,00 mg/l Exposure time: 28 d Analytical monitoring: yes Method: OECD 218 Toxicity to algae : Growth inhibition ErC50 Species: Pseudokirchneriella subcapitata (green algae) Dose: 0,02 mg/l Exposure time: 96 h Analytical monitoring: yes Method: OECD Test Guideline 201 : Respiration inhibition EC50 Species: activated sludge Dose: 11,00 mg/l Exposure time: 3 h Page 7 / 10 Print Date 2011.02.19

Toxicity to bacteria

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Material Safety Data Sheet

Bardac 2250
Version 1.14 Revision Date 2011.02.18 Method: OECD 209 Print Date 2011.02.19

SECTION 13. DISPOSAL CONSIDERATIONS Further information : Dispose of in accordance with local regulations. Contact waste disposal services.

SECTION 14. TRANSPORT INFORMATION DOT UN number Description of the goods Class Packing group Labels

: : : : : :

1903 Disinfectants, liquid, corrosive n.o.s. (Didecyldimethylammonium chloride) 8 II 8

IATA UN number Description of the goods Class Packing group Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Packing instruction (passenger aircraft) IMDG-CODE UN number Description of the goods Class Packing group Labels EmS Number 1 EmS Number 2 Marine pollutant RID 1043.6 / CO00001534

: 2920 : Corrosive liquid, flammable, n.o.s. (Didecyldimethylammonium chloride, Ethanol) : 8 : II : 8 (3) : 855 : 851 : Y840

: 2920 : CORROSIVE LIQUID, FLAMMABLE, N.O.S. (Didecyldimethylammonium chloride, Ethanol) : 8 : II : 8 (3) : F-E : S-C : yes

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Material Safety Data Sheet

Bardac 2250
Version 1.14 UN number Description of the goods Class Packing group Classification Code Hazard identification No Labels Revision Date 2011.02.18 Print Date 2011.02.19 : 2920 : CORROSIVE LIQUID, FLAMMABLE, N.O.S. (Didecyldimethylammonium chloride, Ethanol) : 8 : II : CF1 : 83 : 8 (3)

SECTION 15. REGULATORY INFORMATION OSHA Hazards WHMIS Classification : Corrosive : E B2 : 1 000 lbs : Acute Health Hazard Fire Hazard

CERCLA Reportable Quantity SARA 311/312 Hazards

EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO - KNOW SARA 302 Components : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components

: SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

US State Regulations Massachusetts Right To Know Components Pennsylvania Right To Know Components New Jersey Right To Know Components California Prop. 65 Components : Ethanol Listed : Ethanol Listed : Ethanol Listed 64-17-5

64-17-5

64-17-5

: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

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Material Safety Data Sheet

Bardac 2250
Version 1.14 Revision Date 2011.02.18 Print Date 2011.02.19

This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. Federal regulatory information: This product is EPA registered : EPA registration No: 6836-51

SECTION 16. OTHER INFORMATION Further information HMIS Classification : Health hazard: 3 Flammability: 2 Reactivity: 0

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by: : Product Safety Americas Email: regcomamer@lonza.com

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