Ci (mg/L)

Ce (mg/L)
intial amount of Zn Final amount of Zn Solution used (ml)
4.22E-06
4.00E-06
4.22E-08
0.00000004
10
1.00E-05
9.38E-06
0.0000001
9.38E-08
10
2.00E-04
1.77E-04
0.000002
0.00000177
10
5.00E-03
3.94E-03
0.00005
0.0000394
10
3.01E-02
2.15E-02
0.000301
0.000215
10

1.00E-05

1.00E-04

1.00E-03

1.00E-02

0.01
0.00006 linear isothern
0.001

Cs(mg/Kg

1.00E-06

0.0001
1
1.00E-01
1.00E+00
0.1
0.00008

0.00004
0.0001
0.00001
0.00002
0.000001

Ce(mg/L)
sorption isotherm graph

0
0.0000001 0.00E+00
-5.00E-05
-0.00002

Soil used (kg)

0.0025
0.0025
0.0025
0.0025
0.0025

Soil adsorbed
Cs(mg/kg)
kd
2.2E-09
8.8E-07
6.2E-09
0.00000248
0.00000023
9.2E-05
0.0000106
0.00424
0.000086
0.0344

2.20E-01
2.64E-01
5.20E-01
1.08E+00
1.60E+00

*draw Cs vs Ce graph, called sorption isotherm

*find kd for last0.0001
3 points
0.00009
C _s=k_d C_eq

0.0001
1.00E+00
0.00008

0.00008
0.00007

0.00006 linear isothern

0.00006
0.00005
Series1
0.00004

0.00004
0.00002

0.00003
0.00002

0
0.00E+00
-0.00002

5.00E-05

1.00E-04

1.50E-04

2.00E-04

0.00001
0
0.00E+00
5.00E-05
1.00E-04
1.50E-04
2.00E-04

Series1
Linear (Series1)

Series1
Linear (Series1)

time
C

t
0
5
10
15
20
25
30
35

A
10
9.562
9.142
8.741
8.358
7.992
7.641
7.306

(days)
(mg/kg)

A0
10
10
10
10
10
10
10
10

0
10

5
9.562

ln(A/A0)=-kt
0
-0.044788183
-0.089705913
-0.134560493
-0.179365929
-0.224144052
-0.269056608
-0.313889165

decay constant
k
0
0.008957637
0.008970591
0.0089707
0.008968296
0.008965762
0.008968554
0.008968262

10
9.142

half life
t1/2=ln(0.5)/-k
#DIV/0!
77.38058762
77.26883956
77.26790714
77.28861156
77.310459
77.2863954
77.28890976

15
8.741

0
0.438
0.858
1.259
1.642
2.008
2.359
2.694
2.694

As decay constant follows first degree curve and downward, so radioactive decay follows
first order kinetics

20
8.358

25
7.992

30
30
7.641

35
7.306

25
20

4.38
8.58
12.59
16.42
20.08
23.59
26.94
26.94

15
10
5
0
0

10

20

30

40

Series1

Parameter
Initial biomass
Maximum specific growth
Half-saturation constant
Carrying capacity
Respiration rate
Substrate concentration
Yield coefficinet

a)

Xo
max
Ks
K
Kd
S
Y

Units
Species-A Species-B
(mgDW/L
10
10
day-1
0.3
0.15
(mgS)/L
10
5
(mgDW/L
10,000
10,000
day-1
0.05
0.025
(mgS/L
2000
2000
(mgDW)/(mg S)
0.1
0.1
0.298507 0.149626

Growth-decay model for rate of change of biomass

substrate concentration
600 0.298507463

0.298507463
400 0.298507463

0.298507463
200
0
-200
-400
-600

a
0.298507463
0.298507463
0.298507463
0.298507463
0.298507463
0.298507463
0.298507463
0.298507463
0.298507463
0.298507463
0.298507463
0.298507463
600 0.298507463
0.298507463
400 0.298507463
0.298507463

b
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935
0.149625935

200
0
0
-200
-400
-600

10

Xo
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120

10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
11
12
13
15 14
15
16
17
18

X
44.66139
197.0937
826.5906
2876.644
6441.094
8902.449
9732.276
9938.994
9986.323
9996.945
9999.318
9999.848
9999.966
9999.992
9999.998
10000
10000
10000
10000
10000
20
10000
10000
10000
10000

dx/dt
dx/dt(Logistic)
13.33174
0.298660158
58.83386
0.294087188
246.7431
0.275202282
858.6983
0.213700689
1922.712
0.106767179
2657.443
0.032926526
2905.152
0.00803173
2966.859
0.001830187
2980.987
0.000410314
2984.158
9.16509E-05
2984.866
2.04549E-05
2985.025
4.56436E-06
2985.06
1.01846E-06
2985.068
2.27249E-07
2985.069
5.07062E-08
2985.07
1.13141E-08
2985.07
2.29478E-09
2985.07
4.69318E-10
2985.07
9.66541E-11
Series1
2985.07
2.00239E-11
2985.07
4.16966E-12
2985.07
8.72202E-13
2985.07
1.8312E-13
2985.07
3.85691E-14

dx/dt(Monod Model) dx/dt (combined) Respiration (X)

13.33175929
11.03914811 7.788007831
58.83394913
47.8196824 6.065306597
246.7434597
185.018348 4.723665527
858.699608
467.850143 3.678794412
1922.714637
362.2213578 2.865047969
2657.447506
-153.4540789 2.231301601
2905.156918
-408.8356666 1.737739435
2966.863815
-478.849974 1.353352832
2980.991896
-495.2389954 1.053992246
2984.162677
-498.9355776 0.820849986
2984.871095
-499.7623906 0.639278612
2985.02921
-499.946977 0.497870684
2985.064493
-499.9881687 0.387742078
2985.072366
-499.9973601 0.301973834
2985.074122
-499.999411 0.235177459
2985.074514
0.183156389
2985.074604
0.156906573
2985.074622
0.133307958
2985.074626
0.112472038
2985.074627
0.094331258
2985.074627
0.078712776
2985.074627
0.065388343
2985.074627
0.054107274
2985.074627
0.044617539