POLYISOCYAnATES AnD PREPOLYMERS

Desmodur | Bayhydur | Desmotherm | Bayhytherm Desmoseal | Desmocap | Imprafix | Baybond | Crelan

Contents
150 years of Bayer Science for a better life CAS business unit Leading in polyurethanes Polyisocyanates and prepolymers Grades with shining properties Applications Highlights TDI-based Desmodur

Hydrophilic modified polyisocyanates 4 Bayhydur Hydrophilic modified polyisocyanates 5 Desmodur D Special types water based 6 Desmodur Special types 7 Desmodur R Blocked grades 8 Desmodur BL Solvent-free blocked urethane resins 12 Desmocap Self-crosslinking baking urethane resins 14 Desmotherm Water-based blocked grades 14 Bayhydur BL/Baybond XL/Imprafix 34 Water-based self-crosslinking baking

26

28

28

28

30

MDI-based Desmodur PMDI-based Desmodur

32

32

Silane-terminated Desmoseal S MDI-based prepolymers Desmodur /Desmoseal

16

urethane resins Bayhytherm 34

HDI-based Desmodur n IPDI-based Desmodur Z Aliphatic prepolymers Desmodur 24 We are Where you are Global partnerships 39 22 More than just products Sustainability @ CAS 38 18 Powder hardeners Crelan 36

150 Years of Bayer

Science for a better life

The 150th anniversary of Bayer AG is an occasion to celebrate innovation and quality. What started as a dyestuffs factory in the Barmen district of Wuppertal is now a global corporation with more than 110,000 employees. Although that sounds like tradition and continuity, it is a success story about change. The spirit of inventiveness and the will to succeed form a bridge spanning the companys history from its origins 150 years ago to today. In the beginning there was a friendship between two men, plenty of a researchers natural curiosity and two kitchen stoves. On these, businessman Friedrich Bayer and dyer Johann Friedrich Weskott conducted experiments and eventually discovered how to make the dye fuchsine. In 1863 they established the Friedr. Bayer et. comp company. Bayer products today help to improve the quality of life for people and animals. One example is the pain reliever Aspirin, which came on the market in 1899 and remains one of Bayers top products to this day. When Bayer started selling Antinonnin, the worlds first synthetic insecticide for controlling the nun moth, in 1892, it was the start of the success story that is now Bayer CropScience. In the area of high-performance materials, the polyurethanes for foams discovered in the 1930s and the high-performance polycarbonate (Makrolon) patented in 1953 are the foundation for an everexpanding range of applications. These include lightfast polyurethane coatings, made possible by the Desmodur N family of crosslinkers invented by Dr. Kuno Wagner, and raw materials for the production of anti-corrosion coatings for ships, aircraft and automobiles. Today, high-performance materials from Bayer MaterialScience make an important contribution to conserving fossil resources. It is thanks to the invention of aliphatic polyurethane coatings that assets can be preserved for longer than ever before. Modern coating systems withstand both wind and weather, impart durability and a glossy finish. At the same time, Bayer MaterialSciences production technologies set standards in safety, quality and cost efficiency. A continuous flow of new innovations that benefit both society and the environment provides for sustainable growth. In this way, our products live up to our mission, Bayer: Science for a better life.

CAS Business Unit

Leading in polyurethanes

The Coatings, Adhesives, Specialties (CAS) Business Unit is characterized by its broad range of products and many years of experience in research and development. On this foundation, CAS takes a leading role in polyurethane raw materials, such as isocyanates and polyols, including modified systems such as polyurethane dispersions, silane-terminated prepolymers and blocked isocyanates. ity of aliphatic polyurethane systems. Examples Products manufactured from CAS raw materials are used, for instance, to coat buses, trains and ships. They have an extremely long shelf life and offer good weathering and corrosion protection. For this reason, they also are critical in the manufacturing of wind turbines, pipelines and steel structures. Our raw materials also serve various purposes in the timber processing industry. In paints and coatings they protect against discoloration and wear. Adhesive raw materials likewise are used in this segment, although they further are involved in the production of shoes and motor vehicles, and in the building industry. In the field of specialty chemicals, we produce premium polyurethane dispersions, e.g. for cosmetic formulations and hydrophilic prepolymers for medical wound dressings or functional films. Cast elastomers represent the latest addition to the product range. Apart from the conventional fields of application, the CAS business unit continues to develop its portfolio of products and system solutions toward new, lucrative market segments. These efforts are supported by the quality and versatilThis makes it possible for us not only to meet the demands of existing markets, but also to develop new markets offering promising opportunities. Our success along the way is based on intense research in our own laboratories and continuous dialog with our customers. Most of our efforts in this connection are put into eco-friendly coatings that go easier on resources and are efficient in application. We therefore focus on low-solvent, solvent-free or waterborne systems. To improve our adhesives product portfolio, we also target ecologically compatible and user-friendly systems. At the center of all our activities are our customers. Be it polyisocyanates, prepolymers, dispersion polyols or UV systems, they can profit from our many years of experience and the wealth of knowledge of our experts. At the same time, close collaboration with our customers is essential to the development of innovative solutions and new markets. include encapsulation materials for light-emitting diodes and solar systems, or moldings for optical and transparent applications.

Polyisocyanates and prepolymers:

Grades with shining properties

polyurethane coatings and adhesives, blocked polyisocyanates for one-component polyurethane baking coatings or hydrophilized polyisocyanates as crosslinkers for water-reducible polyurethane systems: Our products are used wherever crosslinking is used to achieve high resistances and reliable adhesion under efficient conditions. Our solutions are in use today in a variety of applications, such as automotive OEM and refinish and the coating of transportation vehicles, wood, industrial goods and plastics. They are also used in reactive adhesives, textile coatings and anticorrosion coatings. Gloss, leveling, scratch resistance, hardness and flexibility can be precisely adjusted by the choice of polyisocyanate and polyol. Chemical resistance, adhesion, light stability and weatherability are additional properties that can be individually Innovation is our tradition. With the breakthrough discovery of the polyisocyanate-polyaddition process in 1937 by Otto Bayer, Bayer became a pioneer of polyurethane chemistry. 50 years ago, Bayer AG developed the first applications using polyisocyanates for the coatings and adhesives sectors. Polyurethane systems also known as DD coatings have established themselves in a number of applications. We work closely with our customers to systematically advance the state of polyure thane technology. Using market-oriented re sea rch and development, we specifically adapt our product portfolio to the increasingly stringent requirements of our customers. We want to continue our successful journey along this path with you. Our polyisocyanates comprise a broad range of products for one and two-component (1K, 2K) polyurethane systems used in numerous applications. Whether crosslinkers for two-component
6

adapted to the respective requirements. With a bit of clever formulation, coatings with easy-toclean, soft-touch or reflow properties can also be produced. Our product range of prepolymers comprise aromatic and aliphatic NCO-terminated as well as silane terminated products. With these prepolymers properties of coatings, adhesives and sealants can be varied over a wide range. Typical areas of application include wood coatings, corrosion protection, floor coatings, elastic adhesives in transportation, parquet adhesives, engeneered wood construction, flexible film lamination and sealants. Prepolymers with a low fraction of non-polymerbound components open up formulation options for the productions of reactive polyurethane adhesive and sealants, that are not subject of labelling requirements.

APPLICATIONS

Highlights

... Marine coatings

... Coatings of glass

... Floor coatings

... Adhesives for modern timber constructions

... Coating of wood and furniture

... Coating of agriculture equipments

... Sealant applications

... Automotive coatings

... Coatings of plastics

for coatings and adhesives

2,4-tDI CONTENT [WT.%]

FUNCTIONALITY

NCO APPROX. [WT.%]

VISC. AT 25 C APPROX. [mPas]

Monomeric TDI products

Desmodur T65N Desmodur T80 Desmodur T100 48 48 48 67.0 80.5 > 99.0 3 3 3 2 2 2

TYPE

NCO (SUPPLY FORM) APPROX. [%] SUPPLY FORM APPROX. [%] EQUIVALENT WEIGHT APPROX.

VISC. AT 23 C APPROX. [mPas]

TDI-based*
Desmodur L 75 TDI Adduct 75 EA 13.3 315 1,600

Desmodur L 67 MPA/X Desmodur L 67 BA

TDI TDI TDI TDI TDI TDI TDI TDI TDI TDI/HDI TDI/HDI

Adduct Adduct Adduct Isocyanurate Isocyanurate Isocyanurate Isocyanurate Isocyanurate Isocyanurate Isocyanurate Isocyanurate

67 MPA/X 67 BA 70 EA 51 BA 51 EA 51 BA 51 EA 51 BA 51 EA 60 BA 60 EA

11.9 11.9 9.8 8.0 8.0 8.0 8.0 7.4 7.4 10.5 10.5

350 350 430 525 525 525 525 565 565 400 400

1,600 600 1,920 2,000 700 1,600 350 250 110 2,200 1,100

Desmodur L 1470 Desmodur IL BA Desmodur IL EA Desmodur IL 1351 Desmodur IL 1351 EA Desmodur IL 1451

Desmodur IL 1451 EA Desmodur HL BA 8 Desmodur HL EA

HC MAX./ACIDITY MAX. [ppm HCI] EQUIVALENT WEIGHT APPROX. PROPERTIES & APPLICATIONS

90 90 90

100/40 100/40 100/40 Stabilizer: Irganox 1076 FD Stabilizer: Irganox 1076 FD

INDUSTRIAL

FLOOR WALL PLASTICS

PROPERTIES & APPLICATIONS

* = These products represent only an assortment of TDI and MDI-based products primarily used in coatings applications. Additonal TDI and MDIbased products can be found e. g. on the BMS-CAS internet site: www.bayercoatings.com

CORROSION PROTECTION

WOOD FURNITURE

Standard crosslinker with broad range of applications, e.g. chemically r esistant coatings, anti-corrosion coatings, industrial coatings, wood and furniture finishes, concrete coatings See L 75 See L 75 See L 75 Very hard and very fast-drying coatings for wood, furniture and paper See IL BA See IL BA See IL BA Like Desmodur IL 1351 but with improved compatibility Like Desmodur IL 1351 but with improved compatibility Very fast-drying coatings for wood, furniture, metal, plastic and paper with better elasticity than Desmodur IL and better lightfastness See HL BA 9

= especially suitable = suitable

Prepolymers are reaction products of aromatic or aliphatic isocyanates and polyols such as polyethers or polyesters. Due to the wide variability of the isocyanate content and functionality, the viscosity of the prepolymers and the mechanical properties of the finished products can be precisely adjusted.

SOLIDS CONTENT [APPROX. %] NCO APPROX. [WT.%] SOLVENT

MONOMER CONTENT [wt. %] VISCOSITY APPROX. [mPas]

Prepolymers based on TDI

Desmodur E 15

4.4

100

0.5

7,000

Desmodur E 14

3.3

100

0.5

6,800

Desmodur E 1361 MPA/X Desmodur E 1361 BA Desmodur E 1160 Desmodur E 1750 PR Desmodur E 1660

6.8 6.8 5.4 5.4 5.3

61 61 60 50 60

MPA/X BA MPA/X MPA/X BA

0.5 0.5 0.5 0.5 0.5

500 250 550 375 1,600

Desmodur E XP 2605

4.3

50

BA

0.5

175

10

VISCOSITY AT TEMPERATURE [C]

FUNCTIONALITY*

PROPERTIES & APPLICATIONS

COLOUR INDEX [IODINE]

EQUIVALENT WEIGHT APPROX.

23

n. m.

LF

955

Polyether-based prepolymer for flexible coatings and membranes, Polyether-based prepolymer for flexible coatings and membranes, flexibilization in anti-corrosion protection Fast drying 1K moisture-curing coatings, good resistance See E 1361 MPA/X 1K moisture-curing coatings with good resistance properties See E 1361 MPA/X 1K moisture-curing coatings in combination with other Desmodur E types: good resistance properties and very fast drying Very fast drying 1K moisture-curing clear coatings, good resistance, wood and furniture applications

* LF

23

n. m.

LF

1,270

23 23 23 23 23

3 3 3 2 n. m.

SF SF LF LF LF

615 615 775 775 790

= Low functionality (2.0 2.8) SF =  Standard functionality (2.8 3.6) HF =  High functionality (> 3.6) n. m. = not measured

23

n. m.

LF

975

11

for coatings and adhesives

VISCOSITY APPROX. [mPas] NCO APPROX. [WT. %] VISCOSITY AT TEMPERATURE [C]

FUNCTIONALITY*

Monomeric MDI products

Desmodur 44M liquid Desmodur 44MC liquid Desmodur 44MN liquid Desmodur LS2424 Desmodur 2460M Desmodur CD-S Desmodur CD-L

33.6 33.6 33.6 33.6 33.6 29.5 29.5

4.1 4.1 4.1 12 12 35 35

40 40 40 25 25 25 25

2 2 2 2 2 2 2

Polymeric MDI products (PMDI products)**

Desmodur VK5 Desmodur VK10 Desmodur VK10L Desmodur VLR10 Desmodur VKS20 Desmodur VKS20F Desmodur VKS20FH Desmodur XP2404 Desmodur 44V70L

32.5 31.5 31.5 31.5 31.5 31.5 31.5 31.5 31.3

22.5 90 90 120 200 200 200 200 680

25 25 25 25 25 25 25 25 25

LF LF LF SF SF SF SF SF SF

12

HC MAX./ACIDITY MAX. [ppm CI-/HCI] EQUIVALENT WEIGHT APPROX. PROPERTIES & APPLICATIONS

125 125 125 125 125

50/ 60/ 25/ 50/ 50/ 50/ 50/

Flexible packaging, hotmelts, sealants; additional supply form: fused and flakes Hotmelts, sealants, prepolymer stability (++); additional supply form: fused and flakes Flexible packaging Flexible packaging, hotmelts, approx. 55 % 2,4-MDI/45 % 4,4-MDI Flexible packaging, hotmelts, approx. 55 % 2,4-MDI/45 % 4,4-MDI colour stabilized Hotmelts, sealants, modified monomeric MDI, liquid at room temperature, storage stable at low temperatures Flexible packaging, modified monomeric MDI, liquid at room tem perature, near to food applications, storage stable at low temperatures

** =  These products represent only an assortment of TDI and MDI-based products primarily used in coatings applications. Additonal TDI and MDIbased products can be found e. g. on the BMSCAS internet site: www.bayercoatings.com * LF = Low functionality (2.0 2.8) SF =  Standard functionality (2.8 3.6) HF =  High functionality (> 3.6)

130 135 135 135 135 135 135 135 135

/600 /1200 /1000 /200 /200 /200 /150 /200 /500

Prepolymers, high 2,4-MDI content, good compatibility with polyethers One- & two-component adhesives, high 2,4-MDI content, low PMDI content, good compatibility with polyethers One- & two-component adhesives, high 2,4-MDI content, low PMDI content good compatibility with polyethers, lower reactivity than Desmodur VK 10,

Standard two-component adhesives Standard two-component adhesives (exact specification on request) Standard two-component adhesives (exact specification on request) Standard two-component adhesives

13

Desmodur VL Family-crosslinkers for solvent-free two-component polyurethane coatings for anti-corrosion and construction applications. Desmoseal S are silane terminated polyurethanes (STPs) which combine properties of polyu r e thanes with those of silicones to give a new class of prepolymers. These prepolymers are primarily designed to act as binders for moisture-curing sealants and elastic adhesives. They are high molecular weight prepolymers consisting of a polyurethane-backbone and a trifunctional silane end group.

TYPE

NCO (SUPPLY FORM) APPROX. [%] SUPPLY FORM APPROX. [%] EQUIVALENT WEIGHT APPROX.

VISC. AT 25 C APPROX. [mPas]

PMDI-products*
Desmodur VL Desmodur VL 50 Desmodur VL 51 Desmodur VL R 10 Desmodur VL R 20 Desmodur VL R 21 Desmodur XP 2551 MDI polyisocyanate MDI polyisocyanate MDI polyisocyanate MDI polyisocyanate MDI polyisocyanate MDI polyisocyanate MDI polyisocyanate Solvent-free Solvent-free Solvent-free Solvent-free Solvent-free Solvent-free Solvent-free 31.5 32.5 32.5 31.5 31.5 31.5 32 135 130 130 135 135 135 130 90 23 22 120 200 200 60

PLASTICIZER

Silaneterminated polyurethanes
Desmoseal S XP 2636 Desmoseal S XP 2458 Desmoseal S XP 2749 Desmoseal S XP 2774 Desmoseal S XP 2821

SOLIDS CONTENT [%]

VISCOSITY AT 23 C APPROX. [mPas]

100 90 100 100 100

Mesamoll

40,000 35,000 4,500 50,000 20,000

14

FLOOR WALL AUTO OEM CORROSION PROTECTION

PROPERTIES & APPLICATIONS

Crosslinker for solvent-free coatings, sealants and membranes Very low viscosity; same applications as Desmodur VL but better compatibility with polyethers and lower reactivity; more flexible See VL 50 Higher reactivity than Desmodur VL; for solvent-free spray coatings and membranes See VL R 10 Lower reactivity than Desmodur VL R 20; for solvent-free coatings and membranes Crosslinker primarily for polyol emulsions

* =  These products represent only an assortment of TDI and MDI-based products primarily used in coatings applications. Additonal TDI and MDIbased products can be found e. g. on the BMS-CAS internet site: www.bayercoatings.com = especially suitable = suitable

MOLECULAR WEIGHT PROPERTIES & APPLICATIONS

High Medium Low High Low

Sealants & Adhesives, Prepolymer for soft formulations with low modulus and and high elongation at break, with good elastic recovery  ealants & Adhesives, Prepolymer for hard formulations with high modulus and medium S elongationat break, with high cohesive strength Adhesives & coatings, medium to high modulus, prepolymer for adhesives, primers, waterproofing membranes, good elastic properties, low elongation at break Sealants & Adhesives, Prepolymer for very soft formulations with low modulus and high elongation at break, with good elastic recovery Adhesives, Prepolymer for very hard formulations with high tensile and lab shear strength.

15

Desmodur and Desmoseal M prepolymers are the reaction products of aromatic or aliphatic isocyanates and polyols such as polyethers or polyesters. Due to the wide variability of the building blocks, isocyanate content and functionality, the viscosity of the prepolymers and the mechanical properties of the finished products can be precisely adjusted.

VISCOSITY APPROX. [mPas] NCO APPROX. [WT. %] VISCOSITY AT TEMPERATURE [C]

FUNCTIONALITY*

Prepolymers based on MDI

Desmodur VH 20 N Desmodur E 29 Desmodur PF Desmodur E XP 2753 Desmodur E21 Desmodur XP 2665 Desmodur E 20100 Desmodur E XP 2723 Desmodur E 23

24.5 24.0 23.0 21.5 16 15.8 15.7 15.4 15.4 15.9 15.3 15.1 9.9 8.6 6.0 2.1

280 220 600 400 5,400 5,250 1,100 1,500 1,800 2,800 800 910 2,750 2,800 4,500 33,000

25 25 25 23 25 25 23 25 23 23 23 70 25 23 23 23

LF LF LF LF SF LF LF LF LF SF LF LF LF LF LF LF

Desmodur E XP 2762 Desmodur E XP 2727 Desmodur E XP 2715 Desmodur E 2200/76 Desmodur E 22

Desmodur E XP 2726 Desmoseal M 280

Low free monomer product

Desmodur VPLS 2397 5.6 10,000 2000 50 LF

16

PROPERTIES & APPLICATIONS EQUIVALENT WEIGHT APPROX.

170 175 180 195 260 265 265 270 270 265 275 280 425 490 700 2,000

Gymnasium floors, storage stable at low temperatures Primer for flooring applications, binder for corrosion protection Hot melts, modified monomeric MDI, liquid at room temperature, s torage stable at low temperatures Corrosion protection e.g. pipe coatings Wood bonding, binder for corrosion protection Wood bonding, higher reactivity compared to Desmodur E21 Injection resin for sealing water-conveying cracks in structures above and below ground 1K and 2K adhesives Wood bonding, flexible packaging, binder for corrosion protection Wood bonding, higher reacitivity compared to E23 1K and 2K binder for corrosion protection and adhesives Low monomer 1K PUR hotmelts Flexible packaging Bonding of granulated rubber Low monomer 1K PUR hotmelts Sealants, elastic adhesives

* LF = Low functionality (2.0 2.8) SF =  Standard functionality (2.8 3.6) HF =  High functionality (> 3.6)

750

Low monomer 1K PUR hotmelts, flexible packaging

17

Desmodur N Family: Hardeners for high-performance two-component polyurethane coatings with excellent weatherability and resistance properties.

FREE MONOMER CONTENT [wt. %] NCO APPROX. [WT. %] VISCOSITY APPROX. [mPas]

VISCOSITY AT TEMPERATURE [C]

Aliphatic Isocyanates Monomers

Desmodur H Desmodur I Desmodur W/1

49.7 37.5 31.8

3 10 30

25 25 25

TYPE

NCO CONTENT ON SUPPLY VISC. AT 23 C FORM APPROX. [%] APPROX. [mPas] SUPPLY FORM APPROX. [%] EQUIVALENT WEIGHT APPROX. AUTO OEM

AUTO-REFINISH LARGE VEHICLES

HDI-based and biuret

Desmodur N 100 HDI biuret

Solvent-free

22.0

190

10,000

Desmodur N 75 MPA/X

HDI biuret

75 MPA/X

16.5

255

250

Desmodur N 75 MPA Desmodur N 75 BA Desmodur N 3200

HDI biuret HDI biuret HDI biuret

75 MPA 75 BA Solvent-free

16.5 16.5 23.0

255 255 185

250 160 2,500

HDI-based Trimer
Desmodur N 3300 HDI Solvent-free isocyanurate HDI isocyanurate HDI isocyanurate 21.8 195 3,000

Desmodur N 3390 BA/SN Desmodur N 3390 BA

90 BA/SN 90 BA

19.6 19.6

215 215

550 500

18

O OCN (CH2)6 N O

H N N H

(CH2)6 (CH2)6

NCO NCO

FUNCTIONALITY

PROPERTIES & APPLICATIONS EQUIVALENT WEIGHT APPROX.

COLOUR INDEX [HAZEN]

30 30 30

2.0 2.0 2.0

85 110 130

HDI IPDI H12MDI PROPERTIES & APPLICATIONS

= especially suitable = suitable

WOOD FURNITURE INDUSTRIAL COATINGS

PARQUET TRADE

CORROSION PROTECTION

PLASTIC COATINGS

FLOOR WALL

Weather-stable and non-yellowing topcoats Outstanding weather stability and gloss retention, no yellowing; for air and force-drying automotive, wood, furniture, industrial and plastics coatings, anti-corrosion coatings and chemically resistant coatings See N 75 MPA/X See N 75 MPA/X Lower viscosity than Desmodur N 100; especially for weather-stable and non-yellowing high-solids coatings, structural coatings and topcoats

Outstanding weather stability and gloss retention, nonyellowing; for automotive OEM, automotive refinish, plastics and industrial coatings, structural coatings and topcoats See N 3300

See N 3300

19

Desmodur N FAMILY: Hardeners for high-grade two-component polyurethane coatings with excellent weatherability and resistance properties.

TYPE

NCO CONTENT ON SUPPLY VISC. AT 23 C FORM APPROX. [%] APPROX. [mPas] SUPPLY FORM APPROX. [%] EQUIVALENT WEIGHT APPROX. AUTO OEM

AUTO-REFINISH LARGE VEHICLES

HDI-based and trimer

Desmodur N 3600 HDI isocyanurate

Solvent-free

23.0

185

1,200

Desmodur N 3790 BA

HDI isocyanurate

90 BA

17.8

235

1,800

Desmodur N 3800

HDI isocyanurate

Solvent-free

11.0

380

6,000

Desmodur N 3900

HDI iminooxadiazine dione

Solvent-free

23.5

180

730

Desmodur XP 2675

HDI isocyanurate

Solvent-free

20.0

210

16,000

HDI-based and specialties

Desmodur XP 2580

HDI allophanate

Solvent-free

20.0

215

500

Desmodur N 3400

HDI uretdione

Solvent-free

21.8

195

150

Desmodur XP 2730

HDI uretdione

Solvent-free

22.7

185

90

Desmodur XP 2840 20

HDI uretdione

Solvent-free

23.0

185

500

WOOD FURNITURE INDUSTRIAL COATINGS

PARQUET TRADE

CORROSION PROTECTION

PROPERTIES & APPLICATIONS

PLASTIC COATINGS

FLOOR WALL

Low-viscosity crosslinker for weather-stable and nonyellowing high-solids and waterborne coatings for automotive refinishing,automotive OEM and industrial applications; also for structural coatings and topcoats Highly functional crosslinker for fast-drying, weather-stable and non-yellowing 2K-PUR coatings for automotive refinishing, automotive OEM and industrial applications For highly elastic coatings with resistance to accelerated and outdoor weathering; combination with suitable polyisocyanates allows variation of the elasticity using the same polyol mill base Low-viscosity crosslinker for lightfast 2K-PUR coatings (high-solids/waterborne e.g. in combination with Bayhydur types) for automotive refinishing, automotive OEM, transportation and plastics finishing applications Solvent-free, highly functional crosslinker for solvent-free 2K applications, outstanding weather-stability and gloss retention,non-yellowing

= especially suitable = suitable

Flexible, low-viscosity crosslinker for weatherstable highsolids and waterborne 2K-PUR coatings e.g. in combination with Bayhydur or Desmudur types, especially for industrial, automotive refinishing,transportation and plastic coatings Low-viscosity crosslinker for waterborne and solventborne 2K-PUR coatings; also for moisture-curing 1K-PUR systems, for structural coatings and topcoats Lowest viscous polyisocyanate, low isocyanate functionality, reactive diluent for various polyisocyanates Low-viscosity crosslinker for waterborne and solventborne 2K-PUR coatings; also for moisture-curing 1K-PUR systems, for structural coatings and topcoats

21

Desmodur Z Family: Fast-drying two-component polyurethane coatings with high chemical resistance.

TYPE

NCO CONTENT ON SUPPLY VISC. AT 23 C FORM APPROX. [%] APPROX. [mPas] SUPPLY FORM APPROX. [%] EQUIVALENT WEIGHT APPROX. AUTO OEM

AUTOREFINISH LARGE VEHICLES

HDI-based and specialities

Desmodur XP 2803

HDI allophanate

100

20

210

7,000

Desmodur XP 2714

Silane modified HDI poyisocyanate

100

15.9

264

1,350

IPDI-based
Desmodur Z 4470 SN IPDI isocyanurate 70 SN 11.9 360 2,000

Desmodur Z 4470 MPA/X IPDI isocyanurate Desmodur Z 4470 BA

70 MPA/X 70 BA

11.9 11.9

360 360

1,500 600

IPDI isocyanurate

Desmodur XP 2565

IPDI allophanate

80 BA

12.0

350

2,800

Desmodur XP 2489

HDI/IPDI polyisocyanate HDI/IPDI polyisocyanate HDI/IPDI polyisocyanate

Solvent-free

21.0

200

22,500

Desmodur NZ 1 Desmodur XP 2838

Solvent-free Solvent-free

20.0 21.0

210 200

3,000 3,000

22

WOOD FURNITURE INDUSTRIAL COATINGS

PARQUET TRADE

CORROSION PROTECTION

PROPERTIES & APPLICATIONS

PLASTIC COATINGS

FLOOR WALL

Highly functional crosslinker , outstanding weatherstability, gloss and improved chemical and scratch resistance for automotive OEM and plastics Crosslinker for improved adhesion

= especially suitable = suitable

Fast-drying hardener for lightfast 2K-PUR coatings with high resistance to chemicals and weathering. For automotive OEM, refinishing and industrial applications. On account of its high hardness, Desmodur Z is normally mixed with Desmodur N products See Z 4470 SN See Z 4470 SN Crosslinker for weatherstable, fast-drying high-solids and waterborne 2K-PUR coatings e.g. in combination with Bayhydur types, for automotive refinishing and transportation applications Outstanding weatherability, gloss and improved resistance for automotive OEM and plastics; especially for ulta high solid and solventfree applications, e.g. in-mould coating Solvent-free crosslinker for lightfast 2K-PUR systems; as a binder for solvent-free decorative floor coatings Solvent-free crosslinker for lightfast 2K-PUR systems; as a binder for solvent-free decorative floor coatings

23

Desmodur prepolymers based on aliphatic isocyanates like HDI or IPDI show good weather stability and are colour stable. These unique properties are important for applications such as corrosion protection or non-yellowing coatings and adhesives.

Prepolymers based on aliphatic isocyanates

HDI PREPOLYMERS Desmodur E XP 2747 Desmodur E 305 Desmodur XP 2617 Desmodur XP 2599 Desmodur E 3265 MPA/SN Desmodur E 3370 IPDI PREPOLYMERS Desmodur VPLS 2371 Desmodur XP 2406

SOLIDS CONTENT APPROX. [wt. %] NCO APPROX. [WT. %]

MONOMER CONTENT [WT. %] SOLVENT VISCOSITY APPROX. [mPas]

16.9 12.8 12.5 6.0 10.4 10.0

100 100 100 100 65 70

MPA/SN100 MPA/SN100

< 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5

2,600 4,000 4,250 2,500 1,200 1,400

3.7 2.8

100 80

MPA

< 2.0 < 0.5

11,000 7,000

24

VISCOSITY AT TEMPERATURE [C]

FUNCTIONALITY*

PROPERTIES & APPLICATIONS

COLOUR INDEX [IODINE]

EQUIVALENT WEIGHT APPROX.

23 23 23 23 23 23

n. m. n. m. n. m. n. m. 4 80 [Hazen]

HF LF LF HF HF HF

250 330 335 700 1,700 420

1K and 2K adhesives 1K and 2K adhesives 1K and 2K adhesives, bonding of granulated rubber 1K and 2K adhesives Anti-corrosion coatings, good weather stability, non-yellowing, 1K application Anti-corrosion coatings, good weather stability, non-yellowing, 1K application

* HF = H  igh functionality (> 3.6) LF = Low functionality (2.0 2.8) n. m. = not measured

23 23

n. m. 200 [Hazen]

LF LF

1,135 1,500

1K sealants Elastic coatings and sealants with very good weather stability

25

The key to easy and reliable application of waterborne 2K PUR systems.

TYPE

NCO CONTENT ON SUPPLY FORM APPROX. [%] SUPPLY FORM APPROX. [%] EQUIVALENT WEIGHT APPROX.

VISC. AT 23 C APPROX. [mPas]

Hydrophilic modified polyisocyanates

Bayhydur 3100 Bayhydur 304 Bayhydur 305 Bayhydur 401-70 Bayhydur XP 2451 Bayhydur XP 2487/1 Bayhydur XP 2547 Hydrophilic polyisocyanate (HDI) Hydrophilic polyisocyanate (HDI) Hydrophilic polyisocyanate (HDI) IPDI type hydrophilic modified Hydrophilic polyisocyanate (HDI) Hydrophilic polyisocyanate (HDI) Hydrophilic polyisocyanate (HDI)

100 100 100 70 MPA/X 100 100 100

17.4 18.2 16.2 9.4 18.6 20.6 22.5

240 230 260 440 225 205 185

2,800 4,000 6,500 600 1,200 5,400 650

Bayhydur XP 2655 Bayhydur XP 2700 Bayhydur XP 2759

Hydrophilic polyisocyanate (HDI) Hydrophilic polyisocyanate (HDI) IPDI type hydrophilic modified

100 65 PGDME 70 MPA

21.2 10.6 11

200 400 380

3,500 77 6,500

26

AUTO-REFINISH LARGE VEHICLES AUTO OEM

GLASS COATINGS

PLASTIC COATINGS PARQUET TRADE

FLOOR WALL CORROSION PROTECTION

PROPERTIES & APPLICATIONS

INDUSTRIAL COATINGS

WOOD FURNITURE

Versatile and economical Versatile use, improved mixing Easy mixing, high gloss Fast drying, chemical resistant Low viscosity, suited for solventfree formulations Highest chemical resistance Highest chemical resistance, low viscosity, suited for solvent-free formulations Highest chemical resistance, easy mixing Easy mixing, high gloss Fast drying, easy mixing, high chemical resistance

= especially suitable = suitable

27

Desmodur D and R: Hardeners for reactive, high-performance adhesives.

SUPPLY FORM APPROX. [%]

Hydrophilic modified polyisocyanates

TYPE

NCO CONTENT ON SUPPLY FORM APPROX. [%]

Desmodur DA-L

Hydrophilic polyisocyanate (HDI)

100

20.0

Desmodur DN

Hydrophilic polyisocyanate (HDI)

100

21.8

Special types water based

Desmodur XP 2802 Carbodiimide 40 % water 20.0

Special types
Desmodur RC TDI isocyanurate 35 EA 7.0

Desmodur RN

TDI/HDI isocyanurate

40 EA

7.2

Desmodur RE

Triphenylmethan-4,4,4-triisocyanat

27 EA

9.3

Desmodur RFE

Tris (p-isocyanatophenyl) thiophosphat

27 EA

7.2

28

EQUIVALENT WEIGHT APPROX. VISCOSITY AT 23 C APPROX. [mPas]

ADHESIVES

PROPERTIES & APPLICATIONS

210

3,000

Crosslinking agent for OH-functional polymer dispersions including polyurethane, polyvinyl acetate, polyacrylate and synthestic rubber dispersions. Improves resistance to heat, water, plasticizers and many solvents see DA-L

= especially suitable = suitable

195

1,250

210

30

Crosslinking agent for aequous dispersion polymers containing carboxyl groups. The product is characterized by its long potlife

600

Hardener for 2K-PUR systems, especially for industrial adhesives applications. Especially palecoloured adhesives used to bond rubber materials Hardener for 2K-PUR systems especially for industrial adhesives applications. For the use in adhesives to achieve significantly reduced discoloration on exposure to light Hardener for 2K-PUR systems especially for industrial adhesives applications. Highly effective crosslinker for adhesives based on Desmocoll, natural or synthetic rubber, with special adhesion on rubber materials Hardener for 2K-PUR systems especially for industrial adhesives applications. A crosslinker with very universal suitability for adhesives based on Desmocoll, natural or synthetic rubber, with special adhesion on rubber materials 29

585

11

450

583

Desmodur BL Family: In combination with Desmophen types for 1K-PUR stoving systems with high grade polyurethane properties. Aliphatics types are light-stable and weather-resistant.

TYPE

BLOCKED NCO CONTENT ON SUPPLY FORM APPROX. [%] SUPPLY FORM APPROX. [%] EQUIVALENT WEIGHT APPROX.

VISC. AT 23 C APPROX. [mPas]

Aromatic blocked polyisocyanates

Desmodur BL 1100/1 Desmodur BL 1265 MPA/X TDI polyisocyanate TDI polyisocyanate

100 65 MPA/X

3.0 4.8

1,400 875

43,000 20,000

Aliphatic blocked polyisocyanates

Desmodur BL 3175 SN Desmodur BL 4265 SN Desmodur BL 5375 Desmodur BL 3575/1 Desmodur PL 350 Desmodur PL 340 Desmodur BL 3370 MPA Desmodur BL 3475 BA/SN Desmodur BL 3272 MPA Desmodur VP LS 2078/2 HDI polyisocyanate IPDI polyisocyanate H12 MDI polyisocyanate HDI polyisocyanate HDI polyisocyanate IPDI polyisocyanate HDI polyisocyanate HD/IPDI polyisocyanate HDI polyisocyanate IPDI polyisocyanate 75 SN 65 SN 75 MPA/SN 75 SN/MPA 75 SN/MPA 60 SN/BA 70 MPA 75 BA/SN 72 MPA 60 SN 11.1 8.1 8.9 10.5 10.5 7.3 8.9 8.2 10.2 7.0 380 520 470 400 400 575 470 510 410 600 3,300 11,000 4,000 3,600 4,300 600 3,800 1,000 2,700 2,000

30

INDUSTRIAL COATINGS AUTO OEM

CAN COATINGS GLASS COATINGS

PROPERTIES & APPLICATIONS

COIL COATINGS

In combination with cycloaliphatic diamines for 1K stoving primers with high film thickness and good stone-chip resistance For primers

= especially suitable = suitable

Standard product Standard product High flexibility Lower thermal yellowing and lowest color value Lower thermal yellowing Lower thermal yellowing High reactive High reactive Very high film thickness  Worldwide first and only polyurethane crosslinker with FDA-Food Contact Notification, which may be used in combination with FDA conform polyol, very high film thickness

31

Specialty polyurethanes

TYPE

VISC. AT 23 C APPROX. [mPas] SUPPLY FORM APPROX. [%] BLOCKED NCO CONTENT ON SUPPLY FORM APPROX. [%]

Solvent-free blocked urethane resins

Desmocap 11 Desmocap 1190 Desmocap 12 TDI-branched prepolymer TDI-branched prepolymer TDI-linear prepolymer

Solvent-free 90 Adimoll DO Solvent-free

100,000 30,000 40,000

2.4 2.2 1.6

Self-crosslinking baking urethane resins

Desmotherm 2170 MDI self crosslinking baking urethane resin 70 BA/SN/IB 2,000

Desmotherm VP LS 2218

HDI aliphatic self-crosslinking baking urethane resin

93 BA/SN

11,000

32

EQUIVALENT WEIGHT APPROX. AUTO OEM

FLOOR WALL CORROSION PROTECTION

PROPERTIES & APPLICATIONS

1,750 1,910 2,625

For elastic coatings and sealants; for the flexibilization of epoxy resins For elastic coatings and sealants; for the flexibilization of epoxy resins For elastic coatings and sealants; for the flexibilization of epoxy resins; stronger flexibilizing effect than Desmocap 11

= especially suitable = suitable

For 1K-PUR baking coatings (primers and primer-surfacers) For high-solids 1K-PUR baking coatings, especially for OEM primer-surfacers with improved elasticity, impact resistance adhesion; also as an additive to improve mechanical film properties and stone-chip resistance in conventional baking coatings

33

TYPE

NEUTRAL AGENT SUPPLY FORM APPROX. [%] ORGANIC CONSOLVENT CONTENT [%] IN

Blocked polyisocyanates for 1K waterborne stoving systems

Bayhydur BL 5335 Bayhydur BL XP 2706 Imprafix 2794 XP Baybond XL 6366 Baybond XL 825 Baybond XL 7270 Blocked, aliphatic polyisocyanate (W) Blocked, aliphatic polyisocyanate (HDI/ IPDI) Blocked, aliphatic polyisocyanate (HDI) Blocked, aliphatic polyisocyanate (HDI) Blocked, aliphatic polyisocyanate (HDI) Blocked, aliphatic polyisocyanate (HDI)

35 42 40 45 30 30

DMEA

MPA 4.5/X 4.5 0 0 0 0 0

Self crosslinking urethane resins for 1K water-borne stoving systems

Bayhytherm 3146 Aliphatic, self-crosslinking baking urethane resin 46 DMEA NMP 1, SN/MPA 3*

34

NCO CONTENT [%] ON SOLIDS AUTO OEM

INDUSTRIAL METAL GLASS COATINGS

PROPERTIES & APPLICATIONS

7.1 (blocked) 8.6 (blocked) 12.4 (blocked) 9.6 (blocked) 10.0 (blocked) 14.0 (blocked)

n combination with Bayhydrol U XP 2239 for glass and can I coatings with good alkali resistance Higher reactivity, DHP blocked, excellent thermostabilty (yellowing) and better chemical resistance High reactivity (DMP blocked) very good thermostability (yellowing), good caustic resistance Medium reactivity (MEKO blocked) Low reactivity (CPL blocked), thermostability (yellowing) Low reactivity (CPL blocked), thermostability (yellowing)

* NMP-free alternatives available = especially suitable = suitable

 or OEM primer surfacers with high solids content; also for F general industrial coatings

35

Hardeners for high-grade, lightfast powder coatings with polyurethane quality.

TYPE

Tg [C]

Powder hardeners
Crelan EF 403 Crelan UI Crelan NI-2 Internally blocked linear IPDI polyisocyanate Blocked linear IPDI polyisocyanate Blocked branched IPDI polyisocyanate Blocked branched IPDI polyisocyanate Blocked branched W polyisocyanate

SUPPLY FORM

BLOCKED NCO CONTENT ON SUPPLY FORM APPROX. [%]

Flakes Flakes Prills

4055 60 5560

(13.5) internally (11.5) (15.0)

Crelan VP LS 2256

Flakes

4658

(15.0)

Crelan NW-5

Prills

4858

(12.7)

36

EQUIVALENT WEIGHT APPROX.

STANDARD BAKE CYCLE PROPERTIES & APPLICATIONS

FUNCTIONALITY* APPROX.

310 365 280

LF LF LF

15 min/180 C 15 min/180 C 15 min/180 C

For emission-free powder coatings with outstanding levelling and pigment wetting and for special one-shot matte coatings For powder coating with good levelling and good pigment wetting or to improve coating properties of hybrid and TGIC systems For economical standard powder coatings with good levelling, good pigment wetting and outstanding corrosion resistance For high chemical resistance powder coatings with easy to clean properties and standard powder coatings with good overall properties For higher reactive powder coatings with excellent flexibility and corrosion resistance properties

* LF = Low functionality

280

LF

15 min/180 C

335

LF

15 min/175 C

LEGEND
BA DMEA EA HDI IB IPDI MDI = Butyl acetate = Dimethyl ethanol amine = Ethyl acetate = Hexamethylene diisocyanate = Isobutanol = Isophorone diisocyanate = Diphenylmethane diisocyanate MPA NMP PGDME SN TDI VP LS... XP... X = Methoxypropylacetate = N-Methyl pyrrolidone = Dipropylenglycoldimethylether = Solvent naphtha = Toluene diisocyanate = Trial products = Xylene

37

more than just products

Sustainability @ CAS

Bayer is committed to the principles of sustainable development. We want to fulfill this commitment in three areas: products and innovations, business practices and corporate social responsibility. Innovations are the driver of sustainability in the CAS Business Unit. Our raw materials make more sustainable and durable solutions possible in our end users products. This applies especially to greenhouse gas emissions, health protection and energy consumption. In production our priority is a high standard of occupational health and safety as well as energyand resource-saving processes. We focus our developments on advanced product technologies that are safe in their application and provide economic and ecological advantages over the whole value chain from raw materials through processing to the end-of-life. The emphasis is on waterborne products, solvent-free products and those with a high solids content. We are investigating the potential of renewable resources for new high-performance products while also taking ethical standards into account. Our main aim is to conduct our business successfully and sustainably. For us this means achieving commercial success on the basis of sound business models and in a way that is compatible with the needs of our employees and society, protects the environment and preserves our natural resources.

38

WE ARE WHERE YOU ARE

Global partnerships

Our global presence also means local presence. You can rely on us wherever in the world you are thanks to our global supply chain management. With production sites in most of the worlds strategically important regions, we aim for short lead times and short routes to your production site. Our quality, fast application support and expert advice are available to you wherever you are. Success is also dependent on the right timing. Speed, flexibility, fast development in response to market requests, efficient production and delivery we will help you to deliver these crucial factors. Because your success is ours as well.

39

This information and our technical advice whether verbal, in writing or by ways of trial are given in good faith but without warranty, and this also applies where proprietary rights of third parties are involved. The information is provided by Bayer MaterialScience AG without assumption of any liability. If any of the above mentioned regulations change after the date of declaration, this declaration is no longer valid. Bayer MaterialScience AG will strive to keep this information up-to-date. Our advice does not release you from the obligation to verify the information provided especially that

Bayer MaterialScience AG 51368 leverkusen Germany www.bayercoatings.com cas@bayermaterialscience.com

contained in our safety data and technical information sheets , to check for updates of any information provided by us and to test our products as to their suitability for the intended processes and uses. The application, use and processing of our products and the products manufactured by you on the basis of our technical advice are beyond our control and, therefore, entirely your own responsibility. Our products are sold in accordance with the current version of our General Conditions of Sale and Delivery. edition: MS00063645 Order-No.: 2013-03 Printed in Germany e