ANSWERS TO PAPER I

PHYSICS
1. As angle between voltage and current is 90 Power = 0 (d)

2.

As they collide elastically so there velocity hence kinetic energy gets exchanged. So B will rise to 4h and A will rise to h (a) Electric field = 1000 N, (a)
dV E.dr 1000 1 10
2

3.

10 V

4.

As in + particle emission proton is converted into neutron neutron to proton ratio increases (a) Applying Kirchoffs voltage law in a loop 2 12 I 4 I 0 2 16 I 1 3 A I 3I 8 8 (b) (a) For a pure inductor circuit potential , V
i i0 sin t 2
V0 sin tV V0 sin t and current
4 I 4 4 4 I I 3I 2V A

5.

6. 7.

thus angle =

(c) 8. Frequency of 1st source [

1

= 100 cm]
2

f1

v
1

Frequency of second source [ Beat frequency = f1 = 396 (d)

= 90 cm]
v
1

f2

v
2

f2

v
2

1 1 90 100

100

396 10 100 90 100

44 Hz.

9.

vrm s.

3RT M and R are constant for the same gas. M v 300 vrm s T , T = 1200 K. 2v T (d)
mv 2 rn 1 4
0

10.

We know that,

Ze 2 (i) and according to Bohrs model mvrn rn2 mn 2 h 2 4 2 m 2 rn3 1 4

0

nh 2

putting v = in (i) we get

Ze 2 rn2

rn

n2 0h2 mZe 2

rn

n2

where h = Planks constant, m = mass of electron Z = atomic weight, n = principal quantum number (d) 11. Refractive index,

B
2

(Cauchys law)

So, refractive index depends upon the wavelength of the light. (b)

12.

We know that, E = V/d 0.5 E 1 10 6 V/m 7 5.0 10 (a) As the capacitors are identical, they will finally have charge Q/2 each.
Q2 2C (Q / 2) 2 Final energy of the system = Ef = 2 2C

13.

Initial energy of the system = Ei =

Q2 4C

Heat produced = loss in energy = Ei Ef = (b) E=

dV dx (a)

Q2 4C

14.

8x

at

(1, 0, 2) E

8i

15.

Equation of trajectory, y

x tan
(i)

1 gx 2 2 u 2 cos 2

tan
u cos
T

1
g
2 g g

(ii)

2u sin g
(b)

2 g

16.

Pressure at depth h = P hgd Pressure inside the bubble will be P h d (b)

2T r

17. 18. As T

(c)

R3/ 2 , T1
(b)

KR 3 / 2 ,

T2

KR 3 / 2 (1.01)3 / 2 ,

T2 T1

T1

100 1.5%

19.

mg ' mg m 2 R 3 mg mg m 2 R 5 2mg m 2R 5 2g 5R (a)

mg

m 2R

20.

When the end A is stopped, reaction force is acted upon end A hence angular momentum about end A is conserved 4ma 2 mva 3 3v 4a (d)

R A 2a v B

21.

r1
I

m2 r and r2 m1 m2
m1r12 m2 r22
2 m1 m2 (m1 m2 ) 2

m1r m1 m2
m1 r1 r2 m2

m2 m12 r2 (m1 m2 ) 2

m1 m2 2 r m1 m2

(a) 22. 23. (c)

2v 2 sin cos 2 v 2 sin 2 g 2g tan 2 v 2 sin 2 2v 2 sin cos Range = g g (a)

As C

4v 2 5g

24.

5F 9 (b)

5 32 9

dC dF

5 9

25.

As internal energy can be increased by doing work also. (c) (c) As temperature and surface area is same (a) As density is maximum at 4C and volume in both case increases (a)

26. 27.

28.

29.

f'

v v0 332 10 , f' f v vs 332 10

(c)

1000

vs

vo

30.

The particle may move along x-axis and y-axis (a)

31.

Intensity (c)

40 , r2

40 3 (25) 2

40 t (50) 2

3 (2) 2

12 s

32.

As P P2 1 (d)

Peq ,

100 80

100 P2 , 20

P2

100

1 80

1 20

100

3 80

3.75 D

33. 34.

(c) Let F is the upward force then Mg F In second case F ( M m) g ( M m) , Mg ( M m) g (2M m) , 2M m g (b) As force is maximum at extreme position (a) 7
1

M Mg F M mg 2M m

35.

Acceleration is maximum at that point

36.

= d1 = 7 (a)

1D

2d

and 7

= d2 = 7

2D

2d

d1 d2

1 2

37.

Work done is area under PV diagram = PV (a)

38.

(b)

39.

VD

4i , (c)

VM

4j,

VDM

4i 3 j ,

| VDM | 5

40.

As net external force on the system is zero hence centre of mass does not move (b) Current through loop = ne Magnetic field at centre = (b)
e

41.

ne 2r
0

42.

As

V1 V2

n1 , n2 (a)

V2

n2 V1 n1

240 V

43.

(d)

44.

Taking potential of point A to be zero Potential of E = 1V Potential of C = 1 + 2 = 1V Potential of D = 1 3 = 4V (a)

A 2 C 1V

2 1 E 2V 3V

1V

B 2 D

45.

hc eV So if voltage is doubled cut off wavelength is halved. (b)

As eV ,

hc

46.

Let N0 is initial no of nucleus of X 1 N0 Yt N 0 1 , , Xt t/2 (2) t / 2 (2) 8 (2) t / 2 8 , , 1 t/2 (2) (a)

N0 1

1 (2)t / 2

N0 (2) t / 2

t=6

47.

h mv

6.63 10 34 10 31 105 (b)

6.6 10 8 m

48.

As K.E. of an electron does not depend on intensity (b) Drawing the phasor diagram, potential drop across Resistor = 100 V I = 2 amp (a)

49.

400 100 400

50.

If I1 is the current in coil of radius R1 then magnetic field at the centre of small coil = 0 I 1 N1 2 R1 Flux through circular coil
M
0 2 N1 N 2 R2 2 R1

0 1

I N1 2 R1

2 R2 N2

I1

(b)

51.

Potential difference across the ring of radius x and width dx R B R2 Bdx x 2 0 (d)

D x dx

52.

As M
M 1T12

1 , M is pole strength and T is time period T2

4M 1T22 , M 1 4 4M 1T22 ,

T2 1

(c) 53. (c)

54.

As cyclotron frequency f 0 (c)

qB 2 M

55.

I
M

2q

2
R2 2q R 2 2
2 R mR 2m R 2

2q 2

Angular momentum L

M L
(a)

q R2 2m R 2

q 2m

56.

Magnetic field can change only direction (b)

57.

If Ti is inversion temperature then (b)

Ti

270 270 20 ,

Ti

520 C

58.

As potential difference across each resistance is same

3663
Rs

I 34

33I Rs , 34

3663 33

Rs

I/34

Soj = 3663 33I/34 Rs

111

(b)

59.

Assuming potential at C to be zero Potential at A = 3V Potential at B = 2V

A 2 2 amp D 3 B C 2 3

VA VB 1V
(b)

60.

Let internal resistance be ri Current in loop I

V E Iri
E r ri
r I E ri

Eri r ri

ri

E V r V

(c)

CHEMISTRY

61. 62. 63. 64.

(d) (a) (b) (c)

NO 3 + 4H+ + 3e

.. .. .. :O=O: O: ..

.. + .. O=O .. .. O: ..

+ ..

.. .. :O O .. O: ..

2H2O + NO (+2)

(+5) 65. (a)

In ionic reactions only ions are exchanged and oxidation states remain same. CaCO3(s)
(+2) (+4) ( 2)

CaO(s) + CO2(g)
(+2) ( 2) (+4)

66. 67.

(d) (b)

nO2 nn2

2 32

125 1 x 4 x = 0.5, wH2 = 0.5 2 = 1 gm

68. 69. 70. 71. 72. 73. 74. 75. (a) (b) (c) (c) (c) (b) (a) (d) Greater the s character, more acidic is the hybridised carbon atom. Alkali metals form oxides, peroxides and superoxides. Reactivity with water increases due to rapid decrease in ionisation energy on moving down the group.

Conjugated diene are generally highly stable; hence in the case of such types of diene heat of hydrogenation is minimum. Terminal alkynes react with amm. AgNO3 or Ag ( NH 3 ) 2 OH precipitate.
H / Hg2

76.

(b)

to give white

OH CH=CH2

O CH CH3

77. 78. 79. 80. 81.

(c) (b) (b) (a) (b)

CH CH + H2O

82. 83. 84. 85. 86. 87. 88.

(c) (a) (a) (a) (b) (b) (a)

In AgNO3 + NaCl AgCl + NaNO3, only ions are exchanged hence this reaction is an ionic reaction.

K2Cr2O7 2 + 2x + 4 = 0 x = +6

K2CrO4 2+x 8=0 x = +6

89. 90. 91. 92. 93. 94. 95.

(d) (d) (a) (c) (b) (c)

Electronegativity difference for O H bond is maximum among given compounds. Decreasing order of stability of free radicals obtained in halogenation of alkanes is (3 > 2 > 1).

(c)

Fe C 2O 4 + MnO 4
n=3 n=5

Fe CO2 + Mn2+

5 mole of MnO 4 = 3 mole of FeC2O4 Mole of MnO 4 96. (c) Fe+2 S 22 FeS2 =

3 3 1= . 5 5

Fe+3 + e 2S+4 + 10e 2S+4 + Fe+3 + 11e molar mass Equivalent mass of FeS2 = . 11

97. 98. 99.

(d) (b) (b) For a bcc structure, Z = 2 M=

a3 NA 8.0 (250 10 10 ) 6.02 10 23 = = 37.6 g mol 1. Z 2

100.

(a)

Kp =

PCl2

PPCl3

PPCl 5

Since, at equilibrium moles of each component is same, so partial pressure be same 2 i.e. PCl2 = PCl3 = PCl5 = 3 =1 6 Kp= 1. 101. 102. 103. 105. (b) (c) (c) (a) t=

a 2.303 2.303 20 2.303 = log o = log log 8 = 30 min. K at K 2.5 0.0693 Po P = Xsolute or 1 Po
Po P =1 Po

Xsolute = Xsolvent =

P . Po

H = U + ng RT H U = ng RT =

3 8.314 298 = 7.43 kJ mol 1. 1000

106. 107. 108.

(d) (b) (a)

0.059 1 ; Eo log cell = 0.54V. 2 0.1 Mn7+ + 5e Mn2+ Thus, 5 moles of electron = 5 faraday.
Ecell = E o cell Using the relation rate (conc. of reactant)n where n is order of the reaction. In the question, since rate is directly proportional to the conc. of reactant, hence the reaction is of first order. Total geometrical isomers = 2n = 22 = 4.

109. 110. 111. 112.

(b) (c) (d) (b)

H+ will attack the double bond and would give

CH3CH2 CH

OH

which would be resonance stabilized. 113. 114. 115. 116. 118. 119. 120. (d) (c) (b) (c) (c) (b) (c)