Art Montemayor

Project Crude Oil Tank

July 29, 2002 Rev: 0

Summary of Relief Calculations for T-201 The Fire Case is the Controlling Case for Pressure relief; the required relief capacity for this case is 523,215 Scfh. The existing installed pressure relief capacity in the existing 12 Varec Model 2020B1 PVSV is approximately 200,000 Scfh according to Varec Representative in Houston, George Izaguirre. Existing pressure emergency relief in the existing 24 Varec Model 221P is 750,000 Scfh according to Varec Representative in Houston, George Izaguirre. Therefore, the existing pressure capacity in T-201 for the new, proposed operating conditions is 723,000 Scfh. No additional relief capacity is required for T-201 in the manner of a PVSV or an emergency Fire Hatch since the present hardware will be sufficient to protect the tank from the worst pressure relief scenario (the Fire Case). T-201 also has an existing vacuum capacity sufficient for the new, proposed operating conditions. In the event that steam-out procedures will be used on T-201 in the future, at least 12 ft2 of open roof nozzle area should be available for this tank in order to avoid a vacuum structural failure during a rainstorm while the tank is being steamed-out. This nozzle area can be made up of existing and/or future Fire Hatches as well as any existing roof manways.

Page 1 of 13

FileName: 161249533.xls.ms_office WorkSheet: Summary of Results

Art Montemayor

Oil Recovery Attachment 1

November 24, 2001 Rev: 2(07/24/02)

Tank Padding Calculation Sheet

Data Entry

Stored Material Flash Point Boiling Point Latent Heat vap. Mol. Wt. Inflows Tag
Product Product Product

Crude Oil F 350 (Estim.) o F 360 (Estim.) Btu/lb 144.0 (Hexane) 274.0
o

Tank MAWP Max Vacuum Diameter Max fill

T - 201 in WC oz/in2 ft ft 3.50 0.50 130.0 40.0

Service
Transfer to Storage Transfer to Storage Transfer to Storage

Line No.
20"-PL-354-D 12"-PL-756-D 12"-PL-756-D

P &ID # 115-01 -157 -157 -157

Max Head Value 125 50 135 Units PSIG PSIG PSIG

Flow, GPM Note 1 1,313 292 729

or : or : or :

Total Inflows, gpm Sonic Flow in Pipe Pipe Flow at Maximum DP 135 psi Other (Attach Method) Use for Relief (gpm) Normal Maximum (gpm) (Note 3) 24"-PL-356-A 24"-PL-356-A 24"-PL-356-A 12"-OP-1910-AA1 12"-OP-1910-AA1 4"-DRG-2900-AA1 4"-DRG-2900-AA1 -157 -157 -157 -157 -157 -157 -157 75 75 75 100 100 65 65 psig psig psig psig psig psig psig

2,333

2,333 2,500

Outflows (See Note 1)

P-2200 P-2210 P-2220 P-202A P-202B P-201A P-201B Booster Booster Booster Transfer Transfer Drain Drain 2,000 2,000 2,000 1,500 1,500 60 60 9,120

Total Outflows, gpm Notes: 1) Pumps are at zero head flowrate (Max. gpm), and Control Valves have the max. trim size (Max. Cv) 2) The above pump capacities are estimated due to a lack of pump performance curves. 3) The "Normal maximum" pump-in rate will be used for the tank relief calculations

Page 2 of 13

Electronic FileName: 161249533.xls.ms_office WorkSheet: Data Entry

Art Montemayor

Oil Recovery Attachment 2

November 24, 2001 Rev: 4(04/20/08)

Tank Pressure & Vacuum Protection

Design Sheet - Based on Data Entry Sheet Stored Material: Crude Oil Tank: o F Flash Point 350 (Estim.) MAWP o F Boiling Point 360 (Estim.) Max Vacuum Latent Heat Vap. Btu/lb 144 (Hexane) Diameter Molecular Wt. 274 Max fill Height Max fill Volume Inflows, SCFH (Note 3) Wetted Area Normal Operation 21,429 Relief Scenario 21,429 Fire (Note 2) Unit Heat Input Required Capacity Outflows, SCFH 73,150 Blow-Through From Upstream Breathing, Note 1 Flashing Feed Out SCFH 56,737 In SCFH 64,528 Vacuum Rain Storm Cooling Vent Valve set at Required selected Fail Open N.A. in WC SCFH NA SCFH NA SCFH 0 T - 201 in. WC oz/in2 ft ft gal ft2 BTU/hr-ft2 SCFH SCFH SCFH MM Scfh

Consider this when using an emission vapor control system on the tank Normal max inflow + out breathing With vent system Pressure Drop of 9 in WC Consider this only if the tank vents to a vacuum source or header

Blanket Gas Feed Valve (set at 7" WC) Required SCFH N. A. Selected SCFH N. A. Valve Fail Open SCFH N. A.

Sum of all outflows + in Breathing + failed open vent valve Fisher Model 1190 Regulator w/ This flowrate assumes the valve's Cv determines the capacity

Pressure and Vacuum Relief Cases Inflow (Pressure) SCFH 78,166 Relief Inflow + Out Breathing Fire (Pressure) SCFH 523,214 Fire Case vapors evolved Outflow (Vacuum) SCFH 137,679 sum of outflows + in Breathing Notes: 1) For Tanks larger than 840,000 gal (20,000 Bbls), refer to API-2000 for breathing requirements. 2) Fire Case calculations are according to API Standard 2000, 5th Ed., Section 4.3.3.2.1; Design pressure < 1.0 psig 3) The wetted area is equal to the total surface area of the vertical shell to a height of 30 ft (API 2000; Table 3A)

Page 3 of 13

Electronic FileName: 161249533.xls.ms_office WorkSheet: Design Basis

Art Montemayor

Oil Recovery

November 24, 2001 Rev: 4(04/20/08)

T - 201 3.5 0.5 130.0 40.0 3,971,616 12,252.2 1,150 523,214 0 0 0.0

system on the tank

rce or header

valve " trim.

e capacity

essure < 1.0 psig 00; Table 3A)

Page 4 of 13

Electronic FileName: 161249533.xls.ms_office WorkSheet: Design Basis

Art Montemayor

Recovery Attachment 3 TANK: T - 201

November 24, 2001 Rev: 3(04/20/08)

Storage Tank Pressure/Vacuum Equipment Specifications for Procurement

Conservation Vent Pressure side set at 1.8 in. W.C. Rated at 2.0 in. W.C. Required SCFH 523,214 zero (if have Vent Valve and Emergency vent) or worst case Selected Size SCFH each from catalog; total number Total 2 2 oz/in Vacuum Side set at 0.5 oz/in Vacuum, rated at 2 1/2 Required SCFH 137,679 Outflow Case Selected Capacity SCFH each from catalog; total number 1 Total Emergency Pressure Relief, Note 1 Set at in. W.C. Required SCFH Selected Size SCFH N. A. Emergency Vacuum Relief oz/in2 Set at Required SCFH Selected Size SCFH

Rated at in. WC 0 zero (if Con vent has capacity) or Worst case w/o Con Vent each from catalog; total number Total

Rated at in. WC 0 zero (if Con vent has capacity) or Worst case w/o Con Vent each from catalog; total number Total

Selected Equipment: Blanket Gas Regulator Nitrogen Valve Conservation Vent Emergency Vent (exist.) Emergency Vent (New)

Tag N. A. N. A. PVSV-T20106 PSV-T20105

Manufacturer

Model

Size, in

Varec Varec

2020B 1 221P

12 24

Notes: 1) A Fire hatch may be required if: cone roof tank does not have a weak roof seam, or if the Conservation Vent does not have sufficient liquid flow capacity. Rated Pressure Capacity, Scfh 200,000 750,000 950,000 523,214 426,786 Rated Vacuum Capacity, Scfh 150,000 0 150,000 137,679 12,321

This existing tank has the following relief devices installed on it: 12" Varec Model 2020B1; set @ 1 oz/in2 24" Varec Model 221P; set @ 2 oz/in2 Total installed Capacity Total Required Capacity Excess Installed Capacity

Note: The above Varec Capacities are taken from Varec Vapor Control Product Manual; pages 40 and 101. The existing, installed Varec relief devices have sufficient pressure and vacuum capacity for the worse cases. No new or additional relief devices are necessary for this storage tank under the calculated conditions.

Page 5 of 13

Electronic FileName: 161249533.xls.ms_office WorkSheet: Requisition Info

Art Montemayor

Recovery

November 24, 2001 Rev: 3(04/20/08)

curement

rst case 0

on Vent 0

on Vent 0

Cv

rvation Vent

ted Vacuum Capacity, Scfh 150,000 0 150,000 137,679 12,321

40 and 101.

worse cases.

Page 6 of 13

Electronic FileName: 161249533.xls.ms_office WorkSheet: Requisition Info

Art Montemayor Storage Tank: Fluid:

Oil Recovery Attachment 4 T - 201 Crude Oil

November 24, 2001 Rev: 3(4/20/08)

Safety Scenario Relief Rates, CFH Pressure Scenario Vacuum Scenario Liquid Steam-Out Inflow Fire Case Outflow Other Overflow (Note 1) Case Contributions: 1 Liquid movement in 2 Liquid movement out 3 Out Breathing (Vapor out) 4 In Breathing (Vapor In) 5 Fire Exposure 6 Pressure Transfer Blow-through 7 Blanket Gas Failure - Blocked 8 Blanket Gas Failure - Open 9 Steam Coil Rupture 10 Vent System Failure - Blocked 11 Chemical Reaction 12 Flashing Feed 13 Steam-Out Total Volumetric Flow: 21,429 N.A. 56,737 21,429 N.A. N.A. 73,150 N.A. N.A. N.A. 64,528 N.A. N.A. N.A. N.A. N.A. (Note 2) N.A. N.A. N.A. N.A. N.A. N.A. N.A. N.A. N.A. N.A. N.A. 137,679 N.A. N.A. N.A. N.A. N.A. N.A. N.A. N.A. N.A. N.A. N.A. 46,078,883 46,078,883 0

N.A.

N.A. N.A. N. A. N.A. N.A. N.A. N.A. 78,166

523,214 N.A. N.A. N. A. N.A. N.A. N.A. N.A. 523,214

Controlling Pressure Case Design Capacity = Controlling Vacuum Case Design Capacity =

654,017 cfh (Includes 25% contingency) 172,098 cfh (Includes 25% contingency)

Air density = Blanket gas density = Blanket gas Molecular Weight = Blanket gas density = Blanket gas specific gravity =

3 0.0807 lb/ft 3 0.33425 lb/ft 25.237 3 0.083877 lb/ft 3 1.0394 lb/ft

at at

o 32 F o 109 F

and and

14.696 psia 79.7 psia

at at

o 109 F o 109 F

and and

20 psia 20 psia

Note 1: The steam-out case is calculated in another Worksheet; relief protection is recommended in the form of 3 - 30" roof-located manways that are required to be left open while steaming out the tank. Note 2: No blanket gas is applied on this tank. The maximum operating vacuum rate is set by the maximum pump out of the tank's content.

Page 7 of 13

Electronic FileName: 161249533.xls.ms_office WorkSheet: Case Summaries

Art Montemayor

Storage Tank Pressure Relief Over-Pressurization Scenario Contributions Consider Event when calculating CASE: 1 Press. Yes No No No No No No No No No No No N. A. 2 Vacuum No Yes No No No No No No No No No No N. A. 3 Press. No No Yes No No No No No No No No No N. A. 4 Press. No No No Yes No No No No No No No No N. A. 5 Press. No No No No No No No No No No No No N. A. 6 Press. Note 2 Note 2 No No No No No No No No No No N. A. 7 Press. Note 2 Note 2 No No No No No No No No No No N. A. 8 Press. No No No No No No No No No No No No N. A. 9 Press. Note 2 Note 2 No No No No No No No No No No N. A. 10 Press. No No No No No No No No No Note 3 No No N. A.

November 22, 2001 Rev: 2(07/18/2002)

No. 1 2 3 4 5 6 7 8 9 10 11 12 13

Event Liquid Movement in and Breathing Out Liquid Movement Out and Breathing In Fire Exposure Pressure Transfer Blow Through Blanket Gas Regulator Failure Failure or Loss of Control - Heat Transfer Devices Failure of Internal Heating / Cooling Coils Failure of Vent Treatment System Failure of Utilities (Steam, Nitrogen, air, CWS) Chemical Reaction Liquid Overfill Flashing Liquid Feed Steam Out (Note 4)

11 Press. No No No No No No No No No No No No N. A.

12 Press. No No No No No No No No No Note 3 No No N. A.

Notes: 1) This event is when the vent valve feeding tank vapors to a vapor treatment system fails closed. 2) Either or both liquid movement events could be applicable depending on the system. 3) Consider this event if the fluids involved normally, or potentially, can cause a reaction 4) Steam Out is a special case that is handled and calculated independently in another spreadsheet; a properly sized nozzle is usually specified to be left open for this case.

Comments on scenarios for Tank T - 201: Event No. 4 is not considered a credible scenario since all liquid transfer into tank is done by pumping, not pressure transfer. Event No. 5 is not considered a credible scenario since no blanket gas is fed into the tank. Event No. 6 is not considered a credible scenario since this tank does not incorporate a heat transfer device or internal coil. Event No. 7 is not considered a credible scenario since this tank does not incorporate an internal coil that could rupture. Event No. 8 is not considered a credible scenario since this tank does not incorporate a Vapor Treating System. Event No. 9 is not considered a credible scenario since no utilities are connected to this tank. Event No. 10 is not considered a credible scenario since the compounds and fluids with potential for introduction into the tank do not react with each other or polimerize. Event No. 11 is not considered a credible scenario since the tank has been designed according to API Standard 2000, 5th Ed.; article 4.2.5.10 Event No. 12 is not a possible scenario.

Page 8 of 13

Electronic FileName: 161249533.xls.ms_office WorkSheet: OverPressure Scenarios

Art Montemayor

Storage Tank Pressure Relief

May 14, 2002 Rev:2(07/18/2002)

Determination of Inflows and Outflows for Storage Tanks for use when calculating Normal and Emergency Venting Requirements
No. Event 1. Liquid Movement in and Breathing Out Inflow / Outflow Inflow

2. Liquid Movement Out and Breathing In

Outflow

3. Exposure to Pool Fire with subsequent tank contents' vaporization

Inflow

4. Pressure Transfer Blow-through 5. Inert Gas Pad/Purge Regulator Failure 6. Failure or loss of Control Heat Transfer Devices 7. Failure of Internal Heating/Cooling Coils

Inflow Inflow Either or both

Either or both

8. Failure of Vent Treatment System 9. Failure of Utilities (Air, Steam, Cooling Water, N2, etc.) 10. Chemical Reaction 11. Liquid Overfill 12. Flashing Liquid

Outflow Either or both

Inflow Inflow Inflow FileName: 161249533.xls.ms_office WorkSheet: Inflow-Outflow

Page 9 of 13

Art Montemayor

Storage Tank Pressure Relief

May 14, 2002 Rev:2(07/18/2002)

on of Inflows and Outflows for Storage Tanks ulating Normal and Emergency Venting Requirements
Calculate Inflow or Outflow by: Determine the Maximum flow, at zero head, for each pump that can be lined up to the tank. For sources that are not pump driven, calculate the maximum flow for the flow limiting element. For Control valves, use the largest trim for the valve body and add the capacity of any bypass valves. The total inflow is the sum from all of these sources. The total inflow can be reduced if engineering judgment indicates that it is unlikely that all of the sources will be feeding into the tank simultaneously. The total inflow can also be reduced if the pressure drop in the line(s) between the inlet manifold(s) and tank exceeds the available pressure drop. The available pressure drop is the highest pressure sources dead head pressure.

Determine the Maximum flow, at zero head, for each pump that can take suction from the tank. The Outflow is the sum of all of these; even installed spare(s). Do not consider inflow for fire case since there is ample time to shutoff the inflow before the fire case fully develops. (see also API-2000 3.4.3.1.4) Do consider the failure of the blanketing gas regulator (if applicable) since these instuments typically fail open and the heat from a fire could cause it to fail. Like Case 1 Like Case 1 Use Case 1 if the failure can cause the tank to vent. Use Case 2 if the failure can create a vacuum in the tank. Use Case 1 if the failure can cause the tank to vent. Use Case 2 if the failure can create a vacuum in the tank. Like case 2 Use Case 1 if the failure can cause the tank to vent. Use Case 2 if the failure can create a vacuum in the tank. Like Case 1 This tank is designed according to API Standard 2000, 5th Ed.; article 4.2.5.10 When introducing flashing liquids, always include the flashed vapor in the total relief capacity. FileName: 161249533.xls.ms_office WorkSheet: Inflow-Outflow

Page 10 of 13

Art Montemayor 24" PSV -T20105 2 oz/in2 set press. 45,000 Bopd from X 20"-PL-354-D

Project Oil Storage Tank 12" PVSV -T20106 1 oz/in2 set press.

June 28, 2002 Rev:1(06-9-02)

T - 201
115 oF

.. Bopd from Y 12"-PL-756-D

24"-PL-356-A

P - 2200 1200 gpm

4"-DRG-2900-AA1

12"-OP-1910-AA1

P-201A 20 gpm

P-202A 875 gpm

P - 2210 1200 gpm

P-201B 20 gpm

P-202B 875 gpm

P - 2220 1200 gpm FileName: 161249533.xls.ms_office WorkSheet: Flow Diagram

Page 11 of 13

To Oil Shipping Pumps

Art Montemayor

Project Oil Storage Tank

June 28, 2002 Rev:1(06-9-02)

To Oil Shipping Pumps

Page 12 of 13

FileName: 161249533.xls.ms_office WorkSheet: Flow Diagram

January 26, 2002 Art Montemayor Eden Yuturi Oil Recovery This calculation is for vacuum protection of Crude Oil Storage tank, T-201: Rev: 0 In order to have safe vessel entry for inspection and repairs of the tank, OSHA requires it be clean of chemicals. Tanks are normally subjected to cleaning with live steam for this purpose and this procedure can introduce the hazard of sudden, uncontrolled vacuum developed due to steam condensation during a rain storm. Diameter = 130 ft Height = 40 ft Cylindrical surface area = Cone top roof surface area = Total Surface Area = For a heat transfer rate heat equation, use:

2 16,336 ft 2 13,456 ft 2 29,792 ft

Where, Q = U = A = DT =

Q = U A DT
Heat transfer rate, Btu/hr Overall heat transfer coefficient, Btu/hr-ft2-oF Heat transfer surface, ft2 mean temperature difference between both fluids, oF

For a condensing system, an overall heat transfer coefficient of 250 to 700 Btu/hr-ft2-oF is considered as very credible. A tropical rain storm at any given time is considered as a design criteria that should be strictly observed because of historical, empirical meteorological data. It is very possible to suffer an instantaneous cloud burst in the rainy season. The actual rain water temperature could be an estimated 60 oF. If an overall condensing heat transfer coefficient of 400 Btu/hr-ft2-oF is used, Q = Steam condensation rate = = 2.E+09 Btu/hr 1,719,425 lb/hr 860 ton/hr
3 26.799 ft /lb

Specific volume of steam at 14.696 psia = Volumetric displacement inside tank = = =

46,078,883
3 767,981 ft /min 3 12,800 ft /sec

ft3/hr

The maximum possible velocity in the Tank's vacuum relief nozzle is:

vs = k g R T = k g 144 P V
Where, vs k g P' V Therefore, vs = = = = = = Sonic velocity of air, ft/sec Ratio of specific heats for air = acceleration of gravity, 32.2 ft/sec2 Absolute pressure, psia Specific volume of air, ft3/lb = 1,118 ft/sec 1.40

13.10

2 Required nozzle area for sonic velocity = 11.45 ft A nozzle to allow safe operation = 46 inch diameter 3 - 30" Manway nozzles are recommended to be installed on the tank roof

Page 13 of 13

FileName: 161249533.xls.ms_office WorkSheet: Steam Out