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emission (38%), |
+
emission (19%) and electron capture (43%).
Write the decay products and calculate partial half-lives for each of the decay processes.
3. Hydrogen peroxide solution (20 ml) reacts quantitatively with a solution of KMnO
4
(20 ml) acidified
with dilute H
2
SO
4
. The same volume of the KMnO
4
solution is just decolourised by 10 ml of MnSO
4
in
neutral medium simultaneously forming a dark brown precipitate of hydrated MnO
2
. The brown
precipitate is dissolved in 10 ml of 0.2M sodium oxalate under boiling condition in the presence of
dilute H
2
SO
4
. Write the balanced equations involved in the reactions and calculate the molarity of
H
2
O
2
.
4. (a) Will the pH of water be same at 4C and 25C? Explain.
(b) Two students use same stock solution of ZnSO
4
and a solution of CuSO
4
. The emf of one cell is
0.03 V higher than the other. The conc. of CuSO
4
in the cell with higher emf value is 0.5 M. Find
out the conc. of CuSO
4
in the other cell (2.203 RT/F = 0.06).
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