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COLOURED SOLUTIONS First addition of reagent Ion Dirty green ppt Pale green Fe (aq) + 2OH (aq) Fe(OH) 2+ (Fe ) Rusty brown ppt Yellow (Fe3+) Fe (aq) + 3OH (aq) Fe(OH) 2+ Blue (Cu ) Pale blue ppt
2+ 3+ -
Reagent in excess
(s) No further change, however at the top of the mixture it may turn brown on standing This is due to oxidation of iron(II) hydroxide to iron(III) hydroxide
Comments
(s)
Cu2+ (aq) + 2OH- (aq) Cu(OH)2 (s) Blue or blue green ppt Cr3+ (aq) + 3OH- (aq) Cr(OH)3 (s) Blue ppt which turns pink on standing Co2+ (aq) + 2OH- (aq) Co(OH)2 (s) White or cream ppt Mn2+ (aq) +2OH- (aq) Mn(OH)2 (s)
No further change
No further change, however ppt may turn brown on standing This is due to oxidation of Mn(II) hydroxide to Mn(III)oxide
TABLE 2. COLOURLESS SOLUTIONS First addition of reagent Ion 2+ Ca No ppt No ppt NH4+ On warming, a colourless pungent gas is evolved which Mg Ba2+ Al3+ Zn2+ Pb2+
2+
turns blue litmus to red + NH4 (aq) +OH (aq) NH3 (g) + H2O(l) White ppt 2+ Mg (aq) + 2OH (aq) Mg(OH)2 (s)
Comments
Little or no ppt
White ppt Al3+ (aq) + 3OH- (aq) Al(OH)3 (s) White ppt 2+ Zn (aq) + 2OH (aq) Zn(OH)2 (s) White ppt 2+ Pb (aq) + 2OH- (aq) Pb(OH)2 (s)
All three hydroxides of Zn, Al and Pb are amphoteric and form a complex ion:- zincate, aluminate and plumbate respectively.
Tests involving the reagent aqueous ammonia solution TABLE 3. COLOURED SOLUTIONS First addition of reagent Ion 2+ Dirty green ppt Pale green (Fe ) Fe (aq) + 2OH (aq) Fe(OH) 3+ Rusty brown ppt Yellow (Fe ) Fe (aq) + 3OH (aq) Fe(OH) 2+ Blue (Cu ) Pale blue ppt
2+ 3+ -
Reagent in excess
(s) (s) No further change, however at the top of the mixture it may turn brown on standing This is due to oxidation of iron(II) hydroxide to iron(III) hydroxide
No further change
Ppt dissolves to give a deep blue solution Cu(OH)2 (s) + 4NH3 (aq) [Cu(NH3)4]2+ (aq) Ppt dissolves forming a royal blue solution Cr(OH)3 (s) + 6NH3 (aq)[Cr(NH3)6]3+ (aq) Ppt dissolves to form a brown solution which then darkens on standing Co(OH)2 (s) + 6NH3 (aq)[Co(NH3)6]2+ (aq) The darkening is due to the oxidation of Co(II) to Co(III) No further change, however ppt may turn brown on standing This is due to oxidation of Mn(II) hydroxide to Mn(III)oxide
Cu2+ (aq) + 2OH- (aq) Cu(OH)2 (s) Blue or blue green ppt Cr3+ (aq) + 3OH- (aq) Cr(OH)3 (s) Blue ppt which turns pink on standing Co2+ (aq) + 2OH- (aq) Co(OH)2 (s) White or cream ppt Mn2+ (aq) +2OH- (aq) Mn(OH)2 (s)
TABLE 4. COLOURLESS SOLUTIONS First addition of reagent Ion 2+ Ca No ppt NH4+ No ppt White ppt Mg2+ Mg (aq) + 2OH (aq) Mg(OH) (s) 2+ Ba Little or no ppt White ppt Al3+ Al (aq) + 3OH (aq) Al(OH) (s) 2+ White ppt Zn Zn (aq) + 2OH (aq) Zn(OH) (s) 2+ White ppt Pb Pb (aq) + 2OH (aq) Pb(OH) (s)
2+ 2 3+ 3 2+ 2 2+ 2
Reagent in excess No ppt No ppt No further change No further change No further change
Dissolves to form a colourless solution Zn(OH)2 (s) + 4NH3 (aq)[Zn(NH3)4]2-
Commenets
No further change
TABLE 5. Tests with various reagents other than sodium hydroxide and aqueous ammonia Test Observation Inference Silver nitrate solution in the presence of dilute White ppt means Cl- present HCl or HNO ppt dissolves to give a colourless solution
Then followed by aqueous ammonia
3
Comme
Cream ppt
Dilute nitric o
(aq)
(l)
ppt remains
Addition of HCl or any source of chloride ions sometimes an additional test may be to warm the mixture if a ppt is formed and then allow to cool Addition of aqueous potassium iodide solution sometimes an additional test may be to warm the mixture if a ppt is formed and then allow to cool White ppt ppt dissolves fully when mixture is warmed and recrystallises to form needle shaped crystals when cool Pb 2+ Pb (aq) + 2Cl (aq) PbCl2(s)
2+
2+
lead(II) chlorid reduction in t occurs and the NB lead(II) br while lead(II) lead(II) iodide ppt present w true shape of
Potassium iodide is a reducing agent and if a colour change is seen, then a redox reaction has occurred and the sample has oxidizing properties.
Conc. sulphuric acid to a solid halide e.g. sodium chloride, sodium bromide, sodium iodide
Vigourous effervescence white mixture Colourless, pungent gas Turns blue litmus red
Cl- present Gas is acidic Gas is hydrogen chloride displacement of hydrogen chloride by sulphuric acid NaCl + H2SO4 HCl + NaHSO4 Br- present Bromide ions are strong reducing agents and a redox reaction occurs and bromine is produced gas is acidic and it also bleaches which implies the halogen is being produced H2SO4 + 2H+ + 2Br- Br2 + SO2 + 2H2O I- present Iodide ions are strong reducing agents and a redox reaction occurs and iodine is produced gas is acidic and it also bleaches which implies the halogen is being produced H2SO4 + 8H+ + 8I- 4I2 + H2S + 4H2O Since acidified potassium manganate is an oxidizing agent, the sample tested must have reducing properties Since acidified potassium dichromate is an
Vigourous effervescence orange/red mixture brown, pungent gas Turns blue litmus red then white
Vigourous effervescence deep purple/black mixture purple, pungent gas Turns blue litmus red then white Addition of acidified potassium manganate solution Addition of acidified Decolourisation i.e. from purple to colourless Goes from orange to green
potassium dichromate solution Addition of dilute acid to a solid sample either dilute HCl or HNO3
Effervescence Solid dissolves No effervescence Solid dissolves Effervescence Colourless, pungent gas evolved turns red litmus blue Effervescence Blue-green solution Brown, pungent gas evolved Turns blue litmus red Brown ring is formed
oxidizing agent, the sample tested must have reducing properties Gas produced sample must be either a carbonate or a sulphite Sample must be either an oxide or hydroxide Gas is basic Gas is ammonia NO3- ion present 3NO3- + 8Al + 5OH + 18H2O 3NH3 + 8[Al(OH)4] Gas is acidic NO2 gas produced (brown gas) NO3- ion present
NO3- + 3Fe2+ + 4H+ 3Fe3++ NO + 2H2O [Fe(H2O)6]2+ + NO [Fe(H2O)5(NO)]2+ (brown ring)
Addition of Devardas alloy to sample in presence of NaOH solution and warm Addition of conc H2SO4with copper turnings present and warm Addition of freshly prepared iron(II) sulphate solution or crystals and then add conc H2SO4 slowly Create a free website with
NO3- present