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The Clausius-Clapeyron equation given below describes the change in vapor pressure above the liquid as the temperature is changed:
dP vap H dT = P R T2
1) Write down the corresponding equation for the change in vapor pressure above a solid as a function of temperature. dP sub H dT = P R T2 2) The vapor pressure of benzene liquid fits the following expression between 10C and 30C: log(P) = 7.960 - 1780/T where log is the decimal logarithm, p is given in torr and T in Kelvin. Calculate the enthalpy of vaporization. The Clausius-Clapeyron equation can be integrated assuming that the heat of vaporization is independent of temperature to yield: 1 P vap H 1 ln = T T * P * R Which implies that ln(P) = ln(P*) + vapH/(RT*) vapH/(RT)
vapH/(2.303RT*)
vapH/(2.303RT)
= 2.303Rx1780 = 34 kJ/mol
since n B and n T must be such that n B + n T = 1 mol and x B = 0.5 then n T = n B = 0 . 5 . and: mix G = 8.3145x300x(0.5 ln(0.5) + 0.5 ln(0.5)) J/mol Since the solution is ideal, mix H = mix V = 0 and mix S = mix G/T = 300 ln(0.5) J/(K.mol)
Tm(A) mixed A
Tm(A) pure A
Tb (A) pure A
Tb (A) mixed A