Jotun Paints Presentation

V SHIPS
September 26th, 2012
Tank Coating / V Ships / September 26th, 2012
Owners requirement for Chemical Resistance

The requirement very much depends on the type of vessel and more so the liquids being carried. Crude Oil Carrier Products Carrier Chemical/Oil Carrier Chemical Carrier Bunker vessel Crude CPP CPP & Chemicals & Vegoil Chemicals & Vegoil (heavy) fuels

The requirement very much depends on the type of vessel and more so the liquids being carried. Crude Oil Carrier Products Carrier Chemical/Oil Carrier Chemical Carrier Bunker vessel Crude CPP CPP & Chemicals & Vegoil Chemicals & Vegoil (heavy) fuels

The requirement very much depends on the type of vessel and more so the liquids being carried. Crude CPP Vegoil Chemicals epoxy pure epoxy phenolic epoxy phenolic epoxy zinc silicate
Free Fatty Acids (FFA%) wide chemical resistance

The requirement very much depends on the type of vessel and more so the liquids being carried. Tankguard Tankguard Tankguard Tankguard Tankguard CPC HB Special Special Ultra Zinc epoxy pure epoxy standard phenolic epoxy high-end phenolic epoxy zinc silicate
Tankguard Zinc
The renew zinc silicate tank coating
BUT BEFORE THAT..

Single hull vs Double Hull Cargo temperature
BUT BEFORE THAT..

Single hull vs Double Hull Cargo temperature Cleaning How, and where to get the info how to clean who are the experts hot cleaning water vs cold wall effct organic coating vs inorganic coating absorption vs desorption
BUT BEFORE THAT..

Single hull vs Double Hull Cargo temperature Cleaning Paint challenges How, and where to get the info Blisters; detachments; pit corrosion
too limited time for cleaning / ventilation tank top of COT: Sulphur Reducing Bacteria ageing of coating deckhead pit corrosion on tank top fast deterioration of zinc silicate
BUT BEFORE THAT..

Single hull vs Double Hull Cargo temperature Cleaning Paint challenges Training How, and where to get the info Blisters; detachments; pit corrosion Riga
(done in the past November 2010)
- under discussion with Neil Barnes to organise cargo tank coating training for Riga office in the near future
BUT BEFORE THAT..

Single hull vs Double Hull Cargo temperature Cleaning Paint challenges Training Approach of owners How, and where to get the info Blisters; detachments; pit corrosion Riga Mondreas; Sonangol; Tri Star; Perosea
Tankguard Zinc
The renew zinc silicate tank coating
Upgraded zinc silicate tank coating
Introduction of an upgraded zinc silicate tank coating Substantially improved resistance to mud cracking
Mud-crack Resistance over 200 microns
Negligible spray dust Relatively Smooth surface

Easier to cleaning in between cargoes Easy inspection of possible spray-dust after application
Tankguard Special Ultra

The new top-of the range epoxy phenolic tank coating
Product characteristics
%FFA resistance Methanol resistance Swelling in aggressive chemicals General chemical resistance Min. application/cure temperature Post cure
100% YES Negligible Excellent 5C 3 days at 60C or 2 days at 70C or 1 day at 80C
Customers concerns on tank coatings

Owners/Managers/Charterers CARGO Flexibility in use Chemical Resistance CLEANING Easy to clean Ventilation
Chemical Resistance
Looking at the chemical resistance of the typical cargoes shipped in Tankguard Special Ultra coated tanks: Palm Oil Vegoils in general Oleochemicals CPP Chemicals no limitations no limitations no limitations no limitations closer look required, but widest chemical resistance for a phenolic epoxy or alike in the market
Chemical Resistance
Looking at the chemical resistance of the typical cargoes shipped in Tankguard Special Ultra coated tanks: Palm Oil Vegoils Oleochemicals CPP Chemicals no limitations no limitations no limitations no limitations closer look required, but widest chemical resistance for a phenolic epoxy or alike in the market
Chemical Resistance - vegoils

Vegoil (derivates) This typical reaction between an alcohol & an acid is called an ester. H2C O R | HC O R | H2C O R With R being C CxHy
||

Vegoil (derivates) Vegetable (and animal) oils are a chemical reaction between fatty acids & glycerine (glycerine is also called glycerol, being an alcohol). H2C O R | HC O R | H2C O R
+ H2O
water
Fatty acid glycerol ester

Vegoil (derivates) Vegetable (and animal) oils are a chemical reaction between fatty acids & glycerine (glycerine is also called glycerol, being an alcohol). H2C O R | HC O R | H2C O R H2C O H | HC O R | H2C O R
+ H2O
water
+ HO-R
free fatty acid
The amount of fatty acids being freed is expressed in a percentage: % FFA free fatty acid

Vegoil (derivates) Vegetable (and animal) oils are a chemical reaction between fatty acids & glycerine (glycerine is also called glycerol, being an alcohol). Zinc silicate can handle 1 ~ 2 % Pure Epoxy can handle 10 ~ 15 % Phenolic Epoxy 10 ~ 50 % High-end Phenolic 100 %
Tankguard Zinc Tankguard HB Tankguard Special Tankguard Special Ultra
Chemical Resistance bio-fuels

Bio-fuels - Bio fuel - Bio diesel addition of ethanol addition of FAME to petrol to diesel

Bio-fuels - Bio fuel addition of ethanol to petrol
Resistance to ethanol (may) require(s) a phenolic epoxy esp. for long term performance of the coating system.

Bio-fuels - Bio diesel addition of FAME to diesel
The addition of FAME to diesel. This is basically not a challenge, provided that the FFA-% is not too high (but this is probably not allowed within the specifications). Fatty Acid Methyl Ester

Biodiesel The addition of FAME to diesel. This is basically not a challenge, provided that the FFA-% is not too high (but this is probably not allowed within the specifications). H2C O R | HC O R + 3 HOCH3 Methanol | H2C O R H2C O H | HC O H | H2C O H
+ 3 H3CO-R
fatty acid methyl ester
This process is called transesterfication and is predominantly done to lower the viscosity.
Chemical Resistance
Often the main deciding factor when selecting a tank coating. Extensive exposure testing has been performed - comparison with bench mark product
- wide range of curing conditions including varying post-curing - a long list of chemicals tested - cyclic testing
Adhesion, blisters, discolouration, etc have been evaluated
Product Resistance List

The new Product Resistance List is a web based solution. It is possible to download the program to a PC or CD for use when not connected to the internet. The resistance list is found as a link in Coatings, Products at www.jotun.com and the direct address is www.jotunprl.com
www.jotunprl.com
What's new in the Resistance list?

Products:
Tankguard Tankguard Tankguard Tankguard Tankguard Zinc CPC HB Special Special Ultra
Advanced search function with MARPOL, IMO classes or IBC codes
A "basic search" for methanol
Click anywhere on this line
..and the resistance for all our coatings to methanol is listed The Notes-text appear when pointing at them
Changed to 6 months
Changed to 5 days
Tailor made advice SEA based owner
Chemical Resistance required

----- Far East / Arab Gulf & Red Sea Chemicals; CCP; Palm Oil
Chemicals CPP Palm Oil depends on type of chemicals, but would suggest Tankguard Special Ultra Tankguard HB would suffice depending on the pretreatment, resulting in a certain level of FFA, probably Tankguard Special Ultra would be best suggested
Tankguard HB Tankguard Special Ultra

pure epoxy high quality phenolic epoxy

------------Far East / Europe Far East / Arab Gulf & Red Sea Straits / Pakistan / India & China
FFAs & Chemicals

zinc silicate pure epoxy common phenolic epoxy high end phenolic epoxy
Tankguard Zinc < 2% Tankguard HB < 15% Tankguard Special < 40% Tankguard Special Ultra 100%

------------Far East / Europe Far East / Arab Gulf & Red Sea Straits / Pakistan / India & China
FFAs & Chemicals We need to have a closer look at what chemicals are actually shipped, & checked with the Chemical Resistance of Tankguard Special Ultra

Acetic Acid Acetone Acid oil mixture Alcohol various grades Alkanes Alkyl Benzenes Aniline Butyl Acetate Butyl Acrylate n-Butyl Alcohol tert-Butyl Alcohol Butylene Glycol n-Butyl Ether Chloroform Citric Acid NR R R R R R R R R R R R R R R Cyclohexanol Cyclohexane Cyclohexanone Dodecane ( all isomers) Ethylene Glycol Formic Acid Glycerine Hexanol Lauric Acid Linseed Oil Methyl tert Butyl Ether Methyl Ethyl Ketone Molasses Nitric Acid Nonane R R R R R NR R R R R R R R NR R Nonyl Alcohol Octane ( all isomers ) Olefin Oil Paraffin wax Phenol Propylene Glycol Propylene Tetramer Rapeseed Oil Propylene Trimer Pyrolysis Gasoline ( containing benzene ) Styrene Monomer Toluene Urea solution Xylenes White spirit R R R R NR R R R R R R R R R R

Acetic Acid Acetone Acid oil mixture NR R Cyclohexanol Cyclohexane R R Nonyl Alcohol Octane ( all isomers ) R R R R NR R R R R R R R R R R
R Olefin Oil Cyclohexanone R For 4 chemicals Tankguard Special Ultra does Alcohol various grades R Paraffin wax Dodecane ( all isomers) R not have sufficient chemical resistance Alkanes Alkyl Benzenes Aniline Butyl Acetate Butyl Acrylate n-Butyl Alcohol tert-Butyl Alcohol Butylene Glycol n-Butyl Ether Chloroform Citric Acid R R Ethylene Glycol Formic Acid R NR Phenol Propylene Glycol
However , feedback from owner: Glycerine R Propylene Tetramer R 1. Based on the acetic Hexanol certificate R of fitness R Rapeseed Oil acid , nitric acid and formic acid shall only R Lauric Acid R Propylene Trimer R Oil R STEEL Pyrolysis Gasoline ( containing benzene ) be loaded Linseed in STAINLESS tanks Methyl tert Butyl Ether R R Monomer 2. Most suppliers/receivers prefer Styrene STAINLESS R Methyl Ethyl Ketone R Toluene STEEL tanks when shipping phenol
R R R Molasses Nitric Acid Nonane R NR R Urea solution Xylenes White spirit
Chemical Resistance Required

Certain owners active the SEA region are typically having the requirement out-bound: Palm Oil products, including Palm Fatty Acid Distillates in-bound: methyl alcohol; MEG; Caustic Soda; pygas; luboil & others In case the cargo tanks are coated with Tankguard Special Ultra, there are no limitations from the coatings point of view.

Pre-wash after carriage of aggressive cargoes and bio-fuels: this can be accepted for all cargoes that require this pre-wash This includes executing pre-wash after carriage of methanol.
Note: the pre-wash procedure needs to be discussed.

In general in cargo tank coating, care regarding subsequent cargoes, since risk of: Cargo contamination Negative effect of sequence of chemicals
But these risks are not applicable when back-2-back shipment. Hence, any cargo can be shipped back-2-back.
Chemical Resistance required by European owner

50% of the cargoes understood to be
FAME Ethanol Caustic soda Gasoil Methanol Crude vegoil
Chemical Resistance required by European owner

50% of the cargoes understood to be
FAME Ethanol Caustic soda Gasoil Methanol Crude vegoil R R R R R R 1B, 10 5 days ventilation for R1, R2, R16 & R18
4,18
5 days ventilation for R1, R2, R16 & R18
Tankguard Special Ultra has resistance for the above cargoes
Chemical Resistance required by

75% of the cargoes also including
MTBE Aromatics Ureas Xylenes Styrene Molasses Isomerates Cyclo-hexane Refined vegoils
Chemical Resistance required by

75% of the cargoes also including
MTBE Aromatics Ureas Xylenes Styrene Molasses Isomerates Cyclo-hexane Refined vegoils R R R R R R R R R
Tankguard Special Ultra has resistance for the above cargoes
V SHIPS
September 26th, 2012

Jotun Paints Presentation

Caricato da

Informazioni sul documento

Descrizione originale:

Copyright

Formati disponibili

Condividi questo documento

Condividi o incorpora il documento

Opzioni di condivisione

Hai trovato utile questo documento?

Questo contenuto è inappropriato?

Copyright:

Formati disponibili

Jotun Paints Presentation

Caricato da

Copyright:

Formati disponibili

V SHIPS

September 26th, 2012

Tank Coating / V Ships / September 26th, 2012

Owners requirement for Chemical Resistance

Tank Coating / V Ships / September 26th, 2012

Owners requirement for Chemical Resistance

Tank Coating / V Ships / September 26th, 2012

Owners requirement for Chemical Resistance

Free Fatty Acids (FFA%) wide chemical resistance

Tank Coating / V Ships / September 26th, 2012

Owners requirement for Chemical Resistance

Tank Coating / V Ships / September 26th, 2012

Tank Coating / V Ships / September 26th, 2012

BUT BEFORE THAT..

Tank Coating / V Ships / September 26th, 2012

BUT BEFORE THAT..

Tank Coating / V Ships / September 26th, 2012

BUT BEFORE THAT..

Tank Coating / V Ships / September 26th, 2012

BUT BEFORE THAT..

Tank Coating / V Ships / September 26th, 2012

BUT BEFORE THAT..

Tank Coating / V Ships / September 26th, 2012

Tank Coating / V Ships / September 26th, 2012

Upgraded zinc silicate tank coating

Negligible spray dust Relatively Smooth surface

Tank Coating / V Ships / September 26th, 2012

Tankguard Special Ultra

Tank Coating / V Ships / September 26th, 2012

Tank Coating / V Ships / September 26th, 2012

Customers concerns on tank coatings

Tank Coating / V Ships / September 26th, 2012

Tank Coating / V Ships / September 26th, 2012

Tank Coating / V Ships / September 26th, 2012

Chemical Resistance - vegoils

Tank Coating / V Ships / September 26th, 2012

Chemical Resistance - vegoils

Fatty acid glycerol ester

Tank Coating / V Ships / September 26th, 2012

Chemical Resistance - vegoils

Tank Coating / V Ships / September 26th, 2012

Chemical Resistance - vegoils

Tank Coating / V Ships / September 26th, 2012

Chemical Resistance bio-fuels

Tank Coating / V Ships / September 26th, 2012

Chemical Resistance bio-fuels

Tank Coating / V Ships / September 26th, 2012

Chemical Resistance bio-fuels

Tank Coating / V Ships / September 26th, 2012

Chemical Resistance bio-fuels

Adhesion, blisters, discolouration, etc have been evaluated

Tank Coating / V Ships / September 26th, 2012

Product Resistance List

Tank Coating / V Ships / September 26th, 2012

What's new in the Resistance list?

Advanced search function with MARPOL, IMO classes or IBC codes

Tank Coating / V Ships / September 26th, 2012

A "basic search" for methanol

Click anywhere on this line

Tank Coating / V Ships / September 26th, 2012

Tank Coating / V Ships / September 26th, 2012

Tank Coating / V Ships / September 26th, 2012

Tank Coating / V Ships / September 26th, 2012