Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Aerosol Propellants
Diversified CPC International, Inc.
1
An Introduction to
Aerosol Propellants
2
Aerosol Product System
3
Aerosol Product System
4
Aerosol Product System
5
Aerosol Product System
6
Aerosol Product System
7
Aerosol Product System
8
Aerosol Product System
9
Aerosol Product System
10
Aerosol Product System
11
Aerosol Product System
12
Aerosol Product System
13
Aerosol Product System
14
An Introduction to
Aerosol Propellants
15
Basic Propellant Properties
• Foam
• Stream
• Spray
16
Basic Propellant Properties
17
Basic Propellant Properties
19
Basic Propellant Properties
22
Basic Propellant Properties
23
Basic Propellant Properties
• Vapor Pressure
• Spray Characteristics
• Solubility
• Flammability
• Corrosion
25
Basic Propellant Properties
Three Categories of
Aerosol Propellants
26
Basic Propellant Properties
• Compressed Gases
• Soluble Gases
• Liquefied Gases
27
Basic Propellant Properties
Compressed and
Soluble Gas Propellants
28
Compressed and Soluble Gases
29
Basic Propellant Properties
30
Liquefied Gas Propellants
DME 134a
Customer Needs
and
Reformulations
152a
31
Hydrocarbons
Liquefied Gas Propellants
General Liquefied Gas Propellant Comparisons
32
Liquefied Gas Propellants
VAPOR DENSITIES
of Liquefied Gas Aerosol Propellants (@70 °F)
Kauri-Butanol value 60 11 10
LOW HIGH
Air Fresheners
Shave Cream Automotive products
Gels and Mousse Flying Insect Spray
Oven Cleaner MEDIUM Spray Paint
Perfume
Hard Surface Cleaners
Furniture Polish
Deodorant Sprays
35
Basic Propellant Properties
Hydrocarbon Propellants
36
Hydrocarbon Propellants
Hydrocarbon Propellants
Organic Compounds
Derived from Natural Gas Liquids
(liquefied under pressure)
CH4 Methane
C 2H 6 Ethane
C 3H 8 Propane
C4H10 Butanes
C5H12 Pentanes
37
Hydrocarbon Propellants
Properties of the Hydrocarbons
Propane I-Butane N-Butane I-Pentane N-Pentane
Chemical Formula C3H8 C4H10 C4H10 C5H12 C5H12
Standard Hydrocarbon
Propellant Blends
48
Standard Hydrocarbon Blends
a
a
49
Standard Hydrocarbon Blends
NIP
A NP
Propane Propane
Isobutane n-butane
n-Butane
Propane
Isobutane
n-Butane
51
Standard Hydrocarbon Blends
• A-31 • A-70
• NP-31 • NP-70
• NIP-31 • NIP-70
• A-46 • A-85
• NP-46 • NP-85
• NIP-46 • A-108
52
Hydrocarbon Propellants
Processing
53
Processing of Hydrocarbon
Propellants
3 - Catalytic Desulfurization
54
Processing of Hydrocarbon
Propellants
55
Processing of Hydrocarbon
Propellants
56
Processing of Hydrocarbon
Propellants
57
Processing of Hydrocarbon
Propellants
58
Processing of Hydrocarbon
Propellants
59
Processing of Hydrocarbon
Propellants
60
An Introduction to
Aerosol Propellants
Propellant Cost
61
Cost Comparison
Hydrocarbons
1x
DME 152a
2x 4x
62
Cost Comparison
Hydrocarbons
1x
DME 152a
2x 4x
134a
5 - 7x
63
Characteristics of
Hydrocarbon Aerosol Propellants
64
Characteristics of
Hydrocarbon Aerosol Propellants
65
An Introduction to
Aerosol Propellants
V O C Issues
66
Low VOC Propellant Options
Non VOC
Propellants Adjust Pressure
Use higher vapor pressure
hydrocarbon propellant
152a and reduce fill volume
134a
Low VOC Blends
DME - Water Based
DME/HC/Water
HFC/Hydrocarbon
67
VOC Reduction Strategies
• Formulate based on
relative reactivity
68
Low VOC (Liquefied Gas) Propellant
Alternatives
69
Custom Blends
152a/A17
IsoPentane
152a/A31
A31/IsoPentane
152a/A46
A31/N-Pentane
152a/A17/DME
A17/N-Pentane
134a/DME 152a/A31/DME
A80/DME 134a/A31
A17/DME 134a/A17
Pentane/DME
70
Expanding Complexity
• Approximately 30
basic hydrocarbon 250
propellant blends
prior to VOC Issue 200
71
Low VOC Propellant Shipments
72
US EPA Supports Hydrocarbon
Propellants
73
Unfortunately, the US EPA forgot to tell
California!
74
Photochemical
Reactivity Concepts
• Reactivity - Measure of a VOC’s potential to react in the
atmosphere and lead to the formation of ozone
• Use of “lower reactive” VOCs may provide means for ozone
reduction benefit where mass-based VOC reductions alone are
not sufficient for attainment or feasible
• Flexible approach that gives manufacturers more reformulation
options
75
An Introduction to
Aerosol Propellants
NO CFCs
(CAPCO)
76
It’s OK to Spray !
77 a
NO CFCs
78
An Introduction to
Aerosol Propellants
Transportation
79
Delivery of Aerosol Propellants
1 - Truck Transports
2 - Railroad Tank Cars
3 - DOT Cylinders
– 1# (laboratory sample)
– 20# (barbecue size)
– 100#
– 200#
– 420#
80
An Introduction to
Aerosol Propellants
Transportation
- Trucks -
81
Transportation - Trucks
82
Transportation - Trucks
83
Transportation - Trucks
84
Transportation - Trucks
85
Transportation - Trucks
86
Transportation - Trucks
87
An Introduction to
Aerosol Propellants
Transportation
- Rail Cars -
88
Transportation – Rail Cars
89
An Introduction to
Aerosol Propellants
Transportation
- ISO Containers -
90
Transportation – ISO Containers
91
Transportation – ISO Containers
92
Transportation – ISO Containers
93
An Introduction to
Aerosol Propellants
Transportation
- Cylinders -
94
Transportation - Cylinders
95
Transportation - Cylinders
96
An Introduction to
Aerosol Propellants
97
Tank Farm Operations
SAMPLE VALVE
AND ROTOGAGE
98
Tank Farm Operations
99
Tank Farm Operations
100
Tank Farm Operations
ESV
Flow Indicator
101
Tank Farm Operations
102
Tank Farm Operations
103
Tank Farm Operations
104
Tank Farm Operations
105
Tank Farm Operations
LIQUEFIED GAS
TRANSFER PUMP
VAPOR BALANCE
PUMP DISCHARGE LINE
LINE
108
Tank Farm Operations
SHUTOFF FOR
INTERNAL VALVES
109
Tank Farm Operations
110
Tank Farm Operations
Liquid
Vapor
112
Tank Farm Operations
113
Tank Farm Operations
115
GAS TRANSFER COMPRESSOR
Tank Farm Operations
(For Tank Car Unloading, the “Supply Tank” is the Tank Car and the
117 “Receiver Tank” is the Propellant Storage Tank)
Tank Farm Operations
Vapor Recovery
Operations
118
Tank Farm Operations
119
Storage Tanks, Equipment, &
Safety Systems
120
Storage Tanks, Equipment, &
Safety Systems
121
Storage Tanks, Equipment, &
Safety Systems
122
Storage Tanks, Equipment, &
Safety Systems
123
Storage Tanks, Equipment, &
Safety Systems
124
Storage Tanks, Equipment, &
Safety Systems
MANUFACTURER’S DATA PLATE FOR LPG STORAGE TANK
125
Storage Tanks, Equipment, &
Safety Systems
127
Storage Tanks, Equipment, &
Safety Systems
130
Storage Tanks, Equipment, &
Safety Systems
Spring
Valve
Body
Poppet
Seat
Seat
135
Storage Tanks, Equipment, &
Safety Systems
136
Storage Tanks, Equipment, &
Safety Systems
1800
1600
Pressure Rise in a 1400
Constant Volume 1200
20
40
80
120
160
200
Temperature (F)
138
Storage Tanks, Equipment, &
Safety Systems
139
Storage Tanks, Equipment, &
Safety Systems
143
Storage Tanks, Equipment, &
Safety Systems
144
Storage Tanks, Equipment, &
Safety Systems
145
Storage Tanks, Equipment, &
Safety Systems
146
Storage Tanks, Equipment, &
Safety Systems
Forged Steel
Sch. 80 Pipe
and 2000#
Fittings
147
Storage Tanks, Equipment, &
Safety Systems
148
Storage Tanks, Equipment, &
Safety Systems
149
Storage Tanks, Equipment, &
Safety Systems
150
Storage Tanks, Equipment, &
Safety Systems
151
Storage Tanks, Equipment, &
Safety Systems
152
Storage Tanks, Equipment, &
Safety Systems
Theoretical Maximum Release
of Liquefied Flammable Gas
The theoretical maximum release of 3 different hydrocarbon
propellants @ 70 °F to the atmosphere through a 0.25” diameter
opening has been calculated to be:
Hydrocarbon
Pressure Vapor Liquid
(psig) (ft3/sec) (gal/min)
Propane 108 12.20 28.60
Isobutane 31 5.94 14.39
N-butane 17 4.66 10.50
153
Storage Tanks, Equipment, &
Safety Systems
HEAT DETECTOR
BACK FLOW
CHECK VALVE
INTERNAL
SAFETY VALVE
154
Storage Tanks, Equipment, &
Safety Systems
EXCESS FLOW
VALVE EMERGENCY
157 SHUT-OFF VALVE
An Introduction to Liquefied Gas
Aerosol Propellants
Fire Protection
158
Fire Protection
Flammability of
Common Aerosol Propellants
• LEL and UEL (lower and upper explosive limits) are tabulated below
• Auto ignition temperatures range from 662 °F for DME to 940 °F for Propane.
(Note: The temperature of an idly burning cigarette is over 1000 °F).
159
Fire Protection
160
Fire Protection
161
Fire Protection
Automatic Detection
Systems
162
Automatic Detection Systems
165
Automatic Detection Systems
HEAT
DETECTOR
167
Automatic Detection Systems
RATE-OF-RISE
HEAT DETECTOR
168
Automatic Detection Systems
Fire Protection
Water Deluge Systems
170
Water Deluge Systems
171
Water Deluge Systems
172
Water Deluge Systems
173
Water Deluge Systems
174
Water Deluge Systems
175
Water Deluge Systems
176
Water Deluge Systems
177
Water Deluge Systems
178
Water Deluge Systems
179
Water Deluge Systems
180
Water Deluge Systems
181
Water Deluge Systems
182
Water Deluge Systems
183
Water Deluge Systems
184
An Introduction to Liquefied Gas
Aerosol Propellants
Fire Protection
Water Cannons / Monitor
Nozzles
185
Water Cannons / Monitor Nozzles
186
Water Cannons / Monitor Nozzles
187
Water Cannons / Monitor Nozzles
188
Water Cannons / Monitor Nozzles
189
An Introduction to Liquefied Gas
Aerosol Propellants
Fire Protection
Insulation
190
Fire Protection - Insulation
191
Fire Protection - Insulation
192
Fire Protection - Insulation
193
An Introduction to Liquefied Gas
Aerosol Propellants
Fire Protection
Mounded Storage
194
Mounded Storage
195
Mounded Storage
196
Mounded Storage
197
Mounded Storage
198
Mounded Storage
199
An Introduction to Liquefied Gas
Aerosol Propellants
Fire Protection
Underground Storage
200
Underground Storage
201
An Introduction to Liquefied Gas
Aerosol Propellants
202
Propellant Tank Farm Safety
204
Propellant Tank Farm Safety
205
Propellant Tank Farm Safety
210
An Introduction to Liquefied Gas
Aerosol Propellants
Regulations
211
Regulations
212
An Introduction to Liquefied Gas
Aerosol Propellants
Diversified CPC International, Inc.
offers custom regulatory
compliance programs to meet
OSHA PSM (process safety
management) and EPA RMP (risk
management program) regulatory
requirements.
213
An Introduction to Liquefied Gas
Aerosol Propellants
ISO 9000:2000
Channahon, Illinois
215
An Introduction to Liquefied Gas
Aerosol Propellants
Questions
216
An Introduction to Liquefied Gas
Aerosol Propellants
Thank you
for
sharing this time with us !
217