Vriti IIT Part Test 2 - Paper I Test Paper

DEXL | IIT-JEEPARTTEST 2 (PAPERI)
CHEMISTRY
SECTION I
Single Correct Choice Type
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
1. Find the molality of a solution containing a nonvolatile if the vapour pressure is 2% below the vapour
pressure of pure water:
(A) 1.1326 (B) 2.492 (C) 3.562 (D) 4.090
2. The ratio of activities of two radio nuclides X and Y in a mixture at time t = 0 was found to be 4 : 1. After two
hours, the ratio of activities become 1 : 1. If the t
1/2
of radio nuclide X is 20 min then t
1/2
[in minutes] of radio
nuclide Y is
(A) 10 (B) 20 (C) 30 (D) 40
3. To make the crystal lattice structure MO
2
; metal ions are arranged as face centred cubic lattice. The oxide ions
are arranged in all tetrahedral voids. The total number of ions present in unit cell are :
(A) 3 (B) 6 (C) 12 (D) 10
4. The acidic hydrolysis of thioacetamide takes place as
||
3 2 2 2 3 2
S
CH C NH H O H S CH CONH + +
Its rate law is; rate = k[H
+
] [CH
3
CSNH
2
]. If some amount of solid NaOH is added to the 0.1 M thioacetamide
and H
+
ion solution at 298 K, then
(A) the reaction rate and rate constant remains constant.
(B) the reaction rate and rate constant both increases.
(C) the reaction rate decreases, and rate constant remains constant.
(D) the reaction rate increases and rate constant remains constant.
Space for Rough Work
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5. 1 gm of radium is known to emit 3.7 10
10
particles/ sec. The half life of radium is:
[given: atomic weight of Ra = 226]
(A) 3 10
10
sec (B) 5 10
10
sec (C) 4.9 10
11
sec (D) 3.9 10
10
sec.
6. A sample of 16 g charcoal was brought into contact with a CH
4
gas contained in a vessel of 1 litre at 27C. The
pressure of gas was found to fall from 760 to 608 torr. The density of charcoal sample is 1.6 g/cm
3
. What is the
volume of the CH
4
gas adsorbed per gram of the adsorbent at 608 torr and 27C?
(A) 125 mL/g (B) 16.25 mL/g (C) 26 mL/g (D) 30.75 mL/g
7. A body centered cubic lattice is made up of hollow spheres of B. Spheres of solid A are present in hollow
spheres of B. Radius A is half of radius of B. What is the ratio of total volume of spheres of B unoccupied by
A in a unit cell and volume of unit cell
(A)
7 3
64
(B)
7 3
128
(C)
7
24
(d) none of these

8. One gram of activates carbon has a surface area of 1000 m
2
. Considering complete coverage as well as
monomolecular adsorption, how much ammonia at STP would be adsorbed on the surface of
44
7
g carbon if
radius of ammonia molecules is 10
8
cm. [N
A
= 6 10
23
]
(A) 7.46 L (B) 0.33 L (C) 44.8 L (D) 23.5 L
SECTION II
Multiple Correct Choice Type
out of which ONE OR MORE is/are correct.
9. Select the correct statement :
(A) Law of mass action and rate law expression are same for elementary process.
(B) Order of a complex reaction is determined by the slowest elementary process of the mechanism.
(C) Order of reaction 2H
2
O
2
2H
2
O + O
2
; is two
(D) The factor
/
a
E RT
e
refers to the effective collisions.

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10. Which of the following is/are correct for CsCl type crystal:
(A) It is ideal BCC structure.
(B) Cs
+
and Cl

both ions forms a simple cubic lattice which inter penetrate each other.
(C) Cs
+
ions are at the body centre of Cl
unit cell
(D) Cl
ions are at the body centre of Cs

+
unit cell.
11. The capacity of an ion to flocculate the colloidal solution depends upon:
(A) amount of its charge (B) type of its charge (C) its shape (D) None of these
12. The correct starting material and end product of different disintegration series are
(A)
232 208
Th, Pb (B)
235 206
U, Pb (C)
38 207
U, Pb
2
(D)
237 209
Np, Bi
SECTION III
Comprehension Type
This section contains 2 groups of questions. Each group has 3 multiple choice questions based on a paragraph.
Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.
Paragraph for Questions Nos. 13 to 15
A vessel contains gaseous dimethylether at initial pressure p
0
atm. Dimethyl ether decomposes on heating as per
the reaction by first order kinetics.
CH
3
O CH
3
(g)
CH
4
(g) + CO(g) + H
2
(g)
It is observed that the halflife period for this reaction is 0.2 hour. After a very long time, pressure in the vessel is
observed to be 1.2 atm. Assume ideal behaviour of all gases with constant VT conditions.
13. What would be the approximate pressure in the vessel at 0.6 hour? [log
10
8 0.9]
(A) 0.05 atm (B) 1.5 atm (C) 2.303 atm (D) 1.1 atm
14. The initial rate of formation of CH
4
gas is
(A) 1.386 atm h
1
(B) 0 (C) 2.07 atm h
1
(D) 1.4 atm h
1
15. The approximate molar ratio of gases at 0.6 hour and at zero hour is :
(A) 11: 4 (B) 4 : 11 (C) 7 : 8 (D) 8 : 7
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Two completely miscible liquid makes a homogeneous solution of single phase. When such solution is kept in a
closed evacuated vessel, the total pressure exerted by vapour is the sum of partial pressure of constituents. If solution
is ideal it will follow Raoults law and partial pressure of each component is given by
p
i
=
o
i i
p x , x
i
= mole fraction of constituent,
o
i
p = vapour pressure of pure constituent.
Change in thermodynamic function when ideal solution is formed by mixing pure components is
ln ln
mix i i total i i
i i
G n RT X n RT X X

ln
mix total i i
i
S n R X X

ln ln
mix total i i total i i
i i
H n RT X X n R X X
= a
U
mix
= 0
As both the components are making ideal solution Raoults law is applicable over entire range of solution and partial
pressure exerted by vapours can be calculated and also the composition of vapours can be determined by Daltons
Law.
16. Two liquids A and B makes an ideal solution at T K. When the total vapour pressure above the solution is 600 torr,
X
A
in vapour phase is 0.35. Calculate &
o o
A B
p p . Given : X
A
in liquid is 0.70.
(A) 800 torr, 300 torr (B) 300 torr, 1300 torr (C) 1300 torr, 300 torr (D) 300 torr, 800 torr
17. One mole of pure nC
6
H
14
and two moles of nC
7
H
16
are mixed at 27
o
C to form an ideal binary solution.
&
mix mix
G S are
(A) 2065 J. and 6.88 J K
1
(B) 1585.38 J & 5.28 J K
1
(C) 1585 J & 5.28 J K
1
(D) 2065 J & 6.88 J K
1
18. A and B makes ideal solution. At what mole fraction of A and B, Gibbs free energy of mixing is minimum
(A) X
A
= X
B
= 0.5 (B) X
A
= X
B
= 1 (C) X
A
= X
B
= 0.75 (D) X
A
= X
B
= 0.66
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SECTION IV
Matrix-Match Type
This section contains 2 questions. Each question contains statements given in two columns, which have to be
matched. The statements in Column I are labelled A, B, C and D, while the statements in Column II are labelled p,
q, r, s and t. Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in
Column II. The appropriate bubbles corresponding to the answers to these questions have to be darkened as
illustrated in the following example: If the correct matches are A p, s and t; B q and r; C p and q; and D s
and t; then the correct darkening of bubbles will look like the following.

19. Match the questions in Column I with their answers in Column II.
Column I Column II
(A)
The edge length of unit cell of NaCl (in pm); If the distance
between Na
+
and Cl
is 265 pm
75
(B)
A certain compound A tetramerises in water to the extent
80%. Its 2.5 gm in 100 gm H
2
O lowers the freezing point by
0.3
o
C. Its molar mass is [k
f
(H
2
O) = 1.86 K kg mol
1
].
(q) 530
(C)
A and B are two identical vessels. A contains 15g of ethane at
298 K and 1 atm. The vessel B contains 75 g gas X
2
at the
same temperature and pressure. The vapour density of X
2
is
20
(D)
Two liquids A and B have vapour pressure in the ratio
: 1: 2
o o
A B
p p at a certain temperature. Suppose that we have
an ideal solution of A and B in the mole fraction ratio A : B =
1 : 2, the mole % of A in the vapour in equilibrium with the
solution at the given temperature is
62
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20. Match the questions in Column I with their answers in Column II
Column I Column II
(A)
Thermal decomposition of a compound is of first
order. If 50% of a sample of the compound is
decomposed in 120 minute show long will it take
for 90% of the compound to decompose in minutes
(p) 363.5
(B)
Two organic liquids A and B have vapour pressure
1 2
&
o o
p p at 80
o
C in their pure states. A mixture of
the two boils at 80
o
C and shows ideal behaviour. It
has mole fraction of A = 0.16. If
2 1
o o
p p = 472
mm; than
1
o
p will be
(q) 2736
(C)
What mass of sugar (M
o
= 342) must be dissolved
in 4.0 Kg of H
2
O to yield a solution that will freeze
at 3.72C (Take k
f
= 1.86/m)
(r) 254
(D)
At 45C the vapour pressures in torr, of methyl
alcoholethyl alcohol solutions is represented by
the equation. P = 119 X
A
+ 135; where X
A
is
molefraction of methyl alcohol in solution phase,
then the value of the value of
3
o
CH OH
p
is
(s) 399
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MATHEMATICS
SECTION I
21. If m and n are positive integers and f(x) = ( ) ( )
x
2n 2m 1
1
t a t b dt
+

, a b, then
(A) x = b is a point of local minimum (B) x = b is a point of local maximum
(C) x = a is a point of local minimum (D) x =a is a point of local maximum
22. The solution of x
2
dy y
2
dx + xy
2
(x y)dy = 0 is
(A)
2
x y y
ln c
xy 2
+ (B)
2
xy x
ln c
x y 2
+
(C)
2
x y x
ln c
xy 2
+ (D)
x y
ln y c
xy
+
23. The value of
1/ 2
x 1
2 3/ 2
0
x
e sin x dx
(1 x )
is
(A)
e 2
6 3 3
(B)
2
e 1
6 3
_
+

,
(C)
e 4
6 3 3
(D) 0
24. F : R R, f(x) = sin x + x, then the value of
1
0
(f (x))dx
is equal to
(A)
2
2
2
+ (B)
2
2
2
(C)
2
(D) cant be evaluated
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25. The area bounded by y = x
2
+ 2 and y = 2|x| cos x is equal to
(A)
1
3
(B)
2
3
(C)
4
3
(D)
8
3
26. If the straight lines a
1
x + b
1
y + c
1
= 0, a
1
x + b
1
y + c
2
= 0, a
2
x + b
2
y + d
1
= 0, a
2
x + b
2
y + d
2
= 0 are the sides of
rhombus then :
(A)
2 2 2 2 2 2
2 2 1 2 1 1 1 2
(a b )(c c ) (a b )(d d ) + + (B)
2 2 2 2
1 1 1 2 2 2 1 2
(a b ) | d d | (a b ) | c c | + +
(C)
2 2 2 2
2 2 1 2 1 1 1 2
(a b )(d d ) (a b )(c c ) + + (D)
2 2 2 2
1 1 1 2 2 2 1 2
(a b ) | c c | (a b ) | d d | + +
27. A point P moves inside a triangle formed by A(0, 0), B(1, 3) , C(2, 0) such that
min{PA, PB, PC} = 1, then the area bounded by the curve traced by P is
(A)
3
3 3
2
(B) 3
2
(C)
3
3 3
2
+ (D) 3
2
+
28. The range of values of for which the line 2y = gx + is a normal to the circle x
2
+ y
2
+ 2gx +2g y 2 = 0 for
all values of g is
(A) [1, ) (B) [1, ) (C) (0, 1) (D) (, 1]
SECTION II
29. Let f(x) =
x
0
| 2t 3| dt
. Then f is
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(A) Continuous at
3
x
2
(B) Continuous at x = 3
(C) Differentiable at
3
x
2
(D) Differentiable at x = 0
30. The equation(s) of the tangent at the point (0, 0) to the circle, making intercepts of length 2a and 2b units on
the coordinate axes, is/are
(A) ax + by = 0 (B) ax by = 0 (C) x = y (D) None of these
31. Let ax + by + c = 0 be a variable straight line, where a, b and c are 1
st
, 3
rd
and 7
th
term of some increasing A.P.
Then the variable straight line always passes through a fixed point which lies on
(A) x
2
+ y
2
= 13 (B) x
2
+ y
2
= 5 (C)
2
9
y x
2
(D) 3x + 4y=9
32. For the differential equation y = e
dy/dx
(A) Order is not defined (B) Order is 1 (C) Degree is undefined (D) Degree is 1
SECTION III
Comprehension Type
Equation of the circumcircle of a triangle formed by the lines L
1
= 0, L
2
= 0 and L
3
= 0 can be written as L
1
L
2
+
L
2
L
3
+ L
3
L
1
= 0, where and are such that coefficient of x
2
= coefficient of y
2
and coefficient of xy = 0.
33.
2 2 2
1 2 2 3 3 1
L L L L L L 0 + + represent
(A) a curve passing through point of intersection of L
1
L
2
and L
3
(B) a circle if coefficient x
2
= coefficient y
2
and coefficient of xy = 0
(C) a parabola (D) pair of straight lines
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34. L
1
= 0, L
2
= 0 be the distinct parallel lines L
3
= 0 and L
4
= 0 be two other distinct parallel lines which are not
parallel to L
1
= 0. The equation of a circle passing through the vertices of the parallelogram formed must be of
the form
(A) L
1
L
4
+ L
2
L
3
= 0 (B) L
1
L
3
+ L
2
L
4
= 0 (C) L
1
L
2
+ L
3
L
4
= 0 (D) L
1
2
L
3
+ L
2
2

L
4
= 0
35. If L
1
L
2
+ L
2
L
3
+ L
3
L
1
= 0 is such that = 0 and is nonzero, then it represents
(A) a parabola (B) a pair of straight lines(C) a circle (D) an ellipse
Let C
1
: x
2
+ y
2
= r
2
is a fixed circle and C
2
is a circle from which two perpendicular tangents are drawn from the
circumference of any point on the circle C
2
on C
1
. A third circle C
3
passes through the centre of C
1
and intersects C
2
at P and Q and C
1
at A and B such that the line PQ is a tangent to C
1
at R.
36. Locus of the centre of variable circle C
3
is
(A) C
1
(B) C
2
(C) C
3
(D) none of these
37. Ratio
AB
PQ
equals
(A)
3
(B)
1
3
(C)
2
3
(D)
3
2

38.
Area ( OARB)
Area ( APQB)
W
W
equals where (O : origin)
(A)
4 3
+ 6 (B) 4 3 6 (C) 2 3 3 + (D) 2 3 3
SECTION IV
Matrix-Match Type
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39. Match the following :
Column I Column II
(A)
If
1 6
0 6 3
cos x cos x / 3
dx A and dx A
1 x 6 3 x

+ +

then is (p) 1
(B)
The area bounded by the curve y = x + sin x and its inverse
function between the ordinates x = 0 and
x = 2 is 4A then the value of A is
(q) 2
(C)
The area bounded by y = xe
|x|
and the lines |x| = 1,
y = 0 is
(r) 3
(D)
If
20
0
20k 2
1 cos xdx ,
then k is (s) 4
Column I Column II
(A)
dy 2y
0,
dx x
+ y(1) = 1, then y(2) = (p)
1
2
(B)
If y(x) is solution of
dy
(x 1) xy 1,
dx
+
y(0) = 1, then y(1) =
(q) 15
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(C)
(x
2
+ y
2
) dy = xydx and y(1) = 1 and y() = e,
then is equal to
(r)
1
4
(D)
x dy = y(dx + ydy), y > 0, y(1) = 1 and y() = 3,
then is equal to
(s)
3e
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PHYSICS
SECTION I
41. A rod is kept making an angle with the vertical as shown, there is a small
bead of mass m at a distance r from end A. End A of rod is hinged. The
rod starts rotating about end A making an angle with the vertical with an
angular acceleration and makes a cone. If the coefficient of static
friction between the ring and rod is , find the time after which ring will
start slipping on the rod. (consider the system is placed in gravity free
space)
r
A
(A)
1
2 2 2
2
(sin cos )

(B)
1
2
2
(sin cos )

(C)
2 2 2
(sin cos )

(D)
2 2 2
2
(sin cos )

42. AB is smooth rod and CD is the rod of length L whose one end D
is fixed at distance R/2 from centre of disc of mass M and radius
R, other end C is free to move over rod AB. Velocity of C.O.M of
disc is V
0
. At the instant rod CD makes angle with AB, the
angular velocity of rod CD is : (Assuming disc is pure rolling
over the horizontal surface):
(A)
0
3V
2Lcos
(B)
0
3V
Lcos
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(C)
0
3V
Lcos
(D)
0
3V
2Lcos
43. A stone of mass 1 kg is attached to one end of a 1m long aluminium wire of 1mm diameter. Stone is now
rotated in horizontal plane at a rate such that wire makes an angle of 60
o
with vertical. The increase in length
of wire makes an angle of 60
o
with vertical. The increase in length of wire is (Youngs modulus of alumimum
= 7 10
10
N/m
2
, neglect the mass of wire)
(A) 0.72 mm (B) 1.6 mm (C) 0.36 mm (D) 0.18 mm
44. A wide vessel with a small hole in the bottom is filled with water and kerosene of density
1
&
2
respectively.
The velocity of water flow if the thickness of water layer is t
1
and that of kerosene is t
2

(neglecting the
viscosity)
(A)
( )
1 2 2 1
2 / g t t + 1
]
(B)
( )
2 1 2 1
2 / g t t + 1
]
(C)
( )
1 2 1 2
2 / g t t + 1
]
(D)
( )
2 1 1 2
2 / g t t + 1
]
45. A solid cylinder of radius R is attached to a uniform sphere. This
combination is floating in a liquid as shown in the figure. The total volume
of the solid immersed in the liquid is V. The force exerted by liquid on the
solid is (P
0
= Atmospheric pressure, = density)
(A) Vg (B) Vg P
0
R
2
(C) Vg + P
0
R
2
(D) P
0
R
2
R
atmospher ic
pressure
46. A string is wrapped around a cylinder of mass m and radius R the string is pulled vertically upward to prevent
centre of mass from falling as the cylinder unwinds the string. Length of string unwound when the cylinder
has reached a speed will be
(A)
2 2
4
R
g
(B)
2 2
3
8
R
g
(C)
2 2
3
4
R
g
(D)
2 2
8
R
g

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47. A uniform rod of mass m = 2 kg and length l = 1 m rests on a smooth horizontal surface. One of the ends of
rod is struck with impulse J = 2N sec in horizontal direction perpendicular to the rod. As a result, the rod
obtains the momentum P = 2Ns. The force exerted by one half of the rod on other in the process of motion
(A) 6N (B) 9N (C) 12N (D) 15N
48. A steel ring of radius r and cross-sectional area A is fitted on to a wooden disc of radius R(R > r). If Youngs
modulus be Y, then the force with which the steel ring is expanded is:
(A)
r
R
AY
(B)
,
_

r
r R
AY
(C)
r
) r R (
A
Y
(D)
AR
Yr
SECTION II
49. The mathematical statement
c
v v v' +
r r r
, where
c
v
r
is the velocity of centre of mass, v'
r
is the velocity of the
point with respect to the centre of mass and v
r
is the total velocity of the point with respect to ground
(A) is true for a rolling sphere
(B) is true for a block moving on frictionless horizontal surface
(C) is true for a rolling cylinder
(D) none of these
50. A particle of mass m and charge q is projected vertically upwards. A uniform electric field
E
r
is applied
vertically downwards. If the total potential energy is U (gravitational plus electrostatic) and height is h (<<
radius of earth) (Assume U to be zero on earths surface) then :
(A) work done by the gravity mgh
(B) work done by electrostatic force qEh
(C) graph between potential energy versus height (h) is straight line
(D) graph of potential energy versus height (h) is parabola.
51. Consider a capillary immersed in a liquid having surface tension S and
angle of contact . Now
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A
R
B
C
D
A
h
E
r
(A) Pressure at point D = pressure at point E = pressure at point A
(B) Pressure at point D is greater than pressure at point A
(C) Pressure at point D is greater than pressure at point B
(D) Pressure at point A = pressure at point B
52. From figure, select the correct alternative (s)
(A) In escaping condition total energy of particle (P) of mass m is
zero
(B) Escape velocity of particle P is ( )
e e m
4G
v M M
r
+
(C) Escape velocity is
e e p
2G
v (M M )
r
+
(D) In escaping condition T.E. (Total energy) of particle is negative
R
e
P ( m )
M
m
M
e
E a r t h
M o o n
R
m
r
SECTION III
Comprehension Type
AB is horizontal diameter of a ball of mass m = 0.4 kg and radius R = 0.2 m. At time
t = 0, a sharp impulse is applied at an angle of 45 with horizontal as shown in figure,
so that the ball immediately starts to move with velocity v
0
= 20 m/s. If the coefficient
of kinetic friction between the floor and the ball is m = 0.2 (take g = 10 m/s
2
, Neglect
the frictional impulse at t = 0)
A
B
4 5
53. Initial angular velocity of ball
(A) 250 rad/sec Anticlockwise (B) 4000 rad/sec Clockwise
(C) 125 rad/sec Anticlockwise (D) 1600 rad/sec Clockwise
54. The time taken by ball to achieve pure rolling
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(A) 5.2 sec (B) 10 sec (C) 11.9 sec (D) 12.8 sec
55. Work done by kinetic friction to achieve pure rolling
(A) 70 J (B) 140 J (C) 280 J (D) 560 J
A cylindrical tank having crosssectional area A = 0.5 m
2
is filled with two liquids
of density
1
= 900 kg m
3
and
2
= 600 kg m
3
, to a height h = 60 cm each as
shown in figure. A small hole having area a = 5 cm
2
is made in right vertical wall at
a height y = 20 cm from the bottom. A horizontal force F is applied on the tank to
keep it in static equilibrium. The tank is lying on a horizontal surface. Neglect mass
of cylindrical tank comparison to mass of liquids. (take g = 10 ms
-2
)
1
h
h
F
y
56. The velocity of efflux
(A) 10 ms
1
(B) 20 ms
1
(C) 4 ms
1
(D) 35 ms
1
57. Horizontal force F to keep the cylinder in static equilibrium, if it is placed on a smooth horizontal plane
(A) 7.2 N (B) 10 N (C) 15.5 N (D) 20.4 N
58. Minimum and maximum values of F to keep the cylinder in static equilibrium just after the water starts to spill
through the hole. If the co-efficient of static friction between contact surfaces is 0.01.
(A) 0, 40 N (B) 5.4 N, 52.2 N (C) 0, 70 N (D) 0, 52.2 N
SECTION IV
Matrix-Match Type
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59. With regard to dependence of quantities given in Column A on the quantities mentioned in Column B, match
Columns A and Column B
Column I Column II
(A) Youngs modulus of a substance (p) Depends on area of cross-section
(B) Bulk modulus of a substance (q) Depends on the nature of material
(C) Modulus of rigidity of a substance (r) Depends on temperature
(D) Volume of a substance (s) Depends on length
Column I Column II
(A) Bernoullis theorem (p) Elasticity
(B) Yield point is related to (q) Venturimeter
(C) Hookes law (r) Aspirator pump
(D) Viscous liquid (s) Terminal velocity

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(d) none of these

refers to the effective collisions.

ions are at the body centre of Cs

Space for Rough Work

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