Atom Label A F Ph Ac H Q* Br I R n-Bu K S s-Bu Me Si t-Bu N TMS C Na X Cl O COOCH3 D OTs CH2OH Et P B Function Change to single bond Change to dashed

bond Change to double bond Change to wavy bond Change to triple bond Position a double bond to the left Change to quadruple bond Center a double bond Change to bold bond Position a double bond to the right Change to wedged bond Bring bond to front Change to hashed bond Open a bond properties text box Change to hashed-wedged bond Add an attachment point Add an atom number Add a negative charge Add a positive charge Sprout one bond Sprout two bonds Sprout three bonds Display the Atom Properties dialog box Display the Choose Nickname dialog box Open an atom label text box. Remove an atom label. a f P or 4 A or 5 h q b i r 1 k s 2 m S 3 n t c N x C or l o E d T 6 e p B

Key

Key 1 d 2 y 3 l 4 c b r w f H / (slash) or ? h . (period) (single quote) + 0 9 8 / (slash) or ? = (equals) <Enter> <Backspace>, <Delete> or <space>

Command Create a new document Open a document Save a document Save a document as... Print a document Page setup Close a document Exit Chem & Bio Draw Cut Copy Paste Select all Undo Redo Repeat last command Clear Actual size Magnify Reduce Fit to window Toggle ruler Toggle crosshair Toggle fixed length Toggle fixed angles Select multiple objects Group selected objects Ungroup objects Join selected objects Bring to front Send to back Flip horizontal Flip vertical Rotate 180 horizontal Rotate 180 vertical Rotate... (opens Rotate Objects dialog box) Scale...(opens Scale Objects dialog box) Clean up structure Convert name to structure Convert structure to name Center Flush left Flush right Justified Automatic justification Plain Bold Italic Underline Formula Subscript selected character, or next character typed Superscript selected character, or next character typed Adds a degree sign () Copy a selected object Copy a selected object(constrained to X and Y axes) Distort (limit resize to X or Y axis) Toggle the Lasso and the previous drawing tool Change direction of a chain Change orientation of double bonds Create resonance delocalized ring Remove a curve segment

Key Combination Ctrl+n Ctrl+o Ctrl+s Shift+Ctrl+s Ctrl+p Shift+Ctrl+p Ctrl+w Alt+F4 Ctrl+x Ctrl+c Ctrl+v Ctrl+a Ctrl+z Shift+Ctrl+z Ctrl+y Delete F5 F7 F8 F6 F11 Ctrl+h Ctrl+L Ctrl+E Shift+Click (w/ Lasso, Marquee, Structure Perspec. Tools Ctrl+g Shift+Ctrl+g Ctrl+J F2 F3 Shift+Ctrl+H Shift+Ctrl+V Alt+Shift+Ctrl+H Alt+Shift+Ctrl+V Ctrl+R Ctrl+K Shift+Ctrl+K Shift+Ctrl+N Alt+Ctrl+N Shift+Ctrl+C Shift+Ctrl+L Shift+Ctrl+R Shift+Ctrl+J Shift+Ctrl+M Ctrl+ Ctrl+B Ctrl+I Ctrl+U Ctrl+F F9 (in a label) F10 (in a label) Alt+248 (in a label) Ctrl+drag Shift+Ctrl+drag Shift+drag (with resize handle) Ctrl+Alt+Tab Ctrl+Drag (with alkane chain tool) Shift+Click (with saturated double-bond ring tools) Ctrl+Click (with ring tools except chairs) Alt+Shift+Click (with the pen tool)

Ac Ad Ala Alloc Allyl Am Arg Asn Asp Benzoyl Benzyl Bn Boc Bz BOM Bs Bt Btm Bu Bzh Bzl BzOM c-C3H5 c-C4H7 c-C5H9 c-C6H11

c-C7H13 c-C8H15 c-Hx C10H20 C10H21 Cbz cHx CoA Cy cyclobutyl cycloheptyl cyclooctyl cyclopentyl cyclopropyl Cys Dan DEAE DEIPS DMIPS DMPM DMPS DMTr DNP Dnp Dns DNS

DPIPS DPTBS DTBMS DTBS Et Fmoc Gln Glu Gly His i-Am i-Bu i-C3H7 i-C4H9 i-C5H11 i-Pr Ile Im Leu Lys m-C6H4 m-Phenylene m-Tolyl MDIPS MDPS Me

MEM Mes Met MMTr MOM MPM Ms MTM n-Am n-Bu n-C3H7 n-C4H9 n-C5H11 n-Pr N3 neo-Am neo-C5H11 Np o-C6H4 o-Phenylene o-Tolyl p-C6H4 p-Phenylene p-Tolyl Ph Phe

Phenyl Pht Piv PMB PMBM PNB Poc PPi Pr Pro Pv s-Am s-Bu s-Butyl s-C4H9 s-C5H11 SEM Ser SES t-Am t-BOC t-Boc t-Bu t-Butyl t-C4H9 t-C5H11

TBDMS TBDPS TBMPS TBS TDS Tf Tfa TFA Thexyl THF Thf THP Thp Thr TIPDS TIPS TMS Tos trans-Cinnamyl Troc Trp Trt Ts Tyr Val Xyl