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AS/OCT2010/CHM095

UNIVERSITI TEKNOLOGI MARA FINAL EXAMINATION

COURSE COURSE CODE EXAMINATION TIME

CHEMISTRY II CHM095 OCTOBER 2010 3 HOURS

INSTRUCTIONS TO CANDIDATES 1. 2. 3. This question paper consists of five (5) questions. Answer ALL questions in the Answer Booklet. Start each answer on a new page. Do not bring any material into the examination room unless permission is given by the invigilator. Please check to make sure that this examination pack consists of: i) ii) the Question Paper an Answer Booklet - provided by the Faculty

4.

DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO

This examination paper consists of 7 printed pages
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CONFIDENTIAL QUESTION 1

AS/OCT 2010/CHM095

a) Give the correct IUPAC name for the following organic compounds:

i)

i)

T
iii)
CI CH H3C C H2 C H2

CH,

iv)
H3C O H3C OH .CHOH / CH

\
CH3

(4 marks) b) Draw the condensed structural formula for the following organic compounds: i) ii) iii) iv) 3-methyl-2-phenylpentane 2,3,4,5-tetrachlorohexanal 4-methyl-2-hexanol propyne (4 marks) c) Each of the following formula can be written as two compounds with different functional groups. Complete the table below by drawing the structural formula and naming the functional groups. Structural formula Name of functional group

C3H60

C5H10

(8 marks)

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d) Write the structural formula of the missing reactant/product and name the type of reaction that has taken place. i) , + .. H2 catalyst

ii) cone. H2S04

CH3CH2CH2CH=CH2

(4 marks) QUESTION 2

a) The insecticide, DDT, decomposes by a first-order reaction with a half-life of 12 years. How long does it take DDT in a soil sample to decompose from 255 ppbm to 5 ppbm (parts per billion by mass)? (3 marks) b) Phosgene is a toxic gas that can be prepared by the reaction as shown below: CO (gr) + Cl2 (g) - COCI2 (g) These data were obtained in a kinetics study of its formation Experiment Initial [CO] (mol L 1 ) Initial [Cl2] (mol L1) Initial rate (mol L s ) 1.33 x1Q-30 1.32x10 w

0.100 0.100
0.100 1.00

0.100 0.0100
1.00 0.100

1.30x10 29 1.29 x10'

2T

i) Determine the rate law and overall order for the reaction, (5 marks) ii) Calculate the rate constant, /cfor the reaction. (2 marks) c) Assuming a one-step reaction for the reaction A + B - * C, Ea(fwd) = 215 kJ/mol and Ea(rev) = 270 kJ/mol, draw a fully labeled reaction energy diagram. (5 marks)

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d) Ethyl chloride decomposes according to the following equation CH3CH2CI - C2H4 + HCI If the activation energy for the decomposition is 247 kJ mol"1 and the value of A is 1.6 x 10 14 s'\ calculate the ratio of k at 500 C and 700 C? (4 marks)

QUESTION 3

a) Consider the system H2 (g) + l2 (s) =^= 2HI (g) AH = +53.0 kJ

Predict by giving an explanation, whether the forward or reverse reaction will occur when the equilibrium is disturbed by i) withdrawing HI gas out of the reaction vessel (2 marks) ii) compressing the system at constant temperature (2 marks) iii) removing solid l 2 from the reaction vessel (2 marks) iv) increasing the temperature (2 marks) b) For the reversible reaction H 2 (g) + F 2 ( g ) ^ 2 H F ( g ) 0.3 mol of H2 (g) and 5 x 10"2 mol of F2 (g) are mixed in a two-litre flask. After equilibrium is established, 8.0 x 10"3mol HF (g) is present. Calculate i) the equilibrium concentration of each reactant. (3 marks) ii) value of Kc (1 Y2 marks) iii) value of Kp (1 1/4 marks)

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c) Mustard gas has been found to be an effective chemotherapeutic agent for Hodgkin's disease. It can be produced according to the following reaction SCI2 (g) + 2C2H4 (g) ^ S(CH2CH2CI)2 (g)

An evacuated five-litre flask at 20 C is filled with 0.258 mol SCI2 (g) and 0.592 mol C2H4 (g). After equilibrium is established, 0.0349 mol mustard gas is present. 1 (R= 0.0821 L atm K ~ mol"1) i) Calculate the partial pressure of each gas at equilibrium. (4 Y2 marks) ii) What is Kp at 20 C (1 J4 marks)

QUESTION 4

a) Predict whether the following substances are acidic, basic or neutral. i) ii) iii) iv) An aqueous solution of CH3COOK An aqueous solution of (NH4)2S04 An aqueous solution of Kl A cup of black coffee ([H+] = 5 x 10"5 M) (2 marks) b) The Ka values at 298 K for four organic acids are given below Conjugate base CH3COOHCOCr CICH2COO" CI3CCOOKa 1.8 x 1 0 s 1.8 x10" 4 1.4 x10" 3 2.2 xlO" 1

Arrange their respective conjugate bases in ascending order of their basic strengths. (4 marks) c) Calculate the pH for each of the following solutions. i) ii) iii) iv) 5x10" 3 MHCI 4x10- 2 MBa(OH) 2 0.1 M ammonia solution (Kb = 1.8 x 10"5M) A mixture of 100 ml_ of distilled water and 2 mL of 2 M NaOH. (4 marks)

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d) Consider the titration of 50 mL of 0.25 M ammonia, NH3 with 0.5 M hydrochloric acid, HCI. (Kb for NH3 = 1.8 x 10"5 M, Ka for NH4+ = 5.6 x 10"10). Calculate i) the initial pH (2 marks) ii) the volume of HCI is required to reach the equivalence point (2 marks) iii) the pH at the equivalence point (3 marks) e) A 3 L buffer solution is prepared by dissolving 1.0 mol propanoic acid and 1.0 mol sodium propanoate in water. (Ka for propanoic acid = 1.30 x 10 "5 M). i) Calculate the pH of this buffer (1 mark) ii) Calculate the pH of this buffer when 0.01 mol of calcium hydroxide, Ca(OH)2, is added to it. (3 marks)

QUESTION 5

a) Balance the following reaction in acidic condition: Cr2072- (aq) + NO (g) -> Cr3+ (aq) + N03" (aq) (3 marks) b) The electromotive force (e.m.f.), E0cen, for the following cell is 0.8 V. Pt(s) / H2(gr, 1 atm)/H+ (aq, 1 M) II Ag*(aq, 1M) / Ag(s) i) Draw a labeled diagram of the cell. Indicate the direction of the flow of electrons in your diagram. (4 marks) ii) Determine the standard reduction (redox) potential of silver. (2 marks) iii) Explain how the concentration of the solution at the anode and cathode would change after the cell had been discharged continuously. (4 marks) iv) If the acid in the above cell is replaced by hydrochloric acid of a different concentration, the e.m.f. of the cell is +1.12 V at 25 C and 1.0 atm. Determine the concentration and the pH of the hydrochloric acid used. (4 marks)

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c) Consider the following table of Standard Reduction Potentials at 25 C Half-reaction Fe27Fe Cr37Cr Cd27Cd AgVAg Br2/2Br" Au37Au E(V) -0.76 -0.74 -0.40 +0.80 +1.07 +1.50

Which species in each pair is a better oxidizing agent under standard conditions? i) Cd 2+ orCr 3+ (1 mark) ii) Br2 or Au
3+

(1 mark) iii) Fe 2+ orAg (1 mark)

END OF QUESTION PAPER

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