DATE # 27.10.98 JOB NO. 6128A SUB : CHEMICAL CLEANING FOR SH HEADER SYSTEM VOLUME = 140m3.(Approx.

) Vendor's name 1 a. Required major items Circulating pumps Enquiry Spec. DC Industrial Plant Services 100HP Pump Motor Set - 150m3/hr. 40HP Pump Motor Set - 90m3/hr. 25HP Pump Motor Set - 250m3/hr. 20HP Pump Motor Set - 70m3/hr. Circulation tank(10m3.approx.) Chemtreat India Dynamic Industrial & Cleaning Services Capacity : 150m3/hr.,80MWC. 75HP Motor,56kW,3000rpm. Remarks

Tanks

# Neutralising tank(20m3), Dissolving tank with steam heating arrangement. capacity 6m3.
turbidity difference between discharge

Pre-Flushing Cold water flushing temp./duration Hot water flushing temp./ duration Analysis criteria

& feed - less than 10ppm

upto 75deg.C Visual check of waste water

# Details awaited. turbidity difference between discharge & feed - less than 10ppm

Room temperature / 2 ~ 4hrs. 70 ~ 80deg.c / 2hrs. Water clearity

CHEMICAL CLEANING Alkali Degreasing Sodium Hydroxide(Conc. In % or Wt.) Sodium Carbonate (Conc. % or Wt.) 0.50% # Sodium Nitrate (NaNO3,conc.%) Tri-sodium phosphate 0.50% d. Wetting Agent (conc%) 0.05% e. Temp in deg.C 70-80 f Time required in hours 12Hrs. Minimum Temperature, pH, concentration of alkalinity to be checked every hour. Oil every 3hours. B. a. Rinsing DM water quantity/time pH Conductivity

3 A. a. b. c.

0.50% 0.50% 0.05% 70-80 12Hrs. Minimum

0.50% 0.50% 0.05% 70-80 12 hrs.

10(_+0.5)

Flush until pH Below 9.0 50 microsiemens

Heating up & Acid Pickling Citric Acid in % or Wt. 3% Ammonium - bi - fluoride 0.30% Acq NH3 in pH 3 ~ 3.5 Corrosion Inhibitor 0.30% Temp in deg.C 75 ~ 85 Treating Time required in hours 6hrs. Minimum End Result of acid cleaning Iron Conc.(Fe+2/Fe+3) equilibrium for 1 ~2hrs. Fe ion, acid concentrations,pH to be checked every hour.

C. a. b. c. d. e f g

3% 0.3% (ABF) 3 ~ 3.5 0.30% 75 ~ 85 6-8 hrs. Minimum equilibrium for 1 ~2hrs.

2 ~ 3% 0.30% 3 ~ 3.5 0.20% (Rodine 92B ) 80 ~ 85 6 ~ 8hrs minimum # Equilibrium of acid% & total iron

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D a. b. c.

Flushing & Draining DM water requirement / time pH Iron Conc.

# No flushing recommended. # No flushing recommended. Only cooling down to 65C

Progressive flushing & draining for 6~8 hrs. Less than 50ppm. Not acceptable

E a. b. c. d. e.

Post Pickling & Passivation System temperature to maintain pH raised byNH3 injec. Charge NaNo3 Treating Time required in hours Completion test

65deg.c 9 ~ 9.5 0.50% Passivation time 4hrs.min

65deg.c 9 ~ 9.5 0.50% 4 Vendor to confirm

65 deg.c 9~9.5 0.50% 4 ~ 6hrs.

F a.

# Final Rinsing& drying DM Water Qty./ Time

DM water containing 100ppm.hydrazine (N2H4) & # 50ppm.ammonia 10ppm.

Ammoniated water. No hydrazine. 50ppm hydrazine is acceptable

Ammoniated water. No hydrazine./ 6~8hrs. duration. 50ppm hydrazine is acceptable

b. c H a

Turbidity Temperature Effluent Alkali Degreasing Temperature,deg.c Typical analysis

Room Temperature

pH6~8,COD60~70ppm, SS50~100ppm.

Approx.volume Neutralising chemical Acid Treatment Temperature,deg.c Typical analysis

pH - Highly alkaline, Res.phosphate : 4000 ~ 5000 ppm. Res.caustic : 400 ~ 500 ppm. Vendor to confirm # Hydrochloric acid

pH - 8~9 400~500m3

70 ~ 80 P.Alk 2000~3000ppm,pH9.5 ~10.5 600 Sulphuric acid with dilution water

pH - 4~5

500m3 Approx.volume Neutralising chemical c Passivation Temperature,deg.c Typical analysis Approx.volume Neutralising chemical Note : # Rev.1 # Total DM water requirement = 1800m3. (approx.) LP steam flow 4~5 T/hr. Vendor to confirm pH6~8,COD5000~6000ppm., pH : 9~10,colour:Wine red, SS50~100ppm Iron : 5000~9000ppm.,Odour:Pungent pH - 7~8 100m3

75 ~ 85 Citric acid 0.5~1.0%, Iron2500~6000 ppm,pH3.5~4,Inhibitor0.05~0.1%, ammonia 600 Burnt lime & dilution with water

50 ~ 60 pH = 10.0 with ammonia

Sulphuric acid with dilution water *Add 0.5% citric acid # DM water requirement = 2250m3. # Steam = 170Tonnes.

steam.xls

DATE # 27.10.98 JOB NO. 6128A SUB : CHEMICAL CLEANING FOR WASTE HEAT RECOVERY SYSTEM TOTAL VOLUME FOR CHEMICAL CLEANING = 200(EQUIPMENT VOLUME+ PIPING VOLUME+BFW PIPING) + TEMPORARY PIPING VOLUME (BY CONTRACTOR) Vendor's name 1 a. Required major items Circulating pumps Enquiry Spec. (BORSIG Procedure) DC Industrial Plant Services 100HP Pump Motor Set - 150m3/hr. 40HP Pump Motor Set - 90m3/hr. 25HP Pump Motor Set - 250m3/hr. 20HP Pump Motor Set - 70m3/hr. Circulation tank(10m3.approx.) Chemtreat India Dynamic Industrial & Cleaning Services Capacity : 150m3/hr.,80MWC. 75HP Motor,56kW,3000rpm. Remarks

Tanks

Neutralising tank(20m3), Dissolving tank with steam heating arrangement. capacity 6m3.
turbidity difference between discharge & feed - less than 10ppm

turbidity difference between discharge

Pre-Flushing Cold water flushing temp./duration Hot water flushing temp./ duration Analysis criteria CHEMICAL CLEANING Alkali Degreasing Trisodium phosphate (wt.%) Surfactant(wt.%), Dispersant (wt.%) sodium carbonate Temp. in deg.C Time required in hours

& feed - less than 10ppm

20 ~ 80deg.c Turbidity

20 ~ 80deg.c Water clearity

Room temperature / 2 ~ 4hrs. 70 ~ 80deg.c / 2hrs. Water clearity

3 A. a. b. c. d e

0.5% 0.05% 0.50% 80 12 hrs.

0.5% 0.05% 0.50% 80 12 hrs.

0.5% 0.05% 0.50% 70 ~ 80 12 hrs.

B. a.

Rinsing DM water quantity/time pH Conductivity

3 ~ 4 system volume 7 50 microsiemens / cm.

9 50 microsiemens / cm.

Flush until pH Below 9.0 50 microsiemens / cm.

C. a. b. c. d. e. f. g.

Acid Pickling Citric Acid in % or Wt. 3% *Ammonium - bi - fluoride Or Hydrofluoric acid 0.6% or 0.3% pH 3 Corrosion Inhibitor 0.25% Suspended Agent Temp in deg.C max.80deg.C Treating Time required in hours Till constant Iron Conc.

3% 0.6%(ABF) 3 ~ 3.5 0.25% 80 6 ~ 8hrs minimum

3% 0.6%(ABF) 3 ~ 3.5 0.20% (Rodine 92B ) 80 ~ 85 6 ~ 8hrs minimum

D a.

Flushing & Draining DM water requirement / time

3 ~ 4 system volume

only cooling down to 65C No flushing & draining

only cooling down to 65C No flushing & draining

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b. c. d E a. b. c. d.

pH Iron Conc. Conductivity **Post Pickling & Passivation System temperature to maintain pH raised byNH3 injec. charge NaNO2, wt% Treating Time required in hours

7 50 microsiemens / cm.

7 Less than 50ppm. 50 microsiemens / cm.

60deg.C 10 # 0.5% 5hrs.minimum

65deg.c 9~9.5 # 0.5% 5hrs.minimum

65deg.c 9~9.5 # 0.5% NaNO2 4 ~ 6hrs.

F a.

Rinsing&drying DM Water Qty./ Time

/ 6 ~ 8 hrs.

H a

Effluent Disposal Alkali Degreasing Temperature,deg.c Typical analysis

40 pH 7

pH - Highly alkaline, Res.phosphate : 4000 ~ 5000 ppm. Res.caustic : 400 ~ 500 ppm. # Hydrochloric acid

70 ~ 80 P.Alk 2000~3000ppm,pH9.5 ~10.5 600m3 Sulphuric acid with dilution water 75 ~ 85 Citric acid 0.5~1.0%, Iron2500~6000 ppm,pH3.5~4,Inhibitor0.05~0.1%, ammonia 600m3 Burnt lime & dilution with water

Approx.volume Neutralising chemical Acid Treatment Temperature,deg.c Typical analysis

1system volume

40 pH = 7

Approx.volume Neutralising chemical c Passivation Temperature,deg.c Typical analysis Approx.volume Neutralising chemical

1system volume Sodium hydroxide(NaOH) Calcium hydroxide(Ca(OH)2)

pH : 9~10,colour:Wine red, Iron : 5000~9000ppm.,Odour:Pungent

50 ~ 60 pH = 10.0 with ammonia

Sulphuric acid with dilution water

Note : # Rev.1

**Solution contains 1% Citric acid & 0.25% inhibitor.

*Add 0.5% citric acid DM Water Qty. = 2600m3(approx.) # Steam = 130Tonnes

steam.xls