13

th
(Date: 03-06-2012) Unit Test-1
Code-A
ANSWER KEY
PHYSICS
SECTION-1
PART-A
Q.1 B
Q.2 B
Q.3 B
Q.4 A
Q.5 D
Q.6 A
Q.7 B
Q.8 C
Q.9 A
Q.10 D
Q.11 A,D
Q.12 A,C
Q.13 A,B,C
PART-B
Q.1 (A) P, S
(B) Q, S
(C) Q, S
PART-C
Q.1 0075
Q.2 0016
Q.3 0001
Q.4 0378
CHEMISTRY
SECTION-2
PART-A
Q.1 B
Q.2 D
Q.3 C
Q.4 C
Q.5 C
Q.6 C
Q.7 C
Q.8 C
Q.9 D
Q.10 C
Q.11 A,C
Q.12 A,C,D
Q.13 B,C
PART-B
Q.1 (A) Q,R,S
(B) P
(C) S
PART-C
Q.1 0134
Q.2 0091
Q.3 0056
Q.4 0004
MATHS
SECTION-3
PART-A
Q.1 B
Q.2 D
Q.3 C
Q.4 B
Q.5 C
Q.6 B
Q.7 B
Q.8 A
Q.9 A
Q.10 B
Q.11 A,C
Q.12 B
Q.13 A,B,D
PART-B
Q.1 (A) Q
(B) S
(C) R
PART-C
Q.1 0015
Q.2 0000
Q.3 0001
Q.4 0003
PHYSICS
Page # 1
PART-A
1. B, D
2. B
3.
2
1
L
L
A
A
=
2 1
1 2
L A
L A
1
2
A
A
=
2
1
2
2
d
d
=
4
1
=
4
1

2
1
=
8
1
]
4. 5.1 5 (48.6 28.2) = 20 4.18 (28.2 22.1)
S = 4.9 J/gC ]
5.
dt
du
= constant.
more time interval more energy gained. ]
6. A
7.
l
l A
= Y
A
F
Al =
AY
Fl
=
6 10
3
10 5 10 10
2 10 5

= 2 cm ]
[PARAGRAPH TYPE]
Q.8 to Q.10 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Paragraph for question nos. 8 to 10
(i). a
scale
= a
hot body
radial elongation of plate = linear elongation of scale.
(ii) A
(iii) If the tape had not expanded, measurement would have been C' = 2pr (1 + a (T0 T)
but the scale also expanded, C < C'
11. [Work] = [Energy] = [Torque] = ML
2
T
2
[Pressure] = [Stress] = [Modulus of elasticity] = ML
1
T
2
12. Dist. travelled = 400 + 300 = 700 m
|displacement | =
2 2
300 400 +
= 500 m
13. Energy density =
2
1
(stress) (strain) =
2
1
y
) stress (
2
=
2
1
y (strain)
2
PHYSICS
Page # 2
PART-B
1. (A) 1g ice at 0C + 1g water at 70C
AQ = 1 80 + MSAT DQ = MSAT
= 80 cal 1 1 (70 T)
max. heat = 70 cal
All ice will not melt
water + ice at 0C
(B) 1g ice 0C + 1g steam at 100C
1 80 + 1 1 100 M LV = 540 cal
water at 100C + steam + water at 100C
(C) 1g ice 0C + 1 g water 50C + 1g steam 100C
mL
f
+ msAT m s AT m Lv
180 + 11100 = 50 cal = 540 cal
= 180 cal
1g water at 100C
water + steam at 100C ]
PART-C
1. (100 T)
18
k 9
A = (T 0)
6
kA
T = 75C ]
2. W =
2
1
(stress) (strain) (volume) (AL
2
= AL
1
, Y
2
= Y
1
, r
2
= 2r
1
, L
2
=
2
L
1
)
W
1
=
2
1
t
1
2
1
L
yr
(AL
1
)
2
W
2
=
2
1
tY
2 / 1
2
1
L
r 4
(DL
1
)
2
= 8
2
1
t
1
2
1
L
yr
(AL
1
)
2
= 8W
1
= 16 J ]
3. A (0, 0, 0) , B (1, 1, 1) , C (1, 0, 0), D (0, 1, 1)
A
B
D
C
y
x
z

AB
=
k

+ +
;

CD
=
k

+ +
cos u =
| CD | | AB |
CD AB


=
3 3
1 1 1 + +
=
3
1
3 cos u = 1 ]
4. v = 210 mm
3
, = 180 10
6
/C
AV = VgAT
= 210 180 10
6
1 mm
3
AV = 378 10
4
mm
3
]
CHEMISTRY
Page # 1
PART-A
1. K
x
H
y
(C
2
O
4
)
z
.2H
2
O
1 x + 1 y + (2) z = 0 x + y = 2z
2. NCl
5
N-atom does not have vacant orbital it cannot expand its valency.
OF
4
Similarly O-atoms also.

3
XeF
3 bp + 3lp = 6, but it is not considered in geometry form.
3. C = 27 gm , O
2
= 48 gm
2C + O
2
2CO
x moles
2
x
moles x moles
C + O
2
CO
2
y moles y moles y moles
Total amount of 'C' used up = 12 (x + y)
Total amount of 'O' used up =16 x + 32 y
Now 12 x + 12 y = 27 (i)
16x + 32y = 48 x + 2y = 3 (ii)
12x + 12 y = 27
12x + 24 y = 36

12 y = 9
y =
4
3
x + 2
4
3
= 3 x =
2
3
W
CO
= 28 x, W
CO
2
= 44 y

4 / 3
3/2

11
7

y 44
28

W
W
2
CO
CO
= =
x
W
CO
:

2
CO
W = 14 : 111
4.

2
ICl
2bp + 3 lp = sp
3
d
I
Cl
Cl
Linear
CO
2
O = C = O linear
sp
5. 22.4 L at S.T.P. = 1 mole gas.

4 2 4
H C CH
n n +
= 1 mole
CHEMISTRY
Page # 2
32
8 . 76
n
2
O
=
= 2.4
CH
4
+ 2O
2
CO
2
+ 2H
2
O
x mole 2x mole
C
2
H
4
+ 3O
2
2CO
2
+ 2H
2
O
y 3y
Total No. of moles of O
2
(used up) = 2x + 3y
Total No. of moles of CH
4
and C
2
H
4
(used up) = x + y
x + y = 1
2x + 3y = 2.4
2x + 2y = 2

y = 0.4
4 2
H C
X
=
1
4 . 0

y
y
=
+ x
4 2
H C
X
= 0.4
6.

5
XeF 5bp + 1 l =

part take is orbital
2
y
2
x
d
2 3
ion hybridisat d sp

]
7. Substance contains atleast one atom of 'N' and one atom of 'O'
Atomic mass of 'N' = 14, Let molar mass of sub = m
% of N =
m
14
100 = 7
m = 200
% of O =
m
16
100 = 4
m = 400
If we take m = 200, then will be
2
1
atom of 'O' and one atom of 'N' ,which is not possible. Now if we
take m = 400 there will one 'O' and two 'N' which is possible
m
min
= 400 gm/mole
Paragraph for question nos. 8 to 10
[Sol.
(i) sp
o
25% s-character means if o = 3, then hybridisation is sp
3
which has 25% s-character.
(ii) Steric number = (bond pairs + lone pairs)
= 4 + 0 Tetrahedral 109.28'
= 3 + 1 Pyramidal
= 2 + 2 Bent shape
If molecule is CH
4
all bond angle = 109.28' but CH
2
F
2
all bond angle are not 109.28'.
(iii) x,y,z belongs to 2
nd
period.
x (Valence electron = 4) + H
2
CH
4
(I)
y (Valence electron = 5) + H
2
NH
3
(II)
CHEMISTRY
Page # 3
z (Valence electron = 6) + H
2
H
2
(III)
C
H H
H
H
= 0
N
H H
H

R
0
O
H H

R
0
Same hybridisation lone pair | dipole increases. I < II < III ]
11. Cl C C H
Cl
H
H
O
O
Cl
Intra-molecular
chloral hydrate
Intra-molecular
OH
Cl
CH
3
C CCH
3
O
O
H
H
O
O
Intermolecular
C
OH
HO
H
O
O
C
H
]
12. Oleum 113.5 % 13.5 gm of water is to be added to get maximum H
2
SO
4
from 100 gm of
solution i .e. to convert free SO
3
into H
2
SO
4
SO
3
+ H
2
O H
2
SO
4
80 gm 18 gm
18 gm of H
2
O converts = 80 gm SO
3
into H
2
SO
4
13.5 gm of H
2
O converts =
18
80

10
5 . 13
= 60
100 gm of such oleum solution contains 60 gm free SO
3
Hence 50 gm of such oleum solution contains 30 gm free SO
3
(A)
Now on adding 6.75 gm of H
2
O, 30 gm free SO
3
is converted to 36.75 gm H
2
SO
4
H
2
SO
4
produced = 56.75 gm
on adding 8 gm H
2
O to 100 gm original solution
W
sol
= 108 gm
Amount of H
2
SO
4
produced from free SO
3
on adding 8 gm of H
2
O to original
Solution =
13.5
10 8 60
=
9
320
gm
CHEMISTRY
Page # 4
Now amount of free SO
3
left in solution =
9
320 60
=
9
220
gm.
108 gm oleum solution contains
9
220
gm of free SO
3
Amount of free SO
3
in 100 gm solution =
100
100
9
220

=
9 108
100 220

Amount of water required to convert aobve amount of free SO

3
into H
2
SO
4
=
27
5 . 137
New labelling of oleum sample =
|
.
|

\
|
+
27
5 . 137
100
% [Ans.A, C, D]
13. ICN (Solid)
[I CN]
2

[ICN]

2
I
C
C
N
N
sp
sp
I (Central atom sp d hybridised)
3
]
PART-B
1. (A) 17% by mass solution of H
2
O
2
W
B
= 17 gm, W
sol
= 100 gm
d
sol
= 1.2 gm/mL
V
sol
=
2 . 1
100
mL, W
A
= W
sol
W
B
, m
B
= 34 gm/mole
Molarity =
(mL) V m
1000 W
sol B
B

=
2 . 1
100
34
1000 17

Molarit = 6 M
Molality =
) gm ( W m
1000 W
A B
B

=
83 34
1000 17

=
83
500
m
Volume strength = Molarity 11.2
= 6 11.2 = 67.2

CHEMISTRY
Page # 5
(B) 100 mL H
2
O
2
+ 100 mL H
2
O
2
solution of volume strength 22.4
Molarity =
11.2
strength Volume
=
2 . 11
4 . 22
= 2
M
1
V
1
+ M
2
V
2
= M (V
1
+

V
2
)
4 100 + 2 100 = M 200
M = 3
B P
(C) 24% by volume NaOH solution W
B
= 24 gm , V
sol
= 100 mL
m
B
= 40 gm/mole
molarity =
) mL ( V m
1000 W
sol B
B

=
100 40
1000 24

= 6 M
C S
PART-C
1. (COOH)
n
+ AgNO
3
Silver salt white residue
Amount of residue obtained (W
2
) = 54 gm
No. of moles of silver salt used (n
1
) = 0.25
n 108
W
2

= n
1
n 108
54

= 0.25 n = 2
2
) COONa (
m

=

2 12 + 4 16 + 2 23 = 0134 gm/mole]
2. CH
2
= C = C = CH(CH
3
)
sp
2
sp sp sp
2
C
H
H
H
H
H
H C
C C C
y-axis x-axis y-axis
-bond -bond -bond
Molecular
Axis
z-axis
All incircle atoms are lying in same plane = 9 atom and only one such plane is possible which has
maximum number of atoms. ]
CHEMISTRY
Page # 6
3. 2NH
3
+ H
2
SO
4
(NH
4
)
2
SO
4
40M mole (5030)=20Mmole
H
2
SO
4
+ 2NaOH NH
2
SO
4
30Mmole 60Mmole
% of N = 100
1
14 10 40
3

= 56% Ans.]
4. *H
3
PO
2
P
O
H OH
H
H
4
P
2
O
7
OO O
OH
H H
P P
O
HO
* H
4
P
2
O
5
OO O
OH
H H
P
P
O
HO
H
2
S
2
O
6
OO
O
O
O
HO S S OH
* H
3
PO
3
P
O
H OH
OH
H
3
BO
3
B
OH
HO OH
H
2
SO
4
S
O
HO
O
OH
H
4
P
2
O
6
OH OH
| |
OH P O P H
| | | |
O O

MATHEMATICS
Page # 1
PART-A
1. o + | = 4 ; o| = 2
o
2
+ |
2
= 16 4 = 12
o
3
+ |
3
= 4(o
2
o| + |
2
)
= 4 (16 3 2) = 40
Quadratic equation is (x 12) (x 40) P(x)
Sum is P(1) = ( 11) ( 39) = 429. Ans.]
2. f (x) > 0 x
2
+ 2px (3p + 4) > 0 for atleast one real x
x
2
2px + (3p + 4) < 0 for atleast one real x
Hence D > 0
p
2
3p 4 > 0 (p 4)(p + 1) > 0
p e ( , 1) (4, )
Hence smallest positive integral value of p is 5 Ans.]
3. We have
+

100 cos 2 2 2
20 sin 20 cos
=


50 cos 2 2 2
20 sin 70 sin
2
=


50 cos 2 2
20 sin 70 sin
=


25 sin 2 2
20 sin 70 sin
2
=

25 sin 2
25 sin 45 cos 2
= cos 45 =
2
1
. Ans.]
4. We have A = 1 ; B = 4 ; C = 3 ; F = 3 ; G = k ; H = 1
Now, ABC + 2FGH AF
2
BG
2
CH
2
= 0
k = 0,
2
3
k
1
=
2
3
, k
2
= 0
(k
2
k
1
) =
2
3
Ans. ]
5. 2cos
2
x + cos x 1 = 0 (2cos x 1) (1 + cos x) = 0 cos x =
2
1
or cos x = 1
i.e.
3
5
, ,
3
t
t
t
. Ans.]
6. x
4
= 3x 1
x
3
= 3
x
1

o
3
= 3
o
1
; |
3
= 3
|
1
;
3
= 3

1
; o
3
= 3
o
1
MATHEMATICS
Page # 2
on adding
|
|
.
|

\
|
o
+

+
|
+
o
= o

1 1 1 1
12
3
=
o|o
o|

12
= 12 3 = 9 Ans.]
7. As, l
1
= ru
1
; l
2
= ru
2
; l
3
= ru
3

r
5
r
4
r
3
+ +
= 2t
r
12
= 2t r =
t
6
u
1
=
r
1
l
=
t 6
3
=
2
t
; u
2
=
r
2
l
=
t 6
4
=
3
2t
and u
3
=
r
3
l
=
t 6
5
=
6
5t
Hence, sin u
1
+ sec u
2
+ cosec u
3
=
6
5
cosec
3
2
sec
2
sin
t
+
t
+
t
= 1 2 + 2 = 1. Ans.]
Paragraph for question nos. 8 to 10
[Sol.
(i) Given
f(x) > g(x) x e R
px
2
+ px 2 > x
2
+ (2p + 1) x + p + 2 x e R
(p 1) x
2
(p + 1) x p 4 > 0 x e R
So, p 1 > 0 p > 1
and, D < 0 (p + 1)
2
+ 4 (p 1) (p + 4) < 0
p
2
+ 2p + 1 + 4 (p
2
+ 3p 4) < 0
5p
2
+ 14p 15 < 0

|
|
.
|

\
|
+ +

|
|
.
|

\
|
+

10
300 196 14
p
10
300 196 14
p < 0
( ) ) 8 . 0 p ( ) 6 . 3 ( p < 0
p e ( 3.6, 0.8) but p > 1
Hence, there is no value of 'p' for which f(x) > g(x) x e R. Ans.
(ii) Given, g(x) = h(x)
x
2
+ (2p + 1) x + p + 2 = 2x
2
+ (p + q) x + 2q
x
2
+ (p + q 2p 1) x + 2q p 2 = 0
x
2
+ (q p 1) x + 2q p 2 = 0, has non real roots q e R
So, D < 0 x e R
(q p 1)
2
4(2q p 2) < 0 q e R
q
2
+ (p + 1)
2
2q (p + 1) 8q + 4(p + 2) < 0
q
2
2q (p + 5) + p
2
+ 6p + 9 < 0 q e R, which is not possible q e R.
So, number of integral values of p is zero. Ans.
(iii) Given,
f(x) = h(x) px
2
+ px 2 = 2x
2
+ (p + q)x + 2q
(p 2)x
2
qx 2 2q = 0, has real roots q e R
For p 2 = 0
So, D > 0 q
2
+ 4(p 2) (2 + 2q) > 0 q e R
q
2
+ 8 (p + pq 2 2q) > 0 q e R q
2
+ 8q (p 2) + 8(p 2) > 0 q e R
So, D' s 0 64(p 2)
2
4 8 (p 2) s 0 (p 2) (2p 4 1) s 0
(p 2) (2p 5) s 0 2 s p s
2
5
MATHEMATICS
Page # 3
but p = 2, therefore p e
(

\
|
2
5
, 2
now for p = 2 equation reduces qx 2 2q = 0 x =
q
q 2 2

+
for q = 0 equation does not have any real solution.
Hence p e
(

\
|
2
5
, 2
Ans. ]
11. Put log
y
x = t 7t
2
48t 7 = 0
t = 7 or t =
7
1
Now, t = 7 log
y
x = 7
As x = 8y log
y
(8y) = 7 log
y
8 + 1 = 7
8 = y
6
y =
2
and x =
2 8
k = 8
Now, verify alternatives. (rejected) ]
12. Given, P(x) = cot
2
x
|
|
.
|

\
|
+ +
+ +
x cot x cot 1
x tan x tan 1
2
2
+
2
) x 2 cos x 2 (sin 2
x sin x 3 sin x 3 cos x cos
|
|
.
|

\
|
+
+
=
x cot x cot 1
1 x cot x cot
2
2
+ +
+ +
+
2
) x 2 cos x 2 (sin 2
) x 2 cos x 2 (sin x sin 2
|
|
.
|

\
|
+
+
= 1 + sin
2
x
P(18) + P(72) = (1 + sin
2
18) + (1 + sin
2
72)
= 1 + 1 + (sin
2
18 + cos
2
18)
= 3. Ans.]
13. a < 0;
a
b
< 0 b < 0;
a
c
< 0 c > 0
now b c = ( ve) (+ ve) must be negative
bc = () (+ve) must be negative
ab
2
= () (+ve) must be negative
c a = (+) ( ) must be positive]
PART-B
1.
(A) Maximum value of P(x) in [1, 2] occurs at x = 1.
Hence, P(1) = 1 c 10 = 1 c = 11. Ans.
(B) Minimum value of P(x) in [1, 5] occurs at x = 3.
Hence, P(3) = 1 c 18 = 1 c = 17. Ans.
(C) Maximum value of P(x) in [1, 4] occurs at x = 1.
Hence, P(1) = 2 c 10 = 2 c = 12. Ans. ]
MATHEMATICS
Page # 4
PART-C
1. u =
15
t
= 12, so
L.H.S. = sin 24 + sin 48 + sin 96 + sin 192 = (sin 24 + sin 96) + (sin 48 + sin 192)
= 2sin 60 cos 36 + 2sin 120 cos 72 = 3 (cos 36 + cos 72)
=
|
|
.
|

\
|

+
+
4
1 5
4
1 5
3 =
|
|
.
|

\
|

4
5
2 3 =
2
15
=
2
p
(given)
Hence, p = 15. Ans.]
2.

= u
|
.
|

\
|
u + u u + u
89
1
2 4 2 4
sin 4 cos cos 4 sin =
( ) ( )

= u
u u
89
1
2
2
2
2
cos 2 sin 2
=

= u
|
.
|

\
|
u + u u + u
89
1
2 4 2 4
cos 4 4 cos sin 4 4 sin
=
( )

= u
u u
89
2 2
1
) cos 2 ( ) sin 2 (
=

= u
u
89
1
2 cos
=

series cosine
178 cos ...... 6 cos 4 cos 2 cos + + + +
=
( )

|
.
|

\
| +
1 sin
89 sin
2
178 2
cos
= 0. Ans.]
3. f (x) = (x 3a) (x a 3) = x
2
x (3 + 4a) + 3a
2
+ 9a
1 3
x-axis
Given f(x) s 0 x e [1, 3]
f(1) s 0 and f(3) s 0
Now, f(1) = 1 (3 + 4a) + 3a
2
+ 9a s 0
3a
2
+ 5a 2 s 0
(a + 2) (3a 1) s 0 a e
(

3
1
, 2
...........(1)
2 1/3
Now, f(3) = 9 3( 3 + 4a) + 3a
2
+ 9a s 0
3a
2
3a s 0
3a (a 1) s 0 ...........(2)
0 1
(1) (2)
a e
(

3
1
, 0
Number of integral values of a is one i.e., a = 0. Ans.]
MATHEMATICS
Page # 5
4. Given
x
2
+ y
2
+ xy + 1 p(x + y) > 0 x, y e R
x
2
+ x (y p) + y
2
+ 1 py > 0 x e R
So, D s 0 y e R
(y p)
2
4(y
2
+ 1 py) s 0 y e R
y
2
2py + p
2
4y
2
+ 4py 4 s 0 y e R
3y
2
2py + 4 p
2
> 0 y e R
So, D s 0
4p
2
12 (4 p
2
) s 0
p
2
+ 3p
2
12 s 0
p
2
3 s 0
So, p e
| | 3 , 3
Number of integral values of p is 3 i.e., { 1, 0, 1}. Ans.]