IITJEE CHEMISTRY SAMPLE PAPER IV

SOLUTIONS
SECTION I Straight Objective Type 1. (c) As the size of F is very small compared to that of Cl, bond length dominates over electro-negativity difference. Hence, dipole moment of CH3Cl > CH3F. As F is more electro-negative than Cl, in CH3F C is more electron deficient than that of the carbon is CH3Cl. So shared pairs of CH bond are staying more closer to C in case of CH3F and more bond pair-bond pair electron repulsion and more will be the HCH bond angle. Lassaignes test for nitrogen fails if the nitrogen containing compound does not contain carbon.

2.

(b)

OCH3
3. (b)

Br
CH3OH

CH2CH2 Br

CH2CH2
+

Br

CH2CH2 Br

Br

O
4. (c)

The compound (A) is CH3CCH(OCH3)2 because it contains CH3C group which responds to iodoform test. It does not react with Tollens reagent, because it does not contain CHO group. O On hydrolysis, it converts to CH3CCH2CHO , which can react with Tollens reagent. The compound (a) is not possible because hemiacetals can give Tollens reagent test.

5.

(d)

CaCO 3
(X)

CaO CO 2
Ca (OH) 2
(Y)

CaO H 2 O
Ca (OH) 2

CO 2

CaCO 3

H 2O
( Z)

CaCO 3
6. (c)
1.6 10
19

CO 2
10 4

H 2O
1 mv 2 2

Ca (HCO 3 ) 2

= 7. (b) X(s) Y(s)

h 0.123 mv

A(g) + 2B(g) p1 (2p1 + 2p2) 2B(g) + C(g)

Since

(2p1 + 2p2) Kp p
1

p2

KP

p2

p1
4.5

2p 2

103 = p2.4(3p2)2 = 36 p23 4.5 1 p23 10 3 10 3 36 8 p2 = 0.05 atm P1 = 2 .05 = 0.10 atm p t p1 2p1 2p 2 p 2 3(p1

p 2 ) = 3(0.10 + 0.05) = 0.45 atm.

8.

(a)

D C

D A

SECTION II Reasoning Type 9. 10. (d) (c) [Cu(NH3)4]+2 has square planar geometry.

CH3CH2CH2CH3 + Cl2

hv

* CH3CH2CHCH3 Cl

11.

(c)
CH3 CH3CH2CHOCH3 + H+ CH3CH2CHOCH3 CH3 H
Br

CH3Br + CH3CH2CHCH3 OH

12.

(d)

ln

k2 k1

Ea 1 R T2

1 T1

Ea 1 R T1

1 T2

Higher the value of Ea, greater is the in rate.

k2 ratio and hence, greater will be the increase k1

SECTION III Linked Comprehension Type PassageI 15. 16. (d) (b) The feasible reaction is Cu (s) 2Ag (aq)
E0 cell 0.8 0.34 ve
Cu (aq) 2Ag (s) as

17. 18. 19. 20.

(d) PassageII (d) (b) (b) SECTION IV Matrix Match Type NaNO2/conc. HCl at 05C results in diazonium salt formation which forms 1, 2, 3tribromobenzene with H3PO2.

1.
2.

(A) 2 ; (B) 3 ; (C) 2, 3 ; (D) 1, 4

(A) 2, 4 ; (B) 1, 2, 3, 4 ; (C) 1, 3, 4 ; (D) 3

SECTION V Subjective or Numerical Type 1. 1.86 = Kf(1) 0.02046 = (1 + ) 1.86 0.01 0.02046 1 1.1 0.0186 = 0.1 [H+] = C = 0.01 0.1 = 103 pH = 3.
x m
1 n kP

2.

log

x m

log k

Now, tan

1 log P n 1 1 n n

tan 45
log 2

n=1 Intercept = log k k 2 x 2(2) 4 . m