Syllabus For 1st Year 1st Semester CHEM-111 Physical Chemistry-I Credit: 3.0 Introduction to Physical Chemistry 01.

States of Matter: Solid , Liquid, and Gaseous State 02. Physical and Chemical Changes 03. Transition Between Different States 04. State Variables: Standard State & Reference State 05. Different Forms of Energy in Chemical Changes: Kinetic Energy & Potential Energy Translational Energy Rotational Energy Vibrational Energy Electrical Energy 06. Degrees of Freedom of Molecules 07. Equipartition of Energy 08. Quantization of Energy 09. Electromagnetic Radiation Gaseous State 01. Boyles Law, Charless Law, Avigadros Law & Combined Gas Equation 02. Ideal Gases & real Gases 03. Perfect gas Equation 04. Equation of State 05. Amagats Curves 06. Principle of Corresponding States & Critical Constants 07. Daltons Law of Partial pressure 08. Grahams Law of Diffusion 09. Kinetic Theory of Gases 10. Application of Ideal Gases 11. Root-Mean-Square Velocity 12. Joule-Thomson Effect 13. Liquefication of Gases CHEM-112 Inorganic Chemistry-I Credit: 3.0

Atomic Structure Wave Mechanical Approach of Atomic Structure General Properties and Periodicity of the Elements Introduction to Bonding Definition of Bond Types of Bond Transition Between Main Types of Bonding Ionic Bond general Properties of Ionic Bond Structure of Ionic Compounds Radius Ratio Rule Covalent Character of Ionic Bonds Covalent Bonds Octet Rule Ionic Character of Covalent Bonds Polar Nature of Covalent Bonds Metallic Bonds General Properties of Metallic Bonds

CHEM-113 CHEM-114
CHEM-121 CHEM-122 CHEM-123 CHEM-124

CHEM-211 Physical Chemistry-II Credit: 3.0 Free Energy and Equilibrium

Chemical Equilibrium Phase equilibrium Properties of Dilute Solutions CHEM-212 CHEM-213 CHEM-214 CHEM-215 CHEM-221 CHEM-222 CHEM-223 CHEM-224 CHEM-225 CHEM-226

Syllabus for 3rd Year 1st Semester

CHEM-311 Chemical Kinetics and Catalysis Credit: 3.0 Reaction Kintetics:
01. Elemetary Concepts 02. Order 03. Molecularity 04. Rate law and Rate constant 05. Integration of rate equations for model reaction system: I. Zero order rections II. First order reactions III. Second order reactions IV. Third order reactions V. Fractional order reactions 06. Parallel, Consecutive, Successive and Opposing Reactions 07. Methods for determining Order and rate constants

Reaction Rates and theories

01. Theories of reaction rates: I. The Arrhenius equation II. Simple Collision Theory III. Absolute Reaction Theory 02. Reaction in solution 03. Heterogeneous reactions 04. Unimolecular reactions I. Lindeman mechanism II. Hinshelwood Mechanism

Kinetics and Reaction Mechanism

01. Principle of Steady State Approximation 02. Iodination of Acetone 03. Decomposition of Ozone, N2O5, Acetaldehyde, Hydrogen-Chlorine/Bromine

Reaction 04. Chain Reaction

Photochemistry
01. Laws of Photochemical Reactions 02. Quantum Fields and Its Determination 03. Photochemical Reactions Such as Decomposition of HI, Combination of H2 &

I2, Photolysis of Acetone and Dimerization of Anthracene.

Catalysis
01. Characteristics of catalysis 02. Classification of Catalysis 03. Acid-Base Catalysis 04. Michael-Menten Equation 05. Hinshelwood and Rideal Mechanism 06. Enzyme Catalysis 07. Autocatalysis 08. Oscillatpry Reactions

CHEM-312 Co-Ordination Chemistry Credit: 3.0

Definition and Scope of Coordination Chemistry

01. Double Salts and Coordination Compounds 02. Ligands and Their Types 03. Coordination Number 04. Nomenclature of Coordination Compounds

Structural Theories of Complex Compounds

01. Werners Theory 02. Sidgwicks Electronic Theory 03. Electro-neutrality Principle 04. Valence Bond Theory and Its Limitations

Stereochemistry of the Coordination Compounds

01. Structural Isomerism 02. Geometrical Isomerism 03. Optical Isomerism 04. Dtermination of Configurations of Cis-Trans Isomer

05. Stereochemistry of 4-Coordinated Complex 06. Stereochemistry of 6-Coordinated Complex 07. Stereochemistry of Non-rigid and Fluxional Molecules

Stability of Complexes
01. Factors Influencing the Stability of Complexes 02. Stability Constant 03. Effect of Ligand On The Stability of Complexes.

Crystal Field Theory

01. Crystal Field Splitting 02. Crystal Field Stabilization Energy 03. High Spin and Low Spin Complexes

Non-Octahedral Symmetry
01. Tetrahedral Symmetry 02. Tetragonal Symmetry 03. Square Planer Symmetry 04. Trigonal Symmetry 05. Pairing Energies 06. Factors Influencing Ligand Field Splitting 07. Spectrochemical Series 08. Measurement of 10 Dq

Stereochemical Distortions of Complexes

01. Jahn-Teller Effects 02. Limitations of Jahn-Teller Theory 03. General Effects of Orbital Splitting On The Properties Of Complexes 04. Limitations of CFT

Molecular orbital Theory

01. Basic Principles 02. -Bonding and -Bonding In Octahedral Complexes 03. Effects of -Bonding 04. MOT In Tetrahedral nad Square Planar Complexes 05. Limitations of MOT 06. Comparison of Different Approaches to Bonding in Coordination Compounds

CHEM-313 Stereochemistry Credit: 3.0 Optical Activity and Optical Isomerism

01. Cause

of Optical Activity

Geometrical Isomerism
01. Conditions 02. Configurations of Geometrical Isomers 03. Cis-trans and E-Z System 04. Physical Properties and Configurational Assignment Isomers by Physical Chemical Methods 05. Geometrical Isomerism of Polyenes 06. Carbon-Nitrogen Double Bonds 07. N-N Double Bonds 08.

Configurations Conformations Optical Rotation and Rotatory Power

CHEM-314

Chemical Spectroscopy-I: Theory Credit: 3.0 Electromagnetic Radiation:

01. The Nature of Electromagnetic Radiation 02. Emission and Absorpsion Spectra 03. Basic Components of Dispersive Spectrometers 04. Modulation Technique 05. Transmittance and Absorbance 06. Representation of Spectra 07. Spectral Peaks Intensities 08. Width and Resolution

09. Signal to Noise Ratio 10. Averaging Fourier Transform Technique and Its Advantage

Atomic Spectroscopy: 01. Rotational Spectroscopy 01. Vibrational Spectroscopy 01. Ultraviolet and Visible Spectroscopy 01. NMR Spectroscopy
01. Nuclear Spin 02. Properties of Nuclei in a Magnetic Field 03. Larmor Frequency 04. Magnetic Resonance 05. Relaxation Process 06. NMR Spectrometer 07. Electron Density of the Nucleus 08. Chemical Shift 09. Scale 10. The Coupling of Nuclear Spin 11. Coupling Constant J 12. Application of NMR Spectroscopy
CHEM-315

Environmental Chemistry Credit: 3.0 Environmental Chemistry

01. Definition

and Scope of the Study Segments

02. Environmental

03. Pollutant 04. Types

and Contaminant

of Pollutants

Environmental Chemistry of Water

01. The

properties of Water Composition of Natural Water Cycle and Uses of Water Carbonate Equilibria(Closed System) of CO2 (Open System) Quantities of Water

02. Chemical 03. Sources

04. Hydrological 05. Dissolved 06. Dissolution

07. Conservative a. b. c.

Alkanity Acidity and CT Buffering

Water Pollution
01. General 02. Types

Causes of Water Pollution

of Water Pollutants

CHEM-316 Natural Product Chemistry Credit: 3.0 Natural Products:

01. General methods of isolation 02. Purification 03. Determination of structure of natural products by chemical and

spectroscopic methods with reference to alkaloids 04. Terpenes 05. Steroids. Alkaloids:
01. Definition

02. Classificalion 03. Test of alkaloids 04. extraction and purification of alkaloids 05. Charecterization of alkaloids by chemicals 06. Spectroscopic 07. Synthetic methods with reference to ephedrine 08. Nicotine 09. Atripine 10. Quinine 11. Papaverine

Terpenoids:
01. Terpenes and terp

Purines Organic Coloring Materials

Antibiotics
01. Chemistry of penicillin 02. Chemistry of Chloramphenicol

CHEM-317

Inorganic Preparation Laboratory Credit: 2.0

01. Preparation and Characterization of tris (thiourea) copper(I)

sulphate, [(Cu(NH2CSNH2)3]SO4.
02. CHEM-318