Safety Data Sheet

MAGNASOL 5000 G
Revision date : 12.05.2010 Version: 1.1 Page: 1/6 (30495504/SDU_GEN_CA/EN)

1. Product and Company Identification

Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) 996-6666 BASF HOTLINE: (800) 454-COPE (2673)

2. Hazards Identification
Emergency overview

Signal word: State of matter: Health:

Potential health effects

WARNING: ! liquid Corrosive to skin, eyes, respiratory system and mucous membranes., Possible reproductive effects.

Primary routes of entry: Skin, Eyes, Inhalation, Ingestion Chronic exposure: Corrosive. Can cause skin and eye burns. Inhalation of mist or vapor may cause irritation of the upper respiratory passages with coughing and discomfort. A component may cause fetotoxic and embryotoxic effects.
Potential environmental effects

Releases to the environment are to be avoided.

3. Composition/Information on Ingredients
Chemical name Aluminum chloride (AlCl3) (9CI) This product is WHMIS controlled. CAS Number 7446-70-0 Content (Weight) 30.0 - 60.0 % Hazardous Y

4. First-aid Measures
Inhalation:

Safety Data Sheet

MAGNASOL 5000 G
Revision date : 12.05.2010 Version: 1.1 Page: 2/6 (30495504/SDU_GEN_CA/EN) Remove to fresh air, if not breathing give artificial respiration. If breathing is difficult, give oxygen and get immediate medical attention. Skin: If clothing is contaminated, remove and launder before reuse. After contact with skin, wash immediately with plenty of water and soap. Seek medical attention. Eyes: Immediately flush the eye(s) with lukewarm, gently flowing water for 20-30 minutes or until the chemical is removed. Get immediate medical attention. Ingestion: Do not induce vomiting. If vomiting occurs naturally, have casualty lean forward to reduce the risk of aspiration. Seek medical attention immediately.

5. Fire-fighting Measures
Suitable extinguishing media: carbon dioxide, dry powder, foam, water spray Unsuitable Extinguishing Media: No restrictions. Hazardous combustion products: Hydrogen chloride and aluminium compounds. Hazards during fire-fighting: Standard procedure for chemical fires. Cool fire-exposed containers with water. Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing.

6. Accidental Release Measures

Cleanup: Pick up with inert absorbent material (e.g. sand, earth etc.). Place into approved waste containers. Wear suitable protective equipment. Should not be released into the environment.

7. Handling and Storage

Handling

General advice: As with all industrial chemicals, use good industrial practices when handling. Avoid eye, skin, and clothing contact. Do not inhale. Do not taste or swallow. Use only with adequate ventilation. Protection against fire and explosion: Corrosive Liquid. Use with adequate ventilation, handle with care.

Safety Data Sheet

MAGNASOL 5000 G
Revision date : 12.05.2010 Version: 1.1
Storage

Page: 3/6 (30495504/SDU_GEN_CA/EN)

General advice: Keep container tightly closed in a dry, cool and well-ventilated place. Protect from direct sunlight. > for industrial use only <

8. Exposure Controls and Personal Protection

Exposure Guidelines

Engineering Controls: Work in well ventilated areas. Do not breathe vapors or mist. Ensure adequate ventilation, especially in confined areas.
Personal protective equipment

Respiratory protection: Wear a NIOSH-certified respirator as necessary. Eye protection: Tightly fitting safety goggles (chemical goggles) and face shield. Body protection: Wear chemical resistant gloves and protective clothing. General safety and hygiene measures: Eye wash station and safety shower should be available in immediate work area. Select additional protective equipment based upon potential for exposure.

9. Physical and Chemical Properties

State of matter: pH value: Lower explosion limit: Upper explosion limit: Flash point: Freezing point: Boiling point: Relative density: Partitioning coefficient noctanol/water (log Pow): Solubility in water: Autoignition: Decomposition temperature: liquid 1.5 not determined not determined not determined 34 C 104 C 1.27 - 1.29 not determined soluble Not tested Not tested

10. Stability and Reactivity

Stability: Stable Conditions to avoid: Avoid temperature extremes.

Safety Data Sheet

MAGNASOL 5000 G
Revision date : 12.05.2010 Version: 1.1 Page: 4/6 (30495504/SDU_GEN_CA/EN) Substances to avoid: Rapidly corrodes most metals (except titanium) with the possible liberation of hydrogen gas., Avoid contact with alkaline materials and strong oxidizers. Possibility of Hazardous Reactions: No hazardous reactions known. Hazardous decomposition products: No decomposition expected under normal storage conditions.

11. Toxicological Information

Acute oral toxicity:

not determined
Acute inhalation toxicity:

not determined
Acute dermal toxicity:

not determined
Skin irritation:

Not tested The low pH would probably cause it to be considered corrosive. Information on: Aluminum chloride (AlCl3) (9CI) CAUSES SKIN IRRITATION. Causes burns to skin. ---------------------------------Information on: Aluminum chloride (AlCl3) (9CI) CAUSES SKIN IRRITATION. Causes burns to skin. ---------------------------------Eye irritation:

Product has not been tested. Information on: Aluminum chloride (AlCl3) (9CI) : Causes severe burns. ---------------------------------Information on: Aluminum chloride (AlCl3) (9CI) : Causes severe burns. ---------------------------------Carcinogenicity: None of the components in this product at concentrations greater than 0.1% are listed by IARC; NTP, OSHA or ACGIH as a carcinogen. Developmental toxicity/teratogenicity: Contains component(s) at greater than 1% which is known to cause teratogenic effects.

12. Ecological Information

Toxicity to aquatic invertebrates: Ceriodaphnia dubia/48 h/LC50: 129 mg/l (under static conditions in the presence of humic acid)

Safety Data Sheet

MAGNASOL 5000 G
Revision date : 12.05.2010 Version: 1.1 Other ecotoxicological advice: No ecological data available May be harmful to the aquatic environment. Page: 5/6 (30495504/SDU_GEN_CA/EN)

13. Disposal Considerations

Waste disposal of substance: Dispose of in accordance with national, state and local regulations.

14. Transport Information

TDG (Canada) Road transport

Proper shipping name: Hazard class: UN/ID-number: Label: Packing Group: Marine pollutant: Proper shipping name: Hazard class: UN/ID-number: Label: Packing Group: Proper shipping name: Hazard class: UN/ID-number: Label: Packing Group: Marine pollutant:

ALUMINUM CHLORIDE SOLUTION 8 UN 2581 8 III NO ALUMINIUM CHLORIDE SOLUTION 8 UN 2581 8 III ALUMINIUM CHLORIDE SOLUTION 8 UN 2581 8 III NO

International Air Transport Association (IATA)

International Maritime Dangerous Goods Code (IMDG)

15. Regulatory Information

US: Toxic Substances Control Act (TSCA): All component(s) comprising this product are either exempt or listed on the TSCA inventory All components either exempt or listed on the DSL

Canada: Domestic Substances List (DSL):

Canada Regulations

Workplace Hazardous Materials Information System (WHMIS Classification): This product is WHMIS controlled. D-2A Materials Causing Other Toxic Effects - Very toxic material E Corrosive material Significant New Activity Conditions (SNAC): This product does not contain any components subject to a SNAC Notice.
International Regulations

Chemical Weapons Convention:

Safety Data Sheet

MAGNASOL 5000 G
Revision date : 12.05.2010 Version: 1.1 Page: 6/6 (30495504/SDU_GEN_CA/EN) This product does not contain any component(s) listed under the Chemical Weapons Convention Schedule of Chemicals.

16. Other Information

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

MAGNASOL 5000 G is a registered trademark of BASF Canada or BASF SE Due to the merger of CIBA and BASF Group all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have resulted in changes of the Material Safety Data Sheets. In case you have questions concerning such changes please contact us at the address mentioned in Section I. END OF DATA SHEET