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Safety Data Sheet

ZETAG 8818 (US)


Revision date : 05.07.2010 Version: 1.2 Page: 1/6 (30485464/SDU_GEN_CA/EN)

1. Product and Company Identification


Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) 996-6666 BASF HOTLINE: (800) 454-COPE (2673)

2. Hazards Identification
Emergency overview

Signal word: Colour: Appearance: State of matter: Odour: Health:

Physical/Chemical hazards:
Potential health effects

DANGER ! cream, almost white emulsion liquid solvent-like Corrosive to eyes, Can cause skin irritation., Contains petroleum distillates and prolonged contact with mists may cause skin, eye and respiratory tract irritation. Continued overexposure may cause headache and dizziness. Ingestion may cause lung complications. Spills are very slippery.

Primary routes of entry: Skin, Eyes, Inhalation, Ingestion


Potential environmental effects

Releases to the environment are to be avoided.

3. Composition/Information on Ingredients
Chemical name Ethanaminium, N,N,N-trimethyl-2-[(1-oxo-2propenyl)oxy]-, chloride, polymer with 2propenamide (9CI) Distillates (petroleum), hydrotreated light ALCOHOLS, (C=12-14)-SECONDARY, ETHOXYLATED CAS Number 69418-26-4 Content (Weight) 30.0 - 60.0 % Hazardous Y

64742-47-8 84133-50-6

10.0 - 30.0 % 1.0 - 5.0 %

Y Y

Safety Data Sheet


ZETAG 8818 (US)
Revision date : 05.07.2010 Version: 1.2 Page: 2/6 (30485464/SDU_GEN_CA/EN)

4. First-aid Measures
Inhalation: Remove to fresh air, if not breathing give artificial respiration. If breathing is difficult, give oxygen and get immediate medical attention. Skin: After contact with skin, wash immediately with plenty of water and soap. Seek medical attention. If clothing is contaminated, remove and launder before reuse. Eyes: Immediately flush the eye(s) with lukewarm, gently flowing water for 15 minutes or until the chemical is removed. Get immediate medical attention if irritation persists. Ingestion: Do not induce vomiting. If vomiting occurs naturally, have casualty lean forward to reduce the risk of aspiration. Seek medical attention immediately.

5. Fire-fighting Measures
Suitable extinguishing media: carbon dioxide, dry powder, foam Unsuitable Extinguishing Media: If water is used, restrict pedestrian and vehicular traffic in areas where slip hazard may exist. Hazardous combustion products: Carbon and nitrogen oxides. Hazards during fire-fighting: Standard procedure for chemical fires. Cool fire-exposed containers with water. Spills can cause very slippery conditions on floors. Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing.

6. Accidental Release Measures


Cleanup: Wear suitable protective equipment. Pick up with inert absorbent material (e.g. sand, earth etc.). Scoop into marked containers for disposal as chemical waste. Should not be released into the environment.

7. Handling and Storage


Handling

General advice:

Safety Data Sheet


ZETAG 8818 (US)
Revision date : 05.07.2010 Version: 1.2 Page: 3/6 (30485464/SDU_GEN_CA/EN) As with all industrial chemicals, use good industrial practices when handling. Avoid eye, skin, and clothing contact. Do not inhale. Do not taste or swallow. Use only with adequate ventilation. Slip hazard when wet. Clean up spills promptly
Storage

General advice: Keep container tightly closed in a dry, cool and well-ventilated place. Avoid extremes of temperature. Keep from freezing. Product becomes viscous and difficult to handle when cold. Temperature tolerance: Product may freeze; however, it should recover upon warming. Should freezing occur, warm slowly. Thawed product should be thoroughly mixed with low shear agitation prior to use. > for industrial use only <

8. Exposure Controls and Personal Protection


Exposure Guidelines

Distillates (petroleum), hydrotreated light (64742-47-8)

ACGIH

200 mg/m3 TWA: 200 mg/m3 Non-aerosol (as total hydrocarbon vapor) P: Application restricted to conditions in which there are negligible aerosol exposures. SKIN_DES: Non-aerosol (as total hydrocarbon vapor) Can be absorbed through the skin

Engineering Controls: Work in well ventilated areas. Do not breathe vapors or mist.
Personal protective equipment

Respiratory protection: Use NIOSH approved respirator as needed to mitigate exposure. Eye protection: Tightly fitting safety goggles (cage goggles) (EN 166) and face shield. Body protection: Wear chemical resistant gloves and protective clothing. General safety and hygiene measures: Eye wash station and safety shower should be available in immediate work area., Select additional protective equipment based upon potential for exposure.

9. Physical and Chemical Properties


Colour: Form: State of matter: Odour: pH value: cream, almost white emulsion liquid solvent-like 3.5 - 4.5

Safety Data Sheet


ZETAG 8818 (US)
Revision date : 05.07.2010 Version: 1.2 Flammability: Lower explosion limit: Upper explosion limit: Flash point: Melting point: Freezing point: Boiling point: Vapour pressure: Relative density: Vapour density: Partitioning coefficient noctanol/water (log Pow): Viscosity, dynamic: Solubility in water: Not applicable not determined not determined (Pensky Martens closed cup) not determined not determined not determined 1.03 not determined not determined Not tested soluble Page: 4/6 (30485464/SDU_GEN_CA/EN)

> 93 C

approx. 100 C

10. Stability and Reactivity


Stability: Stable Conditions to avoid: Avoid temperature extremes, especially frost and freezing conditions. Avoid electro-static discharge. Avoid sources of ignition. Substances to avoid: Strong oxidizing agents, strong acids, strong bases. Possibility of Hazardous Reactions: No hazardous reactions known. Hazardous decomposition products: No decomposition expected under normal storage conditions.

11. Toxicological Information


Acute oral toxicity:

oral / rat: 2,000 mg/kg Analogous: Assessment derived from products with similar chemical character.
Acute inhalation toxicity:

not determined
Acute dermal toxicity:

dermal: not determined


Skin irritation:

Component(s) in greater than 1 percent concentration is known to be an irritant.


Eye irritation:

Corrosive.

Skin Sensitization:

not determined Carcinogenicity: None of the components in this product at concentrations greater than 0.1% are listed by IARC; NTP, OSHA or ACGIH as a carcinogen. Reproductive toxicity: No data for product.

Safety Data Sheet


ZETAG 8818 (US)
Revision date : 05.07.2010 Version: 1.2 Developmental toxicity/teratogenicity: No data for product. Page: 5/6 (30485464/SDU_GEN_CA/EN)

12. Ecological Information


Toxicity to fish: Oncorhynchus mykiss/96 h/LC50: 18 mg/l (under static conditions in the presence of humic acid) Oncorhynchus mykiss/96 h/NOEC (No observed effect concentration): 13 mg/l (under static conditions in the presence of humic acid) Toxicity to aquatic invertebrates: Ceriodaphnia dubia/48 h/EC50: < 3.1 mg/l (under static conditions in the presence of humic acid) Americamysis bahia/96 h/LC50: 5.8 mg/l (under static conditions) Toxicity to aquatic plants: not determined Other ecotoxicological advice: This product contains polymer(s) that may be toxic to aquatic organisms when tested in pure (distilled) water. Toxicity is greatly reduced byparticles in natural water.

13. Disposal Considerations


Waste disposal of substance: Dispose of in accordance with national, state and local regulations.

14. Transport Information


TDG (Canada) Road transport

Special shipping information: Special shipping information: Special shipping information:

Not classified as a dangerous good under transport regulations. Not classified as a dangerous good under transport regulations. Not classified as a dangerous good under transport regulations.

International Air Transport Association (IATA)

International Maritime Dangerous Goods Code (IMDG)

15. Regulatory Information


Canada: Domestic Substances List (DSL): US: Toxic Substances Control Act (TSCA): All components either exempt or listed on the DSL All component(s) comprising this product are either exempt or listed on the TSCA inventory

Canada Regulations

Workplace Hazardous Materials Information System (WHMIS Classification): D-2B Materials Causing Other Toxic Effects - Toxic material

Safety Data Sheet


ZETAG 8818 (US)
Revision date : 05.07.2010 Version: 1.2 This product is WHMIS controlled. Significant New Activity Conditions (SNAC): This product does not contain any components subject to a SNAC Notice.
International Regulations

Page: 6/6 (30485464/SDU_GEN_CA/EN)

Chemical Weapons Convention: This product does not contain any component(s) listed under the Chemical Weapons Convention Schedule of Chemicals.

16. Other Information


This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

ZETAG 8818 (US) is a registered trademark of BASF Canada or BASF SE Due to the merger of CIBA and BASF Group all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have resulted in changes of the Material Safety Data Sheets. In case you have questions concerning such changes please contact us at the address mentioned in Section I. END OF DATA SHEET