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A case study
Dr. R.K.Malhotra Indian Oil Corporation Limited, R&D Centre, Sector -13, Faridabad, Haryana, India
Contents
Indias energy requirements Hydrogen in Indian Context HCNG initiatives in India Emerging Fuel Cell Industry Fuel Cell as back-up power source Recent Developments Challenges & Opportunities
in the refineries through reforming of natural gas and naphtha, for captive utilization and fertilizer industry are also producing hydrogen
Chlor-alkali
Future Developments
Electrolysis using Solar / Wind energy Solar Water splitting thermal & biological routes Bio-mass / Coal Gasification route Plasma gasification of Municipal waste
NOx emissions using HCNG - ? CNG blended with hydrogen up to 20% (v/v) declared as an Automotive
fuel by Govt. of India and to follow all safety and emission norms applicable to CNG
gain experience on Production, Transportation, Storage, Distribution and Application of hydrogen as a Transport fuel Lower HCNG blends are cost competitive as compared to hydrogen
Infrastructure Development hydrogen and HCNG dispensing stations R&D programs initiated on use of HCNG blends along with MNRE, MoP&NG and Indian Automobile manufacturers
Testing of un-modified vehicles on different blends of HCNG Vehicle development and evaluation in collaboration with OEMs Field trials on modified vehicles for durability studies Natural gas reforming Coal / Bio-mass gasification Photo-catalysis of Water Solar hydrogen
Series of workshops on hydrogen safety, development of codes and standards organized by IOC R&D Centre includingWHTC 2009
Centre, Faridabad in Oct, 2005 H2/HCNG dispensing station set-up at a retail outlet I New Delhi for demonstration vehicles
Faridabad Station
Dwarka Station
Hydrogen production Electrolyser (5 Nm3/hr) Hydrogen Dispensing - 350 bar HCNG Dispensing - 250 bar
ZnO Bed
Reformer
Compressor
Technology based on compact steam methane reforming Patent filed Flexibility to produce 15-30% (v/v) hydrogen in HCNG Demo unit set up at IOC-R&D and integrated with HCNG dispenser for direct
dispensing
Process designed for quick start / stop
Suitable for retail filling stations with varying demand
Leading Automotive manufacturers are gearing to launch demo fuel cell operated / FC hybrid vehicles in India Tata Motors has launched programmes to develop fuel cell buses Global Auto majors are coming up with their R&D centers in India Fuel cell manufacturers are launching demonstration projects for providing back-up power to tele-towers De-centralized power generation is the key emerging market Many organizations / academic institutes are working in hydrogen storage field Manufacturers, Distributors, material suppliers and integrators include the leading global players
on March,12
3rd largest internet users : 121 million as on December,11
month
Availability
>20 hrs
Tower share
10%
Description
Mainly metro cities of Delhi, Mumbai, Kolkata, Chennai, Chandigarh, some cities of Gujarat & Punjab covers most other major cities and towns in the rest of the country All semi-urban and small urban towns in all state
B C
16 20 hrs 12 16 hrs
20% 30%
D
E F
8 to 12 hrs
<8 hrs off grid
15%
25%
Diesel Gensets are the prime option to supply power to telecom towers in case of Grid unavailability
About 50 Pilot projects on use of Fuel cells already launched by different fuel cell manufacturers in association with gas suppliers Govt. of India is giving subsidies to power back-up solutions based on alternative energy
Demo systems have been operational in India over significant periods of time ensuring 99.99% site availability
Battery size with fuel cell may reduce due to lower starting time as compared to DG-set Multiple towers can be monitored from the one central location
H2 Supply
1) Mobile Re- Fueller 2) Cylinders
200 bar
6 bar
H2 Cylinders
Electric Power
87,500
New Sites
50,000 new sites per year
35,000
Quantity of hydrogen requirement for providing back up power to 1,00,000 towers with grid failure of 8 hrs/day will be ~300 tonnes/day
Hydrogen Supply-Chain
From Source to End-point
Production
Purification
Compression
Delivery at site
Long Supply-chain significantly increases the total delivered cost of hydrogen at site.
Chlor-alkali Plant
Total hydrogen produced in Chlor-alkali plants is 0.073 MMTPA Excess hydrogen available is ~ 0.009 MMT due to captive consumption Hydrogen Purity available 97-98% Current Capacities would not be able to support future
BGR Total
31745 757622
Site 1
H
2
H
2
Site 2
Site 3
Site 100
To initiate, existing hydrogen production facilities like chlor-alkali, refineries etc. may be utilized As the market grows, infrastructure development can be take up depending upon the availability of production and demand centres Use compressed hydrogen @200 bar in cylinders of suitable capacity to deliver hydrogen to sites The requirement of other demand zones can also be explored
Challenges
Marketing challenges
Cost of the fuel cell Performance of the integrated system under Indian conditions Government plans on supporting the Green initiatives Hydrogen storage technology, Fuel Cell system, Hydrogen and battery energy storage improvements and advanced control systems Major investment required in Hydrogen production Infrastructure expansion: purification, compression and bottling Highway safety Fuel safety (new standards for H2) New local safety and zoning requirements for fueling locations To transport hydrogen at pressures > 200bar To permit more storage capacity per site Mobile refueller
Technological challenges
Fuel Producer
Safety management
Opportunities
HCNG experience gained on vehicles will offer opportunities for Automotive fuel cell applications Indian has an opportunity to implement hydrogen based teletowers due to non-availability of continuous power supply Till renewable H2 sources are developed, hydrogen can be sourced from refineries for fuel cell applications Being an agro based country, India has large potential for biomass gasification to produce hydrogen for different applications There is a potential to produce hydrogen through other routes like solar, wind, MSW gasification etc. The experience so gained can be utilized to develop best safety practices for handling hydrogen