Concept Recap Test Mains 2 Sol

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ANSWERS, HINTS & SOLUTIONS
CRT (Set-II)

ANSWERS KEY
PHYSICS CHEMISTRY MATHEMATICS
Q. No. ANSWER ANSWER ANSWER
1. C B B
2. C C A
3. B B C
4. D A C
5. B D C
6. D C C
7. A B C
8. A C A
9. C C A
10. A D D
11. A D C
12. C D B
13. D B C
14. B C C
15. A C B
16. D B B
17. D C A
18. C D C
19. A B B
20. D C A
21. B D A
22. C A D
23. A C C
24. C A C
25. B A C
26. C C C
27. D B C
28. B A A
29. D C D
30. B A C
A
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L

I
N
D
I
A

T
E
S
T

S
E
R
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AITS-CRT(Set-II)-PCM(S)-JEE(Main)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
2
P Ph hy ys si ic cs s PART I

SECTION A

1.
p
av
2V
200 2
V

= =

3.
2
1
U CV
2
= =
( )
2
2 2
1
C 2IR 2I R C
2
=

4.
dV
E a
dr
= = ; So flux 4R
2
a
Now
in
0
q
= 4R
2
a q
in
= 4R
2
0
a

5.
2
K
M
L
=
l
where K is some constant

6.
2

8.
2
P V constant =

2 1
T V
= constant (by the ideal gas equation)

2
T KV =

2
0 0
T KV = ..(A)

2
1 0
T K3V = ..(B)
By (A) and(B) we get

1 0
T 3T =

9. Using equation of Trajectory, we get
u = 15 2 m/ s

10.
R
mv
N
2
= ..(A)
mg f
max
=

mg N =

mg
R
mv
2
=

f
max
mg
R
m/s 10
2 . 0
10 2 Rg
v =
=

11. Torque will be in clockwise sense.

12. B is independent of x for large number of wires.

AITS-CRT(Set-II)-PCM(S)-JEE (Main)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 16, Ph: 46106000, 26515949, Fax: 26513942.
3
13.
hc
eV
= of V increases decreases

14.
4
nsin sin90
3

( )
4
nsin 90 sin90
3

squaring and adding

4
n 2
3

90

15. T YA t 5000N = =

16. The net horizontal force on the block should overcome friction.

17. For all figure

m
T 2
K
=

19. Extension due to its own weight

2
WL
AY

extension in second rod is
WL
AY

20. Escape velocity is independent of direction.

21. Because in downward journey F and mg Both will act downward, while in upward journey only mg
will act downward.

24. It looks like a dipole.

25. Let B
1
and B
2
be the magnetic fields due to two coils with currents i and 3i respectively. We
have

0 0
1
ni 2 ni
B .
4 r 2r

= =

and
0 0
2
3 ni 2 n 3i
B .
4 r 2r

= =

the magnetic fields will be perpendicular to each other.

2 2
1 2
B (B B ) = +
0
ni
r
= .

26. 12 C
6
14 C
6
Isotopes
extra neutron = 2, no extra electron

28.
14 4 17 1
7 2 8 1
N He O H + +

30. The frequency of sound from the image is Doppler shifted due to its own motion and the motion of
the observer itself.

4
C Ch he em mi is st tr ry y PART II

SECTION A
1. Molar mass of X
4
= 4 25 = 100 g
Suppose 51 g of saturated solution contains x
gm
of X.
Weight of benzene in this solution = 51 x g
Total weight of resulting solution = 50 + 51 x = (101 x) g

( )
f
f
1000 K W 1000 5.5 x
T
m.W 100 101 x

= =

or 0.55 =
55x
101 x
x = 1.0 g
Hence, solubility of x per kg =
1 1000
20g
50
=

2.
5 3
Left
H 1.0 10 0.1 1.0 10 M
+
(
= =

7 4
Right
OH 4 10 0.1 2 10 M

(
= =

14
11 w
4
Right
K 10
H 5 10
2 10 OH
+

(
= = =

(

As per representation of cell

11
Right
Cell
3
Left
H
5 10
E 0.05916log 0.05916log
1.0 10 H
+
+
(

= =
(

= 0.432 V
Infact, the right hand half cell will act as anode having negative polarity. The representation of the
cell is incorrect.

3.
| |
a
H CN
HCN H CN K
HCN
+
+
( (

+ =

At 20% neutralization
CN
20 1
HCN 100 20 4
(

= =

Hence H
+
(

= 4 K
a
= 4 4 10
10
= 16 10
-10

pH = - log16 10
-10
= 8.80
At equivalence point | |
0.2
NaCN CN 0.1M
2
(
= = =

2
CN H O HCN OH

+ +

| |
a
1
pH 7 PK logC
2
= + +

10
1
7 log4 10 log0.1
2

(
= + +

= 11.2

4. Langmuirs adsorption isotherm is

1 2
1
k k p
x / m
1 k p
=
+

5
On rearrangement,
1 2 2
p 1 1
.p
x / m k k k
= +
Plot of
p
x / m
against p is a straight line.

5. [Ni(CN)
4
]
2
has dsp
2
hybridisation with no unpaired electrn, magnetic moment being zero.

6. The T
2g
orbital (d
xy
.d
yz
and d
xz
) are stabilised because they point in between the axes.

7.
2 2
2
a x x
v v
Hg Hg Hg
+ +

| |
( ) ( )
2
2
2
Hg
x / v x
K
a x / v a x
Hg Hg
+
+
(

= = =
(

10.
O
HO
O
O H

O
O

C H
3
C CH
2
CH
2
C CH CH
3
O O
5 4
3
2
1
O
O
O
OH
O

11.
C H
3
C CH CH
2
CH
3
CH
3
(A)

C H
3
CH CH
CH
2
CH
3
BH
CH
3
2
(B)

C H
3
CH CH CH
2
CH
3
CH
3
OH
(C)

12. It is an SN1 reaction, involvement of a carbocationic intermediate and subsequent molecular
rearrangement as shown below

C H
3
H
Br
H Br
+
C H
3
H
H
H
H
CH
3
3
CH O H
C H
3
O
H
CH
3
C H
3
O CH
3
Br

13. Consider hyperconjugation and resonance of C=C

14. X CH
3
CH
2
CN
Y CH
3
CH
2
CH
2
NH
2

6

Z CH
3
CH
2
CH
2
NH C
O
CH
3

15. MgCl
3
(i)
(ii) H O
+
H C H
O
CH
2
OH

16.
Cs
Cs Cl
Cl
r
0.9 r 0.90 r
r
+
+
= =
= 0.90 1.80 = 1.62 A
For precise fitting of the cubic voids,
cs Cl
r / r
+
must be 0.732 which is smaller than the given value
of 0.90. Hence cubic packing of Cl
ions is loose to some extent i.e. two Cl
ions are not in touch

with each other and distance between them is greater than 3.60 A. The Cs
+
ion at the centre of
cube is in touch with 2Cl
ions at the opposite corners of the cube. Hence, distance between Cs

+

and Cl
ions =
0
Cs Cl
r r 1.62 1.80 3.42A
+
+ = + =

19. Normality of diluted solution =
0.02 5 40
0.2
20

=
Normality of original sample = 0.2 10 = 2
Vol. strength = 5.6 2 = 11.2

20. ( )
4 2 2 2 4 2
Dark violet Colourless
2CuSO (aq) 4KI(aq) Cu I s 2K SO I + + +

( ) ( ) ( )
( )
2 3
Dark Brown
I s I aq I aq

+

22. A more stable CO
2
has more negative enthalphy of formation than CS
2

25. EAN = 36 = 2 x + 24

26. Mass of methanol in 1 mole of solution = 0.5 molar mass of CH
3
OH
= 0.5 32 = 16 gm
Mass of water in solution = 0.5 8 = 9 g
% by mass of methanol =
( )
16
100 64 g
16 9
=
+

27. On reversing (I) and (II) and then adding we get (III)
Hence,
3
1 2
1
K
K K
= or K
1
K
2
K
3
= 1

28. We have C
0
= C
1
+ C
2
+ C
3

The rate of disappearance of A is
1
1 1
dC
K C
dt
= (1)
Rearranging and integrating the above equation
1
K t
1 0
C C e
=
Since rate of formation of B is given by K
1
C
1
and the rate of decomposition of B into C is given by
K
2
C
2,
the rate at which B accumulates in the system is given by

2
1 1 2 2
dC
K C K C
dt
=
or
2
2 2 1 1
dC
K C K C
dt
+ =
7
Putting values of C
1
from equation (1)

1
K t 2
2 2 1 0
dC
K C K C e
dt

+ =
Multiplying both sides by
2
K t
e , we get

( )
2 1 2 2
K K t K t K t 2
2 2 1 0
dE
e . e .K C K C e
dt

+ =
On integration under the condition t = 0 at C
2
= 0

1 2
K t K t 1 0
2
2 1
K C
C e e
K K

( =

M Ma at th he em ma at ti ic cs s PART III

SECTION A
1. S = 2
2
+ 4
2
+ 6
2
+ .. + (100)
2
+ 50 2(2 + 4 + 6 + .. + 100)
2
2
+ 4
2
+ 6
2
+ .. + (100)
2
= S + 5050

2.
( )
( )
1 2
xy and a x b y = =
= xy {ay + bx ab} = xy

1
:
2
= 1 : 1
y
(0, b)
(0, y)
0
(x, b) (a, b)
(x, y)
2
(a, y)
(0, 0) (x, 0) (a, 0)

3.
( )
cos70 4cos70 sin70 cos 60 40
3 3
sin70 cos20
+
= =

4. The unit digit is in
2 4 2012
9 (10) 9 (10) ..... 9 (10) 4(671)(2014)(4027) 2 + + + + =

5. a = 0 and y = bx
2
+ cx + d is symmetric about
c
x
2b
=
x = k =
c
2b

c
k 0
2b
+ =
c
a k 0
2b
+ + =

6. x R then k
( )
( ) ( )
2
2 2 2
a b c a b c 2
3 ab bc ca 3 ab bc ca 3
+ + + +
= +
+ + + +

( )
2 2 2
a b c 2 ab bc ca + + < + +

( )
2 2 2
a b c
3 ab bc ca
+ +
+ +
<
2
3

4
k
3
<

7.
n
2
r
n
r 1
x x
lim 1 tan
tanx
2
=
| |
=
|
\ .

Now
x
F(x)
tanx
=
2
2
tanx xsec x
F'(x)
tan x
=

2
g'(x) 2xsec x tanx 0 = < if g(x) = tan x x sec
2
x
8
g(x) < g(0) as x > 0
( )
F' x 0 <
x
1
4 tanx
< < as x 0
+

/ 4
2
0
x
dx
16 tanx 4

< <

8. Let sin x = s and cos x = c then
then (1 + 2sc)(sc + 1)
2
= (7sc 1)
2

A
2
44A + 36 = 0 as A = 2sc
A = 22 8 7

9. L
1
+ L
2
= 0
(1 + 7)x + y( 2) (5 + 50) = 0

OD
cos60
10
= (5 1)(5 + 2) = 0

1 2
and
5 5
= =
O(0,0)
10 10
60 60
A B D
L
1
+ L
2
= 0
4x 3y 25 = 0 and 3x + 4y 25 = 0
a
1
a
2
+ c
1
c
2
= 1274

10.
( )
1/ 3
x / 2
cosx
lim
1 sinx

=
( )
1/ 3
h 0
sin h
lim 0
1 cosh
or
( )
1/ 2
h 0
sin h
lim 0
1 cosh

11. 9.10.10.5 {9.8.7.1 + 8.8.8.4}

12. f(x) = 6x
2
+ 6 > 0, x R

13.
8
5
9 C 504 =

14.
( )
1 1
tan x 2 cot x 1 0
2

| |
>
|
\ .

( )( )
1 1
tan x 1 tan x 2 0

+ <
1 < tan
1
x < 2
tan1 < x < tan2
15. ( ) ( ) ( ) 3 6 5 2 5 4 3 2 3 2 + + + + = 2004
th

16. 3 + 3 + 3

17. The conic is either ellipse or hyperbola, so
|SP SP| = 2a, SS = 2ae
|SP + SP| = 2a, SS = 2ae
18. Total number =
n n n 2 n n 4
2 4
3 C 3 C 3 ..........

+ + +
=
( ) ( )
( )
n n
2n 1 n 1 n 1 n
3 1 3 1
2 2 2 2 1
2

+ +
= + = +

19.
| | | |
2
a b c 2 a b c =

9
20.
9 1
P(A)
216 24
= =

21.
( )
2
cosx
p
cosx sinx
=
Domain x R
{ }
x | x n , n I
4
= +
So at x
4
+
, p is and p as x
5
4

22. x = z 2, y = 8 2z,
2(z 2) + 5(8 2z) + pz = q
z = (q 36)/(p 8)
For infinite solution p = 8 and q = 36

23.
( )
( )
c a b
DE AC c a
2
+
=

=
1 1 1 1 1
1 1
2 2 2 2 2
(
+ +
(

=
1
2

A
( a
)
D
B ( b
)
C
( c
)
E
O ( o
)

24. Clearly, (x, x) R x W,
So, R is reflexive.
Let (x, y) R the (y, x) R and x and y have atleast one letter in common. So R is also
symmetric.
But R is not transitive.

25. Required area = 4 = 3

S
1

S
2
(0, 0)

26. f(x) = k ln (sin x) and k = 2
27.
{ } ( )
( )
sinx 0 x 1
f(x) sin x
sin x 1 1 x
2
< <
= =

Range = [0, sin 1[ ]0, cos 1[

28. a + b = 0
lines are perpendicular
Equation of the angle bisector of the given lines does not satisfy x = 2y
the triangle is not isosceles.
29. ( )
2 2 2
1 1 1 1 1 1
z ax by 2cx y 2bx 2ay c + + + + + ; where
1 1
x y
x , y
z z
= =
it will be factorised in two linear factors if
a c b
c b a 0
b a c
=
3 3 3
a b c 3abc + + =

30.
2
1
y 2 t t
2 t
| | | |
= | |
\ . \ .
where
2 2
t x x = + +
( ) ( )
2
2 2 2 2
y 2 t t t = + = +

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= constant (by the ideal gas equation)

ions is loose to some extent i.e. two Cl

ions are not in touch

ions at the opposite corners of the cube. Hence, distance between Cs

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