Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
ranitic pegmatites have been a focal point of research by petrologists and mineralogists for over a century. Mineralogical interest stems from the diversity of rare minerals that some pegmatites contain. Petrologic efforts are aimed at resolving the processes or agents that produce the complex textures and spatial heterogeneity that distinguish pegmatites from granites. Much of the scientific study of pegmatites has been motivated by exploration for the economic commodities they provide. Pegmatites yield quartz, feldspars, and micas for industrial uses; strategic rare metals for electronic, aerospace, and energy applications; and many of the worlds finest gem and mineral specimens.
Pink pezzottaite crystal, 1.2 cm long, from Ambatovita, Fianarantsoa Province, Madagascar. The rim of the crystal is white beryl with minor microcrystals of milarite and bavenite. Named in honor of Federico Pezzotta. Photo Matteo Chinellato
synonymous with a granitic composition. The bulk compositions of pegmatites plot close to the thermal-minimum composiKeywords : pegmatite, granite, rare metals, industrial minerals, gemstones tion in the granite system, which includes rocks with nearly equal INTRODUCTION proportions of quartz, sodic plagioclase, and potassic Pegmatites are texturally distinct variants of the more (alkali) feldspar. Only a small proportion of pegmatites common and more voluminous plutonic igneous rocks, (<1%) possess assemblages that contain uncommon including gabbros, granites, syenites, etc. Whereas common minerals, e.g. those with essential lithium, beryllium, plutonic bodies tend to be mineralogically and texturally cesium, boron, phosphorus, and tantalum. These exotic homogeneous throughout large volumes of rock, pegma- rocks are termed rare-element pegmatites (not to be tites are precisely the opposite. Most pegmatite bodies are confused with rare earth element pegmatites, which are a small, with dimensions on the scale of meters rather than subset of rare-element pegmatites). Gem-quality crystals kilometers, and display internally complex fabrics. They for the jewelry industry are found in a small number of occur as segregations within granites ( Fig. 1a) and as these already sparse rare-element pegmatites. Most gemsharply discordant dikes intruding igneous and metamor- bearing pegmatites are classified as miarolitic, which refers phic rocks ( Fig. 1b). Exceedingly coarse crystal size is a to the presence of clay-filled or open, crystal-lined hallmark of pegmatites for most geoscientists (Fig. 2 ), but cavities. gigantic crystal size is not the sole or even a necessary defining factor. Other fabrics that qualify as pegmatitic THE PEGMATITE PUZZLE include systematic coarsening in crystal size from the margins to the centers of bodies ( Fig. 3); sharp mineral- Pegmatites have long been viewed as essentially igneous rocks because of their bulk compositions. The origin of ogical zonation from margin to center ( Fig. 4); anisotropic pegmatitic rock fabrics, however, has intrigued and baffled fabrics, including layering or highly oriented crystalpetrologists. By the end of the 19th century, virtually every growth directions; and graphic (skeletal) intergrowths of quartz and feldspar, termed graphic granite ( Fig. 5). conceivable process had been proffered to explain the complex textures and the assemblages of uncommon Pegmatites and hydrothermal vein deposits share all of these textural attributes but one: that of graphic granite, minerals found in some pegmatites. Because pegmatites and hydrothermal veins share common textural features, which is not only unique to pegmatites but was the texture many petrologists have called upon an aqueous fluid, alone for which the term pegmatite (from phgnumi, to make stout or acting in concert with a coexisting silicate melt, to by binding together) was coined. generate the complexities of grain size and mineral zonaPegmatitic textures can be found in igneous rocks of all tion that are diagnostic of pegmatites. compositions. However, pegmatitic textures are so prevaTwo concepts of pegmatite formation have dominated lent in granitic compositions that the term pegmatite implies a granitic composition to many geoscientists. For scientific thought for a century. A model now associated with Cameron et al. (1949) attributed the chemical evoluthe sake of brevity, most of the authors of the articles in tion of pegmatites (among and within individual bodies) this issue use the term pegmatite, without a modifier, as to the fractional crystallization of melt inward from the margins of bodies. Through this process, rare elements (e.g. 1 ConocoPhillips School of Geology and Geophysics Li, Be, and Ta), fluxes (e.g. B, P, and F), and other volatile UniversityofOklahoma, Norman, OK 73019, USA components (e.g. H 2O and Cl) that are excluded by the E-mail: dlondon@ou.edu initial crystallization of quartz and feldspars become 2 Department of Earth Sciences, Laurentian University concentrated inward into a diminishing fraction of residual Sudbury, ONP3E 2C6, Canada
E-mail: dkontak@laurentian.ca
E lements , V ol . 8,
pp.
257261
257
A ugus t 2012
pegmatite
granite
(A) A pegmatitic segregation within granite, Middletown, Connecticut (USA). The scale measures 9 cm. The yellow dashed line indicates the margins of the pegmatite. ( B ) Geologists ponder a set of parallel pegmatite dikes that cut amphibolite and gneiss, Haddam, Connecticut (USA).
FIGURE 1
melt; eventually, this melt becomes saturated in minerals containing these exotic components. In the model identied with Jahns and Burnham (1969), the silicate melt was the source of constituents, and the de ning textures and mineralogical zonation of pegmatites were ascribed to crystallization from an aqueous uid that scoured certain elements from the melt and redistributed them to growing crystals in all parts of the pegmatite body. Since these models were introduced, our knowledge of the bulk compositions, depths, and cooling histories of pegmatites has improved. The more we have learned, the more problematic some aspects of pegmatite geology (and prior conceptual models) have become. For example, pegmatite compositions lie close to the bulk composition of the minimum-temperature melt in the hydrous granite system (NaAlSi3O8 KAlSi3O8 SiO2 H 2O). Even the most chemically evolved pegmatites contain only a few weight percent of viscosity-reducing components like H 2O, B, P, and F. Most pegmatites form thin dikes injected into cooler, brittle host rocks (FIGS. 1B, 4). Evidence from mineral compositions and thermal models indicates that crystallization within pegmatites commences at ~450 C, which is ~200250 C below the liquidus temperature at which crystallization should commence. The viscosity of hydrous granitic liquid at this temperature is ~10 8 Pas, similar to the viscosity of asphaltic pitch at 25 C. Such high viscosity severely impedes the diffusion of components through a melt and commensurately diminishes the transfer of nutrient components to growing crystal surfaces. In their review of the principal models for the internal evolution of pegmatites, London and Morgan (2012 this issue) call attention to graphic granite, the de ning texture that is unique to pegmatites. From what we understand about the origin of graphic granite (Fenn 1986), this texture represents prima facie evidence of the conditions of pronounced undercooling below the liquidus temperature and high supersaturation of very viscous melt in quartz- and feldspar-forming components. E LEMENTS
Yet somehow, within this state of high viscosity and rapidly dwindling thermal energy, giant crystals manage to grow. The uxing components cited above are regarded as essential to the crystallization of gigantic crystals of silicates in pegmatites. Hence, one conundrum in the puzzle of pegmatites is this: how can the need for high concentrations of uxing components be reconciled with their manifestly low abundance in all but a very few pegmatites? London and Morgan (2012) address this problem and, in so doing, reconcile the disparities between the models of Cameron et al. (1949) and Jahns and Burnham (1969).
258
Spodumene average
Perthite average
0.5
0 wall 20 40 60 80 center
FIGURE 3
A gigantic skeletal crystal of tourmaline radiating into a pegmatite from the upper contact, from the gua Santa pegmatite, Coronel Murta, Jequitinhonha valley, Minas Gerais, Brazil (Robert F. Martin for scale). PHOTO : M ILAN NOVAK
FIGURE 2
beryllium, lithium, cesium, rare earths, and other normally rare elements are mined from pegmatites for applications in electronics, nuclear energy, aerospace, deep drilling, and other specialized industries.
nate. These signicant rare-element ores precipitate from a silicate liquid, and hydrothermal processes exert only a minor role in the internal redistribution of the ore-forming elements. As chemically evolved as these ore-producing pegmatites are, their concentrations of most rare metals are not sufcient to reach saturation of the melt at the temperature of the liquidus (the silicate liquidcrystal eld boundary at equilibrium). Linnen et al. (2012), therefore, account for the primary deposition of rare-element ores mostly by the crystallization of melt at temperatures well below the liquidus. Pegmatite-forming melts contain sufcient concentrations of rare elements to achieve saturation in rare-element minerals (such as beryl, tantalite, pollucite, etc.) at temperatures that are mostly 100200 C below the liquidus temperature.
E LEMENTS
259
border zone
3 cm
(LCT) as a diagnostic signature, and pegmatites that carry niobium, yttrium, and uorine (NYF) as a trace element signature. Pegmatites of the LCT family are strongly correlated with S-type granites, whose ultimate protoliths can be traced to chemically mature sedimentary sources, such as marine shales. Pegmatites of the NYF family are associated with A-type granites that form within intracontinental rifts. The origins of A-type granites are more complex than the origins of S-type granites and involve varying degrees of crustal or mantle input. Pegmatites are notably sparse among the subduction-related I-type granites, except where such plutons have inherited a small component of sedi ern et al. (2012) propose that the mentary material. C associations between specic granite types and their tendency to form pegmatites hinge upon the availability of uxing components, such as B, P, and F, in the source regions of those granites.
layered aplite
garnet
Textural and zonal attributes of pegmatites. The image shows a complete section of a pegmatite dike, about 28 cm thick, located near Palomar Mountain, San Diego County, California (USA).
FIGURE 4
minerals and an abundance of hydrous minerals, including clays and zeolites, in association with gem-quality minerals signify that aqueous uid plays a major role in the nal stages of consolidation of these very rare pegmatite bodies. Simmons et al. (2012) ascribe miarolitic cavities to the exsolution of aqueous uid from the pegmatite-forming melt and to the transfer of melt-derived components via aqueous uid to the surfaces of growing crystals.
FIGURE 5
Graphic granite: quartz (gray) in microcline (white), Colorado (USA). This texture is unique to pegmatites.
260
A UGUS T 2012
The systematic fractionation of isotopes (18O/16O, D/H) provides a means to assess equilibrium and, hence, temperatures of crystallization (Walker et al. 1986). However, many studies indicate widespread ingress of externally derived aqueous uids, which results in resetting or disequilibrium among the mineral reservoirs of stable isotopes, especially where pegmatites occur within large granite plutons (Carruzzo et al. 2004). The application of high-resolution analytical techniques provides a means to explore equilibrium in these systems and investigate the role of undercooling in pegmatites. Relatively new studies of 11B/10B and 7 Li/ 6Li by in situ methods are beginning to document the differential fractionation of these isotopes among mineral phases, melt, and uids due to environmentally induced changes in the coordination number of each element ( IIIB versus IV B, and IV Li versus VI Li) (Marschall and Jiang 2011). Thus, these isotopes provide a means to detect the presence of a uid phase and to test when uids appear in the evolution of pegmatite systems. For example, Trumbull et al. (2008) used boron isotopes to show that a hydrothermal uid played a role during the growth of tourmaline in a latestage quartztourmaline intergrowth (i.e. orbicule) in a granite from Namibia.
Spodumene (var. purple kunzite), beryl (var. pink morganite), quartz, albite, and lepidolite from Kunar Valley, Nuristan Province, Afghanistan (26 17 13 cm). This is a common late-stage assemblage in lithium-rich pegmatites, but it is rarely so beautifully crystallized in a miarolitic cavity. See Fig. 3 of Linnen et al. (2012) for the petrologic signicance of the assemblage spodumene + quartz. PHOTO: JOE BUDD, COURTESY OF THE ARKENSTONE
FIGURE 6
REFERENCES
Anderson MO, Lentz D, Falck H (2011) Petrology and chemistry of the Moose II lithium-tantalum pegmatite deposit, NWT. Geological Association of Canada-Mineralogical Association of Canada Annual Meeting, Ottawa, Program with Abstracts Cameron EN, Jahns RH, McNair AH, Page LR (1949) Internal Structure of Granitic Pegmatites. Economic Geology Monograph 2, 115 pp Carruzzo S, Kontak DJ, Clarke DB, Kyser TK (2004) An integrated uidmineral stable isotope study of the granitehosted mineral deposits of the New Ross area, South Mountain Batholith, Nova Scotia, Canada: Evidence for multiple reservoirs. Canadian Mineralogist 42: 1425-1441 Cern P, London D, Novak M (2012) Granitic pegmatites as reections of their sources. Elements 8: 289-294 Fenn PM (1986) On the origin of graphic granite. American Mineralogist 71: 325-330 Glover AS, Rogers WZ, Barton JE (2012) Granitic pegmatites: Storehouses of industrial minerals. Elements 8: 269-273
Jahns RH (1953) The genesis of pegmatites. I. Occurrence and origin of giant crystals. American Mineralogist 38: 563-598 Jahns RH, Burnham CW (1969) Experimental studies of pegmatite genesis: I. A model for the derivation and crystallization of granitic pegmatites. Economic Geology 64: 843-864 Kontak DJ, Creaser R, Heaman L, Archibald DA (2005) U-Pb tantalite, Re-Os molybdenite, and 40Ar/39Ar muscovite dating of the Brazil Lake pegmatite, Nova Scotia: A possible shear-zone related origin for an LCT-type pegmatite. Atlantic Geology 41: 17-30 Linnen RL, Van Lichtervelde M, Cern P (2012) Granitic pegmatites as sources of strategic metals. Elements 8: 275-280 London D, Morgan G VI (2012) The pegmatite puzzle. Elements 8: 263-268 Longstaffe FJ, Cern P, Muehlenbachs, K (1981) Oxygen isotope geochemistry of the granitoid rocks in the Winnipeg River pegmatite district, southeastern Manitoba. Canadian Mineralogist 19: 195-204
Marschall HR, Jiang S-Y (2011) Tourmaline isotopes: No element left behind. Elements 7: 313-319 Simmons WB, Pezzotta F, Shigley JE, Beurlen H (2012) Granitic pegmatites as sources of colored gemstones. Elements 8: 281-287 Tomascak PB, Krogstad EJ, Walker RJ (1998) Sm-Nd isotope systematics and the derivation of granitic pegmatites in southwestern Maine. Canadian Mineralogist 36: 327-337 Trumbull RB, Krienitz M-S, Gottesmann B, Wiedenbeck M (2008) Chemical and boron-isotope variations in tourmalines from an S-type granite and its source rocks: the Erongo granite and tourmalinites in the Damara Belt, Namibia. Contributions to Mineralogy and Petrology 155: 1-18 Walker RJ, Hanson GN, Papike JJ, ONeil JR, Laul JC (1986) Internal evolution of the Tin Mountain pegmatite, Black Hills, South Dakota. American Mineralogist 71: 440-459
E LEMENTS
261
A UGUS T 2012