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Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer

from Hach, Hach-Lange


General information for DR 5000 and DR 6000 when using Spectroquant Test kits from Merck.
Wavelength specification of the instrument:
Photometric range:
Standard cells which can be used:
Important:

190 to 1100 nm
3.0 A
16 mm (only US version), 13 mm (only European version), check your instrument before ordering the cell tests
10, 50 mm, 1-inch round and 1-inch rectangular cells (use the sample cell adapters coming with the instrument)

All Merck Spectroquant cell tests have a diameter of 16 mm and can only be used in the DR 5000 and DR 6000 US-version. Our Spectroquant round
tubes 16 mm are not applicable for the 13 mm diameter tubes from the DR 5000 and DR 6000 European version because of the 13 mm shaft. All

our Spectroquant reagent test kits using the 10, 20 and 50 mm cells can be measured with all DR 5000 instruments. The programming data can be
found in the following list.

Information about Spectroquant test kits:


In our Internet homepage www.analytical-test-kits.com users can find all information about our test kits. All package inserts as well as the manuals from e.g. our
Pharo spectrophotometers can be found there. This information helps to get a quick overview about the easy handling of our test kits. The package inserts include
detailed descriptions about all handling steps, colour reaction, sample preparation if required, interference with other substances, analytical quality assurance data and
more.
Zeroing the instrument:
Before measuring the sample users must enter the Zero value for each range. In the below enclosed programming tables it is mentioned for each parameter and
measuring range, what Zero value is necessary. You can choose between the following options:
1) Own blank (= distilled water and reagents)
2) Cell with blank (white screw cap)
3) Distilled water
4) Clear sample without reagents

The advantages of Spectroquant Tests kits are, that in some cases users can run as Zero distilled water or use the cell with blank (white screw cap) an therefore
need not to waste always on determination. This makes live easier and reduce costs. The zero should be entered when the instruments request Zero.
Message Under range! after zeroing the instrument:
The instrument must be zeroed for each test or series of tests to establish a zero reference for the measurement. This is done by placing a zero solution (distilled water
and reagents) in the cell holder and pressing ZERO. While entering a value of e.g. 25 for the low limit - and not 0 (like Hach) - the message Under range! appears
in the display. This message doesnt influence the results. Just go forward with the measurement. If you implement 0 for the low limit this message will not appear
(identical as if you use an original Hach program).
Please contact our local Merck companies or Merck agents for any questions or use the contact form in our internet homepage.
No endorsement by Hach Company is implied or intended.
Date: January 15, 2013

1 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.01758*

1.01758*

1.00594.0001*

1.01762

1.14825.0001

1.14825.0001

1.14825.0001

replaced by 1.01758

Program name

Acid
capacity01758

Acid
capacity01758

Unit

mmol/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

605 nm

605 nm

550 nm

550 nm

550 nm

550 nm

Resolution

0.01

0.01

0.01

0.001

0.001

Chemical Form 1

OH

CaCO3

Al

Al

Al

Al

Calibration a

-10,074

-503,7

-0.253

-0.165

-0.0649

-0.033

Calibration b

30,24

1512

1.023

0.9585

0.37735

0.1917

Calibration c

-23,081

-1154,1

-0.599

-0.3233

-0.12728

-0.06466

Calibration d

10,358

517,9

0.187

0.0719

0.02829

0.01437

Upper limit

8.00

400

0.50

1.20

0.472

0.240

Lower limit

0.40

20

0.02

0.10

0.039

0.020

Timer 1 (mm:ss)

-----

-----

05:00

02:00

02:00

02:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

Additional Merck
information

3)

3)

3)

3)

3)

3)

16 mm round

16 mm round

16 mm round

10 mm

1 inch

50 mm

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

Aluminium00594 Aluminium14825 Aluminium14825 Aluminium14825

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

2 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

Program name

1.14739.0001*

1.14558.0001*

1.14544.0001*

1.14559.0001*

1.14739.0001*

1.14558.0001*

1.14544.0001*

1.14559.0001*

Ammonium14739 Ammonium14558 Ammonium14544 Ammonium14559 Ammonium14739 Ammonium14558 Ammonium14544 Ammonium14559

Unit

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

Resolution

0.001

0.01

0.1

0.1

0.001

0.01

0.1

0.1

Chemical Form 1

NH4-N

NH4-N

NH4-N

NH4-N

NH4

NH4

NH4

NH4

Calibration a

Calibration b

0.877

4.26

7.84

36.4

1.13

5.49

10.1

46.8

Calibration c

Calibration d

Upper limit

2.000

8.00

16.0

80.0

2.576

10.30

20.6

103.0

Lower limit

0.010

0.20

0.5

4.0

0.013

0.26

0.6

5.2

Timer 1 (mm:ss)

15:00

15:00

15:00

15:00

15:00

15:00

15:00

15:00

Timer 2 (mm:ss)

-----

-----

-----

-----

------

-----

-----

-----

Additional Merck
information

2)

2)

2)

2)

2)

2)

2)

2)

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

3 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

Program name

1.14752

1.14752

1.14752

1.00683.0001

1.00683.0001

Ammonium14752 Ammonium14752 Ammonium14752 Ammonium00683 Ammonium00683

Unit

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

690 nm

690 nm

690 nm

690 nm

690 nm

Resolution

0.01

0.001

0.001

0.1

0.1

NH4-N

NH4-N

NH4-N

NH4-N

NH4-N

Calibration a

Calibration b

1.23

0.483

0.245

27.8

55.6

Calibration c

Calibration d

Upper limit

3.00

1.18

0.500

75.0

150.0

Lower limit

0.05

0.02

0.010

2.0

5.0

Timer 1 (mm:ss)

05:00

05:00

05:00

15:00

15:00

Timer 2 (mm:ss)

05:00

05:00

05:00

-----

-----

Additional Merck
information

1)

1)

1)

1)

1)

10 mm

1 inch

50 mm

10 mm

10 mm

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

4 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

Program name

1.14752

1.14752

1.14752

1.00683.0001

1.00683.0001

Ammonium14752 Ammonium14752 Ammonium14752 Ammonium00683 Ammonium00683

Unit

1.00675.0001*

AOX00675

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

690 nm

690 nm

690 nm

690 nm

690 nm

445 nm

Resolution

0.01

0.001

0.001

0.1

0.1

0.01

Chemical Form 1

NH4

NH4

NH4

NH4

NH4

AOX

Calibration a

Calibration b

1.58

0.622

0.316

35.8

71.5

4.00

Calibration c

Calibration d

Upper limit

3.86

1.520

0.644

96.6

193.2

2.50

Lower limit

0.06

0.024

0.013

2.6

6.4

0.05

Timer 1 (mm:ss)

05:00

05:00

05:00

15:00

15:00

15:00

Timer 2 (mm:ss)

05:00

05:00

05:00

-----

-----

-----

Additional Merck
information

1)

1)

1)

1)

1)

1)

10 mm

1 inch

50 mm

10 mm

10 mm

16 mm round

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

5 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.01747.0001

1.01747.0001

1.00687.0001*

1.00826.0001*

1.14839.0001

1.00605.0001

1.00605.0001

1.00605.0001

Program name

Arsenic01747

Arsenic01747

BOD00687

Boron00826

Boron14839

Bromine00605

Bromine00605

Bromine00605

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

525 nm

525 nm

500 nm

410 nm

565 nm

550 nm

550 nm

550 nm

Resolution

0.001

0.001

0.1

0.01

0.001

0.01

0.001

0.001

As

As

O2

Br2

Br2

Br2

Calibration a

Calibration b

0.114

0.0447

13.5

1.38

0.328

7.519

2.960

1.504

Calibration c

Calibration d

Upper limit

1.000

0.039

12.0

2.00

0.800

10.00

3.937

2.000

Lower limit

0.005

0.002

0.5

0.05

0.050

0.10

0.039

0.020

Timer 1 (mm:ss)

120:00

120:00

-----

60:00

12:00

01:00

01:00

01:00

Timer 2 (mm:ss)

-----

-----

-----

-----

02:00

-----

-----

-----

Additional Merck
information

3)

3)

3)

1)

1)

3)

3)

3)

10 mm

1 inch

16 mm round

16 mm round

10 mm

10 mm

1 inch

50 mm

Unit

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

6 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14834.0001*

1.01745.0001

1.01745.0001

1.01745.0001

1.00858.0001*

1.14815.0001

1.14815.0001
see appendix page 47

Program name

Cadmium
14834

Cadmium01745

Cadmium01745

Cadmium01745

Calcium00858

Calcium14815

Calcium14815s

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

550 nm

525 nm

525 nm

525 nm

565 nm

550 nm

550 nm

Resolution

0.001

0.001

0.001

0.001

0.1

Cd

Cd

Cd

Cd

Ca

Ca

Ca

Calibration a

-29.293

Calibration b

0.595

0.680

0.268

0.136

416.85

137

29.4

Calibration c

-252.27

Calibration d

99.158

Upper limit

1.000

0.010

0.005

0.002

250

160

15.0

Lower limit

0.025

0.500

0.197

0.100

10

10

1.0

Timer 1 (mm:ss)

02:00

02:00

02:00

02:00

03:00

08:00

08:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

1)

1)

3)

1)

1)

16 mm round

10 mm

1 inch

50 mm

16 mm round

10 mm

10 mm

Unit

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

7 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.00858.0001*

1.14815.0001

1.14815.0001

1.00858.0001*

1.14815.0001

see appendix page 47

Program name

1.14815.0001

1.19251.0001

see appendix page 47

180 *)

Calcium00858

Calcium14815

Calcium14815s

Calcium00858

Calcium14815

Calcium14815s

Carbohyrazide
see Oxygen Scavengers

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

g/l

Wavelength

565 nm

550 nm

550 nm

565 nm

550 nm

550 nm

562 nm

Resolution

0.1

0.1

Chemical Form 1

CaCO3

CaCO3

CaCO3

CaO

CaO

CaO

Carbohy

Calibration a

-73.418

-41.011

Calibration b

1045

342

73.5

583.59

192

41.2

Calibration c

-634.44

-353.18

Calibration d

249.09

138.82

Upper limit

625

400

37.5

350

224

21.0

600

Lower limit

25

25

2.5

14

14

1.4

Timer 1 (mm:ss)

03:00

08:00

08:00

03:00

08:00

08:00

10:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

----

Additional Merck
information

3)

1)

1)

3)

1)

1)

1)

16 mm round

10 mm

10 mm

16 mm round

10 mm

10 mm

1 inch

Unit

Cell size used

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.
As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

8 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14730.0001*

1.14897

1.14897

1.01807.0001

1.01804.0001*

1.00595.0001*

1.00597.0001*

1.00598

Program name

Chloride14730

Chloride14897

Chloride14897

Chloride01807

Chloride01804

Chlorine00595

Chlorine00597

Chlorine00598

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

525 nm

500 nm

445 nm

500 nm

445 nm

550 nm

550 nm

550 nm

Resolution

0.1

0.01

0.1

0.01

0.01

0.01

Unit

Chemical Form 1

Cl

Cl

Cl

Cl

Cl

Cl2

Cl2

Cl2

Calibration a

0,01337

-1,537

Calibration b

114

107

28.2

4,873

13,35

2.469

2.469

3.333

Calibration c

-1,329

-2,082

Calibration d

1,018

3,146

Upper limit

125

250

25.0

5.00

15.0

6.00

6.00

6.00

Lower limit

10

2.5

0.10

0.5

0.03

0.03

0.05

Timer 1 (mm:ss)

-----

01:00

01:00

10:00

10:00

01:00

01:00

01:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

1)

1)

3)

3)

3)

3)

16 mm round

10 mm

10 mm

50 mm

16 mm round

16 mm round

16 mm round

10 mm

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

9 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.00598

1.00598

1.00602

1.00602

1.00602

1.00599.0001

1.00599.0001

1.00599.0001

Program name

Chlorine00598

Chlorine00598

Chlorine00602

Chlorine00602

Chlorine00602

Chlorine00599

Chlorine00599

Chlorine00599

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

550 nm

550 nm

550 nm

550 nm

550 nm

550 nm

550 nm

550 nm

Resolution

0.01

0.001

0.01

0.01

0.001

0.01

0.01

0.001

Cl2

Cl2

Cl2

Cl2

Cl2

Cl2

Cl2

Cl2

Calibration a

Calibration b

1.312

0.667

3.333

1.312

0.667

3.333

1.312

0.667

Calibration c

Calibration d

Upper limit

3.00

1.000

6.00

2.36

1.000

6.00

2.36

1.000

Lower limit

0.02

0.010

0.05

0.02

0.010

0.05

0.02

0.010

Timer 1 (mm:ss)

01:00

01:00

01:00

01:00

01:00

01:00

01:00

01:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

3)

3)

3)

3)

3)

3)

3)

3)

1 inch

50 mm

10 mm

1 inch

50 mm

10 mm

1 inch

50 mm

2) cell with blank (white screw cap)

3) distilled water

Unit

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

10 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.00086/1.00087 1.00086/1.00087
1.00088*
1.00088

1.00608.0001

1.00608.0001

1.00608.0001

Program name

Chlorine00086/87 Chlorine00086/87
/88
/88

Chlorine
dioxide00608

Chlorine
dioxide00608

Chlorine
dioxide00608

mg/L

mg/L

mg/l

mg/l

mg/l

Wavelength

550 nm

550 nm

550 nm

550 nm

550 nm

Resolution

0.01

0.001

0.01

0.01

0.001

Cl2

Cl2

ClO2

ClO2

ClO2

Calibration a

Calibration b

2.47

0.67

6.33

2.49

1.27

Calibration c

Calibration d

Upper limit

6.00

1.000

10.00

3.94

2.000

Lower limit

0.03

0.010

0.10

0.04

0.020

Timer 1 (mm:ss)

01:00

01:00

02:00

02:00

02:00

Timer 2 (mm:ss)

-----

-----

01:00

01:00

01:00

Additional Merck
information

3)

3)

3)

3)

3)

16 mm round

50 mm

10 mm

1 inch

50 mm

Unit

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

11 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14552.0001*

1.14758.0001

1.14758.0001

1.14758.0001

1.14552.0001*

1.14758.0001

1.14758.0001

1.14758.0001

Program name

Chromate14552

Chromate14758

Chromate14758

Chromate14758

Chromate14552

Chromate14758

Chromate14758

Chromate14758

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

550 nm

550 nm

550 nm

550 nm

550 nm

550 nm

550 nm

550 nm

Resolution

0.01

0.01

0.001

0.001

0.01

0.01

0.001

0.001

Chemical Form 1

Cr

Cr

Cr

Cr

CrO4

CrO4

CrO4

CrO4

Calibration a

Calibration b

0.971

1.30

0.511

0.260

2.17

2.90

1.14

0.579

Calibration c

Calibration d

Upper limit

2.00

3.00

1.181

0.600

4.46

6.69

2.635

1.338

Lower limit

0.05

0.05

0.020

0.010

0.11

0.11

0.044

0.022

Timer 1 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

2)

3)

3)

3)

2)

3)

3)

3)

16 mm round

10 mm

1 inch

50 mm

16 mm round

10 mm

1 inch

50 mm

Unit

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

12 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.18750.0001*

1.18751.0001*

1.18752.0001*

1.18753.0001*

1.14560.0001*

1.01796.0001*

1.14540.0001*

Hach Program

431 *)

430 *)

435 *)

435 *)

Program name

COD

COD

COD

COD

COD14560

COD01796

COD14540

Unit

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

350 nm

420 nm

620 nm

620 nm

340 nm

340 nm

445 nm

0.1

0.1

COD

COD

COD

Calibration a

Calibration b

-41.7

-40.7

-205,3

Calibration c

Calibration d

Wavelength
Resolution
Chemical Form 1

COD

COD

COD

COD

Upper limit

40.0

150

1500

15000

40.0

80.0

150

Lower limit

0.0

4.0

5.0

10

Timer 1 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

1)

1)

1)

1)

1)

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

Cell size used

*) The above-mentioned Merck COD cell tests can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach COD tubes. Details can be found in the package insert, which is included in the box.
As blank can be used: 1) own blank (= distilled water and reagents). The blank for COD is stabile for e.g. 3 month when storing dark.

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

13 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14895.0001*

1.14690.0001*

1.14541.0001*

1.14691.0001*

1.14555.0001*

1.01797.0001*

1.09772.0001*

Program name

COD14895

COD14690

COD14541

COD14691

COD14555

COD01797

COD
(Hg free)09772

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

445 nm

445 nm

605 nm

605 nm

605 nm

605 nm

445 nm

Resolution

10

10

COD

COD

COD

COD

COD

COD

COD

Calibration a

Calibration b

-222

-397

1667

3226

4608

42553

-238

Calibration c

Calibration d

Upper limit

300

500

1500

3500

10000

90000

150

Lower limit

15

50

25

300

500

5000

10

Timer 1 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

1)

1)

1)

1)

1)

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

Unit

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents). The blank for COD is stabile for e.g. 3 month when storing dark.

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

14 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.09773.0001*

1.17058.0001*

1.17059.0001*

1.14553.0001*

1.14767.0001

1.14767.0001

1.14767.0001

Program name

COD
(Hg free)09773

COD seawater
17058

COD seawater
17059

Copper14553

Copper14767

Copper14767

Copper14767

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

605 nm

340 nm

605 nm

605 nm

605 nm

605 nm

605 nm

Resolution

0.1

0.01

0.01

0.01

0.001

COD

COD

COD

Cu

Cu

Cu

Cu

Calibration a

Calibration b

1923

-57.5

3650

3.60

4.44

1.75

0.889

Calibration c

Calibration d

Upper limit

1500

60.0

3000

8.00

6.00

2.36

1.200

Lower limit

100

5.0

50

0.05

0.10

0.04

0.020

Timer 1 (mm:ss)

-----

-----

-----

05:00

05:00

05:00

05:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

------

------

Additional Merck
information

1)

1)

1)

2)

3)

3)

3)

16 mm round

16 mm round

16 mm round

16 mm round

10 mm

1 inch

50 mm

Unit

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

15 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14561.0001*

1.09701.0001

1.09701.0001

1.09701.0001

1.14800.0001

1.14800.0001

1.14800.0001

Program name

Cyanide14561

Cyanide09701

Cyanide09701

Cyanide09701

Cyanide14800

Cyanide14800

Cyanide14800

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

605 nm

605 nm

605 nm

605 nm

585 nm

585 nm

585 nm

Resolution

0.001

0.001

0.001

0.001

0.001

0.001

0.001

Unit

Chemical Form 1

CN

CN

CN

CN

CN

CN

CN

Calibration a

Calibration b

0.161

0.221

0.0871

0.0442

0.208

0.0819

0.0416

Calibration c

Calibration d

Upper limit

0.500

0.500

0.197

0.100

0.500

0.197

0.100

Lower limit

0.010

0.010

0.004

0.002

0.010

0.004

0.002

Timer 1 (mm:ss)

10:00

10:00

10:00

10:00

05:00

05:00

05:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

3)

3)

3)

3)

3)

3)

3)

16 mm round

10 mm

1 inch

50 mm

10 mm

1 inch

50 mm

Cell size used

*) Instrument-specific calibration necessary!


As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

16 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14557.0001*

1.19253.0001

1.19251.0001

*)

*)

181 *)

Cyanuric Acid
19250

Cyanuric Acid
19253

DEHA
see Oxygen Scavengers

Fluoride14557

Fluoride14557s

Fluoride00809

Fluoride00809s

mg/l

mg/l

g/l

mg/l

mg/l

mg/l

mg/l

Wavelength

525 nm

525 nm

562 nm

620 nm

620 nm

620 nm

620 nm

Resolution

0.01

0.001

0.01

0.001

Cyanuric Acid

Cyanuric Acid

DEHA

Program name
Unit

1.14557.0001

1.00809.0001*

1.19250.0001

see appendix page


47

1.00809.0001
see appendix page
47

Calibration a

Calibration b

1.33

0.323

1.43

0.312

Calibration c

Calibration d

Chemical Form 1

Upper limit

160

160

450

1.50

0.500

1.80

0.500

Lower limit

0.10

0.025

0.10

0.025

Timer 1 (mm:ss)

03:00

03:00

10:00

05:00

05:00

15:00

15:00

Timer 2 (mm:ss)

----

----

----

-----

-----

-----

-----

Additional Merck
information

4)

4)

1)

1)

1)

1)

1)

1 inch

1 inch

1 inch

16 mm round

50 mm

16 mm round

50 mm

Cell size used

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.As blank can be used: 1) own
blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

17 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14598

1.14598

1.00822.0250

1.14500.0001*

1.14678.0001

1.14678.0001

1.14678.0001

190 *)
Program name

Fluoride14598

Fluoride14598

Fluoride

Formaldehyde
14500

Formaldehyde
14678

Formaldehyde
14678

Formaldehyde
14678

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

620 nm

620 nm

580 nm

565 nm

565 nm

565 nm

565 nm

Resolution

0.01

0.1

0.1

0.01

0.01

0.01

0.001

HCHO

HCHO

HCHO

HCHO

Unit

Chemical Form 1

Calibration a

Calibration b

2.02

21.5

3.23

4.22

1.66

0.844

Calibration c

Calibration d

Upper limit

2.00

20.0

2.00

8.00

8.00

3.15

1.500

Lower limit

0.10

1.0

0.02

0.10

0.10

0.04

0.020

Timer 1 (mm:ss)

05:00

05:00

01:00

05:00

10:00

10:00

10:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

1)

3)

3)

3)

3)

10 mm

10 mm

1 inch

16 mm round

10 mm

1 inch

50 mm

Cell size used

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.
As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

18 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14821.0001

1.09711.0001

1.09711.0001

1.09711.0001

1.14731.0001*

1.14731.0001
see appendix page 47

Program name

Gold14821

Unit

Hydrazine09711 Hydrazine09711 Hydrazine09711

Hydrogen
peroxide14731

Hydrogen
peroxide14731s

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

550 nm

445 nm

445 nm

445 nm

410 nm

410 nm

Resolution

0.1

0.01

0.001

0.001

0.1

0.01

Chemical Form 1

Au

N2H4

N2H4

N2H4

H2O2

H2O2

Calibration a

Calibration b

6.25

0.870

0.342

0.174

38.5

10.5

Calibration c

Calibration d

Upper limit

12.0

2.00

0.787

0.400

20.0

5.00

Lower limit

0.5

0.02

0.008

0.005

2.0

0.25

Timer 1 (mm:ss)

-----

05:00

05:00

05:00

02: 00

02: 00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

3)

3)

3)

2)

3)

10 mm

10 mm

1 inch

50 mm

16 mm round

50 mm

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

19 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.18789.0001

1.18789.0001

1.19251.0001

1.00606.0001

1.00606.0001

1.00606.0001

182 *)
Program name

Hydrogen
peroxide18789

Hydrogen
peroxide18789

Hydroquinone
see Oxygen Scavengers

Iodine00606

Iodine00606

Iodine00606

mg/l

mg/l

g/l

mg/l

mg/l

mg/l

Wavelength

445 nm

445 nm

562 nm

550 nm

550 nm

550 nm

Resolution

0.01

0.01

0.01

0.01

0.001

Chemical Form 1

H2O2

H2O2

Hydro

I2

I2

I2

Calibration a

Calibration b

2.65

1.04

11.9

4.69

2.38

Calibration c

Calibration d

Upper limit

6.00

2.36

1000

10.00

3.94

2.000

Lower limit

0.03

0.01

0.20

0.08

0.050

Timer 1 (mm:ss)

10: 00

10: 00

2:00

01:00

01:00

01:00

Timer 2 (mm:ss)

-----

-----

----

----

-----

-----

Additional Merck
information

1)

1)

1)

3)

3)

3)

10 mm

1 inch

1 inch

10 mm

1 inch

50 mm

Unit

Cell size used

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.
As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

20 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14549.0001*

1.14896.0001*

1.14761

1.14761

1.14761

1.100796.0001

1.100796.0001

1.100796.0001

Program name

Iron14549

Iron14896

Iron14761

Iron14761

Iron14761

Iron00796

Iron00796

Iron00796

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

565 nm

525 nm

565 nm

565 nm

565 nm

500 nm

500 nm

500 nm

Resolution

0.01

0.1

0.01

0.001

0.001

0.01

0.01

0.001

Fe

Fe

Fe

Fe

Fe

Fe

Fe

Fe

Calibration a

Calibration b

1.64

28.3

2.08

0.820

0.417

5.56

2.19

1.11

Calibration c

Calibration d

Upper limit

4.00

50.0

5.00

1.97

1.000

5.00

1.97

1.000

Lower limit

0.05

1.0

0.05

0.02

0.005

0.10

0.04

0.010

Timer 1 (mm:ss)

03:00

05:00

03:00

03:00

03:00

10:00

10:00

10:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

2)

2)

3)

3)

3)

3)

3)

3)

16 mm round

16 mm round

10 mm

1 inch

50 mm

10 mm

1 inch

50 mm

2) cell with blank (white screw cap)

3) distilled water

Unit

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

21 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14833.0001*

1.09717.0001

1.09717.0001

1.09717.0001

1.00815.0001*

Isoascorbic acid
see Oxygen Scavengers

Lead14833

Lead09717

Lead09717

Lead09717

Magnesium
00815

g/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

562 nm

525 nm

525 nm

525 nm

525 nm

565 nm

Resolution

0.01

0.01

0.001

0.001

0.1

ISA

Pb

Pb

Pb

Pb

Mg

Calibration a

-20.79

Calibration b

4.39

6.25

2.46

1.25

337.41

Calibration c

-513.33

Calibration d

458.21

1.19251.0001
183 *)

Program name
Unit

Chemical Form 1

Upper limit

1500

5.00

5.00

1.970

1.000

75.0

Lower limit

0.10

0.10

0.039

0.010

5.0

Timer 1 (mm:ss)

10:00

-----

-----

-----

-----

03:00

Timer 2 (mm:ss)

----

-----

-----

-----

-----

-----

Additional Merck
information

1)

2)

1)

1)

1)

3)

1 inch

16 mm round

10 mm

1 inch

50 mm

16 mm round

Cell size used

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.
As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents

* Only applicable to DR 5000 US version. DR 5000 European versions (with 13 mm cell holder) do not allow tests with 16 mm round cells!
Date: January 15, 2013

22 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.00816.0001*

1.01846.0001

1.01846.0001

1.01846.0001

Program name

Manganese
00816

Manganese
01846

Manganese
01846

Manganese
01846

mg/l

mg/l

mg/l

mg/l

Wavelength

445 nm

565 nm

565 nm

565 nm

Resolution

0.01

0.01

0.001

0.001

Chemical Form 1

Mn

Mn

Mn

Mn

Calibration a

Calibration b

4.13

1.67

0.657

0.334

Calibration c

Calibration d

Upper limit

5.00

2.00

0.790

0.400

Lower limit

0.10

0.05

0.020

0.005

Timer 1 (mm:ss)

02:00

10:00

10:00

10:00

Timer 2 (mm:ss)

05:00

-----

-----

-----

Additional Merck
information

2)

1)

1)

1)

16 mm round

10 mm

1 inch

50 mm

Unit

Cell size used

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.
As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

23 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange
Merck order no.

1.01739.0001

1.01739.0001

1.01739.0001

1.14770

1.14770

1.14770

1.19251.0001
184 *)

Program name

Manganese
01739

Manganese
01739

Manganese
01739

Manganese
14770

Manganese
14770

Manganese
14770

Methylethylketoxime
see Oxygen Scavengers

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

g/l

Wavelength

565 nm

565 nm

565 nm

445 nm

445 nm

445 nm

562 nm

Resolution

0.01

0.001

0.001

0.01

0.01

0.001

Chemical Form 1

Mn

Mn

Mn

Mn

Mn

Mn

MEKO

Calibration a

Calibration b

1.72

0.679

0.345

5.62

2.21

1.12

Calibration c

Calibration d

Upper limit

2.00

0.790

0.400

10.00

3.94

2.000

1000

Lower limit

0.05

0.020

0.005

0.50

0.20

0.010

Timer 1 (mm:ss)

10:00

10:00

10:00

02:00

02:00

02:00

10:00

Timer 2 (mm:ss)

-----

-----

-----

02:00

02:00

02:00

----

Additional Merck
information

1)

1)

1)

3)

3)

3)

1)

10 mm

1 inch

50 mm

10 mm

1 inch

50 mm

1 inch

Unit

Cell size used

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.
As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

24 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange
Merck order no.

1.00860.0001*

Hach Program
Program name

1.19252.0001

1.01632.0001

1.01632.0001

1.01632.0001

1.01632.0001

1.01632.0001

1.01632.0001

320 *)
Molybdenum
00860

Molybdenum

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

620 nm

420 nm

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

Resolution

0.01

0.01

0.01

0.001

0.01

0.01

0.001

Chemical Form 1

Mo

Cl2

Cl2

Cl2

NH2Cl

NH2Cl

NH2Cl

Unit

Mo

Monochloramine Monochloramine Monochloramine Monochloramine Monochloramine Monochloramine


01632
01632
01632
01632
01632
01632

Calibration a

Calibration b

1.10

5.00

1.97

1.00

3.67

1.44

0.733

Calibration c

Calibration d

Upper limit

1.00

40.0

10.00

3.94

2.000

7.25

2.85

1.450

Lower limit

0.02

0.2

0.25

0.10

0.050

0.18

0.09

0.036

Timer 1 (mm:ss)

02:00

05:00

05:00

05:00

05:00

05:00

05:00

05:00

Timer 2 (mm:ss)

-----

----

10:00

10:00

10:00

10:00

10:00

10:00

Additional Merck
information

1)

4)

1)

1)

1)

1)

1)

1)

16 mm round

1 inch

10 mm

1 inch

50 mm

10 mm

1 inch

50 mm

Cell size used

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.
As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

25 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.01632.0001

1.01632.0001

1.01632.0001

1.14554.0001*

1.14785.0001

1.14785.0001

1.14785.0001

Program name

Monochloramine
01632

Monochloramine
01632

Monochloramine
01632

Nickel14554

Nickel14785

Nickel14785

Nickel14785

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

690 nm

690 nm

690 nm

445 nm

445 nm

445 nm

445 nm

Resolution

0.01

0.01

0.001

0.01

0.01

0.01

0.001

NH2Cl-N

NH2Cl-N

NH2Cl-N

Ni

Ni

Ni

Ni

Calibration a

Calibration b

0.988

0.389

0.198

3.82

4.76

1.87

0.952

Calibration c

Calibration d

Upper limit

1.96

0.77

0.392

6.00

5.00

1.97

1.000

Lower limit

0.05

0.02

0.010

0.10

0.10

0.04

0.020

Timer 1 (mm:ss)

05:00

05:00

05:00

01:00

01:00

01:00

01:00

Timer 2 (mm:ss)

10:00

10:00

10:00

02:00

02:00

02:00

02:00

Additional Merck
information

1)

1)

1)

2)

3)

3)

3)

10 mm

1 inch

50 mm

16 mm round

10 mm

1 inch

50 mm

Unit

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

26 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14542.0001*

1.14563.0001*

1.14764.0001*

1.00614.0001*

1.14542.0001*

1.14563.0001*

1.14764.0001*

Program name

Nitrate14542

Nitrate14563

Nitrate14764

Nitrate00614

Nitrate14542

Nitrate14563

Nitrate14764

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

525 nm

340 nm

340 nm

340 nm

525 nm

340 nm

340 nm

Resolution

0.1

0.1

0.1

0.1

0.1

0.1

NO3

NO3

Unit

NO3-N

NO3-N

NO3-N

NO3-N

NO3

Calibration a

Calibration b

7.14

14.7

27.9

128

31.6

65.3

124

Calibration c

Calibration d

Upper limit

18.0

25.0

50.0

225

79.7

110.7

221.3

Lower limit

0.5

0.5

1.0

23

2.2

2.2

4.4

Timer 1 (mm:ss)

10:00

10:00

10:00

05:00

10:00

10:00

10:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

2)

2)

2)

2)

2)

2)

2)

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

27 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.00614.0001*

1.14773.0001

1.14773.0001

1.14773.0001

1.14773.0001

Program name

Nitrate00614

Nitrate14773

Nitrate14773

Nitrate14773

Nitrate14773

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

340 nm

525 nm

525 nm

525 nm

525 nm

Resolution

0.1

0.1

0.1

0.1

Unit

Chemical Form 1

NO3

NO3-N

NO3-N

NO3

NO3

Calibration a

Calibration b

568

9.62

3.79

42.6

16.8

Calibration c

Calibration d

Upper limit

996

20.0

7.9

88.5

34.8

Lower limit

102

0.5

0.2

2.2

0.9

Timer 1 (mm:ss)

05:00

10:00

10:00

10:00

10:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

Additional Merck
information

2)

1)

1)

1)

1)

16 mm round

10 mm

1 inch

10 mm

1 inch

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

28 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.09713

1.09713

1.09713

1.09713

1.09713

1.09713

Program name

Nitrate09713

Nitrate09713

Nitrate09713

Nitrate09713

Nitrate09713

Nitrate09713

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

340 nm

340 nm

340 nm

340 nm

340 nm

340 nm

Resolution

0.1

0.1

0.01

0.1

0.1

0.1

NO3

NO3

Unit

NO3-N

NO3-N

NO3-N

NO3

Calibration a

Calibration b

19.6

7.72

3.92

86.8

34.2

17.4

Calibration c

Calibration d

Upper limit

25.0

9.8

5.00

110.7

43.6

22.1

Lower limit

1.0

0.4

0.10

4.4

1.7

0.4

10:00

10:00

10:00

10:00

10:00

10:00

1)

1)

1)

1)

1)

1)

10 mm

1 inch

50 mm

10 mm

1 inch

50 mm

Chemical Form 1

Timer 1 (mm:ss)

Timer 2 (mm:ss)

Additional Merck
information
Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

29 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14556.0001*

1.14942.0001

1.01842.0001

1.01842.0001

1.14556.0001*

1.14942.0001

1.00609.0001*

Program name

Nitrate
seawater14556

Nitrate
seawater14942

Nitrate01842

Nitrate01842

Nitrate
seawater14556

Nitrate
seawater14942

Nitrite00609

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

500 nm

500 nm

500 nm

500 nm

500 nm

500 nm

605 nm

Resolution

0.01

0.01

0.1

0.1

0.01

0.1

0.1

NO3

NO3

NO2

Unit

Chemical Form 1

NO3-N

NO3-N

NO3-N

NO3

Calibration a

-0.047

0.421

-0,5041

-2.2315

-0.0442

-1.865

Calibration b

1.718

8.251

32,2843

142.913

7.182

36.524

82.64

Calibration c

-0.438

-0.5679

-21,08326

-93.329

-1.6478

-2.515

Calibration d

0.0821

0.335

7,1650

31.717

0.3041

149

Upper limit

3.00

17.00

30.0

132.9

13.28

75.3

90.0

Lower limit

0.10

0.20

0.3

1.3

0.44

0.9

1.0

Timer 1 (mm:ss)

30:00

15:00

10:00

10:00

30:00

15:00

20:00

Timer 2 (mm:ss)

-----

60:00

-----

-----

-----

60:00

-----

Additional Merck
information

3)

3)

1)

1)

3)

3)

1)

16 mm round

10 mm

50 mm

50 mm

16 mm round

10 mm

16 mm round

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

30 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14547.0001*

1.14776

1.14776

1.14776

1.14547.0001*

1.14776

1.14776

Program name

Nitrite14547

Nitrite14776

Nitrite14776

Nitrite14776

Nitrite14547

Nitrite14776

Nitrite14776

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

525 nm

525 nm

525 nm

525 nm

525 nm

525 nm

525 nm

Resolution

0.001

0.001

0.001

0.001

0.001

0.001

0.001

Unit

Chemical Form 1

NO2-N

NO2-N

NO2-N

NO2-N

NO2

NO2

NO2

Calibration a

Calibration b

0.274

0.376

0.148

0.0752

0.900

1.22

0.479

Calibration c

Calibration d

Upper limit

0.700

1.000

0.394

0.200

2.300

3.285

1.293

Lower limit

0.010

0.020

0.008

0.002

0.033

0.066

0.026

Timer 1 (mm:ss)

10:00

10:00

10:00

10:00

10:00

10:00

10:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

2)

3)

3)

3)

2)

3)

3)

16 mm round

10 mm

1 inch

50 mm

16 mm round

10 mm

1 inch

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

31 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14776

1.00613.0001*

1.14537.0001*

1.14763.0001*

Hach Program
Program name

1.19251.0001

1.19251.0001

1.19251.0001

180 *)

181 *)

182 *)

Nitrite14776

Nitrogen00613

Nitrogen14537

Nitrogen14763

Oxygen Scavengers
Carbohyrazide

mg/l

mg/l

mg/l

mg/l

g/l

g/l

g/l

Wavelength

525 nm

365 nm

525 nm

365 nm

562 nm

562 nm

562 nm

Resolution

0.001

0.1

0.1

NO2

Carbohy

DEHA

Hydro

Calibration a

Calibration b

0.243

18.4

7.81

185

Calibration c

Calibration d

Upper limit

0.657

15.0

15.0

150

600

450

1000

Lower limit

0.007

0.5

0.5

10

Timer 1 (mm:ss)

10:00

10:00

10:00

10:00

10:00

10:00

2:00

Timer 2 (mm:ss)

-----

-----

-----

-----

----

----

----

Additional Merck
information

3)

2)

1)

2)

1)

1)

1)

50 mm

16 mm round

16 mm round

16 mm round

1 inch

1 inch

1 inch

Unit

Chemical Form 1

Cell size used

Oxygen Scavengers Oxygen Scavengers


DEHA
Hydroquinone

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.
As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

32 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.19251.0001

1.19251.0001

183 *)

184 *)

Hach Program
Program name

Oxygen Scavengers Oxygen Scavengers


Isoascorbic acid
Methylethylketoxime

Unit

1.14694.0001*

1.00607

1.00607

1.00607

1.01744.0001*

Oxygen14694

Ozone00607

Ozone00607

Ozone00607

pH01744

g/l

g/l

mg/l

mg/l

mg/l

mg/l

pH

Wavelength

562 nm

562 nm

500 nm

550 nm

550 nm

550 nm

550 nm

Resolution

0.1

0.01

0.001

0.001

0.1

ISA

MEKO

O2

O3

O3

O3

Calibration a

6.144

Calibration b

13.5

2.25

0.887

0.450

3.218

Calibration c

-2.318

Calibration d

0.714

Chemical Form 1

Upper limit

1500

1000

12.0

4.00

1.575

0.800

6.4

Lower limit

0.5

0.05

0.020

0.010

8.8

Timer 1 (mm:ss)

10:00

10:00

-----

01:00

01:00

01:00

-----

Timer 2 (mm:ss)

----

----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

3)

3)

3)

3)

3)

1 inch

1 inch

16 mm round

10 mm

1 inch

50 mm

16 mm round

Cell size used

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary.
Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.
As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

33 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14551.0001*

1.00856.0001

1.00856.0001

1.00856.0001

1.00856.0001

1.00474.0001*

1.14543.0001*

Program name

Phenol14551

Phenol00856

Phenol00856

Phenol00856

Phenol00856

Phosphate00474

Phosphate14543

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

500 nm

445 nm

495 nm

495 nm

495 nm

690 nm

690 nm

Resolution

0.01

0.001

0.01

0.01

0.001

0.01

0.01

Phenol

Phenol

Phenol

Phenol

Phenol

PO4-P

PO4-P

Calibration a

Calibration b

3.39

0.0895

8.33

3.28

1.67

1.61

1.61

Calibration c

Calibration d

Upper limit

2.50

0.100

5.00

1.97

1.000

5.00

5.00

Lower limit

0.10

0.002

0.10

0.07

0.025

0.05

0.05

Timer 1 (mm:ss)

01:00

30:00

10:00

10:00

10:00

05:00

05:00

Timer 2 (mm:ss)

-----

10:00

-----

-----

-----

-----

-----

Additional Merck
information

2)

1)

1)

1)

1)

2)

2)

16 mm round

1 inch

10 mm

1 inch

50 mm

16 mm round

16 mm round

Unit

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

34 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

Program name

1.00475.0001*

1.14729.0001*

1.00616.0001*

1.00673.0001*

1.00474.0001*

1.14543.0001*

1.00475.0001*

1.14729.0001*

Phosphate00475 Phosphate14729 Phosphate00616 Phosphate00673 Phosphate00474 Phosphate14543 Phosphate00475 Phosphate14729

Unit

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

Resolution

0.1

0.1

0.1

0.1

0.01

0.01

0.1

0.1

Chemical Form 1

3-

3-

3-

3-

PO4-P

PO4-P

PO4-P

PO4-P

Calibration a

Calibration b

8.06

8.06

39.2

39.2

4.95

4.95

24.7

24.7

Calibration c

Calibration d

Upper limit

25.0

25.0

100.0

100.0

15.33

15.33

76.7

76.7

Lower limit

0.5

0.5

3.0

3.0

0.15

0.15

1.5

1.5

Timer 1 (mm:ss)

05:00

05:00

05:00

05:00

05:00

05:00

05:00

05:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

2)

2)

2)

2)

2)

2)

2)

2)

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

PO4

2) cell with blank (white screw cap)

PO4

3) distilled water

PO4

PO4

4) clear sample without reagents

* Only applicable to DR 5000 US version. DR 5000 European versions (with 13 mm cell holder) do not allow tests with 16 mm round cells!
Date: January 15, 2013

35 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

Program name

1.00616.0001*

1.00673.0001*

1.00474.0001*

1.14543.0001*

1.00475.0001*

1.14729.0001*

1.00616.0001*

1.00673.0001*

Phosphate00616 Phosphate00673 Phosphate00474 Phosphate14543 Phosphate00475 Phosphate14729 Phosphate00616 Phosphate00673

Unit

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

Resolution

0.01

0.01

0.1

0.1

P2O5

P2O5

P2O5

P2O5

P2O5

P2O5

3-

Chemical Form 1

PO4

3-

PO4

Calibration a

Calibration b

120

120

3.70

3.70

18.5

18.5

89.9

89.9

Calibration c

Calibration d

Upper limit

307

307

11.46

11.46

57.3

57.3

229

229

Lower limit

0.11

0.11

1.1

1.1

Timer 1 (mm:ss)

05:00

05:00

05:00

05:00

05:00

05:00

05:00

05:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

2)

2)

2)

2)

2)

2)

2)

2)

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

36 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

Program name

1.14848

1.14848

1.14848

1.00798.0001

1.00798.0001

1.14848

Phosphate14848 Phosphate14848 Phosphate14848 Phosphate00798 Phosphate00798 Phosphate14848

Unit

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

Resolution

0.01

0.01

0.001

0.1

0.1

0.1

PO4-P

PO4-P

PO4-P

PO4-P

PO4-P

PO4

Calibration a

Calibration b

2.08

0.820

0.417

35.1

13.8

6.38

Calibration c

Calibration d

Upper limit

5.00

1.97

1.000

100.0

39.4

15.3

Lower limit

0.05

0.02

0.010

1.0

0.4

0.2

Timer 1 (mm:ss)

05:00

05:00

05:00

05:00

05:00

05:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

1)

1)

1)

1)

10 mm

1 inch

50 mm

10 mm

1 inch

10 mm

2) cell with blank (white screw cap)

3) distilled water

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

3-

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

37 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

Program name

1.14848

1.14848

1.00798.0001

1.00798.0001

1.14848

1.14848

1.14848

1.14546.0001*

Phosphate14848 Phosphate14848 Phosphate00798 Phosphate00798 Phosphate14848 Phosphate14848 Phosphate14848 Phosphate14546

Unit

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

690 nm

410 nm

Resolution

0.01

0.01

0.1

0.01

0.01

0.001

0.1

P2O5

P2O5

P2O5

PO4-P

Chemical Form 1

3-

PO4

3-

PO4

3-

PO4

3-

PO4

Calibration a

Calibration b

2.51

1.28

108

42.4

4.76

1.88

0.954

13.4

Calibration c

Calibration d

Upper limit

6.04

3.0

307

120.9

11.46

4.51

2.291

25.0

Lower limit

0.06

0.03

1.2

0.11

0.05

0.023

0.5

Timer 1 (mm:ss)

05:00

05:00

05:00

05:00

05:00

05:00

05:00

-----

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

1)

1)

1)

1)

1)

2)

1 inch

50 mm

10 mm

1 inch

10 mm

1 inch

50 mm

16 mm round

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

38 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

Program name

1.14842.0001

1.14842.0001

1.14546.0001*

1.14842.0001

1.14842.0001

1.14546.0001*

1.14842.0001

1.14842.0001

Phosphate14842 Phosphate14842 Phosphate14546 Phosphate14842 Phosphate14842 Phosphate14546 Phosphate14842 Phosphate14842

Unit

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

410 nm

410 nm

410 nm

410 nm

410 nm

410 nm

410 nm

410 nm

Resolution

0.1

0.1

0.1

0.1

0.1

0.1

0.1

0.1

P2O5

P2O5

P2O5

Chemical Form 1

3-

3-

3-

PO4-P

PO4-P

Calibration a

Calibration b

18.0

7.09

41.2

55.2

21.7

30.8

41.3

16.2

Calibration c

Calibration d

Upper limit

30.0

11.8

76.7

92.0

36.2

57.3

68.7

27.0

Lower limit

1.0

0.4

1.5

3.1

1.2

1.1

2.3

0.9

Timer 1 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

2)

1)

1)

2)

1)

1)

10 mm

1 inch

16 mm round

10 mm

1 inch

16 mm round

10 mm

1 inch

Cell size used

PO4

PO4

As blank can be used: 1) own blank (= distilled water and reagents)

PO4

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

39 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

Program name

1.14562.0001*

1.00615.0001*

*)

*)

Potassium14562 Potassium00615

Unit

1.14683.0001*

1.14683.0001*

1.14683.0001*

1.14683.0001*

1.14683.0001*

1.14683.0001*

Residual
Hardness14683

Residual
Hardness14683

Residual
Hardness14683

Residual
Hardness14683

Residual
Hardness14683

Residual
Hardness14683

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

690 nm

690 nm

565 nm

565 nm

565 nm

565 nm

565 nm

565 nm

Resolution

0.1

0.01

0.01

0.01

0.001

0.001

0.001

Ca

CaCO3

CaO

Calibration a

-0.46153

-1.1538

-0.64615

-0.06461

-0.08077

-0.11538

Calibration b

4.62293

11.557

6.4721

0.64721

0.80901

1.15573

Calibration c

-1.14084

-2.8521

-1.59717

-0.15972

-0.19965

-0.28521

Calibration d

0.32358

0.8089

0.45301

0.0453

0.05663

0.08089

Chemical Form 1

Upper limit

50.0

300

5.00

12.50

7.00

0.700

0.875

1.250

Lower limit

5.0

30

0.50

1.25

0.70

0.070

0.088

0.125

05:00

05:00

10:00

10:00

10:00

10:00

10:00

10:00

-----

-----

-----

-----

-----

-----

Timer 1 (mm:ss)
Timer 2 (mm:ss)

3)

3)

3)

3)

3)

3)

3)

3)

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

Additional Merck
information
Cell size used

*) Instrument-specific calibration necessary!


As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

40 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14794.0001

1.14794.0001

1.14794.0001

1.00857.0001

1.00857.0001

1.00857.0001

1.00857.0001

1.01813.0001

Program name

Silicate14794

Silicate14794

Silicate14794

Silicate00857

Silicate00857

Silicate00857

Silicate00857

Silicate01813

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

665 nm

665 nm

820 nm

410 nm

410 nm

410 nm

410 nm

820 nm

Resolution

0.01

0.01

0.001

0.1

0.1

0.1

0.0001

Chemical Form 1

Si

Si

Si

Si

Si

Si

Si

Si

Calibration a

Calibration b

3.74

1.47

0.286

28.0

11.0

282

111

0.785

Calibration c

Calibration d

Upper limit

5.00

1.97

0.750

50.0

19.7

500

196.9

0.2337

Lower limit

0.10

0.04

0.005

0.5

0.2

2.0

0.0002

Timer 1 (mm:ss)

03:00

03:00

03:00

02:00

02:00

02:00

02:00

05:00

Timer 2 (mm:ss)

10:00

10:00

10:00

02:00

02:00

02:00

02:00

05:00

Additional Merck
information

3)

3)

3)

3)

3)

3)

3)

1)

10 mm

1 inch

50 mm

10 mm

1 inch

10 mm

1 inch

50 mm

2) cell with blank (white screw cap)

3) distilled water

Unit

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

41 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14794.0001

1.14794.0001

1.14794.0001

1.00857.0001

1.00857.0001

1.00857.0001

1.00857.0001

1.01813.0001

Program name

Silicate14794

Silicate14794

Silicate14794

Silicate00857

Silicate00857

Silicate00857

Silicate00857

Silicate01813

mg/l

mg/l

mg/l

Mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

665 nm

665 nm

820 nm

410 nm

410 nm

410 nm

410 nm

820 nm

Resolution

0.01

0.01

0.001

0.1

0.1

0.0001

Chemical Form 1

SiO2

SiO2

SiO2

SiO2

SiO2

SiO2

SiO2

SiO2

Calibration a

Calibration b

8.00

3.15

0.611

59.8

23.5

603

237

1.68

Calibration c

Calibration d

Upper limit

10.70

4.21

1.600

107.0

42.1

1070

421

0.5000

Lower limit

0.21

0.08

0.010

1.1

0.4

11

0.0005

Timer 1 (mm:ss)

03:00

03:00

03:00

02:00

02:00

02:00

02:00

05:00

Timer 2 (mm:ss)

10:00

10:00

10:00

02:00

02:00

02:00

02:00

05:00

Additional Merck
information

3)

3)

3)

3)

3)

3)

3)

1)

10 mm

1 inch

50 mm

10 mm

1 inch

10 mm

1 inch

50 mm

2) cell with blank (white screw cap)

3) distilled water

Unit

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

42 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

Program name

1.14831.0001

1.14831.0001

1.00885.0001*

1.14548.0001*

1.00617.0001*

1.14564.0001*

*)

*)

*)

1.14791.0001

Silver14831

Silver14831

Sodium00885

Sulfate14548

Sulfate00617

Sulfate14564

Sulfate14791

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

550 nm

550 nm

550 nm

525 nm

525 nm

820 nm

525 nm

Resolution

0.01

0.01

Unit

Chemical Form 1

1
2-

2-

2-

2-

Ag

Ag

Na

Calibration a

Calibration b

2.22

0.874

263

256

Calibration c

Calibration d

Upper limit

3.00

1.18

300

250

500

1000

300

Lower limit

0.50

0.20

10

50

100

25

Timer 1 (mm:ss)

05:00

05:00

01:00

02:00

02:00

02:00

05:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

07:00

Additional Merck
information

1)

1)

1)

4)

4)

4)

1)

10 mm

1 inch

16 mm round

16 mm round

16 mm round

16 mm round

10 mm

Cell size used

SO4

SO4

SO4

SO4

*) Instrument-specific calibration necessary!


As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

43 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14779.0001

1.14779.0001

1.14394.0001*

1.14394.0001*

Sulfate01812

Sulfide14779

Sulfide14779

Sulfite14394

Sulfite14394

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

445 nm

445 nm

445 nm

665 nm

665 nm

410 nm

410 nm

0.1

0.1

0.01

0.01

0.001

0.1

0.1

1.01812.0001

1.01812.0001

1.01812.0001

*)

*)

*)

Sulfate01812

Sulfate01812

mg/l

Wavelength
Resolution

Program name
Unit

2-

Chemical Form 1

2-

2-

2-

2-

2-

Calibration a

0.0052

Calibration b

1.1079

0.244

8.77

7.02

Calibration c

-0.0055

Calibration d

0.1062

SO4

SO4

SO4

SO3

SO2

Upper limit

50.0

19.7

10.00

1.50

0.500

20.0

16.0

Lower limit

2.5

1.0

0.50

0.10

0.020

1.0

0.8

Timer 1 (mm:ss)

02:00

02:00

02:00

01:00

01:00

02:00

02:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

4)

4)

4)

3)

3)

2)

2)

10 mm

1 inch

50 mm

10 mm

50 mm

16 mm round

16 mm round

Cell size used

*) Instrument-specific calibration necessary!


As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

44 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14394.0001

1.14394.0001

1.01746.0001

1.01746.0001

1.14697.0001*

1.01764.0001*

1.01787.0001*

1.14622.0001*

see appendix page 48 see appendix page 48

Program name

Sulfite14394s

Sulfite14394s

Sulfite01746

Sulfite01746

Surfact.anion.
14697

Surfact.cat.
01764

Surfact.nonion.
01787

Tin14622

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

410 nm

410 nm

410 nm

410 nm

650 nm

635 nm

605 nm

665 nm

Resolution

0.01

0.01

0.1

0.1

0.01

0.01

0.01

0.01

SO2

Surfact.

CTAB

Triton X-100

Sn

Unit

2-

Chemical Form 1

SO3

SO2

2-

SO3

Calibration a

0.03

Calibration b

1.69

1.35

29.4

23.5

1.80

1.92

6.06

1.5544

Calibration c

-0.5016

Calibration d

0.147

Upper limit

3.00

2.40

60.0

48.0

2.00

1.50

7.50

2.50

Lower limit

0.05

0.04

1.0

0.8

0.05

0.05

0.10

0.10

Timer 1 (mm:ss)

02:00

02:00

02:00

02:00

10:00

05:00

02:00

15:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

1)

1)

2)

2)

2)

3)

50 mm

50 mm

10 mm

10 mm

16 mm round

16 mm round

16 mm round

16 mm round

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

45 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.14878.0001*

1.14879.0001*

1.00961.0001*

1.00961.0001*

1.00961.0001*

1.00961.0001*

1.00961.0001*

1.00961.0001*

Program name

TOC14878

TOC14879

Total hardness
00961

Total hardness
00961

Total hardness
00961

Total hardness
00961

Total hardness
00961

Total hardness
00961

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

605 nm

605 nm

565 nm

565 nm

565 nm

565 nm

565 nm

565 nm

Resolution

0.1

0.1

0.1

0.1

TOC

TOC

Ca

CaCO3

CaO

Calibration a

-22.354

-55.594

-31.296

-3.1296

-3.8748

-5.5594

Calibration b

-64.5

-645

339.98

849.94

475.97

47.597

59.261

84.994

Calibration c

-195.26

-489.08

-273.36

-27.336

-33.641

-48.908

Calibration d

69.671

175.17

97.54

9.754

11.864

17.517

Upper limit

80.0

800

215

538

301

30.1

37.6

53.8

Lower limit

5.0

50

13

0.7

0.9

1.3

Timer 1 (mm:ss)

-----

-----

03:00

03:00

03:00

03:00

03:00

03:00

Timer 2 (mm:ss)

-----

-----

-----

-----

-----

-----

-----

-----

Additional Merck
information

1)

1)

3)

3)

3)

3)

3)

3)

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

Unit

Chemical Form 1

Cell size used

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!

Date: January 15, 2013

46 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Merck order no.

1.01763.0001*

1.01749.0001*

1.01749.0001*

1.01809.0001*

1.01809.0001*

1.00861.0001*

1.14566.0001*

1.14832.0001

Program name

Volatile
Org.Acids01763

Volatile
Org.Acids01749

Volatile
Org.Acids01749

Volatile
Org.Acids01809

Volatile
Org.Acids01809

Zinc00861

Zinc14566

Zinc14832

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

mg/l

Wavelength

495 nm

500 nm

500 nm

500 nm

500 nm

500 nm

500 nm

565 nm

Resolution

0.001

0.01

0.01

HOAc

HOAc

Butyric acid

HOAc

Butyric acid

Zn

Zn

Zn

Calibration a

Calibration b

1430

1841

2486

1841

2486

1.36

4.88

1.08

Calibration c

Calibration d

Upper limit

3000

3000

4401

3000

4401

1.000

5.00

2.50

Lower limit

50

50

73

50

73

0.025

0.20

0.05

Timer 1 (mm:ss)

03:00

01:00

01:00

01:00

01:00

15:00

15:00

03:00

Timer 2 (mm:ss)

10:00

-----

-----

-----

-----

-----

-----

02:00

Additional Merck
information

1)

1)

1)

1)

1)

1)

2)

3)

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

16 mm round

10 mm

Unit

Chemical Form 1

Cell size used

As blank can be used: 1) own blank (= distilled water and reagents)

2) cell with blank (white screw cap)

3) distilled water

4) clear sample without reagents

* Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesnt allow tests!
Date: January 15, 2013

47 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange
Appendix:
Measuring range with appendix
Each test kit contains a package insert with detailed information regarding the standard procedure of the measurement. In some cases, however, special points have to
be considered which are not mentioned in the package inserts.
In this appendix you will find specific applications and modified methods for analyses for sensitive measurements indicated with see appendix page 47.

Calcium: with Spectroquant Calcium Test, Cat. No. 1.14815.0001


Measuring range:
1.0 15.0 mg/L Ca
2.5 37.5 mg/L CaCO3
1.4 21.0 mg/L CaO
Procedure: Add 10 ml of reagent Ca-1A and 8 drops each of reagent Ca-2A and Ca-3A to 1 ml of the sample solution and mix. Leave to stand for 8 min for colour
development. After filling into 10 mm cells measure in the photometer at 550 nm. Prepare the blank required for the measurement according to the above-mentioned
procedure using 1 ml of distilled water instead of the sample solution.

Fluoride: with Spectroquant Fluoride Cell Test, Cat. No. 1.14557.0001


Measuring range: 0.025 0.500 mg/l F
Procedure: Pipette 10 ml of sample solution into the reaction cell, mix and add 1 blue microspoon of reagent F-1K. Close the cell tightly and dissolve the solid by
shaking. Leave to stand for 5 min for colour development. After filling into 50 mm cells measure in the photometer at 620 nm. Prepare the blank required for the
measurement according to the above-mentioned procedure using 10 ml of distilled water instead of the sample solution.

Fluoride: with Spectroquant Fluoride Cell Test, Cat. No. 1.00809.0001


Measuring range: 0.025 0.500 mg/l F
Procedure: Pipette 10 ml of sample solution into the reaction cell, mix and add 1 blue microspoon of reagent F-1K. Close the cell tightly and dissolve the solid by
shaking. Leave to stand for 15 min for colour development. After filling into 50 mm cells measure in the photometer at 620 nm. Prepare the blank required for the
measurement according to the above-mentioned procedure using 10 ml of distilled water instead of the sample solution

Hydrogen peroxide: with Spectroquant Hydrogen peroxide Cell Test, Cat. No. 1.14731.0001
Measuring range: 0.25
5.00
mg/l H2O2
Procedure: The test method of the package insert can be used without any alteration. After filling into 50 mm cells measure in the photometer at 410 nm
Date: January 15, 2013

48 of 49

Programming data for Spectroquant Test Kits for DR 5000 and DR 6000 photometer
from Hach, Hach-Lange

Sulfite: with Spectroquant Sulfite Cell Test, Cat. No. 1.14394.0001


2Measuring range: 0.005 3.00
mg/l SO3
Procedure: Place 1 microspoon of reagent SO3-1K in the cell, close tightly and shake until the complete dissolution of the solid. Then pipette 7 ml of the sample solution
into the cell and mix. After the reaction time of 2 min fill into 50 cells and measure in the photometer at 410 nm. Prepare the blank required for the measurement
according to the above-mentioned procedure using 7 ml of distilled water instead of the sample solution.

Please contact our local Merck companies or Merck agents for any questions. Alternatively contact: environmental.analysis@merck.de.
No endorsement by Hach Company is implied or intended.

Date: January 15, 2013

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