Propiedades y composición de compuestos nitrogenados

PROPIEDADES DE COMPUESTOS
NH3
g/mol
17.031
Cp (cal/mol.K) = A + B.T + C.T2 + D.T3

Hf @ 25C
A
B
C
D
kcal/mol
6.524
0.005692
4.078E-06
-2.83E-09
-19.27
HNO3
63.013
3.146
-0.0028
0.0000156
-5.2E-10
-41.35
NH4NO3
80.043
7.487
0.000444
0.00005478
-6.7728E-07
-87.40
H2O =
NO =
NO2 =
18.015
30.006
46.005
7.701
7.009
5.788
0.0004595
2.521E-06
-0.000224
2.328E-06
0.01155 -0.00000497
-8.59E-10
-1E-09
7E-11
-68.32
21.60
7.96
O2 =
31.999
6.713
-8.79E-07
0.00000417
-2.544E-09
0.00
N2 =
28.014
7.44
-0.00324
0.0000064
-2.79E-09
0.00
985
360
523.95
775.43
TM/dia NH4NO3
das
TM/dia
TM/dia
CONDICIONES DE OPERACIN
Capacidad de produccion
Das/ao
Amoniaco
cido Ntrico (100%)
COMPOSICIN DE LAS CORRIENTES - REPORTE CHEMCAD

STREAM PROPERTIES
Stream No.
Name
- - Overall - Molar flow kmol/day
Mass flow kg/day
Temp C
Pres bar
Vapor mole fraction
Vapor mass fraction
Enth MJ/day
Entropy
MJ/C/day
Tc C
Pc bar
Std. sp gr. wtr = 1
Std. sp gr. air = 1
Degree API
Heating values (60 F)
Gross kJ/kg
Net kJ/kg
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
Vpres bar
- - Vapor only - Molar flow kmol/day
Mass flow kg/day
Enth MJ/day
Entropy
MJ/C/day
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
Cp kJ/kg-K
Cp/Cv
Cp/Cv ideal
Z factor
Visc N-s/m2
Th cond W/m-K
Rel. Humidity %
- - Liquid only - -
1
NH3 (l)
29821.829 17296.6598 12525.1679 12525.1679 17296.6598 17296.6598

507896 294579.413 213316.143 213316.143 294579.413 294579.413
30
30
30
30.0429
30.0429
71
11.7
11.7
11.7
12.3207
12.3207
12.0707
0
0
0
0
0
1
0
0
0
0
0
1
-1.98E+06 -1.15E+06 -8.33E+05 -8.33E+05 -1.15E+06 -7.75E+05
-5563
-3227
-2337
-2336
-3227
-1997
132.4
132.4
132.4
132.4
132.4
132.4
112.8955
112.8955
112.8955
112.8955
112.8955
112.8955
0.619
0.619
0.619
0.619
0.619
0.619
0.588
0.588
0.588
0.588
0.588
0.588
97.1314
97.1314
97.1314
97.1314
97.1314
97.1314
2.25E+04
2.25E+04
2.25E+04
2.25E+04
2.25E+04
2.25E+04
1.86E+04
1.86E+04
1.86E+04
1.86E+04
1.86E+04
1.86E+04
17.031
17.031
17.031
17.031
17.031
17.031
594.0779
594.0779
594.0779
594.0119
594.0119
7.7215
35.6221
20.6608
14.9613
14.963
20.6631 1589.6063
34.1935
19.8322
14.3613
14.3613
19.8322
19.8322
27850.6646 16153.3841 11697.2787 11697.2787 16153.3841 16153.3841
11.693
11.693
11.693
11.708
11.708
33.984
17296.6598
294579.413
-7.75E+05
-1997
17.031
7.7215
1589.6063
19.8322
16153.3841
2.3395
1.3839
1.2639
0.9306
1.20E-05
0.032
Molar flow kmol/day

Mass flow kg/day
Enth MJ/day
Entropy
MJ/C/day
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
Cp kJ/kg-K
H latent kJ/kg
Z factor
Visc N-s/m2
Th cond W/m-K
Surf tens N/m
29821.829 17296.6598 12525.1679 12525.1679 17296.6598

507896 294579.413 213316.143 213316.143 294579.413
-1.98E+06 -1.15E+06 -8.33E+05 -8.33E+05 -1.15E+06
-5563
-3227
-2337
-2336
-3227
17.031
17.031
17.031
17.031
17.031
594.0779
594.0779
594.0779
594.0119
594.0119
35.6221
20.6608
14.9613
14.963
20.6631
34.1935
19.8322
14.3613
14.3613
19.8322
27850.6646 16153.3841 11697.2787 11697.2787 16153.3841
5.0685
5.0685
5.0685
5.0679
5.0675
1144
1144
1144
1144
1144
0.015
0.015
0.015
0.0157
0.0157
0.0001249 0.0001249 0.0001249 0.0001248 0.0001248
0.4682
0.4682
0.4682
0.4681
0.4681
0.02
0.02
0.02
0.02
0.02
FLOW SUMMARIES
Stream No.
Stream Name
Temp C
Pres bar
Enth MJ/day
Vapor mole fraction
Total kmol/day
Flowrates in kmol/day
Ammonia
Oxygen
Nitrogen
Water
Nitrogen Tetroxi
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
NH4NO3
Air
1
NH3 (l)
30
30
30
30.0429
30.0429
71
11.7
11.7
11.7
12.3207
12.3207
12.0707
-1.98E+06 -1.15E+06 -8.33E+05 -8.33E+05 -1.15E+06 -7.75E+05
0
0
0
0
0
1
29821.829 17296.6598 12525.1679 12525.1679 17296.6598 17296.6598
29821.829 17296.6598 12525.1679 12525.1679 17296.6598 17296.6598
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
FLOW SUMMARIES
Stream No.
Stream Name
Temp C
Pres bar
Enth MJ/day
Vapor mass fraction
1
NH3 (l)
30
11.7
-1.98E+06
0
2
30
11.7
-1.15E+06
0
3
30
11.7
-8.33E+05
0
4
30.0429
12.3207
-8.33E+05
0
5
30.0429
12.3207
-1.15E+06
0
6
71
12.0707
-7.75E+05
1
Total kg/day
Flowrates in kg/day
Ammonia
Oxygen
Nitrogen
Water
Nitrogen Tetroxi
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
NH4NO3
Air
507896 294579.413 213316.143 213316.143 294579.413 294579.413

507896 294579.413 213316.143 213316.143 294579.413 294579.413
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
FLOW SUMMARIES
Stream No.
1
2
3
4
5
6
Stream Name
NH3 (l)
Temp C
30
30
30
30.0429
30.0429
71
Pres bar
11.7
11.7
11.7
12.3207
12.3207
12.0707
Enth MJ/day
-1.98E+06 -1.15E+06 -8.33E+05 -8.33E+05 -1.15E+06 -7.75E+05
Vapor mole fraction
0
0
0
0
0
1
Total kmol/day
29821.829 17296.6598 12525.1679 12525.1679 17296.6598 17296.6598
Component mole fractions
Ammonia
1
1
1
1
1
1
Oxygen
0
0
0
0
0
0
Nitrogen
0
0
0
0
0
0
Water
0
0
0
0
0
0
Nitrogen Tetroxi
0
0
0
0
0
0
Nitric Oxide
0
0
0
0
0
0
Nitrogen Dioxide
0
0
0
0
0
0
Nitric Acid
0
0
0
0
0
0
NH4NO3
0
0
0
0
0
0
Air
0
0
0
0
0
0
FLOW SUMMARIES
Stream No.
1
2
3
4
5
6
Stream Name
NH3 (l)
Temp C
30
30
30
30.0429
30.0429
71
Pres bar
11.7
11.7
11.7
12.3207
12.3207
12.0707
Enth MJ/day
-1.98E+06 -1.15E+06 -8.33E+05 -8.33E+05 -1.15E+06 -7.75E+05
Vapor mass fraction
0
0
0
0
0
1
Total kg/day
507896 294579.413 213316.143 213316.143 294579.413 294579.413
Component mass fractions
Ammonia
1
1
1
1
1
1
Oxygen
Nitrogen
Water
Nitrogen Tetroxi
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
NH4NO3
Air
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
FLOW SUMMARIES
Stream No.
Stream Name
Temp C
Pres bar
Enth MJ/day
Vapor mole fraction
Total kmol/day
Component mole %
Ammonia
Oxygen
Nitrogen
Water
Nitrogen Tetroxi
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
NH4NO3
Air
1
NH3 (l)
30
30
30
30.0429
30.0429
71
11.7
11.7
11.7
12.3207
12.3207
12.0707
-1.98E+06 -1.15E+06 -8.33E+05 -8.33E+05 -1.15E+06 -7.75E+05
0
0
0
0
0
1
29821.829 17296.6598 12525.1679 12525.1679 17296.6598 17296.6598
100
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
FLOW SUMMARIES
Stream No.
Stream Name
Temp C
Pres bar
Enth MJ/day
Vapor mass fraction
Total kg/day
Component mass %
Ammonia
Oxygen
Nitrogen
Water
1
NH3 (l)
30
30
30
30.0429
30.0429
71
11.7
11.7
11.7
12.3207
12.3207
12.0707
-1.98E+06 -1.15E+06 -8.33E+05 -8.33E+05 -1.15E+06 -7.75E+05
0
0
0
0
0
1
507896 294579.413 213316.143 213316.143 294579.413 294579.413
100
0
0
0
100
0
0
0
100
0
0
0
100
0
0
0
100
0
0
0
100
0
0
0
Nitrogen Tetroxi
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
NH4NO3
Air
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
Aire
10
11
12
13
14
166115.473 166115.473 166115.473 166115.473 166115.473 183412.13 187736.297 187736.297

4778528.71 4778528.71 4778528.71 4778528.71 4778528.71 5073108.04 5073086.27 5073086.27
310
30
221.7784
150
295.2561
279.5204
960
750
8.2785
1.0132
4
3.75
8.5285
8.2785
9.6317
9.3817
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1.40E+06
22929
9.61E+05
6.06E+05
1.33E+06
6.27E+05
9.78E+05 -3.97E+05
1058
746.5
1244
560
887.6
-333.6
5194
4012
-142.3322 -142.3322 -142.3322 -142.3322 -142.3322 -120.1068
-85.9892
-85.9892
35.8801
35.8801
35.8801
35.8801
35.8801
36.8236
28.5173
28.5173
0.859
0.859
0.859
0.859
0.859
0.84
0.844
0.844
0.993
0.993
0.993
0.993
0.993
0.955
0.933
0.933
33.1854
33.1854
33.1854
33.1854
33.1854
36.8986
36.1463
36.1463
28.7663
28.7663
28.7663
28.7663
28.7663
4.8998
1.1571
2.7937
3.0649
5.1785
40635.4713 172067.715 71268.6748 64963.844 38448.5683
231.73
231.73
231.73
231.73
231.73
155135.571 155135.571 155135.571 155135.571 155135.571
166115.473
4778528.71
1.40E+06
1058
28.7663
4.8998
40635.4713
231.73
155135.571
1.059
1.3798
1.3757
1.0026
2.99E-05
0.0448
166115.473
4778528.71
22929
746.5
28.7663
1.1571
172067.715
231.73
155135.571
1.016
1.4002
1.3979
0.9995
1.85E-05
0.0258
1307
1080
-226.1
-226.1
27.6596
27.0224
27.0224
4.9747
2.5336
2.9737
42490.7663 83430.0809
71082.35
251.5622
250.4375
250.4375
171288.945 175327.295 175327.295
166115.473 166115.473 166115.473 183412.13 187736.297 187736.297

4778528.71 4778528.71 4778528.71 5073108.04 5073086.27 5073086.27
9.61E+05
6.06E+05
1.33E+06
6.27E+05
9.78E+05 -3.97E+05
1244
560
887.6
-333.6
5194
4012
28.7663
28.7663
28.7663
27.6596
27.0224
27.0224
2.7937
3.0649
5.1785
4.9747
2.5336
2.9737
71268.6748 64963.844 38448.5683 42490.7663 83430.0809
71082.35
231.73
231.73
231.73
251.5622
250.4375
250.4375
155135.571 155135.571 155135.571 171288.945 175327.295 175327.295
1.0396
1.0285
1.056
1.1421
1.3136
1.2678
1.3884
1.3953
1.3817
1.3629
1.3066
1.3215
1.3854
1.3912
1.3772
1.3575
1.3061
1.3207
1.001
1.0006
1.0026
1.0018
1.0021
1.0023
2.66E-05
2.38E-05
2.93E-05
2.80E-05
4.84E-05
4.26E-05
0.0391
0.0344
0.0439
0.045
0.0876
0.0742
0.0035
0.0205
8
Aire
10
11
310
30
221.7784
150
295.2561
8.2785
1.0132
4
3.75
8.5285
1.40E+06
22929
9.61E+05
6.06E+05
1.33E+06
1
1
1
1
1
166115.473 166115.484 166115.473 166115.473 166115.473
12
13
14
279.5204
960
750
8.2785
9.6317
9.3817
6.27E+05
9.78E+05 -3.97E+05
1
1
1
183412.13 187736.297 187736.297
0
0
0
0
0 17296.6598
0
0
31360.0733 31360.0733 31360.0733 31360.0733 31360.0733 31360.0733 9739.2486 9739.2486
134755.397 134755.397 134755.397 134755.397 134755.397 134755.397 134755.397 134755.397
0
0
0
0
0
0
25945
25945
0
0
0
0
0
0
0
0
0
0
0
0
0
0 17296.6598 17296.6598
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
310
8.2785
1.40E+06
1
8
Aire
30
1.0132
22929
1
9
221.7784
4
9.61E+05
1
10
150
3.75
6.06E+05
1
11
295.2561
8.5285
1.33E+06
1
12
279.5204
8.2785
6.27E+05
1
13
960
9.6317
9.78E+05
1
14
750
9.3817
-3.97E+05
1
4778528.71 4778528.71 4778528.71 4778528.71 4778528.71 5073108.04 5073086.27 5073086.27

0
0
0
0
0 294579.413
0
0
1003490.96 1003490.96 1003490.96 1003490.96 1003490.96 1003490.96 311646.216 311646.216
3775037.58 3775037.58 3775037.58 3775037.58 3775037.58 3775037.58 3775037.58 3775037.58
0
0
0
0
0
0
467399
467399
0
0
0
0
0
0
0
0
0
0
0
0
0
0
519004
519004
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
Aire
10
11
12
310
30
221.7784
150
295.2561
8.2785
1.0132
4
3.75
8.5285
1.40E+06
22929
9.61E+05
6.06E+05
1.33E+06
1
1
1
1
1
166115.473 166115.484 166115.473 166115.473 166115.473
0
0.188785
0.811215
0
0
0
0
0
0
0
0
0.188785
0.811215
0
0
0
0
0
0
0
8
Aire
0
0.188785
0.811215
0
0
0
0
0
0
0
0
0.188785
0.811215
0
0
0
0
0
0
0
10
0
0.188785
0.811215
0
0
0
0
0
0
0
11
13
14
279.5204
960
750
8.2785
9.6317
9.3817
6.27E+05
9.78E+05 -3.97E+05
1
1
1
183412.13 187736.297 187736.297
0.094305
0.170981
0.734714
0
0
0
0
0
0
0
12
0
0.051877
0.717791
0.138199
0
0.092133
0
0
0
0
13
0
0.051877
0.717791
0.138199
0
0.092133
0
0
0
0
14
310
30
221.7784
150
295.2561
279.5204
960
750
8.2785
1.0132
4
3.75
8.5285
8.2785
9.6317
9.3817
1.40E+06
22929
9.61E+05
6.06E+05
1.33E+06
6.27E+05
9.78E+05 -3.97E+05
1
1
1
1
1
1
1
1
4778528.71 4778528.71 4778528.71 4778528.71 4778528.71 5073108.04 5073086.27 5073086.27
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33
0
0.000168
0.423899
0
0.000015
0.001535
0.574149
0
0
34
0
0.000145
0.366081
0
0.000013
0.001325
0
0.629846
0
35
43.5323
30
30
43.6036
98
9.75
12
12
11.25
11.25
-1.12E+07
1.50E+05
1.50E+05 -1.12E+07 -1.34E+07
6.81E-05
1
1
4.76E-05 0.00036572
44157.7647 140530.121 140530.121 44157.7647 44377.0385
0.042037
0
0.01834
71.968073
0
0.001499
0.102024
27.868024
0
0
31
0.127069
0
95.890725
0.436279
0
3.064651
0.003571
0.477707
0
0
32
Gases
0.127069
0
95.890725
0.436279
0
3.064651
0.003571
0.477707
0
0
33
0.042037
0
0.01834
71.968073
0
0.001499
0.102024
27.868024
0
0
34
0.53594
0
0.018249
71.612477
0
0.001492
0.10152
0
27.730325
0
35
0
0.004146
0.902679
0
0.000363
0.031424
0
0
0
36
0
0
0.346643
0
0
0.000235
0
0.652661
0
37
0
0
0.346643
0
0
0.000235
0
0.652661
0
38
180
180
180.1127
10.95
10.95
12.45
-6.58E+05 -1.25E+07 -1.25E+07
1
0
0
2982.5437 41394.4942 41394.4942
6.607183
0
0.271256
91.847336
0
0.022174
1.252042
0
0
0
36
0.098497
0
0.00002
70.154518
0
0.000002
0.018623
0
29.728341
0
37
0.098497
0
0.00002
70.154518
0
0.000002
0.018623
0
29.728341
0
38
43.5323
30
30
43.6036
98
180
180
180.1127
9.75
12
12
11.25
11.25
10.95
10.95
12.45
-1.12E+07
1.50E+05
1.50E+05 -1.12E+07 -1.34E+07 -6.58E+05 -1.25E+07 -1.25E+07
6.33E-05
1
1
4.41E-05 0.00051553
1
0
0
1350574.43 3960884.35 3960884.35 1350574.43 1563880.75 54670.6556 1509210.17 1509210.17
0.023408
0
0.016798
42.389929
0.076781
0
95.307922
0.278854
0.076781
0
95.307922
0.278854
0.023408
0
0.016798
42.389929
0.259007
0
0.014507
36.608136
6.138878
0
0.41456
90.267903
0.04601
0
0.000015
34.664327
0.04601
0
0.000015
34.664327
0
0.001471
0.15346
57.414937
0
0
0
3.262619
0.005829
1.067994
0
0
0
3.262619
0.005829
1.067994
0
0
0
0.001471
0.15346
57.414937
0
0
0
0.00127
0.132529
0
62.984556
0
0
0.036298
3.142364
0
0
0
0
0.000001
0.023499
0
65.266144
0
0
0.000001
0.023499
0
65.266144
0
39
Aire
40
Aire
41
42
NH4NO3
45
46
47
Vapor
48
Vapor
222028
251007 12415.6519 12415.6519 140530.121 140530.089 10204.1832 10204.1832
6427930.73 6950159.56
986982
986982 3960884.35 3960885.37 183828.358 183828.358
300
142.6453
80
40
114.4731
437.0412
184
175
7
7
7
6.75
12
12
10
10
1
1
0
0
1
1
1
0
1
1
0
0
1
1
1
0
1.79E+06 -6.14E+06 -4.53E+06 -4.53E+06
504090
1880000 -2.43E+06 -2.80E+06
685.1
-2337
-16.49
-17.48
-1718
858.3
-515.5
-1346
-140.7
-97.9713
373.6722
373.6722 -140.8089 -140.8088
374.1333
374.1333
37.74
28.3437
220.5485
220.5485
35.9759
35.9759
220.8978
220.8978
0.862
0.871
5.552
5.552
0.814
0.814
1
1
1
0.956
2.745
2.745
0.973
0.973
0.622
0.622
32.6531
30.9574 -106.0123 -106.0123
42.247
42.2469
10
10
28.951
4.246
63077.85
310.7086
207352.318
2.241
1865
1865
11.95
11.95
-182.2
752.6
752.6
-1.656
-1.66
27.6891
79.4949
79.4949
28.1853
28.1853
5.6214 5549.8447 5551.1831
10.4854
5.7056
51515.9966
7.41
7.4082 15739.6608 28925.2889
332.4812
7.4075
7.4075
202.648
202.648
234415.719 11595.0018 11595.0018 131241.349 131241.321
1.157
1.475
222028
251007
6427930.73 6950159.56
1.79E+06 -6.14E+06
685.1
-2337
28.951
27.6891
4.246
5.6214
63077.85 51515.9966
310.7086
332.4812
207352.318 234415.719
1.0432
1.0883
1.3838
1.3928
1.3802
1.3813
1.0017
0.9975
2.94E-05
2.25E-05
0.0441
0.034
20.7554
140530.121
3960884.35
504090
-1718
28.1853
10.4854
15739.6608
202.648
131241.349
1.0578
1.4044
1.387
1.001
2.16E-05
0.0319
3.1525
-2454
18.015
4.9944
1533.6277
7.6595
9529.7064
10.975
140530.089 10204.1832
3960885.37 183828.358
1880000 -2.43E+06
858.3
-515.5
28.1853
18.015
5.7056
4.9944
28925.2889 1533.6277
202.648
7.6595
131241.321 9529.7064
1.1085
2.6013
1.3667
1.3946
1.3629
1.2158
1.004
0.9491
3.31E-05
1.57E-05
0.0521
0.0333
0.0122
91.19
-2454
18.015
892.0089
8.5868
7.6595
9529.7064
8.918
109.7552
1977.8895
-30895
-16.49
18.021
970.3701
0.0849
0.0825
102.5006
4.2076
2312
0.0053
0.0003571
0.6626
0.0621
39
Aire
109.7552
1977.8895
-31227
-17.48
18.021
991.2178
0.0831
0.0825
102.5006
4.1881
2402
0.0056
0.0006767
0.6249
0.0693
10204.1832
183828.358
-2801300
-1346
18.015
892.0089
8.5868
7.6595
9529.7064
4.4312
2037
0.0066
0.0001523
0.6786
0.0434
300
7
1.79E+06
1
222028
40
41
42
45
46
47
48
Aire
NH4NO3
Vapor
Vapor
142.6453
80
40
114.4731
437.0412
184
175
7
7
6.75
12
12
10
10
-6.14E+06 -4.53E+06 -4.53E+06
504090
1880000 -2.43E+06 -2.80E+06
1
0
0
1
1
1
0
251007 12415.6519 12415.6519 140530.121 140530.089 10204.1832 10204.1832
0
0
0
0
0
0
0
0
0
222028
40.6184
0.1538
0.1538
178.5696
178.5215
0
0
0
0
0
0
0
0
0
0.0081
0
0 134755.355 134755.344
0
0
28930.536
109.5728
109.5728
613.104
613.088 10204.1832 10204.1832
0
0
0
0
0
0
0
0.0007
0
0 4306.7572 4306.7313
0
0
7.6797
0.0291
0.0291
5.0185
5.0819
0
0
0
0
0
671.3218
671.33
0
0
0 12305.8968 12305.8968
0
0
0
0
222028
0
0
0
0
0
0
39
Aire
300
7
1.79E+06
1
40
Aire
142.6453
7
-6.14E+06
1
41
80
7
-4.53E+06
0
42
NH4NO3
40
6.75
-4.53E+06
0
45
114.4731
12
504090
1
46
437.0412
12
1880000
1
47
Vapor
184
10
-2.43E+06
1
48
Vapor
175
10
-2.80E+06
0
6427930.73 6950159.56
986982
986982 3960884.35 3960885.37 183828.358 183828.358
0
691.7721
0
0
0
0.2273
0
521184
0
0
0
0.0201
0
353.3056
0
0
0
0
6427930.73 6427930.73
2.62
0
0.0009
1973.9547
0
0.0001
1.3381
0
985004
0
2.62 3041.2186
3040.4
0
0
0
0
0
0
0
0.0009 3775036.56 3775036.22
0
0
1973.9547 11045.069 11044.7793 183828.358 183828.358
0
0
0
0
0
0.0001 129228.558 129227.782
0
0
1.3381
230.8744
233.7941
0
0
0 42302.0023 42302.5179
0
0
985004
0
0
0
0
0
0
0
0
0
39
Aire
300
7
1.79E+06
1
222028
40
41
42
45
46
47
48
Aire
NH4NO3
Vapor
Vapor
142.6453
80
40
114.4731
437.0412
184
175
7
7
6.75
12
12
10
10
-6.14E+06 -4.53E+06 -4.53E+06
504090
1880000 -2.43E+06 -2.80E+06
1
0
0
1
1
1
0
251007 12415.6519 12415.6519 140530.121 140530.089 10204.1832 10204.1832
0
0
0
0
0
0
0
0
0
1
0.000162
0
0
0.115258
0
0
0.000031
0
0
0.884549
300
7
1.79E+06
1
6427930.73
40
Aire
142.6453
7
-6.14E+06
1
6950159.56
80
7
-4.53E+06
0
986982
0.0001
0.000003
39
Aire
0.000012
0
0
0.008825
0
0
0.000002
0
0.99116
0
41
0.000012
0
0
0.008825
0
0
0.000002
0
0.99116
0
0.001271
0
0.958907
0.004363
0
0.030647
0.000036
0.004777
0
0
0.00127
0
0.958907
0.004363
0
0.030646
0.000036
0.004777
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
42
45
46
47
48
NH4NO3
Vapor
Vapor
40
114.4731
437.0412
184
175
6.75
12
12
10
10
-4.53E+06
504090
1880000 -2.43E+06 -2.80E+06
0
1
1
1
0
986982 3960884.35 3960885.37 183828.358 183828.358
0.000003
0.000768
0.000768
0
0
0
0
0
0
0
0
1
39
Aire
300
7
1.79E+06
1
222028
0
0
0.074989
0
0
0.000051
0
0
0.924861
0
0
0.002
0
0
0.000001
0
0.997996
0
0
0.953079
0.002789
0
0.032626
0.000058
0.01068
0
0
0
0.953079
0.002788
0
0.032626
0.000059
0.01068
0
0
0
0
1
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
40
41
42
45
46
47
48
Aire
NH4NO3
Vapor
Vapor
142.6453
80
40
114.4731
437.0412
184
175
7
7
6.75
12
12
10
10
-6.14E+06 -4.53E+06 -4.53E+06
504090
1880000 -2.43E+06 -2.80E+06
1
0
0
1
1
1
0
251007 12415.6519 12415.6519 140530.121 140530.089 10204.1832 10204.1832
0
0
0
0
0
0
0
0
0
100
0.016182
0
0.000003
11.525799
0
0
0.00306
0
0
88.45495
300
7
1.79E+06
1
6427930.73
40
Aire
142.6453
7
-6.14E+06
1
6950159.56
80
7
-4.53E+06
0
986982
0
0
0
0
0.009953
0
0.000003
7.498872
0.000265
0
0
0.199999
39
Aire
0
0
0.002
0
0
0.000001
0
0.997996
0
0.001239
0
0
0.882538
0
0
0.000234
0
99.115992
0
41
0.001239
0
0
0.882538
0
0
0.000234
0
99.115992
0
0.127069
0
95.890725
0.436279
0
3.064651
0.003571
0.477707
0
0
0.127034
0
95.890743
0.436268
0
3.064633
0.003616
0.477713
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
42
45
46
47
48
NH4NO3
Vapor
Vapor
40
114.4731
437.0412
184
175
6.75
12
12
10
10
-4.53E+06
504090
1880000 -2.43E+06 -2.80E+06
0
1
1
1
0
986982 3960884.35 3960885.37 183828.358 183828.358
0.000265
0
0
0.199999
0.076781
0
95.307922
0.278854
0.076761
0
95.307887
0.278846
0
0
0
100
0
0
0
100
0
0
0
0
0
99.999994
0
0
0.005083
0
0
92.486084
0
0
0.000136
0
99.799597
0
0
0
0.000136
0
99.799597
0
0
3.262619
0.005829
1.067994
0
0
0
3.262598
0.005903
1.068007
0
0
0
0
0
0
0
0
0
0
0
0
0
0
49
Gases
140530.089
3960885.37
420.0316
12
1
1
1.81E+06
752
-140.8088
35.9759
0.814
0.973
42.2469
11.95
-1.66
28.1853
5.8455
28233.1438
202.648
131241.321
140530.089
3960885.37
1.81E+06
752
28.1853
5.8455
28233.1438
202.648
131241.321
1.1043
1.3687
1.3648
1.0041
3.26E-05
0.0511
0.0145
49
Gases
420.0316
12
1.81E+06
1
140530.089
178.5215
0
134755.344
613.088
0
4306.7313
5.0819
671.33
0
0
49
Gases
420.0316
12
1.81E+06
1
3960885.37
3040.4
0
3775036.22
11044.7793
0
129227.782
233.7941
42302.5179
0
0
49
Gases
420.0316
12
1.81E+06
1
140530.089
0.00127
0
0.958907
0.004363
0
0.030646
0.000036
0.004777
0
0
49
Gases
420.0316
12
1.81E+06
1
3960885.37
0.000768
0
0.953079
0.002788
0
0.032626
0.000059
0.01068
0
0
49
Gases
420.0316
12
1.81E+06
1
140530.089
0.127034
0
95.890743
0.436268
0
3.064633
0.003616
0.477713
0
0
49
Gases
420.0316
12
1.81E+06
1
3960885.37
0.076761
0
95.307887
0.278846
0
3.262598
0.005903
1.068007
0
0
PLANTA DE CIDO NTRICO

Base = 1 da
OXIDACION DE AMONIACO
Condiciones de Reaccin:
P=
10
T=
950
R=
0.082
(Patente US 3,634,031)
bar
C
atm.l/mol.K
Eficiencia de reaccin:
NH3
H2O
O2
N2
NO
TOTAL
4NH3 + 5O2 4NO+6H2O
V (NH3) =
V (Aire) =
100%
Ingreso
kmol
18,458.78
23,073.48
127,831.95
-
Salida
tm
314.37
738.33
3,581.08
4,633.78
kmol
27,688.17
1,393.23
127,831.95
18,458.78
tm
498.80
44.58
3,581.08
553.87
4,678.34
182,842.67
1,645,584.03
345,572.65
1,300,011.39
m3 NH3
m3 Aire
m3 O2
m3 N2
1,087.35 tm
3,581.08 tm
4,668.43 4,668,431.00
Clculo de mezcla de aire:

% Vol NH3 mezcla < 12%
% Vol NH3 =
10.0% (Patente US 3,634,031)
% Vol Aire =
90.0%
% O2 =
738,328.22
% N2 =
3,581,084.32
Mw mezcla =
27.67
Densidad =
2.72 kg/m3
Nota: De acuerdo a condiciones de trabajo, se considera que el amoniaco es comprado como materia prima (no se considera el diseo del
proceso de obtencin a partir de gas natural).
OBTENCIN DE DIOXIDO DE NITROGENO
Ingreso
kmol
NO2
H2O
N2
O2
NO
TOTAL
27,688.17
167,490.99
9,229.39
18,458.78
PRODUCCION HNO3 (dil)
NO2
H2O
N2
HNO3
NO
TOTAL
Ingreso
kmol
18,458.78
34,848.60
167,490.99
-
tm
498.80
4,692.09
295.33
553.87
6,040.10
tm
849.20
627.80
4,692.09
6,169.09
2NO + O2 2NO2
Salida
kmol
tm
18,458.78
849.20
27,688.17
498.80
167,490.99
4,692.09
6,040.09
3NO2 + H2O 2HNO3 + NO

Salida
kmol
tm
369.18
16.98
28,695.67
516.95
167,490.99
4,692.09
12,305.85
775.43
6,152.93
184.62
6,186.08
0
0.082581813
0.776823587
0.048895095
0.091699505
1.49
21.75
1.56
2.75
27.55
PLANTA DE NITRATO DE AMONIO

Base = 1 da
NH3 + HNO3 NH4NO3
Reaccin:
Conc. NH3
Conc. HNO3
Conc. NH4NO3
Capacidad =
985.00 TM/dia NITRATO DE AMONIO, NH4NO3
Eficiencia de la reaccin =
99.65% Patente US 4,174,379
NH3
HNO3
H2O
NH4NO3
TOTAL
Ingreso
kmol
12,305.85
12,305.85
28,695.67
-
tm
209.58
775.43
516.95
1,501.96
Salida
kmol
43.07
28,695.67
12,305.85
99.99% Concentracin comercial

60.00% Patente US 3,634,031
83.01% Patente US 3,579,298
tm
0.73
516.95
985.00
1,502.69
0.139538123
0.516277126
0.344184751
0
2.376473771
32.53217056
6.195325515
41.10396984
21%
79%
PLANTA DE CIDO NTRICO

Clculo de la entalpa de reaccin:
Se calcular empleando la siguiente ecuacin:
T ref =
298.15 K
1)OXIDACION DE AMONIACO
T=
1223.15 K
Coeficiente
NH3
O2
NO
H2O
4
5
4
6
Hr =
kcal/mol
Hf @ 25C
-19.27
0
21.60
-68.32
40,139.03
2)OBTENCIN DE DIOXIDO DE NITROGENO

T=
Cp (prom)
11.46
7.66
7.76
9.25
REACCIN ENDOTRMICA
334,047,912 MJ
2NO + O2 2NO2
473.15 K
Coeficiente
NO
O2
NO2
Hr =
kcal/mol
Hf @ 25C
2
21.60
1
0
2
7.96
27,688.17
3)PRODUCCION HNO3 (dil)
kcal/mol.K
Cp @ 200C
7.32
7.38
10.15
Cp @ 25C
7.12
7.02
8.79
-499.41 kcal/mol
Reaccionan (kmol) =
NO2
H2O
kcal/mol.K
Cp @ 950C
14.41
8.30
8.39
10.46
Cp @ 25C
8.51
7.02
7.12
8.04
1987.74 kcal/mol
Reaccionan (kmol) =
T=
4NH3 + 5O2 4NO+6H2O
Cp (prom)
7.22
7.20
9.47
REACCIN EXOTRMICA
57,894,236 MJ
3NO2 + H2O 2HNO3 + NO
331.15 K
kcal/mol
Coeficiente
Hf @ 25C
3
7.96
1
-68.32
Cp @ 25C
8.79
8.04
kcal/mol.K
Cp @ 58C
9.07
8.10
Cp (prom)
8.93
8.07
HNO3
NO
2
1
-41.35
21.60
Hr =
-16735.31 kcal/mol
Reaccionan (kmol) =
24,242.53
3.68
7.12
3.91
7.15
3.80
7.14
REACCIN ENDOTRMICA
1,698,610,865 MJ
PLANTA DE NITRATO DE AMONIO

NH3 + HNO3 NH4NO3
Reaccin:
T=
323.15 K
Coeficiente
NH3
HNO3
NH4NO3
Hr =
Reaccionan (kmol) =
1
1
1
kcal/mol
-68.3174 Cp @ 25C
-19.27
8.51
-41.35
3.68
-87.40 5.46 -
-6442.00 kcal/mol
24,568.64
kcal/mol.K
Cp @ 323C
Cp (prom)
8.69
8.60
3.85
3.77
9.50 7.48
REACCIN EXOTRMICA
662,650,125 MJ
=
=
-323.50
-77.08
80038.00
77803.84
=
=
15.92
43.20
3314.39
3786.52
=
=
-61.10
-44.44
12236
28954.95
=
=
-87.40
-60.62
-2418.07
3997.16
COMPRESORES
Se seleccionar el tipo de compresor a utilizar, a partir de la siguiente figura:
Compresor
G-100
Fluido
Aire
Temperatura
30
P ingreso
1.0
P salida
4.0
Cp/Cv =
1.40
a=
0.29
Flujo
155,136
A partir de la fugura:
Eficiencia
C =
bar =
bar =
m3/h =
86 F
14.70 psi
58.02 psi
91,309 SCFM
COMPRESOR CENTRIFUGO
80% (Heuristic in Chemical Enginering)
Potencia:
Potencia:
THP = [(SCFM)t1/8130a][(P2/P1)^a-1]
5,003.74 hp
3,731.29 kw
Compresor
G-110
Fluido
Aire
Temperatura
P ingreso
150 C =
3.8 bar =
(Heuristic in Chemical Enginering)
302 F
54.39 psi
P salida
Cp/Cv =
a=
Flujo
8.5 bar =
1.40
0.29
155,136 m3/h =
A partir de la fugura:
Eficiencia
Potencia:
Potencia:
123.70 psi
91,309 SCFM
COMPRESOR CENTRIFUGO
THP = [(SCFM)t1/8130a][(P2/P1)^a-1]
15,011.55 hp
11,194.11 kw
BOMBAS
Para la seleccin de bombas se usar los siguientes grficos:
Bomba
P-100
Fluido
Temperatura
P ingreso
P salida
Head
Flujo
Amoniaco lquido
30 C
11.7 bar =
12.3 bar =
10.65 m =
20.66 m3/h =
A partir de las fuguras:

Eficiencia
169.69
178.70
35.0
91.0
psi
psi
pies
GPM
BOMBA CENTRIFUGA - ETAPA SIMPLE

Potencia:
Potencia:
HP = (gpm)(psi)/(1174)(eficiencia)
1.55 hp
1.16 kw
Bomba
P-110
Fluido
Temperatura
P ingreso
P salida
Head
Flujo
Amoniaco lquido
30 C
11.7 bar =
12.3 bar =
10.65 m =
14.96 m3/h =

Eficiencia
169.69
178.70
35.0
65.9
psi
psi
pies
GPM

Potencia:
Potencia:
1.12 hp
0.84 kw
Bomba
P-120
Fluido
Temperatura
P ingreso
P salida
cido Ntrico 7%
47 C
8.9 bar =
10.1 bar =
128.82 psi
146.22 psi
Head
Flujo
12.08 m =
20.75 m3/h =

Eficiencia

Potencia:
Potencia:
3.01 hp
2.24 kw
Bomba
P-130
Fluido
Temperatura
P ingreso
P salida
Head
Flujo
Agua cida
44
2.0
8.3
63.21
28.45

Eficiencia
C
bar =
bar =
m =
m3/h =
29.01
119.66
207.4
125.2
psi
psi
pies
GPM

21.49 hp
16.03 kw
Bomba
P-140
Fluido
Temperatura
P ingreso
P salida
Head
Flujo
cido Ntrico 48%

47 C
8.3 bar =
9.8 bar =
13.02 m =
36.06 m3/h =
Potencia:
Potencia:
Potencia:
Potencia:
Eficiencia
39.6 pies
91.4 GPM
119.66
141.41
42.7
158.8
psi
psi
pies
GPM

6.54 hp
4.88 kw
Bomba
P-150
Fluido
Temperatura
P ingreso
P salida
Head
Flujo
cido Ntrico 86%

30 C
12.0 bar =
13.5 bar =
13.02 m =
9.95 m3/h =

Eficiencia
174.05
195.80
42.7
43.8
psi
psi
pies
GPM

Potencia:
Potencia:
1.80 hp
1.35 kw
Bomba
P-200
Fluido
Temperatura
P ingreso
P salida
Head
Flujo
cido Ntrico 57%

44 C
9.8 bar =
11.3 bar =
12.52 m =
46.39 m3/h =

Eficiencia
141.41
163.17
41.1
204.2
psi
psi
pies
GPM

Potencia:
Potencia:
8.41 hp
6.27 kw
Bomba
P-210
Fluido
Temperatura
P ingreso
P salida
Head
Flujo
Nitrato de amonio 65%

180 C
11.0 bar =
12.5 bar =
7.94 m =
32.06 m3/h =
158.82
180.57
26.0
141.1
psi
psi
pies
GPM
Eficiencia
Potencia:
Potencia:

5.81 hp
4.33 kw
INTERCAMBIADORES DE CALOR
Vaporizador
E-100
Tube Side = NH3

Shell Side = Vapor
o
Q = h2 - h1
347
14,837 M Btu/hr
2 o
200 Btu/hr - Ft - F
m NH3 =
h1 (NH3) =
h2 (NH3) =
Q=
Heat Transfer Area required
1
2
o
231 F =
1
o
304 F
2
243.87 Ft =
1.25
1.00
2
305 Ft =
10 bar, Saturated Steam Req'd,
16,899 lbs/hr =
T in, Cold Side (t1)
86
T out, Cold Side (t2)
160
T in, Hot Side (T1)
363
T out, Hot Side (T2)

Exchanger Heat Duty
Overall U, estimated
Clculo Transferencia de calor:
12,274
-47,950
-32,296

Number of shell passes
Number of tube passes
Log Mean Temperature Difference, LMTD
F Factor (see below)
Adjusted LMTD
Heat Transfer Area calculated
Design contingency factor
Over-design allowance
Calculation of F Factor:
P (or S)
R
Term 1
Px
Term 2
Term 3
Term 4A
Term 4B
Term 4
F
111 C
22.66 m2
28.32 m2
7665 kg/h
0.27
0.22
(1/N)
1.28 [(RP-1)/(P-1)]
0.27
0.5/(R-1)
-1.31 (R^2+1)
-0.25
0.78
9.10
7.10
0.25
1
Tube OD
BWG
Tube ID, d =
Tube Length, L =
15,654
0.75
16
0.620
20
in.
in.
ft.
6.1 m
Flow area per tube, at =
0.302
in.2
Effective transfer area per tube =

Area / foot length=
3.927
0.1963
ft2
ft2
Tubes/pass =
Enfriador
78
E-110
Tube Side = Aire

Shell Side = Gas residual
86
363
T in, Hot Side (T1)
431

Q = h2 - h1
302 F
13,998 M Btu/hr
2 o
5 Btu/hr - Ft - F

Exchanger Heat Duty
m Aire =
h1 (Aire) =
h2 (Aire) =
199,105
40,032
25,263

F Factor
Adjusted LMTD
1
2
o
128 F =
1
o
128 F
2
21,862.16 Ft =
1.25
1.00
2
27,328 Ft =
Tube OD
BWG
Tube ID, d =
Tube Length, L =
Q=
14,768
53 C
2031.06 m2
2538.83 m2
0.75
16
0.620
45
in.
in.
ft.
13.7 m
0.302
in.2

Area / foot length=
8.836
0.1963
ft2
ft2
Tubes/pass =
Condensador
3093
E-111
Tube Side = Tope torre absorcin

Shell Side = Agua de enfriamiento (CW)
77
95
T in, Hot Side (T1)
116
86
Q = (h2+h3) - h1
m Gases =
343,987
Exchanger Heat Duty

18,800 M Btu/hr
2 o
150 Btu/hr - Ft - F

F Factor
Adjusted LMTD
1
2
o
14 F =
1
o
14 F
2
8,862.11 Ft =
1.25
1.00
2
11,078 Ft =
Agua enfriamiento @ 25C
h1 (Gases) =
h2 (Tope) =
h3 (Fondo) =
Q=
-32,723
12,471
-65029
19,835
-10 C
823.32 m2
1029.15 m2
17 gpm =
4 m3/h
Tube OD
BWG
Tube ID, d =
Tube Length, L =
0.75
16
0.620
32
in.
0.302
in.2

Area / foot length=
6.283
0.3272
ft2
ft2
in.
ft.
9.8 m
Tubes/pass =
Precalentador
1058
E-120
Tube Side = Aire

563
590
T in, Hot Side (T1)
819

Exchanger Heat Duty

Q = h2 - h1
788 F
2,946 M Btu/hr
2 o
200 Btu/hr - Ft - F
m Aire =
h1 (Aire) =
h2 (Aire) =
1
2
o
227 F =
1
o
227 F
2
65.00 Ft =
1.25
1.00
Q=
199,105
55,313
58,421

F Factor
Adjusted LMTD
3,108
108 C
6.04 m2

10 bar, Saturated Steam Req'd,
2
81 Ft =
7.55 m2
3,356 lbs/hr =
1522 kg/h
Tube OD
BWG
Tube ID, d =
Tube Length, L =
0.75
16
0.620
20
in.
in.
ft.
6.1 m
0.302
in.2

Area / foot length=
3.927
0.1963
ft2
ft2
Tubes/pass =
Enfriador
21
E-130
Tube Side = Descarga reactor R-100

363
347
T in, Hot Side (T1)
1,760

Exchanger Heat Duty
Q = h2 - h1
m Desc R-100 =
h1 (Descarga) =
h2 (Descarga) =
1,382
13,878 M Btu/hr
2 o
5 Btu/hr - Ft - F
211,380
26,124
40,766

F Factor
Adjusted LMTD
1
2
o
1205 F =
1
o
1205 F
2
2,303.07 Ft =
1.25
1.00
2
2,879 Ft =
Q=
14,642
652 C
213.96 m2
267.45 m2
Tube OD
BWG
Tube ID, d =
Tube Length, L =
0.75
16
0.620
45
in.
0.302
in.2

Area / foot length=
8.836
0.1963
ft2
ft2
in.
ft.
13.7 m
Tubes/pass =
Aeroenfriador
326
E-140
El equipo es un mdulo que toma aire del medio y lo usa para enfriar los gases de
descarga del Reactor R-100. El equipo funciona bsicamente como un radiador.
Q = h2 - h1
m Desc R-100 =
h1 (Descarga) =
h2 (Descarga) =
Q=
T inlet =
T outlet =
211,379 kg/h
-16,562 MJ/h
-131,575 MJ/h
115,013 MJ/h
750 C
300 C
Se emplea un aeroenfriador debido a que la disminucin de temperatura de la corriente

gaseosa es de 450C.
Clculo de la potencia del equipo:
Max HP =
Fan Diam =
17 + 8.4 (Fan Diam - 3.5) =
46.40 hp
34.60 kw
7 feet
2.1 m
Tube Side = Descarga reactor R-100
Shell Side = Aire
T in, Hot Side (T1)
Exchanger Heat Duty
70
200
1,382
572 F
109,012 M Btu/hr
2 o
35 Btu/hr - Ft - F

F Factor
Adjusted LMTD
1
2
794
1
794
F=
423 C
2
3,922.42 Ft =
1.25
1.00
2
4,903 Ft =

364.40 m2
455.51 m2
Tube OD
BWG
Tube ID, d =
Tube Length, L =
0.75
16
0.620
32
in.
0.302
in.2

Area / foot length=
6.283
0.1963
ft2
ft2
in.
ft.
9.8 m
Tubes/pass =
Condensador
780
E-150
Tube Side = Gases NO/NO2

Shell Side = Agua de enfriamiento (CW)
77
95
T in, Hot Side (T1)
572
176 F
2,286,381 M Btu/hr
2 o
260 Btu/hr - Ft - F

Exchanger Heat Duty

F Factor
Adjusted LMTD
1
2
o
240 F =
1
o
240 F
2
36,580.16 Ft =
1.25
1.00
2
45,725 Ft =
116 C
3398.41 m2
4248.01 m2
29 gpm =
Tube OD
BWG
Tube ID, d =
Tube Length, L =
0.75
16
0.620
17
7 m3/h
in.
in.
ft.
5.2 m
0.302
in.2

Area / foot length=
3.338
0.1963
ft2
ft2
Tubes/pass =
13699
Enfriador
E-160
Tube Side = Descarga condensador E-150

Shell Side = Agua de enfriamiento
77
95
T in, Hot Side (T1)
176

Q = h2 - h1
104 F
41,917 M Btu/hr
2 o
53 Btu/hr - Ft - F

Exchanger Heat Duty
m Desc E-150 =
h1 (Descarga) =
h2 (Descarga) =
376,415
-233,192
-277,417

F Factor
Adjusted LMTD
1
2
o
49 F =
1
o
49 F
2
16,090.41 Ft =
1.25
1.00
2
20,113 Ft =
Q=
10 C
1494.85 m2
1868.56 m2
6 gpm =
1.3 m3/h
Tube OD
BWG
Tube ID, d =
Tube Length, L =
0.75
16
0.620
45
0.302
in.
in.2

Area / foot length=
8.836
0.1963
ft2
ft2
in.
ft.
13.7 m
Tubes/pass =
Enfriador
Tube Side = Gases cidos
E-170
44,225
2276
Shell Side = Agua de enfriamiento

77
95
T in, Hot Side (T1)
116

Exchanger Heat Duty
Q = h2 - h1
m Gases cid =
h1 (Descarga) =
h2 (Descarga) =
86
9,875 M Btu/hr
2 o
53 Btu/hr - Ft - F
357,667
334
-10,085

F Factor
Adjusted LMTD
1
2
o
14 F =
1
o
14 F
2
13,197.58 Ft =
1.25
1.00
2
16,497 Ft =
Q=
-10 C
1226.10 m2
1532.62 m2
6 gpm =
Tube OD
BWG
Tube ID, d =
Tube Length, L =
0.75
16
0.620
45
1.3 m3/h
in.
in.
ft.
13.7 m
0.302
in.2

Area / foot length=
8.836
0.3272
ft2
ft2
Tubes/pass =
Evaporador
E-210
Clculo de transferencia de energa:

h1 descarga R-200 =
h2 vapor sal =
h3 pulpa NH4NO3 =
- 559,416.67 MJ/h
- 27,422.08 MJ/h
- 519,208.33 MJ/h
q = m vapor (h1 - h2)

q=
12,786.25 MJ/h
Se asume que el vapor de agua es saturado.

Se desprecia la radiacin y subenfriamiento del condensado.
10,419
1120
La evaporacin se logra empleando Aire caliente de las siguientes caractersticas:

Aire Caliente :
(Sale del secador B-200)
P in =
T in =
Cp =
T out =
7.00
142.65
1.09
72.65
m aire =
167,840.41 kg/h
208
356
T in, Hot Side (T1)
bar
C
kJ/kg.K
C
289
163 F
12,119 M Btu/hr
2 o
250 Btu/hr - Ft - F

Exchanger Heat Duty

F Factor
Adjusted LMTD
1
2
o
56 F =
1
o
56 F
2
869.64 Ft =
1.25
1.00
2
1,087 Ft =
13 C
80.79 m2
100.99 m2
Tube OD
BWG
Tube ID, d =
Tube Length, L =
0.75
16
0.620
16
in.
0.302
in.2

Area / foot length=
3.142
0.1963
ft2
ft2
in.
ft.
4.9 m
Tubes/pass =
Aeroenfriador
346
E-220
El equipo es un mdulo que toma aire del medio y lo usa para enfriar el producto
final NH4NO3. El equipo funciona bsicamente como un radiador.
Q = h2 - h1
m Producto =
h1 (Descarga) =
h2 (Descarga) =
41,124 kg/h
-188,729 MJ/h
-188,742 MJ/h
Q=
13 MJ/h
80.0 C
40.0 C
T inlet =
T outlet =
Clculo de la potencia del equipo:

Max HP =
17 + 8.4 (Fan Diam - 3.5) =
Fan Diam =
29.60 hp
22.07 kw
5 feet
1.5 m
Tube Side = Producto NH4NO3
Shell Side = Aire
70
200
T in, Hot Side (T1)
176
104 F
12 M Btu/hr
2 o
5 Btu/hr - Ft - F

Exchanger Heat Duty

F Factor
Adjusted LMTD
1
2
o
167 F =
1
o
167 F
2
14.23 Ft =
1.25
1.00
2
17.79 Ft =
Tube OD
BWG
Tube ID, d =
Tube Length, L =
75 C
1.32 m2
1.65 m2
0.75
16
0.620
10
in.
in.
ft.
3.0 m
0.302
in.2
1.963
ft2
Area / foot length=

Tubes/pass =
0.1963
7
ft2
kg/h
MJ/h
MJ/h
MJ/h
kg/h
MJ/h
MJ/h
MJ/h
kg/h
MJ/h
MJ/h
MJ/h
MJ/h
kg/h
MJ/h
MJ/h
MJ/h
kg/h
MJ/h
MJ/h
MJ/h
kg/h
MJ/h
MJ/h
MJ/h
kg/h
MJ/h
MJ/h
MJ/h
SHELL AND TUBE HEAT EXCHANGER TUBESHEE

Source: "Process Heat Transfer"; Donald Q. Kern, McGr
BWG
7
8
9
10
11
12
13
14
15
16
17
18
20
22
BWG
7
8
9
10
11
12
13
14
15
16
17
18
20
22
BWG
7
8
9
10
Wall
thickness
inches
0.165
0.148
0.134
0.120
0.109
0.095
0.083
0.072
0.065
0.058
0.049
0.035
0.028
Wall
thickness
inches
0.165
0.148
0.134
0.120
0.109
0.095
0.083
0.072
0.065
0.058
0.049
0.035
0.028
1/2" O. D. Condenser tube

Surface area per linear foot, Tube weight
per linear
ft2
Outside
Inside
foot, lb of
Tube I. D.
inches
Tube flow
area
in2
0.282
0.0625
0.1309
0.0738
0.456
0.334
0.0876
0.1309
0.0874
0.370
0.370
0.1075
0.1309
0.0969
0.302
0.402
0.430
0.444
0.1269
0.1452
0.1548
0.1309
0.1309
0.1309
0.1052
0.1126
0.1162
0.236
0.174
0.141
Tube I. D.
inches
Tube flow
area
in2
0.482
0.510
0.532
0.560
0.584
0.606
0.620
0.634
0.652
0.680
0.1825
0.2043
0.2223
0.2463
0.2679
0.2884
0.3019
0.3157
0.3339
0.3632
Wall
thickness
inches
Tube I. D.
inches
Tube flow
area
in2
0.165
0.148
0.134
0.670
0.704
0.732
0.3526
0.3893
0.4208
3/4" O. D. Condenser tube

per linear
ft2
foot, lb of
Outside
Inside
steel
0.1963
0.1963
0.1963
0.1963
0.1963
0.1963
0.1963
0.1963
0.1963
0.1963
0.1262
0.1335
0.1393
0.1466
0.1529
0.1587
0.1623
0.1660
0.1707
0.1780
0.883
0.808
0.747
0.665
0.592
0.522
0.476
0.429
0.367
0.268
1" O. D. Condenser tube

per linear
ft2
foot, lb of
Outside
Inside
steel
0.2618
0.2618
0.2618
0.1754
0.1843
0.1916
1.473
1.348
1.241
11
12
13
14
15
16
17
18
20
22
0.120
0.109
0.095
0.083
0.072
0.065
0.058
0.049
0.035
0.028
BWG
Wall
thickness
inches
7
8
9
10
11
12
13
14
15
16
17
18
20
22
BWG
7
8
9
10
11
12
13
14
15
16
17
18
0.165
0.148
0.134
0.120
0.109
0.095
0.083
0.072
0.065
0.058
0.049
0.035
0.028
0.760
0.782
0.810
0.834
0.856
0.870
0.884
0.902
0.930
Tube I. D.
inches
0.890
0.920
0.954
0.982
1.010
1.030
1.060
1.080
1.110
1.120
1.130
1.150
1.180
Wall
thickness
inches
Tube I. D.
inches
0.165
0.148
0.134
0.120
0.109
0.095
0.083
0.072
0.065
0.058
0.049
1.170
1.200
1.230
1.260
1.280
1.310
1.330
1.360
1.370
1.380
1.400
0.4536
0.4803
0.5153
0.5463
0.5755
0.5945
0.6138
0.6390
0.6793
0.2618
0.2618
0.2618
0.2618
0.2618
0.2618
0.2618
0.2618
0.2618
0.1990
0.2047
0.2121
0.2183
0.2241
0.2278
0.2314
0.2361
0.2435
1.129
1.038
0.919
0.814
0.714
0.650
0.584
0.498
0.361
1-1/4" O. D. Condenser tube

Tube flow
per linear
ft2
2
foot, lb of
area
in
Outside
Inside
steel
0.6221
0.3272
0.2330
2.059
0.6648
0.3272
0.2409
1.914
0.7148
0.3272
0.2498
1.744
0.7574
0.3272
0.2571
1.599
0.8012
0.3272
0.2644
1.450
0.8332
0.3272
0.2697
1.341
0.8825
0.3272
0.2775
1.173
0.9161
0.3272
0.2827
1.059
0.9677
0.3272
0.2906
0.883
0.9852
0.3272
0.2932
0.824
1.0029
0.3272
0.2958
0.763
1.0387
0.3272
0.3011
0.641
1.0936
0.3272
0.3089
0.455
1-1/2" O. D. Condenser tube

Tube flow
per linear
ft2
foot, lb of
area
in2
Outside
Inside
steel
1.0751
1.1310
1.1882
1.2469
1.2868
1.3478
1.3893
1.4527
1.4741
1.4957
1.5394
0.3927
0.3927
0.3927
0.3927
0.3927
0.3927
0.3927
0.3927
0.3927
0.3927
0.3927
0.3063
0.3142
0.3220
0.3299
0.3351
0.3430
0.3482
0.3560
0.3587
0.3613
0.3665
2.355
2.165
1.970
1.771
1.635
1.427
1.286
1.070
0.997
0.924
0.775
20
22
0.035
0.028
BWG
Wall
thickness
inches
7
8
9
10
11
12
13
14
15
16
17
18
20
22
0.165
0.148
0.134
0.120
0.109
0.095
0.083
0.072
0.065
0.058
0.049
0.035
0.028
Tube I. D.
inches
Tube flow
area
in3
1.760
1.782
1.810
1.834
2.4328
2.4941
2.5730
2.6417
2" O. D. Condenser tube

per linear
ft3
foot, lb of
Outside
Inside
steel
0.5236
0.5236
0.5236
0.5236
0.4608
0.4665
0.4739
0.4801
2.412
2.204
1.935
1.701
BE HEAT EXCHANGER TUBESHEET LAYOUTS (TUBE COUNTS)

Heat Transfer"; Donald Q. Kern, McGraw-Hill Book Co. (1950); page 842
Constant C **
168
198
227
241
Constant C **
285
319
347
384
418
450
471
492
521
567
Constant C **
550
656
708
749
804
852
898
927
997
1,060
Constant C **
970
1,037
1,182
1,250
1,305
1,377
1,440
1,537
1,626
1,706
Constant C **
1,860
2,014
2,180
2,300
Constant C **
3,795
3,891
4,014
4,121
September 30, 2003

Rev: 0
Art Montemayor
Heat Exchanger Tube Sheet Layout Count Table

Source: "Applied Process Design for Chemical and Petrochemical Plants"; Vol. 3; p.24
Ernest E. Ludwig; Gulf Publishing Co.; Houston, TX (1965)
Shell I. D., inches

Fixed Tubes Fixed Tubes
U Tubes
Fixed Tubes
U Tubes
Fixed Tubes
U Tubes
Fixed Tubes
U Tubes
Eight-Pass
Six-Pass
Four-Pass
Two-Pass
One-Pass
Tube O. D. & Pitch
10
12
13-1/4 15-1/4 17-1/4 19-1/4 21-1/4 23-1/4
105
135
193
247
307
391
481
91
117
157
217
277
343
423
85
101
139
183
235
287
355
57
73
103
133
163
205
247
45
65
83
111
139
179
215
25
553
493
419
307
255
27
663
577
495
361
303
29
763
667
587
427
359
31
881
765
665
481
413
33
1,019
889
765
551
477
35
1,143
1,007
865
633
545
37
1,269
1,127
965
699
595
452
398
346
244
218
398
336
304
192
180
528
468
408
292
248
460
406
362
234
214
626
556
486
346
298
558
484
436
284
256
734
646
560
410
348
648
566
506
340
304
846
746
644
462
402
768
674
586
396
356
964
858
746
530
460
882
772
688
466
406
1,088
972
840
608
522
1,008
882
778
532
464
1,242
1,088
946
688
584
1,126
1,000
884
610
526
332
292
242
176
142
286
254
226
142
122
412
360
308
212
188
378
318
286
178
166
484
424
366
258
214
438
386
342
218
198
576
508
440
308
260
534
462
414
266
238
680
596
510
368
310
622
542
482
322
286
788
692
590
422
360
740
648
560
376
336
904
802
688
486
414
852
744
660
444
384
1,024
912
778
560
476
976
852
748
508
440
1,172
1,024
880
638
534
1,092
968
852
584
500
230
202
158
112
88
206
184
160
100
80
294
258
212
150
116
272
268
210
130
110
372
322
266
182
154
358
300
268
168
152
440
388
324
226
184
416
366
322
206
182
532
464
394
274
226
510
440
392
252
224
632
548
460
338
268
596
518
458
304
268
732
640
536
382
318
716
626
534
356
316
844
744
634
442
368
826
720
632
426
362
964
852
224
514
430
944
826
718
488
420
1,106
964
818
586
484
1,058
940
820
562
478
198
170
132
90
74
190
170
146
90
70
258
224
174
120
94
254
226
194
118
98
332
286
228
154
128
342
286
254
154
142
398
344
286
190
150
398
350
306
190
170
484
422
352
240
192
490
422
374
238
206
576
496
414
298
230
578
498
438
290
254
682
588
490
342
280
688
600
512
340
300
790
694
576
400
334
796
692
608
404
344
902
798
662
466
388
916
796
692
464
396
1,040
902
760
542
438
1,032
908
792
540
456
3/4" on 15/16" Triang.

3/4" on 1" Triang.
3/4" on 1" Square
1" on 1-1/4" Triang.
1" on 1-1/4" Square
33
33
33
15
17
69
57
53
33
33
3/4" on 15/16" Triang.

3/4" on 1" Triang.
3/4" on 1" Square
1" on 1-1/4" Square
3/4" on 15/16" Triang.
3/4" on 1" Triang.
3/4" on 1" Square
1" on 1-1/4" Square
32
28
26
16
12
8
8
12
XX
XX
58
56
48
32
26
34
26
30
8
12
94
90
78
52
40
64
60
52
26
22
124
110
94
62
56
94
72
72
42
38
166
154
126
92
76
134
108
100
58
58
228
208
172
126
106
180
158
142
84
76
300
264
222
162
136
234
212
188
120
100
370
326
280
204
172
304
270
242
154
134
3/4" on 15/16" Triang.

3/4" on 1" Triang.
3/4" on 1" Square
1" on 1-1/4" Square
3/4" on 15/16" Triang.
3/4" on 1" Triang.
3/4" on 1" Square
1" on 1-1/4" Square
XX
XX
XX
XX
XX
XX
XX
XX
XX
XX
48
44
48
24
24
28
20
24
84
72
72
44
40
56
52
44
20
16
108
96
88
60
48
84
64
64
36
32
154
134
126
78
74
122
98
90
50
50
196
180
142
104
84
166
146
130
74
66
266
232
192
138
110
218
198
174
110
90
3/4" on 15/16" Triang.

3/4" on 1" Triang.
3/4" on 1" Square
1" on 1-1/4" Square
3/4" on 15/16" Triang.
3/4" on 1" Triang.
3/4" on 1" Square
1" on 1-1/4" Square
XX
XX
XX
XX
XX
XX
XX
XX
XX
XX
80
66
54
34
116
104
78
56
44
110
88
80
42
42
174
156
116
82
66
156
134
118
68
60
3/4" on 15/16" Triang.

3/4" on 1" Triang.
3/4" on 1" Square
1" on 1-1/4" Square
3/4" on 15/16" Triang.
3/4" on 1" Triang.
3/4" on 1" Square
1" on 1-1/4" Square
XX
XX
XX
XX
XX
XX
XX
XX
XX
XX
94
82
140
124
94
66
102
82
70
38
34
142
122
106
58
50
74
56
56
30
68
52
48
24
Notes: 1) The above tube counts have an allowance made for Tie Rods.
2) The Radius of Bend for the U-Tube bundles is equal to (2.5) (Tube O.D.); The actual number of U-tubes is 1/2 of the above figures.
Page 83 of 139
FileName: 136596804.xlsx.ms_office
WorkSheet: Tube Counts
Art Montemayor
October 02, 2003

Rev: 0
Overall Heat Transfer Coefficient
Typical Overall Heat Transfer Coefficients

Source: http://www.the-engineering-page.com/forms/he/typU.html
Shell and Tube Heat Exchangers
Hot Fluid
Cold Fluid
Heat Exchangers
Water
Water
Organic solvents
Organic Solvents
Light oils
Light oils
Heavy oils
Heavy oils
Reduced crude
Flashed crude
Regenerated DEA
Fouled DEA
Gases (p = atm)
Gases (p = atm)
Gases (p = 200 bar)
Gases (p = 200 bar)
Overall U
W/m2-C
Btu/hr-ft2-oF
800 1,500
100 - 300
100 - 400
50 - 300
35 - 150
450 - 650
5 - 35
100 - 300
140 - 264
17 52
17 70
9 53
6 26
79 114
1.0 6
17 53
250 - 750
350 - 700
60 - 300
75 - 200
5 - 35
150 - 400
20 - 300
150 - 500
600 1,200
15 - 250
44 132
62 - 123
11 - 53
13 35
1.0 6
26 70
4 53
26 88
106 211
3 - 44
Water
Organic solvents
Light oils
Heavy oils
Gases
Heavy oils
Gases
Steam
Hydrocarbon vapors
1,500 4,000
500 1,000
300 - 900
60 - 450
30 - 300
50 - 300
20 - 200
30 - 100
30 -100
264 - 700
88 - 176
53 159
11 79
5 53
9 53
4 - 35
5 - 18
5 - 18
Water
Water
Water
Water
Water
1,000 1,500
700 1,000
400 - 550
500 - 700
200 - 500
176 264
123 176
70 - 97
88 123
35 88
Coolers
Organic solvents
Light oils
Heavy oils
Reduced crude
Gases (p = atm)
Gases (p = 200 bar)
Gases
Organic solvents
Water
Gases
Water
Water
Water
Water
Water
Water
Water
Brine
Brine
Brine
Heaters
Steam
Steam
Steam
Steam
Steam
Heat Transfer (hot) Oil
Heat Transfer (hot) Oil
Flue gases
Flue gases
Condensers
Aqueous vapors
Organic vapors
Refinery hydrocarbons
Vapors with some non condensables
Vacuum condensers
Page 84 of 139
WorkSheet: Typical "U"
Art Montemayor
October 02, 2003

Rev: 0
Overall Heat Transfer Coefficient
Vaporizers
Steam
Steam
Steam
Heat Transfer (hot) oil
Aqueouos solutions
Light organics
Heavy organics
Refinery hydrocarbons
Air Cooled Exchangers

Process Fluid (tube side)
Water
Light organics
Heavy organics
Gases
Condensing hydrocarbons
Immersed coils
Coil Fluid
Pool Fluid
Natural circulation
Steam
Dilute aqueous solutions
Steam
Light oils
Steam
Heavy oils
Aqueous solutions
Water
Light oils
Water
1,000 1,500
900 1,200
600 - 900
250 - 550
176 264
159 211
106 159
44 97
300 - 450
300 - 700
50 - 150
50 - 300
300 - 600
53 - 79
53 - 123
9 - 26
9 - 53
53 - 106
500 1,000
200 - 300
70 - 150
200 - 500
100 - 150
88 176
35 53
12 26
35 88
18 26
800 1,500
300 - 500
200 - 400
400 - 700
200 - 300
140 264
53 88
35 70
70 - 123
35 - 53
500 - 700
250 - 500
200 - 500
200 - 300
88 - 123
44 - 88
35 - 88
35 - 53
Agitated
Steam
Steam
Steam
Aqueous solutions
Light oils
Steam
Steam
Water
Water

Light oils
Heavy oils
Water
Water
Jacketed vessels
Jacket Fluid
Vessel Fluid
Light organics
Light organics
Arts Note: Above Us were originally given in metric units and the conversion to good,
old fashioned US engineering units is based on:
1.0 Btu/hr-ft2-oF = 5.678263 Watts/m2-oK
Page 85 of 139
WorkSheet: Typical "U"
REACTOR OXIDACIN AMONIACO R-100

Base = 1 da
OXIDACION DE AMONIACO
4NH3 + 5O2 4NO+6H2O
P=
10
T=
950
R=
0.0821
bar
C
atm.l/mol.K
Eficiencia de reaccin:
100%
Tipo de Reactor =
PFR
Clculos Bsicos:
El reactor es de tipo cilndrico, con fondos superior e inferior elpticos y con una
disposicin vertical en conjunto.
m=
193,074 kg/h
Clculo del Volumen:
tR =
0.10 minutos
p=
2.72 kg/m3
m = Flujo msico total
LL =
90%
tR = Tiempo de residencia
p = Densidad flujo msico
V=
131.42 m3
LL = Llenado en fraccin unitaria
Clculo de las dimensiones:
H/D =
D=
4.06 m
H =
10.15 m
2.50
REACTOR SNTESIS NO2 (CONDENSADOR) E-150

Base = 1 da
Ocurre por enfriamiento en un condensador. Se aproximar el diseo a un reactor PFR.
OBTENCIN DE DIOXIDO DE NITROGENO
P=
7 bar
2NO + O2 2NO2
T=
R=
200 C
0.0821 atm.l/mol.K
Clculos Bsicos:
m=
251,671 kg/h
Clculo del Volumen:
tR =
0.02 minutos
p=
4.90 kg/m3
LL =
90%
V=
19.01 m3
H/D =
D=
2.13 m
H =
5.33 m
2.50
Se considera un condensador de Coraza y Tubos. (Ver intermcabiadores)
SNTESIS NH4NO3 R-200

Base = 1 da
PRODUCCION NH4NO3
NH3 + HNO3 NH4NO3
P=
4 bar
T=
180 C
Tipo de Reactor =
PFR
Clculos Bsicos:
m=
62,582 kg/h
Clculo del Volumen:
tR =
35.00 minutos

p=
LL =
V=
1,230.00 kg/m3
80%
37.10 m3

H/D =
D=
2.66 m
H =
6.66 m
2.50
ABSORCIN HNO3 - D-110

Base =
1 da
30 C
125.19 psig
T =
P=
35 min
T retencin =
Avg mol wt entrada

29.11
T (C) =
46.83
T (K) =
319.98
P (psig) =
119.66
P (atm) =
132 atm
R (m3.atm/mol.K) =
0.0000821
Densidad =
146.4 kg/m3
Avg mol wt salida
mol NO2 salida

NO2 absorbido
Agua requerida absorcion
108,628.09
Agua en la alimentacion
34,848.60
369.2 kmol
18,089.61 kmol
832,212.35 kg
27.47
HNO3 formado
NO2 absorbido agua
554,808.23 kg
NO2 absorbido en acido
277,404.12 kg
2,810,578.70 kg/dia
32.53 kg/s
L
pL
32.53 kg/s
1,175 kg/m3
G
pG
74.38 kg/s
146.38 kg/m3
Cf
u
Y
255
3.70E-03 Pa-s
0.35
G*^2
G*
% carga
G*
Flujo tope
Wt
voidage
ap
7,576.99 kmol/h
27.47 kg/kmol
0.68
262 m2/m3
Difusividad
umix
7.60E-06 m2/s
3.40E-05 Pa-s
12,059.74
759,920.25
0.165
361.65
19.02 kg/m2.s
0.56
10.65 kg/m2.s
A=
6.98 m2
Di =
2.98 m
Gv
Vbg
GT
Gt
Vbg
Vavg
Vp
Flujo liquido
Flujo hmedo
0.51
0.07
57.82
0.40
0.06
0.06
0.10
4.66
1.51E-05
m3/s
m/s
kg/s
m3/s
m/s
m/s
m/s
kg/m2-s
m3/m-s
NSc
d
Kg
Pp NO2 = p1
p2
Aempaq
Nre
0.0253 m
T
Vp
10,356.22
303.15 K
0.31 pies/s
0.064 lb mole / hr-ft2-atm

0.138
0.002746
fuerza motriz
NO2 abs
0.03
0.034 atm
1,660.21 lbmol/h
155,406.58 pie2
14,437.74 m2
Aempaque / m altura
1,829.97 m
Altura empaque
7.9 m
25.88 pies
Vol emp =
Clculo de NTU y HETP:
ANILLOS RASCHING 3/4"
Altura de unidad de transferencia de lquido =

HETP
(2.5 - 3 pies) (Heuristic in Chemical Engineering)

3 pies
0.91 m
Nmero de Unidades de Transferencia (NTU)
8.6 pies
2.63 m
Altura Columna =
H/D =
H=
3.5
10.4 m
rea del equipo:

2Abase + 2.pi.r.L
A=
111.75 m2
e plancha =
0.75 pulg =
Material =
INOX 304
p Inox 304 =
7800 kg/m3
Peso =
16,605.57 kg
36,609.02 lb
0.02 m
kg
kmol
kmol
kg
55.11 m3
1,946.05 pie3
NILLOS RASCHING 3/4"
euristic in Chemical Engineering)
SECADOR
Humedad del aire que entra =
Humedad del aire que sale =
0.0095 kg agua/kg a.s.

Humedad del slido que entra =

Humedad del slido que sale =
34.66%
0.20%
Para el NH4NO3:
Ms1 = Ms2 + Agua eliminada (Ae)
Slidos en (1) = Slidos en (2)
Ms1 x Ss1 =
Ms2 x Ss2
NH4NO3 =
Agua =
TOTAL =
Datos
Convencionales
Ms1 =
Ss1 =
Ss2 =
985.00 TM/dia
65%
99.8%
Ms2 =
Ae =
644.85 TM
340.16 TM
985.00 TM
340.16 TM
1,325.16 TM
0.74 Xi
0.35 kgAgua/kgs
Para el Aire:
Agua ganada por cada kg de aire seco:
Has - Hae =
Agua total ganada por el aire seco = Ae = Ma seco x Hae :

Masa de aire total =

Ma seco =
Mae = Ma seco + agua total contenida en el aire
Agua total contenida en el aire = Ma seco x Hae =

Mae =
4,535.40 TMa.s
43.09 TM
4,578.49 TM
SALIDA SLIDOS:
NH4NO3 =
H2O =
SALIDA AIRE:
AIRE =
H2O =
985.00 TM
43.09 TM
0.958 Xo
4,535.40 TM
340.16 TM
Balance de energa
Tin slidos =
Tsal slidos =
Q=
180.11 C
80.00 C
-5,786.38 (hv-84) +
Cp,sol =
-0.245 kJ/s
4.4499 kJ/kg.C
hv = ENTALPIA DE VAPOR DE AGUA A LA TEMPERATURA DE SALIDA

hv =
2,705.93 kJ/kg
Q=
- 15,171.48 MJ/h
Tamao del equipo:

Velocidad de slidos:
ms =
p=
Luego:
0.001 m/s
(ULRICH)
17.47 kg/s
1,961.44 kg/m3
A = m/p.Vs
A=
8.91 m2
3.37 m
por la siguiente ecuacin:
G = Flujo de masa del gas =
5.95 kg/s.m2
Tbh in = Tbh sal =
38 C
H/D =
2.50 (ULRICH)
H=
8.42 m
onvencionales
SEPARADOR GAS - LQUIDO D-100

Tinlet =
Pinlet =
180 C =
11 bar =
816 R
158.82 PSIA
INGRESO
zi
Ammonia
Nitrogen
Water
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
6.4
7,550.3
527.8
63.8
898.1
42.3
TM
TM
TM
TM
TM
TM
Ammonia
Nitrogen
Water
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
0.539
0.387
0.042
0.003
0.028
0.001
Carga
696.72
Calculando Ki:
zi
Ammonia
Nitrogen
Water
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
0.539
0.387
0.042
0.003
0.028
0.001
Carga =
Ammonia
Nitrogen
Water
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
kmol
Pc (psia)
1,636
492
3,208
941
1,470
999
730
227
1,165
659
776
936
Zi*(Ki-1)
6.3
29.5
0.0
0.0
0.2
0.0
(Ki-1)+1
62.3
401.0
0.0
27.1
45.2
3.1
f(V/F)
0.1010
0.0735
-0.1798
0.0006
0.0052
0.0001
0.0006
phi =
5.253
696.7 kmol
Ki -1
11.7
76.1
-0.2
5.0
8.4
0.4
5.253
Calculando la solucin:
V/F =
F =
Tb
375.6
269.5
29.3
2.1
19.5
0.7
f=
Tc R
5
697
R
432
139
672
218
529
641
V=
L =
3,660
-2,963
Ammonia
Nitrogen
Water
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
Xi
0.00865
0.00096
0.98643
0.00011
0.00062
0.00031
0.99709
Clculo de las diseo bsico:

1) Estimacin del dimetro:
Usg = Velocidad de flujo de operacin superficial del flujo de gas basado en la seccin transversal de la torre
Ksb = Constante ptima de Souders Brown
Ksb =
(rango)
0.04 m/s
0.08 m/s
Sistemas gas-lquido que tienen tensiones superficiales grandes

Sistemas gas-lquido que tienen tensiones superficiales pequeas
Como el sistema presenta componentes polares, se asume una tensin super

grande.
A partir del CHEMCAD:
1,013.22 kg/m3
9.78 kg/m3
pl =
pg =
Usg =
0.41 m/s
V = Flujo de gas =
Mg = Peso molar del gas =
D=
81,920.87 mol/s
1.62
6.52 m
2) Estimacin de la Altura:
Considerando, L/D =
2.5
(Heurstico)
L=
V tanque =
16.30 m
544.08 m3
rea del equipo:
2Abase + 2.pi.r.L
A=
e plancha =
Material =
400.58 m2
0.75 pulg =
INOX 304
0.02 m
p Inox 304 =
Peso =
7800 kg/m3
59,522.84 kg
131,225.39 lb
BASE = 1 DIA
kmol
375.58
269.52
29.30
2.13
19.52
0.67
kmol
b
1.27
1.27
1.27
1.27
1.27
1.27
2,159.38
548.48
3,708.87
590.27
3,323.78
3,728.04
Fi
0.86
0.86
0.86
0.86
0.86
0.86
Ki
2.36
3.27
0.98
1.98
2.21
1.25
12.678
77.148
0.818
5.972
9.413
1.398
Ammonia
Nitrogen
Water
Nitric Oxide
Nitrogen Dioxide
Nitric Acid
yi
0.10962
0.07442
0.80666
0.00067
0.00584
0.00044
0.99764
nsversal de la torre
es superficiales grandes
es superficiales pequeas
polares, se asume una tensin superficial
TANQUES DE ALMACENAMIENTO
F-100
Almacenamiento NH3
Tiempo retencin
Flujo
Capacidad
% Llenado
Cantidad Tanques
7
34
5745
75%
5
das
m3/h
m3
1,517,539 gal
tanques
Volumen Tanque
Material
Posicin
1532 m3
INOX 316
VERTICAL
Tipo Techo
Longitud/Dimetro
FLOTANTE
404,677 gal
(Heursticos en Ingeniera Qumica, Stanley-Wallas)

2 (Heursticos en Ingeniera Qumica, Stanley-Wallas)
Estimando dimensiones:
3
VTANQUE = 3.. /4
=
H=
F-200
8.66 m
17.33 m
Almacenamiento HNO3
Tiempo retencin
Flujo
Capacidad
% Llenado
Cantidad Tanques
2
45
2166
75%
2
das
m3/h
m3
tanques
Volumen Tanque
Material
Posicin
1444 m3
INOX 316
VERTICAL
Tipo Techo
Longitud/Dimetro
FLOTANTE
Estimando dimensiones:
3
VTANQUE = 3.. /4
=
H=
8.49 m
16.99 m
572,236 gal
381,491 gal
(Heursticos en Ingeniera Qumica, Stanley-Wallas)

2 (Heursticos en Ingeniera Qumica, Stanley-Wallas)
EQUIPOS
Item
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
Equipo
Separador Gas - Lquido
Columna Absorcin
Vaporizador
Enfriador
Condensador
Precalentador
Enfriador
Aeroenfriador
Condensador
Enfriador
Enfriador
Evaporador
Aeroenfriador
Compresor
Compresor
Secador
Bomba
Bomba
Bomba
Bomba
Bomba
Bomba
Bomba
Bomba
Reactor
Reactor
TK Almacen NH3
TK Almacen HNO3
TK Almacen H2O
TOTAL CEPCI 2007

TOTAL MS 2007
Cantidad
D-100
D-110
E-100
E-110
E-111
E-120
E-130
E-140
E-150
E-160
E-170
E-210
E-220
G-100
G-110
B-200
P-100
P-110
P-120
P-130
P-140
P-150
P-200
P-210
R-100
R-200
F-100
F-200
F-300
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
1
2
2
2
2
2
2
2
2
1
1
5
2
49.07 MMUS$
50.13 MMUS$
INDICES DE COSTO
CEPCI
1990
2007
TAG
357.6
525.4
Tipo
Vertical
Empacada
Coraza y tubos
Coraza y tubos
Coraza y tubos
Coraza y tubos
Coraza y tubos
Coraza y tubos
Coraza y tubos
Coraza y tubos
Coraza y tubos
Coraza y tubos
Coraza y tubos
Centrfugo
Centrfugo
Contacto
Centrfuga
Centrfuga
Centrfuga
Centrfuga
Centrfuga
Centrfuga
Centrfuga
Centrfuga
PFR
PFR
Vertical
Vertical
Vertical
Material
INOX 304
INOX 304
INOX 304
A36
INOX 304
INOX 304
INOX 304
INOX 304
INOX 304
INOX 304
INOX 304
INOX 304
INOX 304
A36
A36
INOX 304
INOX 316
INOX 316
INOX 316
INOX 304
INOX 316
INOX 316
INOX 316
INOX 316
INOX 316
INOX 316
INOX 304
INOX 304
A36 c/pintura
M&S
1990
2007
915
1373.3
Fluido
Gases cidos
HNO3 (ac)
NH3 (l)
Aire
Gases cidos
Aire
Gases cidos
Gases cidos
NO(g) - NO2(l)
Gases cidos
Gases cidos
Pulpa NH4NO3
NH4NO3
Aire
Aire
NH4NO3
NH3 (l)
NH3 (l)
HNO3 7%
Agua cida
HNO3 48%
HNO3 86%
HNO3 57%
NH4NO3 65%
NH3 - Aire
HN3 - HNO3
NH3
HNO3
H2O
Dimetro (m)
6.52
2.98
2.13
2.13
1.52
Longitud (m)
6.10
13.72
9.75
6.10
13.72
9.75
5.33
13.72
13.72
4.88
3.05
# Tubos
Altura (m)
16.30
10.44
78
3093
1058
21
326
780
13699
2276
1120
346
7
rea (m2)
28.32
2,538.83
1,029.15
7.55
267.45
455.51
4,248.01
1,868.56
13.72
100.99
1.65
3.37
8.42
4.06
2.66
8.66
8.49
10.15
6.66
17.33
16.99
8.91
Capacidad (m3)
544.08
Caudal (m3/h)
Potencia (kw)
38,541
34.60
19.01
41,133
155,136
155,136
22.07
3,731.29
11,194.11
Heat Duty (MJ/h)

70,775,452.73
15,654
14,768
19,835
3,108
14,642
115,013
2,412,260
44,225
10,419
12,786
13
15,171.48
20.66
14.96
20.75
28.45
36.06
9.95
46.39
32.06
131.42
37.10
1,531.87
1,444.10
1.16
0.84
2.24
16.03
4.88
1.35
6.27
4.33
13,918,663
27,610,422
n
0.70
0.70
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.75
0.75
0.65
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.60
0.60
0.80
0.80
0.80
COSTO REFERENCIA
Variable
10,000.00
10,000.00
4,000.00
4,000.00
8,000.00
4,000.00
4,000.00
1,000.00
8,000.00
4,000.00
4,000.00
1,000.00
1,000.00
3,000.00
3,000.00
100.00
20,000.00
20,000.00
20,000.00
20,000.00
20,000.00
20,000.00
20,000.00
20,000.00
1,000.00
1,000.00
100,000.00
100,000.00
100,000.00
COSTO DE EQUIPOS
COSTO REFERENCIA 1990
Variable
US$
lb
80,000.00
lb
104,909.39
pie2
1,320,000.00
pie2
1,320,000.00
gal/min
99,000.00
pie2
1,320,000.00
pie2
1,320,000.00
pie2
66,000.00
gal/min
99,000.00
pie2
1,320,000.00
pie2
1,320,000.00
pie2
1,320,000.00
pie2
66,000.00
hp
1,000,000.00
hp
1,000,000.00
pie2
550,000.00
gpm x psi
19,200.00
gpm x psi
19,200.00
gpm x psi
19,200.00
gpm x psi
13,200.00
gpm x psi
19,200.00
gpm x psi
19,200.00
gpm x psi
19,200.00
gpm x psi
19,200.00
gal
307,200.00
gal
307,200.00
gal
102,000.00
gal
102,000.00
gal
80,000.00
COSTO 1990
Variable
131,225.39 lb
36,609.02 lb
304.84 pie2
27,327.70 pie2
169,688.90 gal/min
81.25 pie2
2,878.84 pie2
4,903.02 pie2
181,102.27 gal/min
20,113.02 pie2
147.64 pie2
1,087.05 pie2
17.79 pie2
5,003.74 hp
15,011.55 hp
95.86 pie2
16,255.45 gpm x psi
11,771.21 gpm x psi
13,361.41 gpm x psi
14,986.68 gpm x psi
22,453.39 gpm x psi
8,579.65 gpm x psi
33,326.00 gpm x psi
25,486.10 gpm x psi
34,716.35 gal
9,800.69 gal
404,677.00 gal
381,490.72 gal
gal
US$
484,956.17
260,211.22
168,338.99
6,140,566.18
1,139,950.40
58,449.31
1,014,612.04
235,458.79
1,200,887.51
4,805,158.44
94,250.57
1,411,151.57
2,628.03
1,467,674.82
3,345,631.89
535,084.85
17,309.55
14,729.80
15,693.23
11,426.46
20,343.57
12,575.38
24,784.37
21,673.94
2,580,724.70
1,208,300.87
312,095.13
297,705.84
-
INDEX CEPCI 2007

COSTO 2007
US$/UNID
US$ TOTAL
712,516.70
712,516.70
382,312.57
382,312.57
247,330.27
247,330.27
9,021,961.61 9,021,961.61
1,674,860.01 1,674,860.01
85,876.03
85,876.03
1,490,707.96 1,490,707.96
345,945.33
345,945.33
1,764,391.21 1,764,391.21
7,059,927.98 7,059,927.98
138,476.65
138,476.65
2,073,319.45 2,073,319.45
3,861.21
3,861.21
2,156,365.63 4,312,731.25
4,915,534.10 9,831,068.19
786,167.73
786,167.73
25,431.87
50,863.74
21,641.60
43,283.21
23,057.11
46,114.22
16,788.20
33,576.41
29,889.57
59,779.15
18,476.24
36,952.47
36,414.17
72,828.33
31,844.21
63,688.42
3,791,702.34 3,791,702.34
1,775,283.22 1,775,283.22
458,542.45 2,292,712.24
437,401.14
874,802.28
-
INDEX MS 2007
COSTO 2007
US$/UNID
US$ TOTAL
727,858.26
727,858.26
390,544.34
390,544.34
252,655.66
252,655.66
9,216,218.08
9,216,218.08
1,710,922.28
1,710,922.28
87,725.07
87,725.07
1,522,805.15
1,522,805.15
353,394.05
353,394.05
1,802,381.22
1,802,381.22
7,211,938.89
7,211,938.89
141,458.26
141,458.26
2,117,961.15
2,117,961.15
3,944.35
3,944.35
2,202,795.44
4,405,590.87
5,021,372.97 10,042,745.94
803,095.11
803,095.11
25,979.46
51,958.92
22,107.58
44,215.16
23,553.56
47,107.13
17,149.68
34,299.36
30,533.14
61,066.28
18,874.06
37,748.11
37,198.22
74,396.44
32,529.86
65,059.73
3,873,343.42
3,873,343.42
1,813,507.75
1,813,507.75
468,415.56
2,342,077.80
446,819.05
893,638.10
-
CURVAS DE COSTO
Se utilizarn las curvas de costo de 1990:
(Fuente: Plant Design Economics ChemicalEngineers, Peters & Timmerhaus)
INVERSION
ACTIVO FIJO
Rango (%) Valor Tpico % MMUS$ (CEPCI)
Costo del equipo

Instalacion (incluye aislantes y recubrimientos)
Instrumentacin y control
Instalacin de tuberas
Instalacin elctrica
Edificios de proceso y auxiliares
Facilidades de servicio y mejoras de planta
Terreno
18 - 40
7.3 - 26
2.5 - 7
3.5 - 15
2.5 - 9
6.0 - 20
8.1 - 35
1.0 - 2.0
20
10
5
10
4
7
15
2
49.07
24.54
12.27
24.54
9.81
17.18
36.80
4.91
Total de Activo Fijo
179.12
INTANGIBLES
Supervision e ingenieria
Costos de construccion
Contingencias
4.0 - 21
4.8 - 22
6.8 - 18
Total Intangibles
TOTAL DE INVERSION FIJA

CAPITAL DE TRABAJO
8
10
9
19.63
24.54
22.08
100
66.25
245.37
49.07
(20% Inversin de Capital Fijo)

INVERSIN DE CAPITAL TOTAL
294.44
MMUS$ (MS)
50.13
25.06
12.53
25.06
10.03
17.55
37.60
5.01
182.97
20.05
25.06
22.56
67.68
250.65
50.13
300.78

Propiedades y composición de compuestos nitrogenados

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PROPIEDADES DE COMPUESTOS

Cp (cal/mol.K) = A + B.T + C.T2 + D.T3

COMPOSICIN DE LAS CORRIENTES - REPORTE CHEMCAD

29821.829 17296.6598 12525.1679 12525.1679 17296.6598 17296.6598

Molar flow kmol/day

29821.829 17296.6598 12525.1679 12525.1679 17296.6598

507896 294579.413 213316.143 213316.143 294579.413 294579.413

166115.473 166115.473 166115.473 166115.473 166115.473 183412.13 187736.297 187736.297

166115.473 166115.473 166115.473 183412.13 187736.297 187736.297

4778528.71 4778528.71 4778528.71 4778528.71 4778528.71 5073108.04 5073086.27 5073086.27

187736.297 318527.155 318527.155 294915.121 26596.8404 294915.121 10195.6697 36792.5108

187736.297 308612.558 293306.022 294915.121

26596.8404 2360.4683 10195.6697 36792.5108

5073086.27 9033962.46 9033962.46 8583997.01

26596.8404 36792.5108 288210.253 37007.7315 7150.0319 281060.241 37007.7315 7150.0319

688353 8255685.04 1016658.44 333916.226 7921768.71 1016658.44 333916.226

44157.7647 140530.121 140530.121 44157.7647 44377.0412 2982.5437 41394.4942 41394.4942

1350574.43 3960884.35 3960884.35 1350574.43 1563880.75 54670.6556 1509210.17 1509210.17

986982 3960884.35 3960885.37 183828.358 183828.358

PLANTA DE CIDO NTRICO

4NH3 + 5O2 4NO+6H2O

Clculo de mezcla de aire:

OBTENCIN DE DIOXIDO DE NITROGENO

PRODUCCION HNO3 (dil)

3NO2 + H2O 2HNO3 + NO

PLANTA DE NITRATO DE AMONIO

985.00 TM/dia NITRATO DE AMONIO, NH4NO3

99.65% Patente US 4,174,379

99.99% Concentracin comercial

PLANTA DE CIDO NTRICO

2)OBTENCIN DE DIOXIDO DE NITROGENO

3)PRODUCCION HNO3 (dil)

4NH3 + 5O2 4NO+6H2O

3NO2 + H2O 2HNO3 + NO

PLANTA DE NITRATO DE AMONIO

(Heuristic in Chemical Enginering)

(Heuristic in Chemical Enginering)

A partir de las fuguras:

BOMBA CENTRIFUGA - ETAPA SIMPLE

A partir de las fuguras:

(Heuristic in Chemical Enginering)

BOMBA CENTRIFUGA - ETAPA SIMPLE

(Heuristic in Chemical Enginering)

A partir de las fuguras:

BOMBA CENTRIFUGA - ETAPA SIMPLE

A partir de las fuguras:

45% (Heuristic in Chemical Enginering)

cido Ntrico 48%

A partir de las fuguras:

(Heuristic in Chemical Enginering)

BOMBA CENTRIFUGA - ETAPA SIMPLE

(Heuristic in Chemical Enginering)

BOMBA CENTRIFUGA - ETAPA SIMPLE

(Heuristic in Chemical Enginering)

cido Ntrico 86%

A partir de las fuguras:

BOMBA CENTRIFUGA - ETAPA SIMPLE

cido Ntrico 57%

A partir de las fuguras:

(Heuristic in Chemical Enginering)

BOMBA CENTRIFUGA - ETAPA SIMPLE

Nitrato de amonio 65%

A partir de las fuguras: