INTRODUCTION

Sumitomo Metals began manufacturing tubing, casing, drill pipe and line pipe more than thirty years ago. At that time, well depths were shallow and oil and gas drilling was relatively uncomplicated. Today, wells are going deeper, and drilling environments are becoming more hostile. Sweet wells, sour wells, and wells operating in arctic conditions or at extraordinary well depths have become commonplace. But these new types of wells require tubular products that are much more sophisticated and more tailored than their predecessors. To meet these new challenges, Sumitomo developed the SM Series, and a line of specialty tubular products (NEW SM Series) that are made from rugged materials like stainless steel and high alloys. In addition to the SM Series, Sumitomo Metals also produces stainless steel and high alloy line pipe, products that were specially developed to fight H2S and CO2, corrosive compounds that are often found in pipelinetransported crude oil and gas. For more than five decades, Sumitomo has been serving the needs of the oil and gas industries. This brochure provides a quick over-view of the family of quality Sumitomo products available to these vital enterprises.

FACILITIES AND LOCATIONS

Sumitomo Metals has almost all kinds of steel pipe manufacturing facilities which produce a wide range of seamless and welded steel pipe and tubes. The main facilities are composed of our Steel Tube Works, Wakayama Steel Works, and Kashima Steel Works. These works are able to produce approximately three million metric tons of steel pipe and tubes annually. The company also possesses facilities in affiliated companies in Sakai, Kashima and Koga. Sumitomo's facilities and locations are tabulated on next page together with their available size ranges (O.D.).

Location of Sumitomo Metal's steel pipe and tubes plants

3 4

1 2

6 5 7 8 9 10 1 Kashima Steel Works 2 Kashima Plant (Sumikin Weld Pipe Co.) 3 Koga Plant (Sumikin Stainless Steel Pipe Co.) 4 Tokyo Head Office 5 Steel Tube Works (Amagasaki) 6 Osaka Steel Works (Osaka) 7 Osaka Head Office 8 Sakai Plant (Sumikin Weld Pipe Co.) 9 Wakayama Steel Works (Wakayama) 10 Wakayama Steel Works (Kainan)

FACILITIES AND LOCATIONS

Sumitomo Tube Making Equipment and Available Sizes
Tube Mills Location of Works Outside Diameter in Inches 1 1 2 3 4 5 6 7 7 8 9 10 15 20 25 30 35 40 45 50 60 70 80 90 100 110 120

Mandrel (2 sets) Seamless (Hot Finished)

Kainan

Mandrel

Wakayama

5 1/2

16 3/4

Ugine-Sejournet

Amagasaki

9 5/8

Ehrhardt (Small)

Amagasaki

28

Ehrhardt (Large) Cold Finished Chain Drawbench Tube Reducing Machine Hydraulic Drawbench 2" ElectricResistance-Weld 4" ElectricResistance-Weld Special 7" ElectricResistance-Weld 20" ElectricResistance-Weld Welded UOE Submerged Arc-Weld Spiral Submerged Arc-Weld (4 Mills) 3-Roll Bender

Osaka

18

50

Amagasaki Kainan Amagasaki

18

20

Wakayama

34

/ 2
1 1/2 4 1/2

Wakayama

Wakayama

3 1/2

Wakayama

7 1/2

24

Kashima

(20) 24

60

Sakai Kashima Sakai

16

64

(20) 24

120

Continuous Hot ERW Kashima (Super Weld) Stainless steel Arc-Weld Koga Wakayama

12

14

12

MANUFACTURING PROCESS OF STEEL TUBES AND PIPES

Blast Furnace

CARBON & ALLOYED STEEL MAKING PRESS

STAINLESS STEEL MAKING PROCESS

Desulphurization

Dephosphorization

Electric Arc Furnace

Dephosphorization

AOD (Argon Oxygen Decaburization)

O2

Vacuum

Decarburization VOD Ladle

VOD (Vacuum Oxygen Decarburization)

RH-PB

IR-UT Blooming Mill

Slab

Continuous Casting Machine

Bar Mill Hot Strip Mill

Round Billet

Bloom

Slab

Ingot

Bloom

Continuous Casting Machine

Billet

Hot Coil

Mandrel Mill Process

Extrusion Process

Forging Process

Electric-Resistance Welding Process

Mandrel Mill Process

Extrusion Process

Forging Process

Electric-Resistance Welding Process

TUBE AND PIPE MAKING PROCESS

Piercer

1200t Vertical Press

3000t Vertical Press

Cold Draw Bench

Cold Reducing Mill

Mandrel Mill

4000t Horizontal Press 3 Roll Reducer

1500t, 600t Horizontal Press

Continuous Barrel Furnace Edge Scarfer Welder Cooling Flying Cut-off

Continuous Bright Annealing Furnace

Coil

Cut Shear Side Trimmer

Forming Mill

Seam Annealer

Sizer

Straightener

Hot Finished Seamless Steel Tubes and Pipe

Cold Finished Seamless Tubes and Pipe

Electric-resistance Welded Steel Tubes and Pipe

AVAILABLE GRADES
AVAILABLE GRADES
AVAILABLE GRADES CASING AND TUBING
API SPEC 5CT Main Yield Strength (PSi) SEAMLESS ERW

GROUP 1

GROUP 2

GROUP 3

GROUP 4

GROUP 1

GROUP 2

GROUP 3

GROUP 4

40,000 55,000

H-40 J-55 K-55 M-65

H-40 J-55 K-55 M-65

65,000 70,000 75,000 80,000

N-80

L-80 L80-13CR

N-80

85,000 90,000 95,000 C-90 C-95 T-95

100,000 105,000 110,000 P-110

125,000

Q-125

130,000

140,000

150,000 155,000 REMARKS 1. Grade SM-S, SB are designed to prevent sulfide stress corrosion cracking (SSCC), but not designed to prevent general corrosion CO2 or CO2 + H2S environment, so inhibitor usage should be considered. 2. Grades from SM22CR to SMC276 are designed to prevent both SSCC and general corrosion. 3. SM-Series designation stand for (1) SM-90SB :SUMITOMO-90,000psi minimum yield strength special sour well service. (2) SM13CR-80 :SUMITOMO 13%Chromium steel-80,000psi minimum yield strength. (3) SM2550-110 :SUMITOMO 25%Chromium 50%Nickel 6%Molybdenum alloy-110,000psi minimum yield strength.

AVAILABLE GRADES
AVAILABLE GRADES
AVAILABLE GRADE CASING AND TUBING
SM SERIES (SUMITOMO STANDARD) Main Yield Strength (PSi) SEAMLESS & ERW GENERAL & HIGH SOUR SERVICE ARCTIC DEEP WELL COLLAPSE SERVICE SERVICE STRENGTH GENERAL SEVERE COLLAPSE3 WET CO2 SERVICE NEW SM SERIES (SUMITOMO STANDARD) SEAMLESS WET CO2 & SOUR SERVICE WET CO2, SOUR & CI- SERVICE

40,000 55,000 SM-65GE

65,000 70,000 75,000 80,000

SM22CR-65

SM25CR-75 SM-80GE SM-80T SM-80TE SM-80S SM-80TS SM-80L SM13CR-80 SM25CRW-80 SM-80LL SM13CRS-80 SM13CRM-80 SM13CR-85 SM-90S SM-95G SM-95T SM-95TT SM-95S SM-90SS SM-90TS SM-95TS SM13CRS-90 SM-95L SM13CR-95 SM-95LL SM13CRS-95 SM13CRM-95

85,000 90,000 95,000

100,000 105,000 110,000

SM-C100

SM-110S SM-110T SM-110TT

SM-C110 SM-110TS SM-110L SM13CRS- SM22CR-110 SM2035-110 SM2550-110 110 SM25CR-110 SM-110LL SM2050-110 SM13CRMSM2535-110 SM2060-110 110 SM2242-110 SMC276-110 SM22CR-125 SM2035-125 SM2550-125 SM25CR-125 SM2050-125 SM25CRW-125 SM2535-125 SM2060-125 SM2242-125 SMC276-125 SM2535-130 SM2060-130 SM2550-130 SMC276-130 SM2050-130

125,000

SM-125G SM-125TT SM-125S

130,000

140,000

SM-140G

SM22CR-140 SM25CR-140 SM25CRW-140

SM2550-140 SM2060-140 SM2050-140 SMC276-140

150,000 155,000

SM-150G SM-155G

SM2060-150 SMC276-150 SM2060-155

REMARKS 1. Grade SM-S, SB are designed to prevent sulfide stress corrosion cracking (SSCC), but not designed to prevent general corrosion CO2 or CO2 + H2S environment, so inhibitor usage should be considered. 2. Grades from SM22CR to SMC276 are designed to prevent both SSCC and general corrosion. 3. SM-Series designation stand for (1) SM-90SB :SUMITOMO-90,000psi minimum yield strength special sour well service. (2) SM13CR-80 :SUMITOMO 13%Chromium steel-80,000psi minimum yield strength. (3) SM2550-110 :SUMITOMO 25%Chromium 50%Nickel 6%Molybdenum alloy-110,000psi minimum yield strength. 1 ERW PROCESS 2 These materials are not suitable for H2S condition. Please consult us when a small amount of H2S is existing in your application. 3 Grade SM-TS is available for high collapse & sour service. Please consult us when 100 & 110 grade is necessary.

AVAILABLE GRADES
AVAILABLE GRADES PHYSICAL PROPERTIES CASING AND TUBING
MECHANICAL PROPERTIES SPECIFICATION APPLICATION GRADE YIELD STRENGTH TENSILE STRENGTH (psi) (psi) 40,00080,000 55,00080,000 55,00080,000 80,000100,000 65,00085,000 80,00095,000 80,00095,000 90,000105,000 95,000110,000 95,000110,000 110,000140,000 125,000150,000 95,000125,000 125,000155,000 140,000170,000 150,000180,000 155,000185,000 80,000110,000 95,000125,000 95,000125,000 110,000140,000 110,000140,000 125,000150,000 80,00095,000 90,000105,000 95,000110,000 110,000125,000 80,00095,000 90,000105,000 95,000110,000 100,000115,000 110,000125,000 90,000105,000 100,000115,000 80,000110,000 80,000110,000 95,000125,000 95,000125,000 110,000140,000 110,000140,000 80,00095,000 85,000100,000 95,000110,000 80,00095,000 90,000105,000 95,000110,000 110,000125,000 80,00095,000 95,000110,000 110,000125,000 65,000100,000 110,000140,000 125,000145,000 140,000160,000 75,000100,000 110,000140,000 125,000145,000 140,000160,000 80,000 125,000145,000 140,000160,000 60,000 75,000 95,000 100,000 85,000 95,000 95,000 100,000 105,000 105,000 125,000 135,000 110,000 140,000 150,000 160,000 163,000 100,000 110,000 110,000 125,000 125,000 135,000 100,000 103,000 105,000 115,000 100,000 103,000 105,000 105,000 115,000 100,000 105,000 100,000 100,000 105,000 105,000 125,000 125,000 95,000 100,000 105,000 90,000 100,000 105,000 110,000 90,000 105,000 110,000 93,000 125,000 130,000 145,000 95,000 125,000 130,000 145,000 116,000 125,000 130,000 145,000 ELONGATION (%) API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA 25 12 11 11 25 12 11 11 20 12 11 11 HRC 23 HRC 24 HRC 27 HRC 27 HRC 27 HRC 28 HRC 32 HRC 27 HRC 28 HRC 32 HRC 26 HRC 36 HRC 37 HRC 38 HRC 26 HRC 36 HRC 37 HRC 38 HRC 30 HRC 36 HRC 37 HRC 38 HRC 15 / 22 HRC 25.4 HRC 26 HRC 19 / 27 HRC 23 / 30 HRC Max. 24 35 HRC 22 HRC 23 HRC 23 HRC 25.4 BHN 235 BHN 241 BHN 241 BHN 255 HARDNESS HRC RANGE HRC

API 5CT

GROUP 1

H-40 J-55 K-55 N-80 M-65 L-80 L-80 13CR C-90 C-95 T-95 P-110 Q-125 SM-95G SM-125G SM-140G SM-150G SM-155G SM-80T SM-95T SM-95TT SM-110T SM-110TT SM-125TT SM-80TS SM-90TS SM-95TS SM-110TS SM-80S SM-90S SM-95S SM-110S SM-90SS SM-C100 SM-C110 SM-80L SM-80LL SM-95L SM-95LL SM-110L SM-110LL SM13CR-80 SM13CR-85 SM13CR-95 SM13CRS-80 SM13CRS-90 SM13CRS-95 SM13CRS-110 SM13CRM-80 SM13CRM-95 SM13CRM-110

GROUP 2

36 36

HRC 25.4 BHN 255

GROUP 3 GROUP 4 SM SERIES G GENERAL & DEEP WELL SERVICE

T, TT HIGH COLLAPSE STRENGTH

TS HIGT COLLAPSE & SOUR WELL SERVICE S SOUR WELL SERVICE

36 36 36 36

SS SEVERE SOUR WELL SERVICE L, LL LOW TEMPERTURE SERVICE

NEW SM SERIES

CO2 CORROSIVE WELL SERVICE

CO2-LOW H2S CORROSIVE WELL SERVICE

SM22CR-65 SM22CR-110 SM22CR-125 SM22CR-140 SM25CR-75 SM25CR-110 SM25CR-125 SM25CR-140 SM25CRW-80 SM25CRW-125 SM25CRW-140

AVAILABLE GRADES
AVAILABLE GRADES

SPECIFICATION

REMARKS

API 5CT

M65 : CHARPY IMPACT TEST

SSCC TEST C-90, T-95 : th 80%SMYS

CHARPY IMPACT TEST SM SERIES CHARPY IMPACT TEST MIN AVE : 30FT-LB (10 10 2V) MIN SINGLE : 20FT-LB (10 10 2V) At50F (46) COLLAPSE TEST SEE PERFORMANCE TABLE

SSCC TEST SM-S, TS SM-90SS : Sc 10 (BENT BEAM) : Sc 12 (BENT BEAM) SM-C100, C110 :th 85%SMYS (NACE)

Mod NACE SSCC TEST SM110S : 0.1 atm H2S th 80% SMYS

CHARPY IMPACT TEST SM-L SERIES : MIN AVE : 20FT-LB (10 10 2V) MIN SINGLE : 15FT-LB (10 10 2V) At50 F (46) SM-LL SERIES : MIN AVE : 23.1FT-LB (10 10 2V) MIN SINGLE : 15.4FT-LB (10 10 2V) At67 F (55) NEW SM SERIES

AVAILABLE GRADES
AVAILABLE GRADES
MECHANICAL PROPERTIES SPECIFICATION APPLICATION CO2-H2S-CI CORROSIVE WELL SERVICE GRADE TENSILE YIELD STRENGTH STRENGTH (psi) (psi) HARDNESS ELONGATION (%) HRC RANGE HRC HRC 32 HRC 33 HRC 32 HRC 34 HRC 35 HRC 32 HRC 35 HRC 33 HRC 36 HRC 37 HRC 39 HRC 34 HRC 36 HRC 37 HRC 38 HRC 34 HRC 36 HRC 37 HRC 38 HRC 40 HRC 40 HRC 38 HRC 38 HRC 40 HRC 40 HRC 40 REMARKS

NEW SM SERIES

SM2035-110 110,000140,000 115,000 11 SM2035-125 125,000145,000 130,000 9 SM2535-110 110,000140,000 115,000 12 SM2535-125 125,000145,000 130,000 10 SM2535-130 130,000150,000 135,000 10 SM2242-110 110,000140,000 115,000 13 SM2242-125 125,000145,000 130,000 9 SM2550-110 SM2550-125 SM2550-130 SM2550-140 SM2050-110 SM2050-125 SM2050-130 SM2050-140 SM2060-110 SM2060-125 SM2060-130 SM2060-140 SM2060-150 SM2060-155 SMC276-110 SMC276-125 SMC276-130 SMC276-140 SMC276-150 110,000140,000 125,000145,000 130,000150,000 140,000160,000 110,000140,000 125,000145,000 130,000150,000 140,000160,000 110,000140,000 125,000145,000 130,000150,000 140,000160,000 150,000170,000 155,000175,000 110,000140,000 125,000145,000 130,000150,000 140,000160,000 150,000170,000 40,00080,000 55,00080,000 55,00080,000 80,000110,000 120,000 130,000 135,000 145,000 120,000 130,000 135,000 145,000 120,000 130,000 135,000 145,000 155,000 160,000 115,000 130,000 135,000 145,000 155,000 60,000 75,000 95,000 100,000 15 13 12 11 16 14 12 12 16 14 13 12 11 11 20 14 12 10 10 API FORMULA API FORMULA API FORMULA API FORMULA API FORMULA

API 5CT (ERW)

GROUP 1

H-40 J-55 K-55 N-80 M-65

GROUP 2

65,00085,000 85,000

HRC 22 (BHN 235)

SM-E SERIES (ERW)

GE SM-65GE GNENRAL &DEEP SM-80GE WELL SERVICE SM-80TE TE HIGH COLLAPSE STRENGTH

65,00085,000 85,000 80,000110,000 100,000 80,000110,000 95,000

API FORMULA API FORMULA API FORMULA HRC 25 COLLAPSE TEST SEE PERFORMANCE TABLE

REMARKS 1. Grade SM-S, SB are designed to prevent sulfide stress corrosion cracking (SSCC), but not designed to prevent general corrosion CO2 or CO2+H2S environment, so inhibitor usage should be considered. 2. Grades from SM22CR to SMC276 are designed to prevent both SSCC and general corrosion. 3. Grades with are ERW products. 4. Example of SM-Series names (1) SM-90SB : SUMITOMO-90,000psi minimum yield strength special sour well service. (2) SM13CR-80 : SUMITOMO 13%Chromium steel-80,000psi minimum yield strength. (3) SM2550-110 : SUMITOMO 25%Chromium 50%Nickel 6%Molybdenum alloy-110,000psi minimum yield strength.

AVAILABLE GRADES
THE NEW SM-SERIES AND THEIR APPLICATIONS TO CORROSIVE WELLS

Concept of Material Selection according to Gas (CO2) and H2S) Partial Pressure
SM 25CRW-110, 125 (250) SM 25CR-110, 125 (250) SM 22CR-110, 125 (200) SM 25CRW-80 SM 25CR-75 (250) SM 22CR-65 (200) SM 2535-110, 125, 130 SM 2035-110, 125 SM 2242-110, 125 (250) SM 2550-110, 125, 130, 140 (300)

103

104

102 SM 13CR-80 -85 (150) Partial Pressure of CO2 (atm) 10 SM 13CRM-80 95 110 (175) SM 13CRS-80 95 (175)

103

102

(Note) SM 2050, SM 2060, SM C276 are available for well containing free S

10

10-1

SM-95G API J-55 N-80 P-110 (Q-125) (150)

SM-80S SM-90S, 95S SM-110S API L-80, C90 T-95 (150)

SM90SS, SM-C100, SM-C110 1

10-2

10-1

10-3 10-2

10-4 10-4 10-3 10-2 10-1 1 10 102 103

Partial Pressure of H2S (atm) (Note) C - content should be less than 50,000ppm for SM 9CR and SM 13CR

Partial Pressure of CO2 (psi)

AVAILABLE GRADES
Special Applications for Corrosive Well Environments Special Application for Corrosive Well Environment Special Application Special Application Special Application
Mild Environment API Specification J-55 M-65 N-80 P-110 (Q-125) SM-95G (SM-125G) L-80 C-90 T-95 SM-80S SM-90S SM-95S SM-110S SM90SS SM-C100 SM-C110 SM13CR-80 SM13CR-85 SM13CR-951 SM13CRS-80 SM13CRS-90 SM13CRS-95 SM13CRS-110 SM13CRM-801 SM13CRM-951 SM13CRM-1101 SM22CR-652 SM22CR-110, -1253 SM25CR-752 SM25CR-110, -1253 SM25CRW-802 SM25CRW-110, -1253 SM2535-110, -125, -130 SM2242-110, -125 SM2035-110, -125 SM2550-110, -125, -130, -140 SM2050-110, -125, -130, -1404 SM2060-110, -125, -130, -140, -150, -155 SMC276-110, -125, -130, -140, -1504
4

Special Application

Sulfide Stress Corrosion Cracking (Medium Pressure and Medium Temperature)

Cr or Cr-Mo Steel

SM110S H2S0.1atm

Sulfide Stress Corrosion Cracking (High Pressure and High Temperature) Wet CO2 Corrosion

Cr or Cr-Mo Steel

Higher Yield Strength for Sour Service

13Cr (Mod. AISI 420)

Quench and Tempered

13Cr-5Ni-2Mo

Quench and Tempered

13Cr- 5Ni- 1Mo

Quench and Tempered

Wet CO2 with a little H2S Corrosion

22Cr-5Ni-3Mo 25Cr-7Ni-3Mo

Duplex Phase Stainless Steel

2 3

Solution Treated As Cold Drawn

25Cr-7Ni-3Mo-2W Wet CO2 and H2S Corrosion 25Cr-35Ni-3Mo 22Cr-42Ni-3Mo 20Cr-35Ni-4Mo Most Corrosive Environment 25Cr-50Ni-6Mo 20Cr-50Ni-11Mo 20Cr-58Ni-13Mo 16Cr-54Ni-16Mo-W

As Cold Drawn

As Cold Drawn
4

Environment with Free Sulphur

1 These materials are not suitable for H2S containing environments.

SM-SERIES GRADE DESCRIPTION

1. CASING AND TUBING FOR GENERAL AND DEEP WELL SERVICE
SM-G meant for general and deep well service are remarkable for their high yield and tensile strengths while maintaining good ductility and fracture toughness. SM-95G was developed as an intermediate grade between N-80 and P-110 to provide economical flexibility in designing casing strings. SM-125G, SM-140G, SM-150G, and SM-155G offer additional tensile and yield strengths for deep well services.
Yield Strength Grade min psi (kg/m ) SM- 95G SM-125G SM-140G SM-150G SM-155G 95,000 ( 66.8) 125,000 ( 87.9) 140,000 ( 98.4) 150,000 (105.5) 155,000 (109.0)
2

max psi (kg/m ) 125,000 ( 87.9) 155,000 (109.0) 170,000 (119.5) 180,000 (126.5) 185,000 (130.1) 110,000 ( 77.3) 140,000 ( 98.4) 150,000 (105.5) 160,000 (112.5) 163,000 (114.6)

Tensile Strength

Elongation min %

Impact Properties min Ave Value At-50 F (- 46) ft-lb (kg-m)

API Formula

15 (2.1) (Specimen: 10 by 10 mm)

CHARACTERISTICS 1. Tensile Strength The resistance to collapse and the longitudinal high strength requirements of well casing is becoming increasingly important with the drilling of deeper and deeper wells. SM-125G through SM-155G offer the high strength properties. 2. Mechanical Properties Mechanical Properties of SM-G series are shown in above Table. SM-125G through SM-155G offer the required high strength properties. 3. Toughness The Toughness of SM-G is equivalent to that of P110, Q125. Typical longitudinal and transverse impact properties are shown in Fig. 4. Micro Structure Typical micro structures are shown in Photo. Each photo shows a well quenched and tempered microstructure.
Photo Tempered Microstructure (500) SM-150G casing
Absorbed energy (ft-lb) 120 100 80 60 40 20 0 Longitudinal 10x10x2V Transverse 10x10x2V SM140G

SM-150G coupling
Brittle fracture (%)

100 80 60 40 20 0 -150 -100

-50 0 50 Testing Temperature ( F)

Typical Longitudinal and Transverse Impact Properties

SM-SERIES GRADE DESCRIPTION

Application of High Strength Grades for Deep Sour Gas & Oil Wells As wells becomes deeper, high strength steels are needed for effective completion. Sumitomo can offer our high strength and high toughness steel for such completions, and have supplied plenty of SM-G Grades all over the world. The smallest amount of H2S contamination should always be taken into consideration when looking at high strength material applications. Fig shows the applicability of high strength steels for sour service integrating the following variables; H2S concentration, applied stress level and temperature. Sulfide stress corrosion cracking susceptibility increases with material strength and grades such as SM150G or SM155G should never be used if H2S is present.
appl.=y PH2S=1atm (25) appl.=(NACE solution, 25)

SM90S SM95S 150

P110

SM125G SM150G 300 no crack crack 250 Partial pressure of H2S (atm) 10

SM90S SM95S

P110

SM125G SM150G

1 crack 0.1 no crack 0.01

Test temperature ()

100 200

no crack 150 50 crack 100

Test temperature ( F)

0.001 SM90S SM95S 60 SM90S SM95S SM125G P110 SM150G 50 80 90 70 100 80 110 SM125G P110 90 100 SM150G 110 150 160 (kg/mm2) 170 180(ksi) no crack crack

120 130 140 Yield strength

70 90 100

80 110 120

90

100

110 160

120 170

(kg/mm2) 180(ksi)

130 140 150 Yield strength

Influence of H2S partial pressure on SSCC (appl.=y)

Dependency of SSCC susceptibility on test temperature (appl.=y, PH2S=1atm (25), NACE solution)
Threshold stress by 4 point bent beam bend test : >1.0y : 0.50.25 : 1.00.75 : 0.25 P110 SM90S SM95S 10 Partial pressure of H2S (atm) SM125G SM150G : 0.750.5

0.1

0.01

0.001 SM90S SM95S 60 80 90 70 100 80 110 SM125G P110 90 100 SM150G 110 120 (kg/mm2) 170 180(ksi)

120 130 140 150 160 Yield strength

SSCC susceptibility versus H2S partial pressure

SM-SERIES GRADE DESCRIPTION

2. CASING AND TUBING FOR SOUR OIL AND GAS SERVICE
In order to prevent possible sulfide stress corrosion cracking in sour gas and oil wells containing H2S, it is necessary to use specially manufactured tubing and casing. API 5CT Group 2 grade tubing and casing have been developed and used widely for this purpose. However these may not be adequate in high concentration of H2S. To address this, Sumitomo Metal, after years of research and development, has succeeded in developing improved materials with higher strength and higher corrosion resistance for casing and tubing. These are available in our SM-S & SM-SB series as shown below. Each of these grades is produced with rigid manufacturing controls covering chemical composition, heat treatment (quenching and tempering), tensile property, hardness and microstructure.
Tensile Strength Elongation min % min psi (kg/mm2) max psi (kg/mm2) min psi 80,000 (56.2) 90,000 (63.3) 95,000 (66.8) 110,000 (77.3) 95,000 (68.8) 105,000 (73.8) 110,000 (77.3) 125,000 (87.9) 100,000 (70.3) 103,000 (72.4) 105,000 (73.8) 115,000 (80.8) API Formula Yield Strength Hardness HRC 1522 25.4 HRC26 2330 min 1100 F (593) min 1100 F (593) min 1200 F (649) NACE Condition H2S=0.1 atm 80% SMYS NACE Threshold 85% SMYS Sc Value12 min 1150 F(621) Sc Value10 Tempering Temperature Sulfide Stress Corrosion Cracking Test

Grade SM-80S SM-90S SM-95S SM-110S

SM-C100 SM-C110 SM-90SS

100,000 (70.3) 110,000 (77.3) 90,000 (63.3)

115,000 (80.8) 125,000 (87.9) 105,000 (73.8)

105,000 (73.8) 115,000 (80.8) 100,000 (70.3)

1927 2330 Max.24

CHARACTERISTICS 1. Materials The chemical compositions have been carefully determined to provide resistance to sulfide stress corrosion cracking as well as to insure complete throughwall hardening. 2. Heat Treatment Quenching and tempering is done under rigid temperature control to assure homogeneous physical properties and metal structures. New Higher Strength Sour Resistant Grades SM90SB SM-100SB, SM-C100, SM-C110 have been developed. 3. Micro Structure These grades exhibit fully tempered martensite which is considered to be the most desirable for resistance to sulfide stress corrosion cracking. 4. Tensile Properties and Hardness Yield strength is limited within a narrow range and hardness is controlled to within the predetermined maximum limit. 5. Sulfide Stress Cracking (SSC) Performance SM sour resistant grades are designed for 85%SMYS in NACE condition or equivalent method such as Sc value (ex. Sc value). Excellent SSC resistance has been achieved through rigorous, chemical composition, heat treatment, microstructure, tensile properties, hardness and so on.

SM-SERIES GRADE DESCRIPTION

NACE Tensile Test and Bent Beam Test

20 110 : SM90SS

th; Threshold stress (ksi)

100

SM-C110 SM-C100 Sc value (10 ksi)

90

15

80 SM-90SS 70

Ordinary API grade

60

SM90SS

10 90 100 110 YS (ksi) 120 130 140

Relationship between YS and threshold stress

90

60

70 100

70 110

80

80 (kg/mm2) 120(ksi)

Yield strength

Relationship between YS and Sc value Test specimens for NACE Tensile Test

Sustained load types Sulfide stress corrosion cracking test apparatus

Constant load type Sulfide streeaa corrosion cracking test apparatus

SM-SERIES GRADE DESCRIPTION

3. HIGH COLLAPSE CASING FOR DEEP WELL SERVICE
Sumitomo High Collapse Casing SM-T grade is a seamless product designed for deep wells where high collapse pressures are anticipated. In order to meet deep well service requirements, SM-T casing has improved collapse properties well in excess of API ratings. These properties are achieved by strict mill control incorporating a unique production technique inclusive of quenching and tempering. SM-T casing shows a very high resistance to tension load, internal pressure, and collapse. SM-95TS is also highly resistant to sulfide stress corrosion cracking and can be used for deep and sour gas and oil service.
Yield Strength Grade SM- 80T SM- 95T SM95TT min psi (kg/mm2) 80,000 (56.2) 95,000 (66.8) 95,000 (66.8) 110,000 (77.3) 110,000 (77.3) 125,000 (87.9) max psi (kg/mm2) 110,000 ( 77.3) 125,000 ( 87.9) 125,000 ( 87.9) 140,000 ( 98.4) 140,000 ( 98.4) 155,000 (109.0) Tensile Strength min psi (kg/mm2) 100,000 (70.3) 110,000 (77.3) 110,000 (77.3) 125,000 (87.9) 125,000 (87.9) 135,000 (94.9) Elongation min % API Formula API Formula API Formula API Formula API Formula API Formula Refer to Performance Table Collapse Resistance

SM-110T SM-110TT SM-125TT

Higher

Maximum

collapse casing than SM-95T & SM-110T are available on request. ardness (HRC) of SM-95TS is controlled bellow 25. More narrow restricted yield strength range is available on request. Sulfide Stress Corrosion Cracking of SM95TS : Sc Value10

As wells are drilled deeper, the external pressures applied to well casings become greater. Thus, a well casing must have adequate collapse strength to withstand these horizontal pressures without deformation. For reasons of economy such casings should also be as light-weight as possible while still retaining ample collapse resistance properties. With this in mind Sumitomo Metals has developed its SM-T High Collapse Casing. This casing was developed from experiments in which Sumitomo studied the critical collapse pressure of a well casing under external pressure in relation to its longitudinal tensile strength and the geometry of its cross section. CHARACTERISTICS 1. Unique Production Technique The material for SM-T casing is carefully selected to insure structural homogeneity. Strict control of heat treatment and dimensional tolerances is adhered to throughout the manufacturing process. 2. Rigid Dimensional Control Dimensional tolerances, such as roundness, straightness, O.D. and wall thickness are strictly controlled. 3. Specified Collapse Value A collapse test is carried out on each production run of SM-T casing with the same frequency as the tensile test using the most modern testing equipment.

Specified Minimum Collapse Pressure 20,000 Example of Actual Data : SM-95T : SM-110T : SM-125TT
25

SM -1

15,000 Collapse pressure (psi)

1 TT M-1 S 0T

-9 SM

5T

10,000

AP

AP
IC -9

IP

-1

10

5,000

12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 D/t

SM-SERIES GRADE DESCRIPTION

4. CASING AND TUBING FOR ARCTIC SERVICE
Sumitomo SM-L grades are designed for high impact toughness at subzero temperatures, as this is experienced in arctic regions. These properties are achieved through tight material chemistry control and specific heat treatment. The following Tables show tensile and impact toughness properties.
Tensile Properties Yield Strength Grade min. psi (kg/mm2 ) SM-80L SM-80LL SM-95L SM-95LL SM-110L SM-110LL 80,000 (56.2) 95,000 (66.8) 110,000 (77.3) max. psi (kg/mm2 ) 110,000 (77.3) 125,000 (87.9) 140,000 (98.4) Tensile Strength min. psi (kg/mm2 ) 100,000 (70.3) 105,000 (73.8) 125,000 (87.9) API Formula Elongation min. % in 2 in

Impact Properties (Charpy Impact Value) Grade SM-80L SM-95L SM-110L Size of Specimen mm 10 by 10 10 by 7.5 10 by 5 10 by 2.5 Test temperature : 50 F (46) Min. Average Value of Each Set of Three Specimens ft-lb (kg-m) 20 (2.8) 15 (2.1) 10 (1.4) 5 (0.7) Min. Value of One Specimen Only of a Set ft-lb (kg-m) 15 (2.1) 11 (1.5) 8 (1.1) 4 (0.6)

Grade SM-80LL SM-95LL SM-110LL Test temperature : 67 F (55)

Size of Specimen mm 10 by 10 10 by 7.5 10 by 5

Min. Average Value of Each Set of Three Specimens ft-lb (kg-m) 23.1 (3.2) 18.5 (2.6) 12.7 (1.8)
(ft-lb) (kg-m) 16

Min. Value of One Specimen Only of a Set ft-lb (kg-m) 15.4 (2.1) 12.3 (1.7) 8.5 (1.2)

CHARACTERISTICS 1. Material Special steel is used in order to obtain sufficient resistance to low temperature impact. 2. Heat Treatment Both casing and coupling are quenched and tempered with special care. 3. Impact Properties (Example of SM-80L & SM-110LL)

110 100 90 80 Absorbed Energy 70 60 50 40 30 20 2 10 0 0 -140 -120 -100 -80 -60 -40 -20 0 20 40() 6 SM-80L 4 10 14 SM-110LL 12

-210 -180 -150 -120

0 -90 -60 -30 30 Testing Temperature

60

90( F)

NEW SM-SERIES
1. CORROSION CONTROL METHOD
1. Inhibitor Treatment Batch or Continuous Increase of Velocity above Critical Point Increase of Temperature above 120 C Selection of Treatment Operation & Treatment Facility Destroy Liquid Film Vaporizing Liquid Film Difficult & Some Risk Costly especially in Offshore Higher Cost Corrosion Problem

2. Plastic Coating

Increase of Temperature & Pressure Rapid Pressure Bleed off Acidizing Liquid Wire Line Job

Damaging Coating Film Coating Blister Damaging Coating Film Corrosion Problem

3. Suitable Material Selection

Maintenance Free Applicable in any well Condition In case Ni Base Alloy, Higher Strength, Thinner Wall Thickness Increase of Flow Velocity, Tubing Size Reduction Economical in long Well Life Reliable & Economical

Cast comparison between CRA completion versus other corrosion mitigation methods. Option remain the most economical, in spite of the high initial investment when considering costs on a life cycle basis. CRA (Corrosion Resistant Alloy) completion is more economical one after well life, in spite of high initial investment. Example Case Economic Comparison of CRA Completion with carbon steel with inhibitor in 13,000 ft highly corrosive well. Well depth : 13,000 ft Highly corrosive CRA : 3-1/2" 9.2# SM 2535-110 Carbon Steel : 4-1/2" 12.6# L-80 In this example CRA becomes the most effective option after 2 years of production.
2 Cum PVNI (Other)Cum PVNI (CRA)<$Millions> 1 0 -1 -2 -3 -4 -5 -6 -7 -8 -9 0 20 40 60 80 Months Since Completion 100 120 Batch No treatment Continuous CRA between the different completions

CRA (Corrosion Resistant Alloy, without Inhibitor) Batch (Inhibitor Treatment) Continuous (Continuous Inhibitor Treatment) No Treat PVNI : Present Value Net Income

NEW SM-SERIES
2. MECHANICAL AND THERMAL PROPERTIES OF NEW SM-SERIES
Mechanical properties of materials of New SM series
Materials No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Alloy SM13CRS-95 SM22CR-65 SM22CR-110 SM25CR-75 SM25CR-110 SM25CRW-80 SM25CRW-125 SM2035-110 SM2535-110 SM2242-110 SM2550-110 SM2550-140 SM2050-110 SM2060-110 SMC276-110
Cold Reduction (%)

Specific Gravity 25 C 7.69 7.85 7.85 7.85 7.85 7.85 7.85 8.10 8.07 8.14 8.29 8.33 8.58 8.71 8.87 201 203 198 189 191 204 200 203 205 210 211 212 216 218 220

Young' Modulus (GPa) 100 C 199 196 194 188 184 199 198 194 194 197 195 202 201 205 207 200 C 192 187 184 180 177 191 191 181 189 184 186 190 192 196 197 250 C 188 187 189 193 193 188 188 178 187 187 185 198 196 196 196 25 C 0.27 0.30 0.25 0.29 0.26 0.33 0.27 0.32 0.31 0.31 0.31 0.31 0.33 0.33 0.33

Poisson's Ratio 100 C 0.27 0.28 0.24 0.28 0.25 0.32 0.27 0.30 0.29 0.29 0.29 0.30 0.31 0.31 0.31 200 C 0.26 0.28 0.23 0.28 0.24 0.33 0.27 0.31 0.30 0.28 0.29 0.30 0.31 0.31 0.31 250 C 0.26 0.29 0.24 0.28 0.27 0.33 0.27 0.30 0.30 0.29 0.28 0.30 0.31 0.31 0.31

0 0 15 0 10 0 10 20 20 20 20 20 20 20 20

Thermal properties of materials in New SM series

Materials No Alloy Thermal Conductivity Heat Capacity Coefficient of Thermal Thermal Diffusivity (10-6J/m3 C) (W/m C) Expansion (10-6 C-1) (10-6m2/s) Cold Reduction 25- 25- 2525 C 100 C 200 C 300 C 25 C 100 C 200 C 300 C 25 C 100 C 200 C 300 C (%) 100 C 200 C 300 C 0 0 15 0 10 0 10 20 20 20 20 20 20 20 20 Specific Heat (J/kg C) 25 C 100 C 492.0 494.1 495.8 493.3 492.0 536.0 536.0 468.6 470.7 467.4 459.8 458.1 442.2 432.2 412.5 200 C 526.8 524.7 525.5 523.8 523.8 574.0 574.2 488.3 490.8 487.4 479.5 477.8 452.4 448.1 429.7 300 C 565.3 554.4 561.9 559.8 561.5 636.0 635.6 508.8 508.8 504.6 469.2 497.1 466.3 464.4 448.9

1 SM13CRS-95 2 SM22CR-65 3 SM22CR-110 4 SM25CR-75 5 SM25CR-110 6 SM25CRW-80 7 SM25CRW-125 8 SM2035-110 9 SM2535-110 10 SM2242-110 11 SM2550-110 12 SM2550-140 13 SM2050-110 14 SM2060-110 15 SMC276-110

10.7 10.9 11.2 4.70 5.18 5.10 5.03 3.49 3.75 4.10 4.39 16.4 19.5 20.9 22.2 447.7 13.4 14.0 14.2 3.81 3.81 3.97 4.08 3.74 4.48 4.94 5.27 14.3 17.1 19.7 21.5 465.3 12.5 12.8 13.3 3.64 3.93 4.01 4.08 3.77 4.12 4.52 4.73 13.7 16.2 18.1 19.3 468.2 12.7 13.2 13.5 3.52 3.64 3.79 3.88 3.82 3.86 4.39 4.73 13.4 15.1 16.7 18.3 464.8 12.5 12.7 13.0 3.38 3.48 3.68 3.82 3.86 4.60 4.98 5.36 13.1 16.0 18.3 20.5 465.3 13.2 13.6 13.9 3.37 3.73 3.87 3.92 3.92 4.23 4.52 5.02 13.2 15.7 17.5 20.3 498.0 13.0 13.2 13.5 3.31 3.64 3.83 3.93 3.93 4.25 4.55 5.08 13.0 15.3 17.7 19.9 497.5 14.8 14.8 14.8 2.80 3.04 3.36 3.69 3.82 3.93 4.17 4.39 10.7 12.0 14.0 16.3 453.5 14.5 14.9 14.9 2.88 3.11 3.48 3.76 3.75 3.99 4.23 4.39 10.8 12.4 14.7 16.6 452.7 14.6 14.7 14.9 2.81 3.02 3.42 3.79 3.68 3.96 4.31 4.52 10.4 12.0 14.7 17.1 451.5 14.0 14.1 14.2 2.74 2.79 3.27 3.60 3.75 4.18 4.23 4.52 10.3 11.7 13.9 16.3 442.2 13.6 13.9 14.1 2.81 3.02 3.29 3.67 3.67 3.86 4.18 4.27 10.3 11.7 13.8 15.6 441.8 13.2 13.5 13.6 2.69 2.72 3.25 3.53 3.74 4.00 4.21 4.41 10.1 11.5 13.9 15.6 421.3 12.6 12.8 12.8 2.67 2.89 3.24 3.51 3.74 3.96 4.23 4.35 10.0 11.5 13.7 15.3 415.5 12.2 12.4 12.5 2.59 2.60 3.19 3.50 3.67 4.09 4.14 4.27
-1 -1

9.5 10.6 13.2 14.9 398.7

Note : 1cal/cms360kcal/mh419Wm

NEW SM-SERIES
3. Martensitic Stainless Steel and Duplex Stainless Steel (13CR, 13CRM, 13CRS, 22CR)
3.1 Chemical composition
Chemical Composition (wt%) Material C SM13CR SM13CRM SM13CRS SM22CR SM25CR SM25CRW 0.22 0.03 0.03 0.03 0.03 0.03 Si 1.00 0.50 0.50 1.00 0.75 0.80 Mn 1.00 1.00 1.00 2.00 1.00 1.00 0.20.8 0.20.8 4.06.0 5.06.5 4.56.5 5.57.5 6.0 Cu Ni Cr 12.014.0 11.014.0 11.513.5 21.023.0 24.026.0 24.026.0 0.21.2 1.52.5 2.53.5 2.53.5 2.53.5 0.080.20 0.100.50 0.100.30 2.012.50 0.240.32 Mo W N

3.2 CO2 Corrosion Resistance (1) High Cr steels such as 13Cr stainless steels are resistant to CO2 corrosion and have been widely, and successfully used in wells containing CO2 and CL-. (2) Effect of Cr content and temperature on CO2 corrosion are shown in Fig. 13CR critical temperature is 150; For 13 CRM & 13CRS is 175. Duplex stainless steels (22Cr, 25Cr) have excellent corrosion resistance up to a temperature of 250

0 15 500 Corrosion rate (mm/Y) Corrosion rate (mpy) 70

100

200

Temperature () 300 400

500

600

C-steel 60 2Cr 5Cr 9Cr-1Mo 50 Corrosion rate (mm/y) 13Cr 22Cr/25Cr 40

2500

10

2000 Corrosion rate (mpy)

1500

30 1000 20 500 10

0 0.01 0.05 0.1 0.5 1 Cr content (wt.%) 5 10

Effect of Cr content of commercial tubular goods on corrosion rate by loop tester

(Synthetic sea water, CO2 partial pressure 0.1 MPa (60 test temperature 60test duration 150h, flow velocity 2.5 m/s, specific volume : 800 cc/cm2)

0 0 0 200 100 Temperature () 300

Effect of temperature on corrosion rate by autoclave

(Synthetic sea water, CO2 partial pressure ; 3.0 MPa (R.T.), test duration 72h, flow velocity 2.5 m/s, specific volume : 42 cc/cm2)

NEW SM-SERIES
0.05 0.5 5 20 100 5 9Cr-1Mo 13Cr (420) SM22Cr-Duplex SM25Cr-Duples Corrosion rate (mm/Y) 0.05 0.5 5 20 150 (A) 13Cr 5 CO2 1 Corrosion rate (mm/y) 0.5 10 0.1 (B) 25Cr 0.2 0.1 0.1 10 5 5 3.0 MPa 0.1 MPa 100 50 Corrosion rate (mpy)

0.5

50 102 103 104 105 102 Cl- (ppm) 103 104 105 100

100 200

150 300

200 400

250 500

() ( F)

Effect of Cl- low concentration on the corrosion rate of Cr steels at 150 in the autoclave.
(3.0MPa CO2 at 25, test duration 96hr, flow velocity 2.5 m/s)

Effect of CO2 partial pressure and temperature on corrosion rate of Cr steel

(5% NaCl, CO2 3.0 and 0.1 MPa at 25, test duration 96hr, flow velocity 2.5 m/s)

101 Solid mark : Cracked Half Solid : Pitting GC : General Corrosion 100 13Cr Corrosion rate (mm/Y) 10
-1

101 Solid mark : Cracked Half Solid : Pitting GC : General Corrosion GC 13Cr GC

GC

GC

100 Corrosion rate (mm/Y)

10-1

SM13CRS

SM13CRS 10-2

10-2

22Cr 10
-3

22Cr

10-3

10-4

10-4 0 50 100 Temperature () 150 200

50

100 Temperature ()

150

200

Effect of temperature on corrosion resistance of SM13CRS

(5%NaCl + 3.0MPa (450psi) CO2 + 0.001MPa (0.15psi) H2S)

Effect of temperature on corrosion resistance of SM13CRS

(25%NaCl + 3.0MPa (450psi) CO2)

NEW SM-SERIES
3.3 Sulfide Stress Corrosion Cracking (SSCC) Resistance (1) 13CR has a high SSCC susceptibility as shown in below fig; 13CR usage is not advisable for usage in environments containing a small amount of H2S ( 0.03atm). (2) 13CRS has good SSCC resistance in environments containing up to 0.03atm H2S. (3) Duplex stainless steels (SM22CR, SM25CR, SM25CRW) are recommendable over marternsitic stainless steel (SM13CRS) in a small amount of H2S.
Calculated H2S at 80 (MPa) 10-3 10-2

10-4 13Cr (Y. S. 602MPa) Temperature 150 100 50 13Cr (Y. S. 768MPa) 300 200 100 25Cr (Y. S. 553MPa) Temperature 25Cr (Y. S. 822MPa) Temperature ( F) Temperature ( F)

10-1

: Type 316L : SM25CR : SM25CRW SM25CR : SM22CR SM25CRW Solid mark : Crack SM22CR 25Cr Type 316L 22Cr Cl- content (ppm) 105

104

150 100 50 10-4 10-3 10-2 PH2S (MPa) 10-4 10-3 10-2 PH2S (MPa)

300 200 100

103

102

10-4

10-3 10-2 H2S (MPa)

10-1

Effect of H2S partial pressure and temperature on the susceptibility SSCC. 5% NaCl, 3.0MPa CO2 + H2S at 25(77F, test duration 336h, flow velocity 2.5m/s 1y with notch

SCC susceptibility of duplex stainless steel in C1- H2S environment.

: No SCC, : SCC (SSRT method ; 80, strain rate 4.2 x 10-5/s)(annealed)

13Cr

Cr:12-16%

Ni:5-7% 120

1.2 SM25CRW SM25CRW SM25CR 1 SM25CR

0.1 0.01 0.001 L/L0

0.8

Corrosion rate (mm/y)

60 0.1 0.01

0.6

0.4 0.001

25 0.1 0.01 0.001 ( : SSC, 13Cr : NcSSC, 1Mo : Pitting) 2Mo SM13CrS 3Mo

0.2

0.5

2 Cl- (104ppm)

10

SCC susceptibility of duplex steel in C1- H2S environment.

: No SCC, : SCC (SSRT method ; 80 ,Calculated H2S 0.015MPa strain rate 4.2 x 10-5/s)

Effect of Mo content on corrosion rate and SSCC. SM13CRS

NaCl + 3.0MPa (450psi) CO + 0.001MPa (0.15pti) H S (5% ( 4-point bent beam with notch, 1y, 336h,
2 2

NEW SM-SERIES
3.4 Erosion properties (1) 13CR and Duplex staianless steels have improved erosion properties.

0.014

0.012

Corrosion rate (mm/y)

0.01

: 13Cr : 22Cr duplex

0.008

0.006

0.004

0.002

0 0 50 100 150 200 250 300 Gas velocity (m/s)

Effect of flow velocity on corrosion rate of 13Cr and 22Cr duplex stainless steels

NEW SM-SERIES
4. RECOMMENDABLE BRINES FOR 13CR AND DUPLEX STAINLESS STEEL
C-steel Corrosion
2

PH NaCl CaCl2 MgCl2 ZnCl2 NaBr CaBr2 MgBr2 ZnBr2 1) In 60 0.1MPaCO2 : pH4 : 3pll4 : pH3

13Cr Corrosion
3

22Cr (Duplex s.s.) Pitting 4) Pitting potential : Vp0.3V : 0Vp0.3 : Vp0

4

SCC

2.3) Autoclave test 150, 0.4MPaCO2 2) : : C.R.1g/m2/h 3 : : C.R0.1 : 1<C.R._10 : 0.1C.R.1.0 : C.R.>10 : C.R.1.0 (1g/m2/h=1.1mm/year)

5) : Crack Free : Crack

Brine with a corrosion inhibitor, a biocide, and an oxygen scavenger added is acceptable as a completion fluid but careful investigation is required at selection brine and additives as a packer fluid. An oil base solids free packer fluid is recommended, either diesel oil with a corrosion inhibitor additive or one of the proprietary oil base packer (Drilling) fluids. All fluids pumped into wells equipped with stainless steel materials should be adequately deoxygenized. Any additives to completion brines and or packer fluids such as corrosion inhibitors, biocide, etc, should be carefully selected to avoid possible degradation with time and subsequent negative effect on stainless steel integrity. Generally Oil based solids free packer fluids such as diesel oil are acceptable.

NEW SM-SERIES
5. H2S+CO2+CL- CORROSION (NI BASE ALLOY)
High Alloy Materials become necessary where severe well conditions with high concentrations of H2S, CO2 and CL- brines are encountered. (1) High Ni corrosion resistant alloys for OCTG feature a single austenitic phase. Strength is developed through cold working. Addition of essential alloying elements such as Cr, Ni, Mo determines the corrosion resistance properties. (2) Resistance to general (weight loss) corrosion and localized (pitting and crevice) corrosion is achieved by the formation of a stable passivation film on the material surface. (3) The effect of fundamental elements on corrosion behaviors are shown in the following Figures. These can be recapped as follows. Cr is effective for high temperature service. Mo is effective for low PH condition. n combined H2S, CO2, CL- media, the basic minimal chemistry of Cr20%, Ni30%, Mo3% is required. Hydrogen embrittlement susceptibility increases with material chemistries exceeding 60% Ni. (4) Precipitation hardened alloys (P.H.) are required as base materials for down hole equipment accessories, to be used in conjunction with CRA OCTG materials. Our precipitation hardened alloys have superior properties at least comparable to conventional alloys.
250(482 F) 300(572 F) 350(662 F) 0 3 6 0 3 Mo (%) 15 30
C SC

0 3 6

0 3 6 0 3 Corrosionresistant region
C

0 3 Mo (%) 6 10 15 60 Corrosion-resistant region 25

) (%

10

Corrosion-resistant region

10 Mo (%)

10

6
C

15 30
SC

6
C SC IG TG

15 30 25
Cr (%

TG

10 15 60

10 15 60

TG

SC

25
Cr (%

20 40 20 Ni (%) 0 15

20 0 15

20 40 20 Ni (%) 0 15

Cr

40 20 Ni (%)

Fig.28 Corrosion resistant region of Fe-Cr-Ni-Mo alloy

(20% NaCl+0.5% CH3COOH, 1.0 MPa H2S-1.0MPa CO2-pH 2)

3Mo 30 Cr (%)

350 SM3040 SM2535

20Cr 15 12 Mo (%) pH0.5 SM2050 9 pH2.0 6 HE

25

250 20 SM2030 150 15 Austenitic single phase 0 10 20 30 40 Ni (%) 50 60 70

3 0

6Mo (5Mo) 30 Cr (%)

350

30

40

50 Ni (%)

60

70

25

SM2550 300 SM2035 250

Fig. 30 Corrosion resistant regionpHalloying element

(1)Corrosion resistance pH 2 ; No SCC and C.R. 0.05 mm/y, (2)Environment, SCC : 20% NaCl 0.5% CH3COOH1.0 MPa H2S 1.0 MPa CO2 250, HE : NACE TM01-77 solution, Iron coupling/ 4001,000h aging)

20

15 0 10

(5Mo) 20 30

Austenitic single phase (6Mo) 40 Ni (%) 50 60 70

Fig. 29 Corrosion resistant region temperature-alloying

NEW SM-SERIES
Cr (mass%) Solid mark : Secondary crack 30 25 20 SCC 15 30 40 (a) SCC SM 2550 300 Cr (mass%) SM 2242 SM 2535 3 6 9 1 Mo+W(%) 2 15 Relationship between testing temperature and Mo content of Ni Base Alloys in H2S-CL- environment in the SSRT tests. (SSRT test condition ; 25% NaCl-0.5% CH3COOH, 7 atm H2S, E=4.010-6S-1) No SCC 12 15 30 25 20 Localized corrosion 3 9 (10) 12 Mo (mass%) (b) Localized corrosion 6 15 50Ni 50 60 Ni (mass%) 70 No SCC 6Mo 422K (300 F) 450K (350 F) 477K (400 F) 505K (450 F)

SCC Temperature ( F) 450 SM 2060 Mo 400 350 SM 2050

SM C276

The effect of Mo content on SCC and localized corrosin in S-containing sour environment (25% NaCl+1g/ S, 1.0MPaH2S+1.0MPaCO2 1.0y, 336h)

Chemical Composition (Wt %) C SM-2035 SM-2535 SM-2242 SM-2550 SM-2050 SM-2060 SM-C276 0.03 0.03 0.05 0.03 0.03 0.03 0.01 Si 0.75 0.50 0.50 1.00 0.50 0.50 0.08 Mn 1.00 1.00 1.00 1.00 1.00 1.50 1.00 Cu 0.70 1.50 1.50 3.00 1.20 2.00 2.00 Co2.5 Ni 33.0 38.0 29.0 36.5 38.0 46.0 47.0 54.0 49.0 53.0 Bal Bal Cr 20.5 23.5 23.0 27.0 19.5 24.0 23.0 26.0 19.0 23.0 19.0 22.0 14.5 16.5 Mo 4.00 5.00 2.50 4.00 2.50 4.00 6.00 9.00 10.1 12.0 11.0 14.00 15.0 17.0 V0.35 1.20 0.69 3.0 1.50 1.50 3.0 4.5 4.0 9.0 4.0 7.0 Ti W 0.20 0.80 Fe

Above chemical compositions are typical

FEATURES OF PREMIUM CONNECTIONS

Improved stress distribution supported by finite element analysis. Reduced machining tolerances for better control over applied torquevalues for make up and safer performance. Strong and efficient modified burttress-type thread. Greatly increased resistance to galling by improvements in thread design. Field-proven reliability of metal-to-metal seal. Streamlined internal profile for improved flow, lower pressure loss had reduced risk of erosion and corrosion. Threaded and coupled concept ensures economical and quick repairs without "upsets." Options Special clearance couplings Special bevel couplings

Proven metal-to-metal sealing that works safely even under extreme tension. Anti-galling design and up-to-date surface treatment that pemits trouble-free use of corrosion resistant alloy tubulars. Hooked thread concept that optimizes stress distributionsupported by finite element analysiswhile resisting "jump out." Streamlined internal profile capable of handling high velocity corrosive gas flows. A threaded and coupled concept that ensures repairability and allows the use of cold worked corrosion resistant chromium and nickel alloys. Available sizes from 23/8 " to 133/8 " O.D. Options Special clearance couplings Special bevel couplings

FEATURES OF PREMIUM CONNECTIONS

15hooked thread for optimal load transmission and resistance to "jump out." Independent metal-to-metal multi-seal arrangement for excellent gas-tight performance with burst and collapse pessure ratings equivalent to the pipe body. External torque shoulder for easy running. Non-upset integral connection so damagad threads may be cut off and remachined.

Newly patented sealing system with 20apered metal-to-metal seal provides gall-free gas-tightness which maintains their integrity, even under the most severe condition as true tubing application in casing sizes (41/2"14 "). Hooked thread design increases resistance to jumping-out and decrease hoop stress on coupling under higher bending and tension/compression, making this connection suitable for application in long deviated or horizontal well. Reverse angle torque shoulder results in superior sealing performance and structual resistance under severe combined load condition. Streamlined internal profile with tight tolerance minimize gas flow turbulance. High compression version (VAM TOP HC) is available. High torque version (VAM TOP HT) provides reinforced torque capacity for liner application where high torque is anticipated. Special coupling with 80% and 90% tensile effciency are avalilable.

FEATURES OF PREMIUM CONNECTIONS

Ideally suited to controlled-yield material T&C design for controlled-yield material with no cold working or upsetting that could alter metallurgy. Self energizing metal-to-metal seal with 50% taper provides pressure integrity to API minimum-yield. Tensile efficiency equals 100% Hook threads with 3reverse angle and proper thread length prevent jumpout under tension or bending, and reduce tensile hoop stresses. Smooth bore for turbulence-free flow. The VAM HW ST is the ideal connection for extra-heavy casing application.

A make-up arrestor positions the coupling accurately on the mill end. Pin to pin torque shoulder for positive torque stop on the field end allows overtorque and compression resistance. Modified hook thread profile, with -9reverse angle on the load flank and +20on the stabbing flank which provides superior load carrying performances. Increased thread taper, combined with a wider thread profile which allows deep stabbing with no cross-threading. Increased thread pitch to reduce make-up time. Jump-out free. Special thread design to offer superior thread sealing performances. Vanishing threads, fully covered. 100% tensile effciency for all sizes with standard API Buttress OD. Pins shoulder, thereby providing a smooth bore ID to minimize turbulence and energy losses. Pins shoulder, thereby providing high compression resistance and immunity to jump-in.

SPECIAL DRIFT TABLE

SPECIAL DRIFT TABLE
The following special drift, API alternative drift are available.
OUTSIDE DIAMETER INCH 7 7

MOMINAL WEIGHT LBS / FT 23.00 32.00 46.10 32.00

WALL THICKNESS INCH 0.317 0.453 0.595 0.352 0.450 0.557 0.395 0.435 0.545 0.595 0.595 0.625 0.400 0.495 0.333 0.489 0.534 0.582 0.514 0.625 0.580 0.625

DRIFT DIAMETER SPECIAL INCH 6.250 6.000 6.500 7.875 7.625 7.511 8.750 8.625 8.500 8.375 8.500 8.500 9.875 9.625 11.000 10.625 10.625 10.625 12.250 12.000 12.250 12.250 12.250 9.875 9.625 11.000 10.625 10.625 8.500 8.375 8.750 API ALTERNATIVE INCH 6.250 6.000 6.500 7.875 7.625 API STANDARD INCH 6.241 5.969 6.435 7.796 7.600 7.511 8.679 8.599 8.379 8.279 8.404 8.469 9.794 9.604 10.928 10.616 10.526 10.555 12.191 11.969 12.184 12.219

7-3 / 4 8-5 / 8

40.00

8-3 / 4 9-5 / 8 9-5 / 8 9-5 / 8 9-5 / 8

49.70 40.00 43.50 53.50 58.40 59.20 62.80 45.50 55.50 42.00 60.00 65.00

9-3 / 4 9-7 / 8

10-3 / 4 10-3 / 4 11-3 / 4 11-3 / 4

11-7 / 8 71.80 13-3 / 8 13-3 / 8 72.00 86.00 81.40 88.20

13-1 / 2 13-5 / 8

Over sized Casing ( Non API Size except 7-3/4" )

RESEARCH AND DEVELOPMENT

MATERIAL AND CONNECTION DESIGN
CUSTOMER SUMITOMO METALS SEARCH DATABASE Application Records Failure Records Expert System ECONOMICAL EVALUATION Analysis Profitability of Selected Material

Well Information
Well Condition Well Operation Running Condition

Material Selection

String Design
STRESS ANALYSIS Under Anticipated Load Conditions

Connection Design
FEM ANALYSIS CAD SYSTEM TESTS Make & Break Tests Leak Resistance Evaluation Test Thermal Cycle Tests Measurment of the Stress Failure Tests

Material Design & Evaluation

MATERIAL EVALUATION Evaluation under Simulated Well Condition Production Acidizing Completion, Packer Fluids Material Combination with DHE NEW MATERIAL DESIGN

DESIGN AND ANALYSIS

CAD

FEM

MARKING, COLOR IDENTIFICATION AND INQUIRY AND/OR ORDER DETAIL

MARKING, COLOR IDENTIFICATION

API 5CT N-80

DIE STAMP MANUFACTURER'S API LICENSE NO DATE OF MANUFACTURE LENGTH Mark TYPE OF THREAD SHIPPING MARK

5CT

. P DATE OF MFR 9-5/8 53.5 N S 41.5 BUTTRESS THREAD SUMITOMO METALS

MADE IN JAPAN NO1

API MONOGRAM COLOR COATING FOR GRADE IDENTIFICATION

SIZE LBS/FT GRADE PROCESS OF MANUFACTURE

PIECE NO

SM SERIES
DIE STAMP MANUFACTURE'S Mark SIZE LBS/FT GRADE LENGTH TYPE OF THREAD SHIPPING MARK

SUMITOMO METALS.

9-5/8

53.5

SM-95T

41.5

BUTTRESS THREAD

MADE IN JAPAN NO1

COLOR BAND COLOR COATING FOR GRADE IDENTIFICATION

PROCESS OF MANUFACTURE

PIECE NO

NEW SM SERIES
MANUFACTURE'S Mark COLOR BAND SIZE LBS/FT GRADE LENGTH TYPE OF THREAD SHIPPING MARK

SUMITOMO METALS

4-1/2

12.6 SM13CRS-95

31.5

VAM-ACE

MADE IN JAPAN NO1

PROCESS OF MANUFACTURE COLOR COATING FOR GRADE IDENTIFICATION NO DIE STAMP

PIECE NO

MARKING, COLOR IDENTIFICATION AND INQUIRY AND/OR ORDER DETAIL

GRADE API H-40 J-55 TUBING J-55 CASING K-55 N-80 M-65

COLOR IDENTIFICATION

COLOR COATING ON COUPLING BLACK BRIGHT GREEN BRIGHT GREEN BRIGHT GREEN RED

COLOR BAND ON COUPLING

ONE WHITE BAND

ONE BRIGHT GREEN + ONE BLUE BAND on Pipe Body Coupling shall be used L-80 TYPE 1 RED RED PURPLE PURPLE SILVER SILVER BROWN WHITE ORANGE ORANGE ORANGE ORANGE BROWN SKY BLUE PINK PURPLE YELLOW BLUE BROWN BROWN WHITE WHITE SKY BULE BROWN RED ORANGE BROWN WHITE WHITE PURPLE RED BROWN SILVER RED ORANGE BROWN RED PINK BROWN WHITE RED BROWN WHITE ONE YELLOW BAND ONE GREEN BAND ONE PURPLE BAND ONE WHITE BAND ONE WHITE BAND ONE WHITE BAND ONE WHITE BAND ONE WHIHT BAND ONE RED BAND ONE RED BAND TWO RED BAND ONE RED BAND TWO RED BAND TWO RED BAND ONE RED AND ONE BLUE BAND ONE BLUE BAND ONE BLUE BAND ONE BLUE BAND ONE BROWN BAND TWO BROWN BAND TWO BLUE BAND ONE SKY BLUE BAND ONE SKY BLUE BAND TWO SKY BLUE BAND ONE YELLOW BAND TWO PURPLE BAND ONE PURPLE BAND TWO PURPLE BAND TWO PURPLE BAND TWO PURPLE BAND TWO PURPLE BAND TWO GREEN BAND TWO GREEN BAND TWO GREEN BAND ONE YELLOW BAND ONE YELLOW BAND ONE BROWN BAND ONE YELLOW BAND

L-80 TYPE1 L-80 TYPE 13CR C-90 TYPE1 C-90 TYPE2 T-95 TYPE1 T-95 TYPE2 C-95 P-110 Q-125 TYPE1 Q-125 TYPE2 Q-125 TYPE3 Q-125 TYPE4 SM-95G SM SERIES SM-125G SM-140G SM-150G SM-155G SM-80T SM-95T SM-95TT SM-110T SM-110TT SM-125TT SM-95TS SM-80S SM-90S SM-95S SM-C100 SM-C110 SM-90SS SM-80L SM-95L SM-110L NEW SM SERIES SM13CR-80 SM13CR-85 SM13CR-95 SM13CRS-80 SM13CRS-90 SM13CRS-95 SM13CRS-110 SM13CRM-80 SM13CRM-95 SM13CRM-110

INQUIRY AND/OR ORDER DETAIL

You are requested to specify your conditions for the following items on your order sheet. Applicable specification, grade and type: (Ex.) SUMITOMO SM-95S SUMITOMO SM-95T SUMITOMO SM2535-110 Type of pipe : Casing or tubing Type of ends : Threaded or plain end Round (Short, Long), Buttress (casing) or Premium joint; NEW-VAM, VAM-ACE (casing, tubing) Non upset or External upset (tubing) Size (outside diameter) Weight per foot or wall thickness Range length (Range-1, 2, 3) Quantity Delivery date and shipping instructions Mill inspection by purchaser. If you have any special requirements, please specify the details accordingly. Hydrostatic test pressure Non-destructive inspection Type of joint (other than regular coupling) Special clearance coupling (same or higher grade) Special bevelled coupling Special designed joints (NEWVAM, VAMACE, VAMTOP, VAMFJL, VAMHWST, VAMPRO, DINOVAM, BIG) Coupling make-up (other than regular power fight): Torque turn device or hand tight Special drift or alternative drift (API 5CT) (EXAMPLE) ABC CO 1234-90 Specification Type of pipe Type of end Size. weight Quantity Delivery Mill inspection : SUMITOMO SM2535-110 : Tubing : VAM-ACE : 3-1/2" * 9.2# Range 2 : 12000 : xxx.xxx.xxx on site shipping mark as per attached sheet : Mill final inspection (No third partyinspection)

SUMITOMO METAL INDUSTRIES, LTD.

HEAD OFFICES Tokyo OfficeTowerY, 1-8-11, Harumi, Chuo-ku, Tokyo 104-6109, Japan Phone: Tokyo (03)4416-6111 Osaka Telex: J22865

5-33 Kitahama 4-chome, Chuo-ku, Osaka 541, Japan Phone: Osaka (06)220-5111 Telex: J63490 Fax: (06)223-0305

OVERSEAS OFFICES SUMITOMO METAL INDUSTRIES, LTD. European(London) 33, Cavendish Square, London W1M 9HF, England Phone: (20)8748-4480 Singapore Fax: (20)8748-8350

6 Shenton Way #25-11, DBS Building, Tower Two, Singapore 0106 Phone: (Singapore)6220-9193, 6224-5684 Cable: SUMITMETAL SINGAPORE Fax: (Singapore)6224-0386

Shanghai

Room 305, Golden Bridge Mansion, 2077 Yan An Road (W), Shanghai, China Phone: (021)62193868 Fax: (021)62193866

OVERSEAS AFFILIATES SUMITOMO METAL USA CORP. Chicago 8750 West Bryn Mawr Ave, Suite 1000 Chicago, IL 60631-3508 Phone: (773)714-8130 Houston Fax: (773)714-8183

333 Clay St. Suite 3650, Houston, TX 77002, U.S.A. Phone: (713)654-7111 Telex: 762362 Fax: (713)654-1261

SUMITOMO METAL AUSTRALIA PTY. LTD. Sydney Level 16, AMP Centre, 50 Bridge Street, Sydney, NSW 2000, Australia Phone: (02)221-7822, (02)221-7824 Fax: (02)233-7996, Telex: AA27439

SUMITOMO METAL PRODUCTS Plates & Sheets Plates, Hot rolled sheets & strip, Cold rolled sheets & strip, Galvanized @sheets, Precoated galvanized sheets, Vinyl-coated galvanized sheets, Electrogalvanized sheets, Floor plates, High tensile strength plates, Corrosion resisting plates, Low temperature service plates. Tubes & Pipes Seamless tubes & pipe, Electric-resistance-welded pipe, Large-diameter arc-welded pipe, Spiral welded pipe, Butt-welded pipe, Galvanized pipe, Coating pipe, Boiler & heat exchanger tubes, Tubes & pipe for nuclear power plant, Oil country tubular goods. Line pipe, Pipe piles, Seamless & welded stainless steel pipe, High alloy seamless tubes, Welding pipe fittings, High pressure gas cylinders. Bars & Shapes Round bars, Deformed high-strength reinforcing bars, Carbon & alloy steel for machine structural use, Spring steel, Cold heading qualities, Free cutting qualities, Lightweight welded beams, Wide flange shapes, Sheet piles. Casting & Forgings Gears, Rolls, Die forgings, Flanges, Ring-shaped rolled products, Various castings, Free forgings, Aluminum wheels. Rolling Stock Parts Solid rolled wheels, Axles, Wheels & axles units, Driving mechanisms, Flexible gear couplings, Couplers, Draft gears, Air springs, Bogie trucks. Fabricated Steel Products Tunnel supports, Steel segments, Prefabricated frames, Prefabricated bridges, High-strength bolts, Aesthetic transmission poles. Titanium CP titanium & Titanium alloy (Plates & sheets, tubes, billets and bars, forgings, rings, extrusions, wire & wire rods), Nb-Ti, Titanium clad copper.
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This catalogue is for your general information only and you should independently evaluate the accuracy and the usefulness of such information for your own particular purpose. You bear the full responsibility for determining the suitability of SMI's product for your own particular use. SMI disclaims all warranties, expressed or implied, including but not limited to those of usefulness, suitability for a particular purpose and noninfringement of the information contained in this catalogue. SMI shall not be liable for any direct, indirect, special, consequential or incidental damages, including but not limited to lost profits or revenues, costs of replacement of goods, or damages resulting from use of or reliance on the information contained in this catalogue. SMI deserves the right to alter the content of this catalogue, and also to discontinue the manufacture or to alter the specification of the products appearing in this catalogue at any time without prior notice.