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Practice Paper 2013 Class XII Subject Chemistry Set 2

Time Allowed: 3Hours Maximum Marks: 80

General Instructions:
1. All questions are compulsory. 2. Question numbers 1-8 are very short answer question and carry 1 mark. 3. Question numbers 9-18 are short answer question and carry 2 marks. 4. Question numbers 19-27 are short answer question and carry 3 marks. 5. Question numbers 28-30 are long answer question and carry 5 marks. 6. Use log table if necessary.

1. What is meant by doping in semiconductor?

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2. What is the role of graphite in the electrometallurgy of aluminium?

3. Which one of PCl4+ and PCl4- is not likely to exist and why?

4. Give the IUPAC name of the following compound.

5. Draw the structural formula of 2-methylpropane-2-ol molecule.

6. Arrange the following compounds in an increasing order of their reactivity in nucleophilic addition reactionethanol, propanal, propanone, butanone.

7. Arrange the following in the decreasing order of their basic strength in aqueous solution- CH3NH2, (CH3)2NH, (CH3)3N and NH3. 8. Define the term, homopolymerization, giving an example.

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9. A 1.00 molal aqueous solution of trichloroacetic acid (CCl3COOH) is heated to its boiling point. The solution has the boiling point of 100.18 0 C. Determine the vant Hoff factor for trichloroacetic acid. (Kb for water = 0.512 K kg mol-1)

10. Define the following termsa. Mole fraction b. Isotonic solution c. Vant hoff factor d. Ideal solution

11. Name the two groups into which phenomenon of catalysis can be divided. Give an example of each group with chemical equation involved. 12. What is meant by coagulation of colloidal solution?describe brefily any three methords by which cogulation of lyophobic sols can be carried out.

13. Describe the principle involved in each of the followinga. Mond process for refining of nickel b. Column chromatography for purification of rare elements

14. Explain the following giving an appropriate reason in each case. a. O2 and F2 both stabilise higher oxidation states of metals but O2 exceed F2 in doing so. b. Structure of Xenon fluorides cannot be explained by Valence Bond approach.
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15. What do you understand by the order of a reaction? Identify the reaction order from each of the following units of reaction rate constant 2 -1 a. L-1 mol s b. L mol
-1 -1

16. What is meant by a. Peptide linkage b. Biocatalysis.

17. Write any two reactions of glucose which cannot be explained by the open chain structure of glucose molecule.

18. Draw the structure of monomer for each of the following polymers a. Nylon 6 b. Polypropene

19. Analysis shows that nickel oxide has the formula Ni0.98O1.00. What fractions of nickel exist as Ni2+ and Ni3+ ions?

20.

Complete the following chemical equations:

a. b.

NH 4Cl (aq ) NaNO2 (aq )

P4 3NaOH 3H 2O

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21. For the reaction 2NO (g) +Cl 2(g) 2NOCl (g) the following datas were collected. All the measurement were taken at 263 K

Experiment No.

Initial [NO] M

Initial [Cl2]M

Initial rate of disappearance of Cl2

1 2 3 4

0.15 0.15 0.30 0.25

0.15 0.30 0.15 0.25

0.60 1.20 2.40 answer

a. Write the expression form the rate law b. What is the initial rate of disappearance of Cl2 in exp 4?

22. How would you account for the following a. Many of the transition elements are known to form interstitial compounds b. The metallic radii of the third (5d) series of transition metals are virtually the same as those of corresponding group member of second (4d) series. c. Lanthanoids form primarily +3 ions, while the acitnoids usually have higher oxidation states in their compounds, +4 or even +6 being typical.

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23. Give the formula of each of the following coordination entries + a. CO3 ion is bound to one Cl , one NH3 molecule and two bidentate ethylenediamine molecules + b. Ni 2 ion is bound to two water molecules and two oxalate ions. c. Write the name and magnetic behaviour of each of the above coordination entries.

24. Although chlorine is electron withdrawing group, yet it is ortho-, paradirecting in electrophilic aromatic substitution reaction. Explain why it is so. ?

25. Draw the structure and name product formed if the following alcohol are oxidised. Assume that an excess of oxidizing agent is used. a. CH3CH2CH2CH2OH b. 2- butenol c. 2-methyl-1-propanol

26. Write chemical equations for the following conversion a. Nitrobenzene to benzoic acid b. Benzyl chloride to 2- phenylethanamine c. Aniline to benzyle alcohol

27. Explain the following terms with suitable examples a. Cationic detergents b. Anionic detergents and
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c. Non-ionic detergents.

28. a. Define molar conductivity of a solution and explain how molar conductivity changes with change in concentration of solution for a weak and strong electrolyte. b. The resistance of a conductivity cell containing 0.001 M KCl solution of 298 k is 1500 ohm-s. What is the cell constant if the conductivity of -3 -1 0.001 M KCl solution at 298 K is 0.146x10 S cm .

29. Complete the following chemical equations a. P4 + SO2CL2 b. XeF6 +H2O Predict the shape and asked angle 90 or more or less in each of the following i. SO3
2-

and angle O-S-O

ii. ClF3 and angle F-Cl-F iii. XeF2 and angle F-Xe -F

30. Illustrate the following name reaction giving suitable example in each a. Clemmensen reduction b. Friedel-Crafts reaction c. How are following conversions carried out i. ethyl cyanide to ethanoic acid ii. Butan-ol to butanoic acid iii. Benzoic acid to butanoic acid.

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