Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
=
97 . 28
02 . 18
(continue)
Saturated air is air in which the water vapor is in equilibrium
with liquid water at the given conditions of pressure and
temperature.
In this mixture the partial pressure of the water vapor in the
air water mixture is equal to the vapor pressure p of pure air-water mixture is equal to the vapor pressure p
AS
of pure
water at the given temperature. Hence, the saturation
humidity H
S
is
AS
AS
S
p P
p
H
=
97 . 28
02 . 18
(9.3-2)
8
Humidity and Humidity Chart
Percentage humidity
The percent humidity H
P
is defined as 100 times the actual
humidity H of the air divided by the humidity H
S
if the air
(continue)
y y y
S
water saturated at the same temperature and pressure:
S
P
H
H
H 100 =
(9.3-3)
Humidity and Humidity Chart
Percentage relative humidity
The amount of saturation of an air-water vapor mixture is also
given as percentage relative humidity H
R
using partial
(continue)
g p g y
R
g p
pressures:
Note that H
R
H
P
since H
P
expressed in partial pressures by
combining Eqs (9 3 1) (9 3 2) and (9 3 3) is
AS
A
R
p
p
H 100 =
(9.3-4)
combining Eqs. (9.3-1), (9.3-2), and (9.3-3) is
( ) 100
97 . 28
02 . 18
97 . 28
02 . 18
) 100 100
A
AS
AS
A
AS
AS
A
A
S
P
P P
p P
p
p
p P
p
p P
p
H
H
H
=
= =
(9.3-5)
Humidity and Humidity Chart
Example 9.3-1. Humidity from Vapor-Pressure Data
The air in a room is at 26.7 C (80 F) and a pressure of
101.325 kPa and contains water vapor with a partial pressure
(continue)
p p p
p
A
= 2.76 kPa. Calculate the following:
(a) Humidity, H.
(b) Saturation humidity, H
S
, and percentage humidity, H
P
.
(c) Percentage relative humidity, H
R
.
R
Humidity and Humidity Chart
Dew point of an air-water vapor mixture
The temperature at which a given mixture of air and water
vapor would be saturated is called the dew-point temperature
(continue)
vapor would be saturated is called the dew point temperature
or simply the dew point.
For example, at 26.7 C, the saturation vapor pressure of
water is p
AS
= 3.50 kPa. Hence, the dew point of a mixture
containing water having a partial pressure of 3.50 kPa is
26 7 C 26.7 C.
9
Humidity and Humidity Chart
Humid heat of an air-water vapor mixture
The humid heat c
S
is the amount of heat in J (or kJ) required
to raise the temperature of 1 kg of dry air plus the water
(continue)
to raise the temperature of 1 kg of dry air plus the water
vapor pressure by 1 K or 1 C.
The heat capacity of air and water vapor can be assumed
constant over the temperature ranges usually encountered at
1.005 kJ/kg dry airK and 1.88 kJ/kg water vapor K.
c
S
kJ/kg dry air K = 1.005 + 1.88H
(9.3-6)
c
S
btu/lb
m
dry air F = 0.24 + 0.45H
Humidity and Humidity Chart
Humid volume of air-water vapor mixture
The humid volume v
H
is the total volume in m3 of 1 kg of
dry air plus the vapor it contains at 101.325 kPa abs pressure
(continue)
and the given gas temperature. Using the ideal gas law,
( ) K T H x x
H K T air dry kg m v
H
3 3
3
10 56 . 4 10 83 . 2
02 . 18
1
97 . 28
1
273
41 . 22
+ =
|
.
|
\
|
+ =
(9.3-7)
| |
1 1 359
( ) R T H
H R T air dry lb ft v
m H
+ =
|
.
|
\
|
+ =
0405 . 0 0252 . 0
02 . 18
1
97 . 28
1
492
359
3
For a saturated air-water vapor mixture, H=H
S
and v
H
is the
saturated volume.
Humidity and Humidity Chart
Total enthalpy of an air-water vapor mixture
The total enthalpy of 1 kg of air plus its water vapor is H
y
J/kg or kJ/kg dry air. If T
0
is the datum temperature chosen for
(continue)
both components, the total enthalpy is the sensible heat of
the air-water vapor mixture plus the latent heat
0
in J/kg or
kJ/kg water vapor of the water vapor at T
0
.
Note that (T - T
0
)C=(T - T
0
) K and that this enthalpy is
referred to liquid water.
(9.3-8)
( ) ( )( )
0 0 0 0
88 . 1 005 . 1 / H C T T H H T T c air dry kg kJ H
S y
+ + = + =
( )( )
0 0
45 . 0 24 . 0 / H F T T H air dry lb btu H
m y
+ + =
Humidity and Humidity Chart
Total enthalpy of an air-water vapor mixture
(continue)
If the total enthalpy is referred to a base temperature T
0
of
0 C. (32 F), the equation for H becomes
(9.3-9)
0 C. (32 F), the equation for H
y
becomes
( )( ) H C T H air dry kg kJ H
y
4 . 2501 0 88 . 1 005 . 1 / + + =
10
Humidity and Humidity Chart
Humidity chart of air-water vapor mixtures
A convenient chart of the properties of air-water vapor
mixtures at 1.0 atm abs pressure is the humidity chart in
(continue)
Figure 9.3-2.
In this figure the humidity H is plotted versus the actual
temperature of the air-water vapor mixture (dry bulb
temperature).
The curve marked 100% running upward to the right gives The curve marked 100% running upward to the right gives
the saturation humidity H
S
as a function of temperature.
Humidity and Humidity Chart
Humidity chart of air-water vapor mixtures
(continue)
Figure 9.3-2 Humidity chart for mixtures of air and water vapor at a
total pressure of 101.325 kPa (760 mmHg).
Adiabatic Saturation Temperatures
Consider the process shown in Figure 9.9-3, where the
entering gas of air-water vapor mixture is contacted with a
spray of liquid water.
The gas leaves having a different humidity and temperature
and the process is adiabatic. The water is circulated, with
some makeup water added.
The temperature of the water being
recirculated reaches a steady state
Figure 9.3-3 Adiabatic
air-water vapor saturator.
recirculated reaches a steady-state
temperature called the adiabatic
saturation temperature, T
S
.
Adiabatic Saturation Temperatures
If the entering gas at temperature T having a humidity of H is
not saturated, T
S
will be lower than T.
If the contact between the entering gas and the spray of
(continue)
g g p y
droplets is enough to bring the gas and liquid to equilibrium,
the leaving air is saturated at T
S
, having a humidity H
S
.
Figure 9.3-3 Adiabatic air-water vapor saturator.
11
Adiabatic Saturation Temperatures
Writing an enthalpy balance (heat balance) over the process,
a datum of T
S
is used. The enthalpy of the makeup H
2
O is
then zero.
(continue)
Or, rearranging, and using Eq. (9.3-6) for c
S
,
(9.3-10) ( ) ( )
S S S S S S S S
H T T c H T T c + = +
This means that the total enthalpy of the entering gas mixure
= enthalpy of the leaving gas mixture, or, using Eq. (9.3-8).
(9.3-11)
( )
( )
S S
S
S
S
H c
T T
H H
88 . 1 005 . 1 +
= =
(SI)
( )
( )
S S
S
H
T T
H H
45 . 0 24 . 0 +
=
(English)
Adiabatic Saturation Temperatures
Equation (9.3-11) is the equation of an adiabatic
humidification curve when plotted on Fig. 9.3-2, which
passes through the point H
S
and T
S
on the 100% saturation
(continue)
S S
curve and other point of Hand T.
These series of lines, running upward to the left, are called
adiabatic humidification lines or adiabatic saturation lines.
Since c
S
contains the term H, the adiabatic lines are not quite
straight when plotted on the humidity chart straight when plotted on the humidity chart.
Wet Bulb Temperature
The adiabatic saturation temperature is the steady-state
temperature attained when a large amount of water is
contracted by the entering gas.
The wet bulb temperature is the steady state nonequilibrium
temperature reached when a small amount of water is
contacted under adiabatic conditions by a continuous stream
of gas.
h f l d ll h d Since the amount of liquid is small, the temperature and
humidity of the gas are not changed, contrary to the case of
adiabatic saturation, where the temperature and humidity of
the gas are changed.
Wet Bulb Temperature
The method used to measure the web bulb temperature is
illustrated in Fig. 9.3-4, where a thermometer is covered by
the a wick or cloth.
(continue)
The wick is kept wet by water and is immersed in a flowing
stream of air-water vapor having a temperature of T (dry bulb
temperature) and humidity H.
At steady state, water is evaporating
to the gas stream The wick and
Figure 9.3-4 Measurement of wet bulb temperature.
to the gas stream. The wick and
water are cooled to T
W
and stay at
this constant temperature.
12
Wet Bulb Temperature
The latent heat of evaporation is exactly balanced by the
convective heat flowing from the gas stream at T to the wick
at a lower temperature T
W
.
(continue)
A heat balance on the wick can be made. The datum
temperature is taken at T
W
. The amount of heat lost by
vaporization, neglecting the small sensible heat change of the
vaporized liquid and radiation, is
(9 3-12) A N M q (9.3-12) A N M q
W A A
=
q = kW (kJ/s), M
A
= the molecular weight of water
N
A
= kg mol H
2
O evaporating/sm
2
W
= the latent heat of vaporization at T
W
in kJ/kg H
2
O
Wet Bulb Temperature
The flux N
A
is
(continue)
(9.3-13)
( ) ( ) y y k y y
x
k
N
W y W
y
A
= =
,
x
BM
k
y
= the mass-transfer coefficient in kg mol/sm
2
mol frac
x
BM
= the log mean inert mole fraction of the air
y
W
= the mole fraction of water vapor in the gas at the surface
y = the mean fraction in the gas
Wet Bulb Temperature
For the dilute mixture x
BM
~ 1.0, and k
y
~ k
y
. The relation
between H and y is
(continue)
M H
(9.3-14)
A B
A
M H M
M H
y
/ / 1 +
=
M
B
= the molecular weight of air
M
A
= the molecular weight of H
2
O
Since H is small as an approximation Since H is small, as an approximation,
(9.3-15)
A
B
M
HM
y ~
Wet Bulb Temperature
Substituting Eq. (9.3-15) and then substituting the resultant
into Eq. (9.3-12),
(continue)
(9 3-16) ( )A H H k M q = (9.3 16) ( )A H H k M q
W W y B
=
The rate of convective heat transfer from the gas stream at T
to the wick at T
W
is
(9.3-17) ( )A T T h q
W
=
h the heat transfer coefficient in kW/m
2
K (btu/hft
2
F) h = the heat-transfer coefficient in kW/m K (btu/hft F)
Equation Eq. (9.3-16) to (9.3-17) and rearranging,
(9.3-16)
W
y B
W
W
k M h
T T
H H
13
Wet Bulb Temperature
Experimental data on the value of h/M
B
k
y
, called the
psychrometric ratio, show that for water vapor-air mixtures,
the values is approximately 0.96-1.005.
(continue)
Since this value is close to the value of c
S
in Eq. (9.3-11),
approximately 1.005, Eqs. (9.3-18) and 9.3-11) are almost
the same.
This means that the adiabatic saturation lines can also be
used for wet bulb lines with reasonable accuracy used for wet bulb lines with reasonable accuracy.
Equilibrium Moisture Content of Materials
Figure 9.4-1 Typical equilibrium moisture contents of some solids at
approximately 298 K (25 C).
Equilibrium Moisture Content of Materials
(continue)
Figure 9.4-2 Typical equilibrium moisture contents of some food
materials at approximately 298 K (25 C).
Rate of Drying Curves
Introduction
In the drying of various types of process materials from one
moistures content to another, it is usually desired to estimate
the size of dryer needed, the various operation conditions of
humidity and temperature for the air used, and the time
needed to perform the amount of drying required.
14
Rate of Drying Curves
Experimental determination of rate of drying
To experimentally determine the rate of drying for a given
material, a sample is usually placed on the tray.
(continue)
If it is a solid material it should fill the tray so that only the
top surface is exposed to the drying air stream.
By suspending the tray from a balance in a cabinet or duct
through which the air is flowing, the loss in weight of
d d b d d d ff moisture during drying can be determined at different
intervals without interrupting the operation.
Rate of Drying Curves for Constant-Drying Condition
Conversion of data to rate-of-drying curve
Data obtained from a batch-drying experiment are usually
obtained as W total weight of the wet solid (dry solid plus
moisture) at different times t hours in the drying period.
These data can be converted to rate-of-drying data in the
following ways. First, the data are recalculated. If W is the
weight of the wet solid in kg total water plus dry solid and
WS is the weight of the dry solid in kg WS is the weight of the dry solid in kg,
(9.5-1)
|
|
.
|
\
|
=
solid dry lb
water total lb
solid dry kg
water total kg
W
W W
X
S
S
t
Rate of Drying Curves for Constant-Drying Condition
Conversion of data to rate-of-drying curve
For the given constant drying conditions, the equilibrium
moisture content X* kg equilibrium moisture/kg dry solid is
(continue)
determined. Then the free moisture content X in kg free
water/kg dry solid is calculated for each value of X
t
:
Using the data calculated from Eq. (9.5-2), a plot of free
moisture content X versus time t in h is made, as in
(9.5-2) * X X X
t
=
moisture content X versus time t in h is made, as in
Fig. 9.5-1a.
To obtain the rate-of-drying curve from this plot, the slope of
the tangents drawn to the curve in Fig. 9.5-1a can be
measured, which give values of dX/dt at given values of t.
Rate of Drying Curves for Constant-Drying Condition
(continue)
The rate R is calculated for each
point by
Conversion of data to rate-of-drying curve
(9.5-3)
dt
dX
A
L
R
S
=
Where R is drying rate in kg H
2
O
/hm
2
, L
S
kg of dry solid used,
and A exposed surface area for
Figure 9.5-1a Typical drying-
rate curve for constant drying
conditions: (a) plot of data as
free moisture versus time.
and A exposed surface area for
drying in m
2
.
The drying-rate curve is then
obtained by plotting R versus the
moisture content, as in Fig. 9.5-1b.
15
Rate of Drying Curves for Constant-Drying Condition
Conversion of data to rate-of-drying curve
Another method for obtaining the rate-of-drying curve is to
first calculate the weight loss AX for a At time.
(continue)
g
For example if X
1
= 0.350 at a time t
1
= 1.68 h and
X
2
= 0.325 at time t
2
= 2.04. Then, using Eq. (9.5-4) and
L
S
/A = 21.5,
493 1
325 . 0 350 . 0
5 21 =
|
|
|
=
A
=
X L
R
S
493 . 1
68 . 1 04 . 2
5 . 21 =
|
.
\
=
A
=
t A
R
This rate R is the average over the period 1.68 to 2.04 h
and should be plotted at the average concentration
X = (0.350+0.325)/2 = 0.338.
Rate of Drying Curves for Constant-Drying Condition
(continue)
Plot of rate-of-drying curve
At zero time the initial free
moisture content is shown at point
A. In the beginning the solid is
usually at a colder temperature
than its ultimate temperature, and
the evaporation rate will increase.
Eventually, at point B, the surface
Figure 9.5-1b Typical drying-
rate curve for constant drying
conditions: (b) rate of drying
curve as rate versus free
moisture content.
Eventually, at point B, the surface
temperature rises to its equilibrium
value. Alternatively, if the solid is
quite hot to start with, the rate
may start at point A.
Rate of Drying Curves for Constant-Drying Condition
Plot of rate-of-drying curve
From point B to point C in Fig. 9.5-1a the line is straight,
and hence the slope and rate are constant during this period.
(continue)
This constant-rate-of-drying period is shown as line BC in
Fig. 9.5-1b.
At point C on both plots, the drying rate starts to decrease in
the falling-rate period until it reaches point D. In this first
falling-rate period, the rate shown as line CD in Fig. 9.5-1b is g p , g
often linear.
Rate of Drying Curves for Constant-Drying Condition
Plot of rate-of-drying curve
(continue)
At point D the rate of drying falls even more rapidly, until it
reaches point E where the equilibrium moisture content is reaches point E, where the equilibrium moisture content is
X* and X=X*-X*=0. In some materials being dried, the region
CD may be missing completely, or it may constitute all the
falling-rate period.