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ELEKTRONIK

Your supplier for


XRF Application Solutions

Fusion machines

Application
Cement Industry
We offer ready to go calibration packages
for x-ray fluorescence analysis.
Our team has developed special calibration packages:
Products: Cement, Clinker, Raw meal


Raw materials:
Clay, Sand, Limestone, Gypsum, Iron Ore, Fly Ash
Bauxite, Dolomite, Pozzolana

We install the complete analytical method, within a few


days, on the XRF instrument in your laboratory.

1,008

He

Hydrogen

6,941

Li
Lithium

FLUXANA GmbH & Co. KG

Be

Periodic Table of Fusion

Tel.: +49 (0) 2821 997 32-0


Fax: +49 (0) 2821 997 32 29
E-mail: info@fluxana.de
Web: www.fluxana.com

Natrium, Sodium

Magnesium

0,7420 Na2O 1,3477

0,6030 MgO 1,6584

39,098

19

Kalium, Potassium

Amtsgericht Kleve: HR-A 2935, HR-B 8211


Ust-IdNr.: DE 814692564, Steuer-Nr. 116/5755/0442
Finanzamt Kleve

0,8300

37

K2O

1,2048

85,468

40,078

20

Rubidium

HD Elektronik und Elektrotechnik GmbH

0,9140 Rb2O 1,0941

Sommerdeich 22, 47533 Kleve, Germany

55

Calcium

0,7150 CaO
0,5133 CaF2

132,905

56

Cesium

SrO

1,1820

137,327

Barium

0,8960 BaO 1,1161


0,5884 BaSO4 1,6995

87

223,02

0,6520 Sc2O3 1,5337

39

Strontium

0,8460

88

22

Scandium

1,3986
1,9480

87,62

38

Cs Ba

Tel.: +49 (0) 2821 148 10


Fax: +49 (0) 2821 148 09
E-mail: hde@hdelektronik.de
Web: www.hdelektronik.de

44,956

88,905

Ytrrium
0,7874

Y2O3 1,2700

47,88

Ti

23

50,996

Titanium

Vanadium

TiO2

0,6798 V2O3 1,4711


0,5600 V2O5 1,7857

0,6000

1,6667

91,224

40

41

92,906

24

51,996

25

54,938

26

55,847

58,933

27

58,69

28

29

63,546

65,39

30

12,011

Boron

26,982

13

Ox>El Oxid El>Ox


21

10,811

Symbol
Element

Ca Sc

Rb Sr

In cooperation with:

24,305

12

Na Mg

Borschelstr. 3, 47551 Bedburg-Hau, Germany

Amtsgericht Kleve: HR-B 2162


Ust-IdNr.: DE 812941185, Steuer-Nr. 116/5707/1869
Finanzamt Kleve

Helium

9,012

Berylium

22,990

11

4,003

Al

31

Al2O3 1,8904

69,723

Carbon

14

Aluminium
0,5290

14,007

Nitrogen

28,086

Si
Silicon

0,4670

SiO2 2,1413

72,61

32

30,974

15

15,999

P2O5 2,2936

74,922

33

S
SO3
SO4

72

ZrO2 1,3514

Chromium

0,6840 Cr2O3 1,4620

42

95,940

Niobium

Molybdenum

0,6670 MoO3 1,4993

178,49

73

180,948

Hf Ta
Hafnium

Tantalum

0,8480 HfO2 1,1792

0,8190 Ta2O5 1,2210

Ne
Neon

39,948

18

Ar
Argon

2,5000
2,9959

78,96

34

Cl
Chlorine

Sulphur
0,4000
0,3338

35,453

17

20,183

10

79,904

35

83,80

36

Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

0,6990 Nb2O5 1,4306

Zirconium

Fluorine

32,066

Manganese

0,7745 MnO 1,2912


0,6960 Mn2O3 1,4368
0,7203 Mn3O4 1,3883

43

98,906

Iron

0,7770 FeO
1,2870
0,6990 Fe2O3 1,4306
0,7236 Fe3O4 1,3820

44

50,996

Cobalt

0,7860 CoO

45

Nickel

1,2723

101,07

0,7860

46

NiO

Copper

1,2723

106,42

0,7990

47

CuO

Galium

Germanium

Arsenic

0,7440 Ga2O3 1,3441

0,6940 GeO2 1,4409

0,7570 As2O3 1,3210

Zinc

1,2516

107,868

0,8030

ZnO

1,2453

112,411

48

49

114,82

50

118,71

121,75

51

74

183,85

Technetium

75

Wolfram, Tungsten

WO3 1,2610

Palladium

Silver

0,9310 Ag2O 1,0741

186,207

76

190,2

W Re Os

0,7930

Rhodium

Ruthetium

Rhenium

77

192,22

Ir

Iridium

Osmium

78

195,08

79

196,967

Cadmium

Indium

CdO

0,8270 In2O3 1,2092

0,8750

80

1,1429

200,59

81

204,383

Tin

0,7880

82

SnO2 1,2690

207,19

Antimony

Tellurium

0,8000 TeO2 1,2500

208,980

208,982

84

Krypton

SeO2 1,4045

127,60

52

0,8350 Sb2O3 1,1976

83

Bromine

Selenium

0,7120

Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te

0,7400

Oxygen

16

Phosphorus
0,4360

18,998

126,904

53

Iodine

209,987

85

131,29

54

Xe
Xenon

222,018

86

Pt Au Hg Tl Pb Bi Po At Rn
Platinum

Gold

Thallium

Mercury

0,8534 ReO2 1,1719

0,8949 Tl2O3 1,1174

Lead

0,9280 PbO

Bismuth

1,0776

Astatium

Polonium

Radon

0,8970 Bi2O3 1,1148

226,025

Fr Ra
Francium

Official agent

Radium

57

138,906

58

140,115

59

140,908

Cerium

Lanthanum

0,8527 La2O3 1,1727

89

227,028

0,8141 CeO2

90

1,2284

232,038

144,24

Praseodynium

Neodymium

0,8277 Pr6O11 1,2082

0,8574 Nd2O3 1,1663

91

231,036

Ac Th Pa
Actinium

Thorium

0,8790 ThO2 1,1377

FXMM-0005 - V2.0e - 21.09.2010

60

61

146,915

62

150,36

63

151,965

64

157,25

65

158,925

66

162,50

67

164,930

167,26

68

168,934

69

70

173,04

174,967

71

La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Protactinium

92

238,029

Promethium

93

237,048

Samarium

Europium

Gadolinium

Terbium

Dysprosium

Holmium

Erbium

Thulium

Ytterbium

Lutetium

0,8623 Sm2O3 1,1596

0,8636 Eu2O3 1,1579

0,8676 Gd2O3 1,1526

0,8502 Tb4O7 1,1762

0,8713 Dy2O3 1,1477

0,8730 Ho2O3 1,1455

0,8745 Er2O3 1,1435

0,8756 Tm2O3 1,1421

0,8782 Yb2O3 1,1387

0,8794 Lu2O3 1,1372

94

244,064

95

243,061

96

247,07

97

247,07

98

251,079

U Np Pu Am Cm Bk Cf

Uranium

0,9084 U2O3 1,1008

Neptunium

Plutonium

Americium

Curium

Berkelium

Californium

99

252,083

100

257,095

101

258,099

102

259,10

103

260,105

Es Fm Md No Lr

Einsteinium

Fermium

Mendelevium

Nobelium

Lawrencium

Advantages to developing your application with us:


1.
2.
3.
4.
5.
6.
7.
8.

Concentration ranges for fusion and pressed pellet programs

No development time in your laboratory


Cost saving
Fast introduction of new methods
Easy calculation of costs
Guarantee on reproducibility and accuracy
Calibration with highest quality
Newcomers become experts quickly
Guaranteed after sales support

Cement / Clinker / *Raw meal

Vulcan 4MA

Typical content of a package:

















NEW

Sample preparation tools: fusion machine, mill, press


Chemicals: flux, binder, grinding agent
1 set of calibration standards ready for measurement
1 set of drift correction samples
1 set of validation samples
Installation of measuring program on the XRF
instrument in your laboratory
Calibrating on site
Validation with your own samples
Training of your laboratory staff
Customer acceptance
After sales support from our team of XRF experts
Contribution to our round robin tests
Cross check of routine results with our application
laboratory
Powder sets for calibration: 25 standards for raw materials
and 21 standards for cement

Raw Materials:
Clay, Sand, Limestone, Gypsum, Iron Ore,
Fly Ash, Bauxite, Dolomite, Pozzolana

Component

Min %

Max %

Min %

Max %

Na2O

1,0

3,5

MgO

6,0

35,0

Al2O3

4,0 / 2,0*

10,0

100,0

SiO2

19 / 10*

28,0

100,0

P2O5

0,3

2,4

SO3

0,8 / 0,4*

5,0

5,0

K2O

1,5

5,0

CaO

50 / 25*

70,0

100,0

TiO2

0,7

2,7

Cr2O3

0,05

0,1

Mn3O4

0,15

1,6

Fe2O3

4,0

30,0

ZnO

0,10

0,07

SrO

0,7

0,7

Validation example for pressed pellet methods vs fusion method


Cement

Vaneox - 40t automatic

Clinker

Raw Meal

Sample preparation

LOI

FUSED BEAD

2,01

Ask for a free presentation in our lab whenever you like.

CaO

4,69

63,43

PRESSED PELLET

4,74

63,33

Diff

0,05

-0,10

Al2O3

CaO

Sample preparation

LOI

FUSED BEAD

0,23

5,05

65,07

PRESSED PELLET

5,19

64,91

Diff

0,14

-0,16

LOI

Al2O3

CaO

34,34

3,48

42,61

PRESSED PELLET

3,55

42,60

Diff

0,07

-0,01

Sample preparation
FUSED BEAD

All standard calibrations are developed in our own application laboratory.


We will be pleased to accept your test samples for evaluation in our laboratory and can
work together with you to develop new methods to transfer to install in your laboratory.

Al2O3

Cl

Cr2O3
0,047

3,45

0,43

2,28

0,043

0,33

0,171

3,41

19,20

0,061

0,348

0,018

99,92

0,02

0,039

3,45

0,42

2,34

0,013

0,28

0,165

3,31

19,32

0,059

0,359

0,019

97,86

-0,01

0,00

-0,01

0,06

-0,03

-0,05

-0,01

-0,10

0,12

0,00

0,01

0,00

Cl

Cr2O3

Fe2O3

K2O

MgO

Mn2O3

Na2O

P2O5

SO3

SiO2

SrO

TiO2

ZnO

0,059

3,39

0,43

2,86

0,047

0,39

0,176

1,23

20,78

0,054

0,334

0,021

100,12

0,01

0,055

3,35

0,39

2,94

0,032

0,34

0,187

1,23

20,96

0,051

0,354

0,023

100,02

0,00

-0,04

-0,04

0,08

-0,01

-0,05

0,01

0,00

0,18

0,00

0,02

0,00

Cr2O3

Fe2O3

K2O

MgO

Mn2O3

Na2O

P2O5

SO3

SiO2

SrO

TiO2

ZnO

Sum

0,035

2,39

0,41

1,83

0,034

0,31

0,124

0,30

13,78

0,039

0,259

0,008

99,95

0,029

2,36

0,40

1,84

0,032

0,26

0,127

0,28

13,95

0,036

0,277

0,007

65,81

-0,01

-0,03

-0,01

0,01

0,00

-0,05

0,00

-0,02

0,17

0,00

0,02

0,00

Cl

0,065

Fe2O3

K2O

MgO

Mn2O3

Na2O

P2O5

SO3

SiO2

SrO

TiO2

ZnO

Sum

Sum

All FLUXANA methods are in agreement with the standard methods for cement analysis ISO 29581-2 and ASTM C114.

Application packages
FLUXANA has developed applications for the following products. We will be pleased to help you set
up your own high precision method. Ready to go application packages:

Samples from process

FLUXANA sample prep


Pressed pellets
Fused bead

X-RAY instrument with


FLUXANA calibrations

Process control

Article-No.:

Application

CS- 0001 Set

FLUXANA Calibration Cement, Clinker, Raw Meal based on fused bead

CS- 0007 Set

FLUXANA Calibration Raw Materials Basic based on fused bead

CS- 0002 Set

FLUXANA Calibration Coal Ash, Coke Ash and Fly Ash based on fused bead

CS- 0018-KP

FLUXANA Calibration Cement based on pressed pellets

CS- 0019-KP

FLUXANA Calibration Clinker based on pressed pellets

CS- 0020-KP

FLUXANA Calibration Custom Raw Meal based on pressed pellets

CS- 0021-KP

FLUXANA Calibration Individual raw material based on pressed pellets

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