IIT-JEE Sample Test Paper For Class XI

Date : 09-02-2013 Duration : 3 hours Max.
Marks : 204
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
I NSTRUCTI ONS
Do not break the seal of the question paper booklet before instructed to do so by the invigilator.
This Paper contains 60 questions. Please ensure that theQuestion paper you have received contains ALL THE
QUESTIONS.
QUESTION PAPER FORMAT
1. The question paper consists of Maths, Physics and Chemistry. Each part has four sections.
2. Section I contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which only ONE is correct. Each questions is of 3 marks. 1 mark will be deducted for each wrong answer.
3. Section II contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D), out of
which ONE or MORE is/are correct.Each questions is of 4 marks. No negative marking will be done
for this Section.
4. Section III contains 2 groups of questions. Each group has 2 questions based on a paragraph. Each question
has four choices (A), (B), (C) and (D) out of which only ONE is correct. Each questions is of 3 marks. 1
mark will be deducted for each wrong answer.
5. Section IV contains 4 questions.Each questions is of 4 marks. The answer to each of the questions is an
integer, ranging from 00 to 99. The answer will have to be appropriately bubbled in OMR.No negative
marking will be done for this Section.,
NOTE : GENERAL INSTRUCTION FOR FILLING THE OMR ARE GIVEN BELOW :
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shading the circles against the question by dark HB pencil or blue/black pen.
4. While filling the bubbles please be careful about question paper format.
Name of the student EW Roll Number .
Class - XI J EE Advanced
I have read all the instructions and shall
abide by them.
................................................................
Signature of the Student
I have verified all the information filled in
by the candidate.
................................................................
Signature of the invigilator
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2
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MATHEMATICS
SECTI ON-A
[STRAI GHT OBJ ECTI VE TYPE QUESTI ONS]
Q.1 to Q.8 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1 The distance of the point(1, 2) fromthe line x +y +5 =0 measured parallel to the line 2x y +3 =0
is equal to
(A)
4 5
(B)
2 5
3
(C)
8 5
3
(D)
5 3
Q.2 In a sequence of 9 terms, first 5 terms are in AP with common difference 2 and last 5 terms are in GP
with common ratio 2. If the middle term of AP is equal to the middle term of the GP then the middle
term of the entire sequence is
(A)
3
4
(B)
3
2
(C)
3
28
(D)
3
7
Q.3 If reflection of circle x

2
+y
2
4y +3 =0 in the line y =x intersect the circle x
2
+y
2
6x 8y +k =0
orthogonally then K is equal to
(A) 3 (B) 6 (C) 9 (D) 12
Q.4 If S
n
=
= =
|
.
|
\
|
n
1 r
1 r
0 t
t
t
r
r
n
n
3 C C
5
1
then the value of , where =
=1 n
n
) S 1 (
, is equal to
(A) 2 (B) 3 (C) 4 (D) 5
3
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Q.5 The number of integral roots of the equation
( ) 2 x x 3 4 x 5 x log
2 2
+ +
=
( ) 4 x 5 x 2 log
2
+
is(are)
(A) 0 (B) 1 (C) 2 (D) infinite
Q.6 Let be the maximumvalue of expression sin
10
x +cos
5
x. If in a AABC sinAcosB +cosAsinBsinC =,
(where ZA<t/2) then
(A) A +B =C (B) A =B (C) A =B =C (D) A=C
Q.7 If sin
2
u
1
+sin
2
u
2
+.....+sin
2
u
n
=0 then the number of different set of values of (u
1
, u
2
,....,u
n
) where
u
i
e [0, t] for which cosu
1
+cosu
2
+....+cosu
n
=n 4 is
(A) n(n 1) (B)
2
) 1 n ( n
(C)
2
) 1 n ( n +
(D) n(n +2)
Q.8 The number of solution of the equation
1
A cot 1
A sin
A tan 1
A cos
= +
. in [0, 2t] is
(A) 3 (B) 2 (C) 1 (D) 0
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SECTI ON-B
[MULTI PLE OBJ ECTI VE TYPE QUESTI ONS]
Q.9 to Q.12 has four choices (A), (B), (C), (D) out of which ONE OR MORE THAN ONE is/are correct.
Q.9 If in a AABC a
2
+b
2
+c
2
=bc + 3 ca , then
(A) c is longest side (B) AABC is right angled triangle
(C) ZB, ZC, ZA are in AP (D) AABC is scalene triangle
Q.10 If a
1
, a
2
, a
3
...a
n
are the positive numbers in AP such that a
22
+a
79
=100 then identify the correct
statement
(A)
100
i
i 1
a 5000
=
=
(B) 50 a a
72 29
> (C) 50 a a
72 29
s (D)
75 100
i i
i 26 i 1
2 a a
= =
=

Q.11 If f (x) =ax
2
bx +c is many one in (4, 12) & has roots A
r
& A
r +1
(where A
r
=
5
C
r
) then the value
of r can be
(A) 1 (B) 2 (C) 3 (D) 4
Q.12 Two concentric circles, whose centre is origin and radii are 3 & 6 respectively as shown in the figure.
Then the value of log
3
MN +log
3
TS +log
3
(MN +NR) +log
3
(TS +SR) is a factor of
(A) (
4
C
0
+
4
C
1
) +(
4
C
1
+
4
C
2
) +......+(
4
C
3
+
4
C
4
)
(B) The number of different ways in which 8 different books can
be distributed among 3 students, if each students receives at least 2 books.
(C) The number of words formed by arranging the letters of the word 'BULBUL'
(D) The number of six digit numbers which contains exactly four different digits such that exactly one
digit is repeated
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SECTI ON-C
[COMPREHENSI ON TYPE QUESTI ONS]
Q.13 to Q.16 are based upon a paragraph. Each question has four choices (A), (B), (C), (D) out of which
ONLY ONE is correct.
Paragraph for Question Nos. 13 to 14
Consider a fucntion f whose domain is [3, 4] and range is [2, 2] with following graph
Q.13 Domain & Range of g(x) =f(|x|) are [a, b] & [c, d] respectively then b a +c +d is equal to
(A) 11 (B) 10 (C) 8 (D) 7
Q.14 If h(x) =| f (x) 3/2| has range [e, f] & n be number of real solution of h(x) =1/4 then n +e +2f
is equal to
(A) 8 (B) 9 (C) 10 (D) 11
Paragraph Question Nos. 15 to 16
Let ABCDEF be a regular hexagon, whose equation of sides AB & BC are
7 x 3 y=
&
5 x 3 y + =
respectively and if point C is (0, 5) then
Q.15 The radius of circle passing through ABC
(A)
3 4
(B)
3 8
(C)
3 6
(D)
3 3
Q.16 The area of triangle ACE is
(A)
3 18
(B)
2 36
(C) 3 36 (D)
2 16
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SECTI ON-D
[I NTEGER TYPE QUESTI ONS]
Q.17 to 20 are "Integer" type questions. (The answer to each of the questions are upto 2 digit)
Q.17 Let f be an odd periodic function fromR R with period 2 & satisfies
1 .....
3 2
1
6
3 2
1
6
3 2
1
6
3 2
1
log 65 . 3 f
4 / 9
=
|
|
|
.
|
\
|
|
|
|
.
|
\
|
+ then find the value of f
2
(0.85).
Q.18 Consider f(r, u) =
n 100
i
2
n
r 1 i 1
r
cos(r / 2),A 2n log sin f (r, )
2
= =
| | u
u = + u
|
\ .
[ . If the value of A at
u =
) r 2 3 (
r 6
t
is an +b, where a, b e I then find the value of a +b .
Q.19 If A =sin50|cos50 sin50| +cos50 {|tan50 cot50| +|cot50 cos50| | tan50 sin50|}
B =|sin 100 cos 100|+|sec100 cos100| +|cosec100 sin100| |cosec100 sec100|
+cosec100 then value of expression B
2
(A B)
2
+A
2
+
2
B
1
Q.20 Let o and | be roots of x
2
3x +5 =0, with o >|.
If S
n
=o
n 1
+o
n 2
| +o
n 3
|
2
+.... +o|
n 2
+|
n 1
for n > 1,
then find the value of
2012 2010
2011
S 5S
S
+
.
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PHYSI CS
SECTI ON-A
Q.21 The brick shown in the drawing is glued to the floor. A 3500-N force is applied to the top surface of
the brick as shown. If the brick has a shear modulus of 5.4 10
9
N/m
2
, how far to the right does the
top face move relative to the stationary bottomface?

0.10 m 3500 N
0.25 0.10 m
(A) 5.8 10
6
m (B) 2.6 10
6
m (C) 1.1 10
6
m (D) 6.5 10
7
m
h
W
Q.22 Figure shows an iron paddle mounted in a tank of water. There is
20.0 kg of water in the tank and the iron has a mass of 2.0 kg. The
paddle is rotated for 5.0 min at a constant rate. A 2.2 kW motor turns
the paddle, but the paddle rotates at only 30% of its maximum rate
because of the resistance of the water. If the tank is originally at 20C
and no heat escapes, the final temperature of the water is approximately.
(A) 35C (B) 40C (C) 25C (D) 30C
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Q.23 A speaker generates a continuous tone of 440 Hz. In the drawing, sound travels into a tube that splits
into two segments, one longer than the other.

The sound waves recombine before being detected by a
microphone. The speed of sound in air is 340 m/s.
What is the minimumdifference in the lengths of the two paths for sound travel if the waves arrivein
phase at the microphone?
(A) 0.10 m (B) 0.39 m (C) 0.77 m (D) 1.11 m
Q.24 Suppose one mole of an ideal gas undergoes the reversible cycle ABCA
shown in the P-V diagramabove, where AB is an isotherm. The molar
heat capacities are C
P
at constant pressure and C
v
at constant volume.
The net heat added to the gas during the cycle is equal to
(A) RT
h
V
2
/V
1
(B) C
P
(T
h
T
c
)
A
T
h
T
c
B
V
V
2
V
1
P
2
P
1
P
C
(C) C
v
(T
h
T
c
) (D) RT
h
ln V
2
/V
1
R (T
h
T
c
)
Q.25 A particle of mass m moves in a one dimension such that its potential energy is given as :
U(x) =ax
2
+bx
4
, where a and b are positive constants. The angular frequency of small oscillations
about the minima of the potential energy is equal to
(A) t (a/2b)
1/2
(B) t (a/m)
1/2
(C) (a/m)
1/2
(D) 2(a/m)
1/2
Q.26 A hoop of mass M and radius R is at rest at the top of an inclined plane a shown figure. The hoop rolls
down the plane without slipping. When the hoop reaches the bottom, its angular momentumaround its
center of mass is
(A) MR gh
(B)
1
MR gh
2
(C) M 2gh
(D) Mgh
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Q.27 A cylinder with moment of inertia 4kg - m
2
about a fixed axis intially rotates at 80 radian per second
about this axis. A constant torque is applied to slow it down to 40 radian per second. If the cylinder
takes 10 seconds to reach 40 radian per second, the magnitude of the applied torque is
(A) 80 N-m (B) 40 N-m (C) 32 N-m (D) 16 N-m
Q.28 Small-amplitude standing waves of wavelength occur on a string with tension T, mass per unit length
, and length L. One end of the string is fixed and the other end is attached to a ring of mass M that
slides on a frictionless rod, as shown in the figure. When gravity is neglected, which of the following
conditions correctly determines the wavelength ? (You might want to consider the limiting cases
M 0 and M )
M
L
(A)
2 2 L
/ M cot
t t
=

(B)
2 2 L
/ M tan
t t
=

(C)
2 2 L
/ M sin
t t
=

(D) 2L / n, n 1,2,3... = =
10
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SECTI ON-B
Q.29 For a particle, x Acos t
6
t | |
= e +
|
\ .
then the value(s) of t when it is at rest is :
(A)
e
t
6
(B)
e
t
6
5
(C)
e
t
3
(D)
e
t
6
11
Q.30 A particle moves along y-

axis according to the equation, y =sin 150 t t +4 sin
3
50 t t +2.
y

is in cm and t is in seconds .
(A) it performs SHM of amplitude 3 cm (B) it performs SHM of frequency 25 Hz
(C) it does not perform SHM (D) the mean position is at y =2cm
Q.31 Which of the following statements is/are true
(A) work done by kinetic friction on a rigid body may be positive
(B) a uniform sphere rolls up an inclined plane without sliding. The friction force on it will be up the
incline. (only contact force and gravitational force is acting)
(C) a uniformsphere rolls down an inclined plane without sliding. The friction force on it will be up the
incline. (only contact force and gravitational force is acting)
(D) a uniformsphere is left fromrest fromthe top of a rough inclined plane. It moves down the plane
with slipping. The friction force on it will be up the incline.
Q.32 Two coherent waves represented by y
1
=A sin
|
|
.
|
\
| t
+ e
t
4
t
x 2
1
and y
2
=A sin
|
|
.
|
\
| t
+ e
t
6
t
x
2
2
are superposed. The two waves will produce
(A) constructive interference when (x
1
x
2
) =2 (B) constructive interference when (x
1
x
2
) =
24
23
(C) destructive interference when (x

1
x
2
) =1.5 (D) destructive interference when (x
1
x
2
) =
24
11
11
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SECTI ON-C
Paragraph for question nos 33 to 34
Because heating a solid increases the vibrational energy of its molecules resulting in an increase in space
required by each molecule, a typical solid will expand when heated. For such solids, the fractional
change in their length per unit temperature is given by a coefficient of linear expansion, which is specific
for each solid. Although the change in length varies slightly with temperature for any solid, The following
equation gives a good approximation.
L L T A = oA
where L is the original length of the solid, AL is the change in length, o is the coefficient of linear
expansion for the particular substance, and AT is the change in temperature.
Of course, any solid that increases in length when heated will also expand in both other directions. The
change in volume V for such a solid is given by:
V V T A = |A
where | is the coefficient of volume expansion which is exactly three times the coefficient of linear
expansion. The equation for the change in volume can be applied to most liquids as well as solids.
Water, however, has a maximum density at 4C. A list of the coefficients of linear expansion for some
common substances is provided in Table 1.
6
Substance (10 /C)
Ice(at0C) 51
Aluminium 23
Brass 19
Steel 11
Glass(ordinary) 9
o
Table-1
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Q.33 A bimetallic strip consisting of brass and steel is welded together lengthwise
as shown. As the temperature increases:
s
t
e
e
l
B
r
a
s
s
(A) the brass will contract and the steel will expand, bending the rod to the left.
(B) the steel will contract and the brass will expand, bending the rod to the right.
(C) the brass will expand faster than the steel, bending the rod to the right.
(D) the steel will expand faster than the brass, bending the rod to the left.
Q.34 Which of the following is true concerning an aluminumbuoy that floats in a lake all year round? (Note:
The volume coefficient of expansion for water is 2 10
3
/C.)
(A) The buoy floats higher in the winter because the density of water changes more than the density of
aluminum.
(B) The buoy floats higher in the winter because the density of water changes less than the density of
aluminum.
(C) The buoy floats lower in the winter because the density of water changes more than the density of
aluminum.
(D) The buoy floats lower in the winter because the density of water changes less than the density of
aluminum.
Paragraph for question nos 35 to 36
Alice places two stereo speakers a distance d apart. She sends a signal which is a sine wave of
frequency f, so that the speakers are producing the same pure tone in phase. The sound wave in air has
a wavelength .
She enlists her friend Bob to do an experiment. Alice sits directly in front of the speakers on theline
which bisects the line segment connecting the speakers (see figure) but relatively far away fromthe
speakers. Bob starts at the same place, but he slowly moves to the right. For himthe sound gets quieter
as he moves right, until he can barely hear it. Then it begins to get louder again. The figure shows Bobs
position : where he first can barely hear the sound. This is the set up.
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: Rough Space :
In experiment 1, Alice and Bob keep their positions and Alice changes
the frequency of the signal sent to both speakers, so that both speakers
are still producing a sound in phase at the same frequency (a different
frequency fromthe set up).
In experiment 2, Alice changes the frequency of the second speaker
slightly, but the first speaker remains at the original frequency.

d
speakers
d
1
d
2
Alice bob
The distance d is large compared to the wavelength, and it is small
compared to the distance Alice and Bob sit fromthe speakers. The distance
fromBob to the left speaker is d
1
, and his distance to the right speaker is d
2
.
Q.35 In experiment 1, what is the best prediction for what Alice and Bob will observe ?
(A) Alice will hear very little sound, and bob will hear sound clearly.
(B) Alice will continue to hear sound, and Bob will continue to hear little.
(C) Alice will continue to hear
(D) Nothing can be predicted, in that Alice and Bobs sharing of sound frequency.
Q.36 In experiment 2, what is the best prediction for what Alice and Bob will observe ?
(A) Alice will continue to hear sound, and bob bill continue to hear little
(B) Alice will continue to hear sound, and bobs hearing of sound depends on the chosen frequency
(C) Alice and bob will hear a sound which grows and fades and grows
(D) Neither Alice nor Bob will hear very much sound.
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SECTI ON-D
Q.37 The velocity of blood flow in an artery can be measured using Dopplershifted ultrasound. Suppose
sound with frequency 1.5 10
6
Hz is reflected straight back by blood flowing at 1 m/s. Assuming the
velocity of sound in tissue is 1500 m/s and that the sound is incident at a very small angle as shown in
figure, calculate the frequency shift (in KHz) between the incident and reflected waves.
v=1m/s
Sound source
and
receiver
Q.38 A mass mtravels at speed v
0
perpendicularly to a stick of mass mand length l, which is initially at rest.
The mass collides completely inelastically with the stick at one of its ends, and sticks to it. What is the
location of point fromend A (in cm) which is at instantaneous rest just after collision. (take l =1.2meter)
A
B
15
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Q.39 Find the kinetic energy of pulse travelling in a taut string. Given T =10 N & =0.1 kg/m.
[Give answer in micro joules] fill the first two digits.
1mm
10cm 5cm
Q.40 One stick leans on another as shown in figure. A right angle is formed where they meet, and the right
stick makes an angle with the horizontal. The left stick extends infinitesimally beyond the end of the
right stick. The coefficient of friction between the two sticks is . The sticks have the same mass
density per unit length and are both hinged at the ground. What is the minimumvalue of tan u for which
the sticks do not fall? (Take =0.04)
16
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CHEMISTRY
SECTI ON-A
Q.41 The critical volume occupied by 1 mole of gas is 0.09 l mol
1
. The value of compressibility factor for
this gas under the conditions of high pressure 821 atm and temperature 300K is
[Take R =0.0821 atm l
1
K
1
mol
1
]
(A) 1 (B) 2 (C)
1
2
(D) 3
Q.42 Which of the following will not show geometrical isomerism?
(A) (B)
H
Me
(C) (D)
Q.43 In which of the following compound sulphur has maximumelectro negativity
(A) SO
2
(B) H
2
SO
3
(C) H
2
SO
4
(D) H
2
S
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: Rough Space :
Q.44 Find the approximate radius in of the orbit in which circumference is 6 times the de Broglie wavelength
in case of H atom if nucleus is non stationary. Consider in H atom(M
n
>>>m
e
), where M
n
is the mass
of nucleus and m
e
is mass of electron.
(A) 0.529 6
2
(B) 0.529 3
2
(C) 0.529 (D) None of these
Q.45 Which of the following is not the correct order ?
(A) CH
2
=CH
2
< < < (C=C bond length)
(B) > > (Heat of hydrogenation)
(C) CH
3
CH =C =CH
2
>CH
3
CH
2
CH =CH
2
>CH
2
=CH CH =CH
2
(Heat of hydrogenation per t-bond)
(D) > > (Heat of hydrogenation per t-bond)
Q.46 In H
6
P
6
O
18
compound, how many atoms has sp
3
hybridization
(A) 20 (B) 18 (C) 24 (D) 22
Q.47 Calculate the mole ratio of C
2
H
5
OH to CH
3
OH in aqueous solution if molality of C
2
H
5
OH is 40/9 and
mole fraction of CH
3
OH is 0.1 in solution.
(A) 0.33 (B) 0.66 (C) 0.24 (D) 0.45
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Q.48 Choose the correct statement :
(A) N
H
is less basic than CH
3
N CH
|
CH
3
3
. .
(B) is more stable than
(C)
is more basic than
(D) is nonaromatic
19
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SECTI ON-B
Q.49 Which of the following ions are paramagnetic in nature -
(A) Fe
+2
(B) Hg
+2
(C) Sc
+3
(D) Ti
+3
Q.50 Select the correct statement(s)
(A) Volume of gas is always equal to volume of container
(B) Boyle's temperature is 3.375 times of critical temperature
(C) Critical pressure is the maximumpressure at which gas can be liquified at critical point
(D) At critical temperature value of compressibility factor for van der Waal gas is always 3/8
Q.51 In which of the following pair, first compound is more basic than second.
(A)
NMe
2
Me
and
NH
2
Me
(B)
NH
2
NO
2
and
NH
2
(C)
NH
2
CH
3
and
NH
2
(D)
NH
2
and
NH
2
CCl
3
Q.52 If photon having wave length 6.2 nmwas allowed to strike a metal plate having work function 50eV
which of the following is/are correct [Given hc =1240 eVnm]
(A) When accelerating potential is 10V is applied the KE
max
can be 160 eV
(B) KE of photo electron may be between 0 to 150 eV if no potential is applied
(C) Stopping potential will be 150 volt.
(D) If wavelength of photon increases the KE of photo electron will increase
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SECTI ON-C
Paragraph for questions Nos. 53 to 54
10 moles of pure PCl
5
gas is put into a closed container of volume 'V' and temperature 'T' and allowed
to come at equilirbium, at an equilibriumpressure 20 atm. The pure PCl
5
is found to be 50% dissociated
at equilibrium PCl
5
(g) PCl
3
(g) +Cl
2
(g)
Q.53 K
p
for the above reaction is (in atm.)
(A) 20/3 (B) 100 (C)10/3 (D) 20/6
Q.54 By Changing the volume if equilirbium is restablished, then the partial pressure of PCl
5
is, if new
equilibriumpressure is 35 atm
(A) 10 atm (B) 15 atm (C) 18 atm (D) 12 atm
Paragraph for questions Nos. 55 to 56
Consider the following compound and answer the questions given below:
HO
NH
2
COOH
NH
2
HOS
3
NH
2
p
r
b
s
c
q
a
d
NHMe
Q.55 Which of the following is correct order of acidic strength
(A) q >r >p >s (B) q >r >s >p (C) r >q >p >s (D) r >p >q >s
Q.56 Which of the following is correct order of basic strength
(A) d >b >c >a (B) a >b >c >d (C) d >a >b >c (D) d >c >b >a
21
: Rough Space :
SECTI ON-D
Q.57 How many compounds has non zero dipole moment-
CCl
4
, CH
2
Cl
2
, BF
3
, XeF
4,
6
PCl ,
4
6
XeO , XeO
3
, BH
2
,
5
XeF
Q.58 A solution of solute 'y' contains 20% 'y' by weight of solution. 400 g of this solution was cooled when
38 g of solute gets precipitated. Now 100 g of solvent is added. Calculate the mass % of solute in new
solution (Fill your answer by multiplying it with 1/2)
Q.59 PCl
5
dissociates according to the reaction, PCl
5
(g) PCl
3
(g) +Cl
2
(g)
The density of equilirbium mixture at 1 atmand 5C is 6.25 gm/l, then calculate the value of K
p
for the
dissociation at this temperature. [Given R =0.08] Fill your answer by multiplying it with '3'
Q.60 Consider the following pair(s) of compound(s) and find the relationship between them:
(A) C O CH
3
||
O
and
C OH
||
O
HC
3
(B) and (C) and
Write (1) If the compounds are chain isomer
(2) If the compounds are position isomer (3) If the compounds are functional group isomer
(4) If the compounds are ring chain isomer (5) If the compounds are metamers
Give the answer in 1 digit (sum) for example if answer of (A) is 1, (B) is 2 and (C) is 3, then
fill 6 {1 +2 +3}in the OMR sheet

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Date : 09-02-2013 Duration : 3 hours Max.

Q.3 If reflection of circle x

(C) destructive interference when (x

is more basic than

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