Code No.

Total No. of Questions : 39 ]

34

Total No. of Printed Pages : 15 ]

June/July, 2010

CHEMISTRY
( Kannada and English Versions )
Time : 3 Hours 15 Minutes ]

[ Max. Marks : 90
( Kannada Version )

i)

XR XxY @ .

ii)

- A,
O .

iii)

- A XR x@ 10 , - B
XR x@ 2 20 , - C XR x@
5 40 - D Y D 1 10
D 2 Y XR x@ 5 10 O.

iv)

WY XR O R .

B, C

Y XRR W

- A
:

1.

i)

Y 10 XRR O .

ii)

XR Y WY O R
. X XR O.
10 1 = 10

XK XR
Y Q } ?

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Code No. 34

2.

W } .

3.

| xX| X | x] XX
SO xX OR .

4.

W WZW X R .

5.

0732 10

X{WR T X

Z zW J ?
6.

W@ ?

7.

W X X ?

8.

X @ XY
_ W SR .

9.

xY] XY y ?

10.

y YR .

-B

i)

O XRR O.

ii)

X XR R O.
10 2 = 20

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11.

Code No. 34

_ x] K Y x _ R YW x\
.

12.

TWy Y | O ?
R .

13.

R } .

14.

W J x\ O Y XR @
.

15.

XR R .

16.

zW ? K zWR x.

17. 10 3 M

HA

XY

43%

_O.

PR @ .
18.

O ?

19.

Xy YR ? R x.

20. -D ( + )

J W R .

21.

QM XR .

22.

|XY ? |XY W XR .
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Code No. 34

I.

-C

xY XR O :
23. a)

2 5 = 10

xX| | xXR
S ? R .

b)

24. a)

b)

XK X xY E YR
OR .

J } x R .

(]) QM Y ||Xy x
(O)

25. a)

Y R , R .

J X O OR
XY . x ?

b)

c)

II.

yd

QM

b)

R ?

K @ PR .

xY XR O :
26. a)

- XR } .

3 5 = 15

y O J }Y
WWR x.

5
27. a)

b)

Code No. 34

X X XXR .

XR @ | y
? R .

28. a)

x X R :
i)

yW] || O yW] |
XR 400C Y @ J

ii)

b)

yd y]y Y Y X
} ? y .

R .

X Y { ? R .

b)

@ ? R .

c)

WzW : W P P.

c)

29. a)

III.

{L x]

xY XR O :
30. a)

b)

3 5 = 15

Xx] O xY y\
X XR .

W }R } WzW.

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Code No. 34
31. a)

J O \ x R .
XR .

b)

X X O
.
,

32. a)

298 K

308 K

566 kJ/mol.

24 10 3 /min.

Y R @ .

( R = 8314

J/K/mol. )

WX X ? O .

b)

56 pH

c)

HCO

33. a)

X X R . 2

1
3

V XWYR .

X J O O } ? P
P R ?

b)

R R X WF ?

c)

Z T } x.

X R .

34. a)
b)

QMR WzW.

A2B

O QMx@ R .
c)

N XY

u}VQ Y

X Z-X ?

Code No. 34

-D

D1
IV.

xY XR O :
35. a)

1 10 = 10

J X xd O yR .
.

b)

UR || QM N Y XR
.

c)

d)

36. a)

WzW :
i)

x xX

ii)

{W .

K O . .

R WzW. X X X
YR .

b)

298 K

Zn|Zn + 2

xdR

Mg|Mg 2 +

W@ J O OR @ .

( O : E

o
Zn

= 076 V

E Mg = 237 V

c)

y YR ? R x.2

d)

Z \ QM XR .

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Code No. 34

8
D2

V.

xY XR O :
37. a)

b)

38.

|X

||XR

2 5 = 10

XY

O ?

xX x\R .

| T| O | XY
X }R XR .

39.

X y]y Y XR | R
XY,
i)

X R .

ii)

| | XWR .

iii)

R .

iv)

X WY N }R .

v)

xJ

250

cm 3

XY |

| XWR XW @
XR .

Code No. 34

( English Version )

Instructions :

i)

The question paper has four Parts.

ii)

Parts A, B, C and D are common to all the candidates.

iii) Part A carries 10 marks. Each question carries one mark.

Part B carries 20 marks. Each question carries two marks.
Part C carries 40 marks. Each question carries five marks.
In

Part

D D 1 carries 10

marks and

D 2 carries

10 marks. Each question of D 2 carries five marks.

iv) Write balanced chemical equations and draw diagrams
wherever necessary.

PART A
Note :

i)

Answer all the ten questions.

ii)

Questions have to be answered in one word or in one

sentence each. Each question carries one mark.
10 1 = 10

1.

At what temperature is neon adsorbed on charcoal in the separation of

noble gases by Dewar's method ?

2.

Give an example for polydentate ligands.

3.

Name the chromium compound formed when potassium dichromate

solution is treated with potassium hydroxide.

4.

State Faraday's first law of electrolysis.

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Code No. 34
5.

10

What is the co-ordination number of each ion, for a crystal that has radius
ratio between 0732 10 ?

6.

What is electrophoresis ?

7.

What is Pseudo first order reaction ?

8.

Name the main product formed when bromoethane is heated with sodium
metal in dry ether.

9.

What is the reducing agent used in Clemmensen's reduction ?

10. Name an amino acid containing aromatic ring.

PART B
Note :

i)

Answer any ten questions.

ii)

Each question carries two marks.

10 2 = 20

11. With the help of Ellingham diagram, explain why oxide of silver can be
thermally decomposed at relatively lower temperature.

12. How does concentrated sulphuric acid react with potassium iodide ? Write
the equation.

13. Explain ionisation isomerism with an example.

14. Write the energy level diagram for helium molecule and calculate the bond
order in it.

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Code No. 34

15. Write any two factors deciding the order of a reaction.

16. What is gold number ? Give the gold number of starch.

17. A weak acid HA dissociates to an extent of 43% in a 10 3 M solution of it.
Calculate its dissociation constant.

18. What is osmotic pressure ?

19. How is picric acid obtained from phenol ? Give the equation.

20. Write the Haworth's structure of -D ( + ) maltose.

21. Give any two postulates of Baeyer's strain theory.

22. What are triglycerides ? Write the general formula of a simple triglyceride.

PART C
I.

Answer any two of the following questions :

23. a)

How is potassium dichromate manufactured from concentrated

chromite ore ? Give the equations.

b)

24. a)
b)

2 5 = 10

Name the chemical used to remove the last traces of oxygen from
a mixture of noble gases.

State Nernst distribution law.

On the basis of valence bond theory, explain the hybridisation in

tetracarbonyl nickel ( O ). Indicate the geometry of it.

3
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Code No. 34
25. a)

12
Many transition metals and their compounds are used as
catalysts in several chemical reactions. Why ?

b)

c)
II.

How does electron gas theory explain the malleability and

ductility of metals ?

Write the highest oxidation state of Vanadium.

Answer any three of the following questions :

26. a)
b)

27. a)
b)

3 5 = 15

Explain ReimerTiemann reaction with an example.

Give any two differences between mesomeric and inductive

effects.

Explain the mechanism of nitration of benzene.

What happens when bromoethane is heated with alcoholic

potash ? Give the equation.

28. a)

Write the equations for the following reactions :

i)

a mixture of calcium acetate and calcium formate crystals

are dry distilled at 400C.

ii)

Benzaldehyde

is

treated

with

concentrated

sodium

hydroxide solution.
b)

What is the effect of electron releasing groups on the acidity of

carboxylic acids ? Give reason.

Give any two uses of methanal.

How does nitrous acid react with aniline ? Give the equation.

b)

What is a drying oil ? Mention one use of it.

c)

Define the term 'isoelectric point'.

c)
29. a)

III.

Answer any three of the following questions :

30. a)

b)

3 5 = 15

Explain the buffer action of a basic buffer containing ammonium

hydroxide and ammonium chloride.

Define common ion effect with an example.

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31. a)

Code No. 34

State Raoult's law of relative lowering of vapour pressure. Give

the mathematical form of it.

b)

Energy of activation of a first order reaction is 566 kJ/mol. If its

rate constant at 298K is 24 10 3 /min, calculate the rate

32. a)
b)

constant at 308K. ( R = 8314 J/K/mol. ).

What is an electrochemical series ? Give one application of it.

Calculate the hydrogen ion concentration of a solution whose pH

is 56.

c)
33. a)

Write the conjuate base of HCO

1
3

What is standard free energy change of a chemical reaction ?

How is it related to the equilibrium constant ?

b)

How is gold sol prepared by Bredig's electric arc method ?

c)

Give an example for molecular crystals.

Give any two characteristics of an ideal solution.

34. a)
b)

Define

solubility

product.

Write

the

relationship

between

solubility and solubility product of a sparingly soluble salt of the

type A 2 B.
2
c)

Under

what

condition,

an

exothermic

spontaneous, if S is negative ?

reaction

will

be
1

PART D
D1
IV.

Answer any one of the following :

35. a)

Explain the construction and working of standard hydrogen

electrode. Give one limitation of it.

b)

1 10 = 10

Explain with equation, the role of limestone in the extraction of

iron from haematite ore.

2
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Code No. 34
c)

d)

36. a)

14
Define the following :

i)

Chirality centre

ii)

Geometrical isomerism.

Carbohydrate is a source of energy. Explain.

Define the term 'half-life period'. Show that the half-life period of
a first order reaction is independent of initial concentration of
the reactant.

b)

Calculate the standard free energy change of a cell prepared by

combining Zn|Zn + 2 and Mg|Mg + 2 electrodes at 298K.

( Given : E
c)

d)

o
Zn

= 076V ; E Mg = 237V

How would you convert acetic acid to methane ? Give the

equations.

Give any three salient features of molecular orbital theory.

D2
V.

Answer any two of the following questions :

37. a)

b)

2 5 = 10

How is m-dinitrobenzene prepared in the laboratory from

nitrobenzene ?

Explain Acrolein test.

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Code No. 34

38. Describe an experiment to show the effect of concentration on the

rate of the reaction between potassium persulphate and potassium
iodide.

39. For the estimation of potassium permanganate using standard oxalic

acid solution
i)

write the chemical equation for the reaction involved.

ii)

give the equivalent mass of potassium permanganate.

iii)

name the indicator used.

iv)

write the colour change at the end point.

v)

write the equation for calculating the mass of potassium

permanganate present in 250 cm 3 of the solution from its
normality.

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