1 CHEM 111 Second hour test October 18, 2002 page 1 of 5 Your full name (PLEASE PRINT) _______________________________

Your scheduled Tuesday quiz section (please circle) B hr E hr

Your scheduled Tuesday quiz instructor:__________________________ You may use a writing implement, hand-calculator, and your Periodic Table (unmarked, tan, honor code) as obtained in this course. NO scratch paper is permitted! As requested of the faculty by the Student Executive Committee, students must sit in every other seat during the test. The PROPER METHOD (i.e., Problem Set 0) must be shown clearly on all problems, and final answers must be expressed in appropriate form. Pay attention to dimensions!! When blanks for answers are provided, write your answer to be graded in the blank---we may not grade answers written in other locations! These constants may apply to problems on this test: h = 6.626076 x 10-34 J.s, c = 2.99792458 x 108 m/s, -27 1 u = 1.660540 x 10 kg -19 1 eV = 1.602177 x 10 J dimensions of the Joule (J) = kg.m2.s-2 mass of electron, me = 0.00054857990 u mass of proton, mp = 1.00727647 u mass of neutron, mn = 1.00866490 u -19 charge of electron, e = 1.6021773 x 10 C -12 vacuum permittivity, 0 = 8.8541878 x 10 C2.J-1.m-1 LD50 (human radiation) = 5 Gy 1 Gy = 1 J.kg-1 (should be on your calculator, in case it is not....) = 3.1415926 -28 k (Dr. Uffelman's little constant in Coulomb's law) = e2/40 = 2.3070795 x 10 J.m e4me Rydberg constant, R = = 2.18 x 10-18 J 2 2 8 0 h

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2 1. (7 pts) Chem 111 veterans Patrick Lawler and Karl Kuersteiner, wanting to set themselves apart from other medical school applicants, team up and build a three billion dollar particle accelerator on a little 45,000 acre spread in Texas. In a test of the wave theory of matter, they accelerate a proton to a velocity of 1.37 x 105 miles per second. Given that there are 1.609 km per mile, and given the information on the cover of the test, what wavelength (in meters) do you predict Pat and Karl will observe?

Answer:_________________ 2. (7 pts) Chlorine monofluoride, ClF, is a colorless gas at room temperature but can be frozen into a crystalline solid at temperatures below 125 K, at which low temperatures its density becomes 1.62 g/mL as a solid. If a 2.00 L (STP) sample of ClF is cooled to 120 K, what will be the final volume (in liters) as solid ClF?

Answer:_________________ 3. (8 pts) a) Given En = (Z2/n2) R , calculate the energy of the transition from n=2 to n=1 for a single He+ ion.

Answer:_________________ b) Sketch all of the electron and nuclear interactions that occur in the He+ ion. Label the particles and identify the interactions as was done in class.

c) Referring to the interactions you diagrammed above, write the equation that describes the potential energy for the He+ ion. Answer:_________________ 4. (8 pts) Write formulas for the following compounds:

3 ammonium thiosulfate:______________ zinc sulfide:_______________ barium hydroxide:__________________ calcium chromate:________________

5. (8 pts) Draw pictures of the following orbitals (be sure to indicate phases, axes, and label and identify nodes where appropriate): a) sp2 b) 2p c) 3pz d) 3dx2-y2

6. (6 pts) Please fill out the table below according to the method illustrated in recitation. electron pool? dot picture? electron pair shape? molecular shape? (sketch and name) (show work) (draw dots clearly!) (sketch and name) hybridization? how many -bonds likely? ICl3

7. (5 pts) Which of the following combinations of quantum numbers are allowed for an electron in a oneelectron atom? Circle the letter(s) of your choice(s). (a) n = 4, l = 2, ml = 1, ms = 1/2 (c) n = 5, l = 1, ml = -1, ms = -1/2 (e) n = 4, l = 0, ml = 0, ms = 0 8. (4 pts) For each of the following pairs of atoms or ions, circle the species which you expect to have the larger radius: (a) 11Na or 19K (b) 55Cs or 55Cs+ (c) 37Rb+ or 36Kr (d) 17Cl or 18Ar (e) 32Ge or 33As 9. (2 pts) Which of the following has the least favorable electron affinity? (Please circle your answer) F Cl Si S Ar (b) n = 3, l = 1, ml = 2, ms = -1/2 (d) n = 3, l = 3, ml = 1, ms = 1/2

4 10. (2 pts) Which of the following ions has the largest radius? (Please circle your answer) 53I35Br55Cs+ 57La3+

11. (2 pts) Which of the following will be the most electronegative? (Please circle your answer) 55Cs 53I 17Cl 11Na

12. (3 pts) What are the possible values of n, l, ml, and ms for a 6p electron? n = ________________; l = ________________; ml = ________________; ms = _______________ 13. (3 pts) For a 6dz2 atomic orbital, how many radial nodes? _____ How many angular nodes? _____ 14. (5 pts) For the three resonance structures of the cyanate ion shown below, write the formal charge of each atom underneath each atom on the line provided. Circle the resonance structure that will contribute the least to the real structure of cyanate, and briefly explain why in the space at the right.

O C N

O C N

O C N

15. (11 pts) (a) Draw a molecular orbital energy correlation diagram below for F2 in the manner done in class and in the textbook. (b) Carefully label both the atomic and molecular orbitals in your diagram (g and u label are NOT necessary). Orbital cartoons are NOT required in your diagram. (c) Fill your diagram with the appropriate number of electrons for F2. (d) What is the bond order of F2? _____ (e) What is the bond order of F2 ? _____ (f) Is F2 paramagnetic? ______ (g) Would F2 be stable by itself? ______ (h) Would F2 be stable by itself? _____ (i) What aspect of the diagram you have drawn at left allows you to predict the relative ionization energies of the F2 molecule and the F atom? 16. (19 pts) Circle the letter of all of the statements below that are true:
2+ +

5 a) The Born-Oppenheimer Approximation simplifies the three body problem encountered with the + H2 molecule. b) The Self Consistent Field Approximation simplifies the potential energy operator for the He atom. c) Because a 3s atomic orbital has two radial nodes that separate three regions of space, the 3s orbital can hold a maximum of six electrons. d) For a one-electron H-like atom, the 3s, 3p and 3d atomic orbitals are degenerate in energy. e) For a multi-electron atom, the energy depends only on the value of the n quantum number. f) The solution to the Schrodinger equation gives information regarding both the energy and the wave function. g) It is possible to write wavefunctions for molecular orbitals by combining atomic orbital wave functions. h) In valence bond theory for NH2 , each of the N-H sigma bonds can be described as the overlap of nitrogen sp3 hybrid orbital with a hydrogen 1s atomic orbital. i) In valence bond theory, the dxy and dxz orbitals may be chosen to make sp3d2 hybrid orbitals. j) Constructive and destructive interference between atomic orbitals on the same atom can be used to understand the shapes and geometries of hybrid orbitals. k) Constructive and destructive interference between atomic orbitals on different atoms can be used to understand the shapes and geometries of molecular orbitals. l) In valence bond theory, the energy price of electron promotion in energy is more than compensated for by the lowering in energy due to the enhanced bonding that results. a m) In the valence bond treatment of formaldehyde, H2CO, the pi bond is described as the overlap of 2p molecular orbital on C with a 2p molecular orbital on O. n) Paramagnetic compounds are attracted into a magnetic field. o) The emission spectra of atoms give continuous values of wavelength across the visible spectrum. p) In the atomic orbital wavefunctions, e-r means that the electron has a possibility of existing at infinity. q) The cos term in the wave function for the 2pz orbital leads to a node in the xy plane. r) For Br atom, a 4s electron experiences a different Zeff than a 4p electron. s) For NO2 , all of the atoms are sp2 hybridized in valence bond theory.
PLEDGE: I have neither given nor received any unacknowledged aid on this test. Signed, ______________________________________
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