DHRUVA KUMAR BANERJEE STOICH IOMETRY PROBLEMS (A) 0.45 (B) 0.90 (C) 1.8 37. 38.

What was the molarity of permanganate solution ? (A) 0.675 (B) 0.135 (C) 0.27

(D) 0.6 (D) 0.405 (D) 9.76 x 1021

How many ferrous ions were present in 25 mL of its solution ? (A) 4.88 x 1020 (B) 2.44 x 10R3 (C) 2.44 x 1021 Paragraph for Question Number 39 to 41

Air sample from an industrial town, heavily polluted by CO2 was collected and analyzed. In one analysis, 56 L of air measured at NTP was passed through a 250 mL of a 0.025 M NaOH solution, where CO2(g) was absorbed completely. 25mL of the above solution was then treated with of BaCl2 solution where all the carbonate was precipitated as BaCO3(s). The solution was filtered off and the filtrate required 25 mL of a 0.005M HCI solution for neutralization. Answer the following four questions based on the given observations. 39. 40. ppm strength of CO2(g). volume by volume i.e., mL of COR per 106 mL of air was : (A) 560 (B) 5600 (C) 100 (D) 1000

Weight (in milligrams) of precipitate BaCO3(s), obtained from the 25 mL of test solution was (Molar masses : Ba = 137, C = 12, 0 = 16). (A) 27.58 (B) 275.8 (C) 4.925 (0) 49.25 Fraction of original NaOH (by mole) that reacted with CO2 was : (A) 0.2 (B) 0.4 (C) 0.6 Paragraph for Question Numbers 42 to 44 Temporary hardness is caused by a combination of calcium ions and bicarbonate ions in the water. It can be removed by boiling the water or by the addition of lime (calcium hydroxide). Boiling promotes the formation of carbonate from the bicarbonate and precipitates calcium carbonate out of solution, leaving water that is softer upon cooling. The following is the equilibrium reaction when calcium carbonate (CaCO3) is dissolved in water: CaCO3(s) + H2CO3(aq)---> Ca2=(aq) + 2HCO3-(aq) Upon heating, less CO2 is able to dissolve into the water. Since there is not enough CO 2 around, the reaction cannot proceed from left to right, and therefore the CaCO3 will not dissolve as rapidly. Instead, the reaction is forced to the left (i.e. products to reactants) to re-establish equilibrium, and solid CaCO3 is formed. (D) 0.8

41.

42.

Temporary hardness can best be removed by (A) Boiling and cooling it suddenly. (B) Boiling and filtering immediately (C) Boiling and filtering after cooling to room temperature (D) Boiling and adding some CaCl2 To a sample of permanent hard water, if excess CO2 gas is passed (A) it becomes temporary hard water (B) it remains permanent hard water (C) all Ca2+. ions will be precipitated as CaCO3 (D) Cl will be oxidized to Cl2 and water gets chlorinated. Use of excess lime is not effective in removing temporary hardness because A)it makes water alkaline B)it converts CaCO3 precipitate back into bicarbonate C)it is insoluble in water D)increases the temperature of water which increases the solubility of CaCO3 in water.

43.

44.

SECTION - IV : (Assertion & Reason Type) This section contains 3 Assertion-Reason type questions. Each question contains STATEMENT-I (Assertion) and STATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct. In each of the following questions, two statements are given. Choose the correct code (A), (B), (C) or (D) defined below : A) Statement-I and Statement-2 are true, Statement-2 is the correct explanation of Statement-l. 0)Statement-l and statementr-2 are true but Statement-2 is not the correct explanation of Statement-2 is false. A)Statement-I is true and Statement-2 is false. B)Statement-l is false and Statement-2 is true.