Petrologia Metamrfica

Aula 11
Tipos de reaes metamrficas

Profa. Dra. Hanna Jordt Evangelista DEGEO/EM/UFOP 2011

Reaes de intercmbio ou troca catinica (exchange reactions) reactions)

Troca de Fe-Mg entre solues slidas

Ex.: Ex : Troca de Fe e Mg entre biotita e granada (bom geotermmetro!)

NetNet-transfer reactions Reaes de transferncia de massa (de minerais reagentes para produzir novos minerais):

- descontnuas (= univariantes) - contnuas (= de equilbrio mvel, divariantes) ( q , )

Reaes descontnuas: slido - slido

As curvas de equilbrio univariante so retas

Reaes descontnuas: slido = slido + fluido

Curva univariante tem inclinao varivel (Best, 1982)

Reao descontnua: slido = slido + fluido

Moscovita + quartzo = ortoclsio + sillimanita + H2O M it t t l i illi it (para PH2O = Ptotal)

Influncia da composio da fase fluida no equilbrio de reaes metamrficas

Moscovita + quartzo = ortoclsio + sillimanita + H2O (Winter, 2001)

Influncia da composio da fase fluida no equilbrio de d reaes metamrficas t fi

Calcita + quartzo = wollastonita + CO (Winkler, 1979)

Reaes contnuas d equilbrio mvel R t de ilb i l (reaes divariantes)

Os minerais so solues slidas

Reao contnua ( equilbrio mvel) (de q )

Clorita + quartzo = granada + H2O (Winter, 2001)

Reao contnua (de equilbrio mvel)

Cordierita = granada + sillimanita + quartzo (Best, 1982) C di it d illi it t (B t

Grade t G d petrogentica para rochas mficas (Winter, 2001) ti h fi

Reaes contnuas envolvendo anfiblios e piroxnios

Reao cclica (Yardley, 1989)

a) Cia + qu + K+ + H2O = mosc + H+ + Si(OH)4

b) Mosc + H+ = M sill + qu + K+ + H2O

a+b = cianita

sillimanita

Reaes de exsoluo (reaes de solvus) solvus)

Feldspato alcalino = K- feldspato + Na-feldspato (pertita) KNa-

Curvas de fuso e do solvus dos feldspatos alcalinos

Sistema KNASH (Spear, 1993)

Reaes de oxidao - reduo

Magnetita + O2 = hematita 4Fe3O4 + O2 = 6Fe2O3 Faialita + O2 = quartzo + magnetita 3Fe2SiO4 + O2 = 3SiO2 + 2 Fe2O3

Reaes de oxidao - reduo

Referncias Bibliogrficas
Best, M.G. 1982 - Igneous and Metamorphic Petrology. W.H. Freeman and C F d Company, N New Y k 630 York, 630p. SPEAR, F.S. SPEAR F S - 1993 Metamorphic Phase Equilibria and Pressure-Temperature-Time Paths. Mineralogical Society of America, Monograph, Washington, D.C., 799p. WINKLER, H.G.F. - 1979 Petrogenesis of Metamorphic Rocks. Springer Verlag 334p Verlag,

WINTER, J. D. - 2001 - An Introduction to Igneous and Metamorphic Petrology. Prentice H ll N M t hi P t l P ti Hall, New J Jersey, 697 697p. YARDLEY, B.W.D. - 1989 - An Introduction to Metamorphic Petrology. Longman, England, Petrology Longman England 248 p p.