Set 1 STRUCTURE OF THE ATOMS 1.

Matter is anything that

Structure of the atoms & Chemical Equation Perfect Score F4 2010

and has

2.The particle theory of matter state that matter is . 30. . Type Property of particle Example Diagrammatic representation of the particles in each of the physical states Arrangement of particles. Solid Liquid Gas

Forces of attraction between particles Movement of particles Energy content

0.

Subatomic particles in an atom. Subatomic particle Symbol Relative mass Charge

Isotope are atoms with the

same ..................................................................

but different

The isotopes of an element

have same........................................................ because they have....................................

. but different

Compare and contrast the

atoms below.
12 6

14 6

1
Chemistry Perfect Score Module Form 4 2010 Set 1

Set 1 9. Complete the table below. Isotope Carbon-14 Cobalt-60 Sodium-24

Structure of the atoms & Chemical Equation Perfect Score F4 2010

mistry Perfect Score Module Form 4 2010 Set 1

Uses

PAPER 2 : STRUCTURE 1. (a) Diagram 1.1 shows the results of an experiment to investigate the movement of bromine particles in air.

Air Gar jar Reddish brown vapour spreads throughout both gas jars within 10 minutes Cover Bromine vapour Cover removed Diagram 1.1 name of the process involved in this experiment. (i) State the [1 mark] ii) State the type of particles present in bromine gas. [1 mark] 0)Explain the observation in this experiment based on the kinetic theory of matter.

[3 marks]

Set 1

Structure of the atoms & Chemical Equation Perfect Score F4 2010

Temperature

Diagram 1.2

Chemistry Perfect Score ModuleT R Form 4 2010 Set 1

83

Time, s
(b) Diagram 1.2 shows a graph of temperature against time when solid X is heated? (i) State the melting point of X. [1 mark] (ii) What happens to the temperature while the substance changes state? Explain.

(iii) Explain the movement of particles X between R and T during heating.

[2 marks]

[2 marks]

Glass wool soaked in concentrated ammonia solution

Glass wool soaked in concentrated hydrochloric acid

Diagram 2
2. Diagram 2 shows the set-up of apparatus to investigate the reaction between concentrated hydrochloric acid and concentrated ammonia solution to form substance X. Based on the information, answer the following questions. (a) (i) What is the observation in the glass tube?

[1 mark]

Set 1

Structure of the atoms & Chemical Equation Perfect Score F4 2010 (ii) Name substance X

[1 mark] (iii) Name the process occurs in the glass tube.

[1 mark] (b) Which gas diffused faster? Why?

[2 marks] (c) Write the chemical equation for the reaction in the experiment.

[1 mark] 3. Table 3 shows proton number and nucleon number for atom W, X and Y. Atom W X Y Proton number 11 17 17 Nucleon number 23 35 37

Table 3
(a) (i) What is meant by proton number? [1 mark] (ii) What is the number of neutron in atom W ? [1 mark] (b) Which atoms are isotopes? Explain why.

(c) Write the electron arrangement of atom X .

Chemistry Perfect Score Module Form 4 2010 Set 1

[2 marks]

[1mark]

Thermometer Set 1 Structure of the atoms & Chemical Equation Perfect Score F4 2010

mistry Perfect Score Module Form 4 2010 Set 1

(d) (i) Draw the electron arrangement of atom Y. In your diagram , show the number of proton Water and the number of neutron in the nucleus.

[2 marks] ii)What is the number of valence electron of atom Y? [1 mark] iii)Write the formula of ion Y.

(e) Write the symbol of atom X in the form of X

Z

[1 mark] .

[1 mark] 4. (a) Diagram 4.1 shows the set-up of an experiment to determine the melting point of solid X.

Diagram 4.1 The temperature of X is recorded at 30 seconds intervals as shown below. Time/second Temperature/oC

0 70

30 77

60 80

90 80

120 80

150 82

180 85

210 95

(i) Plot the graph of temperature against time for the heating of X on the graph paper. [3 marks]

Set 1

Structure of the atoms & Chemical Equation Perfect Score F4 2010 Graph temperature against time

6
Chemistry Perfect Score Module Form 4 2010 Set 1

Set 1

Structure of the atoms & Chemical Equation Perfect Score F4 2010 ii)On the graph that you have drawn in (a), label the melting point of substance X. [1 mark] 0)Explain why the temperature remains constant from 60 s to 120 s?

[2 marks] (iv) Draw the arrangement of particles in X at 85oC

[ 1 mark ] (b) Why has the solid X in the boiling tube be stirred constantly with the thermometer during the experiment? [1 mark] (c) Why solid X is not directly heated without using water bath? [1 mark] 5. Table 5 shows four substances and their respective formulae. Substance Iodine Copper Ethanol Potassium chloride Table 5 (a) State 2 substances that consist of molecules. [2 marks] (b) Which of the following substances has a highest melting point? [1 mark] (c) State the substance that can conduct electricity in the solid state. [1 mark] (d) Name the particles present in potassium chloride.
Chemistry Perfect Score Module Form 4 2010 Set 1

Chemical formula I2 Cu C2H5OH KCl

X
7

[1 mark]

Set 1 PAPER 2 : ESSAY 6.

7 p 7n

Structure of the atoms & Chemical Equation Perfect Score F4 2010

mistry Perfect Score Module Form 4 2010 Set 1

Diagram 6.1 shows an atom of an element based on the model by James minutes Time, Chadwick.

Electron

[2 marks]

Neutron Diagram 6.1

(a) Compare the relative mass and the charge of two of the subatomic particles in diagram 6.1. [4 marks]

Diagram 6.2
Diagram 6.2 shows an atom of element X. (b) (i) Describe fully the atomic structure shown in diagram 7.2. [4 marks] (ii) Write a symbol for the element in the form of A

Z
(c) Graph 6.3 shows the heating curve of element Y.

Temperature /o C

Melting point

Graph 6.3 to t1 t2 t3
[10 marks]

Describe the graph in term of states of matter, particles arrangements and changes in energy.

ee e

3+
Water

Jelly

ee Set 1 Chemistry 14 n Score Module Form 4 2010 Set 1 Structure of the atoms & Chemical Equation Perfect Score F4 2010 Perfect n - neutron e - electron ee
7
Potassium manganate(VII) (a) What is meant by melting point? e During the melting of naphthalene, the temperature remains constant even though heat ee is applied. Explain why. Diagram 7

Condensation is the process where a gas changes to its liquid state at a certain temperature and pressure when it is cooled. (b) Describe the change of the kinetic energy, arrangement and the forces of attraction between the particles at the following states: i)Before condensation ii)During condensation iii)After condensation

[10 marks]

(c) Diagram 7 shows the electron arrangement of ion Y3+.

(i) Calculate the nucleon number of atom Y. (ii) Y reacts with oxygen to form oxide Y, with the formula Y2O3. The chemical equation for reaction Y with oxygen is show as: 4Y + 3O2 - 2Y2O3. Given that the relative atomic mass of Y = 27 and O = 16. Calculate the mass of oxide Y, Y2O3 formed when 10.8 g Y is completely burnt in oxygen.

[2 marks]

[4 marks]
PAPER 3 : STRUCTURE
Gas jar _____ cover Gas jar Bromine vapour

Diagram 8

Set 1 8.

Structure of the atoms & Chemical Equation Perfect Score F4 2010 A group of students set up the apparatus for an experiment as shown in diagram 8. The result is obtained by the students are shown in table 8. Experiment A B C Observation After a few minutes the gar jar was filled with a reddish brown gas. After a few hours, the water turns purple. After a few days, the jelly turns purple.

(a) State the aim of the experiments carried out.

(b) State the hypothesis of the experiments.

(c) State i)The manipulated variable. 0)The responding variable.

0)The fixed variable of the experiments.

(d) Based on the observation, arrange the three states of mater in a sequence to show their speed in increasing order. (e) Based on the rate of the movement of the particles, describe the arrangement of the particles in the three states of matter.

(f)

Give the daily application of the process in one of the above experiment.

mistry Perfect Score Module Form 4 2010 Set 1

10

Set 1

Structure of the atoms & Chemical Equation Perfect Score F4 2010 1 1

CHEMICAL FORMULA AND EQUATION 1. Write the chemical formula of the compound in the table below. Ion Sodium Magnesium Lead(II) Copper (II) Iron (II) Iron (III) Aluminium 2. Write balanced chemical equation for the following chemical reactions. a)Heat solid of copper (II) carbonate 0)Nitric acid reacts with sodium hydroxide 0)Hydrochloric acid reacts with zinc metal 0)Copper(II)nitrate reacts with magnesium 0)Chlorine gas reacts with lithium hydroxide 0)Hydrogen gas reacts with lead(II) oxide Chloride Nitrate Hydroxide Sulphate Carbonate oxide

3.

Avogadro constant, NA is defined as the number of particles in one mole of a substance [1 Mol any substance consist of 6.02 X 1023 particles]. Calculate the number of particles in: a)0.1 mol of calcium b)1.5 mol of iron c)2.0 mol of oxygen gas d)1.5 mol of helium
Chemistry Perfect Score Module Form 4 2010 Set 1

0)2.0 mol hydrogen chloride

Set 1 4.

Structure of the atoms & Chemical Equation Perfect Score F4 2010 Calculate the number of moles of the following substances. a)6.0 x 1023 aluminium b)1.8 x 1021 argon c)1.2 x 1023 bromine gas d)2.4 x 1020 carbon dioxide e)3.0 x 1023 ammonia

1 2

5.

Calculate the mass of following substances. b) 2.5 moles of oxygen gas

a) 1.5 mol of chlorine gas

c) 2.0 moles of sulphuric acid

d) 0.5 moles of ammonia, NH3

e) 2.5 moles of lead (II) carbonate

f) 0.5 moles copper(II) nitrate, Cu(NO3)2

Molar volume: The volume of one mole of the gas [22.4 dm3 mol-1 at STP, standard temperature and pressure] [24 dm3 mol-1 at Room condition] 6. Calculate the volume of gases below. a)0.5 mol of chlorine at STP. b)0.2 mol of carbon dioxide at Room condition. c)1.5 mol of methane at room condition. d)0.5 mol of helium at room condition. 0)2.5 mol of ammonia at STP
Chemistry Perfect Score Module Form 4 2010 Set 1

Set 1 7.

Structure of the atoms & Chemical Equation Perfect Score F4 2010 Calculate the number of moles of the gases below. a)250 cm3 of carbon dioxide in room temperature. b)500 cm3 of hydrogen sulfide at STP. c)200 cm3 of hydrogen chloride in room temperature. d)750 cm3 of neon in room temperature. e)300 cm3of ammonia at STP.

1 3

8.

Magnesium powder reacts with hydrochloric acid to produce salt and hydrogen gas. a)Write the balance chemical equation for this reaction. 0) If 2.4 g of magnesium powder is added into excess hydrochloric acid, calculate, i)The mass of salt formed.

0)The volume of hydrogen gas liberated at room temperature. 9. Lead is extracted according to the following equation. C a) b) + P b O

C O

P b

Write the balanced chemical equation for the reaction. Determine the number of moles of lead extracted from 0.5 mole of lead (II) oxide.

c)

Calculate the number of moles of carbon required to extracts 0.5 mole of lead(II) oxide.

0)

What is the mass of lead are produced if 44.6 g of lead (II) oxide is heated with excess carbon. [ RAM : Pb = 207, O = 16, C = 12 ]

Chemistry Perfect Score Module Form 4 2010 Set 1

Set 1 10.

Structure of the atoms & Chemical Equation Perfect Score F4 2010 Excess sodium carbonates is added into 50 cm3 of 0.5 mol dm-3 copper(II) chloride. The chemical equation for the reaction is as follows: CuCl2 + Na2CO3 -

NaCl + CuCO3

a)Balance the chemical equation for the reaction. b)Calculate the mass of copper(II)carbonate.

11.

5g of calcium carbonate is added to excess hydrochloric acid. a)Write balanced chemical equation for the reaction.

1 4
0)Determine the volume of carbon dioxide gas evolved at room temperature

12.

When sodium bicarbonate is heated, it decomposed to sodium carbonate, carbon dioxide and water. a)Write a balanced chemical equation for the decomposition of sodium bicarbonate on heating.

0)If 8.4 g of sodium bicarbonate decomposes, calculate i)The volume of carbon dioxide gas evolved at room temperature.

0)The mass of sodium carbonate formed.

Chemistry Perfect Score Module Form 4 2010 Set 1

Set 1

Structure of the atoms & Chemical Equation Perfect Score F4 2010

Concentration of acids and alkalis (STOICHEIOMETRY) The concentration of a solution is the mass (in gram) or the number of mole of solute dissolved in a solvent to form 1.00 dm3 of solution. Concentration, g dm-3 Concentration, mol dm-3 / molarity Mass of solute, g Volume of solution , dm3 Number of mole of solute, mol Volume of solution , dm3

Ma Va a

= Concentration of the acid, Mb = Volume of used acid, Vb Formula MaV2 = a = the number of mole of acid, M b V bb b

Titration

= Concentration of the alkali = Volume of used alkali = the number of mole of alkali

Dilution M1V1 = M2V2

13. 100cm3 of HCl 2.0 mol dm-3 reacts completely with excessive zinc powder. Calculate the volume of gas released at room temperature? (Molar volume = 24 dm3 at room temperature).

0.

5 g of Calcium carbonates dissolves in 100 cm3 of nitric acid 0.5 mol dm-3 to produce salt, carbon dioxide gas and water. (i) Write out the equation. ii)Calculate the moles of calcium carbonates used. (RAM Ca =40, C = 12, O = 16).

iii)Calculate the moles of acid.

iv)Calculate the volume of gas produced.

15
Chemistry Perfect Score Module Form 4 2010 Set 1

Set 1

Structure of the atoms & Chemical Equation Perfect Score F4 2010

15. X g sodium carbonate reacts completely with 100 cm3 hydrochloric acid 1.0 moldm-3 to produce sodium chloride, carbon dioxide and water. Find X. (relative atomic mass: Na =23, C = 12, O = 16)

16.

10 g of copper(II) oxide reacts completely with 100 cm3 hydrochloric acid to form copper(II) chloride and water. Calculate the molarity of acid used. (JAR Cu =64, O = 16 )

17. The concentration of sodium hydroxide solution is 8.0 g dm-3. a) What is the molarity of the solution?

b) What is the molarity of the solution produced when 100 cm3 of distilled water is added to 50 cm3 of this solution?

18.

In the titration experiment, 25.0 cm3 of 2.0 mol dm-3 sodium hydroxide solution is titrated with sulphuric acid from a burette. 18.50 cm3 of sulphuric acid is needed for complete neutralization. (a) Write a balanced chemical equation for the neutralization. b) Calculate the number of mole of sodium hydroxide used in this experiment.

c) Calculate the number of moles of sulfphuric acid needed to exactly neutralize 25.0 cm3 of 2.0 mol dmsodium hydroxide.
3

d) Calculate the molarity of sulphuric acid.

19. 1.25 mol dm-3 hydrochloric acid reacts completely with 25.0 cm3 of 1.0 mol dm-3 sodium carbonate. (a) Write a balanced chemical equation for this reaction.

b) Calculate the number of mole of sodium carbonate used in this experiment. c) Calculate the volume of hydrochloric acid needed to exactly neutralize 25.0 cm3 of 1.0 mol dm-3 sodium carbonate.
Chemistry Perfect Score Module Form 4 2010 Set 1

16

Dry hydrogen gas

Set 1 PAPER 2: STRUCTURE 1. Diagram 1 shows the set-up of the apparatus for an experiment to determine the empirical formula of an oxide of copper. Structure of the atoms & Chemical Equation Perfect Score F4 2010

Oxide of copper

Heat Diagram 1
Table 1 shows the results of an experiment after heating, cooling and weighing are repeated until a constant weight is obtained. Substance Mass of combustion tube + porcelain dish Mass of combustion tube + porcelain dish + oxide of copper Mass of combustion tube + porcelain dish + copper Mass(g) 18.75 20.75 g 20.35 g g

Table 1
(a) What is meant by empirical formula? [1 mark] (b) Based on Table 5 results, (i) Calculate the mass of copper and the mass of oxygen used in the experiment.
Chemistry Perfect Score Module Form 4 2010 Set 1

[2 marks] (ii) Calculate the mole ratio of copper atoms to oxygen atoms. Given that the relative atomic mass of Cu, 64; O ,16.

[2 marks] (iii) State the empirical formula of this oxide of copper. [1 mark] (iv) Write the chemical equation for the reaction in this experiment. [1 mark]

17

Set 1 (c)

Structure of the atoms & Chemical Equation Perfect Score F4 2010 Describe the steps that should be taken to ensure that all the air in the combustion tube has been expelled , before any heating is carried out.

[3 marks] 2. (a) Culculate the relative molecular or formula masses of the following substances. i)Ethanol, C2H5OH. Given that relative atomic mass of H = 1, C = 12, O = 16. [1 mark] 0)Zinc nitrate, Zn(NO3)2 Given that relative atomic mass of O = 16 , N = 14, Zn = 65 .

[1 mark] (b) A closed glass bottle contains 4 mol molecules of oxygen, O2. i)What is the number of oxygen molecules in the bottle?

[1 mark] ii)How many oxygen atoms are there in the bottle? [1 mark] (c) Find the number of moles of atoms in a sample containing 9.03 1020 atoms of copper. [1 mark] (d) Calculate the mass, in gram, of 3.5 moles of copper(II) carbonate, CuCO3. Given that relative formula mass of CuCO3 = 124

[1 mark] (e) When silver carbonate, Ag2CO3 is heated, it will decompose to produce silver metal, carbon dioxide gas and oxygen gas as shown in the equation below. 2Ag 2 CO 3 (s) - * 4Ag(s) + Form 4 2010 (g) Chemistry Perfect Score Module 2CO 2 (g) + O 2Set 1

18

mistry Perfect Score Module Form 4 2010 Set 1

Set 1

Structure of the atoms & Chemical Equation Perfect Score F4 2010 A student heats 8.28 g silver carbonate. Calculate the volume of carbon dioxide gas, CO2 collected at room temperature. Given that relative atomic mass of C = 12, O =16, Ag = 108,

[3 marks] 3. Diagram 3 shows 3.1 g of copper (II) carbonate being heated strongly in attest tube. The gas given out is passed into limewater in a test tube through a delivery tube. (a) State the observation made when copper(II)carbonate powder is heated until the reaction is complete. [1 mark] (b) Write the chemical equation to represent the reaction that takes place. Heat

Copper(II) carbonate

strongly Lime water

(c) Calculate the number of moles of copper(II)oxide produced. [1 mark]

Diagram 3

[2 marks] (d) Calculate the volume of gas produced at STP.

[2 marks] (e) (i) What can be observed if the product is heated in a stream of hydrogen gas? [1 mark] (ii) Calculate the mass of the substance produced.

[2 marks]

19

mistry Perfect Score Module Form 4 2010 Set 1

Set 1 PAPER 2 : ESSAY 4.

Structure of the atoms & Chemical Equation Perfect Score F4 2010

( (a) The information below is regarding substance X C Carbon 85.70% H Hydrogen 14.30% Relative molecular mass = 56

i) ii) 0)

Determine the empirical formula of substance X. [Given that the relative atomic mass of C = 12 , H = 1] Determine the molecular formula of substance X. Based on the answers in (a)(i) and (a)(ii) , compare and contrast the empirical formula and the molecular formula. [ 8 marks]

(b)

Magnesium can react actively with oxygen to form magnesium oxide. Describe an activity that can be carried out in the laboratory to determine the empirical formula of magnesium oxide. Include the calculations involved in your answer. Given that the relative atomic mass for O = 16, Mg = 24. [11 marks]

20

Set 1 PAPER 3 : STRUCTURE 5.

Structure of the atoms & Chemical Equation Perfect Score F4 2010

21

A student carried out an experiment to determine the empirical formula of magnesium oxide. The steps and set-up of apparatus of the experiment are shown in Diagram 5. 1.The crucible and lid are weighed.
lid crucible

123.3632g

digital balance

2.The crucible, lid and magnesium powder are weighed.

Magnesium powder

128.1580g

0.The magnesium powder is heated until it reacts completely with oxygen.

white fumes

heat

3.The crucible, lid and magnesium oxide are weighed when cooled.

magnesium oxide powder

131.3580g

Diagram 5
Chemistry Perfect Score Module Form 4 2010 Set 1

Set 1

Structure of the atoms & Chemical Equation Perfect Score F4 2010 (a) Complete the following table by stating the observations and related inferences in the experiment. Observations (i) ............................................. Inferences (i) .............................................................

(ii) ............................................

ii)

iii))

(iii)

[6 marks] (b) Round off the reading to two decimal places and record it in the table below. Description The crucible and lid. The crucible, lid and magnesium powder. The crucible, lid and magenesium oxide. Mass / g

(c) (i) ii) 0)

Calculate the mass of magnesium that has been used. Calculate the mass of oxygen which reacted with magnesium. Determine the empirical formula of magnesium oxide. Use the information that the relative atomic mass, O = 16, Mg = 24

(d)

The student wants to determine the empirical formula of lead(II) oxide. He used the steps and set-up of apparatus as the experiment before. Predict whether the empirical formula of lead(II) oxide can be determined. Explain your answer.

22
Chemistry Perfect Score Module Form 4 2010 Set 1