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3 KINETICS REVISION
1.
(a)
A fixed mass of marble is reacted with dilute hydrochloric acid at a constant temperature.
Explain why the rate of the reaction is increased if the lumps of marble are reduced in size.
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(2)
(b)
The initial rate of the reaction between substances A and B was measured in a series of
experiments and the following rate equation was deduced.
rate = k[A][B]
(i)
Complete the table of data below for the reaction between A and B.
Expt
Initial [A]
3
/mol dm
Initial [B]
3
/mol dm
0.020
0.020
0.040
0.040
(ii)
0.040
0.060
0.040
Initial rate
3 1
/mol dm s
4
1.210
2.410
0.030
4
7.210
Using the data for Experiment 1, calculate a value for the rate constant, k and state
its units.
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(7)
(Total 9 marks)
2.
The hydrolysis of methyl propanoate was studied in acidic conditions at 25C and the rate
equation was found to be
rate = k[CH3CH2COOCH3][H+]
(a)
Use the data below to calculate the value of the rate constant, k, at this temperature.
Deduce its units.
Initial rate of reaction /
3 1
mol dm s
4
1.15 10
Initial concentration of
3
hydrochloric acid / mol dm
0.150
0.555
(b)
The reaction in part (a) was repeated at the same temperature, but water was added so that
the volume of the reaction mixture was doubled. Calculate the initial rate of reaction under
these conditions.
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.............................................................................................................................................
(1)
(Total 4 marks)
3.
(a)
The following table shows the results of three experiments carried out at the same
temperature to investigate the rate of the reaction between compounds P and Q.
Experiment 1
Experiment 2
Experiment 3
0.50
0.25
0.25
0.36
0.36
0.72
7.6 10
Initial rate/mol dm s
1.9 10
3.8 10
Use the data in the table to deduce the order with respect to P and the order with respect
to Q.
Order with respect to P ..............................................................................................
Order with respect to Q ..............................................................................................
(2)
(b)
In a reaction between R and S, the order of reaction with respect to R is one, the order
of reaction with respect to S is two and the rate constant at temperature T1 has a value of
4
6 1
4.2 10 mol dm s .
(i)
Write a rate equation for the reaction. Calculate a value for the initial rate of reaction
3
when the initial concentration of R is 0.16 mol dm and that of S is
3
0.84 mol dm .
Rate equation ...............................................................................................
Calculation .......................................................................................................
.......................................................................................................................
(ii)
3 1
4.
(a)
The initial rate of the reaction between compounds A and B was measured in a series of
experiments at a fixed temperature. The following rate equation was deduced.
rate = k[A][B]
(i)
Complete the table of data below for the reaction between A and B.
Expt
Initial [A]
3
/mol dm
6.60 10
3.30 10
4.80 10
4.80 10
Initial [B]
3
/mol dm
13.2 10
2
1.60 10
Initial rate
3 1
/mol dm s
3
10.4 10
2
2
(ii)
5.20 10
10.4 10
Using the data for experiment 1, calculate a value for the rate constant, k, and state
its units.
Calculation ....
............
Units ..
(6)
(b)
State how the value of the rate constant, k, would change, if at all, if the concentration of A
were increased in a series of experiments.
......................
(1)
(Total 7 marks)
5.
rate = k [CH3COCH3][H ]
(a)
Deduce the order of reaction with respect to iodine and the overall order of reaction.
Order with respect to iodine ...................................................................................
Overall order .........................................................................................................
(2)
(b)
Concentration / mol dm
1.50
2
2.00 10
3.00 10
Use these data to calculate a value for the rate constant and deduce its units.
Rate constant .........................................................................................................
................................................................................................................................
................................................................................................................................
Units .......................................................................................................................
(3)
(c)
6.
The reaction between hydrogen and iodine can be represented by the following equation:
H2(g) + I2(g)
2HI(g)
H = +52 kJ mol
Kinetic data are available for both forward and reverse reactions. A series of experiments to
investigate the kinetics of the forward reaction was carried out at a constant temperature. The
results are shown in Figure 1.
Experiment
Initial concentration
3
of H2 / mol dm
Initial concentration
3
of I2 / mol dm
3.0 10
3.0 10
6.0 10
2.0 10
6.0 10
6.0 10
Initial rate
3 1
/ mol dm s
l.2 10
3.6 10
7.2 10
6
6
Figure 1
(a)
rate of reaction;
(1)
(ii)
rate constant;
(1)
(iii)
(b)
(i)
Use the results in Figure 1 to work out the order of the forward reaction with respect
to both hydrogen and iodine, explaining your reasoning.
(4)
(ii)
Write the rate equation for the reaction between hydrogen and iodine.
(1)
(iii)
Calculate the value of the rate constant for the forward reaction and give its units.
(3)
(c)
The experiment was repeated with the following initial concentrations for reactants:
3
7.
The second-order rate constant for the reaction of 1-bromopropane with aqueous hydroxide ions was
measured as a function of temperature.
CH3CH2CH2Br(aq) + OH-(aq) CH3CH2CH2OH(aq) + Br-(aq)
The results are shown in the table below.
Temperature/K
1/T/K-1
k/ mol-1dm s
298
0.00336
l.4 10
Temperature/
C
25
3 1
lnk
-8.9
35
3.0 10
45
6.8 10
55
l.4 10
(a) Complete the table above (the first row is done for you)
(b) Plot a graph of lnk against 1/T. Measure the slope (gradient) of the line and hence calculate the
activation energy of the reaction (give your answer to 3 sig figs).
8.
The activation energy of the oxidation of iodide ions by iodate (V) ions can be found by experiment:
The equation for the reaction is:
IO3-(aq) + 5I-(aq) + 6H-(aq) 3I2(aq) + 3H2O(l)
The iodine produced then reacts with the sodium thiosulfate:
I2(aq) + 2S2O32-(aq) 2I-(aq) + S4O62-(aq)
When all the sodium thiosulfate has been used up, the next iodine that is produced forms an intense
blue colour with the starch. The time was recorded when the solution turned intense blue, the
experiments repeated with the same volumes of solutions but at a higher temperature. The results are
shown in the table below:
Time/s
1/time/s-1
ln (1/time)
Temperature/C
135
25
46
40
14
60
Temperature/K
1/Temperature/K-1
line and evaluate the activation energy. (You may assume that the gradient of this line is the
same as that of lnk against 1/T and that its value is Ea/R.
(a)
(b)
(i)
Experiment 2 = 9 6 10
(1)
Experiment 4 = 8 1 10
(1)
k=
1.2 10 4
( 0 020)( 0 020)
6 1
7
[9]
2.
(a)
k = rate/[CH3CH2COOCH3][H ] or
=
1 15 10 4
(0.150)(0.555)
= 1.38 10 to 1.4 10
1
(b)
3 1
mol dm s
3.
(a)
(b)
(i)
rate = k[R][S]
(if wrong expression, no further marks)
4
2
rate = (4.2 10 ) 0.16 0.84
5
3 1
= 4.7 10 (mol dm s )
ignore units even if wrong
(ii)
k=
rate
8.110 5
=
[ R ][S] 2 0.76 0.982
4
= 1.1 10
(iii)
1
1
1
1
1
1
T1
1
4
[8]
4.
(a)
(i)
Experiment 2
Experiment 3
Experiment 4
(ii)
k=
2.60 10
2
0.60 10
2
11.4 10
1
1
1
10.4 10 3
(4.80 10 2 )(6.60 10 2 ) 2
= 49.7
(Allow 49.8 and 50)
2
6 1
mol dm s
(b)
No change
1
[7]
5.
(a)
(b)
Rate constant: k =
1
2 10 5
4
= 4.4(4) 10 (1)
2
(1.5) (3 10 )
3 1
(c)
2
[7]
6.
(a)
(i)
(ii)
(iii)
(i)
sum of
nd
dependent on 2 mark or reference to orders (1)
powers in rate equation (1)
allow reference to annotated rate equation
(b)
(H2) 1 (1)
eg rate trebles as [H2] trebles not rate doubles as [H2] doubles (1)
10
(I2) 1 (1)
eg rate doubles as [I2] doubles (1)
mark these points independently
allow 1 mark for orders if not clear that both are first order
(ii)
(iii)
3 1
4 10 (1)
allow e.c.f. from (b)(ii) and (b)(iii)
could be worked by ratio from values in table or from rate equation
1
[13]
7.
Temperature/
C
Temperature/K
1/T/K-1
k/ mol-1dm s
25
298
0.00336
l.4 10
35
308
0.00325
3.0 10
45
318
0.00314
6.8 10
55
328
0.00306
l.4 10
3 1
lnk
-8.9
-8.1
-7.3
-6.6
11
8.
Time/s
1/time/s-1
ln (1/time)
Temperature/C
Temperature/K
1/temperature/K-1
135
0.0074
-4.9
25
298
0.00336
46
0.0217
-3.8
40
313
0.00319
14
0.0714
-2.6
60
333
0.00300
12