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.

IT

IS MY DUTY TO RECORD MY SINCERE THANKS AND DEEP MY RESPECTED TEACHER Mrs. AND OF

SENSE OF GRATITUDE TO SEEMA SINGHAL FOR CONSTANT THIS HER

VALUABLE

GUIDANCE , INTEREST FULFILLMENT

ENCOURAGEMENT

FOR THE

PROJECT .

I AM -OVIDED

ALSO ME

HIGHLY THE

OBLIGED TO MR. MATTER

WHO

PR-

REQUIRE.D

THIS IS TO CERTIFY THAT HITESH KUMAR

OF CLASS XII S HAS WORKED UNDER MY SUPER-

-VISION

ON

THE PROJECT STUDY

OF

MINERAL

CONTENT IN INDIAN COINS AND COMPETED TO

MY TOTAL SATISFACTION

WITHIN STIPULATED TIME

AND THUS FILLING THE EXPECTATIONS OF CBSE

EXAMINATIONS .

Small beakers , glass rods , test tubes ,test tube stand , burner ,etc.

Water , dilute hydrochloric acid , Sulphuric acid ,nitric acid, ammonium Chloride , ammonium hydroxide , blue litmus solution ,DMG.

VALUE OF COIN SHAPE OF COIN

: :

1 PAISA SQUARE SILVER

COLOUR OF COIN :

PRELIMENARY TEST : EXPERIMENT


Original solution +dil. HCL

OBSERVATIONS
No precipitate is formed

INFERENCE
Group 1(Pb) is absent

HS gas is passed To avoid conc. HNO. Boil to excess add NHCl and NHOH Filterate +NHCl +NHOH + HS and divide into two parts .

No precipitate is formed White gelatinous ppt. is formed

Group 2(Cu) is absent May be due to the presence Of Al

Dirty white ppt. is

formed

May be due to of (Zn)

presence

CONFIRMATORY TEST : EXPERIMENT


Dissolve the white gelatinous ppt. in dil. HCL + blue litmus solution + excess of NHOH drop wise . To one of the divided part of the dirty white ppt. add K{Fe(Cn)} Bluish White ppt. is formed Presence of confirmed Znis

OBSERVATION
Blue lake formed colour is

INFERENCE
Presence of Al is confirmed

RESULT : 1 Paisa Indian coin contains Al ad Zn metals.

VALUE OF COIN SHAPE OF COIN

: :

3 PAISA HEXAGON SILVER

COLOUR OF COIN :

PRELIMENARY TEST : EXPERIMENT


Original solution +dil. HCL

OBSERVATIONS
No precipitate is formed

INFERENCE
Group 1(Pb) is absent

HS gas is passed To avoid conc. HNO. Boil to excess add NHCl and NHOH Filterate +NHCl +NHOH + HS and divide into two parts .

No precipitate is formed White gelatinous ppt. is formed

Group 2(Cu) is absent May be due to the presence Of Al

Dirty white ppt. is

formed

May be due to of (Zn)

presence

CONFIRMATORY TEST : EXPERIMENT


Dissolve the white gelatinous ppt. in dil. HCL + blue litmus solution + excess of NHOH drop wise . To one of the divided part of the dirty white ppt. add K{Fe(Cn)} Bluish White ppt. is formed Presence of confirmed Znis

OBSERVATION
Blue lake formed colour is

INFERENCE
Presence of Al is confirmed

RESULT : 3 Paisa Indian coin contains Al ad Zn metals.

VALUE OF COIN SHAPE OF COIN

: :

5 PAISA SQUARE SILVER

COLOUR OF COIN :

PRELIMENARY TEST : EXPERIMENT


Original solution +dil. HCL HS gas is passed

OBSERVATIONS
No precipitate is formed No precipitate is formed

INFERENCE
Group 1(Pb) is absent

Group 2(Cu) is absent

To avoid conc. HNO. Boil to excess add NHCl and NHOH Filterate +NHCl +NHOH + HS and divide into two parts .

White gelatinous ppt. is formed

May be due to the presence Of Al May be due to presence of (Zn)

Dirty white ppt. is formed

CONFIRMATORY TEST : EXPERIMENT


Dissolve the white gelatinous ppt. in dil. HCL + blue litmus solution + excess of NHOH drop wise . To one of the divided part of the dirty white ppt. add K{Fe(CN)}

OBSERVATION
Blue lake colour is formed

INFERENCE
Presence of Al is confirmed

Bluish White ppt. is formed

Presence of Znis confirmed

RESULT : 5 Paisa Indian coin contains Al and Zn metals.

VALUE OF COIN SHAPE OF COIN

: :

10 PAISA CIRCLE SILVER

COLOUR OF COIN :

PRELIMENARY TEST : EXPERIMENT


Original solution +dil. HCL

OBSERVATIONS
No precipitate is formed

INFERENCE
Group 1(Pb) is absent

HS gas is passed To avoid conc. HNO. Boil to excess add NHCl and NHOH Filterate +NHCl +NHOH + HS and divide into two parts .

No precipitate is formed White gelatinous ppt. is formed

Group 2(Cu) is absent May be due to the presence Of Al

Dirty white ppt. is

formed

May be due to of (Zn)

presence

CONFIRMATORY TEST : EXPERIMENT


Dissolve the white gelatinous ppt. in dil. HCL + blue litmus solution + excess of NHOH drop wise . To one of the divided part of the dirty white ppt. add K{Fe(Cn)} Bluish White ppt. is formed Presence of confirmed Znis

OBSERVATION
Blue lake formed colour is

INFERENCE
Presence of Al is confirmed

RESULT :

10 Paisa Indian coin contains Al ad Zn metals.

VALUE OF COIN SHAPE OF COIN

: :

25 PAISA CIRCLE SILVER

COLOUR OF COIN :

PRELIMENARY TEST : EXPERIMENT


Original solution +dil. HCL HS gas is passed

OBSERVATIONS
No precipitate is formed No precipitate is formed

INFERENCE
Group 1(Pb) is absent

Group 2(Cu) is absent

To avoid conc. HNO. Boil to excess add NHCl and NHOH Filterate +NHCl +NHOH + HS and divide into two parts .

White gelatinous ppt. is formed

May be due to the presence Of Al May be due to presence of (Zn)

Dirty white ppt. is formed

CONFIRMATORY TEST : EXPERIMENT


Dissolve the white gelatinous ppt. in dil. HCL + blue litmus solution + excess of NHOH drop wise . To one of the divided part of the dirty white ppt. add K{Fe(Cn)}

OBSERVATION
Blue lake colour is formed

INFERENCE
Presence of Al is confirmed

Bluish White ppt. is formed

Presence of Znis confirmed

RESULT : 25 Paisa Indian coin contains Al ad Zn metals.

VALUE OF COIN SHAPE OF COIN

: :

50 PAISA circle SILVER

COLOUR OF COIN :

PRELIMENARY TEST : EXPERIMENT


Original solution +dil. HCL HS gas is passed

OBSERVATIONS
No precipitate is formed No precipitate is formed

INFERENCE
Group 1(Pb) is absent

Group 2(Cu) is absent

To avoid conc. HNO. Boil to excess add NHCl and NHOH Filterate +NHCl +NHOH + HS and divide into two parts .

White gelatinous ppt. is formed

May be due to the presence Of Al May be due to presence of (Zn)

Dirty white ppt. is formed

CONFIRMATORY TEST : EXPERIMENT


Dissolve the white gelatinous ppt. in dil. HCL + blue litmus solution + excess of NHOH drop wise . To one of the divided part of the dirty white ppt. add K{Fe(Cn)}

OBSERVATION
Blue lake colour is formed

INFERENCE
Presence of Al is confirmed

Bluish White ppt. is formed

Presence of Znis confirmed

RESULT : 50 Paisa Indian coin contains Al ad Zn metals.

VALUE OF COIN SHAPE OF COIN

: :

1 RUPEE ROUND SILVER

COLOUR OF COIN :

PRELIMINARY TEST : EXPERIMENT


Original solution +dil. HCL

OBSERVATION
No precipitate is formed

INFERENCE
Group 1 ( Pb) is formed

HS gas is passed

Black precipitate is formed

May be due to presence of Cu May be due to the presence of (Fe)

Filter the sol. + heat + conc. HNO + Boil (2-3 min) + NHCL Then add excess NHOH

Reddish brown ppt. is formed

CONFIRMATORY TEST : EXPERIMENT


Dissolve the black ppt. in conc. HNO To the above formed bluish green sol. Add acetic acid and add K{Fe(CN)}

OBSERVATION
Bluish green sol. Is formed

INFERENCE
Presence of (Cu)is confirmed

A chocolate brown ppt. is formed

Presence of (Cu) is confirmed

Boil reddish brown ppt. and add conc. HNO+ NHCl then add excess NHOH Residue +dil. HCl + KCNS

A brown ppt. formed

Presence of (Fe) is confirmed

Blood red colour is formed

Presence of (Fe) is confirmed

RESULT : 1 rupee Indian coin contains Fe and Cu metals.

VALUE OF COIN SHAPE OF COIN

: :

2 RUPEE ROUND SILVER

COLOUR OF COIN :

PRELIMINARY TEST : EXPERIMENT


HS gas is passed

OBSERVATION
Black precipitate is formed

INFERENCE
May be due to presence of Cu May be due to the presence of (Fe)

Filter the sol. + heat + conc. HNO + Boil (2-3 min) + NHCL Then add excess NHOH

Reddish brown ppt. is formed

Original solution +dil. HCL HS Yellow residue is formed gas is passed

May be due to the presence of (Ni)

CONFIRMATORY TEST : EXPERIMENT


Add excess of NHOH to the formed black ppt. Residue +dil. HCl + KCNS

OBSERVATION
Blue colour ppt. is formed

INFERENCE
Presence of ( Cu) confirmed

Blood red colour is formed

Presence of (Fe) is confirmed Ni is confirmed

Dissolve the ppt. in aquaregia And then add DMG and NHOH

A bright red ppt. is confirmed

RESULT : 2 Rupee Indian coin contains Cu ,Fe and Ni metals .

VALUE OF COIN SHAPE OF COIN

: :

5 RUPEE ROUND SILVER

COLOUR OF COIN :

PRELIMINARY TEST : EXPERIMENT


Original solution +dil. HCL

OBSERVATION
No precipitate is formed

INFERENCE
Group 1 ( Pb) is absent

HS gas is passed

No precipitate is formed

Group II ( Cu )is absent

To avoid conc. HNO. Boil to excess add NHCl and NHOH To the above pass Hs

White gelatinous ppt. is formed Yellow residue is formed

May be due to the presence Of Al May be due to the presence of (Ni) May be due to presence of (Zn)

Filterate +NHCl +NHOH + HS and divide into two parts .

Dirty white ppt. is formed

CONFIRMATORY TEST : EXPERIMENT


Dissolve the white gelatinous ppt. in dil. HCL + blue litmus solution + excess of NHOH drop wise . Add NHOH to the yellow residue and DMG To one of the divided part of the dirty white ppt. add K{Fe(Cn)}

OBSERVATION
Blue lake colour is formed

INFERENCE
Presence of Al is confirmed

A bright red rose ppt. is formed Bluish White ppt. is formed

Presence of (Ni )is formed

Presence of Znis confirmed

RESULT : 5 rupee Indian coin contains Al ,Ni , and Zn metals .

VALUE OF COIN SHAPE OF COIN

: :

10 RUPEE ROUND SILVER AND GOLD

COLOUR OF COIN :

PRELIMINARY TEST : EXPERIMENT


HS gas is passed

OBSERVATION
Black precipitate is formed

INFERENCE
May be due to presence of Cu May be due to presence of (Zn) May be due to the presence of (Fe)

Filterate +NHCl +NHOH + HS and divide into two parts . Filter the sol. + heat + conc. HNO + Boil (2-3 min) + NHCL Then add excess NHOH

Dirty white ppt. is formed

Reddish brown ppt. is formed

Original solution +dil. HCL HS Yellow residue is formed gas is passed

May be due to the presence of (Ni)

CONFIRMATORY TEST : EXPERIMENT


Add excess of NHOH to the formed black ppt. To one of the divided part of the dirty white ppt. add K{Fe(Cn)} Residue +dil. HCl + KCNS

OBSERVATION
Blue colour ppt. is formed

INFERENCE
Presence of ( Cu) confirmed

Bluish White ppt. is formed

Presence of Znis confirmed

Blood red colour is formed

Presence of (Fe) is confirmed Ni is confirmed

Dissolve the ppt. in aquaregia And then add DMG and NHOH

A bright red ppt. is confirmed

RESULT : 10 Rupee Indian coin contains Cu ,Zn , Fe , and Ni metals .

BIBLIOGRAPHY
COMPREHENSIVE PRACTICAL CHEMISTRY ARYA PRACTICAL CHEMISTRY ANALYTICAL CHEMISTRY O.P AGGARWAL

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