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TABLE OF CONTENT
Procedure ......................................................... Error! Bookmark not defined. Process Flow Diagram ..................................... Error! Bookmark not defined.8 Theory .9 QUESTION12 DISCUSSION...17
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2. Then, the components for this laboratory is added in the component list view which are ammonia and water
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5. After clicking the enter simulation environment, the simulation window will come out as below
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7. The composition option from the list is selected to display the window in figure 1.12. The ammonia section is completed by entering value of 0.8 to indicate 0.8 mole fraction of ammonia and value of 0.2 in the water section to indicate 0.2 mole fraction of water.
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9. The Parameters option is selected. At the Parameters page, the Duty section is completed by entering the value of 5.8 x 106 Btu/hr.
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11. Then, a valve was added to the system to reduce the pressure from 250psia to 150psia
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13. It was adjusted that the vapor product of this process produce at the top of the separator and liquid at the bottom of the separator
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Where: = Partial pressure of a particular component A, B, C = coefficient value of Antoine equation constant T = temperature Raoults Law For liquid phase
Where: = total pressure of mixture x = liquid fraction of component y = vapour fraction of component
There are assumptions made to this process to make the calculation easier. The assumptions are: 1. Steady state. So, accumulation equal to zero 2. Nonreactive species. So, generation and consumption equal to zero
x 100%
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3. What are the mole fraction for ammonia and water in the vapor and liquid outlet of the separator? Vapor phase Ammonia= 0.9990 Water= 0.0010 Liquid phase Ammonia= 0.7146 Water= 0.2854
4. Determine the mass flow rate for each outlet stream of the separator Mass flow rate at vapor stream is 1487kg/h Mass flow rate at liquid stream is 3049kg/h
5. Use a manual calculation on mass and energy balance to determine the composition of the liquid stream leaving the separator.
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F4 YNH3 YH2O
F2 Valve
F3
F5 XNH3 XH2O
ANTOINE CONSTANT NH3 H2O A 7.55466 8.10765 B 1002.711 1750.286 C 247.855 235
From Antoine equation Log10 Pi = A For NH3 Log10 PNH3 = 7.55466 = 12001.6mmHg x = 1600kPa For NH3 Log10 PH2O = 8.10765 = 57.31 mmHg x = 7.64kPa
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For both stream, the total pressure is 1034kPa By applying Raoults law for both liquid and vapor phase Composition at outlet vapor stream = = [ = + + + ] x [1600] x [7.64] where YH2O = 1 YNH3
11.822 = 7.64YNH3 + (1 - YNH3)(1600) 11.822 = 7.64 YNH3 + 1600 - 1600 YNH3 1592.36 YNH3 = 1588.178 YNH3 = 0.9974 = = 0.16% YH2O = 1 0.9974 YH2O = 0.0026 Error (%) = = 61.5% x 100% x 100%
Error (%)
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Error (%)
Overall balance F1 = F4 + F5 F4 = 10000 F5 Component balance NH3 balance 0.8(10000) = 0.9974F4 + 0.6446F5
8000 = (10000 F5)(0.9974) + 0.6446F5 8000 = 9974 -0.9974F5 + 0.6446F5 0.3528F5 = 1974 F5 = 5595.24 x
= 2357.96kg/h
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