0 valutazioniIl 0% ha trovato utile questo documento (0 voti)
30 visualizzazioni7 pagine
The negative effects of high-volume FA on the mechanicaland durability-related properties of ECC may be remedied with the binary use of FA and metakaolin (mk) MK is a silica-based product that, on reaction with ca(OH) 2, produces CSH gel at ambient temperatures. Mk also contains alumina that reacts with CH to produce additional alumina-containing phases, including c 4 AH 13, c 2 ash 8.
Descrizione originale:
Titolo originale
Karahan_2012_Investigation of Properties of Engineered Cementitious
The negative effects of high-volume FA on the mechanicaland durability-related properties of ECC may be remedied with the binary use of FA and metakaolin (mk) MK is a silica-based product that, on reaction with ca(OH) 2, produces CSH gel at ambient temperatures. Mk also contains alumina that reacts with CH to produce additional alumina-containing phases, including c 4 AH 13, c 2 ash 8.
Copyright:
Attribution Non-Commercial (BY-NC)
Formati disponibili
Scarica in formato PDF, TXT o leggi online su Scribd
The negative effects of high-volume FA on the mechanicaland durability-related properties of ECC may be remedied with the binary use of FA and metakaolin (mk) MK is a silica-based product that, on reaction with ca(OH) 2, produces CSH gel at ambient temperatures. Mk also contains alumina that reacts with CH to produce additional alumina-containing phases, including c 4 AH 13, c 2 ash 8.
Copyright:
Attribution Non-Commercial (BY-NC)
Formati disponibili
Scarica in formato PDF, TXT o leggi online su Scribd
AC MATERALS JOURNAL TECHNCAL PAPER ACI Materials Journal, V. 109, No. 5, September-October 2012. MS No. M-2011-234.R1 received November 17, 2011, and reviewed under Institute publication policies. Copyright 2012, American Concrete Institute. All rights reserved, including the making of copies unless permission is obtained from the copyright proprietors. Pertinent discussion including author`s closure, if any, will be published in the July-August 2013 ACI Materials Journal if the discussion is received by April 1, 2013. Investigation of Properties of Engineered Cementitious Composites Incorporating High VoIumes of FIy Ash and MetakaoIin by E. zbay, O. Karahan, M. Lachemi, K. M. A. Hossain, and C. Duran Atis negative effects of higher cement content in ECC produc- tion, Yang et al. 11 ash (FA) (up to 85% by weight) and concluded that both the crack width and free drying shrinkage were reduced with increased FA content. Increasing the FA/PC ratio up to 5.6 decreased compressive strength (from 52.6 to 21.4 MPa [7.63 to 3.10 ksi]) and tensile strength (from 5.7 to 3.5 MPa [0.83 to 0.51 ksi]) and increased chloride-ion permea- bility 12 drastically while reducing drying shrinkage to approximately 1000 10 -6 . However, these negative effects of high-volume FA on the mechanical- and durability-related properties of ECC may be remedied with the binary use of FA and metakaolin (MK). - ation of a kaolin precursor by way of heating it to 650 to 900C (1202 to 1652F). 13,14 MK is a silica-based product that, on reaction with Ca(OH) 2 , produces CSH gel at ambient temperatures. MK also contains alumina that reacts with CH to produce additional alumina-containing phases, including C 4 AH 13 , C 2 ASH 8 , and C 3 AH 6 . This pozzolanic material has been extensively investigated, particularly in relation to its effects on the durability and other properties of portland cement (PC) composites. 15,16 Previous research has shown that the inclusion of MK in concrete remarkably improves early-age mechanical properties and enhances resistance to alkali-silica reaction, 17 sulfate attack, 18 and chloride-ion permeability. 19 Introducing high-reactivity MK into concrete also ameliorates the energy absorption or toughness of high- 20 Therefore, for applications where both enhanced durability and high toughness are required, the use of high-reactivity cementi- tious composites containing MK may be advantageous. 13,20 This study investigated the binary uses of FA and MK in the production of ECC. ECC mixtures with two different FA + MK-PC ((FA + MK)/PC) ratios (1.2 and 2.2 by weight) were prepared by keeping the FA/MK ratio at 4.5. The investigation focused on the experimental characterization water absorption (WA), water porosity (WP), sorptivity, and chloride-ion permeability of ECC incorporating FA and MK. Two types of ECC mixtures-standard (FA/PC = 1.2) This study was carried out to develop engineered cementitious composites (ECCs) incorporating binary blends of high volumes low drying shrinkage and high composite strength with adequate ductility and improved durability. ECC, an ultra-ductile cement- strain-hardening and multiple-cracking behavior in uniaxial tension and bending. Standard (M45) and high-volume FA ECC mixtures are typically produced by replacing portland cement (PC) with 55% and 70% of FA, respectively (FA-to-cement ratio of 1.2 and 2.2 by weight). In this study, the (FA MK)/PC ratio was maintained at 1.2 and 2.2 and the FA/MK ratio was maintained at 4.5. Two replacement levels of MK with FA were adopted. The investigation used 10% and 12.5% MK by weight of total binder content, respectively. For the purposes of comparison, standard and high-volume FA ECCs were also studied. To determine the effect of binary blends of FA and MK on the properties of ECC, this and compressive strengths, porosity and water absorption (WA), sorptivity, and chloride-ion permeability. The experimental results showed that the drying shrinkage, porosity, absorption, sorp- reduced with the use of binary blends of FA and MK, while ECC's ultra-high ductility and strain-hardening properties were preserved at an adequate level. Keywords: drying shrinkage; durability; engineered cementitious composites; metakaolin. INTRODUCTION Engineered cementitious composites (ECCs) consti- - ites and are microstructurally tailored based on the micro- mechanics design theory. 1-4 Their strain-hardening and multiple-cracking behavior is characterized by a higher which is associated with the appearance of closely spaced multiple cracks until composite peak load is reached. 5 The tensile strain capacity of ECCs is 2 to 5%-several hundred times that of normal concrete. The compressive strength ranges from 50 to 80 MPa (7.25 to 11.6 ksi), depending on the composition of the mixture, which puts ECCs in the same class as high-strength concrete materials but without the associated brittleness. 6 To obtain strain-hardening and needs to be added to the matrix to control fracture tough- ness. 7-10 Coarse aggregates are eliminated from the mixture, resulting in a higher cement content than that of conven- tional concrete. As a result of this special requirement, a high-drying shrinkage strain must be developed during the setting and hardening of the composite. 7 To eliminate the 566 AC Materials Journal/September-October 2012 and high-volume FA (FA/PC = 2.2)-were also studied for comparison purposes. RESEARCH SIGNIFICANCE reinforced cementitious composite with substantial bene- its minimum crack width. To obtain strain-hardening and sand needs to be added to the matrix to control the frac- ture toughness. Coarse aggregates are eliminated from the mixture, resulting in higher cement content than conven- tional concrete. Therefore, a high drying shrinkage strain must be developed during setting and hardening of this unique composite. Researchers tried to decrease the drying shrinkage of ECC mixtures by using high volumes of FA; however, this resulted in a decrease in the mechanical and durability properties. This study focused on the binary use of FA and MK in ECC production. The negative effects of high-volume FA on the mechanical- and durability-related properties of ECC may be overcome with the binary use of FA and MK. EXPERIMENTAL PROCEDURE MateriaIs and mixture proportions included standard and high-volume FA ECC, which incorpo- rated Type I PC; Class F FA; normalweight microsilica sand (with an average and maximum grain size of 110 and 200 m [0.004 and 0.008 in.], respectively); water; polyvinyl alcohol water-reducing admixture (HRWRA) with a solid content of approximately 30%. The second group of ECC mixtures was produced by replacing FA with MK at (FA + MK)/PC ratios of 1.2 and 2.2 while maintaining a constant FA/MK ratio of 4.5. The chemical composition and physical properties of the PC, FA, and MK used in this study are presented in Table 1. ECCs can be found in Table 2. All four mixtures contained m (0.002 in.) in diameter with a tensile strength of 1600 MPa (235 ksi) and Erdogan zbay is an Associate Professor in the Civil Engineering Department at Mustafa Kemal University, Antakya, Turkey. His research interests include durability of concrete, use of waste materials in concrete, and self-consolidating concrete. Okan Karahan is an Assistant Professor in the Civil Engineering Department at Erciyes University, Kayseri, Turkey. His research interests include construction materials and concrete technology. ACI member Mohamed Lachemi is a Professor of Civil Engineering and Dean of the Faculty of Engineering and Architectural Science at Ryerson University, Toronto, ON, Canada. He is a member of ACI Committees 231, Properties of Concrete at Early Ages, and 237, Self-Consolidating Concrete. His research interests include the use of high-performance materials in the built infrastructure, including the development and use of self-consolidating concrete in construction. ACI member Khandaker M. A. Hossain is an Associate Professor in the Department of Civil Engineering at Ryerson University. He is a member of ACI Committees 213, Lightweight Aggregate and Concrete, and 232, Fly Ash and Natural Pozzolans in Concrete. His research interests include sustainable construction, high-performance/ self-consolidating concrete, reinforced concrete, and thin-walled composite structures. Cengiz Duran Atis is a Professor of Civil Engineering and Dean of the Faculty of Engineering at Abdullah Gul University, Kayseri, Turkey. His research interests include construction materials and reinforced concrete structures. TabIe 1Characteristics of cement, FA, and MK Chemical composition Cement FA MK Sum (SiO 2 + Al 2 O 3 + Fe 2 O 3 ) 27.60 85.60 95.00 SiO 2 , % 19.60 59.50 61 to 64 Al 2 O 3 , % 4.90 22.20 30 to 32 Fe 2 O 3 , % 3.10 3.90 1.10 CaO, % 61.40 5.57 0.40 MgO, % 3.00 - 0.30 SO 3 , % 3.60 0.19 0.05 Alkalis as Na 2 O, % 0.70 2.75 1.35 Loss on ignition, % 2.30 0.21 0.95 Physical properties Blaine, cm 2 /g 3870 3060 13,900 +45 m, % 3.00 9.60 1.20 Density, g/cm 3 3.15 2.18 2.55 Notes: 1 cm 2 /g = 0.155 in. 2 /g; 1 m = 0.0000393 in.; 1 g/cm 3 = 168.45 lb/yd 3 . TabIe 2Mixture properties of ECC mixtures Ingredients ECC-1_FA/PC = 1.2 ECC-2_FA/PC = 2.2 ECC-3_(FA + MK)/PC = 1.2 ECC-4_(FA + MK)/PC = 2.2 Water (W), kg/m 3 331 327 326 318 Portland cement (PC), kg/m 3 570 386 558 375 FA, kg/m 3 684 847 547 673 MK, kg/m 3 - - 122 150 Silica sand (S), kg/m 3 455 448 446 435 Fiber (PVA), kg/m 3 26 26 26 26 HRWRA, kg/m 3 4.9 3.7 7.5 6.5 FA, % 55 69 45 56 MK, % - - 10 12.5 FA/PC 1.2 2.2 0.98 1.80 FA/MK - - 4.5 4.5 (FA + MK)/PC - - 1.2 2.2 Water-cementitious material ratio (w/cm) 0.27 0.27 0.27 0.27 Note: 1 kg/m 3 = 1.6845 lb/yd 3 . AC Materials Journal/September-October 2012 567 a density of 1300 kg/m 3 (2190.5 lb/yd 3 chemical and friction bond. 21 The water-cementitious material ratio (w/cm) in all mixtures was controlled at 0.27. Slight adjustments in the amount of the HRWRA in each mixture were made to distribution and workability. Therefore, all specimens in the to those in self-consolidating performance. 11 As seen in Table 2, ECC mixtures incorporating FA and MK showed a higher HRWRA demand than those containing only FA. MK, a soft material made primarily of amorphous silicon dioxide and aluminum oxide and produced by the decom- position of kaolin at a temperature of 650 to 900C (1202 to 1652F), tends to absorb water to form kaolin. After the MK was added to the PC, it prompted cement hydration, which shortened the setting time. However, the MK-blended mixtures needed more water to achieve the same work- dosage of HRWRA was added for the same workability; the study concluded that MK-blended mixtures require more HRWRA. 22 Moreover, ECC mixtures with an FA/PC ratio of 1.2 had higher HRWRA demand than those with an FA/PC of 2.2. 23 The smooth surface characteristics and spherical shape of the FA improved the workability characteristics of ECC mixtures so that similar workability properties at a constant w/cm were achieved by using a lower HRWRA content at a higher FA replacement level. 24 A mortar mixer was used in the preparation of all ECC mixtures in this study. Solid ingredients, including cement, mineral admixture (FA or FA/MK), and aggregate, were initially mixed at 100 rpm for 1 minute. Water and HRWRA were then added into the dry mixture and mixed at 150 rpm for 1 minute and then mixed at 300 rpm for another 2 minutes to produce a consistent and uniform ECC matrix (without at 150 rpm for an additional 3 minutes. Specimen preparation and testing Several 285 x 25 x 25 mm (11.22 x 0.985 x 0.985 in.) bar and 355 x 50 x 76 mm (13.97 x 1.97 x 2.99 in.) prism speci- mens from each mixture were prepared for drying shrinkage and four-point bending tests, respectively, and 100 x 200 mm (3.93 x 7.87 in.) cylinder specimens were prepared for rapid chloride permeability testing. Fifty mm (1.97 in.) cubic spec- imens were prepared to determine compressive strength, WA, water sorptivity, and WP. All specimens were demolded at the age of 24 hours and cured in sealed plastic bags at 95 5% relative humidity (RH) and 23 2C (73F 3.6F) for 7 days. They were then air-cured at 50 5% RH and 23 2C (73F 3.6F) for 28 days prior to testing. The complete testing program is detailed in the following sections. The compressive strength of the ECC mixtures was determined by testing at least three 50 mm (1.97 in.) cubic specimens at the age of 28 days according to the procedure described in ASTM C39-94. 25 A four-point bending test was performed under displacement control at a loading rate of 0.005 mm/s (0.0002 in./s) on a closed-loop controlled servo- loading was 304.8 mm (12 in.) at the tension surface with a 101.6 mm (4 in.) center-span length at the compression - tion were recorded on a computerized data recording system. Drying shrinkage Drying shrinkage measurements for all ECC mixtures were made on three 285 x 25 x 25 mm (11.22 x 0.985 x 0.985 in.) bars up to 120 days after an initial curing of 1 day in the mold and 27 days in lime-saturated water in accor- dance with ASTM C157/C157M-04. 26 The drying shrinkage specimens were stored in a drying room at 23 2C (73F 3.6F) and 50 4% RH. WA and porosity WA was determined as per ASTM C642-06 27 ; speci- mens were initially oven-dried at 105 5C (222F 9F) for 72 hours to reach constant mass and obtain oven-dry mass (W 1 ). They were then immersed in water for 72 hours and the saturated surface-dry mass (W 2 ) of the specimens was measured. The WA of each specimen was calculated as follows 2 1 1 W W WA (%) 100 W (1) To determine the WP, the hydrostatic weight (W 3 ) of the ECC specimens was also determined and the WP was calcu- lated as follows 2 1 2 3 W W WP (%) 100 W W (2) Sorptivity The sorptivity test was performed as per ASTM C1585-04. 28
The test evaluated the increase in the mass of a 50 x 50 x 50 mm (1.97 x 1.97 x 1.97 in.) cubic specimen at given intervals of time (up to 360 minutes for initial sorptivity and up to 8 days for secondary sorptivity) when permitted to absorb water by capillary suction. Only the bottom surface of the specimen was in contact with water. The water depth was up to 4 mm (0.16 in.) to prevent water ingress from the sides; the perim- eter and top surface of the specimens were sealed with adhe- sive aluminum tape. This test was chosen because it measures the rate of ingress of water through unsaturated concrete and can therefore be considered a measure of water transport associated with capillary suction. Three specimens were used to determine the ingress of water for each ECC mixture. ChIoride-ion permeabiIity The chloride-ion permeability test, conducted in accor- dance with ASTM C1202-97, 29 measures the ease with which the charge passes through concrete, giving an indi- cation of the ECC`s resistance to chloride-ion permeability. Disc specimens 100 mm (4 in.) in diameter and 50 mm (2 in.) thick were cut from the midportion of 100 x 200 mm (4 x 8 in.) cylinder specimens and conditioned according to ASTM C1202. 29 Specimens were then subjected to 60 V potential for 6 hours and the total charge that passed through the specimens was determined and used to evaluate the chlo- ride permeability of each ECC mixture. A minimum of three specimens were tested for each mixture. 568 AC Materials Journal/September-October 2012 MK were slightly higher than in the ECC mixtures produced of the FA and MK mixtures (ECC-3 and ECC-4) were lower than those of the mixtures with only FA (ECC-1 and demonstrated that the most important feature of ECC-high ductility with multiple-cracking behaviors-was maintained at an adequate level by replacing FA with 12.5% MK. After the four-point bending test, the bending load was released and the specimens were taken out of the closed- loop controlled servo-hydraulic material test system. A crack closure occurred in the unloading position; the crack width in the loaded position was approximately 30% greater than in the unloaded position. All crack width measurements were conducted in the unloaded state. Crack widths were measured on the tension surface of the specimens using a portable crack microscope with 5 m (0.00019 in.) magni- numbers on the span length of 102 mm (4.02 in.) at the center of the prism specimens` tension surface. Each data point in Table 4 is an average of at least three or more prism specimens; more than 10 m (0.00039 in.) crack widths were measured from each specimen. All four ECC mixtures showed crack widths of smaller than 75 m (0.003 in.). Mixture ECC-2_FA/PC = 2.2 showed a very tight average crack with a width of 51 m (0.002 in.). It was found that the number of cracks increased, whereas crack width decreased as FA content increased from 55 to 70%. ECC mixtures (ECC-3 and ECC-4) incorporating MK and FA led to a slightly wider crack width and a lesser number of cracks compared to FA-ECC mixtures. Drying shrinkage The results of drying shrinkage testing at 120 days after RESULTS AND DISCUSSION crack behaviors The compressive strength variation of ECC mixtures is presented in Table 3. It shows that with increases in FA content and decreases in cement, compressive strength 1.2 to ECC-2_FA/PC = 2.2. As seen in Table 3, the compres- sive strength of ECC mixtures incorporating FA and MK (Mixtures ECC-3_(FA + MK)/PC = 1.2 and ECC-4_(FA + MK)/PC = 2.2) was 20.3% and 12.8% higher than in the control ECC mixtures containing only FA (Mixtures ECC-1_FA/PC = 1.2 to ECC-2_FA/PC = 2.2), respectively. Inclusion of MK into the matrix improved the bond between the cement paste and silica sand particles and increased improved the compressive strength of the ECC mixtures. - - ural loads varied from 8.57 to 11.01 MPa (1.24 to 1.60 ksi) bending load varied from 4.30 to 7.17 mm (0.169 to 0.28 in.), depending on the content of FA or the FA/MK combination. Table 4 shows that increasing the FA/PC ratio from 1.2 to 2.2 (Mixtures ECC-1_FA/PC = 1.2 to ECC-2_FA/PC = 2.2) improved the bending deformation capacity by approxi- approximately 22.3%. The improvement in bending defor- mation capacity with increased FA content can be attributed to the fact that greater amounts of FA tend to reduce the PVA and increase the interface frictional bond in favor of attaining high bending capacity 12,30 due to the change of matrix chem- ical composition and coating effect of inert particles on a the load-carrying capacities of ECC mixtures with FA and TabIe 3Compressive strength and chIoride-ion permeabiIity test resuIts of ECCs Mixture ID Compressive strength, MPa Chloride-ion permeability Coulombs Rating ECC-1_FA/PC = 1.2 46.4 1072 Low ECC-2_FA/PC = 2.2 46.8 1719 Low ECC-3_(FA + MK)/ PC = 1.2 55.5 627 Very low ECC-4_(FA + MK)/ PC = 2.2 52.8 1468 Low Notes: 1 MPa = 1.6845 lb/yd 3 ; 1 MPa = 0.145 ksi. of ECCs. TabIe 4Number of cracks, average crack widths, and bending test resuIts of ECCs Mixture ID Bending test results After bending test m ECC-1_FA/PC = 1.2 5.37 11.01 33 65 11 ECC-2_FA/PC = 2.2 7.17 8.57 41 51 9 ECC-3_(FA + MK)/PC = 1.2 4.35 11.33 27 73 12 ECC-4_(FA + MK)/PC = 2.2 4.30 8.75 32 68 5 Notes: 1 MPa = 0.145 ksi; 1 mm = 0.0393 in.; 1 m = 0.0000393 in. AC Materials Journal/September-October 2012 569 ranged from 990 to 1450 at 120 days. When the FA/PC ratio was increased from 1.2 to 2.2, drying shrinkage was reduced by approximately 14%. Yang et al. 11 studied the effect of the FA/PC ratio on the drying shrinkage of high- volume FA-incorporated ECC and noticed that increasing the FA/PC ratio from 1.2 to 5.6 effectively decreased the drying shrinkage up to 50%. According to their conclu- sions, a possible mechanism behind the reduction of drying the matrix, which may prevent internal moisture evapora- - explanation would be that unhydrated FA particles serve ECC can also be seen in Fig. 2. The substitution of 10% (for Mixture ECC-3_(FA + MK)/PC = 1.2) and 12.5% (for Mixture ECC-4_(FA + MK)/PC = 2.2) MK with FA led to a reduction of 29.7% (according to Mixture ECC-1_FA/ PC = 1.2) and 20.8% (according to Mixture ECC-2_FA/PC = 2.2) at the age of 120 days, respectively. The reduction in drying shrinkage with the incorporation of MK can be partly attributed to the lower amount of evaporable water, - cant amount of the free water. 7,31 With the inclusion of 10% MK for Mixture ECC-3_(FA + MK)/PC = 1.2 and 12.5% for ECC-4_(FA + MK)/PC = 2.2, the drying shrinkage of these two ECC mixtures became close to each other at 120 days. Mixtures ECC-3 and ECC-4 exhibited drying shrinkages of 1020 10 -6 and 990 10 -6 , respectively, at the end of 120 days. WA and WP Figure 3 presents the results of the WA and WP tests. An increase of FA/PC from 1.2 to 2.2 remarkably increased both WA and WP. Mixture ECC-2_FA/PC = 2.2 had 8.63 and 14.89% WA and WP values, respectively, while those values were 6.36 and 10.34% for Mixture ECC-1_FA/PC = 1.2. It of ECC decreased (refer to Tables 3 and 4), while WP and specimens have also been reported by other investigators. The most probable reason for the higher WA and WP with high volumes of FA is the slow pozzolanic reaction of FA 'Specimen preparation and testing section of this paper, the ECC specimens were cured in air after a 7-day sealed curing. With the incorporation of the blend of MK and FA (Mixtures ECC-3 and ECC-4), the WP and WA of the ECC mixtures improved due to an increased packing density. For example, the WP and WA values of the ECC mixture with 12.5% MK (ECC-4_(FA + MK)/PC = 2.2) decreased from 8.63% to 6.53% and from 14.89% to 12.84%, respec- tively. It is widely accepted that the principal reaction is facilitated by the dissolution of glassy/amorphous silica in pore water, which then reacts with CH to form CSH gel. which is the main factor behind the strength, porosity, and pore diameter of various pozzolanic materials. Due to the 2 /g [2154 in. 2 /g]), more of the silica enters the solution faster than FA (3870 cm 2 /g [600 in. 2 /g]), forming additional CSH gels on reaction and leading to an enhanced microstruc- ture and a decreased value of the total porosity and WA of ECC. 32 Khatip and Wild 33 studied the pore size distribution of MK paste containing up to 15% MK and observed that of curing, after which the pore size changed slightly. This and porosity values than those containing only FA. Sorptivity Sorptivity is a material property that characterizes the tendency of a material to absorb and transmit water by capillary suction. Sorptivity testing measures the rate of value indicates water mass uptake by concrete from the bottom surface. 34 When testing the 50 mm (1.97 in.) cubic specimens, the cumulative WA per unit area up to 6 hours and 8 days was performed using linear regression analysis and the slope of equation was obtained to describe the initial and secondary sorptivity of the ECC mixtures, respectively. Figure 4 demonstrates the initial and secondary sorptivity from 1.2 (Mixture ECC-1) to 2.2 (Mixture ECC-2) slightly the ECC incorporating only FA. The initial and secondary 55% FA content) were 0.0219 mm/sn 0.5 and 0.0021 mm/ sn 0.5 0.0331 mm/sn 0.5 and 0.0024 mm/sn 0.5 in Mixture ECC-2 (FA/PC = 2.2 and 70% FA content), respectively. A similar trend for mortar and ECC has also been observed by previous researchers. 12,35 However, even at approximately a 70% Fig. 2-Drying shrinkage variation of ECC mixtures. Fig. 3-Water absorption and porosity test results of ECCs. 570 AC Materials Journal/September-October 2012 time of curing, most of the FA particles in the matrix expe- rienced no hydration and pozzolanic reactions. Because Mixture ECC-2 had more FA content (70%) than ECC-1 (55%), it was more negatively affected by the short period - bility properties, such as chloride-ion permeability resis- tance, are usually manifested at later ages with the contin- uous supply of moisture. 12 Another possible reason could 2 /g [474 in. 2 /g]), as of the cement used (3870 cm 2 /g [585 in. 2 /g]). As mentioned positively affected the resistance of composites to chlo- ride-ion permeability. ECC mixtures (ECC-3 and ECC-4) produced with FA and MK had considerably lower chloride- ion permeability values than the ECC mixtures made only with FA. For instance, with the introduction of 10% MK, chloride-ion permeability decreased from 1072 coulombs (for Mixture ECC-1_FA/PC = 1.2) to 627 coulombs (for Mixture ECC-3_(FA + MK)/PC = 1.2), representing a reduction of approximately 42%. Mixtures ECC-2 (FA/ PC = 2.2) and ECC-4 ((FA + MK)/PC = 2.2) demonstrated the same behavior. The binary use of FA and MK in Mixture ECC-4 (12.5% MK and 56% FA) decreased the chloride-ion permeability value of Mixture ECC-2 (70% FA) from 1719 to 1468 coulombs. Reduced capillary pores and reduced connectivity due to the rapid pozzolanic activity may be the reasons behind the better performance of ECCs with MK. Using FA and MK together can compensate for some of the shortcomings of ECC made exclusively with FA and create ECCs with increased durability. CONCLUSIONS The following conclusions can be drawn from this experi- mental study: - cantly alter the compressive strength of ECC mixtures produced with FA. However, the use of a binary blend of FA and MK in ECC production had a positive effect on the compressive strength; it increased from approxi- mately 12 to 20% with respect to ECC with only FA. Under the four-point bending test, all ECC mixtures exhibited multiple-cracking and strain-hardening behavior. Although the binary incorporation of FA - tion capacity of ECC specimens, it could still attain a higher than that of normal concrete. Moreover, ECC mixtures with the binary use of FA and MK had some- values than their ECC counterparts with only FA. unhydrated FA constraint effect, increasing the amount of FA reduced drying shrinkage by approximately 14%. The binary use of FA and MK in ECC produc- tion had a very positive effect on the drying shrinkage. The substitution of 10% (for Mixture ECC-3_(FA + MK)/PC = 1.2) and 12.5% (for Mixture ECC-4_(FA + MK)/PC = 2.2) MK with FA resulted in a reduction in the drying shrinkage as high as 30% and 21% for Mixtures ECC-1_FA/PC = 1.2 and ECC-2_FA/PC = 2.2 at 120 days, respectively. replacement of cement with FA (Mixture ECC-2_FA/PC = 2.2), the initial sorptivity was still lower than the sorptivity 36 typical sorptivity is 0.09 mm/minute 0.5 (0.00354 in./minute 0.5 ) for normal concrete. Incorporating MK with FA in ECC produc- tion (Mixtures ECC-3 and ECC-4) positively affected the pore 10% MK with FA in Mixture ECC-3 ((FA + MK)/PC = 1.2) 0.5
(for Mixture ECC-1_FA/PC = 1.2) to 0.0224 mm/sn 0.5 (for Mixture ECC-3_(FA + MK)/PC = 1.2). This trend was seen between Mixtures ECC-2 and ECC-4. These results show the value of using a binary FA/MK mixture rather than just FA and impermeable pore structure that will, for example, inhibit ingress of aggressive agents into the pore structure. 37 ChIoride-ion permeabiIity The rapid chloride-ion permeability test results of the ECC mixtures and their chloride-ion ratings according to ASTM C1202 29 are presented in Table 3. Rapid chloride-ion permeability testing is based on the electrical conductivity of ECC. The ECC sample is subjected to a potential differ- ence of 60 V and the total charge passing through it at the end of 6 hours is measured and expressed in coulombs. A reduction in this total charge value indicates better resistance to chloride-ion permeability and lower permeability. 38,39 As seen in the table, increasing the FA/PC ratio from 1.2 (Mixture ECC-1 with 55% FA) to 2.2 (Mixture ECC-2 with 70% FA) reduced resistance to chloride-ion permeability. This result performed on mortar and concrete. Normally, concrete with high volumes of pozzolans shows lower chloride-ion permeability due to a denser microstructure. The pozzolanic reaction may result in fewer capillary pores and less clog- ging of those pores, which reduces chloride-ion transport in concrete. 40 - to the lower chloride-ion permeability. 41 As mentioned by Sahmaran and Li, 12 however, the trend in ECC is completely different than in mortar and concrete. As seen in Table 3, increasing FA content from 55% (Mixture ECC-1_FA/PC = 1.2) to 70% (Mixture ECC-2_FA/PC = 2.2) increased chloride-ion permeability from 1072 to 1719 coulombs. The possible reason behind the higher chloride permeability with higher FA content is that the ECC specimens were cured in air after a 7-day sealed curing. Due to a relatively short Fig. 4-Initial and secondary sorptivity test results of ECCs. (Note. 1 mm/minute 0.5 = 0.0393 in./minute 0.5 .) AC Materials Journal/September-October 2012 571 Increasing the amount of FA in the ECC mixtures worsened their durability-related properties. Remark- able increases in WA, porosity, initial and secondary sorptivity, and chloride-ion permeability values were monitored. This can be attributed to the inadequate binary blend of FA and MK in ECC, however, all of the aforementioned durability-related properties improved - lary pores and the reduction in pore connectivity due to - ness of MK, as well as better particle packing density of the matrix. ACKNOWLEDGMENTS Council of Higher Education of Turkey (YOK), the Natural Sciences and Engineering Research Council (NSERC) of Canada, and the Canada Research Chair Program. REFERENCES 1. Ahmed, S. F. U., and Mihashi, H., 'A Review on Durability Prop- erties of Strain Hardening Fibre Reinforced Cementitious Composites (SHFRCC), Cement and Concrete Composites, V. 29, 2007, pp. 365-376. 2. Kanda, T., and Li, V. C., 'Practical Design Criteria for Saturated Pseudo Strain Hardening Behaviour in ECC, Journal of Advanced Concrete Tech- nology, V. 4, No. 1, 2006, pp. 59-72. 3. Li, V. C.; Wang, S.; and Wu, C., 'Tensile Strain-Hardening Behavior of Polyvinyl Alcohol Engineered Cementitious Composite (PVA-ECC), ACI Materials Journal, V. 98, No. 6, Nov.-Dec. 2001, pp. 483-492. 4. Kanda, T., and Li, V. C., 'A New Micromechanics Design Theory for Pseudo Strain-Hardening Cementitious Composite, Journal of Engi- neering Mechanics, ASCE, V. 124, No. 4, 1999, pp. 373-381. 5. Ahmed, S. F. U.; Maalej, M.; and Paramasivam, P., 'Analytical Model for Tensile Strain Hardening and Multiple Cracking Behavior of Hybrid Fiber-Engineered Cementitious Composites, Journal of Materials in Civil Engineering, ASCE, V. 19, No. 7, 2007, pp. 527-539. 6. Yang, Y.; Yang, E. H.; and Li, V. C., 'Autogenous Healing of Engi- neered Cementitious Composites at Early Age, Cement and Concrete Research, V. 41, 2011, pp. 176-183. 7. Zhang, J.; Gong, C.; Guo, Z.; and Zhang, M., 'Engineered Cementi- tious Composite with Characteristic of Low Drying Shrinkage, Cement and Concrete Research, V. 39, 2009, pp. 303-312. 8. Li, V. C., 'From Micromechanics to Structural Engineering-The Design of Cementitious Composites for Civil Engineering Applications, Journal of Structural Mechanics and Earthquake Engineering, V. 10, No. 2, 1993, pp. 37-48. 9. Li, V. C.; Mishra, D. K.; and Wu, H. C., 'Matrix Design for Pseu- dostrain-Hardening Fiber Reinforced Cementitious Composites, Materials and Structures, V. 28, No. 183, 1995, pp. 586-595. 10. Zhang, J., and Leng, B., 'The Transition from Macro-Multiple Cracking to Micro-Multiple Cracking in Cementitious Composites, Tsinghua Science and Technology, V. 13, No. 5, 2008, pp. 669-673. 11. Yang, E. H.; Yang, Y.; and Li, V. C., 'Use of High Volumes of Fly Ash to Improve ECC Mechanical Properties and Material Greenness, ACI Materials Journal, V. 104, No. 6, Nov.-Dec. 2007, pp. 620-628. 12. Sahmaran, M., and Li, V. C., 'Durability Properties of Micro- Cracked ECC Containing High Volumes of Fly Ash, Cement and Concrete Research, V. 39, 2009, pp. 1033-1043. 13. Qian, X., and Li, Z., 'The Relationships between Stress and Strain for High-Performance Concrete with Metakaolin, Cement and Concrete Research, V. 31, 2001, pp. 1607-1611. 14. Klimesch, D. S., and Ray, A., 'Autoclaved Cement-Quartz Pastes with Metakaolin Additions, Advanced Cement Based Materials, V. 7, 1998, pp. 109-118. 15. Asbridge, A. H.; Chadbourn, G. A.; and Page, C. L., 'Effects of Metakaolin and the Interfacial Transition Zone on the Diffusion of Chlo- ride Ions through Cement Mortars, Cement and Concrete Research, V. 31, 2001, pp. 1567-1572. 16. Kostuch, J. A.; Walters, G. V.; and Jones, T. R., Concrete 2000, V. 2, E&FN Spon, London, UK, 1993, pp. 1799-1811. 17. Walters, G. V., and Jones, T. R., 'Effect of Metakaolin on Alkali- Silica Reaction in Concrete Manufactured with Reactive Aggregate, V. M. Malhotra, ed., Proceedings of the 2nd International Conference on the Durability of Concrete, Montreal, QC, Canada, 1991, pp. 941-953. 18. Asbridge, A. H.; Jones, T. R.; and Osborne, G. J., 'High-Performance Metakaolin Concrete: Results of Large-Scale Trials in Aggressive Environ- ments, Radical Concrete Technology, Proceedings of the International Conference on Concrete in the Service of Mankind, R. K. Dhir and P. C. Hewlett, eds., Dundee, Scotland, 1996, pp. 13-24. 19. Chadbourn, G. A., 'Chloride Resistance and Durability of Cement Paste and Concrete Containing Metakaolin, PhD thesis, School of Engi- neering and Applied Science, Aston University, Birmingham, UK, 1997, 237 pp. - olin and Silica Fume on the Flexural Toughness of High-Performance Steel Fiber Reinforced Concrete, ACI Materials Journal, V. 95, No. 3, May-June 1998, pp. 284-292. 21. Li, V. C.; Wu, C.; Wang, S.; Ogawa, A.; and Saito, T., 'Interface Tailoring for Strain-Hardening PVA-ECC, ACI Materials Journal, V. 99, No. 5, Sept.-Oct. 2002, pp. 463-472. 22. Li, Z., and Ding, Z., 'Property Improvement of Portland Cement by Incorporating with Metakaolin and Slag, Cement and Concrete Research, V. 33, 2003, pp. 579-584. 23. Sahmaran, M.; Lachemi, M.; Hossain, K. M. A.; and Li, V. C., 'Internal Curing of Engineered Cementitious Composites for Prevention of Early-Age Autogenous Shrinkage Cracking, Cement and Concrete Research, V. 39, 2009, pp. 893-901. 24. Sahmaran, M.; Keskin, S. B.; Ozerkan, G.; and Yaman, I. O., 'Self- Healing of Mechanically Loaded Self-Consolidating Concretes with High Volumes of Fly Ash, Cement and Concrete Composites, V. 30, 2008, pp. 872-879. 25. ASTM C39-94, 'Standard Test Method for Compressive Strength of Cylindrical Concrete Specimens, ASTM International, West Conshohocken, PA, 1994. 26. ASTM C157/C157M-04, 'Standard Test Method for Length Change of Hardened Hydraulic-Cement, Mortar, and Concrete, ASTM Interna- tional, West Conshohocken, PA, 2004, 7 pp. 27. ASTM C642-06, 'Standard Test Method for Density, Absorption, and Voids in Hardened Concrete, ASTM International, West Conshohocken, PA, 2006, 3 pp. 28. ASTM C1585-04, 'Standard Test Method for Measurement of Rate of Absorption of Water by Hydraulic-Cement Concretes, ASTM Interna- tional, West Conshohocken, PA, 2004, 6 pp. 29. ASTM C1202-97, 'Standard Test Method for Electrical Indication of Concrete`s Ability to Resist Chloride Ion Penetration, ASTM International, West Conshohocken, PA, 1997, 6 pp. 30. Wang, S., and Li, V. C., 'Engineered Cementitious Composites with High-Volume Fly Ash, ACI Materials Journal, V. 104, No. 3, May-June 2007, pp. 233-241. 31. Brooks, J. J., and Megat Johari, M. A., 'Effect of Metakaolin on Creep and Shrinkage of Concrete, Cement and Concrete Composites, V. 23, 2001, pp. 495-502. 32. Sabir, B. B.; Wild, S.; and Bai, J., 'Metakaolin and Calcined Clay as Pozzolans for Concrete: A Review, Cement and Concrete Composites, V. 23, 2001, pp. 441-454. 33. Khatip, J. M., and Wild, S., 'Pore Size Distribution of Metakaolin Paste, Cement and Concrete Research, V. 26, No. 10, 1996, pp. 1545-1553. 34. Siddique, R., and Kaur, A., 'Effect of Metakaolin on the Near Surface Characteristics of Concrete, Materials and Structures, V. 44, 2011, pp. 77-88. 35. Chindaprasirt, P.; Jaturapitakkul, C.; and Sinsiri, T., 'Effect of Fly Ash Fineness on Compressive Strength and Pore Size of Blended Cement Paste, Cement and Concrete Composites, V. 27, 2005, pp. 425-428. 36. Neville, A. M., Properties of Concrete, fourth edition, Longman Group Limited, New York, 1995, 844 pp. 37. Bai, J.; Wild, S.; and Sabir, B. B., 'Sorptivity and Strength of Air- Composition on Carbonation Depth, Cement and Concrete Research, V. 32, 2002, pp. 1813-1821. 38. Sengul, O., and Tasdemir, M. A., 'Compressive Strength and Rapid Chloride Permeability of Concretes with Ground Fly Ash and Slag, Journal of Materials in Civil Engineering, ASCE, V. 21, No. 9, 2009, pp. 494-501. Type on Mechanical Behavior of Normal- and High-Strength Concretes, ACI Materials Journal, V. 99, No. 6, Nov.-Dec. 2002, pp. 528-533. 40. Li, S., and Roy, D. M., 'Investigation of Relations between Porosity, Pore Structure and Chloride Diffusion of Fly Ash and Blended Cements, Cement and Concrete Research, V. 16, No. 5, 1986, pp. 749-759. 41. Zhang, M. H.; Bilodeau, A.; Malhotra, V. M.; Kim, K. S.; and Kim, J. C., 'Concrete Incorporating Supplementary Cementing Materials: Effect on Compressive Strength and Resistance to Chloride Ion Penetration, ACI Materials Journal, V. 96, No. 2, Mar.-Apr. 1999, pp. 181-189.