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JEE Mains Chemistry Model Paper 2

CHEMISTRY 41. The electrons are identified by quantum numbers n and l (i) n = 4, l = 1 (ii) n = 4, l = 0 (iii) n = 3, l = 2 (iv) n = 3, l = 1. These can be placed in order of increasing energy from the lowest to highest as (a) (iv) < (ii) < (iii) < (i) (b) (ii) < (iv) < (i) < (iii) (c) (i) < (iii) < (ii) < (iv) (d) (iii) < (i) < (iv) < (ii) The standard heat of formation values of SF6(g), S(g) and F(g) are: 1100, 275 and 80 kJ mol 1 respectively. Then the average S F bond energy in SF6 is (a) 301 kJ mol 1 (b) 320 kJ mol 1 (d) 280 kJ mol 1 (c) 309 kJ mol 1 The best indicator for detection of end point in titration of a weak acid and a strong base is (a) Methyl orange (3 to 4) (b) Methyl red (5 to 6) (c) Bromothymol blue (6 to 7.5) (d) Phenolphthalein (8 to 9.6)
(Values in the parentheses indicate pH range).

42.

43.

44. 45.

46.

47.

48.

49.

50.

The pH of a 1 M CH3COONa (pKb CH3COO = 9.2) solution in water will be nearly (c) 7.4 (d) 9.4 (a) 2.4 (b) 5.4 In a flask of volume V litres, 0.2 mol of oxygen, 0.4 mol of nitrogen, 0.1 mole of NH3 and 0.3 mol of He are enclosed at 27C. If the total pressure exerted by these non reacting gases is one atmosphere, the partial pressure exerted by nitrogen is (a) 0.4 atm (b) 0.1 atm (c) 0.2 atm (d) 0.3 atm + If in a standard hydrogen electrode half cell 2H (aq) + 2e H2(g, 1 atm). It on addition of a base, hydrogen ion concentration is reduced to 10 1 M then the emf will be (a) + 0.0591 V (b) 0.1182 V (c) 0.0591 V (d) 0.1182 V A solution of (+) 1 chloro 1 phenylethane in toluene racemises slowly in the presence of a small amount of SbCl5 due to the formation of (a) a carbene (b) a carbocation (c) a free radical (d) a carbanion Which of the following structure corresponds to the product expected, when excess of C6H6 reacts with CH2Cl2 in presence of anhydrous AlCl3? (a) Ph2CHCl (b) PhCHCl2 (c) Ph2CCl2 (d) Ph2CH2 The ratio of Kp/Kc for the reaction CO(g) + O2(g) = CO2(g) is (a) 1 (b) RT 1/2 (c) (RT) (d) (RT) 1/2 What is the hybridisation of Xe in XeF2? (a) sp2 (b) sp3d (c) dsp2 (d) sp The hydrolysis of PCl3 gives (a) H3PO3 (c) H2P2O7

51.

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(b) H3PO4 (d) HPO3

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JEE Mains Chemistry Model Paper 2

53.

54.

56.

57.

Sodium salt of benzoic acid gives benzene on being heated with X and phenol gives benzene on heating with Y. Therefore X and Y are respectively (c) Zinc dust and soda lime.

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CH3 CH=N OH.

(a) Soda lime and copper. 58.

(a) 1 (c) 4 59.

The magnetic moment of certain complex is 2.8 . The number of unpaired electrons in the compound are (b) 2 (d) unpredictable

CH3CHO + H2NOH The above reaction occurs at (a) pH = 1 (c) Any value of pH

60.

A mixture of benzaldehyde and formaldehyde on heating with aqueous NaOH solution gives (a) benzyl alcohol and sodium formate. (b) sodium benzoate and methyl alcohol. (c) sodium benzoate and sodium formate. (d) benzyl alcohol and methyl alcohol.

61.

Given standard electrode potentials

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(b) Zinc dust and sodium hydroxide. (d) Soda lime and zinc dust.

(b) pH = 4.5 (d) pH = 12

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55.

Aluminium vessel should not be washed with material containing washing soda since (a) washing soda is expensive. (b) washing soda easily decomposed. (c) washing soda forms sodium aluminate. (d) washing soda forms insoluble aluminium oxide. The number of enantiomeric forms which can be produced by monochlorination of 3 methylbutane is (a) 2 (b) 4 (c) 3 (d) 0 Cyclohexanone is subjected to reduction by NaBH4. The product formed is: (a) Cyclohexane (b) Cyclohexanal (c) Cyclohexadiene (d) Cyclohexanol Which of the following aromatic acid has lowest value of pKa (a) C6H5COOH (b) p nitrobenzoic acid (c) m nitrobenzoic acid (d) p amionobenzoic acid (CH3)3C.MgCl on reaction with D2O produces (a) (CH3)3CD (b) (CH3)3C OD (c) (CD3)3CD (d) (CD3)3C OD

www.myengg.com Fe2+ + 2e Fe
3+

JEE Mains Chemistry Model Paper 2 Fe ; Fe ; Fe2+ is (b) 0.404 V 0.44 V 0.036 V (i) (ii)

+ 3e

The standard electrode potential (E) for Fe3+ + e (a) 62. 0.476 V

64.

238 92 U

234 92 U

65.

66.

(a) 1,1 (c) 1,2 White phosphorus reacts with NaOH to give an example of (a) Oxidation (c) Neutralization Antichlor is a substance which (a) absorbs chlorine. (b) changes Cl2 to HCl. (c) gives chlorine with bleaching powder. (d) acts as catalyst in preparation of chlorine.

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67.

Which among MeX, RCH2X, R2CHX, R3CX is most reactive towards SN2 reaction? (a) MeX (b) RCH2X (c) R3CHX (d) R3CX The chemical system that is non aromatic is (a) (b)

68.

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63.

(c) +0.404 V (d) +0.772 V The combustion of benzoic acid occurs according to expression, 1 C6H5COOH(s) + 7 O 2 (g) 7CO2(g) + 3H2O(l) 2 in a bomb calorimeter at 25C. If it liberates Q J mol 1, then H for the reaction is (a) Q + (RT)1/2 (b) Q + (RT) 1/2 1 1 (c) Q + RT (d) Q RT 2 2 A 0.01 M solution of glucose in water freezes at 0.0186C. A 0.01 M solution of KNO3 in water will freeze at (a) 0.0093C (b) 0.0372C (c) 0.0186C (d) 0.093C The number of and particles emitted in the transformation (b) 1,0 (d) 2,1 phosphine and NaH2PO2. This reaction is (b) Reduction (d) Oxidation and reduction both

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JEE Mains Chemistry Model Paper 2

(c) 69.

(d)

70.

A(g) + 2B(g) 3C(g) + D(g) is x M, if volume becomes double, the reaction shifts in (a) forward direction (b) backward direction (c) equilibrium will not be disturbed (d) none of these Which of the following does not give yellow precipitate with I2/NaOH?

O
(a) CH3 C OC2H5 (c) CH3 CH CH3

O
(b) CH2I C CH2 CH3 O (d) H C H

(b) geometrical isomers (d) anomers

72.

Conjugate acid of NH 2 is (a) NH3 (c) NH 3

73.

The equivalent weight of the compound KHC2O4.H2C2O4.4H2O used in neutralisation is molecular weight molecular weight (a) (b) 1 2 molecular weight molecular weight (c) (d) 3 4 75. On performing a borax bead test with a given inorganic mixture of qualitative analysis, the colour of the bead was found to be emerald green both in oxidising and reducing flame. It indicates the possibility of the presence of (a) Ci2+ (b) Ni2+ (c) Cr3+ (d) Cu2+ 76. A gas decolourises alkaline KMnO4 but does not give precipitate with ammoniacal AgNO3. The gas is (a) C2H6 (b) C2H2 (c) C2H4 (d) CH4 77. When phenol is distilled with Zn dust it gives (a) Benzaldehyde (b) Benzoic acid (c) Toluene (d) Benzene

74.

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Which of the following will give 4 stereoisomers? (a) [CO(en)2 Cl2]+ (b) [CO(en)3]3+ (c) [Cr(NH3)2Cl2(en)]+ (d) Pt[(NH3)(Br)(Cl)(py)]

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(b) NH 2 (d) NH 4

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Cl 71. D (+) glucose and (a) enantiomers (c) epimers

D (+ve) glucose are

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JEE Mains Chemistry Model Paper 2

79. 80.

The insecticide gammexane is a formation based on (a) DDT (b) Benzene hexachloride (c) Hexachloroethane (d) Chloral Nylon is a (a) Polyamide (b) Polyester (c) Polyethylene (d) Polypropylene Which chloroderivative of benzene among the following would undergo hydrolysis most readily with aqueous NaOH to furnish the corresponding hydroxy derivative? NO2 (a) O2N

Cl NO2

(b) O2N

Cl

(c) (CH3)2N

Cl

(d) C6H5Cl

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