System Feature

Versatile high quality multichannel Potentiostat/Galvanostat/Impedance Analyzer 8 fully independent channels with 12 EIS techniques capability(option) including multisine at affordable price Capable of multitude of applications: corrosion, sensor, solar cell, battery, fuel cell, super capacitor, general electrochemistry etc. High speed data sampling time: burst mode(50usec/sample) normal mode(1msec/sample) per channel Optional Battery test S/W package, Corrosion test S/W package, EIS S/W package, Electrochemical analysis S/W package and FRA package available Voltage pulse or current pulse charge/discharge test(GSM,CDMA etc) and sine wave function for ripple simulation in battery test package (option) & pulse plating available For accurate control/measurement, this system has 3 measurement voltage ranges and 12 measurement/control current ranges(lowest two ranges are with gain) Multichannel FRA function to control external electronic load or potentiostat/galvanostat is available as option Internal 350,000 data point storage and test running regardless of PC failure.

Internal FRA included FPGA/DSP control Plug-in type Aux port includes 3 analog input (auxiliary voltage measurement) 1 analog output 2 digital input 3 digital output

Hardware Feature

Compact design Wide current ranges(2A to 20pA*) for various application (200pA and 20pA range is with gain)

Independent operation by DSP with FPGA per channel

Built-In

FRA

in

each

channel:

Impedance

measurements (S/W option per 8 channels) Temperature measurement (K type) Thermocouple (option)

Simultaneous 3 auxiliary voltage measurements

Misc port includes I2C com port for external device control FRA port 1 Sig generator output 1 Voltage input 1 Current input

Bipolar pulse capability Max. sample rate : 50usec/point(Burst mode)

Temperature measurement as standard One auxiliary analog output 3 digital output & 2 digital input 8 channel system expandable up to 32channels via USB hub

Cell Port: Working, reference, counter, working sense

Free software upgrade 4ch, 6ch system available

System
ZIVE MP2, the outstanding multichannel potentiostat/ galvanostat/FRA is the best choice for the complete DC and impedance characterization of corrosion, coatings, sensors and other fundamental electrochemical analysis. And also, its versatile functions make it suited to other application including various energy sources and storage such as fuel cells, batteries, solar cells, and super capacitors. Each channel was Gate designed Array) and under FPGA (Field Signal

Safety
1. When communication failure between PC and ZIVE occurs, running channel will continue the experiments and save the data into each channels memory up to 350,000 data point set. When the communication is recovered, ZIVE will transfer saved data to PC. User can transfer data set from ZIVE to PC anytime. This function will be highly efficient for long time experiment and protect experiments from unexpected PC failure. 2. User can define safety condition setting by inputting his/her own safety levels for voltage, current, temperature etc. If the measurement value exceeds this setting value, the system will automatically stop to protect the system and cell. 3. If control value of voltage or current is different from measured value, the experiment will be stop automatically to protect the cell. 4. Automatic calibration function is supplied for user calibration. The system is controlled from a PC via USB or an Ethernet connection(future function). 8 channel system can be expanded to 16ch, 24ch etc. using USB hub.

Programmable

DSP(Digital

Processor) control with high speed capability DAC control: Two set of high speed 16bit DAC(50MHz) for offset & scanning & one set of for auxiliary analog output control ADC Reading: Two set of 16 bit 500kHz ADC for reading voltage/current and 4 channel 16bit 250kHz ADCs for auxiliary data input such as temperature, auxiliary voltage etc. It can provide high frequency EIS, fast pulse techniques with options and high speed sampling time. ZIVE MP2s each channel is equipped with a frequency response analyzer(FRA) as standard and it provides high performance impedance measurements over the frequency range 10uHz to 1MHz. ZRA(zero resistance ammeter) function can measure max 2Amp in galvanic corrosion technique. ZIVE MP2 can be easily upgraded with adding optional application software package without returning the system to the factory for upgrade. 16bit DAC(1MHz)

Maintenance 1. 2.
System has its own hardware parameters and calibration data. Channel is plug & play type and easy to install or to be removed (just plug-in or plug out).

Versatility
ZIVE MP2s system comes with additional three analog inputs (auxiliary voltage input) and 1 analog output, whereas 3 digital outputs and 2 digital inputs and one temperature input for K type thermocouple. user expand the usage of instrument. For example, 1. User can measure the voltage between working electrode and counter electrode and between counter electrode and reference working electrode electrode adding and to measurement electrode between using 2 reference It will help

Application
ZIVE MP2 multichannel electrochemical workstation is ideal for fundamental and quality research in electrochemistry, of new sensors, membrane, development assurance

corrosion/coatings,

electrode

material,

conducting polymer, evaluation power device research such as battery materials, fuel cells, super capacitors and solar cells. - Sensors ZIVE MP2 can be used for sensor research using with DNA chips or screen printed electrodes. Systems minimum current range is 20pA with EIS capability. - Corrosion The system is suitable for measuring low corrosion rates (corrosion software package is needed) and providing EIS test (EIS option) to evaluate corrosion. ZRA function is supplied for galvanic corrosion measurement.

additional analog inputs(auxiliary voltage inputs). 2. Using analog output, it can control rotating speed of rotator, MFC flow rate etc. by +/-10V full scale. 3. User can control on/off of max 3 devices by DO etc.

- General Electrochemistry ZIVE MP2 is also suitable for the development of bio-research, electron transfer kinetic studies or electrochemical analysis of compounds at low trace levels, where multichannel DC and impedance analysis is beneficial in providing high throughput of results. Techniques list by license Standard software includes; The system is very well adapted for

- Batteries
researches on cycling behavior of battery. It provides various control modes for battery cycling. It can support EVS(electrochemical voltage spectroscopy) test. Fast pulse capability for GSM, CDMA test is included in battery test S/W package. Pulse profile measurement function to check pulse shape is available. For ripple simulation test, sine wave charging/discharging is available - Fuel Cells ZIVE MP2 is ideal for characterizing the fuel cells and anodic/cathodic process mechanism at a development and research grade. This system can be directly used for PEMFC, DMFC, DEFC etc.

Basic techniques with standard functions 1. Potentiostatic 2. Galvanostatic 3. Voltage sweep 4. Current sweep 5. Cyclic voltammetry The above functions can be used sequentially by step control function.

Sequence editor User can design his/her experiment procedure using TASK sequential routine editor.
Constant

Control task parameters:

Standard Yes No Yes No No No No No Yes Yes No No No No No No No No No No No No Yes No Vpulse Ipulse GSINE PSINE No No No No EIS Yes No Yes No No No No No Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No No No No Yes No No No No No FRA Yes No Yes No No No No No Yes Yes No No No No No No No No Yes Yes Yes Yes Yes No No No No No COR Yes No Yes No No Yes Yes Yes Yes Yes No No No No No No No No No No No No Yes Yes No No No No EAS Yes No Yes No No No Yes Yes Yes Yes No No No No No No No No No No No No Yes No Yes Yes Yes Yes BAT Yes Yes Yes Yes Yes No Yes Yes Yes Yes No No No No No No No No No No No No Yes No Yes Yes Yes Yes GSTAT Crate PSTAT POWER LOAD OCP

- Super Capacitors ZIVE MP2 has fast potentiostat circuit with

high speed data acquisition (50usec/point, burst mode). This function is well applicable to this application. - Solar Cells Solar cell development and production and device requires extensive material super capacitors testing. Charging/discharging capability is used for

Softwarepackagename

STEP SWEEP

GSTAT PSTAT GSTAT PSTAT GSTAT PSTAT OCP PSUEDO HFRG HFRP MsineG MsineP GSTAT

testing to improve efficiency and match individual cells for panel construction. ZIVE MP2 is the best solution for photovoltaic cell characterization. With systems AI, AO, DI, DO, this system can monitor other devices signal and controllable those device too.

EIS

FRA REST ZRA Pulse

PSTAT HFRG HFRP

Main Software
Smart Manager (SM) is to control ZIVE MP2 model. It provides user defined test sequence using sequence file, technique menu and batch file which serial test using sequence files and/or technique files. This software is easy to use and functions which support various electrochemical experiments including functions of system control, schedule file editor, real time graph, analysis graph, user calibration, data file treatment etc.

Constant potential, current, C-rate, power, load, Sweep potential, current Step potential, current

OCP

EIS control FRA control Pulse control Rest (voltage monitoring only) Loop(cycle) control Device control

1.

EIS software package(EIS)-Option

1) Potentiostatic EIS 2) Galvanostatic EIS 3) Pseudo galvanostatic EIS Cut-off(Vertex) condition - Time(step, test, loop, cycle) - Current, current density - Voltage - Capacity -.. -dV - |dV/dt| - |dI/dt| - |dT/dt| - Temperature - Aux1,2,3 - Eoc etc Sampling condition: time, |dI/dt|, |dV/dt|, |dT/dt|, |dA1/dt|, burst time Rs,Cp&IdcvsVdcplot 8) Galvanodynamic HFR 9) Galvanostatic HFR monitor 10) Potentiostatic HFR monitor Sequence editor Flow view 11) Multisine potentiostatic EIS 12) Multisine galvanostatic EIS *1. The system measures open circuit potential before for each frequency change and apply AC sine wave on this potential. . 2 Electrochemical analysis software package(EAS) 6) Galvanodynamic GEIS 7) Potentiodynamic HFR 5) Potentiodynamic PEIS 4) OCP(*1) EIS

Batch function; User can design batch file including multiple technique files and/or sequence files. With this batch file, user can do experiments as several techniques/sequence in series automatically. - Step techniques CA(Chronoamperometry) CC(Chronocoulometry) CP(Chronopotentiometry)

Other application software package can be added by option.

Smart Manager optional software package

For a wide range of application, specific experimental techniques software packages are provided as option

50usecsampling

4. Battery software package(BAT) - Sweep techniques LSV(Linear sweep voltammetry) SDV(Sampled DC voltammetry) 4-1) Battery test techniques CC/CV test for lithium battery charging/discharging cycle life test - Pulsed techniques DPV(Differential pulse voltammetry) SWV(Square wave voltammetry) DPA(Diff. pulse amperometry) NPV(Normal pulsed voltammetry) RNPV(Reverse normal pulse voltammetry) CC/CC test for NiCd or NiMH etc. battery charging/discharging cycle life test

NPV&RNPVoverlay DNPV(Differential normal pulse voltammetry)

Discharging test EVS(Electrochemical voltage spectroscopy)

3. Corrosion software package(COR)-Option

Variable scan rate CV

Tafel(Tafel experiment)

Pulse mode is available for GSM & CDMA profile. Pulse shape profile can be measured by users demand.

Rp(Polarization resistance)

Pulse shape profile monitor (micro seconds order)

RpEc trend PDYN(Potentiodynamic) CYPOL(Cyclic polarization resistance)

Current sine wave (Charge ripple simulation) 4-2) Control mode 1) Charge: CC, CC-CV, pulse, sine wave 2) Discharge: CC, CP, CR, pulse, sine wave 4-3) Cutoff condition;

GDYN(Galvanodynamic) Reactivation RpEc trend Galvanic corrosion Potentiostatic ECN Galvanostatic ECN ZRA mode ECN

Time, voltage, current, power, temperature, AuxV etc. Various battery charge/discharge test is available including pulse discharge for GSM, CDMA application. Each software packages upgrade will be provided at free of charge.

Control & real time graph

Smart Manager provides 2 kinds of control & data acquisition with real time graph.

Simple monitor

This display window is for monitor the major data values and channel status for multiple channel operation. Multichannel control panel

Graph
Smart Manager graph function is to simplify the operation. There are 3 kinds of graphs per experiments. You can change X, Y1, Y2, Y3, Y4 axis parameter as you want. Each graph provides short buttons. When you click these buttons, Multichannel data monitor (EIS data/DC data selectable) graph format will be changed following short button format.

DC graph For general data display

multichannel real time graph 4 Short buttons: User can control and monitor for specific channel in details and he/she can monitor data in VOI(value of interest) window and channel status in one window. Real time graphs X Y axis format will be changed techniques. per techniques

I vs. V, E vs. LogI, V, I vs. time, V vs. Q.

Graph parameters: Time, Eref, I, Eoc, Id, Aux1, Aux2, Aux3, Temp,
LogI, Load, ChQ, DchQ, ChQs, DchQs, Ch P, Dch P, Ch-Wh, Dch-Wh, Sum Wh, Sum Q, Sum |Q|, |Q|, Rp, Ch Q/Q0, dQ/dV, Q-Q0

EIS graph For EIS data display

automatically. It can be defined by users demand per For experiment using sequence file or batch file, user can select 3 real time graphs X, Y axis parameter. Channel number which you will control can be changed in this window. Even if you control the channel in this mode, you can also monitor and control same channel in control panel at same time. Real time graph and VOI will be changed depending on DC test or impedance test automatically. Virtual control panel always display graph for recent test result. For impedance measurement, wave monitor will be displayed on real time graph to check wave quality. This monitor can be switched to Lissajous (I vs. E) plot. Strip Chart Strip chart recorder function is provided independently of real time graph function. You can monitor 2 Y axis data such as voltage, current,auxV1,2,3, Temp, power, capacity etc in real time and can select channel(s) which you want to monitor. You can also can set max. data point for showing strip chart length.

3 Short buttons Nyquist plot , Bode plot, Cs vs. frequency.

Graph parameters: Frequency, Zre, -Zim, Zmag, Zph, Y, Yimg, Y ,

|Y|, Yph, LogZ, LogY, Rs(R-C), Cs(R-C), Rp(R|C), Cp(R|C), Rs(R-L), Ls(R-L), Q(R-L), time, Vdc, Idc, Temp, Aux(1,2,3)

BAT graph For battery cycle data display

3 Short buttons: cycle capacity , cycle average, Log(cycle No) vs. depth of discharge plot.

Graph parameters: cycle number, Ch Q, Dch Q, Sum Q, Coulomb

Eff, Ch-Wh, Dch-Wh, Sum Wh, Energy Eff, MinV, MaxV, ChQs, DchQ, ChVavg, DchVavg, Vavg

Data Analysis Software

ZIVE data file can be used for analysis using external IVMANTM software for DC analysis, IVMAN DATM software for battery data analysis and ZMANTM software for EIS data analysis without license.

ZMANTM EIS Data Analysis software

Model simulation and fitting 2D- and 3D-Bode- and Nyquist plots Automatic equivalent circuit model search function Project concept to handle multiple EIS data analysis Parameter plot from fitted elements value Compatible with data format from Zahner, Gamry, Ametek etc. (License code is needed) Various weighting algorithm Model library and user model KK plot Batch fitting for project data Impedance parameter simulation Interpolate bad data Black-Nichols plot 3D graph setting option Improved model editor Application model library for automatic searching Parameter simulation of model Genetic algorithm option for initial guessing Automatic initial guessing

Trace movie function on fitting Free for ZIVEs data format(*.seo, *.wis) analysis (No license code required) Circle fitting Data editing available (insert, delete, edit) Add/subtract element parameters Add/subtract model parameters Impedance,Z in polar, admittance, Y in Polar, modulus, M in polar, dielectric constant, E in polar. data display Empty cell capacitance calculation Find file function Data replacement by formula function Cursor data display Model finding result automatic sorting by Chi square value R, C R,L R, Q preview & graphic ZHIT function Mott-Schottky analysis Donor density vs. Vfb graph C vs. voltage graph

Fitting display 3d Bode plot for series measurement Parameter plot

Importing 3rd parties ASCII data file

Project manager with data preview Model editor & model library

Cursor data display

Data replacement by formula function Automatic model searching LEVM fitting

2D Nyquist plot Parameter simulation KK consistency

2D Bode plot

Element add/subtraction

Rp,Cp vs frequency (R|C)

Finding data file menu Empty cell capacitance

Mott-Schottky analysis window

Circular fitting

Donor density vs. Vfb graph and analysis

C/R-V graph

IVMANTM DC Data & Battery Test Data Analysis Software

IVMANTM software package consists of IVMAN software IVMAN utilities differential analysis(battery analysis) Extractor peak find module Harmonic analysis Tafel analysis IVMAN Diff. Software Battery test data analysis Electrochemical voltage spectroscopy (dQ/dV vs. V) Voltage vs. capacity analysis (V vs. Q) Cycle graph (Q vs. cycle) Differential voltage graph(dV/dQ vs. Q)

IVMAN Software Electrochemical analysis software Ideal for DC corrosion data analysis and electro-analytical data analysis Initial guessing function on Tafel analysis Automatic Tafel fitting Polarization resistance fitting 3D graph Find peak function Interpolation, differentiation, integration etc. Reporting function Cycle graph dQ/dV vs. V Measured data V vs. Q

dV/dQ vs. Q Extractor Polarization resistance fitting Polarization analysis result

Export ASCII file

Extracting data by cycle number or step Exporting ASCII file

Time graph

Find peak menu Peak Find Module Independent peak finding software

CV graph

3D graph Tafel Analysis

Edit data menu

Universal graph

Tafel analysis

Tafel analysis result

ZIVE MP2 Specification

Main system PC communication Line voltage Max channel no. per unit Max channel Size Channel System Cell cable USB2.0 High Speed 100-240VAC, 50/60Hz, 1Amp 8 independant channel per unit 32 channels(4 units) expandable per PC 448.7X188.4X535.4 mm (WxHxD) / 8ch 60cm shielded type (Standard) Working, reference, counter, Working sense DSP with FPGA Automatic 2x16bit ADCs (500kHz)for voltage, current 4x 16bit ADCs(250kHz) for auxiliary reading 2x16bit DAC(50MHz) for bias & scan 1X16bit DAC(1MHz) for analog output 4ea (5Hz,1kHz,500kHz, 5MHz) 0 200V/sec Busy, Run 350,000 points 30Watt / channel 30Watt (15V@2A) 15V 2A 8ea 5MHz 10V/usec Electrometer Max input voltage Input impedance Bandwidth CMRR 10V 1013||60pF >5MHz >60dB (@100kHz)

Control Calibration Data acquisition ADC DAC Filter Scan rate Front Panel LED Internal Data Memory Max output power Power amplifier(CE) Power Compliance voltage Maximum current Control speed selection bandwidth Slew rate

EIS(Internal FRA) for system Frequency range 10uHz ~ 1MHz Frequency accuracy <0.01% Frequency resolution 5000/decade Amplitude 0.2mV ~ 5V rms (Potentiostatic) 0.1 ~ 70%(Galvanostatic) Mode Static EIS: Potentiostatic, galvanostatic, pseudogalvanostatic, OCP Dynamic EIS: Potentiodynamic, Galvanodynamic Fixed frequency Impedance: Potentiostatic, Galvanostatic, potentiodynamic, galvanodynamic Multisine EIS: Potentiostatic, Galvanostatic Interfaces for system Auxiliary port Digital output Digital input Auxiliary voltage inputs

Analog output Potentiostat mode(voltage control) - voltage control Control voltage range 10V, 1V, 100mV Voltage resolution 16 bit per each range Voltage accuracy < 0.02% f.s Max. scan range 10V vs. ref. E - current measurement Current ranges 12 ranges(auto/manual setting) 20pA ~ 2A (20pA & 200pA with gain) Current resolution 16 bit; 60uA,6uA,600nA,60nA,6nA,600pA, 60ppA,6pA, 600fA, 60fA,6fA,0.6fA Current accuracy 0.02% f.s(2A-2uA), 0.5%f.s(200nA-2nA) Galvanostat mode(current control) - Current control Control current range Max. 2A full scale depending on selected range Current resolution 16 bit; 60uA,6uA,600nA,60nA,6nA,600pA, 60ppA,6pA, 600fA, 60fA,6fA,0.6fA Current accuracy - Voltage measurement Voltage ranges Voltage resolution Voltage accuracy 0.02% f.s(2A-2uA), 0.5%f.s(200nA-2nA) 10V,1V,100mV 16 bit; 0.3mV,30uV,3uV <0.02% f.s Misc. port Sig generator output Peripheral communication Temperature measurement Zero Resistance Ammeter Software Max steps per experiment Shutdown safety limits Max. sampling rate Min. sampling time Sampling condition PC requirement Operating system PC specification(minimum) Display USB

3 (open collector) 2 (photo coupler) 3 analog Inputs: 10V For measurement of WE vs. CE CE vs. RE or other signal 1 analog output: 10V For stirrer, MFC, RDE etc. 1 analog output for FRA output or waveform generation output I2C to control external devices 1 K-type thermocouple input 20pA ~ 2A ranges

1000 Voltage, current, temperature etc 20kHz(50usec)-burst mode unlimited Time, dv/dt, dI/dt, temp etc.

WindowsXP/2000/Vista/7 Pentium4, RAM 1GB 1280x800 high color High speed 2.0

General Dummy cell One external dummy cell included Thermocouple 1.5meter K-type (option) Auxiliary cable Option Misc. cable Option Specifications&softwaresubjecttochangewithoutnotice. ZIVELAB WindowsisaregisteredtrademarkofMicrosoftCorporation.

Designed by http://www.zivelab.com

LocalDistributor

WonATech Co., Ltd. WonA Bldg, 8-6, WooMyunDong, SeochoGu Seoul, Korea Tel: +82-2-578-6516 Fax: +82-2-576-2635 e-mail: sales@wonatech.com Web site: www.wonatech.com