SULIT 4541/1 Gerak Gempur Chemistry 2007 Set 1 Paper 1 1 hours

Gerak Gempur SPM 2007

JABATAN PELAJARAN PERAK

GERAK GEMPUR

SIJIL PELAJARAN MALAYSIA 2007

CHEMISTRY Paper 1 One hour and fifteen minutes

DO NOT OPEN THE QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO

This question paper consist of 14 printed pages 4541/1 1 SULIT

SULIT INFORMATION FOR CANDIDATES 1. 2. 3. 4. 5. 6. 7.

Gerak Gempur SPM 2007

This question paper consists of 50 questions. Answer all questions. Answer each question by blackening the correct space on the answer sheet. Blacken only one space for each question. If you wish to change your answer, erase the blackened mark that you have made. Then blacken the space for the new answer. The diagrams in the questions provided are not drawn to scale unless stated. You may use a non-programmable scientific calculator.

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SULIT 1 When iodine sublimes, the particles A B C D 2 move further apart shrink to a smaller size vibrate and rotate about their fixed positions lose energy to the surroundings

Gerak Gempur SPM 2007

What happens to the particles when a liquid turns to solid? A B C D The particles become lighter. The particles able to move randomly. The distance between the particles is shorter. The kinetic energy of the particles becomes higher.

Which of the following correctly describes the relative charges of the subatomic particles? A B C D Proton +1 -1 +1 +1 Nucleon +1 0 -1 0 Electron -1 +1 0 -1

Which of the following statements is TRUE about the isotopes of an element? A B C D Isotopes have the same number of protons Isotopes are atoms of different element Isotopes have the same number of neutrons Isotopes have different chemical properties

The diagram shows the atomic structure of an atom of P.

Which of the following is the correct electron arrangement for the ion of P? A B C D 6 2.8 2.8.1 2.8.2 2.8.8

What is the number of molecules in 1 mol of water, H2O? [ Avogadro constant : 6.02 x 1023 mol-1 ] A B C D 2.01 x 1023 molecules 3.01 x 1023 molecules 6.02 x 1023 molecules 1.806 x 1024 molecules 3 SULIT

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Gerak Gempur SPM 2007

Which of the following elements are in Group 17 in the Periodic Table of elements? A B C D Chlorine and argon Chlorine and oxygen Chlorine and bromine Oxygen and nitrogen

Which of the following statements about the element in Group 1 is true ? A B C D Group 1 elements form diatomic molecules Group 1 elements do not react in cold water Group 1 elements are chemically unreactive Group 1 elements form chlorides with the formula of XCl

The diagram shows the symbol of Lithium atom and Flourine atom. 7 19

Li
3 9

How ionic bond can be formed between these two atoms ? A B C D 1 0 A Fluorine atom donates one electron to a atom of Lithium. A Lithium atom donates one electron to an atom of Fluorine. A Lithium atom shares one electron with an atom of Fluorine. A Lithium atom and a Fluorine atom donate one electron each.

Why an element has a tendency to combine with other elements? A B C D To get the formula. To show the reactivity. To make a chemical reaction. To form a compound that are more stable.

1 1

An ionic nitrate compound has the formula X(NO3)2 . What is the possible proton number of atom X? A B C D 6 9 10 12

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Gerak Gempur SPM 2007

The diagram shows the set up of apparatus of an electrolytic cell

Carbon Electrode Concentrated aqueous lithium chloride

A current was passed through concentrated aqueous lithium chloride, LiCl. Which of the followings is correct? Ions moving towards The cathode (negative) The anode ( positive) A B C D 13 Li+ Li+ Li+ and H+ Li+ and H+ Cl- and OHClClCl- and OH-

Which of the following substances is an acid? A B C D Toothpaste Lemon juice Liquid detergent Coconut milk

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Which of the following pH values is correct for water, acid and alkali ? A B C D Water pH = 7 pH > 7 pH < 7 pH = 7 Acid pH > 7 pH = 7 pH > 7 pH < 7 Alkali pH < 7 pH < 7 pH = 7 pH > 7

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Which of the following statements is the best to desribe an acid ? A B C D An acid is a chemical substance that has a bitter taste. An acid is a chemical substance that contains hydrogen atoms. An acid is a chemical substance that ionises completely in water . An acid is a chemical substance that ionises in water to produce free hydrogen ions

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Which of the following sulphate salts is insoluble in water? A B C D Sodium sulphate Zink sulphate Lead(II) sulphate Ammonium sulphate 5 SULIT

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Gerak Gempur SPM 2007 Which of the following substances are products of decomposition of lead(II) nitrate by heat? I Lead(II) oxide II Water III Nitrogen dioxide IV Oxygen A B C D I and II only I and III only I, II and III only I, III and IV only

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An alloy consists of two or more .. A B C D elements combined physically. elements combined chemically. compounds combined physically. compounds combined chemically.

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The diagram shows the steps involved in the manufacture of sulphuric acid. Sulphur J K L M Sulphuric Sulphur Oleum Sulphur dioxide acid trioxide

Oxygen Which of the following steps requires the used of a catalyst ? A B C D J K L M

20 A mixture of silica and boron oxide is heated at a high temperature. What is the type of glass formed? A B C D Soda lime glass Borosilicate glass Lead crystal glass Fused silica glass

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21 Which of the following electron arrangements for an atom is the most stable? A C B D

22 Substance R has a melting point of -7 oC and boiling point of 59 oC. Which of the following temperatures will R exists as a solid ? A B C D - 20 oC 0 oC 40 oC 100 oC

23 Which of the following substances contains the highest number of atoms ? [ Relative atomic masses : H, 1; He, 4; 0, 16; Ar, 40 ] A B C D 24 4 g hydrogen 8 g helium 16 g oxygen 20 g argon X is used in filling weather ballons and airship Y is an atom with electron arrangement 2.8

Which of the following statements is true about X and Y ? A B C D X and Y exist as diatomic molecules X and Y have a stable electron arrangements X and Y react with oxygen to form oxides X and Y react to form covalent compound

25 The diagram shows part of the Periodic Table of the Elements P Q S Which of the following is the correct order in the increasing size of the atom of the element P,Q,R and S ? A B C D 4541/1 P,R,Q,S P,Q,R,S S,Q,R,P S,R,Q,P 7 SULIT R

SULIT 26 The information below is about element R. Atom R has 14 neutron Nucleon number of element R is 27

Gerak Gempur SPM 2007

Which of the following is true about R ? A B C Atom of R forms R3+ ion Atom of R has 4 valence electrons The standard representation of atom R is
27

R
14

Element R is placed in Group 14 in the Periodic Table of an element

27 The diagram represents the electron arrangement for the compound when atom of X combines with atom of Y. 2+ X Y 2-

What is the number of electrons for atom Y? A B C D 6 8 10 12

28 The table shows the electron arrangements of four elements represented by the letters P, Q, R and S. Element Electron arrangemen t P 2.6 Q 2.8.2 R 2.8.4 S 2.8.7

Based on the information given, which of the following pair of elements will form a covalent compound with the formula XY2 ? A B C D Q and R Q and S R and P R and S

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SULIT 29 The table shows information about two voltaic cells. Pairs of metals X and copper Y and copper Potential difference / V 0.45 1.30

Gerak Gempur SPM 2007

Metal at negative terminal X Y

What is the potential difference of the pair of metals X and Y? A B C D 0.85 V 0.95 V 1.10 V 1.75 V

30 The diagram shows the set up of apparatus of an electrolytic cell.

Copper Electrode Copper(II) sulphate solution

Which of the following graphs show the changes in mass of the cathode during electrolysis ? A Mass /g

Time / sec B Mass /g

Time / sec C Mass /g

Time / sec D Mass /g

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Gerak Gempur SPM 2007 Which of the following substances is soluble in water and produces an alkaline solution? A B C D Zink oxide Sodium oxide Carbon dioxide Sulphur trioxide

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The table shows the pH values of five solutions P, Q, R, S and T. Aqueous solution (1.0 mol dm-3) pH value P 3 Q 5 R 7 S 11 T 13

Which combination of solutions when mixed together at the suitable volumes will produce a neutral solution? A B C D 33 P and Q S and T P, Q and R P, Q and T

Double decomposition method is used to prepare insoluble salts. Which of the followings is a double decomposition equation used in preparing insoluble salt? A B C D 2KI 2HCl Na2SO4 NaOH + Pb(NO3)2 + PbO + Mg(NO3)2 + K2CO3 2KNO3 + PbI2 PbCl2 + H2O MgSO4 + 2NaNO3 Na2CO3 + 2KOH

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When sodium hydroxide is added to solution X , a white precipitate is formed. The precipitate is insoluble in excess sodium hydroxide. The cation present in solution Y could be A B C D Al3+ Mg2+ Zn2+ Pb2+

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Which of the followings is a synthetic polymer ? A B C D Perspex Starch Naphtalene Natural rubber

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Gerak Gempur SPM 2007

An atom of element X has a mass equals to two molecules of nitrogen. What is the relative atomic mass of X ? [ Relative atomic mass : N, 14 ] A B C D 14 28 56 84

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How many atoms of helium have a mass equals to three molecules of oxygen ? [ Relative atomic masses : He,4 ; O, 16 ] A B C D 4 8 12 24

38 Relative molecular mass of Ca(YO3)2 is 164. What is the relative atomic mass of element Y ? [ Relative atomic masses : O, 16; Ca, 40 ] A B C D 39 14 28 76 124

The chemical equation below represents the extraction process of aluminium from aluminium oxide. 2Al2O3 4Al + 3O2 What is the volume of oxygen gas can be liberated from 7.65 g of aluminium oxide? [ Relative atomic masses : O, 16; Al, 27 ; Molar volume of any gas : 24.0 dm3 mol-1 at room condition ] A B C D 0.8 dm3 1.2 dm3 1.8 dm3 2.7 dm3

40 Element X combines with oxygen to form an oxide of X. The table shows the mass of elements X and O used and their corresponding relative atomic mass. Element X O Mass/ g 8.4 3.6 Relative atomic mass 56 16 What is the empirical formula for this oxide ? A B C D 4541/1 XO XO2 X2O3 X2O5 11 SULIT

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41 Aluminium reacts with lead (II) oxide to produce aluminium oxide and lead. If 4.0g of aluminium is reacted with 0.09 mole of lead (II) oxide, What is the mass of aluminium left after the reaction occurred ? [ Relative atomic masses : 0, 16; Al, 27; Pb, 207 ] A B C D 42 1.57 g 1.62 g 2.38 g 2.43 g

The diagram shows the descending order of metal X, metal Y and metal Z in electrochemical series. X Y Z

Less electropositive

Which of the following statements is true ? A B C D 43 Z can displaced Y from its salt solution Atom X is more difficult to lose electron than Y X can displaced Y from its salt solution Z is the negative terminal in the simple cell using Y and Z as electrodes

A student intends to electroplate an iron key with silver. He sets up the apparatus as shown below.

o o

s e p te ilv r la Iro k y n e s e c lo e ilv r h rid

When the current is allowed to flow for an hour, he find that the iron key was not electroplated. Which one of the following causes the failure of the experiment? I he uses silver chloride as an electrolyte II he uses silver plate as a cathode III he uses iron key as an anode IV he uses an ammeter A B C D I only IV only I, II and III only I, II, III and IV

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SULIT 44

Gerak Gempur SPM 2007

A solid deposit of element R is formed at the cathode when an aqueous solution containing ions of R is electrolysed. Which statement about element R is correct? A B C D R forms negative ions R ions gain electrons at the cathode R ions lose electrons at the cathode R is above hydrogen in the reactivity series

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If 8 g of copper(II) sulphate CuSO4 is dissolved in 200 cm3 of solution, what is the concentration of copper(II) sulphate solution g dm3? A B C D 0.04 g dm3 0.40 g dm3 4.00 g dm3 40.00 g dm3

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If 150 cm3 of a 4 mol dm3 solution Y is added to 250 cm3 of water, what is the molarity of the diluted solution? A B C D 1.50 mol dm3 2.40 mol dm3 2.80 mol dm3 3.00 mol dm3

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Salt X show the following observations when certain tests were carried out.
When heated, solid X decomposes and a brown gas which turns moist

blue litmus red is given off. Solution of X gave a positive brown ring test. A white precipitate is formed when hydrochloric acid is added to a solution of X. When the resulting solution is heated, the white precipitate dissolve. Salt X could be A B C D 48 Silver chloride Lead nitrate Zinc bromide Iron(III) sulphate

The equation below represents the action of heat on zinc nitrate . 2Zn(NO3)2 2ZnO + 4NO2 + O2 In an experiment, 47.25 g zinc nitrate is heated. Calculate the volume of nitrogen dioxide produced. [Relative atomic masses : N ,14; O,16; Zn,65. 1 mole of gas occupies 24 dm3 at room condition] A B C D 6 dm3 12 dm3 24 dm3 48 dm3 13 SULIT

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Gerak Gempur SPM 2007

Which of the following ions will form a precipitate when ammonia solution is added but the precipitate dissolve when excess ammonia is added? I II III IV A B C D Al3+ Zn2+ Pb2+ Cu2+ II only I and II only II and IV only I, II and III only

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Calculate the percentage of nitrogen in ammonium sulphate, (NH4)2SO4 by weight. (Relative atomic mass : N, 14 ; H,1 ; S,32 ; O,16) A B C D 6.7 % 21.2 % 27.3 % 66.7 %

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