CHEMICAL KINETICS

1. The half-life period of a first order reaction is 30 minutes. Calculate the specific reaction rate of the reaction: What life fraction of the reactant remains after 70 minutes? 2. A first order react ion is 20% complete in 10 minutes. Calculate (i) specific rate constant of the reaction and (ii) the time taken for the reaction to go to 75% completion. 3. The specific reaction rate of a first order reaction is 0.02 sec the initial concentration of the reactant is 2 mole/liter. Calculate (a) initial rate and (b) rate after 60 seconds. 4. 8. A first order gas reaction has k = 1.5 106 per second at 200C. If the reaction is allowed to run for 10 hours, what percentage of the initial concentration would have changed in the product? What is the half-life of this reaction? hat half 5. Rate of a reaction, A + B > product is given below as a function of different initial concentrations of A and B. > Initial Rate [A] (mole/liter) [B] (mole/liter) (i) 0.01 (ii) 0.02 (iii) 0.01 0.01 0.01 0.02 (mole/liter/mm) 0.005 0.010 0.005

Determine the order of the reaction with respect to A and with respect to B. What is the half4ife of A in the reaction? 6. 14. Per the reaction NO + Cl2 2 NOCl , it is found that doubling the concentration of both reactants increases the rate by a factor of 8, but doubling the Cl2 concentration alone, only doubles the rate. What is the order of the reaction with respect to NO and Cl2 ? 7. In a reaction 2 N 2O5 4 NO2 + O2 the rate can be expressed as (i)

d [ N 2O5 ] = k1[ N 2O5 ] dt

(ii)

d [ NO2 ] = k2 [ N 2O5 ] dt

(iii)

d [O2 ] = k3 [ N 2O5 ] dt

How are k1 , k2 & k3 related? 8. 20. For a reaction at 800C, 2 NO + 2 H 2 N 2 + 2 H 2O the following data were obtained:

[ NO] 104 mol lit 1

(i)1.5 (ii)1.5 (iii) 0.5

[ H 2 ] 10 3 mol lit 1
4 2 2

d [ NO ] 104 mol lit 1 min 1 dt

4.4 2.2 .24

What is the order of this reaction with respect to NO and H 2 ? ction 9. The following data were obtained for a gaseous reaction:

[ A2 ] mol lit 1
(i)0.01 (ii)0.01 (iii) 0.02

[ B]mol lit 1
0.01 0.04 0.01

d [ A2 ] mol lit 1 min 1 dt

0.072 0.288 0.144

Calculate the rat constant and rate of formation of AB when [ A2 ] = 0.01 and [B] = 002. 10. What will be the order of reaction of the type, A > Product, for which the following data were obtained? > [A] (i)1 (ii)2 (iii) 3

d [ A] dt
1 8 27

11. Calculate order of the reaction, A > Product, from the following data: [A]mol/lit. (i)0.0025 (ii)0.005 (iii) 0.01 D[product]/dt (mol/lit/sec)

10 10 5 5 10 5 2.5 10 5

12. For a chemical reaction A + B Product, the order is one with respect to each A and B. Find x and y from the > given data. Rate(mol/lit/sec) .10 .40 .80 [A] .20M X .40M [B] .05M .05M Y

13. 27. In the decomposition of H 2O2 at 300 K, the energy of activation was found to be 18 kcal/mole while it decreased to 6 kcal/mole when the decomposition was carried out in the presence of a catalyst at 300 K. How many times is the catalyzed reaction faster than the uncatalysed one? 14. 28. The energy of activation and specific rate constant for a first order reaction at 25C

2 N 2O5 (in CCl4 ) 2 N 2O4 (in CCl 4 ) + O2 are 100 kJ/mole and
half-life 3.46 10 5 sec 1 respectively. Determine the temperature at which the half life of the reaction is 2 hours. 15. 29. In the Arrheniuss equation for a certain reaction, the value of A and F (activation energy) are 4 1013 sec 1 and 986 kJ mol 1 respectively. If the reaction is of first order, at what temperature will its half-life period be ten half minutes? 16. The decomposition of H 2O2 in aqueous solution is a reaction of first order, How can it be justified from the following data: Time (min) X: 0 25 10 20 20 15.7 30 12.5

Where x is the volume (ml) of KMnO4 required to titrate a definite volume of H 2O2 ? 17. 34. From the following data for the decomposition of diazobenzene chloride, show that the reaction is of first order: Time (min) Vol. of N 2 :( ml) 20 10 50 25 70 33

162

18. 1 ml of methyl acetate was added to 20 ml of 05 N HC1 and 2 ml of the mixture was withdrawn from time to time d ml during the progress of hydrolysis of the ester and titrated with a solution of alkali. The amount of alkali needed for titration at various intervals is given below: Time (min) Alkali used (ml) 0 19.24 20 20.73 119 26.6

42.03

Establish that the reaction is of first order.

CHEMICAL KINETICS
1. The half-life period of a first order reaction is 30 minutes. Calculate the specific reaction rate of the reaction: What life fraction of the reactant remains after 70 minutes? 2. A first order react ion is 20% complete in 10 minutes. Calculate (i) specific rate constant of the reaction and (ii) the time taken for the reaction to go to 75% completion. 3. The specific reaction rate of a first order reaction is 0.02 sec the initial concentration of the reactant is 2 mole/liter. Calculate (a) initial rate and (b) rate after 60 seconds. 4. 8. A first order gas reaction has k = 1.5 106 per second at 200C. If the reaction is allowed to run for 10 hours, what percentage of the initial concentration would have changed in the product? What is the half-life of this reaction? hat half 5. Rate of a reaction, A + B > product is given below as a function of different initial concentrations of A and B. > Initial Rate [A] (mole/liter) [B] (mole/liter) (i) 0.01 (ii) 0.02 (iii) 0.01 0.01 0.01 0.02 (mole/liter/mm) 0.005 0.010 0.005

Determine the order of the reaction with respect to A and with respect to B. What is the half4ife of A in the reaction? 6. 14. Per the reaction NO + Cl2 2 NOCl , it is found that doubling the concentration of both reactants increases the rate by a factor of 8, but doubling the Cl2 concentration alone, only doubles the rate. What is the order of the reaction with respect to NO and Cl2 ? 7. In a reaction 2 N 2O5 4 NO2 + O2 the rate can be expressed as (i)

d [ N 2O5 ] = k1[ N 2O5 ] dt

(ii)

d [ NO2 ] = k2 [ N 2O5 ] dt

(iii)

d [O2 ] = k3 [ N 2O5 ] dt

How are k1 , k2 & k3 related? 8. 20. For a reaction at 800C, 2 NO + 2 H 2 N 2 + 2 H 2O the following data were obtained:

[ NO] 104 mol lit 1

(i)1.5 (ii)1.5 (iii) 0.5

[ H 2 ] 10 3 mol lit 1
4 2 2

d [ NO] 104 mol lit 1 min 1 dt

4.4 2.2 .24

What is the order of this reaction with respect to NO and H 2 ? ction 9. The following data were obtained for a gaseous reaction:

[ A2 ] mol lit 1
(i)0.01 (ii)0.01 (iii) 0.02

[ B]mol lit 1
0.01 0.04 0.01

d [ A2 ] mol lit 1 min 1 dt

0.072 0.288 0.144

Calculate the rat constant and rate of formation of AB when [ A2 ] = 0.01 and [B] = 002. 10. What will be the order of reaction of the type, A > Product, for which the following data were obtained? > [A] (i)1 (ii)2 (iii) 3

d [ A] dt
1 8 27

11. Calculate order of the reaction, A > Product, from the following data: [A]mol/lit. (i)0.0025 (ii)0.005 (iii) 0.01 D[product]/dt (mol/lit/sec)

10 10 5 5 10 5 2.5 10 5

12. For a chemical reaction A + B Product, the order is one with respect to each A and B. Find x and y from the > given data. Rate(mol/lit/sec) .10 .40 .80 [A] .20M X .40M [B] .05M .05M Y

13. 27. In the decomposition of H 2O2 at 300 K, the energy of activation was found to be 18 kcal/mole while it decreased to 6 kcal/mole when the decomposition was carried out in the presence of a catalyst at 300 K. How many times is the catalyzed reaction faster than the uncatalysed one? 14. 28. The energy of activation and specific rate constant for a first order reaction at 25C

2 N 2O5 (in CCl4 ) 2 N 2O4 (in CCl 4 ) + O2 are 100 kJ/mole and
half-life 3.46 10 5 sec 1 respectively. Determine the temperature at which the half life of the reaction is 2 hours. 15. 29. In the Arrheniuss equation for a certain reaction, the value of A and F (activation energy) are 4 1013 sec 1 and 986 kJ mol 1 respectively. If the reaction is of first order, at what temperature will its half-life period be ten half minutes? 16. The decomposition of H 2O2 in aqueous solution is a reaction of first order, How can it be justified from the following data: Time (min) X: 0 25 10 20 20 15.7 30 12.5

Where x is the volume (ml) of KMnO4 required to titrate a definite volume of H 2O2 ? 17. 34. From the following data for the decomposition of diazobenzene chloride, show that the reaction is of first order: Time (min) Vol. of N 2 :( ml) 20 10 50 25 70 33

162

18. 1 ml of methyl acetate was added to 20 ml of 05 N HC1 and 2 ml of the mixture was withdrawn from time to time d ml during the progress of hydrolysis of the ester and titrated with a solution of alkali. The amount of alkali needed for titration at various intervals is given below: Time (min) Alkali used (ml) 0 19.24 20 20.73 119 26.6

42.03

Establish that the reaction is of first order.

CHEMICAL KINETICS
1. The half-life period of a first order reaction is 30 minutes. Calculate the specific reaction rate of the reaction: What life fraction of the reactant remains after 70 minutes? 2. A first order react ion is 20% complete in 10 minutes. Calculate (i) specific rate constant of the reaction and (ii) the time taken for the reaction to go to 75% completion. 3. The specific reaction rate of a first order reaction is 0.02 sec the initial concentration of the reactant is 2 mole/liter. Calculate (a) initial rate and (b) rate after 60 seconds. 4. 8. A first order gas reaction has k = 1.5 106 per second at 200C. If the reaction is allowed to run for 10 hours, what percentage of the initial concentration would have changed in the product? What is the half-life of this reaction? hat half 5. Rate of a reaction, A + B > product is given below as a function of different initial concentrations of A and B. > Initial Rate [A] (mole/liter) [B] (mole/liter) (i) 0.01 (ii) 0.02 (iii) 0.01 0.01 0.01 0.02 (mole/liter/mm) 0.005 0.010 0.005

Determine the order of the reaction with respect to A and with respect to B. What is the half4ife of A in the reaction? 6. 14. Per the reaction NO + Cl2 2 NOCl , it is found that doubling the concentration of both reactants increases the rate by a factor of 8, but doubling the Cl2 concentration alone, only doubles the rate. What is the order of the reaction with respect to NO and Cl2 ? 7. In a reaction 2 N 2O5 4 NO2 + O2 the rate can be expressed as (i)

d [ N 2O5 ] = k1[ N 2O5 ] dt

(ii)

d [ NO2 ] = k2 [ N 2O5 ] dt

(iii)

d [O2 ] = k3 [ N 2O5 ] dt

How are k1 , k2 & k3 related? 8. 20. For a reaction at 800C, 2 NO + 2 H 2 N 2 + 2 H 2O the following data were obtained:

[ NO] 104 mol lit 1

(i)1.5 (ii)1.5 (iii) 0.5

[ H 2 ] 10 3 mol lit 1
4 2 2

d [ NO] 104 mol lit 1 min 1 dt

4.4 2.2 .24

What is the order of this reaction with respect to NO and H 2 ? ction 9. The following data were obtained for a gaseous reaction:

[ A2 ] mol lit 1
(i)0.01 (ii)0.01 (iii) 0.02

[ B]mol lit 1
0.01 0.04 0.01

d [ A2 ] mol lit 1 min 1 dt

0.072 0.288 0.144

Calculate the rat constant and rate of formation of AB when [ A2 ] = 0.01 and [B] = 002. 10. What will be the order of reaction of the type, A > Product, for which the following data were obtained? > [A] (i)1 (ii)2 (iii) 3

d [ A] dt
1 8 27

11. Calculate order of the reaction, A > Product, from the following data: [A]mol/lit. (i)0.0025 (ii)0.005 (iii) 0.01 D[product]/dt (mol/lit/sec)

10 10 5 5 10 5 2.5 10 5

12. For a chemical reaction A + B Product, the order is one with respect to each A and B. Find x and y from the > given data. Rate(mol/lit/sec) .10 .40 .80 [A] .20M X .40M [B] .05M .05M Y

13. 27. In the decomposition of H 2O2 at 300 K, the energy of activation was found to be 18 kcal/mole while it decreased to 6 kcal/mole when the decomposition was carried out in the presence of a catalyst at 300 K. How many times is the catalyzed reaction faster than the uncatalysed one? 14. 28. The energy of activation and specific rate constant for a first order reaction at 25C

2 N 2O5 (in CCl4 ) 2 N 2O4 (in CCl 4 ) + O2 are 100 kJ/mole and
half-life 3.46 10 5 sec 1 respectively. Determine the temperature at which the half life of the reaction is 2 hours. 15. 29. In the Arrheniuss equation for a certain reaction, the value of A and F (activation energy) are 4 1013 sec 1 and 986 kJ mol 1 respectively. If the reaction is of first order, at what temperature will its half-life period be ten half minutes? 16. The decomposition of H 2O2 in aqueous solution is a reaction of first order, How can it be justified from the following data: Time (min) X: 0 25 10 20 20 15.7 30 12.5

Where x is the volume (ml) of KMnO4 required to titrate a definite volume of H 2O2 ? 17. 34. From the following data for the decomposition of diazobenzene chloride, show that the reaction is of first order: Time (min) Vol. of N 2 :( ml) 20 10 50 25 70 33

162

18. 1 ml of methyl acetate was added to 20 ml of 05 N HC1 and 2 ml of the mixture was withdrawn from time to time d ml during the progress of hydrolysis of the ester and titrated with a solution of alkali. The amount of alkali needed for titration at various intervals is given below: Time (min) Alkali used (ml) 0 19.24 20 20.73 119 26.6

42.03

Establish that the reaction is of first order.

CHEMICAL KINETICS
1. The half-life period of a first order reaction is 30 minutes. Calculate the specific reaction rate of the reaction: What life fraction of the reactant remains after 70 minutes? 2. A first order react ion is 20% complete in 10 minutes. Calculate (i) specific rate constant of the reaction and (ii) the time taken for the reaction to go to 75% completion. 3. The specific reaction rate of a first order reaction is 0.02 sec the initial concentration of the reactant is 2 mole/liter. Calculate (a) initial rate and (b) rate after 60 seconds. 4. 8. A first order gas reaction has k = 1.5 106 per second at 200C. If the reaction is allowed to run for 10 hours, what percentage of the initial concentration would have changed in the product? What is the half-life of this reaction? hat half 5. Rate of a reaction, A + B > product is given below as a function of different initial concentrations of A and B. > Initial Rate [A] (mole/liter) [B] (mole/liter) (i) 0.01 (ii) 0.02 (iii) 0.01 0.01 0.01 0.02 (mole/liter/mm) 0.005 0.010 0.005

Determine the order of the reaction with respect to A and with respect to B. What is the half4ife of A in the reaction? 6. 14. Per the reaction NO + Cl2 2 NOCl , it is found that doubling the concentration of both reactants increases the rate by a factor of 8, but doubling the Cl2 concentration alone, only doubles the rate. What is the order of the reaction with respect to NO and Cl2 ? 7. In a reaction 2 N 2O5 4 NO2 + O2 the rate can be expressed as (i)

d [ N 2O5 ] = k1[ N 2O5 ] dt

(ii)

d [ NO2 ] = k2 [ N 2O5 ] dt

(iii)

d [O2 ] = k3 [ N 2O5 ] dt

How are k1 , k2 & k3 related? 8. 20. For a reaction at 800C, 2 NO + 2 H 2 N 2 + 2 H 2O the following data were obtained:

[ NO] 104 mol lit 1

(i)1.5 (ii)1.5 (iii) 0.5

[ H 2 ] 10 3 mol lit 1
4 2 2

d [ NO] 104 mol lit 1 min 1 dt

4.4 2.2 .24

What is the order of this reaction with respect to NO and H 2 ? ction 9. The following data were obtained for a gaseous reaction:

[ A2 ] mol lit 1
(i)0.01 (ii)0.01 (iii) 0.02

[ B]mol lit 1
0.01 0.04 0.01

d [ A2 ] mol lit 1 min 1 dt

0.072 0.288 0.144

Calculate the rat constant and rate of formation of AB when [ A2 ] = 0.01 and [B] = 002. 10. What will be the order of reaction of the type, A > Product, for which the following data were obtained? > [A] (i)1 (ii)2 (iii) 3

d [ A] dt
1 8 27

11. Calculate order of the reaction, A > Product, from the following data: [A]mol/lit. (i)0.0025 (ii)0.005 (iii) 0.01 D[product]/dt (mol/lit/sec)

10 10 5 5 10 5 2.5 10 5

12. For a chemical reaction A + B Product, the order is one with respect to each A and B. Find x and y from the > given data. Rate(mol/lit/sec) .10 .40 .80 [A] .20M X .40M [B] .05M .05M Y

13. 27. In the decomposition of H 2O2 at 300 K, the energy of activation was found to be 18 kcal/mole while it decreased to 6 kcal/mole when the decomposition was carried out in the presence of a catalyst at 300 K. How many times is the catalyzed reaction faster than the uncatalysed one? 14. 28. The energy of activation and specific rate constant for a first order reaction at 25C

2 N 2O5 (in CCl4 ) 2 N 2O4 (in CCl 4 ) + O2 are 100 kJ/mole and
half-life 3.46 10 5 sec 1 respectively. Determine the temperature at which the half life of the reaction is 2 hours. 15. 29. In the Arrheniuss equation for a certain reaction, the value of A and F (activation energy) are 4 1013 sec 1 and 986 kJ mol 1 respectively. If the reaction is of first order, at what temperature will its half-life period be ten half minutes? 16. The decomposition of H 2O2 in aqueous solution is a reaction of first order, How can it be justified from the following data: Time (min) X: 0 25 10 20 20 15.7 30 12.5

Where x is the volume (ml) of KMnO4 required to titrate a definite volume of H 2O2 ? 17. 34. From the following data for the decomposition of diazobenzene chloride, show that the reaction is of first order: Time (min) Vol. of N 2 :( ml) 20 10 50 25 70 33

162

18. 1 ml of methyl acetate was added to 20 ml of 05 N HC1 and 2 ml of the mixture was withdrawn from time to time d ml during the progress of hydrolysis of the ester and titrated with a solution of alkali. The amount of alkali needed for titration at various intervals is given below: Time (min) Alkali used (ml) 0 19.24 20 20.73 119 26.6

42.03

Establish that the reaction is of first order.

CHEMICAL KINETICS
1. The half-life period of a first order reaction is 30 minutes. Calculate the specific reaction rate of the reaction: What life fraction of the reactant remains after 70 minutes? 2. A first order react ion is 20% complete in 10 minutes. Calculate (i) specific rate constant of the reaction and (ii) the time taken for the reaction to go to 75% completion. 3. The specific reaction rate of a first order reaction is 0.02 sec the initial concentration of the reactant is 2 mole/liter. Calculate (a) initial rate and (b) rate after 60 seconds. 4. 8. A first order gas reaction has k = 1.5 106 per second at 200C. If the reaction is allowed to run for 10 hours, what percentage of the initial concentration would have changed in the product? What is the half-life of this reaction? hat half 5. Rate of a reaction, A + B > product is given below as a function of different initial concentrations of A and B. > Initial Rate [A] (mole/liter) [B] (mole/liter) (i) 0.01 (ii) 0.02 (iii) 0.01 0.01 0.01 0.02 (mole/liter/mm) 0.005 0.010 0.005

Determine the order of the reaction with respect to A and with respect to B. What is the half4ife of A in the reaction? 6. 14. Per the reaction NO + Cl2 2 NOCl , it is found that doubling the concentration of both reactants increases the rate by a factor of 8, but doubling the Cl2 concentration alone, only doubles the rate. What is the order of the reaction with respect to NO and Cl2 ? 7. In a reaction 2 N 2O5 4 NO2 + O2 the rate can be expressed as (i)

d [ N 2O5 ] = k1[ N 2O5 ] dt

(ii)

d [ NO2 ] = k2 [ N 2O5 ] dt

(iii)

d [O2 ] = k3 [ N 2O5 ] dt

How are k1 , k2 & k3 related? 8. 20. For a reaction at 800C, 2 NO + 2 H 2 N 2 + 2 H 2O the following data were obtained:

[ NO] 104 mol lit 1

(i)1.5 (ii)1.5 (iii) 0.5

[ H 2 ] 10 3 mol lit 1
4 2 2

d [ NO] 104 mol lit 1 min 1 dt

4.4 2.2 .24

What is the order of this reaction with respect to NO and H 2 ? ction 9. The following data were obtained for a gaseous reaction:

[ A2 ] mol lit 1
(i)0.01 (ii)0.01 (iii) 0.02

[ B]mol lit 1
0.01 0.04 0.01

d [ A2 ] mol lit 1 min 1 dt

0.072 0.288 0.144

Calculate the rat constant and rate of formation of AB when [ A2 ] = 0.01 and [B] = 002. 10. What will be the order of reaction of the type, A > Product, for which the following data were obtained? > [A] (i)1 (ii)2 (iii) 3

d [ A] dt
1 8 27

11. Calculate order of the reaction, A > Product, from the following data: [A]mol/lit. (i)0.0025 (ii)0.005 (iii) 0.01 D[product]/dt (mol/lit/sec)

10 10 5 5 10 5 2.5 10 5

12. For a chemical reaction A + B Product, the order is one with respect to each A and B. Find x and y from the > given data. Rate(mol/lit/sec) .10 .40 .80 [A] .20M X .40M [B] .05M .05M Y

13. 27. In the decomposition of H 2O2 at 300 K, the energy of activation was found to be 18 kcal/mole while it decreased to 6 kcal/mole when the decomposition was carried out in the presence of a catalyst at 300 K. How many times is the catalyzed reaction faster than the uncatalysed one? 14. 28. The energy of activation and specific rate constant for a first order reaction at 25C

2 N 2O5 (in CCl4 ) 2 N 2O4 (in CCl 4 ) + O2 are 100 kJ/mole and
half-life 3.46 10 5 sec 1 respectively. Determine the temperature at which the half life of the reaction is 2 hours. 15. 29. In the Arrheniuss equation for a certain reaction, the value of A and F (activation energy) are 4 1013 sec 1 and 986 kJ mol 1 respectively. If the reaction is of first order, at what temperature will its half-life period be ten half minutes? 16. The decomposition of H 2O2 in aqueous solution is a reaction of first order, How can it be justified from the following data: Time (min) X: 0 25 10 20 20 15.7 30 12.5

Where x is the volume (ml) of KMnO4 required to titrate a definite volume of H 2O2 ? 17. 34. From the following data for the decomposition of diazobenzene chloride, show that the reaction is of first order: Time (min) Vol. of N 2 :( ml) 20 10 50 25 70 33

162

18. 1 ml of methyl acetate was added to 20 ml of 05 N HC1 and 2 ml of the mixture was withdrawn from time to time d ml during the progress of hydrolysis of the ester and titrated with a solution of alkali. The amount of alkali needed for titration at various intervals is given below: Time (min) Alkali used (ml) 0 19.24 20 20.73 119 26.6

42.03

Establish that the reaction is of first order.