PHYSICAL CHEMISTRY

PHYSICAL CHEMISTRY by: SHAILENDRA KR.

Meq. Approach
Topic: Mole Concept

By: Shailendra Kumar

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01)

Which mode of expressing concentration is independent of temperature : (a) Molality (c) Mole fraction (b) Percent by weight (d) All 07)

(c) VD = (d) All

wt. of 1 mole of gas wt. of mole of H2

02)

W1g of an element combines with oxygen forming W2 g of its oxide. The equivalent weight of the element is : (a) [W1/W2] 8 (b) W1 8 W2W1 W1 W1W2

at A g of a metal desplaces V mL. of H2 NTP. Equivalent weight E, of metal is : (a) E = A EH wt. of H2 displaced

A 1.008 22400 (b) E = volume of H displaced 2 2 (c) E = volume of H displaced 0.0000897 2 (d) All 08) The equivalent weight of a substance is the weight which either combines or displaces: (a) 8 part of oxygen (b)1 part hydrogen (c) 35.5 part chlorine (d) All 09) Which of the following is correct : (a) Meq. = N Vin mL = (b) Eq. = N Vin L = wt. 1000 Eq. wt.
A 1.008

(c) 03)

W2W1 8 (d) W1

A molal solution is one that contains one mole of a solute in : (a) 1000 g of the solvent (b) 1000 mL of the solution (c) One litre of the solvent (d) 22.4 litre of the solution

04)

One mole electron means : (a) N electrons (b) 6.023 1023 electrons (c) 0.55 mg electron (d) All

05)

Avogadros number is the number of molecules present in : (a) 22.4 litre of a gas of NTP (b) 1 mole of a substance (c) g mol.wt. of a substance (d) All 10)

wt. Eq. wt. (c) Equal equivalent or milliequivalent of reactants react to give same eq.or Meq. of products (d) All The hardness of water is usually expressed in : (a) ppm (c) mol/litre (b) g/litre (d) None

06)

The vopour density of a gas is given by : (a) VD = mol.wt./2 (b) VD = wt. of N molecules of gas wt. of N molecules of H2

1. 2.

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PHYSICAL CHEMISTRY
11) Which of the following is correct : wt. (a) Mole = molarity Vin L = Mol. wt. wt. (b) Millimole = M V in mL= Mol. wt. 1000 (c) Mole and millimole of reactants react according to stoichiometric ratio of balanced chemical equation (d) All 12) A solution of known normality is diluted to two times. Which of the following changes during dilution : (a) Equivalent of solute (b) Moles of solute (c) Milliequivalent or millimole of solute (d) Normality of solution 13) Specific gravity of solution is given by: (a) Weight of 1 mL solution (b) Mole present in 1 mL solution (c) Volume of 1 g solution (d) None 14) Which sample contains the largest number of atoms : (a) 1 mg of C4H10 (c) 1 mg of Na 15) (a) 1 molecule (b) 1 mg of N2 (d) 1 mL of water (b) 4 molecules
23

By: Shailendra Kumar

19) The equivalent weight of H3PO4 in the following reaction is, H3PO4+Ca(OH)2 CaHPO4+2H2O : (a) 98 (c) 32.66 20) (b) 49 (d) 40

The equivalent weight of Zn(OH)2 in the following reaction is equal to its, Zn(OH)2+ HNO3 Zn(OH)(NO3)+H2O Formula wt. (a) Formula wt. (b) 2 1 (c) 2 formula wt. (d) 3 formula wt.

21)

The atomic weight of a metal (M) is 27 and its equivalent weight is 9, the formula of its chloride will be : (a) MCl (c) M3Cl4 (b) MCl9 (d) MCl3

22)

An element A (at. wt. = 75) and B (at. wt. =25) combine to form a compound. The compound contains 75% A by weight. The formula of the compound will be : (a) A2B (c) AB3 (b) A3B (d) AB

23)

One mole of P4 molecules contain : (c) 1/4 6.022 10 atoms (d) 24.088 1023 atoms 24)

The hydrated salt Na2SO4.nH2O, undergoes 55% loss in weight on heating and becomes anhydrous. The value of n will be : (a) 5 (c) 7 (b) 3 (d) 10

16)

The total number of protons, electrons and neutrons in 12 g of 126C is : (a) 1.084 1025 (c) 6.022 10
22

100 mL of PH3 when decomposed produces phosphorus and hydrogen. The change in volume is : (a) 50 mL increase (b) 500 mL decrease (c) 900 mL decrease(d) None

(b) 6.022 1023 (d) 18 25)

17)

1 mole of any gas : (a) Always occupies 1 litre (b) Always occupies 22.4 litre (c) Can occupy any volume at NTP (d) Always occupies a fixed volume at NTP

What is the weight of oxygen that is required for the complete combustion of 2.8 kg of ethylene : (a) 2.8 kg (c) 96.0 kg (b) 6.4 kg (d) 9.6 kg

26)

When 100 g of ethylene polymerizes to polyethylene according to the equation, nCH2=CH2 ( CH2 CH2 )n. The weight of polyethylene produced will be : n (a) g (b) 100 g 2 100 (c) n g (d) 100n g Page No.: 2

18)

4.4 g of CO2 and 2.24 litre of H2 at STP are mixed in a container. The total number of molecules present in the container will be (a) 6.022 1023 (c) 2 mole (b) 1.2044 1023 (d) 6.023 1024

1. 2.

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PHYSICAL CHEMISTRY
27) A mixture containing 100 g H2 and 100 g O2 is ignited so that water is formed according to the reaction, 2H2 + O2 2H2O; How much water will be formed : (a) 113 g (c) 25 g 28) (b) 50 g (d) 200 g 36)

By: Shailendra Kumar

(b) CH3COOH and C2H5OH (c) HCOOCH3 and C12H22O11 (d) C6H12O6 and C12H22O11 On analysis a certain compound was found to contain iodine and oxygen in the ratio 254 g of iodine and 80 g of oxygen. The atomic mass of iodine is 127 and that of oxygen is 16. Which is the formula of the compound : (a) IO (c) I5O2 37) (a) 48 (c) 24 38) (b) I2O (d) I2O5 (b) 32 (d) 16

5 mL of N HCl, 20 mL of N/2 H2SO4 and 30 mL of N/3 HNO3 are mixed together and volume made one litre. The normality of the resulting solution is : (a) N/5 (c) N/20 (b) N/10 (d) N/40

The vapour density of pure ozone would be :

29)

1000 g aqueous solution of CaCO3 contains 10 g of calcium carbonate. Concentration of solution is : (a) 10 ppm (c) 1000 ppm (b) 100 ppm (d) 10000 ppm

30)

1.0 g of pure calcium carbonate was found to require 50 mL of dilute HCl for complete reactions. The strength of the HCl solution is given by : (a) 4 N (c) 0.4 N (b) 2 N (d) 0.2 N 39)

The haemoglobin from the red blood corpuscles of most mammals contains approximately 0.33% of iron by weight. The molecular weight of haemoglobin as 67,200. The number of iron atoms in each molecule of haemoglobin is (atomic weight of iron = 56 ) : (a) 2 (c) 4 (b) 3 (d) 5

31)

What will be the normality of a solution obtained by mixing 0.45 N and 0.60 N NaOH in the ratio 2 : 1 by volume : (a) 0.4 N (c) 1.05 N (b) 0.5 N (d) 0.15 N 40)

A person has as many as notes as number of oxygen atoms in 24.8g Na 2 S 2 O 3 .5H 2 O (m.wt. = 248.0). A note counting machine counts 60 million notes per day. How much day would be taken to count these notes : (a) 1017 (c) 1015 (b) 1010 (d) 1012

32)

100 mL each of 0.5 N NaOH, N/5 HCl and N/10 H2SO4 are mixed together. The resulting solution will be : (a) Acidic (c) alkaline (b) Neutral (d) None of these (b) 50 (d) 18

To what extent must a given solution containing 40 mg AgNO3 per mL be diluted to yield a solution containing 16 mg AgNO3 per mL : (a) Each mL must be diluted to 2.5 mL (b) To each mL of solution 2.5 mL of water should be added (c) To 1.5 mL of solution 2 mL of water should be added (d) To 1.5 mL of solution 1.5 mL of water should be added

33)

The molarity of pure water is : (a) 55.6 (c) 100

34)

H3PO4 is a tribasic acid and one of its salts is NaH2PO4. What volume of 1 M NaOH should be added to 12 g NaH2PO4 (mol. wt. 120) to exactly convert it into Na3PO4: (a) 100 mL (c) 200 mL (b) 300 mL (d) 80 mL

41)

H2O2 solution used for hair bleaching is sold as a solution of approximately 5.0 g H2O2 per 100 mL of the solution. The molecular weight of H2O2 is 34. The molarity of this solution is approximately : (a) 3.0 (c) 0.15 (b) 1.5 (d) 4.0

35)

The pair of species having same percentage of carbon is : (a) CH3COOH and C6H12O6

1. 2.

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PHYSICAL CHEMISTRY
42) The vapour density of a volatile chloride of a metal is 95 and the specific heat of the metal is 0.13 cal/g. The equivalent weight of the metal will be approximately: (a) 6 (c) 18 43) (b) 12 (d) 24 51)

By: Shailendra Kumar

Mixing up of equal volumes of 0.1M NaOH and 0.1 M CH3COOH yields a solution which is : (a) Basic (c) Neutral 52) (b) Acidic (d) None

If 250 mL of a solution contains 24.5 g H2SO4, the molarity and normality respectively are : (a) 1 M, 2 N (c) 0.5 M, 1 N (b) 1 M, 0.5 M (d) 2 M, 1 N

If 20% nitrogen is present in a compound, its minimum molecular weight will be : (a) 144 (c) 100 (b) 28 (d) 70 53)

44)

The specific heat of a metal is 0.11 cal/g and its equivalent weight is 18.61. Its exact atomic weight is : (a) 58.2 (c) 55.83 (b) 29.1 (d) 27.91 54)

0.5 mole of H2SO4 is mixed with 0.2 mole of Ca(OH)2. The maximum number of mole of CaSO4 formed is : (a) 0.2 (c) 0.4 (b) 0.5 (d) 1.5

45)

Concentration of HCl is 10N. 100 mL of 1N HCl can be obtained by diluting : (a) 10 mL of conc. HCl to 100 mL (b) 20 mL of conc. HCl to 100 mL (c) 100 mL of conc. HCl to 200 mL (d) 100 mL of conc. HCl to 100 mL 55)

An aqueous solution of urea containing 18 g urea in 1500 cm3 of solution has a density of 1.052 g/ cm3. If the molecular weight of urea is 60, then the molality of solution is : (a) 0.2 (c) 0.064 (b) 0.192 (d) 1.2

The amount of anhydrous Na2CO3 present in 250 mL of 0.25 M solution is : (a) 6.625 g (c) 66.25 g (b) 6.0 g (d) 6.225 g (b) 6.02 1023 g (d) None (b) 0.2 (d) 1

46)

The normality of a solution containing 60g of CH3COOH per litre is : (a) 1 N (c) 0.5 N (b) 2 N (d) 1.5 N 57) 56)

Weight of a single molecule of water is : (a) 3.0 1023 g (c) 6.02 1023 g (a) 0.02 (c) 0.1

47)

10 mL of concentrated H2SO4 (18M) is diluted to one litre. The approximate strength of the dilute acid is : (a) 18 M (c) 0.18 M (b) 180 M (d) 1.8 M

The normality of 1% (wt./vol.) H2SO4 is nearly :

48)

A 5 M solution of H2SO4 is diluted from one litre to a volume of 10 litre. The normality of this solution is : (a) 1 N (c) 0.5 N (b) 2 N (d) 5 N

58)

The volume of 0.25 M H3PO4 required to neutralise 25 mL of 0.03 M Ca(OH)2 is : (a) 1.32 mL (c) 26.4 mL (b) 13.2 mL (d) 2.0 mL

59)

49)

The volume occupied by one molecule of water (density 1g cm3) is : (a) 18 cm3 (c) 6.023 1023 cm3 (b) 22400 cm3 (d) 3.0 1023 cm3

How many mole of atoms are in a mole of CH3COOH molecule : (a) 2 mole of C atoms, 4 mole of H atoms, 2 mole of O atoms (b) 1 mole of C atom, 2 mole of H atoms, 1mole of O atom (c) 2 mole of C atoms, 3 mole of H atoms, 2 mole of O atoms (d) None

50)

Sulphur forms the chlorides S2Cl2 and SCl2. The equivalent mass of sulphur in SCl2 is 16. The equivalent mass of sulphur in S2Cl2 is : (a) 8 (c) 64 (b) 16 (d) 32

1. 2.

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PHYSICAL CHEMISTRY
60) Equal volumes of 0.1 M AgNO3 and 0.2 M NaCl are mixed. The concentration of NO3 ions in the mixture will be : (a) 0.1 M (c) 0.2 M 61) (b) 0.05 M (d) 0.15 M 71)

By: Shailendra Kumar

(a) 12.25 litre (c) 1 litre 70 (a) 6.02 1023 (c) 0.6022 1023 (b) 4 litre (d) 3 litre (b) 3.011 1023 (d) 60.22 1023

Number of electrons in 1.8 mL of H2O is :

1.5 litre of a solution of normality N and 2.5 litre of 2M HCl are mixed together. The resultant solution had a normality 5. The value of N is : (a) 6 (c) 8 (b) 10 (d) 4

The weight of 350 mL of a diatomic gas at 0C and 2 atm pressure is 1 g. The weight of one atom is : (a) 16/N (c) 16 N (b) 32/N (d) 32 N (N is the Av. no.)
22

62)

The molality of 15% (wt./vol.) solution of H2SO4 of density 1.1 g/cm3 is approximately : (a) 1.2 (c) 1.8 (b) 1.4 (d) 1.6

72)

6.022 10 molecules of N2 at NTP will occupy a volume of : (a) 22.4 litre (c) 6.02 litre (b) 2.24 litre (d) 6.02 mL

63)

100 mL of 0.3 N HCl solution were mixed with 200 mL of 0.6 N H2SO4 solution. The final acidic normality is : (a) 0.9 N (c) 0.5 N (b) 0.6 N (d) 0.4 N

73)

22.4 litre of water vapour at NTP, when condensed to water, occupies an approximate volume of : (a) 18 litre (c) 1 mL (b) 1 litre (d) 18 mL

64)

On dissolving 1 mole each of the following acids in 1 litre water, the acid which do not give a solution of 1 N strength is : (a) HCl (c) HNO3 (b) HClO4 (d) H3PO4

74)

If 0.5 mole of BaCl2 is mixed with 0.2 mole of Na 3PO 4 the maximum number of mole of Ba3(PO4)2 that can be formed is : (a) 0.7 (c) 0.30 (b) 0.5 (d) 0.1

65)

The density of NH4OH solution is 0.6 g/mL. It contains 34% by weight of NH4OH. Calculate the normality of the solution : (a) 4.8 N (c) 0.5 N (b) 10 N (d) 5.8 N

75)

Number of O2 molecules present in one litre flask at pressure 7.6 1010mm of Hg and at 0C are : (a) 2.69 1010 (c) 2.69 109 (b) 2.69 1011 (d) 2.69 1012

76)

66)

The reaction, 2C + O2 2CO2 is carried out by taking 24 g carbon and 96 g O2. Which one is limiting reagent : (a) C (c) CO2 (b) O2 (d) None 77)

10 g of hydrofluoric acid gas occupies 5.6 litre of volume at STP. If the empirical formula of the gas is HF, then its molecular formula in the gaseous state will be : (a) HF (c) H3F3 (b) H2F2 (d) H4F4

67)

The highest mass corresponds to which of the following : (a) 1 molecule of O2 (b) 1 1023 g mole of O2 (c) An O2 ion (d) 1 mole of O2

At STP 5.6 litre of a gas weight 60 g. The vapour density of gas is : (a) 60 (c) 30 (b) 120 (d) 240

68)

Density of air at NTP is 0.001293 g/mL. Its vapour density is : (a) 0.001293 (c) 14.48 (b) 1.293 (d) Cant be calculated

78)

A metal oxide has the formula Z2O3. It can be reduced by hydrogen to give free metal and water. 0.1596 g of the metal oxide requires 6 mg of hydrogen for complete reduction. The atomic weight of the metal is : (a) 27.90 (c) 79.80 (b) 159.60 (d) 55.80 Page No.: 5

69)

The volume of oxygen required for complete oxidation of 2.0 litre methane at NTP is :

1. 2.

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PHYSICAL CHEMISTRY
79) An oxide of a metal (M) contains 40% by mass of oxygen. Metal (M) has atomic mass of 24. The empirical formula of the oxide is : (a) M2O (c) M2O2 80) (b) MO (d) M3O4 86)

By: Shailendra Kumar

One g of a mixture of Na2CO3 and NaHCO3 consumes y equivalent of HCl for complete neutralisation. One g of the mixture is strongly heated, then cooled and the residue treated with HCl. How many equivalent of HCl would be required for complete neutralisation : (a) 2y equivalent 87) (b) y equivalent (c) 3y/4 equivalent (d) 3y/2 equivalent A partially dried clay mineral contains 8% water. The original sample contained 12% water and 45% silica. The % of silica in the partially dried sample is nearly : (a) 50% (c) 55% 88) (b) 49% (d) 47%

0.52 g of a dibasic acid required 100 mL of 0.1 N NaOH for complete neutralisation. The equivalent weight of acid is : (a) 26 (c) 104 (b) 52 (d) 156

81)

34 g of hydrogen peroxide is present in 1120 mL of solution. This solution is called : (a) 10 vol solution (c) 30 vol solution (b) 20 vol solution (d) 32 vol solution

82)

Polyethylene can be produced from calcium carbide according to the following sequence of reactions; CaC2 + H2O CaO + HC CH nHC CH + nH2 ( CH2 CH2 )n The mass of polyethylene which can be produced from 20.0 kg of CaC2 is : (a) 6.75 kg (c) 8.75 kg (b) 7.75 kg (d) 9.75 kg 89)

One mole of a mixture of CO and CO2 requires exactly 20 g of NaOH in solution for complete conversion of all the CO2 into Na2CO3. How much NaOH would it require for cinversion into Na2CO3 if the mixture(one mole) is completely oxidised to CO2 : (a) 60 g (c) 40 g (b) 80 g (d) 20 g

A solution of HCl containing 0.03659 g/mL and another solution of acetic acid containing 0.04509 g/mL, then : (a) NHCl is more (b) NCH
3COOH

83)

A solution contains Na2CO3 and NaHCO3. 10 mL of the solution required 2.5 mL of 0.1 M H2SO4 for neutralisation using phenolphthalein as indicator. Methyl orange is then added when a further 2.5 mL of 0.2 M H2SO4 was required. The amount of Na2CO3 and NaHCO3 in 1 litre of the solution is : (a) 5.3 g and 4.2 g (b) 3.3 g and 6.2 g (c) 4.2 g and 5.3 g (d) 6.2 g and 3.3 g

is more

(c) Both have same N (d) None of these

84)

0.5 g of fuming H2SO4 (Oleum) is diluted with water. This solution is completely neutralised by 26.7 mL of 0.4 N NaOH. The precentage of free SO3 in the sample is : (a) 30.6% (c) 20.6% (b) 40.6% (d) 50%

85)

0.7 g of NaCO3.xH2O were dissolved in water and the volume was made to 100 mL, 20 mL of this solution required 19.8 mL of N/10 HCl for complete neutralisation. The value of x is : (a) 7 (c) 2 (b) 3 (d) 5

1. 2.

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