Title:

Chapter 16(1) Total score adjusted by 0.0 Maximum possible

Total score: 10.75/12 = 89.5833% score: 12

1.

Average Rate 2
The compound AX2 decomposes according to the equation, 2 AX2(g) => 2 AX(g) + X2(g). In one experiment, [AX2] was measured at various times, and these data recorded: Time (s) [AX2] mol/L 0 2.0 6.0 8.0 10.0 20.0 0.0500 0.0448 0.0300 0.0249 0.0209 0.0088

What is the average rate from 6.0 to 20.0 seconds in mol / L s? Use 3 significant figures! [don't include units in your answer; if you want to use scientific notation, use the E format. e.g., 0.0011 is 1.1E-3 Student Response Correct Answer Equals 0.00151 (100%) Equals 0.0015 (100%) Equals 1.5E-3 (100%) 100% Equals 1.51E-3 (100%) Equals .00151 (100%) Equals .0015 (100%) Value

1. 1.5E-3

Score: 1/1

2.

Relative Rates of Substances 3

Consider the reaction, 2 D(g) + 3 E(g) + F(g) => 2 G(g) + H(g) When [D] is decreasing at 0.55 mol/Ls, how quickly is [G] increasing? Student Response Value 100% 0.550 Answer: 0.55 Score: 1/1 Correct Answer

3.

Rate Law General 3

What is the reaction order of Br- for a reaction with the following rate law? Rate = k[BrO3-][Br-][H+]2 Student Response 1. First 2. Second 3. Fifth 4. Fourth 5. Third Score: 1/1 Value 100% Correct Answer

4.

Known Rate Law, Change Conc 47

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2 By what factor does the rate change if the concentration of BrO3- is decreased by a factor of 2, that of Br- is doubled and that of H+ is doubled ? Student Response 1. 4 Score: 1/1 Correct Answer Equals 4 (100%) 100% Equals 4/1 (100%) Value

5.

Known Rate Law, Change Conc 9

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2 By what factor does the rate change if the concentration of BrO3- is decreased by a factor of 4? Just put in the number as a whole number or fraction. Student Response 1. 0.25 Score: 1/1 Correct Answer Equals 1/4 (100%) 100% Equals 0.25 (100%) Equals .25 (100%) Value

6.

Determine Rate Law 39

Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is 1.----- order in A, 2.----- order in B, 3.----- order in C and 4.----- order overall. USE WORDS TO FILL IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! : Experiment Initial conc Initial conc Initial conc Initial rate, of A, mol/L of B, mol/L of C, mol/L mol/L.s 1 2 3 4 0.1 0.2 0.3 0.4 Student Response first fisrt second fourth 0.2 0.2 0.4 0.6 Value 25% 0% 25% 25% 0.4 0.4 0.4 0.2 2 x 10-3 4 x 10-3 1.2 x 10-2 6.0 x 10-3

1. 2. 3. 4.

Correct Answer Equals first (25%) Equals first (25%) Equals second (25%) Equals fourth (25%)

Score: 0.75/1

7.

Determine Rate Law 3

For the reaction, 4 A(g) + 3 B(g) => 2 C(g), the following data were obtained at constant temperature. Experiment Initial [A], Initial [B], Initial Rate, mol/L mol/L M/min 1 2 3 4 0.200 0.400 0.200 0.400 0.150 0.150 0.300 0.300 5.00 10.0 20.0 40.0

Which of the following is the correct rate law for the reaction? Student Response 1. Rate = k[A][B] 2. Rate = k[A]2[B]2 3. Rate = k[A][B] 4. Rate = k[A]2[B] Score: 1/1
2

Value 100%

Correct Answer

8.

Calculate k from Rate Law 19

For the reaction, 4 A(g) + 3 B(g) => 4 C(g), the following data were obtained at constant temperature. Experiment Initial [A], Initial [B], Initial Rate, mol/L mol/L M/min 1 2 3 0.15 0.30 0.30 0.22 0.22 0.44 2.7 x 10-2 5.4 x 10-2 2.16 x 10-1 7.3 x 10-1

4 0.45 0.66 Calculate the value of k to 3 significant figures. Student Response 1. 3.72 Score: 1/1 Value

Correct Answer Equals 3.72 (100%) 100% Equals 3.72E0 (100%)

9.

Units of k 0
Which of the following would be a reasonable unit for the rate constant of a zero order reaction? Student Response 1. mol/L.sec 2. mol/sec 3. 1/sec 4. L/mol.sec 5. no units Score: 1/1 Value 100% Correct Answer

10.

IRL 2 k 1
The reaction, AB => A(g) + B(g), has a rate law, rate = k[AB]2. Calculate the rate constant in L/mol.s if it takes 13 seconds to reach an [AB] of 0.081 mol/L from an initial concentration of 0.265 mol/L. (If necessary, write scientific notation using the E-format. e.g., 0.0111 is 1.11E-2... NO SPACES!!!!) Student Response Value 100% 0.659 Answer: 6.59E-1 Correct Answer

Score: 1/1

11.

IRL 1 t 8
A reaction has a rate constant of 0.00714 sec-1, how long will it take (in minutes) until 0.484 mol/L of the compound is left, if there was 0.586 mol/L at the start? (give answer to 3 sig figs using E notation)? Student Response Value 0% 0.446 Answer: 2.68E1 Score: 0/1 Correct Answer

12.

IRL 1 t 5
A reaction has a rate constant of 0.0604 sec-1, how long will it take (in seconds) until 0.500 mol/L of the compound is left, if there was 0.639 mol/L at the start? (give answer to 3 sig figs using E notation)? Student Response Value 100% 4.061 Answer: 4.06 Score: 1/1 Correct Answer

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Title: Started: Submitted: Time spent: Chapter 16(1) February 11, 2012 8:40 PM February 11, 2012 9:40 PM 01:00:11 Total score adjusted by 0.0 Maximum possible score:

Total score: 7/12 = 58.3333% 12

1.

Average Rate 1
The compound AX2 decomposes according to the equation, 2 AX2(g) => 2 AX(g) + X2(g). In one experiment, [AX2] was measured at various times, and these data recorded: Time (s) [AX2] mol/L 0 0.0500

2.0 6.0 8.0 10.0 20.0

0.0448 0.0300 0.0249 0.0209 0.0088

What is the average rate from 8.0 to 20.0 seconds in mol / L s? Use 3 sig figs. [don't include units in your answer; if you want to use scientific notation, use the E format. e.g., 0.0011 is 1.1E-3 Student Response Correct Answer Equals 0.00134 (100%) Equals 0.0013 (100%) Equals 1.3E-3 (100%) 100% Equals 1.34E-3 (100%) Equals .00134 (100%) Equals .0013 (100%) Equals .001341 (100%) Value

1. 1.3E-3

Score: 1/1

2.

Relative Rates of Substances 4

Consider the reaction, 2 D(g) + 3 E(g) + F(g) => 2 G(g) + H(g) When [D] is decreasing at 0.99 mol/Ls, how quickly is [H] increasing? Student Response Value 100% 0.495 Answer: 0.495 Score: 1/1 Correct Answer

3.

Rate Law General 7

What is the overall reaction order for H+ in a reaction with the following rate law? Rate = k[Cl2][H+]2[CO]2 Student Response 1. Second 2. First 3. Fifth 4. Third Value 100% Correct Answer

5. Fourth Score: 1/1

4.

Known Rate Law, Change Conc 48

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2 By what factor does the rate change if the concentration of BrO3- is decreased by a factor of 2, that of Br- is doubled and that of H+ is decreased by a factor of 2? Student Response 1. 0.25 Score: 1/1 Correct Answer Equals 0.25 (100%) 100% Equals 1/4 (100%) Equals .25 (100%) Value

5.

Known Rate Law Change Conc 56

For the reaction, A(g) + B(g) => AB(g), the rate is 0.783 mol/L.s when the initial concentrations of both A and B are 2.00 mol/L. If the reaction is first order in A and second order in B, what is the rate when the initial concentration of A = 2.45 mol/L and that of B = 3.85 mol/L (give answers in E notation to 3 significant figures) Student Response Value 100% 3.55 Answer: 3.55 Score: 1/1 Correct Answer

6.

Determine Rate Law 17

For the reaction, 4 A(g) + 3 B(g) => 4 C(g), the following data were obtained at constant temperature. Experiment Initial [A], Initial [B], Initial Rate, mol/L mol/L M/min 1 2 3 4 0.15 0.30 0.30 0.45 0.22 0.22 0.44 0.66 2.7 x 10-2 5.4 x 10-2 5.4 x 10-2 8.1 x 10-2

Which of the following is the correct rate law for the reaction?

Student Response 1. Rate = k[A][B] 2. Rate = k[A]2[B] 3. Rate = k[A]2[B]2 4. Rate = k[A][B]2 5. Rate = k[A] Score: 1/1

Value

Correct Answer

100%

7.

Determine Rate Law 29

Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is 1.----- order in A, 2.----- order in B, 3.----- order in C and 4.----- order overall. USE WORDS TO FILL IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! : Experiment Initial conc Initial conc Initial conc Initial rate, of A, mol/L of B, mol/L of C, mol/L mol/L.s 1 2 3 4 0.1 0.2 0.3 0.4 Student Response not answered not answered not answered not answered 0.1 0.3 0.1 0.3 Value 0% 0% 0% 0% 0.2 0.2 0.2 0.6 2 x 10-3 1.2 x 10-2 6 x 10-3 2.4 x 10-2

1. 2. 3. 4.

Correct Answer Equals first (25%) Equals first (25%) Equals zero (25%) Equals second (25%)

Score: 0/1

8.

Calculate k from Rate Law 28

Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F Experiment Initial conc Initial conc Initial conc Initial rate, of A, mol/L of B, mol/L of C, mol/L mol/L.s 1 2 3 0.1 0.2 0.3 0.1 0.3 0.1 0.2 0.2 0.2 2 x 10-3 2 x 10-3 2 x 10-3 4 x 10-3

4 0.4 0.3 0.4 Calculate the value of k to 3 significant figures.

Student Response 1. 0.01 Score: 0/1

Value 0%

Correct Answer Equals 0.0100 (100%) Equals .0100 (100%) Equals 1.00E-2 (100%)

9.

Units of k 0
Which of the following would be a reasonable unit for the rate constant of a zero order reaction? Student Response 1. mol/L.sec 2. mol/sec 3. 1/sec 4. L/mol.sec 5. no units Score: 0/1 Value Correct Answer

0%

10.

IRL 1 c 2
A reaction has a rate constant of 0.0200 sec-1, how much of the compound (in mol/L) is left after 6.42 sec, if there was 0.346 mol/L at the start? (give answer to 3 sig figs using E notation)? Student Response Value 100% 0.304 Answer: 3.04E-1 Score: 1/1 Correct Answer

11.

IRL 1 t 1
In a first order decomposition in which the rate constant is 0.0866 sec-1, how long will it take (in seconds) until 0.399 mol/L of the compound is left, if there was 0.757 mol/L at the start? (give answer to 3 sig figs using E notation)? Student Response Value 0% 7.395 Answer: not answered Score: 0/1 Correct Answer

12.

IRL 2 c 1
The reaction, AB => A(g) + B(g), has a rate law, rate = k[AB]2 and k = 0.063 L/mol.sec. What will be the concentration of [AB] after 193 seconds from an initial concentration of 0.648 mol/L. (Use scientific notation using the E-format. e.g., 0.0111 is 1.11E-2... NO SPACES!!!!) Student Response Value 0% 0.073 Answer: not answered Score: 0/1 Correct Answer