Redox- Cambridge + answers *15. 25.0 cm3 of a solution of X2O5 of concentration 0.

100 mol dm is reduced by sulphur dioxide to a lower oxidation state. To reoxidised X to its original oxidation number, this required 50.00 cm3 of 0.0200 mol dm potassium manganate (VII) in acidified medium. To what oxidation number was X reduced to by sulphur dioxide? [Ans: +4] 21. 10.0 cm3 of 0.100 mol dm aqueous iron (II) sulphate is titrated against 88n/3 0.0250 mol dm aqueous potassium permanganate (VII) in the presence of both hydrogen ions and fluoride ions. It is found that exactly 10.00 cm3 of manganate (VII) solution is required to reach the endpoint. What is the oxidation number of manganese at the endpoint? [Ans: +3] 1. Sodium thiosulphate is used in the textile industry to remove excess chlorine from bleaching processes by reducing it to chloride ions. S2O3 + 4Cl2 + 5H2O 2HSO4 + 8H + 8Cl In this reaction, how many moles of electrons are supplied per mole of thiosulphate? a. 1 b. 2 c. 4 d.8 95s

3c. 0.013 mol of a vanadium complex was dissolved in 100 ml of water. 99n1 To oxidize all the vanadium to the +5 state, 20.8 ml of 0.025 mol dm KMnO4 was needed for 10 ml of the solution. Calculate the original oxidation number of the vanadium. [3] 13 In an experiment, 50.0 cm3 of a 0.10 mol dm 3 solution of a metallic salt reacted exactly with 25.0 cm3 of 0.10 mol dm 3 aqueous sodium sulphite. The half-equation for oxidation of sulphite ion is shown below. If the original oxidation number of the metal in the salt was +3, what would be the new oxidation number of the metal? A +1 9. 25cm of 0.20 mol dm TiNO3 needs 25cm of 0.10 mol dm acidified KMnO4 solution to oxidise it to Ti. What is the oxidation state of the manganese after the reaction? 3 18. Tin (II) ions can be oxidised to tin (IV) ions by iodate ions, in the presence of HCl: Sn Sn +2e In an experiment 25.0 cm3 of 0.025 mol dm of IO (aq) was found to react with 31.20 cm3 of 0.04 mol dm Sn in the presence of excess hydrochloric acid. (a) Determine the number of moles of Sn that reacted with 1 mole of IO. (b) The possible product from the reduction of IO3 can be ICl3, ICl, I2 or I. Which is the actual product in the above reaction? s02, c07n9

B +2

C +4

D +5 s07