Pengukuran Angka Ketidakpastian (Uncertainty) dari analisis komposisi kimia baja (SS) dg Instru

Data SSR kurva kalibrasi standar Ni AAS trial version

No
1
2
3
4
5
6

Xi

SSR

1.1964E-06

SSR
(n-2) Degree of Freedom

0.003913128
0.008628366
0.023604328
0.095875072
0.21340427
0.34542636
4.0

Var=ssr/
nilai k (dari tabel)

0.08635659
2.78

S=var
u5 (S*k)

0.293864918

0
2
3
5
10
15

Yi [ ] ppm
0.0007092
0.03351
0.04842
0.07832
0.1572
0.2324

a
0.001803
0.001803
0.001803
0.001803
0.001803
0.001803

residual

ri = yi-(a+b.xi)

residual

0.816944472

Data SSR Kurva Kalibrasi Standar Carbon Spark OES

No
1
2
3
4
5

Xi
0.00011
0.3275
0.655
0.983
1.30488

Yi [ ] %
0.02978
0.28795
0.54619
0.8112
0.98149

a
0.05094
0.05094
0.05094
0.05094
0.05094

SSR

0.000444355

residual

ri = yi-(a+b.xi)

SSR

0.226603918
0.947290796
2.183546723
3.5452769
6.903162693

residual

(n-2) Degree of Freedom

Var=ssr/
nilai k (dari tabel)
S=var
u5 (S*K)

3
2.301054231
3.18
1.516922619
4.823813927

Data SSR Kurva Kalibrasi Standar Sulfur Spark OES

No
1
2
3
4
5

Xi
0.0005
0.004
0.0104
0.015
0.0177

Yi [ ] %
2.42
3.576
5.939
7.648
8.251

a
2.2474
2.2474
2.2474
2.2474
2.2474

SSR

0.120363096

residual

ri = yi-(a+b.xi)

SSR
(n-2)Degree of Freedom

7.41620385
53.54937842
113.0099859
36.04321296
210.1391442
3

Var=ssr/
nilai k (dari tabel)
S=var
u5 (S*k)

70.04638141
3.18
8.369371626
26.61460177

residual

Data SSR Kurva Kalibrasi Standar Silicon Spark OES

No
1
2
3
4
5

SSR

Xi
0.0008
0.0103
0.0273
0.0515
0.0563

Yi [ ] %
0.0370
0.0530
0.0830
0.1120
0.1290

a
0.0369
0.0369
0.0369
0.0369
0.0369

1.83895E-06

residual

0.001041484
0.007914545

ri = yi-(a+b.xi)

SSR
(n-2)Degree of Freedom

0.024323568
0.032579033
0.06586047
3.0

Var=ssr/
nilai k (dari tabel)
S=var
u5 (S*k)

0.02195349
3.18
0.148167102
0.471171383

residual

Data SSR Kurva Kalibrasi Standar Krom Spark OES

No
1
2
3
4
5

Xi
0.00057
0.01589
0.02942
0.04603
0.05844

Yi [ ] %
0.03485
0.06397
0.08978
0.11334
0.14968

a
0.0330176
0.0330176
0.0330176
0.0330176
0.0330176

SSR

8.51873E-06

residual

ri = yi-(a+b.xi)

SSR
(n-2)Degree of Freedom

0.003749726
0.01273061
0.028239042
0.052000101
0.096727998
3.0

Var=SSR/
nilai k (dari tabel)
S=var
u5 (S*k)

0.032242666
3.18
0.17956243
0.571008526

residual

Data SSR Kurva Kalibrasi Standar Mangan Spark OES

No
1
2
3
4
5

Xi
0.00093
0.00331
0.01121
0.01659
0.02207

Yi [ ] %
2.43590
3.30870
6.39590
8.32750
10.31700

a
2.10643
2.10643
2.10643
2.10643
2.10643

SSR

0.459087487

residual

ri = yi-(a+b.xi)

SSR
(n-2)Degree of Freedom

5.959314844
71.99970391
154.5184634
271.2989885
504.2355581
3.0

Var=ssr/
nilai k (dari tabel)
S=var
u5 (S*k)

168.0785194
3.18
12.96450999
41.22714178

IPB 2009

Derajat Kebebasan
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20

t
12,7
4,30
3,18
2,78
2,57
2,45
2,36
2,31
2,26
2,23
2,20
2,18
2,16
2,14
2,13
2,12
2,11
2,10
2,09
2,09

residual

25
30
35
40
45
50

2,06
2,04
2,03
2,02
2,01
2,01

posisi kimia baja (SS) dg Instrumen Spark OES

0.25

0.1572

0.15
0.1
0.07832
0.05

0.04842
0.03351

-0.0010938

0
0

0.000859
0.000345
-0.000603
0.001157
-0.000763
-9.88E-05

0.0007092

10

15

20

Concentration (ppm)

1.2
y = 0.737x + 0.050
R = 0.9962

1
Intensity

b
0.72983
0.72983
0.72983
0.72983
0.72983

0.2324

y = 0.015424x + 0.001803
R = 0.9998

0.2
Absorbansi

b
0.015424
0.015424
0.015424
0.015424
0.015424
0.015424

0.8
0.6
0.4
0.2

-0.021240281
-0.002009325
0.01721135
0.04283711
-0.02179057
0.015008283

0
0

0.2

0.4

0.6

0.8

Concentration (%)

1.2

1.4

9
y = 348.6x + 2.247
R = 0.9974

8
7
Intensity

b
348.6677
348.6677
348.6677
348.6677
348.6677

-0.0660708
0.06545592
0.1705845
-0.16781829
0.00041748

8.251

6
5.939

5
4
3

3.576

-0.00173385

7.648

2.42

1
0
0

0.005

0.01

0.015

0.02

Concentration (%)

rk OES

0.14

0.112

0.1
Intensity

1.5701
1.5701
1.5701
1.5701
1.5701

0.129

y = 1.569x + 0.0369
R = 0.9902

0.12

0.083

0.08
0.06

0.053

0.04

0.037

0.02

-0.00115608
-7.203E-05
0.00323627

0
0

0.01

0.02

0.03

0.04

Concentration (%)

0.05

0.06

Concentration (%)

-0.00576015
0.00370337
-4.862E-05

0.16
y = 1.905765x + 0.0330176
R = 0.9892

0.14

0.11334

0.1
0.08978

0.08
0.06397

0.06
0.04

0.000746114

0.02

0.000669794
0.000694794
-0.007399963
0.005289493
2.3225E-07

0.03485

0.01

0.02

0.03

0.04

0.05

0.06

0.07

Concentration (%)

ark OES

12

10

y = 374.29027x + 2.10643
R = 0.9997

10.317

8
Intensity

374.29027
374.29027
374.29027
374.29027
374.29027

0.14968

0.12
Intensity

b
1.905765
1.905765
1.905765
1.905765
1.905765

6
4

8.3275
6.3959

Intensity
4

3.3087
2.4359

-0.018619951
-0.036630794
0.093676073
0.011594421
-0.050016259
3.4903E-06

0
0

0.005

0.01

0.015

Concentration (%)

0.02

0.025

20

1.4

0.02

0.129
0.112

0.06

0.07

10.317

0.025

Data kalkulasi SSR pada Standar Nikel, Mangan, Cromium 316 L

Data SSR kurva kalibrasi standar Ni AAS trial version
No
Xi
Yi [ ] ppm
a
b
1
0
0.0007092
0.001803
0.015424
2
2
0.03351
0.001803
0.015424
3
3
0.04842
0.001803
0.015424
4
5
0.07832
0.001803
0.015424
5
10
0.1572
0.001803
0.015424
6
15
0.2324
0.001803
0.015424

SSR

1.2E-06

residual

ri = yi-(a+b.xi)

SSR

0.00391
0.00863
0.0236
0.09588
0.2134
0.34543

(n-2) Degree of Freedom

Var=ssr/
nilai k (dari tabel)

0.08636
2.78
0.29386

u5 (S*k)

0.81694

SSR

0.000859
0.000345
-0.000603
0.001157
-0.000763
-9.88E-05

4.0

S=var

No
1
2
3
4
5
6

residual

-0.0010938

Data SSR kurva kalibrasi standar Mn AAS trial version

Xi
Yi [ ] ppm
a
b
0
-0.00754
0.0444
0.0748
2
0.1854
0.0444
0.0748
3
0.2844
0.0444
0.0748
5
0.4612
0.0444
0.0748
10
0.8491
0.0444
0.0748
15
0.0444
0.0748
1.1130

0.0027
0.08445

residual

ri = yi-(a+b.xi)

-0.05194
-0.0086

SSR
(n-2) Degree of Freedom

0.21567
0.62536
2.41088
4.79873
8.13778
4.00

Var=ssr/
nilai k (dari tabel)
S=var

2.03445
2.78
1.42634

u5 (S*k)

3.96523

No
1
2
3
4
5
6

SSR

Data SSR kurva kalibrasi standar Cr AAS trial version

Xi
Yi [ ] ppm
a
b
0
0.035375
0.025099
-0.00294
2
0.035375
0.025099
0.1078
3
0.035375
0.025099
0.1277
5
0.035375
0.025099
0.1688
10
0.035375
0.025099
0.2868
15
0.035375
0.025099
0.4025

0.00147

0.01504
0.0281
0.06704
0.25242
0.55296
SSR
0.91702
(n-2) Degree of Freedom
Var=ssr/
nilai k (dari tabel)
S=var

u5 (S*k)

residual

0.0156
0.0428
0.0567
-0.0534
0.00116

residual

ri = yi-(a+b.xi)

residual

-0.038315
0.022227
0.017028
0.00793
0.000435
-0.00936
-5.5E-05

0.25

Absorbans

0.2324

y = 0.015424x + 0.001803
R = 0.9998

0.2

0.1572

0.15
0.1
0.07832
0.05

0.04842
0.03351

0
0

0.0007092

10

15

20

Concentration (ppm)

1.4

y = 0.0748x + 0.0444
R = 0.9985

1.2

1.113

Absorbansi

1
0.8491

0.8
0.6
0.4612

0.4
0.2844
0.1854
0
-0.00754
0
2
4
-0.2
0.2

10

Konsentrasi standar Mn (ppm)

12

14

16

Konsentrasi standar Mn (ppm)

Kurva kalibrasi larutan standar Mangan

0.45
0.4

y = 0.025099x + 0.035375
R = 0.9609

0.35

0.4025

Absorbansi

0.3
0.25

0.2868

0.2
0.1688

0.15
0.1277

0.1
0.05
0
-0.05 0

0.1078
-0.00294

10

15

Konsentrasi standar Cr (ppm)

Kurva kalibrasi larutan standar Kromium

20

Data kalkulasi SSR pada Standar Nikel, Mangan, Cromium 304

Data SSR kurva kalibrasi standar Ni AAS trial version
No
Xi
Yi [ ] ppm
a
b
1
0 -0.00123
0.001546
0.014452
2
2
0.001546
0.014452
0.02942
3
3
0.001546
0.014452
0.04242
4
5
0.001546
0.014452
0.06854
5
10
0.001546
0.014452
0.1396
6
15
0.001546
0.014452
0.2178

SSR

7.7062E-06

residual

-0.002776

ri = yi-(a+b.xi)

SSR

0.00322374
0.00709469
0.01939168
0.07984807
0.18751845
0.29708433

-0.00103
-0.002482
-0.005266
-0.006466
-0.000526
-0.018546

(n-2) Degree of Freedom

Var=ssr/
nilai k (dari tabel)

4.0

0.07427108
2.78

S=var

0.27252721

u5 (S*k)

0.75762565

No
1
2
3
4
5
6

SSR

residual

Data SSR kurva kalibrasi standar Mn AAS trial version

Xi
Yi [ ] ppm
a
b
0 -0.00444
0.005515
0.042241
2
0.08416
0.005515
0.042241
3
0.1072
0.005515
0.042241
5
0.2101
0.005515
0.042241
10
0.4249
0.005515
0.042241
15
0.6234
0.005515
0.042241

9.9102E-05

residual

-0.009955

0.02661042

ri = yi-(a+b.xi)

-0.005837

0.05217021
0.17288132
0.70861882
1.56625225
SSR
2.52663213
(n-2) Degree of Freedom
4.00
Var=ssr/
nilai k (dari tabel)
S=var

0.63165803
2.78
0.79476917

u5 (S*k)

2.20945829

No
1
2
3
4
5
6

SSR

Data SSR kurva kalibrasi standar Cr AAS trial version

Xi
Yi [ ] ppm
a
b
0 0.008029
0.050439
0.028605
2
0.050439
0.028605
0.1056
3
0.050439
0.028605
0.1535
5
0.050439
0.028605
0.2313
10
0.050439
0.028605
0.3520
15
0.050439
0.028605
0.4534

0.00179861

0.01262724
0.03567414
0.10490214
0.34528669
0.69228391
SSR
1.19257273
(n-2) Degree of Freedom
Var=ssr/
nilai k (dari tabel)
S=var

u5 (S*k)

residual

-0.025038
-0.00662
-0.003025
-0.01573
-0.066205

residual

ri = yi-(a+b.xi)

residual

-0.04241
-0.002049
0.017246
0.037836
0.015511
-0.026114
2E-05

0.25

Absorbansi

0.2

y = 0.014452x - 0.001546
R = 0.9986

0.15

0.2178
0.1396

0.1
0.06854
0.04242
0.02942
0 -0.00123
0
5
-0.05
0.05

10

15

20

Konsentrasi standar Ni (ppm)

Kurva kalibrasi larutan standar Nikel

0.7
y = 0.042241x - 0.005515
R = 0.9980

0.6

0.6234

Absorbansi

0.5
0.4

0.4249

0.3
0.2101

0.2
0.1072

0.1

0.08416

0
-0.1

-0.00444
2

10

Konsentrasi standar Mn (ppm)

12

14

16

Konsentrasi standar Mn (ppm)

Kurva kalibrasi larutan standar Mangan

0.6
y = 0.028605x + 0.050439
R = 0.9977

Absorbansi

0.5
0.4

0.4534
0.352

0.3
0.2313

0.2

0.1535
0.1056
0.008029

0.1
0
0

10

15

Konsentrasi standar Cr (ppm)

Kurva kalibrasi larutan standar Kromium

20