Chm 13P-T

Problem Set No.1

1. A laboratory technician boils an unknown volatile sample of liquid at 56 degree C and atmospheric pressure. The volume of her flask is 2.0 L and when the liquid is gone, leaving only vapor, the mass of the gas is 3.23 g. What is the molecular weight of the gas? 2. What volume of hydrogen gas at STP is produced by dissolving one half mole of aluminum in sulfuric acid? 3. Calculate the weight of potassium chlorate that would be required to produce 29.52 liters of oxygen gas measured at 127 degree C and 760 torr. 4. A 0.72 gram sample, known to contain only calcium carbonate and barium carbonate, was heated until the carbonates were decomposed to oxides as indicated. After heating , the mass of the solid residue was 0.516 gram. What volume of carbon dioxide was measured at STP, was produced from the reaction?

5. A 4.52 g sample containing only calcium carbonate and magnesium carbonate was heated to decompose the carbonates . The liberated carbon dioxide occupied 1.36liters at 800 degree C under a pressure of 3.30 atmosphere. What mass of magnesium carbonate was contained in the original sample? 6. What volume of 12.6 M HCl must be added to enough water to prepare 5.0 liters of 3.0 M HCl? 7. What volume of 12.0 M nitric acid is required to prepare 900 mL of 2.0 M nitric acid? 8. How many grams of sucrose are needed to make 10.0 L of 3.0 M solution? 9. If 50 mL of 0.25 M nitric acid and 50 mL of 0.25 M potassium hydroxide are mixed, what is the molarity of the salt in the resulting solution?

10. If 35 mL of 2.0M sulfuric acid is mixed with 35 mL of 0.5M sodium hydroxide, how many moles of sulfuric cid remain after the completion of the reaction? 11. What volume of 0.123 M hydrochloric acid would react with 26.7 mL of 0.176 M sodium hydroxide? 12. Which of the following reactions are acid-base reactions according to the Brnsted-Lowry model? A. NH4+(aq) + H2O NH3(aq) + H3O+(aq) B. F-(aq) + H2O HF(aq) + OH-(aq) C. H2PO4-(aq) + OH-(aq) HPO42-(aq) + H2O a. 1 only b.2 only c.3 only d. 1 and 3 e. 1, 2, and 3 13. The species formed when a proton is removed from an acid is called the a. cation. b. conjugate base. c. conjugate acid. d. buffer. e. antacid.

14. What is the conjugate base of HBr? a. H+ b. Hc .Br+ d. Br e. Br15. What is the conjugate acid of ammonia? a. H+ b. Hc. NH4+ d. NH3 e. NH216. If the H+ concentration in a certain tap-water sample is 2.6 10-7 M, what is the OH- concentration? (Kw = 1.0 10-14) 17. If the OH- concentration in a bottle of an ammonia based cleaner is 7.2 10-5 M, what is the H+ concentration? (Kw = 1.0 10-14) 18. What is the pH of a solution prepared by diluting 0.35 mol HCl to a volume of 750 mL? a. -0.33 b. 0.33 c. 0.45 d. 0.58 e. 1.08

19. Which of the following solutions will have a pH of 3.0? a. 1 10-3 M CH3CO2H b. 1 10-3 M NH3 c. 1 10-3 M NH4+ d. 1 10-3 M HI 20. The pH of 0.650 M ammonium chloride, NH4Cl, is 4.74. What is the value of Ka for this acid? a. 2.8 10-10 b. 5.1 10-10 c. 3.3 10-5 d. 1.7 10-5 e. 6.7 10-3 21. The pH of 0.350 M benzoic acid, HC7H5O2, is 2.32. What is the pKa for this acid? a. 0.350 b. 1.38 c. 1.79 d. 2.32 e. 4.18
22. The pH of 0.400 M sodium nitrite, NaNO2, is 8.42. What is the Kb for this base? a. 1.7 10-11 b. 3.6 10-10 c. 3.8 10-9 d. 9.5 10-9 e. 8.8 10-7

23. A solution of 0.25 mol HF diluted to 1.0 L has a hydronium ion concentration of 1.3 10-2 M. What is the percent ionization of HF? a. 0.80 % b. 1.3% c. 4.2% d. 5.2% e. 31%
24. What is the pH of 0.66 M hypochlorous acid? HOCl(aq) + H2O OCl-(aq) + H3O+(aq) Ka = 2.8 10-8 a. 3.87 b. 4.02 c. 6.51 d. 7.55 e. 7.73

25. Ammonia is a weak base (Kb = 1.8 10-5). What is the pH of 1.2 M ammonia? a. 2.33 b. 4.74 c. 9.26 d. 10.14 e. 11.67