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Thermal oxidation ( µm vs.

minutes)
{100}
1000
1 DRY 1 WET

0
90
00
00

10

00
11

11

0
0.1 0.1

80
90
0
80
0.01 0.01

10 100 1000 1 10 100 1000

0.543 nm

Surface

1/4 down

{111} 1/2 down (face center)

3/4 down
{111}
(for {100} picture only)

(001)

Etch rate in KOH 2


Resistivity vs. dopant density

1 Boron

log( Ωcm)
0
44 gm in 100ml H 2O@ 85 C
(111) −1
{100} 1.4
{111} 0.0035
SiO 2 0.0014
Si 3N 4 not etched
µ /min (111) (101) −2
−3
14
Phosphorus

15 16 17 18 19

3
20

log(atoms/cm )

Available via anonymous ftp 0.543 nm


[100]
reduced by 10−100 (KOH).
Presence of boron reduces
etch rate in KOH and EDP.

from synergy.icsl.ucla.edu
Etching Si+Boron

(110)

in pub/crystal.i − ksjp
1019 /cm .3 At 10 20/cm 3
reduced by 100 (EDP)
No dependence below

(110)

0.543 2 nm
(010) (100) (010)
[100]
pister@ee.ucla.edu, 1/26/93
Etch rate in EDP
750 ml Ethylene Diamine
<100>

110
0.543 2 nm

120 gm Pyrocatechol
100 ml water @115C
{100} 0.75 (abc) specific plane
{111} 0.021 {abc} equivalent planes
SiO 2 0.0002 µ /min [abc] specific direction
<abc> equivalent directions
Si 3N 4 0.0001

Single crystal silicon


28.1
14 Si
3
density: 2.33 gm/cmo
melting point: 1415 C
band gap: 1.12 eV 2
electron mobility: 1350 2
cm /Vs
hole mobility: 480 cm /Vs
resistivity: 2.5 x 10 5 Ω−cm (intr.)
relative permitivity: 11.8 11
Young’s modulus: 1.9x10 Pa
thermal conductivity: 1.57 W/cm C o
The idea for the shape came from a similar yield strength: 7.0x10 9Pa

paper model that I saw once. I don’t know


who made that one. Perhaps Monsanto?
Most of the data comes from "Silicon as a mechanical
Material", by Peterson (Proc.IEEE, v70n5, 1982, pp.420−457).
This is an idraw generated PostScript file. Feel free to hack
Other data from "VLSI Technology", edited by Sze (McGraw−Hill) it up (physically and electronically) as much as you like, but
and "Solid State Electronic Devices", by Streetman (Prentice−Hall). please keep my name on it. Copyright Kris Pister 1993

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