Identification Essential Oil by Gc-Ms - Robert Adam1

IDEI{TTFICATION OF
ESSENTTALOtL COMPONE'NTSBY
GAS CHROMATOGRAPHY/
MASS SPECTROMETRY,4th Ed.
Dr. ROBERT P. ADAMS

Professor
Biology Department
Baylor University
BRITISH
LIBRARY
DOCUMENT
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CONTENTS =
=
Preface
vil
PART A GAS CHROMATOGRAPH/MASS SPECTROSCOPY
I. Introduction
I
II. Nomenclature
I =
III.Mass Spectrometry Consitlerations
2 -
A. Obtainingeuality Spectrafor Iclentification -
2 -
=
B. The Role of RetentionTimesin l.ibrary Searches a
J
Iv. operating conditions used for spectra Acquisition
v'
4
compatibility with Mass SpectrometerData systems
VI. Explanationsof Formats Used in Appendices
5
VIL References
6
PART B APPENDICES
L AlphabeticalListing of Compoundswith rheir Retention

Time and Arithmetic Retention Index on DB_5
T. compounds Listed in order of rheir Retention Time
and
Arithmetic Index on DB-S
31
IIt. Mass spectra and structures of compouncrsListetr in
order
of Their Retention Time/Arithmetic Index on DB_5
IV. CrossIndex of Common Names 53
698
Preface
This is the foLrrtheditionon rllassspectraatrdretentiorrtirnesof corlrnon cornponents in plarrt

essentialoils. It ditfersfi'om tlte previousedition in that an additiorral600 conrpouncls have beerr
adclecland the sourceof the satnplehas beeuadded.along lvith a ferv sourcesiu naturefor nrostof the
cotnpottttds.All of tlte contpottttds have beettattalyzedon arr HP5970MSD massspectronreter usiltg
F{PChetnstation softn'are.I hope it rvill be usefulas a tool fbr the identificatiorr
of compouncls iu
this foltttat. In adclitiorr.
the litrrary(includirrgretentiorrtinres)is availablefol the urostcor1r1ol
nlassspect|orneler/ contl)Uters.rslerrrs.
Changesirt technologyallorvus to tttaketlrisavailablertorv. For instance. rvherrI beganresearch orr

essetttial oils itt 1966.a ttta.iorportionof ntv thesisrvolk irrvolvedthe iderrtificatiorr
of coutlronerlts
itl .lttnipertts
by lR spectra.Of coursethat involvedcold trappingcornpoulrds as tlreyelutedfi.ornthe
TC detectorott CC. Witlt currettttttassspectrometers, we call lrow acconrplishin a coupleof hours
the analysistlrat took morrthsor years.
This book is an outgror,vth of the previousbooks(lclentitication of EssentialOils by lon Trap Mass

Spectrosct'rpy. AcadertricPress"1989;lderrtification of EssentialOil Conrpolrents by Gas
Chronratogt'aplr1'/Mass Spectroscopy. Allured Puhlislring.1995),but its roots reaclrback to 1976
ultett I took a sabbaticalstudy rvith E,rrrstvorr RudlofTand[.arvrenceHogge at the National Research
Coutlcilof Canada.Our collaborative effortsy'ieldednurnerous nlassspectraon their quadrupolenrass
spectronreter. [.ater,as I visiteclrvith colleaguesin clrenricalecologv,I beganto appreciate the
librarythat lhad assentbled.So this book is an outgror,r'tlr of nranycollaborations. startingrvith E,rnst
von Rudlofl'andnorvreachingarouncltlre rvorld.
I orvea specialdebtof thanksto colleagues rvho Lrnselfishly

sentsalnplesof oils. nrassspectra,
tttarkedcltrotttatogratls. attcleven purifiedcornpounds.Thesecolleagues ilrclLrde:
E. A. Aboutabl.
Eg1'pt:AlclrichClrenrical Co.. USA; .f. Altarios,Spain;AppliedScienceClo.,USA: A. Bacloc,France:
Al .1.Barroso.Portugal;K. H.C. Baser.T'urkey;A. F. Barrero"Spain:J. Berlin.Gentranl,:H.
Bttssertit-ts,
Haiti: .f. J. Brophy,Australia:E.-J.Bnrrrke,SyrnriseGrnbli & Co. (fornrerly'Dragoco),
Gertttanl';.f. L. R. Canavate, Spain;R. M. Carnran.Australiat.1.Casanova. France:F. M. Chaudary,,
Pakistan: T. S. Chanrblee. ClocaCola Co.. USA; A. Chainteau, Nestec.Sr,vitzerland;J. C. Chalchat.
Frattce;M. Clrielr.Givaudarr. USA: G. Collin.Canada:D. Clark,NervZealand:L. Cool. USAI A.
Corttat.France;A. A. Craveiro.Brazil:W. Cretnev.Canada:R. Croteau.USA; .fian-QinCu, China;C.
Dernetzos, creece:H. De Pooter.Belgiunr:M. Deyrup,USA; v. Dev, USA; R. p. Doss,USA: v.
Dlagar,Australia:G. Dugo,ltal-v:L. Doinro.Australia:F. S. El-Feraly.SaudiArabia;G. Elzerr.USA:
W. W. Epstein,USA; N. Fisher,Gerntany:R. Estell,USA; Z. Fleisher,Cronrpton& Knorvles.USA;
C. Franz.FrancetR. P. Garry.France;S. Geritraldi,FranceiK. Gollnick,Gerrnany;J. HafizoLrglLr.
TLrlkey:K. .f. Harkiss,England:C. Harvala.Greece;S. Hasegarva. .lapan;A. R. Haylnan,Nerv Zealand,:
E. Hetlrelyi.Httngary:H. C. ttills" USA: .t. Hendricksorr, USA; L. Flogge,Canada:G. Honda..fapan:
\1. Ito..fapan:P..loseph-Natltatt. Mexico: D..loulailr.Frarrce: A. J. Kahn,tt\A; W. A. Konig.
Certttatty;S. Kral, IFF. USA: .1.Lartgenheim. USA: D. Lanrparsky. Givaudan.Sr,vitzerland; A. Lara,
Spaitr;B. M. La,uvrerrce. USA: N. G. t-ervis,USA: M. Maff-ei.ltaly; M. L. Mahesh'uvari, Irrclia:
C. S.
\lathela.lrrclia:C. A. McDaniel,USA; B.Y. Meklati.Algeria:A. Michet,Frarrce;C. Menut"France:
L. N. Nlishra.India;D. McMalron.Union CarbideColp.. USA: K. Moriai,.fapan; M. G. Moshonas.
L'SA: R. D. H. MLrrray', Scotland:S. Nagaharna. Japan;K. R. Neisess,USA: l. Nykarren,Finland:J.
Oda.Japan;T. H. Ohaski"Japan:S. Park.USA: F. Perineau, France:W. Phillips.USA; G. Prestrvich,
vtl
USA; R. A. Raguso,USA; P. Raharivelomanana,France;P. Richomrne,France;B. Rodriguez,Spain;
V. Roussis,Greece;A. San Feliciano,Spain;J. J. C. Scheffer,Netherlands;R. Scheffrahn,USA; G.
Schmaus,SymriseGmbH & Co. (formerly Dragoco),Germany;N. Sellier,France;D. Senalik,USA;S.
Shatar,Mongolia; H. Shiota,Japan;E. Silva, Mexico; I. Southwell,Australia;E. Stahl-Biskup,Germanl':
R. Stipanovic,USA; A. B. Svendsen, Netherlands;A. Tara,ltaly; A. Tenaglia,France;R. S. Thakur,
India; R. K. Thappa,India; A. F. Thomas,Firmenich,Switzerland;M. Toyoat, Japan;R. R. Trenkle,
IFF, USA; A. O. Tucker,USA; A. Ulubelen,Turkey; T. A. van Beek,Netherlands;A. Velasco-
Negueruela,Spain; J. P. Vidal, France;O. Vostrowsky, Germany; G. J. Wagner, USA; P. Waterman,
U.K.; R. Weavers,New Zealand; H. Weyerstahl,Germany; P. Weyerstahl,Germany; P. T. White,
USA; M. Whitten,USA; H. J. Woeerdenbag, Netlrerlands;K. C. Wong, Malaysia;Xu Ji-Qing,China;
Xiaobing Yu, China; P. Yates, Canada;Y. Yuesa, Japan;T. A. Zanoni, USA; M. G. B. Zoghbi,Brazil; J.
A. Zygadlo, Argentina; and J. H. Zwaving, Netherlands.
Special tlranks to Tanya Yank, Lou Gamett,Madeline Reed and Ryan Perezfor assistancewith word
processingand drawing structures. Also thanksto severalyourlg studentswho helped: Carlos Borunda,
Blake Fitzgeraldand Ryan Remick.
Finally, I would like to tlrarrkmy wife, Janice,for her patienceand encouragement.
Mr,.
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PART A CON{BTNEDGAS CHRONIATOGRAPHY/
MASSSPECTROMETRY
I.INTRODUCTION
Thc utilization ol'thc essctttial ttils ol'plants is rviclesprcacl,ran-cin-glxrrn

pcrfurncs ancl fl.agrancesto sl"liccsancl
nlcdicirrals' Rcscatc h has v ar ic c l liot n v c r y aPplic d . a s i n t h c c a s e o l 'c ; u r l i t y
c o n l r . c , lo l 'l . u i t . i u i c e i . t ' a c a c l cr n i cstu cl i o s
irlr'<lIr,ing inscc1.1 r |ant c t lc r ' ' t llut it lt - t . I nt r t os t c as c s , | 'h c i n v c s t i g a t t r r ( ) r u s c r i s f i r c e c l w i t l r t h c
nt | lllcf()ttsc()|ll|]()nenlSinv er . y c r r t t t p|c x lnix t t t t . es , . f h e v t t | a t i l e ( u s L r a l | y l a k c n t o | l | e a n S t e a l }l - t | i s t i | | a b | c )
ctc.). Itl solltc sl.rccics.orlc rltay obtain alkarrcsanclaliphatic alcolrols. kctoncs ancl
alclchycle,s.
, E 1 lstcincta|'.l9 76 ) u' ' it lr it s nt ln_|r c r r c l_t ir . t

F ili'1 11
ttt* an tl Kub c c z k a 11982) . Lawr c nc c ( 1978. 1 9 7 9 ) . a n c l M a s a c l a( 1 9 7 ( t ) . h o w c v c r .
t o s e c t h c r c 'o r . t s . l 'a l 'ew h u n e l .ctl
phlsi<lltrg ica litna ly s c s t ll. s eas t lt lalalr c |c c |a1lhic |i l c t <l r . s i n c o n l t t t c r c i a l s 1 r i c e a n t | e s s e n t i a l c t . r l p s ) n t a y

lirJ'rcrrtrirls.
un ccluiv oc alir lc nt il- ic at ionc un hc r lil' l' ic: L r(lAt c l a r n s .c t a l . . 1 9 7 9 t .
His(o r.ica l|1',.cs s c nt ialoilc t lt t t |r t llt c t lt s lr ar ' c bcc n i t | c n t i l . i c
.it e|citt'ttta gn cticfc s ( ) t lit nc e( NM t t ) . ( ) n|y alc ly
' . 1trit|1rlra sclRisvc r . y c x p|ic it ( c s s c nt ial|y l. ir r gc r . p r . i n t s ) l i l r l t t t l s t
...n tain illgtln lya sin elc t nint t r c t r t t l1- lt lnent lt ils
' e\\cntia l oils.
.nr llatch(o llatch(.| c llnin. es . l9871. G il' c nr epr . oc lt r c i l l l c t . c t c t l t i t l t t t i n l c s 't | r c
' ll1|1()llclllsisptrss it r |elr y t . c t c r r t it lnt ilr t c / t r r as s Sp e c t t . o l l l c t f y / c t l t r l 1 l u l c r s c a l . c h i n g

-\ q: l9 c)-5 2: (X)I ).
Tlrein trrrc|L rctitlns r ll. t heir lnt t . apt lc t c c lr lt . ( I TD ) . t l l . i t r n t r a p l l l i . t S S s P e L ] t r ( ) n l c t r . y . | y
--' r.lrttlltrlc[r1,He r'v |c t [ - Pac k ar t |. [ onat llc lr ut t wt r k r : y t c c h n t l | t l g i e s . l r a r . e l r r a t l e a v a i | a b l c r . c l a t i r 'c | y i n e x 1 - t c t r s i v el tl ss
Th c n ul'1 11 1*0l't
ss his book
- ' rr rrttu l).occu lrilr- g
lt lant es s ent iuloiI c or - nponc nt s .
I I . \ O\IENCT,ATT]R I i
Thcrc is n o g clte r al agr c c nlc nI on lhc nor ngr c lut u r c o l 'c r x r u n o n n a m c s r r t i l i z e d f
o r . e s s e n t i ao
l i l c o r n p o n c n t s .B c c a u seo l .th c
-: }li.ttrI.ica|tlsag c t ll. c ( ) |lllll( ) l1t lit lllc S. t |r c t t lor c ll r o c i s c c h c n t i c a l n i r l r t c s 1 - l l l v i c
. -. - lrl,'rn u\1 .(1.
Thcrc alc s()lltc c()nvcntions. lrolr.,cr,'er.
that llcc(l to he adoptccllirr the c()nrnonnalllcsto leaclto rnor.cunilirrnrity.It has
i- -"r
-'\rnun()ltlo c-nllis1y111c1.s
about a rlouhlc boncl as r,r.ritntltrortsrtrthertlrarrF,andZ (bclow):
&o'
/i'arr,r-hcx-3-cnol r:r,r-hcx-3-enol
Adarns:EssentialOil Componentsby GC/MS
to my
In tlris hook,I shalltry to be consistentin namingall doublebond isomersas E or Z,n)t transor cl.r.So, accor(ling
c.n'entions.the hexenolabovewill be called(3E)-hexenoland (3Z)-hexenol, o[
not /runs-ltexencll cls-hexenol.
(E)-
The nomenclaturalsituation gets rnore con'rplicatedwith ringed cornpoundssuch as "p-caryophyllene"i.e.,
caryophylleneancl(Z)-caryophyllene:
(E)-caryophyllene (Z)-caryophyllene
Even moreconl'usingfbr (E)-caryophyllene ("p-caryophyllcne"):The cloublebond in the a positionresultsin the nameof

u-caryophyllene, yet this compounclis universally calletlcrt-humulencl
naming that
Tr.uecjs- and trans-,rc,,r"is,htrvealst'lresultedin problems.Decouzonet al. (1990) htrveprtlposeda systemof
is olien fbllowecl(antlwill be lbllowecl in this book).They thc
present following ol'menthol:
isonrers
=l=
il : I
r r llll
|\.'-:^" | \'--^"" 9'"..- \"*/'"'rt^.
T' oHl'.l
lJ- r
\
t'- \
,'-
--\
neomenthol neclisomenthol nrenthol isomenthol
isomers.
The nanringconventionof Decouzonet al. (1990)is usedin this book ftrr thesekinclso[ neo-,iso- and neoistl-
III. MASS SPECTROMETRY CONSIDERATIONS

fiS l0fsil
A. Obtaining Quality Spectra for Identification

Although operationof the HP tnass selec{ive
detector (MSD) and other desktop mass
spcctrometersis autolnatic in most aspects,there
area numberof areasin which the userncedsto be
carelul in choosinga spectl'umtbr identil'ication.
Obviouslythe choiceo1'a column, its installation
and useare very importantin obtainingseparation,
eliminatingbleed, etc. BecauscJennings(l9t{7)
has published an excellent treatiseon capillary
column gas chrotnatttgraphy,the readeris refened
T.trgetTune.FC43
to that book fbr dctaileddiscussionof c.apillarygas
chromatography. I larfvs l!,it
The HP MSD can be tuncd trsing either an
"automatic tune"" (or "autotune") or a "target
li
1fr t t3 itd!
tune." The use ol autotuneshould be avoidecl.as
the targettune gives lnore consistenImassspcctl'a l
or,era time period.Our HP MSD was tunedusing F)At3 ! '(i J
talgettune,with targettttnevaluesof M69 - lOOVol

..1
r.l \-.'-.,,-.
-rl
li6'0
-.
'-,-....:\.rrf-
fr r. -$^ f. {^ !
I
!*tl r0s 5[r

l3l3 - 40%. 219 - 617c, 502 - 3Vo.
In Figure I, one can seethe autottlne Figure l. Cotnparisonof alttotttnevs. targettune spectra
(upper)and targettune(lower).Noticethe much
loiger.omountof M219, in aclclition to someincreasein M I 3 | . Becausethe essentialoil componentsare often of' mass | 36-
the MSD
222, increasingthe ion intensitiesin this rangeis very usc.ful.It is intportantto do a targetttlneany time one cleans
or changesgas cylinclers.
Adants:EsscntialOil Conrporrents
by,GC/l\,{S
Oxyg en attclr,r'ater c anSeVc l. c |y af f . ec t t hel} laSS S l ] e C t | . ( ) n t c t c r . l r t r t h i n t I r c c 1 u a | i t y ( ) l - s p e ( ] t f a t r b t i r i n e c l a t r t l i tl p e l l l a l l cl l l

clanritgc
cloin-ua lcak clreck. Rttn a slandalcl (cx. cc(lr()l) cach week to cleterrnineil'any cftan-uesin tunine Save gccurrccl.Whcn rhc
lirrairan c|wa [cl'.Be c lt t Sc c v c llt |r c ht lndc d1r has c 1r t r | a r . c t r | t t l t t n s a r c t | e g l . a d c c |

hvch'ogen)shoulcl be usetl. antl holh oxygcn and watcr.traps slrorrltl be inscr.teclbetrvccn the supply cylinders tucl gas
clrrorll;111rg1
111111.
N <ltlt|tt.rlrsp ectis as c t r ns is t c nt ly t [ ot lb|c s ( ) lllc as t r r 'c r | t r a t | c ( l s l ] c c t | a . B c v c r y c a r c | . t t l w i t h l a r . u e p e i r k s t 0
sl)cct|a .Asitg cn cra |r t llc . t h9Spc c t r aint lr is bt lt r k wc r c c I l t l s c t l c i t h e r a t t l r c r r r i d - p t l i n t | i l r . s r r r a l | 1 r e a k s o r . i t t i t b t l l t
litur thc stal"tol'thc pcrrk hrr lalgc pcaks.
Please note: T-he t'ctcllti()lttirncs are rrrrt at thc ccnter lirr lar-ucpcaks! On thc systcm uscd lirr. lhis brlok. srnall pc,aks
avcirscd a bo ut 0 .I rn in in
nerc lalgcrlthan 0. 1 rnin lvidc wcrc sct to 0.0-5rnin past thc staft ol'thc pcak.
B. Tlre Role of Retention Tinres in Library Searches
B ccitttscttncc1 triv oc ir |ic |c r r 1i|ic t r t it r nt t |' s t lt lt c t e t . p c n r l i t | s c a | r | 1 0 t b y r r r a c l c t r n {h c b i r s i s r r l . t l r e l i
.i. 62thtricnc<Cx'->).Thus . 5' ( l2is t hc r c t c nt it r nt int c in l t t i t r t r n D B . 5 . . ] ( ) l l l . t c | l 1 l ) c | . a t t t f c l l ( ) g | l l l ] ] l l ]

.l C/ntin. r'anr1.r.
F ictrrc2shtlrvstlrc r c s t r |t t l|. a|i|r r aly Sc a|c hf i) |t hcc t r m p t l t t t t c l a t 5 . . 5 t i 9
Lt ic it t'ctctltiontirne (RT) of ' - 5. - 589 r nin + 0. 05 nt in = 5 . 6 - 1 9m i n . 'l 'h i s c l o s e l y m a t c h e st l r e R T l i x 't h e l 'i r s tr l a t c h ( 5 . 6 2 ) r Su j e n e
<cl->
tr.nErillE'-'f 5 :iil tf 5.E41ilrirr..LElllli5l ri t' {-)
!,ttLtfrLlilfrie
#Ll4D:5.8: THUJEI{EcALFH,o,,r
F i.ctrrc2 'Lib r.arys c ar c hlilr . a- lht r jc nc ll. t lt lt lc lt r t ln r l i | ( t t l p ') \ 's . t I - l h l , c n e

'.',:rrto cl-plrcllanclre
nc at ncafly lhc sanrc rluality lcr,'cl(9.1vs. t)l )
' ' r llre HP Cltcln s t at it lr r ( Hewlc t t - Pac k alc l.

Pak l A l t o . C A . L J n i t c c lS t a t c s ) s c a r c h . A l t h o u - u h f l r e s c c o n c l r l a t ch ( 7 .8 5 )
- I'rn tltcn c(<o->) is nc ar ly as s ir t t ilar .not e t lt at t lt c r c t c n t i o r rt i r r r c( 7 . t 1 - t5n i n . yi s l u l t r r o l a t e t 9 h e t h e u n k l g r v n p c a k.
\ .ccrlntlcran tplc(Figt r r c l3, ) s ht r r v s t |r es c al. c h|ilr . a l a r . u c
, ' \ 6 -57to 8.ll(r,5 .I would r ount l u|. l t hc las t t li. gi t t 8 . 6 - 5 7- > 8 . ( t 6 a n c l
a d d 0 . 0 5 r n i l t = 8 . 7 1 ) . T h c H p C l l r c r n s t a ti o nse a r ch
..t|ritlcnti|.icclth c ; r c ak as lit llt uc nc ( Fiigul. c ] ) . wit l r a r l R T i n t h c | i [ r r a r y o f '[ t . 6 9 n r i n . l n
min of the library time if you usethe sameDB-5, 30m column, sametemperatureramp (60'C to 246"C at'3'C/min) and if you
correctyour peak'sRT to liblary valueswhen identifying new peaks.
We routinely add two internalstanclartls to our samples:octane(C8) and eicosane(C20). If the startingtime is incorrect,a
correctioncan be a6de6to the early peak's RT. If someproblernhas developedin the gas chromatograph'soven temperature
controllerand/orcolumn characteristics, this changesthe RT of eicosane.
In actual practice,you can easily adjust RT as you processthe output by merely noting the RT of major peaksthat al'e
easily iclentifiedan4 then either.aclclingor subtractingthe diflferencein their RT and that in the library. For inslance,if in the
abnveexlmple u-thuienein lemonoil haclan RT of 5.50,versus5.62in the library,I would begin to add 0. l2 ntin to the RT
9l t6e next peak(s).lf lurther along in the chromatogram geraniolhad an RT of 17.81versus17.95in the library, I would
begin aclding0. 14 min to the RT of tlre next peak(s).By adjusting the RT as one "crawls" along the chromatogram,one can
attain very good RT.
It should also be noted that, occasionally,the lihrary searchiust doesnot seemto pick up some subtledifferences.In these
just look on the pages! The
instancesit is useful to have the book openeclto roughly arounclthe unknown's RT and
researcher'seyesare still prelty gooclat seeingpattcrnsthat computersearchesmiss.
Avef age ol 8.657to 8.8F5min.:LE['1I154S7.8
Figure 3. Libraty searchfor unknown and lnatch to library litnonene
IV. OPERATING CONDITIONS USED FOR SPECTRA ACQUISITION
(Hewlett-Packard.Palo
Mass spectrawere obtained on a Hewlett Packard(HP) rnoclel5970b MSD rnassspectrometer
Alro, CA, UniteclStates),coupleddirectly to an HP 5890 gas chromatograph(Hewlett-Packard,Palo Alto, CA, United States)
fltted with a J&W DB-5 (J&w Scienrific,Folsom,CA, UnitedStates),0.25 mm i.d. x 30 m,0.25 ptmcoatingthickness'fused
sifica capillary colurnn.The GC/MSD was operateclunder the following conditions:injeclor temperature.220"C; tl'ansferline,
(at 210'C);
240.C: oven temperatureprogrammecl60"-246'C at 3'C/min: calrier gas, He at34.96 cm/sec or 1.02 rnl/min
injecrion(for moit wholc essenrialoils).0.1 pL (t07o solution),split l:20,500 ng/on column; injection (for individual or
Internal standards (n-octane and
simple mixturesof referencecgmpounds),0. I pL (l % solution),split I :20, 50 ng/on colun.rn.
n-eicgsane)were addedto eachsampleto aid in the standardizationof RT.
The following is a typical set oi valuesfor our instrument:EM Volts 1800v.,X tay 44.0,emissionon, AMU gain 88'
AMU offs 60, mass gain'52,massof[.s14, repeller10.20,ion focus 0.0, ent lens 54. Acq. mode scan'scanrange4l-415' I
scan/sec,solventdelay 2.00 min'
()il Conrporrcnts
Aclunrs:Essr.:ntial bv GC/N,IS
V. CONIPATII}II-TY WITH NIASSSPECTRONIETER DA'I'A SYSTENIS

lrr aclclition to lllis llrin{ctlbook.it c()lnl)r.rtcr scalchablclitrlaryis availablclirr uscon the lirll.r,vrngsysre*s:
l . P alis adcB c nc hT o p /[)BM.(P BM2 2 0 -5 .S p C )
2 . F innc ganG CQ / ( C C IQ M2 2 0 5 .L B R )
3 . V ar ianS r r t ur n( V AR S2 2 O5 .l -BR )
4 . F innc glnk r n T ' r ' a ;r(l T D 2 2 0 5 .L tB& l l ' D 2 2 0 5 .1 N X)
5 . Fir r nc garI NCOr S(F IN C I2 2 0 .5 .L&SF IN C 2 2 0 -5.LX )
6 . F is ons / V ( Jl CA M P (F l SV 2 t0 5 .J D X)
7 . tr is ons / V GN, lasls-a h ( F l M l -2 :0 5 .I D B ..l D I..p D B .&pD . l)
8 . Ht ' . I CA I \ lP .Unix (H P .l C 2 2 0 .s .H p J )
9 . HP Chc nr s iat it ul D i r \tJ PC H 1 2 0 -5 .L p l.u s7 l ' i l e , s:
R OO' f: H E A D E R I H E A D E R .IN D :C A S .IN D :
C r )( NI ) E NS E :CoN D ts N S E.tN D I F U t.t_ .DI
1 0 .nc t CDF ( NE T C 2 2 0 .5 .C D Ir)
I L P E T ur bor r r ass ( P E' IU 2 2 0 -5 l D. B..lD I..p D B .c tp D I )
1 2 .S hir nailz Q u P 5(x x (6) l ' i l c s :s H tM2 2 0 5 .N AM..FoM. .LtB . .spc, .coM. .FLc)
| -1.N{assFintlcr' ( MF32205.rnl'l )
l l 4 'l F innc ganT r ipl c QL ra dc a na u to tn a l i c a l lcyo n v crtthc.t,S ..l ,X (#-5.atrovo)l i rrnrattccl l i br.ary
l l -5. 1F innc . t arI CI
r S c a n rc a cF l i n n c -ta n
k rn T l a p (.LIB . .l N X . #-1.abovc)l i rrrl arrecl l i brary
[ 16.I Tcknircnt vcctor 2 can lcaclPBI\{ (#1. ab.r'e) lirnnattccllitrrary
M any t lf . t lr c da1 a S y s l c tl ts c a n i n 1 l tl ta n H P J canrp(8)fi l rl l atl ccl l i l rrar.yancl ctl trr,crti tt< l t| rci r
n trtc t lt |iat { heN{ as s Iri n tl c r.(p tri n tl 3 a b rl r,,c )i sstanc| -a| < l ncstl | trvat.c
N{assFinclc| can l.rcusccl[o llrocessrncl idcntily cornpouncls usinga corlbinationspcrctfal (lataanclRT.
t) ua
II {_t Il El
1,.c .'
I
,]:
i]
I
i_
;--
3B?9448:17 fl lrrl il Lr,llJrf I lt l:t td., 5,:dnlllT lZirlS) ff r'l:,ti2:r_r5,r'fl

Figure4. MassFildersearchpageshowingthe iilentificationof E-cadinene: the middlesectionclisplaysthe previotrs,cuffent,

anclnextscanfrom the RIC(leli); matches
libr.ary are on the right side.rankedby similarity(l and 2 of 27 shown)
Figure 4 showsa searchfrom MassFinclcr.One of the benefitsof MassFincleris that it displaysthe previousanclnexf nrass
is the
spectl;l scan,as well as the currentscan.So it is easylo cletectmixeclpeaks.Anotherrvery usel'ull'eatureof MassFinder
capabilityof outputtingcustor.nizeclRIC and massspcctrafiom publication.Inlbrmation on MassFindcr is availablefiom
Detlev Hochrnuthat u;h'w'massfinder.cont.
VI. EXPLANATIONS OF FORMATS USED IN APPENDICES
seric's
BecauseRT rnay vary as columnsage anclil'different carrier gasesare used,it is useful to have an index basedon a
The
of stanclar{s.suchas straightchain hyclrocarbons. most comtnon index is thc Kovats Index (Kovats, 1965).
Kovatsindicesarecornputecl usingl'orntula(2) tp.230 from Kovats(1965)l as lollows:
KI (x) = 100P, + 100[(log RT (x) - log RT (P,)) I (log RT (P'*r ) - log RT (P, ))l
Where: RT (P,) < RT(x) < RT(P,*1), and Pa ... P3aafe n-paraffins.(up to N=34 in thts book).
However.Van clenDool anclKratz (1963) notedearlierthat when temperature progratnrning is dtlne,an aritlrmeticindex
index. The arithmeticinclexusedin tlris edition was computcdas:
(AI) would be nrqreappropriatethan a logarithrn-basecl
AI (x) = 100P, + 100 t(RT (x) - RT (P. )) / (RT (P,+t) - RT (P, ))l
Both AI anclKI inclicesare presentcdfof eachcompounclin Appendix III.

The first appenclixpresentsan alphabetic.al list of the compounclsfor which massspeclrawere obtainedanclincludestheir
RT a nd ar it hm er icin c l e xo n a J & W D B-5 ,3 0 m.0 .26 mm i .d..0.25 prmcoati ngthi ckness, w i th H e as can' i erga s at 31. 9
cm/sec (1.0f 7 mllmin). with a programmedremperatureof 6o'-246nC at 3nC/min. The prohlem of presentingditl'erent
rerentionindices has been discussecl by Jennings (1978) ancl Jennings and Shibamoto (1980). I have chosento lbllow
JenningsanclShibarnoto(1980)in publishingRT, buthave also includccl both arithrneticand Kovats indices'
RTs'
A small DOS program (ARITHIND.EXE). includcclon the CD-ROM, rnay be useclto print out a cornpletetable of
=
AIs and KIs from RT 1.43-82.80min (Ca-C,a alkanes).
bonded
It should be noted that r.etentionon a Carbowax-rypecolumn may seem essential,but we have found even
rather quickly (ancltherefbre change thc RT). The non-polar phases lack some of
Ca1bowaxto changepolarity characteristics
ketones, but the longer term stabilityand lower batch-to-batch variability offset that
the resolvingpower frrr alcoholsand
OV-3'
liability. The polarity of a DB-5 colur-nnis equivalentto: BP--5,CP-SIL-8CB,DC-200, DC-560, Dexsil 300, GB-5,
OV-73. SE-52,SE-54,SPB-S, Ultra 2 and 007-2.
AppendixII lisrsthe compouncls by RT on a DB-5. This list is usefulwhen you areidentifyingcompounds,as it is a quick
guideto seeiI'a libraly matchrunsclosefo the peakyou areanalyzing'
AppenclixIII presentsthe quaclrupt'rle spectiaof compounclsthat are most commonly encounteredin the identiflcalion of
essentialoils. Unforlunalely,severalvery commoncompouncls do not appearin Appendix III hecausewe could not ohtain
eruthenticreferencecor-,rpc,unds. Each of lhe compounclswas searchedin ChernicalAbstlacts Service to obtain the current
camc fiotn
chernicalclr systematicnarne(CN), supplementregistrynumbersand supplementsynonyms.Structuralinformation
Co. catalog' Chernical Abstracts
original literature sources(see pret'ace),Aldrich Chernical Co. catalog. Alla Chemical
Conrpounds (19S2), Food Chemical CODEX (Doclgcn, l98l)'
Service,Devon and Scou (1912), Dictionary of Or'-eanic
and Kubeczka (1982), Jennings and Shibamoto
EpA/NlH mass spectralclatahase (Heller and Milne, 1980),Formacek
(1970),
(lgS0). pfaltz and Bauer ChenricalCo. catalog,Swigar anclSilvc:rstein(1981), von Sydow, Aniou and Karlsson
(1973). As far as practical,the structural patterns used by
Masadail976). Merck Inclex(Winclholz,lgUi), and Yukawa
Devtrn anclScott (1972) were lirllowecl.Each of the compounds tbllows the same fcrrmat:
RT..............AI......KI..... Common name............

CAS#: MF:..............
a-N.
SYNONYMS:.................
SOURCE:...
Where:
timeon DB-5column,in min.
RT = Rel.ention
Adarns:EsscntialOil Conrponcnts
by CC/NIS
AI: = A r it hlnet icin c l e xo rrD B --5i n r.e l ' c r.e nto

c cn -a l kanes.
KI = K ov at sir r c lcx
o n D B--5i n rc l c re n c ck r n -a l k a n es..
C tr nr t r r on|la|lle= C tl tl tl n tl n n a trtc .tc n c l .a | | ),ttset| (rl | .ctl ttrsc.

usctl.so it is sorncwlri
ty;l c t ||. ir s t . r v it hn ttx l i l .i c rs ;l | a c e d
h o pc l' Lr llywill aid t l rcu s c ri n l i n d i n gl l a n l c )s ..
CAS# = ChcrrricalAbstractsScrvicc rcl'et'cncc

nuntbcr.i\'lanyol'tlre esscntialoil cornponcnlshavc Sccn assi.unccl
scvcral
CAS#sor'cr Ihcr
i nl i r |lnat iolr
CAS |cvealcclboth R (+) and S (-) lirrms havcbecnrcpoltccl.Thcrelorc.the choosing
ol a CAS# 5cc.'rcs arbilrary.This also
llfcsclllsa 1lt'tll-rlcnl
lb| thc stal'l'atCAS rvhcnthey assignrc-tis{r'y
nurnbcrstg comp6un4si' thc litcr.ature.
N IF = N4olc c ular
lir rrn u l a .
FW = Forrnulau,ci-rhl(or.molecular-
wciglrt)i n A M U.
NISD Libr# = HP MSD libr.arycnrry nunrtrcr(the librrry is ar,ailal"rlc

on cD-RoM fiorn Allur.cclpublishin-c).
CN = Chcrnicalor syslglltalicnar.ncuscd lry ChcrDicalAl'rstracts

Sen'icc.Alrtrostall the narnesale frrirlrthc nintlrchcrnical
i n tl c x .
SYNONYN{S = S)'trtlnylllslill thc cotllttl()ttnatttc. Sotttc ol'thcse arc various pernru(ations

o1'an oldcr systcrnaticnarne (cx. 3-
rtrcthl'l --l-hcl.rltrnonc ancl:l-hcptanonc"3-rnelhyl-). Alllt()st all ol'the syl.lonvt.lls are cross inclcxeclin A;rpcndix lV.
Ttlth crig |rttll.ea c hc t llt t 1- lt t t t nt |nat r lc ant l1lar . ir g l . a p h i s t h c s t r t | c t [ | f c ,
sclcetiVe dclcct()r (lvtSD). Although tttost ci,r- and lrrlr.r- isonrcrs lollow
rhe CIAS rules. Lrsingthe gro''s lvith tlre largcst
lcr. 1lin ctll.c,l.r-/rlttlt . l. - s abinc nc hy c |r . at es . L] t c . ) . A s | r r r a s p o s s i h | e . t h o C A S S y s t e n l i s l o | l o r l . c c | a n t l n o t o t l

enl| v.
SOURCE = Sorttcc of the cotttpottnclttsccllil'thc analysis. plus othcl natural s()pr.cec

rvhcre kn6wr.
A;tp cn dir IV lisls all lhc s Ynony llr slt nd c r os s - r c l c 'r c n c c s( h c s y l r o n y n r s( o l l r c

c o r n n r o n u a n r e a s a n . i t l l i r r t h c r ca tl cr ..'l - h c
ilcccl)tc(lc()llltl)ol1trattlcs(ttsccllirr'llrc sl.rcctrain Apl.rentlixItl) a|c irr hokl lircc
capitals (cx. AIIIETAL).
VI. RI'FT]RENCBS
A tIattts.R.P.l97 ().Seas t lt t alr . ar . iat it lt t t r l. t c r 1lc r lt li c | c t r t l s t i t u c n t s

P h yto ch cn r.9:3 97 - 402.
A t lattrs.R,P.l9 ll9.It| elt t i' |' it ' t t t ir lt t o. f ' E' s ' ' lc lt t iuloilsb l , [ o t t T t . t t 1 l L 4 t t 's '. s S P e t , t t . t
Atlaltls.It.P.|99.5'Itletttif.icoritlttr|E.s'letttia|0ilColtt1lottattt.rb1,Gct,sCltrottt.ttttlgropltl'/Mcts's
Allu lcrl Pu blishin g Cor . p. .Car ol St r . c iut rlL. . USA.
Atlanrs.R.P.2(x)l.lderrtifit'rrtiort o.fE.s.sctrtittr
oil Corrtltortettt.r
lt cla.sCI rn tt rrrrtutg r up I n'/ Q tta t I r up o I c M a.s.sS ec t r o st.o t,,
1.t 1.t
Allur c d P ublis hi n g C l rrp ..C a r.oSl tr.c u rrr.
tL . U SA .
\tlanrs.It.P. and I-. Hogge.lc)t13. Cllrcrnosystcrrratic stuclies
ol' theC al i bbcan.j uni pcrs basecl on thci rvol ati l eoi l . B i ochem .
Svs t .Hc ol. I l: t t 5- U c .).
,\t| itttts.ItP..M.Gt.a lt at . E, . v t r n[ { t r c l|ol. |. anc lL. Ht r gg c . | c ) 7 9 . I t | e n t i l . i
t rt ltsss;.rcctratllta
l hv or t - linc c ( ) nr put c rr r r c llr oc l. . lC
. h r o r n a t o g r a p h i cS c i . l 7 : 7 - 5 - 8l .
A t| ltttls.R.P..T.A.Zat t t lniar r t l[ - . Ht lgge. l9[ . t . 5. J . hc r 't r | a t i l c l c a l . t l i | s t r l 't h c . l u n i p e t . s t r l . C l l l t c l l l
.lr0tiltcrtr.tt'otilittrrttt,J. gttiltbottrrttulrtl.l. ,rtorrrllcr.r. .1.Nat. pr.od..lti:67g-61J0.
. \ ltlrich Ch e rn ica l Co nt panv Ca{ alo- s .M ilr ' , , aLr k c cW. l.
C | aY cirtr.A' A.. A.G' Fc r t r anc lc sC. . H. S. Ant lr adc . F.J . D . M a l o s . . 1 . W.A l c n c a l a r r d M . L l - . M a c h a c k r .
l g t t l . O l e o , s E s su r ci a i s
Aclarns:EssentialC)il Cornponentsby GC/MS
de Planta,sdo Nordeste,EdicoesUFC, Fortalez'a,Btazil

alcoholsby
of diasteroisomeric
1990.Dif'f'erentiation
Decouzon,M., J-F.Gal, S. Gcribalcli,M. RouliarclanclJ-M. Sturla. translorm
with A
dissociation.
collision-inclucecl Fourier
electronimpactanclnegativeion chemicalionizationassociated
ion cycfotron,.rnnun." stucly'OrganicMassSpectrometry 25:312-316'
T.K. and A.I. Scott. tglZ. ianabook ctf Naturalll' Occurring Compomds' Vot' IL The Terytenes'Academic Press'
Devtrn,
New York, NY'
ecl.,chapmanand Hall' New York' NY'
Dictionan,of'orgattic compountl,s. -5thEdition 1982.J. Buclringharn,
National Academy Press,Washington'DC'
Doclgen.D.F. l98l . Food ihenticats Codex.3rclEdition,
of sagebrush. Phytochemistry 2?: 2257-62'
Epsrein,W.W. antlL.A. Gauclioso.1984.Volatileconstituents
oils AnaLysis by Capillary Gas chrttnwtograplry and Carbon-l-l NMR
Formacek.v. anclK.-H. Kubeczka.19g2. Essen.tial
Spectroscopl',JohnWiley & Sons,New York, NY'
Data Base'U'S' GovernmentPrinting O'fice,
Heller,S.R.and G.W.A. Miine. 1980.EPA/NIHMass Spectral
Washington,DC'
Jennings.w. 1978.Gas chromatography'ntith. GIassCapillarl' columns, AcaclemicPress,New York' NY'
Press'New York' NY'
Jennin!s' w. 1987. AnalltticalGai Chromatographtt'Academic
Je nnings , W . anc lT .S h i b a rn o to .l g S0 ' Q tml i ta ti veA nal l ' si 5ofFl avoral dFragranceV ol ati l esb)' Gl assC ap illar yG as
Cltiomotograple.r', Ac'aclenric Press'New York, NY'
rerention inclex systern . pp.229-247.in Advances in chronrcttography,Yci.I',J'c' Giddingsand R'A'
Kovats,E,. 1965.The
Keller (ecls.),Marcel Dekker,Irlc.NewYork' NY'
corp" carol Stream', IL'
Lawrence.B.M. 197U.Essentialoils 1976-1977,AllwedPublishing
Corp., Carol IL'
Streartr,
Lawrence.B.M. 1979.EsserfiialOils 1978,AllureclPublishing Wiley & Sons' Inc"
Masada, y. lgi6. enatysisttf Essen.tial Oit, ilv Gas Chroiatogiaphl'and Mass Spectrometrl"John
New York, NY.
Pfalzand BaucrChemicalCompanyCatalog'
Flora.Pllt 2. Flavor andFfag' J' 2: 2l -21'
Srruthwell,I.A. lgg7. Essentialoil isolaresfrornthe Australian l H N MR un4 l S C N MR S pectra' andK ot'at s
Swigar , A . A . anc lR .M .Si l v e rs tc i1n9. 81 .Mo n o te rpenes:l nfrared,Mas' ,
indices,AlcirichChemicalCo.' Milwaukee'WS'
g63.A generalization of the rctentioninclexsystemincludinglineartemperature
Van clenDool. H. and p. Dec. Kratz. I
463-411'
p r ogr am m edg a s -l i q u i d p a rti ti o n c h ro m a to g raphy' J' C hromatographyl l
C. Karlsson. 197O. ltiassSpectral Data of Terpetres, SvensakInstitut for
von Sydtrw,E., K. Anjou un,t
Konserveringslbrskning Rapport'Nr 279,Kalleback'
Wincfholz. M. (erd.).
| 983 .Vne nterc* Inclex.10thEdition,Merck & Co', Inc', Rahway'N'J'
Publishingcompany'
yukawa. y. anclS. lto. (eds.). 1973.SpectralArtlaso.frerpenesarrl the RelatedConrpounds,Hirokawa
Inc. Tokyo.
PART B APPENDICES
AppendixI
ALPHABETICAL LISTING OF COMPOUNDSWITH

THEIR RETENTION TINIE AND ARITHMETIC RETENTION INDEX ON DB-s
t0 Adams: EssentialOil Componentsby GC/MS
CommonName RT Conrmon Name RT AI

Abienol .5|.98 2149 Allyl anthranilate 28.89 l50l
Abieta-(8(14),| 3( 1.5)-diene 52.t2 2t53 Allyl butanoate 04.60 0881
Abieta-7,l 3-diene-3-one -56.8.52312 Allyl cinnarrate<(E)-> 30.78 1.s48
Abieta-8,12-diene 48.03 2022 Allyl cyclohexylpropanoate 25.61 1423
Abietaclien-l 8-ol <8, l 3-> 57.11 2324 Allyl decanoate 27.84 1476
Abietadiene .50.08 2087 Allyl heptanoate 14.8(r I178
Abietal .56.87 2313 Allyl hexanoate 10.72 1079
Abietal <4-epi-> 56.44 2298 Allyl isovalerate 0.5.82 0931
Abietalcdehydro-> 55.74 2214 Allyl nonanoate 23.65 r 378
Abietatriene 49.08 2055 Allyl octanoate 19.22 1278
Abietol 59.37 2401 Allyl tiglate 08..57 l02l
Abietol <4-epi-> 57.72 2343 Amhersage t8..58 1263
Ahietol <neo-> 6r.r5 2468 Arrrbrinol<cis-c,-> 26.26 1439
Ahietol<dehydro-> 58.42 2368 Amhrinol <trans-0-> 25.27 1415
Acetanisole<o-> 19.16 129{) Arnbroxide 38.8l 1756
Aceton\'l acetone 05.48 0919 Anrorph-4-ene<l o. | Oo-epoxy-> 3l .70 l -570
Acetophenone 09.99 10.59 Amorpha-4,I I -diene 26.7| 1449
Acetophenone<2,4,6-trinethyoxy-3- Arnorpl.ra-4,7( I I )-dien-8-one
meth\.1-> 36.80 l70l <2u-acetoxy-> 46.84 198-5
Acetophenone<3'-methoxy-> 20.11 1298 Amorpha-4,7( 11)-diene 27.97 1479
Acetcrphenone <4'-methoxy-> 22.30 1347 Amorpha-4,7(I I )-diene<2o-acetoxy-> 40.59 1805
Acetophenone<p-methyl-> 14.91 1119 Antorpha-4.7(lI )-diene<2a-hydroxy-> 39.49 llt5
Acetoxyelenrol<8o-> 40.14 1792 Atnorpha-4,7-diene <2u-acctoxy-I I -
.Acetoxyeudesman-4a-ol < | I -> 45.24 1938 methoxy-> 42.55 1861
,Acetoxyhexane <2-> 06.10 0941 Amorpha-4,9-dien- l4-al 36.91 1104
.\cetr'lpvridine<2-> 08.83 l028 Amorpha-4,9-dien-2-ol 36.77 1700
\cetvl thiophene<2-> 10.97 t086 Anrorpha-4,9-diene<7,14-anhydro-> 38.78 1755
^\cetll-1.-5dintethylfuran <3-> t0.78 108| Amorplrane<cis-4,1O-epoxy-> 28.0.5 l48l
,\cetr'lacetophenone <p-> 26.47 t444 Amorplrane<trans-4,l0-epoxy-> 2l .91 1478
-\cen'll-uran<2-> 0-5.19 0909 Atnorphcne<u-> 28.13 1483
Acetvlpl'rrole<2-> 09;79 1054 Amorplrene<6-> 29.29 l5l I
Aciphyllene 28.89 l50l Arnorphene<y-> 28.63 1495
Acora-2.-1( l5)-diene 26.50 1411 A myl acetate 05.25 09ll
Acora-3.7(l4)-diene 24.93 1407 Anryl cinnamaldehyde <(tj)-> 35.48 1661
Acoradiene<10-epiB-> 21.73 1474 Amyl cinnarrralclehycle <(.2)-> 34.73 1647
Acoradiene<a-> 27.32 1464 Anryl cirrnanrylalcohol <u-> 36.06 1682
Acoradiene<p-> 27.52 1469 Andro encecalinol 35.80 1675
Acoradienol<p-> 39.03 l7(t2 Anetholc <(E)-> 19.43 1282
Acorenol <c{-> 34.13 1632 Anethole<(7.)-> 17.96 1249
Acorenol <p-> 34.30 1636 Angustifolenone 14.36 | 167
.\corenone 36.45 l(t92 Arrgustione 23.38 1372
.\corenoneB 36.64 1697 Angustione<dehydro-> 23.80 l38l
Acorone 41.09 l8l9 Anisaldehyde <p-> 17.8.5 1247
Acorone <iso-> 40.83 t8 t 2 Anisaldehyde <o-> 17..50 1239
Acrolein<(3E)-(2-furyl)-> I 1.80 t107 Anisalclchyclc <p->, dinrethylacetal 22.93 l36l
Adanrantanonc <2-> 20.64 l3l0 Anisalclehyde,<meta-> 15.57 l l9-5
A-earoluran<u-> 30.79 t -548 A ni sol e 05.32 0913
Agarospirol 34.69 1646 Anisolc<p-but-(1E)-enyl-> 23.74 1380
Ageratochrclrnene 3.5.
| 6 t658 Anisole<p-nrcthyl-> 08.34 l0 | 5
Agcratochronrene <6-demethoxy-> 21.t8 146l Anisyl ac:etate <p-> 25.13 l4l2
Ag-ulomerone 36.69 t698 A ni syl al cohol< meta-> 19.3l | 280
Alaskene<u-> 29.31 1512 Anisyl alcohol<p-> 19.24 1278
Alaskene<B-> 28.75 t498 Anisyl forrnate 21.52 1330
AIlo-cedlol 32.45 t.589 Anisyl methylketone 23.15 1380
Allo-hedycaryol 32.45 r.589 Anisyl propanoate 29.26 l -5l0
Alloevodione 43.34 1883 Anthranilate<ethyl-> 25.23 l4l4
Allohimachalol 35.25 1661 Anthranilate<rncthyl-> 21.72 1334
APyrcrrclix
I: AlphnhcticalList ol'Contrrouncls
il
Ct r t t t t t t o n N i t r t t c RT AI Conirnon Narre RT Al
Apiolc 3.5.87 1617 Bcnzcncaccticacicl,cthyl ester. 17.69 t243
Apockr;tliylcrrc 3(r.99 1706 Bcnzcrrcacelicacid.ntcthylesterr t1.73 | 17.5
Apo liu'rresal<( lJ)-clihyclro-> 29.65 t-s20 Bcnzcncacctonitr.ilc <-1-nrcthoxy-> 23.42 t373
ApoI arncsal<(Z)-cli hycfi.o-> 28.11 t498 Bcnzcrrcnrcthanol<tr-nicthyl-> 0L).92 | 0.s7
Apo Iitlncsol<( [i)-clihvch.o-> 32.52 t-590 B crrzencaccti caci cl ,3-nrethyl phcnyl estcr
41. 31 lg2l
Apolirlncsol<(Z)-dihyclro-> 3t .72 1.57 | B cnzencacctoni tri l e 12.94 | t.r4
Aplitonc <( E)-> 37.{).t t70t3 Ilerrzencnte-than<il <2-hyclroxy-> 18.22 l2.s.s
Alrritrrnc<(l)-> 36.31 l(rti9 Bcnzerrcrnrcthanol <zl-lrych.oxy-> 2t.76 t33.5
At'ltozol<enclo-> 26.(\) l.l.l3 Bcnzencrncthan<tl <3-hych.oxy-> 21.92 | 339
All-rozol<cxo-> 26.81 1452 Bcnzollran <2.-3-di rrrethyl-> 16.64 l2l9
Arbuscrrlonc <cis-> 09.-5 | 1046 Ilenzoin zl0.-53 t803
Ar'busc:lrlone <lrans-> 10.22 106(r B onzophcnone 33.92 1626
Ari s t oloc hc nc 28.28 t487 Bcnzyl acctatc | 3.96 | t.57
A li slt'lrrclrcrrc<1.-5-d i -cPi-> 27.63 t41l Bcnzylacctylacetate 28.24 l48fi
Ari s t olonc 39.0| 1762 B enzylal cohol 08.71 1026
Aloruitclcnclrane <clchycho-> 27.1(t l-l(r0 Benzylbenzoatc 38.90 115()
Arrrrrraclctrdrene 26.21 1.1-19 Benzylbutan()ate 22.13 13,13
Atornadcnclrcnc <allo-> 2l .01 14.58 B cnzylci nnarnate 50.22 2092
Aronraclcncll'cnc <c1.lox icle-allo-> 31.42 | (r-19 Bcnzr'lltl'rnate 10.43 l0l I
Artcdouglasia oxicleA 30.22 l-s34 lJcnzt,Iisobutanoate 20.09 1297
Artcckruglasiu oxiclcB 32.t2 t.5t3 | 13cnzyl propanoate 18.29 t25l
Altcckruglasia oxidc C 2e.14 t 522 B cnzylsal i cyl ate 42,68 t864
Artedou- ulasox iaid el ) 31.22 t.s.5tt llcnzyl tiglatc 28.7| | 191
A| tc nr is c olc 06.96 091| Bcrgalnal o().67 l0-5|
Artqrisia alcohol 10.16 t0ti0 Rcrgantt'rtcne <0-cis-> 2.s.l0 l4l I
Ar'lclnisiakctone 09.88 t0.56 Berganrrtene <c{-tl.ans-> 25.99 1432
Al tcnt is iat r ic nc 0-5.(rI 0923 llcrgarnotol<(Z)-c-trans-> 36..r7 t69r)
Arl.cnrisylacetate 14.48 | | (r9 Belgantotolacctate<(Z,1-a-rrans-> 40.20 1794
Asalic in 28.62 t49.s Rerr-qirptenc 49.l0 2056
Asaronc<(E)-> .1.5.79 l(r7.5 llergaptene<iso-> 48.39 2033
Asar'<rne <(Z)-> 33.-53 t6t6 Beyercne 44.98 193l
Asaronc<y-> 3l .78 1572 13icycIogerrnacl'enc 28.83 t-500
Ascaliclolglycol <tlans-> f 8.7| 1266 Bifloratriene 46.56 t977
Ascalickrle n.28 t234 B i otol < p-> 33.39 l6t2
Atlantol<p-> 33.20 1608 Biotonc<B-> 3.r.l8 1607
Atlantone<(11)-rr-> :19..59 l77l B i phcnyl 23.-sI t37.5
Atlantone<(E)-T-> 36.98 1706 Ilisabol-l 1-ol <B-> 35.47 l6(t7
At.fantonc<(./.)-u-> 37.39 t7 t7 B i saboladicn - | 2-ol <2.7( | 4)-> 38.9-s n60
Atlantone<(.7y-y-s 3(r.-5l 16()1 Bisabtrf irdicn-4-ol<2.(7'Z)-> 33. 60 t6 | 8
Atlantone<p-> 3.5..53 l668 B i sahol atri cn-l -ol -4-one< 2,7(14),10->1l .gj lg44
Atractylone 3.s.09 1657 Bisabolatrien-7-ol < t ,3,-5-> 32.9.5 t6{)|
Avocadynofr.rr"an 41.32 182(t Bisabolc-nal <0-> 39.2(t | 7(ru
Azu lc nc 20.1| t298 Bisabolene<(lt)-y-> 30.03 1529
llaeckcol 42..58 I 86| Bisaholcnu. <( Fi)-iso-1r-> 29.9(t 1.528
llakerol 26.17 1444 Bisabtrlene <(7)-u-> 29.O9 t.s06
l Ja nc r olt inone 39.2(t 1768 Il isah<rfcne <0-)-^t -> 29.40 r 5 t4
Barl-ratcnc <q.-> 21.92 1401 Bisabolene<B-> 29.04 1.50.5
Barhatcne<B-> 26.32 r440 [Sisabolcnol <p-> 40.0t t789
Bazzanenc(B-> 29.62 l5 t 9 Bisabolol<u-> 36.17 I (r8.5
Benzalclchydc 06.43 09.52 llisabolol <B-> 35.14 t674
13cnzaldchycle. clirnethylacetal | 1.90 I t09 Bisabolol<cpi-{r-> 36.12 I (r83
Bcnzene< 1.3-clinrctlxrxy-> 11.27 | t6.5 Ilisahokrl<epi-B-> 3.5.(r0 l67O
.Licnzcne < 1,3-di nrcthclxy--5- Bisab<llolacetatc<0-> 40.33 r798
( l-nrethylethyl)- 21.37 1391 Uisabololacrctatc <cpi-c-> 40.48 l802
Benze:ne <2-urethoxycthyl-> 10.16 1080 Bisabololoxidc A <u-> 38..50 1748
Benzenc<pcntyl-> 13.73 | t52 BisahololoxiclcB <a-> 3.5.08 l (r.56
Bcnzcneacctalclclrydc 09.l4 103(r lJisarbolonc <6R.7R-> 38.24 n4(l
t: Adanrs;EssentialOil Componentsby GC/MS
CornmonNatte RT Conrmon Narne RT AI ru

Bisaholone<(rS,7R,> 38.52 1748 Cadina-1(6),4-diene<trans-> 27.11 1415
Bisabolt'rne oxideA <s-> 36.14 t684 Caclina- | .4-cliene <cis-> 28.62 1195
B trrneol 14.29 116.5 Cadina-1,4-diene <trans-> 30.r 8 r s 33
Bcrrnr'lacetate 19.62 1287 Cadincne 40.52 1803
Bornll angelate 31.44 1564 Caclinene<o-> 30.33 1537
Bo tn d i ol 3 6 .3 4 1 6 89 Cadinene<6-> 29.72 1522
Bo u rb o nanol < enc lo- l- > 2 9 .5 9 1 .5l 8 Cadinenc<y-> 29.35 t.513
B<rurhonanone 3l .32 | -56I Cadineneether<cis-> 30.94 1552
Bourbonene<B-> 24.05 l-387 Cadineneether<trans-> 3t .14 l-5-57
Bufnesene<c-> 29.20 l-509 Caclinol<u-> 34.93 1652
Bu l n e s ol 3 -5 .6 0 1 670 Caclinol<epi-o-> 34.38 1638
Ilutanal.2-methyl- 02.02 0654 Caff'eine 41.8.5 t84l
tsutancdiol<2.3-> 03.03 078-5 Calacorenc<u-> 30.62 ts44
Ilutanethiol<2-methyl-> 03.0-5 0787 Calacorene<B-> 31.43 t564
Butanoate<3-nrcthyl-2-hutenyl 2-mcthyl->13.08 1137 Calamenen- | 0-ol <cis-> 35.20 | 660
Butanoate<3-methyl-2-hutenyl 3-methyl->13.51 | l4l Calarnenen- | 0-ol <trans-> 3.5..5
I 1668
Butanoate<3-nrethylpentyl, 3-rncthyl-> l -5.86 1202 Calarrencn- | 0-one 36.82 1702
Butanoicacid 02.83 0163 Calamerncne < | 0. | | -epoxy-> 28.41 1491
Butanoicacid<2-methyl-> 03.7-5 0832 Cr larrrencne<.5-hydroxy-cis-> 31.22 t7l3
Butanoicacid,2-methyl-4-nrethylhexyl Calamenene<cis-> 30.II t.528
ester 20.40 t304 Calanrenene <trans-> 29.69 l52l
Butanoicacid,2-methyl-4-r-rrethylpentyl CalIitrisin<dihydlo-> 46.25 t968
ester 15.66 | 197 C al l i tri n 40.52 | 803
B utanone<3-hydroxy-4-phenyl-2-> 21.95 1339 C al l i tri si n 45.34 1941
Buten-I -ol <3-mcthyl-2-> 02.8.s 0765 Carneroonan-7u-ol 29.26 t.5t0
Buten-| -ol <3-nrethyl-2->, acetate 0.5.3.s 0914 Clarnphene 06.26 0946
Buten-I -ol <3-methyl-3-> 02.45 0723 Carnphenehydrate t3.43 l145
B utc-n-| -ol acetate<3-nrethyl--j-> 04..59 0880 Carnphenilone 10.70 1078
Buten-2-olacetate<2-methyl-3-> 02.88 0769 Camphenol<6-> 1t.98 |ltl
Butenoicacid.3-nrethyl-2- 04.60 0881 Campl.rcnone <(r-> 1t.32 109-5
But\'l acelate 03.31 0807 Canrpholenal<a-> t2.46 | 122
Bun I an,selate t0.94 1085 Camphor 13.28 I t4l
Butr I anlhranilate 33..56 t617 Carnphoricacid 34.20 1634
Butll hutanoate 07.-58 0993 Camphorquinone 19.93 t294
Butr I butyrr,llactate 22.51 I3-5.1 C anel l al 48.75 2045
Butll chrontone<2-> 40.97 1816 Capillene 28.53 1493
Butvl dodecanoate 39.92 1786 C api l l i n 34.35 t637
Bu n l h e pt anoat e t9.14 1289 Car-3-en-2-one 17.75 1244
Bu n 'l l e v ulinat e 17.86 1247 Caranone<cis-4-> 1.5.80 t200
Ilutr'l n-hexanoate <n-> t5.19 I 186 Caranone<trans-4-> 15.ff n96
Butr I penlanoate I l.l9 1092 Carene<6-2-> 01.84 t00t
B u tvl p ht halide < 3- > 34.72 t647 Carene<6-3-> OrJ.l0 t008
Bun'l propanoate 0.5.13 0907 Calissone 44.84 1926
Butr I ti-elate 12.(t8 | 127 Carotol 32.67 1594
Ilutvlatedhydroxyanisole 28.34 t488 Carpacin<(E)-> 32.63 l-593
Butr latedhydroxytoluene 29.43 1514 Carpacin<(Z)-> 30.46 1.540
B u n l i d enepht halide< ( 3 E )-> 37.39 l7l7 Carquejolacetate 20.12 1298
B utvlidene-phthalide <(]2) -> 3.5.65 167| Carvacrol 20.14 1298
Bun'rophenone t7.95 1249 Carvacrolacetate 23.32 t-170
Cahreuvaoxide A 26.50 1444 Carvacrol.ethyl cther 20.t0 1297
Cabreuvaoxide B 27.23 14(t2 Carvacrol,metlrylether 17.61 t24l
Cabreuvaoxide C 27.13 1166 Carvenone 18.2t 1255
Cabreuvaoxide I) 27.94 1419 Carvqol<cis-> 16,94 1226
Cadalene 3.5.80 1615 Carveol<trans-> 16.44 l2t5
Cadalene<8,9-cpoxide> 3s.77 1614 Carvorncnthyl acetatc<ncoiso-> 22.30 1347
Cadin-4-en-7-ol<cis-> 34.25 t63-s Carvone 17.53 1239
Cadina-| (6),4-diene<cis-> 21.18 1461 Carvonehydral.e 25.54 t422
Appendixl: Alphabeticall-ist ol'Compounds
l3
C otttttto ltNulu c RT AI Comrnon Nirnre RT AI

Carvoncoxicle<cis-> 13.,12 125() CenrhrcrreA <(37.)-> 46.16 | 96.5
Carvoncoxide <tlans-> 19.()2 1273 Chanrazulcne 37.87 1730
Carvolanacetone 11.12 1211 Chantigrene <a-> 28.{)(t l-503
Cat'r,otanace{one <6-lryclroxy-> 20.63 1309 Chanrigre ne <p-> 21.82 l4t6
Calvotanacetone <8-acctoxy-> 3l .44 l-564 Chamipinene <u-> 24.14 1396
Calvyl acctatc<c:is-> 23.08 l3(r-5 Chavibetolacctate 29.f30 1524
Car v v lac c t at c< t r a n s -> 2 1.9 5 l -139 Clhtrvicol 17.8-s t247
Carvyl propiu't()iltc <cis-> 2-5.48 1420 Chcnopocliol <o-> 42.36 18.s.5
Carvyl pr'opanoatc <trrurs-> 26.90 14.54 Chcnopocliol <B-> 40.80 r8l I
Car y olan- 8- ol 3 | .7 3 l -57| Chenopitdiol-(r-acctatc<c-> 45.99 1960
Caryophylla-4( | 2).8(l-j )-clicn--5o-ol -lzl.40 l(r39 Chenopocliol-(r-acctatc <B-> 4.3.-58 t890
Car y ophy lla- . 1( 1 2 ).8 (1 3 )-d i c n --5 8 -o l 3 4 .4 0 1639 fiht'ysanthenol <cis-> 14.06 | t60
Car y ophy llar < r e4. 8 u -c p o x y -> 2 5 .2 6 141.5 Chlysanthenonc | 2."s3 | t21
Calyophyllanc<4.8p-crpoxy-> 2.5.-59 1423 (' l rrysi rrrthcnyl i rcctl rtc
< ci s->
(l a ly oplr y llc ne f 8.-5| 126l
< ( I 1 )-> 2 .5 .3 6 l 1l 7 Chrystrnthenylacetate<trzrns-> l7.33 123-5
Calyophyllurc<(Z)-> 21.95 l40g C i neol e< | ,4-> 08.22 l0t2
Clarvo;rhyllcric < l4-hydroxyl/.)-> 3-5.4"5 | 66(r C i ne.ol< c 1.8-> 08.76 1026
Carvophyllene <lzl-hydroxy-,l.-5-clihyclrrr-> 3(r.98 li0(t Cineole<clchydro- | .8-> 01.45 0988
Caryr4rlrvllcnc < l4-hych'oxy-9-cpi-( lr)-> 3-5.-5-3 | (16g Ci nnarnalclchydc <( li)-> 18.74 t267
Calyophyllore<9-epi-(lr)-> 27.33 l4(t4 Clinnarnaldclryde <(lt )-p-nrcthoxy-> 3 r.38 1562
Caryoplryllcnc acctate 3(t.^7() l10l Cinnarrralcleh yde<(/,)-> 16.53 t2t7
C aly ophy llor cox ic l c 3 2 .1 6 l -5tt2 Ci nnarnalclehyde <2-hcxyl-(E)-> 38..s 1 1748
Calyophyllcnylalc:ohol 3 | .70 l-570 Ci nnanraldchyder<2-hcxyl-(Z)-> 39.12 1173
Calalpalactonc .5-1.-5-12lg9 Ci nnarlaltlchyde <a-nrcthyl->
(iatalponol
21.00 t3l8
48.08 2023 Cinnanralclehyde <hych.o-> 32.fJ8 t-599
Cat alponol < c pi- > 4 6 .9 4 l ggu Cinnanralclhyclc<4-hydroxy-3-n-rethoxy-> 37.78 ll.2g
Cat alpononc 4 3 .7 | l g94 C i nnarni caci d< (E )-> 26.80 1452
Cateclrol<3-rncrtlryl-> 18.20 12.54 Cinnarnylacc'tate <(U)-> 2(t.46 1413
Ccclr-8(l-5)-ep- | g-,t; 3,1.8-5 | (r.50 Cinnanrylacetale<(7)-> 24.10 1388
Ceclr-u(l-5)-en-9a-ol 34.83 l(r-50 Cinnantvlacetate<c-arnyl-> 38.82 1756
Ccd r - 8(1. 5) - c n- 9a -oa lc, c ta re 3 8 .2 6 l j 4l Cinnanrylalcohol<(I1)-> 20.36 t303
Cccflancr 26.31 | 441 C i nnarrrr,l al cohol< (Zl -> r8.38 t259
Ccclranc<cpi-> 2(t.62 l14l Citral <il inrcthoxy-( lJ)-> 21.90 | 338
C'cclraner-cliol <,3S.l3-> ,l-1.83 | ti97 Ci tlal <cli rncthoxy-(Z)-> 20.93 l3 t6
C cc lr lnc - diol < 8S . 1 4 -> 4 3 .-5 .1 l B 89 Citronc:llal 13.-58 I t48
Cclh'anol<-5-iso-> 3-5.68 1612 Citroncllene. <F-> 0(r.1.5 0942
Cech'anol<-5-neo-) 3(r.l,l I (r8,1 Ci tloncllene<tctt'ahyc'h.o-> 0-5.80 0930
Ccclurnont: <-5-> 34.00 l(r2fi Citronollicacicl 20.15 t3t2
Ccc lr lnor it lc< 8. 14 -> 3 0 .-5 0 l -5,1 I C i l roncl l ol 16.80 t223
Ccch'clr- l.l-ol <8-> 3(r.30 t(r8lJ Ci tnrnerl krl isobutilnoate 28.07 t482
C'cclrcrr- | 3-ol acetatc<8-> 3().91 l7tj8 Citronellylacetate 22.41 t3.50
Ccdlen-3-onc<2-cpic-> 33.90 l(t26 Ci tlonellyl antll"lnilate 52.93 2l80
Ccdrcn--l-onc <2-cpiB-> 34.-58 l64.} Citlonellylbutanoatc 30.0.5 t.s30
Ccclrcrn-9-onc <F-) 34.0-5 I (r30 (litroncllyl lirrlnatc
(lcdlcrral< 1.7-cliepiu->
18.92 127|
31.42 t(r39 Ci trorrei lyl oxy-acctalclelryde 2.s.0 I | 409
Ccclrcnc<n-> 2-5.0(r l4l0 []itroncllylpcntanoatc 33.U2 l(t21
Ccrllc nc< p- > 2 5 .4 2 l 4l 9 Citloncllyl llt'()palt()ate 26.11 1444
Cctllcncc;roxillsqs->, 31.84 l5j1 C i troncl l ylti gl ate< 1l i )-> 3-5.46 t666
C cclr c nc c p< t x idc 3 3 .1 2 162l C i tr' oncl l yl
ti gl arc< (Z)-> 3.s.06 t6-56
Cccflol 32.91 ta)(X) C i tronet n.30 1234
C cd lol< c pi- > 3 j .5 9 l (r 18 Clovcne<q'-rlco-> 26.80 1152
C cc llr r x y dc 3 l .2 3 l l 13 C oahui l ensol 14.3-s 1166
C cc f ly ac
l c t at c 3 9 .2| 1767 C oahui l cnsoltrcthyl
. ethcr 16.64 tzl{)
(iccllyl rncllrylkct()ne 39.-50 1115 Cogei.icrenc r9.48 t283
C cl c s t olidc 1 7 .5 5 1122 C ol urnel l al i n 45.70 1952
(l cr nblc nc 4 -5 .2 1 l 93i Colulncllarin <clih;,dro-> 43.9-5 1900
C crr r hr c ncA < ( 3H) -> 4 _ 5 .5 5 l ()l l Clrrnrnunicacicl .s8.35 2365
Ctlmntcrn Name RT AI Common Name RT Al

Conalomerone 40.60 180.5 Ctrrcumen-12-ol <B-(Z)-> 38.75 t754
Conilervlalcohol<(E)-> 37.98 1733 Curcumen-I 2-ol <y-(Z)-> 37.80 1728
Conif-ervlalcohol <(Z)-> 3.5.48 1667 Curcurnen-l-5-al<y-> 39.19 1766
f opaen-| I -ol <u-> 30.43 t -539 Curcumen-l -5-al<ar-> 31.21 t7 t2
ft paen-4cr-ol<B-> 32.49 t.590 Curcurnenc<ar-> 27.9(t 1479
frrpaene (c-) 23.49 1374 Curcurnenc<B-> 29.42 t.514
glrpaene<B-> 25.90 1430 Curcumene<y-> 28,04 t48l
Cortrc-alene <cr-> 33.7.5 1622 Curcumenol 37.95 1733
Co<tol<cr-> 39.42 1173 Curcuphenol 37.38 t7 t7
Cosllrl qB->' 39.t.5 1',766 Curzercne 28.79 1499
Costtrl<v-> 38.40 lt45 Curzeren<.rne 33.1| 1605
Crrumarin 25,97 1432 Cyclamenaldchyde 2t .10 t4.59
Coumarin<3-nrethyl-> 28.65 1495 Cyclohutanone 02.00 0650
Coumarin<3.4-dihydro-> 23.66 1378 Cyclocitral <B-> t6..5.5 l2t7
Coumarin<4-hydroxy-> 40.22 1795 Cyclocolorenone 38.92 1759
Coumarin<6-ntethyl-> 30.98 1.553 Cyclocolu'enone <epi-> 39.48 1774
Counrarin<7-hydroxy-> 41.69 t836 Cyclodoclecanone 28.92 1502
Coumarin <7-hydroxy-4-methyl-> 46.69 l98l Cyclo-ueranylacelate<0-> 28.02 t480
Coumarin<7-hydroxy-4,8-dimethyl-> 47.75 2013 Cyclohexadecanolide 45.07 193.1
Cresol<2-rnethoxy-p-> t5.27 I r88 Cyclohexacliene <2-methyl-| ,3-> 02.81 0160
Cresol<meta-> 10.4.5 1072 Cyclohexacliene 02.90 0711
Cresol<o-> 09.6.5 10.50 Cycfohexanedione <3-methyl-|,2-> 10.94 1085
Cresol<p-> 10.43 1071 Cyckrhexanol <3-methyl-> 05.9.5 093.5
Cresolacetate<meta-> 14.00 I1.58 Cycfohexanolacetateccis-2-tert-butyl-> 19.8-5 1292
Cresol acetate<o-> 12.98 | 134 Cycfohexanofacetate<trans-2-tert-butyl->20.74 l3l2
Cresol acetate<p-> 14.3.5 | l(t6 Cyclohexanone <3-methyl-> 06.21 0945
Crescrlmethyl ether<o-> 0l .96 1005 Cyclohexene <3-ntethylene-> 03.03 0785
Cresoloctanoate<p-> 39..s6 1777 Cyclohexene <3,3,-5-trirrethyl-> 03.60 0824
Cresolacetate<methyl-> 24.16 1403 Cyclohexene<3,-5,-5-trimethyl-> 03.14 0832
Cresol isobutyrate<p-> 20.42 130.5 Cyclohexylanlhranilate 43.22 18130
Crrrqeacin 21.04 1457 Cyclohexyl forrnate 06.49 0954
Crrptomeridiol 40.86 1813 Cyclohexyl propanoate t2.79 l r 30
Cn"ptomeric'rne 37.62 t724 Cycloisolongiltrl--5-ol <frans-> 29.35 1.513
Cn'ptone t5.07 I t83 Cycloisokrngilirlene <didehydlo-> 20.96 l3l7
Cn ptone <.1-ht'droxy-> 20.83 l3t4 Cyclopent-2-en-| -one <2-pentyl-> 19.69 1288
Cubehan-I I -ol 32.70 t -59-5 Cycfopent-2-enone<5-melhylene-2,3,4,4-
Cuhehene<a-> 22.33 1345 tetranrethyl-> l5,07 | 183
Cuhebene<p-> 24.04 t387 CycIopentaclecanol idt: 41.56 t832
Cubehl 29.41 1514 Cyclopentadiene carboxylicacid <3,4,-5,-5-
Cuhebol< 1O-epi-> 30.l9 r -533 tetramcthyl -l ,3-> | 9.53 128- 5
Cuhebol<epi-> 28.5.5 1193 Cyclopentaneclione <3-rne(hyl-l,2-> 08.43 l0l7
Cutrenol 34.63 1645 Cyclopentanol 03.04 0786
Cur 33.60 l6r8 Cyclopcntene <3,-5-dirnethylene-1,4,4-
-bnol
C u h e n o<
l l- epi- > 33.9.5 1621 trimethyl-> 0.5.83 0931
Cuhitc-ne 43.l-s I878 Cyclosativene 23.25 t36e
Cumacrene 27.57 1470 Cycloseychellene 21.90 t406
Cumene 0.5.63 0924 Cymen-7-ol<p-> 19.74 1289
Cunrenol<m-> | 6.8-5 1224 Cymen-7-olacctate<p-> 25.51 l42l
Cumenol<o-> 1.5.6l 1196 Cymen-8-ol<meta-> 14.78 1176
Cumin aldehyde l1 .47 t238 Cyrnen-8-ol<p-> 14.91 ll79
Cuparenal 38.64 l751 Cynen-9-ol<p-> | 5.98 1204
Cuparene 29.00 1.504 Cymene<2,5-dimethoxy-p-> 25.66 1424
Cuparernic acid 45.02 1932 Cymenc<o-> 08.59 1022
Cuprenen-| -ol <4-> 3(t.45 l(t92 Cymene<p-> 08.-53 1020
Cuprenene<o-> 29.03 1.50.5 Cynrenene<nleta-> | 0.82 | 082
Cuprenene<6-> 30..54 1542 Cymenene<p-> I I .09 1089
Cuprenene<y-> 30.14 1532 Cyperene 24.54 l398
IIf-
Appendixl: Alphabeticall.ist of Compounds
l-5
Conrnron Naue RT AI Connron Naure RT AI

Cypctolunclonc 36.-5(1 169-5 I)codiirone 36.68 l698
l)iunascenone <( lt)-p-> 23.81 I 383 l)esnrethoxy cncecalin 34.68 t616
I)arrrasccnon c <(/.)-9-> 22.89 t36l l)ichlorohenzcnc < | .4-> 08.t8 l0ll
L)atrnscotrc <(H)-s-> 24.28 t392 l)ichktrrtethanc 01.99 0647
l)anrascotrc<( 11)-B-> 25.11 t4 | 3 I)ictantine 44.97 1930
I)arnascone <(7,\-a-> 22.(t1 135.5 l )i ctamnol 25.79 1428
[)anrasconc <(l)-F-> 24.00 1386 [)ictanrnol<8-cpi-> 23.69 1319
l)aLrca-4( | | ),7-cliene <trans-> 3r.il t.s.56 Dicyclohexylanrinc 25.33 t4t1
I)auc a- 4( I | ) , 8- di e n c 30.0.5 t-530 l)iethyl phrhalare (plastizer) 32.-50 t590
Dauca-5.8-diene 21.60 l41l l )i ethylsucci nate 14.76 | 176
l )auc c ne 23.71 t380 l)ifirrlirryl sulllcle 27.10 1459
I)aucol 34.47 t61l I)ihydro agalolirran<zlu-hydroxy-> 34.81 l65|
I)avana.his-ethcr 26.13 14.s0 I)ihyclroagarolirran <B-> 28.9.5 t -503
|)avanalulan<cis, thrc<l-> 25.23 l4l1 l)ihydro carveol t.5.4.s | 192
I)avanolacetale 36.32 t689 I)ihydrocarvcol<iso-> I (r.34 1212
l )a v anoll) | ( is or re r| ; 33.47 16r.5 t)ihyclrocarvcol<neo-> 15.47 | t93
I)avanoll)2 (isorner2) 33.95 1627 | )ihydlo carvcol<nco-iso-> f 6.93 1226
| )avanone 32.37 t.sri7 Dihyclrocarveol acctilte 20.48 l.l0(r
I)avanotrc<nor-> 17.02 1228 | )i hydrrrcarvcoli tccl al c 21.36 1326
I)avanoneB 3l ..1(r 1.564 l)ihydro carveolacelate<nco-> 20.48 | 306
I)avanone-2-ol <p-> 37.4t I7ln T)i l tydl trC arvcolacctatc< ncoi so-> 22.69 t3-5(r
l)ec-| -en-3-ol 14.79 | t71 I)ihydro carvonc<cis-> 15.41 r le l
l)cc-9-cn-I -ol 18.-57 1263 l)ihyclro carvonc<trans-> | .5.80 I 200
I )ccaclicnal<(2li.4E)-> 20.87 t3 t.5 I)ihydrocilroncllol l.s.5.s l19+
I )ccacfi enal <(28.47,)-> f 9.86 1292 I)ilrydrocitronellolacetate 2 1.0,1 l3l9
l)ccaclicnol<(211"4H)-> 2t.01 t3 t9 l)ihydro rnyrcenol 10.3.s t069
l)ccalactone<6-> 28..55 l,t9.l l)ihydro myrceuolacctate 16.39 l2t4
I)ecalactonc<y-> 27.35 l4(r-5 l)i h-vdlolearrrI ulirrr<-l-cpi-cis-> 28.80 1499
[)ccalactonc<y-rnctlryl-y-> 28.08 1482 l )i l tycl roangel i ci<n2' .3' .3' -ti nrcthyl -2' .3'43.
-> ( r 8 I 893
l)ecanal<n-> | 5.83 | 20r I)ihydroatlantone <(Ir)-10,I I -> 3.5..52 1668
I)ecarrc< | . I -clintethoxy-> 2.1.52 1.17.5 l) i hyclroi s<r.j astnone 21.91 13.10
I)ecanc'<n-> 07.11 1000 l)ilrydroagarofuran <cis-> 29.60 1.519
l )c c anc c liol< 1. 10- > 30.7.5 | 541 l )i l l api ol e 33.(16 1620
I)ccanoicacid 23.02 l3(r4 I)i l l ethcr t.s.lt il84
I)ccanol<2-> 15.12 il 98 l)inrcthoxy,-5-vi nyt-1,2-benzodioxide
I)ccanol<J-> l-5.(r0 I 196 <4,6-> 34.94 t6.53
I)ccanol<n-> t8.73 1266 Dinrcthoxybenzenc < | .4-> 14.12 I l(rI
l)ccanorrc<2-> 1.5.38 |190 D i rrrethyl ani l i nc< 2.6-> 14.2t I t63
l)ccanonc<3,> 1.5.r6 ll85 I)irrrethylphcnc(lrylaccate <o,.o-> 21.01 t3 t9
I)ccen-l-ol <(2E)-> t[J.80 1268 Dinretlrylplrcnol<2.6-> 11.74 l r06
I)ercen- I -ol <(411)-> t8.38 1259 l)inrethylsfyrene<2.5-> 11.44 1099
l)eccn-f -ol <(47.)-> I 8.24 125.s l)i rncthyl-3-llentanonc <2.4-> 03.06 07tt8
|)eccn-2-onc<(3H)-> 17.30 1231 I)i rncthyl-4-lrcptanont: <3,5-> 07.02 0913
l)ccenal<(211)-> lft.44 126{) l)isull'iclc,cliphenyl 4 r .30 1825
I)c c c nal< ( 4E ) - > t.5.60 1196 I)isulllde,clipropyl r f .60 1102
l)ecenal<(4E)->,clicthylacclal 27.13 1414 l)ocosane<n-> 53.-54 2200
f)cccnal<(42)-> t.s.48 lt93 l )ocoscne< 1-> 53.22 2 t89
l)cccnal<(4/,)->, clietlrylacetal 21.05 1451 I)odecarlie n- l-al <(27.68)-> 26.51 t44-5
I)eccrraf<(77)-> 15.11 ll99 I)oclccaclicnal <(2F..411 )-> 29.5(t 1.518
I)c c ene< 1- > |t].39 098(r I)odecaclienol <(2B.4fl)-> 29.11 1523
I)cccnoicacicl<9-> 22.80 t3.s9 l)oclecalactone <6-> 36.9r 1704
l)ccenylacetatc<(2E)-> 24.96 r40[r I)oclc.calactonc <y-> 3.s.85 1676
l)ccenylacctatc<9-> 24.57 t399 | )oclccanal 24.95 1,108
l)ecyl iicctatc 21.91 | 107 I)oclccane <n-> t5.11 t2(x)
I)ec y lant hr anilate .54.7.5 2241 l)odecanoicacid 3l .47 1.565
I)c'cylplopanoatc, 2ti.t39 t-50| [)oclecanol <n-> 27.52 t469
l)endrolasin 3|.69 l-s70 I)odecanone <3-> 24.t5 1389
l6 Adams: EssentialOil Componentsby GC/MS
Comnron Nanre RT Comrnon Narue RT

Dodecen-l-ol<(2E)-> 27.55 14(t9 F,tlrylbutanoate 03.22 0802
I)odecenal<(2R)-> 27.33 1464 Ethyf chromone<2-> 33.42 |6 | 3
f)odecene<l -> 15.25 I 187 F,tlrylchrysanthemunrate <cis-> 18.87 1270
I)odecenylacetate<(2ti)-> 33.20 1608 Ethyl chrysanthcmumate <trans-> 19.| 8 1217
I)odecyl acetate 33.11 1607 Ethyl cinnamare <(E)-> 27.31 1465
Dofabradiene 46.42 1973 Etlrylcinnamate<(Z)-> 23.-5-5 1376
[)ofabrndiene <13-epi-> 47.35 2000 Ethyl decanoate 24.40 139-5
I)oh'iacontane 78.48 3200 Ethyf dodecanoate 32.68 1594
Dracunculilbliol<cis-> 30.-50 1541 Ethyl ether 01.63 0529
I)racunculifoliol<1O-epi-cis-> 30.45 1,540 IJtlrylfuran <2-> 02.25 0702
Drinr-8(l2)-ene 28.45 1491 Irthyl geranate 24.37 1394
I)rinrenin 45.34 1941 H,thylhcptanoate l 1.40 1097
Dri n renol 3 9 .1 6 1766 Ethyl hex-(2E)-enoate 09.20 1038
Drimenone 40.12 1792 Ethyl hexadecanoate 47.Ct9 1992
I)uprezianen-3-one <2-epi-B-> 34.42 1639 Ethyf hexanoate 07 .11 0997
I)uprezianene <o-> 24.07 1387 Ethyf hexanoicacid <2-> 12.30 11 19
Duprezianene <B-> 25.-51 l42l Ethyl hexyl acetate<2-> 13.-59 | 149
Eicosane<n-> 47.33 2000 Ethyf hydroquinone 25J9 1413
Eicosene<l -> 4(t.92 1987 Ethyl isovalerate 04.04 0849
Elerna-l ,3-dien-8-ol<7-acetoxy-> 39.89 1786 Hthyllcvulinate 09.64 10-50
El e m ene 2 4 .1 5 1389 Ethyf menthone<2-> 19,34 1280
Elemene<6-> 21.77 133-5 Erfrylnerolare 22.48 l3-5l
Elemene<y-> 26.08 1434 Ethyl ocr(2li)-enoate 17.80 1245
Rfenrenone <cis-B-> 32.45 l-589 Ethyl oct-(22)-enoare 1.5.75 1199
Eferrenone<trans-B-> 32.99 l60l lJthyloctadecanoate 53.43 2196
Elerlicin 3l .09 l -5-5-5 Ethyl ootanoate l -5.63 | 196
Elernicin<6-methoxy-> 32.10 1-59-5 Ethyl penr-4-en0are 04.6-5 0884
Elenrodiol<8s- l | -> 38.44 1146 H,rhylpenranoare 04.96 0901
El e n r ol 3 0 .7 8 1548 Hthyf propanoate 02.34 07 | |
Eferrrolacetate 35.91 1680 Ethyf salicylate 18.72 1266
Elshrrltziaketone l -5.86 1202 Etlrylsorbate I 1.20 1092
Elsholtziaketone<p-dehydro-> 20.29 1302 h,thyltetraclecanoate 40.25 1795
Elsholtziaketonc<a-dehydro-> 16.55 '1217 Ethyl tiglate 0.5.78 0929
En ce c alin 4 2 ,7 5 1866 Ethyl-(2E)-decenoate 25.33 1417
Epizonarene 28.88 l-50| Etl'ryl-(28,42)-decaclienoate 27.45 1467
Epoxv-ocimene <(E)-> 13. 10 l l37 lrthyl-(3E)-hexenoate 07.91 1003
Epoxy-ocirnene <(Z)-> 12.72 1128 Iithyl-(48)-clecenoate 23.75 1380
Epoxy-pseudoisoerlgenyl 43.7-5
2-methylbutyrate 189-5 Ethyl-(4tr)-octcnoate 15.12 I 184
Epoxy-pseudoisoeugenylisobutyrate 40.16 1193 Ethyl-2-ocrynoare 19.40 1282
tp o xy m y r c ene< 6, J-> 1 1 .1 4 1090 trthyl-3(2-furyl)-propanoate 14.8-5 | 178
Eremoligenol 34.04 1629 Ethylenebrassylate 4l .82 2015
Eremophilakekrne 31.22 1-5-58 BtrcaLvone 13.4'7 1146
Erernophilone 38.02 1734 Euclesm-I I -en-44,6s-diol 40.70 | 808
IJremophilone <8-hydroxy-> 42.05 1846 Eudesrr-7(| l)-en-4-ol 36.74 1700
Erenrophilone <8-hydroxy-dihydro-> 38.80 1756 Eudesrn-7( I l)-en-4-ol.acetate 41.80 | 839
Ethoxyethanol<2-> 02.33 0111 lludesna-4(15),7-dien-lp-ol(irnpure) 36.27 1687
Ethoxy ethyl acetate<2-> 0-5.03 0903 Iluclesnra-6,1l-diene <cis-> 28.36 1489
Ethyl2-nrethylpentanoate 0-5.81 0930 Eudesrnolcl0-cpiy-> 33.77 1622
ErhYl2-methyl-2-penrenoate <(E)-> 08.41 l0l7 Eudesmol<5-epi-7-epicr-> 33.17 1607
Eth1,l2-rncthyl-2-pentenoate <(7)-> 08.5| l0l9 Eudesmol<7-epia-> 35.29 1662
Ethl{ 2-merhyl-4-pentenoate 0-5.53 0921 Eudesrnol<c-> 34.91 1652
Ethr'l2-nonynoate 23.78 138| fiuclesmol<B-> 34.19 1649
Ethr| 3-hydroxyhexanoate 12.40 | l2l Eudesmol<dihydro-> 35.25 166l
Ethr'l -l-methylpentanoate 06.34 0949 F,udesrnol<y-> 34.08 1630
Ethl'l acetate 0l .80 0606 Eudesnrolacetate<0-> 40.21 1794
Ethrl acetophenone <p-> 19.30 1219 Eudesnrolacetate<B-> 40.11 1792
Ethrl henzoate 14.47 I 169 Eudcsmolacetate<v-> 39.80 1783
III-
Appcrrclixl: AlplrabcticalI-istol' Cornpounds tt
(lonrnou Narnc RT AI Cotnr.rron Narne RT AI

IJtrgcnol 22.10 l3-5(r F'urlin'aI <-5-rrrelhyl-> 06..56 09.57
Hus c nol< dihv dlo-> 2 3 .1 5 l -3fi 6 Furlurylacetate 01.42 0987
IJtt-ucnol acctirtc 29.10 | 52 | Ijullirryl acclone 11.94 | t80
Huscnolacctatc<clihyclro-> 30.30 153(r Furlirfyl bulanoate t4..50 | 170
litrpatoliochl'olncuc. 38.98 116l Fur'lirrylhcptanoatc 27.12 1466
lrvoclionc 4.1.01i 1904 F-ur'lirrylhexanoate 23.16 1367
Fi v or lonc 2 1 .8 -5 t337 F-urfirylrnethylsulllcle 01.71 0998
Ilxalaracin 35.0| 16-5-5 Furliryl octan(')ate 31.52 l -5(16
Fafcalinol<(/-)-> 48.44 2035 Furfin'yl pcntan<l.rtc 18.82 1269
I jalcrral 29.18 l -508 l.urluryl proltionate 10.88 I083
Falncsal<(21i.(rl-r)-> 38.22 1140 F-ulr4relar-uone A 30.39 r.538
l i a l nc s af< ( 2/ ^6F . 1 -> 3 7 .:l l 171.5 Gci.iercnc r3.t5 I t38
l,'irrncsal <(2'/^67,)-> 36.13 l(r84 Gcosrnin 24.57 r399
f i n rr r c s al
< ( 2L^67.)-> 3 1.2 2 ll l3 Clcranial 18.62 1264
liirrrrescrrc <(B)-P-> 26.92 14-54 Gcraniol 17.95 1249
Farncscnc <(fr.tl)-o-> 29.03 l-50-5 Gcranyl2-nrcthylbutanoate 32.93 | 601
liarrrcscnc <U,\-B-> 26.33 1440 Geranylacetate 23.70 1379
lianrcsoicacid <(2lr,6lr)-> 40.98 l8 l6 Geranyl acct()ne 26.8.5 l4.53
l ra rnc s ol< ( 2H. 6ll )-> 3 8 .3 0 1742 Ccranylanthranilate 54.0,1 2211
Fa rnes of < ( 2E . 67\-> 3 l .2 7 1l 11 Gcranylbenzoatc 45.92 1958
l-itt'ncsof <(27^6t\)-> 37.58 1722 Gcranyl butanoatc 3 f .36 1562
Frrrrcsrrl<(2/^6'/,)-> 36.(rtt l(r98 Ccranyl forntatc 20.tl t298
l'arncsol<2.3-clihyclro-> 36.3| l6tt8 Gcranylisobutanoate 29.41 t.5t4
Falncsylacctate<(2li.6lt1-> 12.(ll ltt45 Ge,r'anyl isovalcrate 3.1. t5 1606
Fa rnc s yac l c t at r<r( 2 /.,6 b 1 -> 1 1 .1 6 l tt2l Gerranyl Iinalool<(Ii,I1)-> .18.f (r 2026
F;arncsyl acct()nc<(-58,911)-> 44.31 l9l3 Geranyflinalool<(l'.,'11-> 4(t.90 1987
: Firlnesyfacct()nc) <(5h.97,)-> 4-1.4.5 18136 Gcranyllinalool<(/.,F.)->
I 47.29 1998
I Falnesylacet()ne<(-52.98)-> 43.-5.5 1889 Ccranyllinalurl <(/.,'/,)-> 4-5.98 1960
Farnesyfacct()llc<(7.2)-> 42.54 18(10 Ceranyl propanoatc 27.82 1416
Fcrtchcne <o.-> (\6.22 094-5 Geranylti_elate 36..59 l69(r
Fenclrocanrph(n'()nc <o.-> 11.69 | 104 Geranylvalerate 3.s.02 16.5.5
Fcnchol<2-elhyl-cnclo-> 19.62 l28l Cerrnacla-4( l-5).-5,l0( l4)-trien-l o-ol 36.I 8 168.5
Fenchol<2-ethyl-cxo-> 20.08 1297 Cc'rnracleneA 29.18 | -508
Fcrnc hol < c nc lo- > 1 2 .1 0 | | 14 Gerrnacrcnell 31.24 1559
Fenclrol<exo-> 12.28 1 I 18 GernracrencI) 28.l.s 1484
Fcnc hor r e 1 0 .8 8 1083 Gerrnacrenc l)-4-ol 3 t.8-5 1574
Fcnchylacctater <endo-> 16.57 12| 8 Gernracrone 3(r.48 1(r93
I'enchylacctate<cxo-> 17.09 1229 Cilcenol 32.33 t.586
Fert'rtrginol <(r-kcto-> 60.84 2456 Gl obul ol 32.50 t590
Fcrluginol<(r,7-clehydro-> 56.92 23 l5 Glycerol 06.3.5 09.50
Fcrrtr-uinol <cis-> 58.50 2370 Gossonotol 34.28 1636
Fcrmginol<trilns-> ^57.39 2331 Crandillolenc 52.76 2174
Fcrruginolacctate<cis-> -59.63 2411 Guaia-3,| 0( | 4)-clien-ll -ol 3.5.84 1676
Fcrruginolacctatc<trans-> -58.28 2363 Guaia-3.l0( l4)-dicne<9, I l -epoxy-> 32.94 | 60 |
Fcrtrfa lactone| 46.45 1914 Guaia-3,9-dicn- I | -ol <cis-> 34.75 t648
Flavesone 30.(19 l-5,15 Guaiacol<o-> | | .00 1087
Flourcnsircliol 42.84 1869 Guaiacol<p-r'inyl-> 20.59 t309
Fo enic ulin 3 -5 .8 7 1617 Guaiacolacetate<o-> 18.-51 t26l
F<rkienol 32.73 1596 Guaiadiene <(r,9-> 26.39 1142
Fragr anol 1 6 .3 9 1214 Guai azul ene 39.66 t779
Fruitaletrr(=ctlryl2-rlethyl-3-pcntcnoate) 0(r.00 0937 Gr-raiene <a.-> 2(>.20 1437
Furreblenc <2-cpi-u-> 23.75 1380 Guiriene<cis-B-> 2tt.5l 1492
Fu nc hr c ne < 2- epi-B-> 2 5 .1 | l 4l 1 Guaicne<trans-B-> 28.92 t.502
I'ttncbrcnc<s-> 24.7| 1402 Guai ol 32.92 l6(X)
Fu n ef ' r lene <B-> 2 5 .1 9 l 4l 3 Guaiolacetate 37.68 1725
Furan<2-acetyl--5-rrrethyl-> 08.9-5 103| Curiunene<o-> 2.s.00 1409
Furl'utal 03.67 082tt Cr-u'iunenc <p-> 25.95 l43I
r8 Adarns:EssentialOil Componentsby GC/MS
CornrnonName RT Al Cornmon Narne RT AI

Gurjunene<y-> 21.80 1475 Hexacleccne < | -> 32.44 t.s88
Cymnomitrol 3.s.t 6 l6-58 Hcxadecylacetate 41.45 2003
Gymnornitrone 34.10 l 63l Hcxadienal<(2E,4ll)-> 05.14 0907
Hasmigone<(E)-> 21.68 l333 Hcxadienol<( 2Il,4E)-> 05.29 09t2
Hasrnigone <(Z)-> 21.39 1327 Hexadienolacetate<(2E,4E)-> l0.ll l0(r3
Hedl,caryol 30.12 t546 Hexadienrrf butanoate <OE.4E\-> 17.91 1248
Helilblen-| 2-al A <syn-anti-anti> 32..58 1592 Hexadienolisobutanoate <(2F-.4F)-> I-5.90 1202
Ht--lilblen-| 2-al B <anti-anti-anti-> 32..58 1592 Hexaciienol propanoate<(21:.4F,)-> 14.0.5 I I59
Helifolen-I 2-al C <anti-syn-syn-> 33.64 r6r9 Hexalactonecy-> 09.33 1042
Hc-lifolen-I 2-al D <syn-syn-syn-> 33.64 t6l9 Hexanal 03.19 0801
He 'l i l olenoI A 35.74 1674 Hexanal,dimethylacetal 07.01 0973
HelifirlenolB 3.5.89 1617 Hexane<n-> 0 | .88 0623
He l i tb lenolC 36.03 l68l Hexanedione <3.4-> 03.17 0800
Helit'olenolD 36.03 l68l Hexanoicacid (-caproic acid) 06.84 0967
Heneicosane <n-> 50.47 2100 Hexanoicacicl<2-nrcthyl-> 08.80 1027
Hepta-1.3..5-triyne 31.48 1720 Hexanoicacid <-5-methyl-> 09.03 1033
Heptacosane 61.12 2700 Hexanol<2-> 03.t4 0796
Heptadecane <n-> 36.74 1700 Hexanol<3-metlrylthio- | -> 16.10 1201
Heptadienal <(28,48)-> 01.99 100.5 llexanol <n-> 04.28 0863
H eptndienol <(2E,48)-> 08.21 t0l 3 H exen-3-ol< l -> 02.88 0769
Heplalactone<y-> | 3.38 1144 Hexenal<(2Il)-> 03.99 0846
Heptan-2-ol<6-methyl-> 06.58 09.58 Hexenal<(2E)->,diethylacetal 11.42 1098
Hcptan-2-one<6-methyl-6- Hexenal<(27)->, diethylacetal 10.80 t08|
(3-methylphenyl)-> 34.41 1639 H exenal < (3E )-> 03.10 0792
Heptanal 04.98 090l Hcxenal<i37\-> 03.1.5 0797
He p ta n al. diet lr y ac
l et a l - 15.26 I I 8ft Hexenal<diethylacetal<(3E-)-> il .0t t087
Heptanal,dimethylacetal | 0..52 1014 Hexenal<diethyl acetal<(32-)-> I t.t4 t090
Heptane 02.23 0700 Hexenoicacid <(2E)-> 07.99 | 005
Heptanol<2-> 04.84 0894 Hexenoicacid <(3E)-> 07.30 0983
Heptanol<2.6-dinrethyl-2-> 07.48 0989 H exenol < (2E )-> 04.l3 08.54
Heptanol<.1-> 0,1.68 088-5 Hexenol<(27.)-> 04.22 08.59
Heptanol<n-> 06.63 09-59 Hexenol<(3E)-> 03.96 0844
Heptanone<2-> 04.74 0889 Hexenrrl<(32)-> 04.06 0850
Heptanone <2-methyl-4-> 0-5.46 0918 Hexenol<{47)-> 04.42 087|
Hr-ptanc'rne <-3-nrethyl-4-> (irnpure) 0.5.46 09t8 Hcxcnyl-(32)-hexenoate <G7.1-2 23.86 t383
Hr'pt0none <:l-nrethyl -3-> 0-5.66 0925 Hexenyl 2-rnethylbutanoate<(.37.)-> 11.07 1229
Heptanone <-5-rnethyl-3-> 0-5.98 0936 Hexenyl2-nrethyl-2-pcnrenoare <(.32)-> 24.61 1400
Ht--ptcn- I -ol <( 211)-> 06.-58 09-58 Hexenyf3-nrethylbutanoate<(3lZ)-> 11.22 1232
Hepten-l-ol<(42,1-2 06.63 09.59 Hexenylacetate<(2H)-> 08.t7 r010
Hepten-2-ol<6-nrethyl-5-> 01.47 0989 Hexenyl acetate<(38)-> 07.84 t00|
HL'plen-2-one <(3E)-> 05.7| 0927 Ilexenyl acetate<(37.1-s 01.93 1004
Hcpten-2-one <6-nrethyl--5-> 07.25 098l Hexenylangelate<(37\> t9.10 1215
Heptenal<(28)-> 06.27 0941 Hexenyl anthratrilate<(3Z)-> 4t.13 1820
Heptenal<(4E)->. diethyl ircetal 15.26 1| 88 Hexenyl benzoate<(28)-> 32.37 1587
Heptenal<(.42)-> 04.82 0893 Hexenyl bcnzoate<(37,)-> 3 l .48 1.5(r-5
Heptenal<(47,)->,diethylacetal r4.89 |n9 Hexenylbutanoate <(211)-> t.5.48 | t93
Heptencrl <(.37Y> 06.28 0941 Hexenyl butanoate<(37,)-> | 5.09 I 184
Heptenolacetate<(32)-> l | .42 1098 Hcxenylcaproate<(2E)-> 23.99 138.s
Heptenl,lacetate<(28)-> 1t.99 lllt Hexenylcinnamate<(.32)-> 43.25 | 880
Hcptenylacelate<(22)-> I t..56 I lOt Hexenyl fbrnrate<(2H)-> 0-s.46 09r8
Heptylacetate 12.02 nt2 Hexenyl frrrmate<(37)-> 0.s.32 09l3
Hc'ptylacetate<2-> 09.19 t038 Hexenylhexanoate <(32)-> 23.65 1378
Hcptyl isobutanoate 11.84 124(t H exenyl isotrutanoater<( 37,)-> 13.30 | t42
Hexacosane 64.61 2600 Hexenyl isovalerate<(28)-> 17.7| 1243
Hexadecane <n-> 32.89 1600 Hexenylisovalerate <(2Z)-> l7.60 t24l
Hexadccanoic acid 45.9.s 19.59 Hcxcrryllactate<1.12;-> 15.68 | t97
Hexadecanol <n-> 43.03 1874 Hcxenyl methyl carbonate<(32)-> I Ll I t090
Apncndixl: Alphabcticall,ist ol' Corlpouncls l9
Clonrrlon Nanrc RT AI CumrnonNanre RT AI

Hc'xenvloxy-acctlldelrycle <(3Ir)-> 10.t2 l0(r3 Hyclroxycitronellol 22.83 l3.s9
Hc'xenyloxy-acetalclclrycle <(-jZ)-> t0.02 l0(r0 Flydroxybcnzaldchyclc <rl-> 22.65 l35.s
Hexcnylphcnylacctatc<(211)-> 34.24 163.5 Flyclroxybutanoic acridIactone<4-> 05.0.s 0904
Flexenyfplruryl acc{atc<(3l)-> 34.l(r 1632 Hydloxycliphcnyl methane<2-> 35.75 1614
Hcxenylpropan()ate <( 211)-> 11.6.5 l103 lncensole 52.2(t 2l.5ti
Hcxcnyfllr()pionrte<(3'/.)-> l |.30 t09.5 lnccns<.ile
acctate -53.0-5 2184
l{cxcnyl l.lyru\,ate<(37,)-> t4.99 l l8l Incc'nsolcoxide 5.5.88 2279
Hcrcnyl salicylate<(3/.)-> 3.s.51 l6(18 lnclanol<-5-> 21.90 1.138
I Icxcnyltiglate<(3lJ)-> 20.ft8 1.1t5 Incliponc 28.69 1496
Fl cx c nytl iglnt c< ( 3 2 )-> 21.o7 l3 t9 lnclole 19.76 | 290
Hcxcnylvaleratc<( 2H)-> 19.61 1287 Intcrtnedeol 35.42 l(165
Hcxcnyfvalcratc<12/.)-> t9.40 t282 Intermeclcrol <nco-> 3-5.1.5 l(r5ft
Hcxenyfvolcratc<(371-s 19.28 1279 lortol<a-(E)-> 23.55 1376
Hcxyl-(2lr)-butcn()atc t].49 I 238 Ionol <u-isorncthyl-( t1)-> 27. 08 | 458
Hcxyl 2-lirroatc 26.62 1111 Ionol <p-> 2.s. t.5 l1l2
IJcx y l2- nr et hyhut l a n o a tc < n -> l 7 .2 3 | _:-r-1 krnol <nrcthyl-F-(trl-> 27.9(t 1119
Hcxyl 2-nrcthyl-3-pcntcnoate 2t.t I 1320 lonol ercctate <(lJ)-a-isornctlryl-> 3l ..57 1567
Hcxyl acetate 08.0-5 I (X)7 Ionol acelate<(Z)-s-isorncthyl-> 3 | .08 1.5.5.5
Hc'xylbcnzoalc<n-> 32.0-5 1579 krnol .cct-te <F-(lr)-> 30.34 l-5.17
IIcryl l-rutanoate 1.5.40 il91 Ionone<(H)-s-> 2.5.8 | 1428
Hcxy l hc x anoat c 2.t.tt3 r 382 krr.rone<(F,.)-0-> 2n.30 1481
Flcxylisobutanoate t3.-50 | 117 Iononc<(r-nretlryl-u-> 29.65 | 520
He x y l is ov alc r at c 17.59 l24l krnonc'<cli hych'o-a-> 25.r0 llll
Ilcxyl octlnoatc 32.12 t58l Iononc<dihyclro-p-> 26.08 t+.r+
Hcxyl phcrtylacetale 33.91 1626 Iononc<dirnethyl-> 3l .19 I 56-5
Flcxylpropanoate I 1..53 il01 I onone 27.92 t-178
- ) t<l
H cxy l t iglat e | 330 Iononc<rnclhyl-y-> 28.00 t480
Heyclcriol -s9.0-5 239o lpsdicnol 13.23 ll40
Hi l lonc 33.18 t601 Ipsenol 11.49 I t00
Hi l ly l ac er t at e 41.12 I 837 Iriclolactone <tlans,cis-> 26.46 t443
Fliniachal-'l-cn- I p-ol < | | aH-> 3(t.12 I 699 Ishwarane 27.35 1165
Hi n r ac hala- 1. 4- c lic n<cl I u H -> 28.20 1485 Ishwarone 36.([ t680
Hirnachalcnc <u-> 26.68 l44L) lsoitnryl-1-(
2-l'uriur
)propionllr' 2.s.88 1430
Hi rnacrhalcnc <c-dchyclo-ar-> 29.48 t5 t6 IsoatnylacetoacctatLl 14.72 | t7-s
Flirrrachalcnc <p-> 28.86 1.5(x) Isoarnylangelate t3. 34 I r43
Flirnachalcne <y-> 28.0.s t.l8| lsoarryl hcnz()etle 26.03 t.133
l"li rrrachalcnc <y-clchydro-ar-> 30.08 1.s30 lsoarnylhenzylcther 20.(t4 | 310
H i rnac halc nc epor i c l c 32.01 l-57tt Isoerrnylcinnatrurtc <(I1)-> 38.21 1110
ll i rnaclralcnc oxitle<B-> 3-l.,1il l6l.s Isoanrylclodccanoate 4t ,q7 1844
[ | irnaclrakrl 3-1.91 1652 lsoanrylgeranatc 34.1J.5 I (r.50
H i n er s ol 3,1.45 l(r40 Isoamylhexanoate 17.83 1246
Hincsolacrctatc 39.19 r 783 Isoarnylisobutyl'atc 08.05 l007
Hittokiernonc 63.50 2557 lsoarttylnerolater 33.00 l(fi2
H i n ok iol 6,1.3.1 2589 lsoarnylnonillloate 30..s9 l-s43
Il i n ok ionc (r3.30 2549 lsoanryl()clanoatc 26.12 1442
lJornoisol'racckcol 4 l.tiO I 839 Isoarnylpr<pionatc 06.6.1 0960
llornoisobacc l<erol rncthylcther 42.93 It37t Isoarnylti gl ate 13..57 I t48
l l u tt t ulenc < l4- hv d ro x y u -> .1 | ,Z+ r 7l3 Isohacckcol 3rJ.70 | 7-53
[{unrulcrte<o.-> 26.82 1452 Isobaeckcolrncthylcthcr' 39..58 1117
HLrrnulenc <p-> 26.16 I'l.l(r lsobazzanenc 26.16 1436
l l u m ulc nccrpox ic lcII .13.20 l60fl I sobicyc:logctrnacrenal 37.9.s t733
llyacirrtlrRody #-l 26.19 t137 IsoborncoI 13.87 r l -5.5
Hyclrocinnarnyl accta{ct 23.1| I 366 I sobonre<ll<8-isohutyryloxy-> 34.14 1632
Hyclrocirrnarrryl alcohol l6.ll7 1224 Isoholnyl2-rncthylbutanoatc 29.76 1523
llyrlr'oxyacctophcnonc <2'-> t3.87 I 1.s.5 lsobornylacetato t9.48 1283
H ytlr ox yc it r or r c , l l a l 1 9 .6 0 l2rJ6 lsobornyllirrrnatc t] .36 t23.5
l l yclr ox y c illonella l < d i c th y l a c c ta l -> 3 0 .1 -+ l 532 Isot-rolnyl
isohutanoate 2.s.9-s l43l
20 Adams: EssentialOil Componentsby GC/MS
Cont nro n N l r n e RT Conrrnon Name RT Al

Isobornylisobulanoate <5-lrydroxy-> 3.5.08 I 656 Isophorone<4-keto-> 13.23 I140
Isobt'rrnyl isobutanoate <S-oxy-> 33.04 l ar03 lsophorone<4-lt.rethylene-> t6.48 l2t6
Isohornylisobutanoate<(r-hydroxy-> 34.56 1643 I sophyllocladcne 4(t.18 l96fi
Isohnrnylisobutanoate<S-hydroxy-> 35.15 l(t14 Isophytol 45.52 194(t
Isobornvlisohutanoate <8-isobutyryloxy->43.-56r I 889 Isopirnara-9( I l ), l -5-diene 44.1l 190-5
Isobornylisovalerate 29.',70 t52l lsopimarol 56.77 2310
Isobornyln-bufanoate 21.12 1473 l sopi nrpi nel l i n 54.63 2231
Isohornylpr()panoate 23.88 I 383 lsol.rrenylcinnamate<( IJ)-methyl-> 49.40 2065
Isohutanol 02.00 06-50 Isoprenylcinnamate<(Z)-methyl-> 46.34 t910
lsobutylacetate 02.8r 0761 Isoprenyloxycoumarin <7-> .50.9.52l l5
Isobutyl acetoacetate 10.00 l 060 Isopropylbutanoate 03.8| 0836
lsobutylangelate 09.45 t04.5 lsopropyl hexadecanoate 48.09 2024
Isobutylbenzoate 2t.39 1327 Isopropylisobutyrate 03.08 071)0
lsobutylcinnanrate 33.80 1623 Isoprrryylphenylacetate 18.77 126l
Isobutyl lorrnatc 02.t4 0680 Isopropyltetradecanoate 41.42 | 828
Isobutyl hexirnoate 13.(t2 n49 Isopropyltiglate 06.93 0970
Isohutyl isobutyrate 05.t8 0908 Isopropyl-2-rnethoxypyrazine <3-> | | .14 1090
Isobutyl phcnylacctatc 24.01 I 386 Isopropyl-2-mcthylbutyrate 04..59 0880
Isol'rutylsalicylate 25.59 1423 I sc4rt'opyl-4-nrethyl thiazole <2-> 08,24 l0l2
Isohutyltiglate lt.t.5 I 088 Iscrpropyl--5-mcthyl-(28)-hexcnal<2-> 11.66 ll04
I sobuty|-(2IJ)-butenoate 07.62 0994 Isoprrrpyl--5-rncthyl-(22)-hexenal <2-> 12.00 | | l2
Isocitral<(E)-> 14.82 I t]] Isopulegol 13.43 ll45
Isocitral<(Z)-> 11.0(t I t60 Isopulcgol<iso-> 13.86 l r5s
Isocitlal<exo-> 13.21 l 140 lsopulegol<neo-> 13.37 | t44
l.trcitronellenc 05.46 09t8 Isopulegol<ncoiso-> | 4.38 | 167
I.,--otnene<0-> 24.05 I 387 Isopulegylacetate 19.f0 1215
l * ro n re ne < 0- ) 24.94 t401 Isopulegylacetate<iso-> 19.45 1283
l' ,Lrrr$'eacin <(E)-> 30,98 l-553 lsc4rulcgylacetate<neo-> 19.0-5 l2l4
ls ilaucene 28.83 t-500 Isrrpul cgyl accl al e< neoi so-> 20.13 1312
l +,cl rnr ic in< ( E ) - > 3t.62 1.568 Isoqui nol i ne t7.91 1249
I*,eIenricin<(.2)-> 31.62 t-568 Isosall'ole<(E)-> 23.15 1373
Iveus.-nt l <(E)-> 2(t.67 1448 lsosafl'ole<(Z)-> 21.82 l336
Isteusenr.l<(Z)-> 24.90 1406 Isotorcluatone 40.42 l80i)
Ist*-u"entl acetate<(E)-> 33.46 l(tl4 Isotorquatone<dcrnethyl-> 41.96 1844
I screuge nr.l acetate<(Z)-> 3t..51 t.566 Isovalencenol <(E)-> 40.15 1793
IsoeugenrIhenzylether<(E)-> 5t.24 2t25 Isovaleraldehyde 02.04 06.s8
Iscreugenr I henzylsther <('Z)-> 49.60 2072 Isovalericacid 03.66 0827
Isoeugenr I phc-n1'lacetate <(E)-> 56.42 2297 Italicene 24.84 140.5
IsoeugenrI phenr'lacetate <(7,)-> 54.7(t 2241 Italicene<iso-> 24.69 1401
Isogeijerc'ne C t7.83 1246 Italiceneepoxide 30.14 l54l
Isohibaene 4.5.0.5 1933 Itrl i ceneepoxi de 29.10 l5t4
Isoledene 23.48 1374 Italicencether 30.30 1.536
Isolimonene<trans-> 07.22 0980 I taliceneether 29.45 151.5
Isolongifolan-74-ol 33..59 l6l8 Jasmolactone <(E)-> 28.45 t49l
Isolongifolanone <cis-> -l -). -1 / 1612 Jasmolactone <(7)-> 28.31 1487
lsolongifolant'ne <trans-> 33.88 1625 .Iasmolactone, cxtraC <(E)-> 32.02 l578
lsomenthone <l-l -3-oxobLrtyl)-> 33.93 1627 Jasnrolactone, extraC <(Z)-> 3 t.5l rs66
Isomenthone <2-eth1'l-> 19.92 1293 .Iasmone <(E)-> 24.19 t390
Isorrryristicin 33.52 l( t l 6 .lasmrrne<(7,)-> 24.26 1392
Isopentyl2-methylhutanoate | 1.49 I l0t) .lasrnone<clihydro-> 23.67 1378
Isopentylacetate 04.40 0869 .lasmune <iso-> 24.12 t388
Isopentylalcohol 02.53 073| .lasmonelactone<(3E)-> 28.14 1483
lsopentylbutanoate 09.72 la52 .Iastnonelactone<(32)-> 27.56 t4t0
Isopentyllillmate 03.06 0788 .lasmonol<cis,(E)-> 2t.43 t328
Isopentylisovalerate I t.60 lt02 .Tasmouol <trans,(IJ)-> 2f.18 1322
Iiopentylsalicylate 30.2-5 1.53.5 .Tasnronyl acetate<(E)-> 24.55 1398
I.ophorone t2.27 I118 .lasmonylacetate<(7,)-> 26.84 1452
Appenclixl: Alphabcticall_istof Cornpoutrcls al
(lonrmon Name
RT Common Niurre RT AI
.fensenorre 46.30 | 9(r9 Linalool <dihydro-> 12.82 il31
.luncnol 33.61 l 6 t8 Li nalurl <tetrahydro-> | | .43 t098
.luniccclrtrnol 36.14 t692 Linaloolacetate | 8.l6 1254
Juniccclranune 3.s.38 t664 Li nalool acetate<d ihyclro-> IrJ.99 t272
.l uv ibione 47.90 20trJ Linalool acatatc<tctrahVclro-> t7.t5 1231
Juvibione<clehydro-> .50.00 208.5 Linalool butanoate 2.5..53 1421
Kalalranacnonc 13.82 I t-54 Linaloolltrrnrtrtc 16.42 t2t4
Kaur-l-5-enc 4t.25 1991 l,i naloolisohutanoate 23.43 t37.3
Kaurcnc 4rJ.66 2012 Linalool isovalc.ratc 21.43 1466
Kessane 30.02 1529 Linakxtl oxide <cis->(lirranoitl) 10.29 1067
Kh us ilal 34,1| 1647 Linalooloxicle<cis->(pyranoid) 14.52 | 170
Khus ilol 3.s.80 1615 l .i rti tl tx'rrxi
l dc< del rydrl xyci s-> 08.01 | ()06
Khusirncne 26.8.5 t 4-s3 Li nalooloxicle<clchydroxytrans-> 07.52 099|
Khusinrol 38.26 t]4l Linaktoloxide <trans->( luranoicl) 10.89 t0n4
Khusinrone 33.0.5 I 604 Linalooloxide <trans->(pyranoicl) 14.64 1173
Khus inol 3.5.9-5 1619 Linalooloxicleacetale<trans->(pyranoicl)19.64 l2gl.
Khusinolacetate 41.21 | 823 Li naltxrl pt'()neln(
)iltcr 2t .73 13.34
Kucltdiol 44.33 t9t2 Linalool<1.2-dihyclro-8-hydroxy-(2ts)-> 31.9j 16.54
Labd-l -lIr-8,I -5-cliol 59.92 ) J)) Li nol ci caci d 5t.41 2132
Labcl-7, | 3-dien-I 5-ol 56.24 2291 Lippifirli-| (6)-en-.5-one 30.89 1.s.50
Labcl-7, I 3-dien-l -5-ol,aceratc 59.12 2392 Longiborneol(=.luniperol ) 32.8.5 1.s99
Laciniatatlranonc li 34.47 t -540 Longibrtrneol acetate(=Junipcrolacetatc) 3(r.l6 t6u4
Laciniataf'uranonc F 30.09 t.531 Longicanrphcnylone 31.3-5 l-5(r2
Laciniata1ut'anonc. G 29.96 t-s2ti Longicyclcnc 23.37 137|
LacinialafuranoncH 3().8f) l -548 Longilblene 24.92 1407
Lanccol<(7.)-> 38.94 11(t0 Longilirlene<iso-> 24.11 t389
Lanccrrlacrctate <(Z)-> 42.32 18.s4 Longilirlol 37.25 l7 t3
Larixol ) - ) .4 / 2265 Longilirlol<iso-> 37.80 1728
Laurcnan-2-one .50.96 2t l5 Longifololacetate<iso-> 4 r. 09 l8 t9
Laurenene 43.20 1879 Longiltinanol 31.58 1561
Laurencnc<epi-> 43.97 I 90t Longipinanol<epi-> 31.3.5 1562
Lavandulol r4.30 1165 Longipinene<o-> 22.41 l3.50
Lavanclulol<tcttahydro-> t3.9-5 I t.57 Lon_eipinenc <B-> 24.64 l4(X)
Lavandul<tl acctalc<tctrahych.o-> 18.79 1268 Lyral 3-s.4 t t665
Lavandulyl2-nrethylbutanoate 29.27 l-5|l Maal i ol 3|..53 l-566
Lavandulylacetate 19.70 r 288 M ltcrttcarpcne <( F.)-y-> 29.92 1527
Lavandulvlilcctate<hydroxydihyclro-> 26.15 1436 Macrocarpene <(Z)-y-> 2L).31 l5l2
Lavandulylisobutanoate 2-5..51 1421 Macrocarpenc<0-> 27.s9 1410
L.avanclulyl isovalcrate 29.t9 t.509 Maclocarpenc<ar-> 29.88 t526
Lavcndcrlactonc 09.0.1 r 034 Macrocarpene <p-> 28.8l 1499
Lcaf alcohol,ethyl acctal I t.t7 I t06 Mal tol 11.71 ll0(r
Lcclol 32.99 l(t02 Maltol propionate 26.99 l4-56
Lcptospetnronc 31.02 1629 Maltyl isobutyrate 28.-58 1494
Lcl.rtospclntonc <iso-> t62l Man<xrl
-1-1.11 49.1| 2056
Liboccclrol 57.16 2344 Manool< 13-epi -> 49.20 2051)
L i g u lox idc 30.24 l-53,1 Manool <3a-acetoxy-> .58.| 8 2359
L i g us t ilide< ( I l) - > 40.28 t796 Manool <3o-lrydroxy-> 56.4t 2297
Li _qusti Iicle<(.7,) -> 38.02 1731 Manool <7u-hyclroxy-> .54.63 2231
Lilial 29.93 1521 Manooloxicle 46.89 t987
Lirrronen- 10-ol 19.67 l 2n8 Manooloxi de< 13-epi -> 17.(t4 2009
Linroncne 0li.(r9 lo21 Manool oxide <2-keto-> 54.02 22t6
Lirnoncnealdelrydc 21.37 1326 Manool oxiclc<3a-I 4, l -5-dihydro-> .57.55 2337
Lir.noncne oxide <cis->(Me vs. IPP) l2.fi8 I t32 Maple luranonc t.5.02 I I82
L i n t onc ncox ido< t ra n s ->(M e v s . IP P) 1 3 .1 0 I l.l7 Massoiadoclecalactone 36.20 r68.5
L i n alool 11.32 t09.5 Massoialactone 27.60 1471
Li nalool<(Z )-8-hydroxy-> 33.6-5 l(rl9 Mayurone 37.09 1109
Linalool<delryclro-> I t.05 | 088 Mayurone<cis-dilrydr.o-> 32.10 1.59-5
by GC/MS
Oil Components
Adams:Essential
22
Al ConrnronNarne RT AI
CornrnonName RT
1423 Merhyl anthranilate <me thyl-n-> 24'86 1405
Mefi'anal 25.60
Methyl benzoate 1 l '07 l08u
Melaleuccll 36.98 1106
Methyl benzyltrutyrate <o-> 23'00 1363
Menth-| -en-7-al<3-oxo-P-> 21.5(: 1330
Methyl benzyl propanoate <o-> l9'31 1280
Menth-l-en-7-al <P-> | 9.00 12'73
Metlrylbiphenyl<4-> 28'35 1488
Menth-l-en-9-ol <P-> 19.96 1294
2.5.-53 t42l Metlryl butanoate 02'43 0721
Mcnth-l -en-9-ol acetate <P->
Methyl butanoate, <3-> l2'03
3-methyl-3-butenyl 1l l2
Menth-2-en- | -ol <cis-P-> 12.29 I I l8
Metlryl butyl acctate<2-> 04"50 087'5
Menth-2-en- I -ol <trans-P-> 13.04 I 136
Methyl butyl hcnzoaLe<2-> 26'24 1438
Menth-3-en-8-ol <P-> 13.4-5 114.5
| Methyl butyl isovaletatc<2-> | I '65 | 103
Mcnth-6-en-2,8-diol <h'ans-P-> 23.37 13',7
f 7.00 lz27 Methyl hutyl-2-rrethylbu{yrate<2-> I I "50 I 100
Mentha-I (7),8-dien-2-ol <cis-p->
| l9-5
Vetnyt chavicol 15'57
Me n tha- l( 7) , 8- c lien -2 -o l < tra n s -p -> l 5 ' 2 4 l l87 1376
07.79 l000 vetnyl cinnanrate <(E)-> 23.-58
Mentha-I (7).S-cliene <meta->
07.89 1003 Mcthyl cinnatnate <(Z)-> 20' 18 1299
Mentha-1(7),8-diene<P->
21.30 1325 Metlrytcitronellate 18'33 1257
Mcntha-1.4-dien-7-ol <P->
Vettryl communate <(E)-> 55'22 2257
Mcntha-1.5-dien-8-ol <P-> t4.32 l166
Methylcomnrunate <(Z)-> 54'47 2231
Mentha-2.4(8)-cliene <P-> 10.94 108.5
Mcthylcyckrhexene 02'61 0740
Mcrrl ha- 2. 8- dicIn- - ol < c i s -p -> 12.93 l l33
Itettryl cyclohexylcarboxylate 09'84 10-5'5
Mentha-2,8-dien- I -ol <trans-P-> 12.33 I 119
Mcthyl claniellatc 5'l '39 2331
Mentha-2,8-diene <cis-mcta-> 01.31 0983
Mcthyl clecanoate 2t '23 1323
Mentlra-2.8-diene <trans-nleta-> 07.18 0919
t0.30 l068 Methyl clecylketone(=2-dodecanone) 24'09 1388
Mentha-3,8-diene <P->
1357 Methyl clehydroabietate 57 '65 2341
Mentha-8-thiol-3<tne <cis-p-> 22.74
Mcthyl clihyclrolasmonate <trans-> 36'05 1682
Mcntha-8-thiol-3-one <trans-p-> 23.?6 l31l
15..5.5| 194 Methyl dihyclro.iasmonate <cis-> 34'99 1654
Menthan-2-one <cis-P->
Methyl doclecanoate 29'82 1524
Menthan-2-one<trans-P-> t.5.75 I 199
Methyl epcruate 54' 15 2220
N,lenthane <trans-P-> 07.03 0913
Vettryl epi-.iasmonat e <(Z)-> 3-5'9 | 1678
lr'lcnthatriene 11.86 ll08
08..58 1021 Methyl eudesmatc 31 '40 | 7l t3
l rl e n t hene< l- P - > 1403
0984 Methyleugcnol 24'75
Irlcnthene<3-p-> 01.32
Metlryl larnesoate <(28,6E)-> 39'19 1783
lrlenthothiophene 21.96 1340
Methyl geranate 2l '19 1322
NIc-nthofuran t4.0-s | 159
Methyl heptanoate 08'-57 l02l
lvlenthol 14.39 1161
Methyl heptine carbonate 15'60 | 196
Menthol <8-hydroxY-neo-> 2t.44 1328
Mcthyl hexaclecanoate 44'64 l92l
Menthol<iso-> 14.91 | 179
Methyl hexanoate 05'54 O92l
Mentlrol <rteo-> t4.13 I l6l
l184 Uettryl isoborneol<2-> 14'8-5 I178
Mcnthol <neo-iso-> 1.5.1l
tr.letnylisc'reugenol<(E)-> 28'47 1491
Mentholactonc <cis-> 23.05 1364
23.35 137| Vettryl isoeugenol <(Z)-> 26'18 14-51
Mentlrolactone<trans->
13.55 I 148 Mcrlryliso;rimarate 56'42 2291
Menthonc
I 3'99 | 1-58 Mettryl iasmonatc<(Z)-> 34'74 I (r48
Menthone<iso->
1 9 ' 9 3 1294 Methyl labdanolate -58'80 2381
Me n t hy lac et at e
20'39 1304 Metlryl levopinrarate 56'66 2306
Me nthyl acetate<iso->
18'92 121t Methyl linoleate '50'33 2095
Menthyl acctate<rrco-> 19'92 121)3
29'-50 1516 Methyl myrtenate
tllcnthytisovalcrate 60'48 2443
28'0-5 l48l Methyl neoabietate
Menthyl lactale 19'34 1280
28'49 1492 Mcrhyl nerolate
Menthyl lactate<iso-> 2387
Mcthyl nitloreseclate 58'96
Menrhyl lactate<neo-> 27 '44 1467
Methylnonanoate l6'tt3 1223
Mercaptopropanoicacid <2-> 06'35 0950
Metlryl octaclccanoate 5l '23 2124
Mcsitylene 07 '61 0994
1527 Methyl octanoate 12'50 | 123
Methoxy cinnanralclehycle <(E)-o-> 29'93
Methyt octine cat'bonate | 9'98 1295
Methoxycinnanric acid <(4E)-> 36'11 1700
Methyl o-ani sate 2l ' 12 1334
l,letnoxy-:-1t-nethylpropyl)pyrazine <2-> 14'42 l 168
0969 Methyl p-tert-butylphenylacetate 28'10 1497
Methyl2-l'uroate 06'90
Mcthyl p-anisate 23'33 l3l I
Merhyt2-octenoate <(E)-> 14'22 I 163
| 2385 Mettryl pcnt-2-enolide<4-> (inrpure) 06'21 0945
Methyl abietate 58'9
Mcthylpentanoate 03'-5'5 0821
Methyl u-cyclogeranate 1-5'66 ll9'l
I -I I -
Appenrlixl: AlphabcticalList ot'Clonrpouncls 23
(lrnrntrn Nanrc RT Al ContnronNarrrc RT AI

Mctlrvl pcrltan()alc<2-hy,droxy-.3-ltrcthyl-> 07.;1ft 09ti9 Myroxicle<(/,)-> 12.82 | r3 |
Mcthvl pcntanoalc<2Jryclroxy-,1-nrethyl-> 07.31 ()91J3 Myrtanol<cis-> t8. 00 t2.s0
Mct hy lpc lr t an( ) at<c2 -n re th y l -> 04.42 0871 Myrtanol<trans-> 18.34 l2-58
Mcthyl llcnt\/lalgclatc<-l-> \J.96 t249 Myltanol acctatcr <trans-> 23.97 I 38.5
Mct hy lpc lillat c 24.30 1392 Myrtcnal 15..56 | t 9.5
I\4cthyll.rilrraratc -5,1.(r-52231 Myrtcnol l.s.-5.5 | 194
Mcthyl pt'()pauoatc 0I .93 0(134 Myrtcnyl acetatc 2l.29 1324
Mct hv l s alic y la{ c t.s.3-s I t90 Naphthalcnc t4. 84 | | 78
\4cthyl sanclaritcopi ntala{c -55.l9 2256 Naphthalcnc 26.17 1444
I\4cthvlstrictatc -5[i.96 2381 Naplrthalene <2-ruethoxy-> 26.53 t445
N4cth1'l te'tr"aclccanoate 31.57 1122 Naphthalcrne <cis-dccahych'o-> 1.16 1099
Me t hy lt hujat c 2t.02 t.rtf3 Naphthalcne <trans-clecalryclro-> 09.71 r0.53
Mct hy l t iglat c 04.28 08(13 Naphthalcne <2-acctyl-> 33.22 t608
N'lcthylunclccanoatc 25.66 t121 Nccrorlol<cis-o.-> t4.48 I 169
Mct lr v lv anillin 21.78 1415 Ncclodol <trans-0-> 13.31 | | 44
Methyl-(2lt )-ll()ltclt()atc t6.73 llt I Neclodolacetatc<cis-c-> 20.18 1299
Mcthyl-(llt )-hcxcn-2-onc <5-> 04.tiO 0n92 Nccroclolacctate<lrans-tr-> 19.42 1282
lrtlcthv I-l -llr)-hcxcnoatc 05.72 0e2l Ncocalli h'o1-rsclre <rl-> 27. 75 l4l4
Me:thyl-( 3Z )-lrcxcn-2-onc <5-> 04.40 0tl(r9 N errcni di l i de 37. 55 1122
N'lctlr1,l- | -hutanol<2-> o2.46 0721 Nepctalactone <4au,7u.7aa-> 22.73 13.57
Mcthyl-| .4-cyckrhcxacl iernc 03.2.5 0804 Ncpetalactonc<z1aa.7cr.7ap-> 24.00 t386
Mct hl, l- 2- but anol < 3 -> 02.t0 067| Nepetalactone <4ao.7[},7as-> 24.21 | 39t
N4 ct hy l- 2- but c na < 3l-> 02.91 0178 Ncral 17.32 12.1.5
I\'lcthyl-2-cyclohcxcn-| -orrc<3-> 09..50 t046 Ncrol 16.97 1227
N4cthyl-2-pentan()nc <4-> 02..s0 0128 Ncrol oxide t3.80 I t.5-t
Mcthyl--l(2-lirryl)acr()lein <(2H)-> t.s.07 | t83 Ncrolidol <(11)-> 3 t .32 t.56|
Mcthyl-3(2-lirryl)ac:r'olci n <Q /,y-2 14.43 | r68 Nelofirlol<(/.)-> 30.09 t.s3l
Me t lr y l- 7.|. 1.| 5- : r lr i c tu tl i c n o u l c 62.0-5 2.50 | Nerolidyl acctate<(11)-> 37.3.s ll l(t
Mctlryoxyilriophcnitl <2-> 16.23 l2 t0 Ncr<rficlyl acetatc<(.7,)-> 3.5.n.5 t6l6
Mi n t s Lr lllc lc 38.2I 111(\ Ncroliclylisobutyrate <(E)-> 4 | .30 lti2.5
Mocllrcph-2-errc 23.133 1382 Ncrol iclyl i sol.rutylate <('l) -> 39.19 I 783
Moclhcphcn-88-ol 29.3-5 1.513 Ncronc<cis-> 2.s. l5 t1l2
MLrskanrl.r'ctte 44.92 1929 Neronc <trans-> 26.25 1,138
Musl<l<ctonc 4(r.80 l9tt4 Nclyl acctate 22.81 l3-59
I\{uskxykrl 12.73 l8(r(r Neryl acetone 26.0(t 143.1
Mu s t ak one 3.5.83 1676 Ncryl lbrrnate 19.32 l2ti0
Ntuurol-.5 -cn-4s-ol<cis-> 31.24 l.s-s9 Neryl isobutanoate 28.43 t490
Nluurol-.5-en-4p-ol <ci s-> 30.86 | -5.s0 Nclyl isovalerate 32.l8 1.582
MLrulol-5-cn-4-onc <cis-1.1-nor-> 36.3| 1(rU8 Nelyl plopanoate 2(r.8.1 1452
Mu ur ola- 3. 5- c lien < cci s -> 26.61 144ri Nezukol 51.47 2132
M uurola-3,.5-dicnc <trans-> 26.18 l4.sI Nezukonc 26.t2 143.s
lVlrrurolrr-J( I 4 ).-5-1lig11c q.1:i-t 27.35 l4(r-5 N i coti ne 22.09 1342
Muurola-4(| 4 ),-5-clicne <tl'ans-> 28..53 t493 N i rani n 37.31 t7 t-5
Mu ur ola- 4. | 0( l4) - c l i c nI-B-o l 34.06 1630 No.iigikuacctate l7 .41 t238
I\4uurolc.ne. < I'l-hyclroxy-a-> 39.(>4 1179 Nonacosane 71.78 2900
Muulolcne< | 4-oxy-<r-> 39.22 1767 Nonildgaataat-t 13.92 l9(X)
Muunrlcnc<o-> 28.83 t.5(X) Nonacl i enaf<(2h,411) -> 16. 24 r2 r0
MuLrrolcnc <y-> 27.9t t47rJ Nonaclierral<(2F,.6'/,) -> 13. 64 I t.50
Mtrurolol<0-> (=Ton'cyol) 34.6| 1644 Nrrnacf icnaf <clicthylacctal- (2[,,62)-> 23.73 1380
Muurolol <cpi-a-> 31.46 | 640 Nonaclicnol <(2li,4H)-> f 6.5.5 t2l7
Myl t ay l- 4(l2) - c nc r 2(r..53 1415 Nonacli en<rl<( 21.,.6'/.) -> 14.04 I l.s9
Mylac alclchyclc 29.60 t5l9 Nonacfienrr| <(31..,62.1 -> r3.59 | t49
Mylccrne 07.43 098fJ N<rnard i c nrrI acetatc<(21-^67) -> 20.36 t303
Myrccnol 12.32 r I t9 Nonadicnol acctiltc'<(.3Ll"(rZ)-> 20.05 129(t
Myrccnone t3.43 I t4.s Nonalactone<6-> 23.98 138.5
Myris t ic in 29.54 r.5| 7 Nonalactone <y-> 22.18 t3.s8
Myroxide<(11)-> 13.23 I l,t0 Nonanal<n-> il..51 I t00
1,1 by GC/MS
Adams:EssentialOil Components
ConrrnonNanre RT Al Conrnron Nanre RlI Al

Nonanal,dirncthylacetal 19.t9 1271 Ocirnenone <(7)-> 16.94 1226
Nonane<n-> 04.93 0900 ()ctacosane 69.-5"5 28(X)
Nonanoicacid 18.77 1267 Octaclecanc <n-> 40.40 1800
Nonanol<2-> I 1.40 loel Octadecanol<n-> 49.76 2077
Nonanol<n-> 14.29 I 16.5 Octaclecanol acetate 53.82 2209
Nonanone <2-> l | .03 1087 Octaclecene < l -> 40.02 1789
Nonanylacetate<n-> 20.69 l3 | l Or:tadienal <(28.4h.)-> I L59 ll02
N o n cn - l- al< ( 2t s ) - > 13.94 l 157 Octadienal<2,2-clirnethyl-3,4 -> n.62 ll03
Nonen-l-al<(27.)-> 13.40 | 141 Octadienol<(2Il,4E)-> 12.01 I I l:l
Nonen- l-ol <(32,1-2 13.14 1152 Octalactone <6-> 19.f.5 1276
Nonenal<(62)-2 I t.38 1091 Octalactone <y-> | 8.02 12.50
Nonenal<dimethylacetal-(32)-> 18.89 1270 Octanal <n-> 07,12 0998
Nonenol<12H)-> t4.20 l163 Octanc 14.12 | 175
Nonenol<(27.)-> t4.1.5 | 162 Octane<n-> 03.| 7 0800
Noncnol<(67.)-> 14.26 1164 Octiurcclioicacid. clicthylester 32.25 1.584
Nonenolacctate<(2I1)-> 20.49 1306 Octanediol<2,4-> 21.92 l339
Nonl'ne< l. I -dirnethoxy-2-> 2t.16 l32l Octanoictrcid(=g3p1y1ic acid) 14.37 | 167
Nootkatcne 29.53 1.5 l7 Octanol<2-> 07,60 0994
Nootkatin 45.9-5 1959 Octanol<3-> 07.44 0988
Nootkatinol .50.10 2088 Octanol<n-> t0.l I 1063
Nootkatol 37.28 17t4 Octanolacetate l(r.30 l2l I
Nootkatol <epi-> 36.72 1699 Octanol acetate<3-> t2.35 | 120
Nootkatone 40.62 1806 Octanone<2-> 01.45 0988
Nopinone 13.02 113.5 Octanone<3-> 01.19 0919
Nopol t9.23 1218 Octanone<-5-hyclroxy-4-> 10.23 l0(16
Nopsan-4-ol 30.03 1529 Octen-l -al <(28)-> 09.59 1049
Nopyl acetate 2.5.(r.5 1424 Octcrn-l-ol<(2E)-> t 0.03 1060
Nolbornen-2-ol<enclo--5-> 0.5.8-5 0932 Octen-l -ol <(32)-> 09..52 1041
Norhornen-2-ol <exo-5-> 06.0.5 0939 Ocfen-2-ol <(3E)-> 07.28 0982
Nr.rhrrrncn-2-ol acetate<endo--5-> 1t.22 lo92 Octen-2-ol<(37.)-> 07.00 0972
Ni.rhornen-2-ol acetate<exo--5-> il ,0-5 1088 [)cten-2-one<(3E)-> 08.90 10.10
\rrrhornene 02..s0 0728 Octen-3-ol< l-> 07.04 0914
Nr,rhornene <5-nreth;'lcne-2-> 03.30 0807 Octen-3-olbutanoate <l -> t9.32 | 280
Norhornene-2-methanol <enclo-5-> 10.30 1068 Octen-3-one <l-> 06.98 0912
Norbornene-2-mothan()l <exo--5-> 09.95 10.58 Octen-3-ylacetate<l -> 11.95 lll0
Not'bornene-2-ntcthanol <endo-5->
acetate 1 6. l 2 1207 Octen-5-yne <(2E-)-nrethyl-3-> 06.-59 09.58
Nolbornene-2-methanolacetatecexo--5-> 15.90 1202 Octenc<(211)-> 03.4.5 08l-5
Norborneol <cnclo-2-> 07.26 0982 Octene<(27)-> 03.32 0808
Norhorneol<exo-2-> 06.93 0970 Oclene<(4E)-> 03.20 0tt0I
Norborneolacetate<cndo-2-> f 2.55 | 124 Octcne< l -> 03.06 0788
Norborneolacelate<exo-2-> 12.59 ll25 Octbnol<(57.)-> 10.20 106-5
Norpatchoulenttl 3l .00 1.s.53 Octcnol acctate<(28)-> 16.14 1208
Nuciferal <(E)-> 37.15 1127 Octenol acctate<(22)-> 15.67 l l91
Nucil'eral<(7)-> 37.25 l l l3 Octenolbutanoate <(2Ii)-> 24.03 1386
Nucil'erol<(E)-> 38.75 1754 Octenol propanoatc <(52)-> 20.13 1298
Nucilbrol<(Z)-> 37.(r3 1124 Octenylcyclopentanone <(E)-> 29.91 I.s28
Nuc,iI'erol acetate<(7.)-> 41.41 1830 Octyl for"r-nate 12.64 | 127
Occidcnol 3.5.8.s 1616 Olcic acid .51.75 2t4l
Occiclentalol 30.88 1550 Oplopanone 38.| 7 1739
Occiclentalol acetate 36.02 l6ttl Oplopanonylacctate 43.47 1887
Occi dol 4t.68 1836 0pkrpenonc<B-> 33.17 1607
Occidolacetate 46.51 1975 Orcinol 23.23 1368
Oc:inrenc<(E)-B-> 09.42 1044 Orosclone .52.08 2152
Ocimene<(Z)-9-> 08.96 1032 Osthole 5l.72 2110
Ocinrene<allo-> 12.70 I l28 Oxazole<2-ethyl-4,-5-dinrethyl-> 0-s.80 0930
Ocirrrene <neo-allo-> 13.20 ll40 Ox< rl uranoerentophi l<anel ,l 0B -epoxy-6->42.10 l8'18
Ocimcnone<(E)-> l7.32 1235 Palustrol 3 1..56 1567
Appcnclixl: Alphabcticall-ist of Conrpouncls
25
Conrnron Nanrc RT AI Common Nalne RT AI

Pa n as ins enc < p- > 23.18 138| P henylcthyl al cohol | 1.7 - 5 | 106
Paputnonc 39.91 1187 Plrenl'lcth1,lanthranilate <2-> -51.28 212(t
Patchcnol<(11)-> 2l .45 1328 Phenylcthyl butanoatc<2-> 26.2j 1.139
Patclrcnol<(.7.)-> 20.94 l3l(r P hcnyl ethylfi rrrnatc < 2-> 14.60 1l7Z
Patchoulenc <c.-> 2(t.92 l4-54 Plrcrnyl cthvl hexanoate 34.46 1640
Patchoulenc <B-> 23.10 1379 P henylethyli sobutanoare 24.3 1 139. 1
Patchoulenc <y-> 2tt.9| 1502 Plrc.nyl cfhyl octanoatc 42.03 t846
Pa tchoulialc ohol 3.5.08 | (r-56 Plrernyl cthyl oxyacetaldehycle 2l.28 1324
Pcarlatcr (=3-octcnol,propnnoatc) t().64 l28l Phcnylc.thylphenylaccrarc<2-> 44.38 l9 | 3
Pcntacosanc <n-> 62.ff) 2.5(X) Plrcnylcthyl lrropanoal.e <2-) 22.47 l-l-5|
Pentlclccanc <n-> 28.82 t-s00 Phcnylcthyl ti-qlatc<2-> 32.25 l-5ti4
Pentaclecanol <n-> 3e.42 1173 P frenyl hcptan-3-onc < l -> 29.83 1524
Pcntaclecanorrc <2-> 36.61 t69l Phcnylhexan-3-onc <1-> 2.5.-58 1423
Pcnliltlcccn-2-onc <{(rZJ-> 35.49 1667 P hcnyl pcntan-3-onc< l -> 21.8 0 lj36
Pcntanal 02.21 0104 Phenl,lpropanal<2-> I l.-58 I 102
Pcntanal<-5-hyclroxy-> 04.70 0886 Phenylpropyl hutanrrate (2-) 28.12 l48.l
Pcntanclionc <2.3-> 02.23 0700 Pfrcnylpropyl isobutanoatc <2-> 26.24 1438
Pcnt anoic ac id< 2- r r rc th y l -> 0.5.7| 0927 Plrenyl-4-rne thyl-pcntan-3-one < l-> 23.77 1380
Pcntanoicacid <.1-rnctlryl-> 0.s.rJ9 0933 P hcnyl -tert-butanol 13.1 9 l1. 53
Pe nt anol 02.82 0762 Pfrlrrroacetol-rhenone <2.21-dirncthylcther-> 3-5.47 1667
Pcn t anol< 2- > 02.l8 0(rit9 Phthalide<3-butylhexahydro-> 3.1.1.5 1632
Pentanol<3-nrcthyl-> 03.7(r 0833 Plrylloclaclanol 53.83 220()
Pcntanol<4-rncthyl-> 03.7() 0830 P hyl l rrcl acl enc 47.86 2O 16
Pctt lano| < J - t net hy l -2 -> 02.66 0145 Phytol 45.3j tgl2
Pentanone <2-> 02.l5 0(182 Plrytolacetate<(E)-> -5.1.07 22lg
Petttitnone'<4-hydroxy-zl-ntctlry l -2-> 03.12 083| Pirnaraclienc 4-5.59 1948
Pcrrtcn- l-al <2b,> 02.6-5 0141 Pirranc<cis-> {17.2i 0982
Pcnton-.]-ol 02.16 0(184 Pinane<trans-> 06.91 09(19
Pentcnoicacicl<2-ntetlryl-4-> 0.5..59 0923 P i nanccl i ol< ci s-2.3-> 21.01 l3 |8
Pcn{enoicacid <4-> 04.20 08.58 Pinchotencacetate Zl .50 l4(r8
Pcntcn<rl <Q/.)-> 02.8-5 07(t5 Pinene<c-> 0-5.8-5 0932
Pcntylbcnzoatc 21.84 1476 Pinenc<p-> 07.{)4 0()j4
Pcniylbutanoate I | .08 1089 P i ncnchycl rnte < ci s-> 13.18 I 139
Pcrttylcvclolrexa- I .3-clicnc I 3.91 I l5(r Pinenc hydratc<tt'atls-> 12.33 I I 19
Pcntylliu'an<2-> 07.34 0984 Pincrreoxiclc<o-> l 1.4.5 1099
Pcntylisobutanoiltc 09.62 10"19 P i neneoxi cl e 13.83 | 1. 54
Pontyll)fopanoate 0l .99 l(x).s P i nocarnpl rcol 14,32 1166
Pcntylsalicylatc 31.8.s t574 Pirrocan'rpheol <iso-> l4.j8 | 176
Pcri llaalc ohol 19.94 1294 P i nocantphonc < ci s->i = ci s-3-pi nanone) 14.5j I lj2
Pcrillaalclchycle t8.8.1 1269 Pinocarlphotrc <trans-2-hydl.oxy-> l7.U-5 l24j
Pcrillaketone 11.17 1245 Pin<lcalnphone <trilns->
PcriIlcnc 1t.50 llo2 (=trnns-3-pinanonc) 14.00 I r58
Pcucclrin.7-nrerthyl cthcr .s8.2 | 2360 Pinocarveol<cis-> l.s.(x) il 82
Phcllanch'cnc <s-> 07.ti-s t 002 Pinocarvcol<lralts-> 12.99 I 1.3.5
Phcllanclrcnc <p-> 0tt.70 t025 P i nocarvone 14.07 | t60
Phencthyl2-liu'oatc 31.28 t7t4 Pinocarvylacetate<cis-> 20.(18 l3 | |
Phencthylcinnanrate 52.q) 2179 Pinocarvylacetate<trans-> 20.1| I 298
Phcnol<2-( | [t)-propcnyl-> 1n.62 1264 P i noni caci cl 26.32 1440
Ph cnol< 2- ally l- > 15.33 | | n9 Pipcritenone 21.98 1340
Phenol<2.(r-dirncthoxy-> 22.24 134(t P i pel i tcnonc oxi de 23.12 l3(16
Plrcnolacctatc<2.(t-dirlcthoxy-> 26.32 1,t40 Piperitol<cis-> t-s.59 il 9-5
Ph en ol, 2- (lZ ) - pr opc n y l t3.47 |46 Pipelitol<trans-> l(r.l0 1207
Ph cr r ycl t hanc< | - nitro -2 -> 19.91 1291 Pi;rerilolacetater <cis-> 2t.63 t332
Phcnr'lethyl 2-rtrctlrylbutilnoatc 28.25 t4ri6 Pipcritol ilcrctatc: <trans-> 22.1{) r4.l
Ph cn y lc t hy l - 3- r net h y l h u ta n o a te 28.43 1,190 P i pcl i tone fl.95 1249
Ph cny lc t hv l ac c t at c< l -> 1.5.4-s| 192 Piperiloneepoxicle<cis->
Phcrnyl cthyl acetirtc<2-> lri.20 1254 (cpoxiclevs. IPlr) 18.00 12.50
26 Adams:EssentialOil Componentsby GC/MS
Al Comrnon Narne RT AI
ClommonName RT
18.10 1252 Pyrazine<2,5-dirnethYl-> 0.5. t8 0908
Piperitoneepoxide<trans->
21.51 1329 Pyrazine <2.6-cli rncthyl-> 05.21 0909
Piperonal
28.9-5 1.503 Pyrazine <3-ntethyl-2-isobLrtyl-> 12.90 | 133
Piperonylacetate
41.82 l840 Pyrazine<r.netlryl-> 03..52 08l9
Pipitzol<o-rnethyl,a->
42.30 18.53 Pylazine<nrethylthio-> | | .23 1093
Pipitzol<o-rnethyl,P->
33.19 1607 Pyrazine<tetrantethyl-> 10.86 l083
Platyphyllol
34.89 l6.5I Pyruvicacid 02j5 0682
Pogostol
47.85 2016 Quinoline<6-isopropyl-> 29.23 1.510
Polygodial
19.57 1285 Raspherryketone 30.67 l545
Pregei.jerene
r9.05 1274 Raspbcn"ykctone,methyl ether 28.5.s 1493
Pregci.icrene B
29.05 1505 Resveratrol 67.83 2729
Pretnnaspirodiene
31.9| 1.57.5 Rctene 53.96 2214
Prenopsan-8-ol
1.5.30 l l 89 Rimucne 43.79 l tt96
Prcnyl angclate
28.19 148.5 Rimuene<tetrahydro-> 45.99 1960
Prenylbenzoatc
<2-> t6.86 1224 Rosa-5.l -5-dienc <ent-> 4-5.06 1933
Prenyl cyclttpentanone
03.62 082.5 Roseoxide <cis-> 11.71 | 106
Plcnyl lhnnate
| 9.84 1292 Roseoxide <trans-> 12.45 | 122
Prcnyl hexanoate
09.-57 1048 Roseoxide <tlans-dihydlo-> 10.31 1068
Prenyl isobutyrate
26.44 1443 Roseoxide <cis-dihydro-> 09.17 1037
PrenylIirnonene<cis->
21.04 1451 Rosellran cpoxide 14.6.5 I173
Prcnyllirnonene <trans->
21.70 1334 Rositirliol 32.89 l (r00
Presi Iphi perh rI-7-enc.
32.30 l -s8.5 Rotr"rndene 27.05 1451
Presilphiperlblan-8-ol
26.48 1444 Sabinaketone 13.83 I 1.54
Prez,izaene
44.98 1931 Sahinaket.one<dehydro-> 12.25 | | l1
Procerin
04.9'l 0901 Sabinene 06.91 0969
Pro p anal. 3- m c t hy lth i o -
06.90 0969 Sabincnehydrate<cis->(IPP vs. OH) 10.20 106'5
Pro p anol. . 1- nt et hy l th i o -
04.91 0898 S abi nene hydrate< trans->(IP P vs' OH ) I1.4I 1098
Propyl butanotttc
Propyl chromone<2-> 36.98 ll0() Sahinenehydrateacetate<cis->
08.99 1032 (cis for Ac vs. IPP) 16.62 l2t9
Propvltiglate
Pseudt''phytol<(6E.l0I1)-> 49.16 20.s8 Sabinenehyclrtrteacetate<trans->
47.91 2018 (Ac vs. IPP) t8.12 1253
Pseudoph1'tol<((rE,. l0Z)->
48.29 2030 Sabinol<trirns->(lranslor'OH vs. IPP) 13.f0 ll37
Pscudoph1'tol<t62. I 0E)->
46.93 1988 Sabinyl acetate<tlans-> (lPP vs' Acetyl) 19.73 1289
Psctrdo phr-tol <t 62. | 0 Z) ->
<(E)-> 41.8-5 l84 l Sall"anal 15.64 l196
Pseudoisoeugenyl 2-meth1'lbtrtyrate
<(E)-> 38.24 1140 Satiole l9.56 128.5
Pseudoisoeu-eenyl isobutyrate
28''15 1498 Salicylaldehyde 09.23 1039
Pseudowidclrene
| (r.9-5 1226 S l l i cyl ate.2-cthyl hcxY l - 40.6-5 1807
Pulegol<cis->
16.3-5 1213 Salicylicac,id.butyl estcr 21.54 1469
Pufegol <trans->
17.21 1233 Salicylicacid,hexyl esl.er 35.7.5 1674
Pulegone
3 2 .1 4 l 58l Salvene<(ll)-> 04.20 08.58
Pyg m aein
27.89 1477 Salvenc<(l)-> 04.01 0847
Pyran-2-one<6-nonyl--5.6-clihydro-2H>
imethyl-7-isobutyl- Salvial-4(l 4)-en-I -one 32.66 1594
Pyran-5-one <2,2-d
40.74 l809 Sandalore 28.72 t491
2H,.5H-pyranol4,3-bl->
Sandaracopimnra-8( I 4), I -5-diene 46.26 1968
Pyran--5-one <2,2-dimethyl-7-sec-hutyl-
40.49 1802 Sandaracopi nrarinal .5.3.06 2184
2H.5H,p1'rano [ 4.3-b]>
08.41 l0l7 Sandaracopirnarinol 55..58 2269
Pytazine<2-acetyl->
13.89 I156 Santalene <0-> 25.31 1416
Pyrazine<2-acetyl-3-ethYl->
10.7l 1011) Santalene <p-> 27.05 1457
Pyrazinc<2-acetyl-3-methYl->
05.29 0912 Santirlene<epi-|3-> 26.51 1445
Pyrazine<2-ethyl->
07.85 1002 Santalenone 3l .92 l.57fi
Pyrazine <2-ethyl-3-methYl->
04.86 0896 Santalol<(E)-B-> 38.15 1738
Pyrazine<2-melhoxY->
Santalol<(7)-[]-> 31.31 l7 l5
Pyrazine <2-rnethoxy-3-(2-methyl
14.91 1179 Santalol<(Z)-epi-P-> 36.84 1702
propyl-)->
(2-rnethoxy-3-methyl-> 06.8.5 0961 Santalol<(Z).u-> 35.14 1614
Pyrazine
-> 10.79 108| Santalolacetate<(E)-P-> 42.19 1867
Pyrazine<2,3-diethyl
0.s.38 0915 Santalolacetate<(.7')-a-> 39.-59 1171
Pyrazine<2,3-dimethYl->
07.71 1000 Santafol acetate<(ZYp-> 4 t.0.5 l8l8
Pyrazine <2,3,5-trirncthYl->
Appcndixl: Alphal.rctical
I-ist ol' Cornyrounds 21
Cornrrlrn Narne RT ConrnronNanre RT Al

Santaf ol acelate<(7)-epi-fJ-> 40.60 180.5 Silphipcr'lirlan-(rp-ol<7-epi-> 29,57 l.5l8
Santalone 14.n2 | 177 Silphipcrlirlan-7B-ol 29.62 t.5t9
Santene 04.6(t 0884 S i ncnsal< u-> 38.78 r75.5
Sant olina alc ohol 09.06 I034 S i ncnsal< p-> 36.73 1699
Sirnkrlinatricnc 0.s.12 0906 Skatole 23.8l r 38l
Santolinylacc'latc f .l..s4 | 17| Spathule'nol 31.96 l57l
Santoninc<g-> 53.65 2203 Spiroethcr<(E)-> 43..59 t890
Sativcne 24.21 1390 Spirocther<(7.y; 43.l9 | 879
Sclarcnc 46.15 tgt4 Spirolcpcchinene 2(t.(t9 1419
Sclare'ol -s4.2 t 2222 Scluanrulosone 39.3| 1710
Sclar c olidc 49."10 2065 Stenr<lne 12.54 | t24
Scclanenolidc 37..1.5 n 19 S{igrnast-4-cn-3-onc 79.26 3231
Sclin- Il- en- 4u- ol 3.5.r4 l6-58 Stilbene<3.-5-cli mcthyoxy-> 51.49 2232
Sclina-1, 3, 7(I | ) - t r i c n -S -o n c 34.t.s 1632 Stilbenc<4-hydroxy-> 48.65 2042
Se lina-1, 3. 7(I l) - t li e n -8 -o n e p o x i c l e 38.46 1746 Stilbcne<4-rncthoxy-> 41.06 1992
Selina-3.| | -clien-6u-ol 34..s4 1642 Styrcne<2,3,4,(r-tctramethoxy-> 34..53 1642
Sclina- 3, 7( | l ) - dic n c 30.66 t545 Styrenc<2,4,(r-trirnetlroxy-> 33.42 16t3
Selincnc<7-cpi-o-> 29.67 t520 S ugi ol 6-5.36 2629
Sc linc nc< a- > 28.71 1498 Sylvestlene 08.7.1 102.5
Selinene <B-> 28.37 1,189 Sylvcstrerre <iso-> 08.03 | 007
Sclinc.ne <6-> 28.11) 1492 Sylingaldehl,clc 35.04 I 6.5.5
Sempelvirol .5.s.98 2282 Tagetone<(11)-> t3.t9 | 139
Scsanxrl 20.69 l3l I Tagctcrnc <(7,)-> I .1..5-+I t.18
Sc.sclin 41.21 1998 Tagctone<dihydro-> 09.5| l016
Sesquici ncol-2-one 3(r.8| 1701 Tasrnanone 31.70 n26
Scsquicineolc 29.11 t.5l.s T'axoclione <6-dct'rxy-> 60.28 24.1.s
Se s quic ineolc 39.l(r 1766 Terninc<(7.)-> 41.97 t844
Sc,scluicincolc<7-c1i-I .2-dchydro-> 27.62. l41l Tc,rpincn-4-ol 11.66 n14
Sescl uici ncoIc <clchyclro-> 21.54 1469 '[erpincn-4-olacetate 20.17 1299
Sesquilavanclulol <(lr)-> 34.r0 163I Terpinen-7-al <u-> 19.46 1283
Sescluilervandulol <t Z)-> 33.f 6 1(t07 Tcrpinen-7-al<y-> 19.1(t 1290
Scscluilavandulyl acctatc<(Il)-> 38.| 9 1139 Tcrpinene<u-> 08.30 l0l4
Sesqrri Iavanclu lyl acetate<(7)-> 31.92 n32 Terpinene<y-> 09.78 10.s4
Scsqr-riphcl lanclrcne <B-> 29.10 l.s2I Tcrpi rrcol< | -> 12.11 I | 3t)
Sesquisabinene 27.05 t45l Ter;rineol<o-> 15.21 | 186
Scstluisuhi ncnchl,tllatc<cis-> 30..56 1542 Tclpineol<cis-p-> 1.1.20 | t40
i: Scsquisabincnc hydt'ate<tl'ans-> Telpi ncol <cis-dihych'o-a-> t4.09 I160
(lI ' t ' v s . O H) 3 | .99 l5l7 Terl-rineol <cis-clilryclro-p-> 13.89 I 1.56
Sesquitlru.iene 2'1.84 140.5 'ferpineol <6-> t4.11 | t62
Sesquitlrujcnc <7-e.pi-> 21.t9 r 390 Terpincol<y-> t.s.73 I t99
Scsrluithuril'erol 33.08 t604 Ter'pineol<trans-B-> 11.02 I t.s9
Seychcllcne 26..50 1444 Terpincol<tlans-dilrydro-a-> I3.33 |r43
Shisof'ulan 15.(r9 I 198 Telpincol <trans-di hydro-B-> 12.97 1134
Sh1,ol-runol 36.31 l (r88 Terpinolcnc l0.98 I0t36
Si hilc nc 24.(t2 1400 Terpinyl acclate<0.-> 22.26 13216
Sil phinc nc 22.t8 134-s Terpinylacetate<cis-clihydro-cr-> 20.9t | 316
Si lphipor lir l- 4.I74()-d i c n e 22.17 13.58 Terpinylacctate<6-> 20.90 l3l6
Silphipcrlirl--5-err-3-ol A 3t.t8 r.557 Terpinyl acetate<trans-dihyclro-n-> 20.22 t3(X)
Si lphipcrlirl--5-en-3-ol R 30.23 153,1 'l'cqlinyl isotrutanoatc<s-> 27.62 l41l
Silphipc r lol- 5- c n -3 -o A ne 3 | .84 t511 Tetracosarre <n-> .s9.33 2400
Silphipc r lir l- - 5- e n -3 -ou n c 30.86 l-s-50 Tetraclccanal 33.3.5 t 6 il
Si l phipc r lir l- 5- en e 21.31 1326 Tetraclccanc <n-> 21.61 t400
SiIphipc r lir l- 5- c rrc < 7 -c p i -> 22.20 l3,t-5 Tetladccanol<n-> 3-5.6.1 167|
Si lphi pcrlirl-6-cn--5-one 33.133 1621 Tcl raclccatric nc <(37,,67.92)-> 19.68 1288
Silphipcrlbl-(r-enc 2.1.(rI 1311 Tetlaclcccne< | -> 24.10 1.388
Si Iphipcrf'olan-(ru-ol 29.t2 1.507 Tetrahydroj asmone<cis-> t8.84 1269
Si lphipcrlbltrn-(rp-ol 30.70 t.546 Tctrahydro.jasrnoue<trans-> 20.(tl 1309
28 by GC/MS
ComrnonName RT AI Common Namc RT AI

Tetrahydrolutan<2,5-diethenyl-2- Totarol <7a-hydroxy-trans-> 60,.5.s 2445
methyl-> 05.29 0912 Totarol <cis->, nrethylether 53.78 2208
Teh'atriacontane 82.80 3400 Totarol <trans-> .56.88 2314
Thiazoleethanolacetate<4-methyl-5-> 24.18 1390 Totarol <trans->,methyl ether' 54.63 2237
Thiazole 02.54 0732 Tottrrol acetate<trans-> 60.f0 2428
Thiazole<2-acetyl-> 08.32 l 0l4 Totarolone 63.t0 2542
Tlriazole<2-cthoxy-> 06.38 09-s I Triacetin 22.31 1347
Thiazole<2-isotrutyl-> 08.89 1030 Triacontane 74.16 3000
Thiazole<2,4,-5-trinrethyl-> 07.62 091)4 Tricosane<n-> .56.48 2300
Thiazole<4-mcthyl-> 03.42 08l4 Tricyclene 0-5..53 0921
Thiazole<4,-5-dimethyl-> 0.5.7.5 0928 Tridccanal 29.22 | 509
Thiazolc<5-acetyl-2,4-dirnetlryl-> t7.23 1233 Triclecane <n-> 20.19 1300
Thio roseoxide <cis-> f 9.05 1274 Tridecanol<n-> 3 | .68 1.570
Thio roseoxide <trans-> 19.95 1294 Tridecanone <2-> 28.64 1495
Thir4rhene<2-butyl-> 09.89 10.57 Tridecen-l -al <(2E)-> 31.5-5 1561
ThLri-3-e n- l0-al 14.99 I l8l Tridecene 19.77 1290
Thu.ia-2,4( l0)-diene 06.44 09.53 Tridecenol<(2E)-> 3t .62 l -568
Th u j a nol< 3- > 14.26 1164 Tri decenolac'c'tate<(2Il)-> 36.8.5 1703
Thuianol<iso-3-> t2.94 | 134 Trihydroxy henzaldehyde<2,4,6-> 41.06 | 8l8
Thuianol<neo-3-> f 3.60 | 119 Trinrenal<(E)-> 25.45 l4l9
Tlrujanol<neoiso-3-> | 3.-s0 1147 Trirrrenal<(7)-> 24.51 t397
Thu.lanolacetatc<3-> | 9.98 1295 Trinrctfrylbenzaldchycle <2,3,4-> 20.79 l3 l3
Thirianolacetate<iso-3-> 18.7-5 1267 Trimethylbenzaldehyde <2,3,6-> 22.51 | 352
Thu.ianolacetate<neo-3-> 19.04 1273 Trimethylbenzene<1,2,4-> 08..57 l02l
Thujanolacetate<neoiso-3-> r9.38 r28l Tripropionin 33.00 1602
Thu.laplicin <a-> 25,06 l4l0 Tritriac-ontane 80.5-5 3300
Thu.iaplicin <p-> 21.19 1475 Tnrmerol <ar-> 32.fl 1.582
Thu-iaplicin <y-> 28.12 1483 Turmet<lne<ar-> 3.5.-s I l66u
Thuiaplicinol<u-> 29.20 1.509 Turmerone<ar-dihydro-> 32.70 1.59.5
Thujaplicinol<p-> 30.32 l-536 [Igandensidial .53..50 2198
Thu.jene<o-> 05.62 0924 [Jrnbellulone f 4.38 | 167
Thuiic acid 23.15 l380 Undec-l0-en-I -al 20.18 1299
Thu.jone<cis-> I 1..56 I 101 Undec-9ll-cn-l -al 20.70 l3l I
Thuione <tl'ans-> 12.00 | | 12 Unclec-9Z-en- 1-al 2t.17 1322
Thu.iopsadicne <cis-> 21.38 l46s Undecaclienal <(2E,4E)-> 25.28 l4l.s
Thu.iopsan-2u-ol 32.34 158(r [Jndecalactone <6-> 32.62 1593
Thulopsan-2p-ol 32.44 1.588 Undecalactone<T-> 3 | .6.5 1.569
Thuiopsanone <3-> 34.9.s 16.53 Undecan-4-ol 19.60 I 286
Thulopsanone <3-iso-> 34.48 l64l Unclecanal 20.45 130.5
Thujopsenal<cis-> 37.06 1708 Undecanal<2-methyl-> 23.10 136-5
Thu.iopsene <cis-> 2.5.8(1 1429 lJndecanal,dirnethylacetal 27.73 1474
Thujopsenicacicl<cis-> 42.65 1863 Undecane<n-> I1.48 ll00
Thynrohydroquinone 30.99 1.5.53 Undecanol<2-> 20.26 130|
Thynrol 19.11 1289 [Indecanol<3-> 19.92 1293
Thym<llacetate 22.38 1349 Undecanol<-5-> 19.52 1284
Thyrnol, nethyl ether 17.19 1232 Undecanol<6-> 19.51 1284
Thymoquinone t7.93 1248 Undecanol<n-> 23.19 1367
Ti g l i c ac id 05.20 0909 Undecanone <2-> 19.90 1293
Tiglic aldehyde 02.58 0137 Undecenal<(2ll)-> 22.74 t357
Tolualdehyde<meta-> | 0.1.5 1064 Undecenal<(8'Z)-> 20.20 l300
Tolualdehyde <o-> t0.09 1062 fJndecenol<(2E)-> 23.08 1365
Tolualclehycle <p-> 10.66 1077 Unclecenol <10-> 22.90 136|
Tol uene<2,4,6-trimethoxy-> 28.09 1482 Undecenolacetate<(2ts)-> 29.00 1.504
Torquatone 40.94 | 8l -5 fJndecenolacetate<l 0-> 28.76 1498
Torquatone<demcthyl-> 42.75 1866 Undecyne< | -> 12.45 | 122
T<lt'ulosol 58.21 23(t0 flntriacontane 16.35 3100
Totarene 44.68 1922 Valencene 28.66 1496
t Appendix I: Alplrabeticall-ist of Cornpounds 29
Conrnron Narne RT AI Conrnnn Name RT AI

Vafcncene<l l,l2-clthydroxy-> 44.40 l9l4 Vertocitral C <cis-> r0.6t 1076
Valcncene< | 3-hydroxy-> 39.22 1767 Veflocitral C <trans-> 11.72 I t0-s
Valeranone 35.14 1674 Vestitenone 26.49 1444
Valerianol 3.s.07 l6-56 Vetiselinenol 37.84 1130
Valeric acid <3-metlryl-> 06.0.5 0939 Vetispirene<c-> 28.38 1489
Valcrolactone <y-> 06.10 0941 Vetispirene<B-> 28.-s3 1493
Va nillin 24.32 1393 Vetivenene<1-> 30.09 t.531
Vanillin <ethyl-> 26.83 t4s2 Vetivenene<B-> 31.02 1.5.54
Va nillin< o- > 20.29 1302 Vetivenicacid 40. 80 l8l r
Vanillin acetate 29.85 1525 Vetivone <u-> 4t.89 1842
Vanillone,aceto- 28.0.5 148| Vetivone <B-> 41.20 1822
Vanillyl alcohol 2(t.51 1445 Viridene 14.21 l163
Vel<'rutone 20.63 1309 Viricliflorene 28.68 1496
Veltonal<(11)-> 3 | .07 15.s.5 Viridiflorol 32.58 1592
Velbnal <(Z)-> 30.40 r 538 VulgaroneB 34.8r 1649
Veratrole 13.28 1141 Warburganal 48.08 2023
Verbanol I -5.66 1197 Widclra-2,4( I4)diene 28.03 r48l
Velbanol <iso-> 14.78 1176 Widclrol 32.85 r.599
Velbanol <nco-> 1.5.01 1182 Xanthorrhizol 38.64 1751
Verbanol<neoiso-> 15.25 I I 87 Xanthosternone 25.94 l43l
Ver'l"ranol
acetate 22.00 r 340 Ylangene<c-> 23.43 1373
Verrl.ranol
acelata<iso-> 20..58 l308 Ylangcne<p-> 25.43 1419
Verbanol acetats<neo-> 21.05 l3l9 Yomogi alcohol 07.75 0999
Vcrl-ranolacctate<ncoiso-> 21.45 1328 Zerumbone 37.94 lt32
Verbenenc 06.6't 961 Zlerone 3l.86 1574
Verbenol<cis-> l:r.07 | 131 Zingiberene<u-> 28.-s3 1493
Verbenol <tfans-> 13.22 lt40 Zizanal 36.63 1697
Verhenone 1s.97 1204 Tizanone <epi-> 3.s.-54 1668
Verbcnyl acetate<c,is-> l9.3_5 1280 Zonatene 29.97 l -528
Verbenyl acetate<trans-> f 9.83 1291
AppendixIl: Compounds
Listedin Orderof Elutionon DB-5 3t
AppendixII
COMPOUNDSLISTED IN ORDER OF THEIR

RETENTION TIME AND ARITHMETIC RETENTION INDEX ON DB-s
32 Adarns:
Esscntial by GC/MS
Oil Components
RT AI ConrrnonNamc RT AI Corrmon Naure

f .63 529 lJthyl etherr 3.22 802 Hthyl butanoate
|.80 (106 Iithyl acetate 3.25 804 Methyl-1,4-cyckrhexadiene
1.88 623 Hexanc<n-> 3.30 807 Nothorncnc<-5-nrethylcne-2->
1.93 634 Methyl propanoate :1.3| 807 Butyl acetate
1.99 647 I )ichloroethane < 1,2-> 3.32 808 Octcne<(27.)->
2.00 650 Cyclol-rutanone 3.42 8l4 Thiazole<4-nrethyl->
2.0Q 650 Isrrbulanol 3.4-5 8l5 Octene<(21'.)->
2.02 654 Ilutanal,2-mcthyl- 3.52 819 P yl azi nc'
< mcthyl ->
2.04 658 Isovaleraldehycle 3.5-5 82 | Mcthyl pentanoate
2.10 6t I Mcthyl-2-hutanol <3-> 3.60 824 Cyclohexene<3,3,-5-trirlcthyl->
2.11 680 Isohtrtylfornrate 3,62 825 Prenylfbrnratc
2.15 (t87 Pcntanone <2-> 3.6(1 827 Isovalericacid
2.15 682 Pyruvicacid 3.(t7 828 Furlirral
2.16 684 P ent en -3 -o<ll -> 3.70 830 Pentanol<4-rnethyl->
2.18 689 Pentanol<2-> 3.12 83 1 Pentanonc <4-hydroxy-4-rncthyl-2->
2.23 700 Heptang 3.14 832 Cyclohexene <3,.5,5-trinrcthyl->
2.23 7(X) Pcntandione <2,3-> 3.15 832 Butanoicacid<2-mcthyl->
2.25 702 lrthyl lulan <2-> 3.16 833 Pcntanol<3-nrcthyl->
2.27 101 Pentanal 3.ttI 836 Isoprr4rylbutanoate
2.33 7tl IJthoxyethanol<2-> 3.96 844 Hexcnol<(3E)->
2..r+ 7 11 Ethl'l prol.ranoate 3.99 846 Hexenal<(28)->
') f f 111 4.0I 841 Salvene<(/.1->
Methyl butanoate
') t< lrtlryl isovaleratc
B utcn-I -ol <3-rrethyl-3-> 4.04 849
"11
2.J6 724 Methyl-l-butanol<2-> 4.06 850 Hexenol<Q7)->
2.-50 12,3 N'lethyl-2-pentanone <4-> 4. f 3 854 Hexcnol<(2h)->
2..50 7I8 Norhornene 4.2O 858 Pentenoicacicl<4->
2..5.1731 Isopentylalcohol 4..20 858 Salvene<(E)->
2..s-1732 T hiaz o l e 4.22 8-59 Hexenol<(27,)->
2.58 731 Tiglic aldehyde 4.28 863 He'xanol<n->
2.61 740 Nlethylcyckrhexene 4.28 86.1 Mcthyl tiglate
2.6s 744 P ent enl--a l < 2 E -> 4.10 8(r9 Isopcntylacetate
2.66 745 Pcntanol<4-mcthyl-2-> 4.40 869 Mcthyl-(32)-hexen-2-one<-5->
2.81 t(fi Cyclohexarcliene <2-rnethyl- 1,3-> 4.42 871 H cxenol< (4ZJ->
2.81 761 Isobulyl acetate 4.42 87 | Methyl pentanoate <2-rncthyl->
2.82 7(t2 Pentanol 4.50 87-5 Mcthylbutyl acetate<2->
2.83 763 Butanoicacid 4.59 8lt0 lluten-l-ol ac:etate <3-rrrcthyl-3->
2.8.5 765 Buten-I -ol <3-me.thyl-2-> 4.59 tt80 Isopropyl-2-rne.thylbutyrate
2.8.5 765 Pentcnol<(27.1-s 4.60 8ttl Allyl butanoate
2.88 169 B Lrten-2-ol acetate<2-rnethyl-3-> 4.60 881 Butenoicacid,3-methyl-2-
2.88 769 Hexen-1]-ol < l-> 4.65 884 lithyl pent-4-enoate
2.90 77| Cyclohexacliene 4.66 884 Santcnc
2.91 778 Methyl-2-butenal <3-> 4.68 885 Hcptanol<4->
3.03 7ti-5 Butanecliol <2,3-> 4.70 88(r Pentanal<-5-hydroxy->
3.03 78.s Cyclohexene <3-rnethylene-> 4.74 889 Heptanone<2->
3.04 186 Cyclopentanol 4.80 892 Methyl-(3lr)-hexen-2-one<-5->
3.05 181 ll utanethiol<2-methyl-> 4.82 893 Heptenal<(47.)->
3.06 788 f )irnethyl-3-pentanone <2,4-> 4.84 894 Hcptanol<2->
3.06 788 Isopcntyl firrmate 4.86 896 Pyrazinc<2-melhoxy->
3.06 788 Octene< I-> 4.91 898 Propylhutanoate
3.08 790 lsoplopyl isohutyratc 4.93 900 Nonane<n->
3.10 792 llexenal<(3E)-> 4.96 90 I frlhyl pentanoate
3,t4 196 Hexanol<2-> 4.97 901 P ropanal ,3-methyl thi o-
3.15 797 Hexcnal<(32)-> 4.98 901 H eptanal
3.17 800 Hexaneclione <3.4-> 5.0.1 90.1 H,thoxyethyl acetate<2->
3.t7 800 Octane<n-> 5.0-5 904 Hydroxyhutanoic acid lactone<4->
3.19 801 Hexanal .5.l 2 906 S antol i nul ri ene
3.20 80r Octcnc<(4I1)-> -5.| 3 907 llutyl propanoate
AppendixI[: CornpoundsListeclin Ortlcr of Elution on I)B-5 f-l
RT Conrnron Nanre RT AI Cor.nn'ronNanre

5.14 907 Hcxaclienal <(28,4F.)-> 6.3.5 950 Mercaptopropanoicacid <2->
.s.l8 908 Isobutylisohutylate 6.38 95 | Thiazole<2-ethoxy->
-s.II 908 Pyrazine<2,-5-dinrcthyl-> 6.43 952 Benzalclehyde
5.t9 909 Acetyllin'an<2-> 6.44 953 Thu.ia-2.4(l0)-cliene
.s.20 909 T igl i c a c i d 6.49 954 Cyckrhexyllbrmate
i
-s.2| 909 Pyrazinc<2,(r-dimcthyl-> 6.-56 957 Furfulal<5-rnethyl->
.s.2-s9l I Anryl acetate 6.-58 958 Hcptan-2-ol<(r-nrethyl->
5.29 912 Hexaclienol <(28.4E)-> 6..58 9-58 Hepten-l-ol <(2Ii)->
5.29 912 Pyrazinc'<2-ethyl-> 6.-59 9-58 Octcn--5-yne<(2E-)-rnethyl-3->
5.29 912 Tetrahydrofuran <2,-5-cliethenyl -2-methyl-> 6.63 959 Heptanol<n->
-s.-r2 9 t.l A ni s o l e (t.63 9-59 Hepten-l-ol <(47.\->
5.32 913 Hexe:nylfolmate<(37,1-2 (t.64 96O lsolrrrylpropionatc
.5.3.5914 Butcn-| -ol <3-mctlryl-2->.acetate 6.61 961 Verhencne
-5..r891.5 Pyrazine<2.3-dimcthyl-> 6.84 967 Hexanoicacid (=ssp1olcacid)
-5..169 l 8 Heptanone<2-methyl-4-> 6.85 967 Pyrazine<2-rnetl"roxy-3-rnethyl->
-5.46 918 Heptanone<3-nrethyl-4-> (impurc) 6.9() 9(r9 Methyl2-l uroate
-5..169l8 Hexcnyllirnnate<(2H)-> 6.90 969 Propanol,3-methyltlrio-
-5.:t6 9 | 8 IsociIronellene 6.91 969 Pinane<trans->
-s.+8 919 Acetonyl acetoue 6.9| 969 Sabincne
-5..s.3921 Iil lryl 2-methyl-4-pentenoate 6.93 970 lsoplopyltiglate
-s.-s-3921 Tricyclene 6.93 910 Norbolneol<exo-2->
-s.-s+921 Methyl hexanoate 6.96 91 | Arterriseole
-5.-59923 Pentenoicacicl<2-rnethyl-4-> 6.98 972 Octen-3-one < l ->
.5.6| 923 Altcrnisiatriene 7.00 912 Octcn-2-ol<(37)->
-5.62 924 Thuiene<o-> 1.01 913 Hcxanal,dinrethylacetal
-5.6-3924 Cumene 7.02 973 Dimethyl-4-heptanone<3,-5->
5.66 925 Heptanone<4-nrc.thyl-3-> 7.03 973 Menthane<trans-p->
.5.71 927 Hepten-2-one <(38)-> 1 .04 974 Octen-3-ol< l ->
_5.71927 Pentanoicacid <2-methyl-> 7.04 974 Pinene<B->
5.72 927 Methyl-(3tr)-hexenoate 7. l8 919 Mentha-2,8-diene <tlans-meta->
-s.75 928 Thiazole<4,-5-dimethyl-> 7.19 919 Octanone < 3->
-s.78 929 Ethyl tiglate 7.22 980 lsolinronene <tt'ans->
-5.80 930 Citlonellene<tetrahydro-> 1.25 9ft I Heptcn-2-one <6-rnethyl--5->
5.U0 93t) Oxazolc<2-cthyl-4,5-dirncthyl-> 7.26 982 Norborneol<endo-2->
-5.8| 930 Ethyl 2-methylpentanoal"c 7.27 9132 Pinane<cis->
-5.82 9-rI Allyl isovalcrate 7.28 982 Octcn-2-ol<(3E)->
-5.83 931 Cyckrpentene <3,-5-dimethylenc-
1,4,4- 7.30 983 Flexenoicacid <(3E)->
trirncthyl-> 1.31 983 Mentha-2.S -di cne< ci s-mcta - >
5.8-5 932 Norhtrrncn-2-ol <cnclo-5-> 7.31 983 Mcthylpentanoate<2-hydroxy-4-methyl->
5.8-5 932 Pincne<u-> 1.32 984 Menthene<3-p->
5.89 933 Pentanoicacid <4-methyl-> 7.34 984 Pcntyl frn'an<2->
5.95 93.s Cyckrhexanol <3-rncthyl-> 7 .39 98(r l)eccnc
.5.98 936 Heptanone<5-rnethyl-3-> 1.42 987 Furlirrylacetate
6.00 931 Fruitaleur(=ethyl2-mcthyl-3-pcntenoate) 1.43 988 Myrccnc
6.05 939 Norbornen-2-ol<exo--5-> 7.41 9ft8 Octanol<3->
6.0.5 939 Valeric acid <-3-nrethyl-> 7 .45 988 Cineole<dehydro-1,8->
6.10 941 Acetoxyhexanc<2-> 1.45 988 Octanonc<2->
6.10 941 Valerolactonc<T-> 1.47 989 flcpten-2-ol<6-nrethyl--5->
6.15 942 Citroncllene<p-> 7.48 989 Hcpttrnol<2,6-dimethyl-2->
6.21 945 Cyclohexanone <3-methyl-> 1.48 989 Metlrylpentanotrte<2-hydroxy-3-methyl->
6.21 945 Methyl pent-2-enolide <4-> (impure) 7 .52 99 | Linakroloxide <dehydroxytrans->
(t.22 945 Fenchene<o,-> 7.-58 993 Br.rtylbutanoate
6.26 916 Canrphene 1.60 994 Octanol<2->
6.21 947 Hcptcnal<(2ll)-> 7.61 994 Mesitylenc.
6.28 947 Heptcncrl<(37)-> 7.62 994 lsobutyl-(2tj)-butcn()ate
6.34 949 Irthyl 3-methylpentanoate 7.62 994 Thiazolc<2,4.-5-trirnethyl->
6.35 9.50 Glyccrol 7 .71 991 Ethvl hexanoate
by GC/MS
Oil Components
Adams:Essential
RT Al ComrnonNatrte RT AI CorrrrnonName
1.72 998 Octanal<n-> 9.l9 1933 lJcptylacelate<2->
t).20 1038 lrthyl hex-(2E)-enoate
7.14 998 Furluryl methylsulllde
7.15 999 Yonrogialcohol 9.23 1039 S al i cyl al dehyde
1 .11 l000 I)ecane<n-> 9.33 1042 Hexalactone<y->
1 .17 1000 Pyrazine<2,3,-5-trintethyl-> 9.42 1044 Ocimenc<(Ir)-[J->
1 .79 1000 Mentha-| (7).8-diene<meta-> 9.45 10,15 lsobutylangclate
'7.84 l00l Cat'ene<6-2-> 9.-50 1046 Methyl-2-cyclohexen-1-one
1 .81 100I Hexenylacetate<(3ts)-> 9.5| 104(r A rhuscttl onc < ci s->
7.85 1002 Phellandrene <u-> 9.5I l046 Tagetone<dihydro->
7.85 I002 Pyrazine<2-ethyl-3-methyl-> 9.52 1047 Octen-l-ol<(37')->
7 .8 9 1003 M ent ha -l (7 ),S -d i e n e 9.51 | 048 Prenylisobutyrate
7.91 1003 Ethyl-(.31i)-hexenoate 9..59 1049 Octcn-l-al<(2E)->
1 .93 100,1 Hexenyl acctate<(.32)-> 9.62 I049 Pentylisohutanoate
7 .96 100.5 Cresolmethylether<o-> 9.64 1050 lltltyl levulinate
1.99 1005 Heptndienal <(2E,48)-> 9.65 1050 Cresol<o->
'7.99 1005 Hexenoicac:id<(2E)-> 9.61 l0-51 Bergantal
1 .99 100-5 Pentyl Propanoate 9.12 I0-52 Isopentyl hutanoate
8.01 1006 Linalool oxidc <dchydroxycis-> 9.77 1053 Naphthalene <trans-dccahydro->
8 .0 3 l( X ) 7 S y lv esl t' c n<ei s ()-> 9.18 l0-54 Terpinene<Y->
8.0-5 1007 Hexyl acetate 9.79 105,1 Acetylpyrrole<2->
8.05 1007 lsoamylisobutYrate 9.84 10.5.5Methylcyclohexylcarboxylate
8 .1 0 1008 Car ene< 6 -3 -> 9.88 l0-56 Artemisiaketone
8 .1 7 1010 Hex en y l a c e ta te < (2 E)-> 9.89 1057 Thiophene<2-hutYl->
8 .1 8 101I l) ic lr lo ro h c n z e n e < 1 ,4 -> 9.92 l0-57 Benzc.ne metlranol<u-methyl->
8 .2 2 l0l2 Cineol e< 1 ,4 -> 9.9-5 1058 Norbornene-2-mcthanol<exo-5->
8.24 I0I2 Isopt'opyl-4-methyl tlriazole<2-> 9.99 | 0-59 Aceto;rhenone
8.21 l0l3 Heptadienol<(2lr,4f:,)-> 10.00 1060 lsobtrtylacetoacetate
< c r-> 10.02 1060 Flcxenyloxy-acetaldehyde <(3iZ)->
8 .3 0 l0l- 1 T er pin e n e
8 ..12 101. 1T hiaz o l e< 2 -a c e tYl -> 10.03 1060 Octen-l -ol< (2l r)->
8 .3 4 l0l- 5 A nis ol e< P-n re th Y l -> 10.09 1062 Tolualclehyde <o->
8 .4 1 l0l7 lr t hy l2 -mc th y l -2 -p e n l e n o a te < (E )- > l0.l | 1063 Hexadienolacetate<(28,48)->
8 .4 1 l0l7 P y r az i n e< 2 -a c e tYl -> 10.11 1063 Octanol < n->
<3-methyl-I '2-> 10.| 2 1063 Hexenyloxy-acetaldehycle <(38)->
8.43 l0l7 Cyclopentanedions
8.51 I0l9 trthyl 2-methyl-2-pentenoate <(1')-> 10.l-5 1064 Tolualdehyde<meta->
8.53 1020 Cyntenc<P-> 10.20 1065 Octenol<62)->
8.57 l02l Allyl tiglate 10.20 106-5Sabinenehyclrate<c:is->(IPP vs. OH)
8.-57 l02l Methyl hePtanoate 10.22 1066 Arbusculone<u'ans->
8 .5 7 l02l T r im et h y l h e n z e n4e,2 ,4 -> 10.23 1066 Octanone<5-hydroxy-4->
8 .-58 l02l M ent h e n e< l -P -> 10.29 l06l Linirlooloxicle<cis->(furanoid;
8.-59 1022 Cynrcne<o-> 10.30 1068 Mentha-3,8-diene <P->
10.30 1068 Norbornene-2-rnethanol <endo--5->
8.69 1024 Limonene
8.70 102-5Phellanclrene <B-> 10.3I 1068 Roseoxide <trans-dihydro->
8.73 l025 Sylvestre,ne 10.35 1069 l)ihyct'onryrcenol
8 .7 6 1026 Cineol e< l .t3 -> 10.43 1071 Benzyl firrmate
8.17 l02fr Bcnzyl alcohol 10.43 l 07l C l esol < p->
8.80 1027 Hexanoicacicl<2-methyl-> 10.45 1072 Cresol<meta->
8 .8 3 1028 A c et Y l PY ri d i n<e2 -> 10.52 10"74Heptanal,dirncthylacetal
8.89 1030 Thiazole<2-isohutyl-> 10.61 1076 V erl oci tral C< ci s->
8.90 1030 Octcn-2-one <(3E)-> 10.66 1071 Tolualclehyde <P->
8.95 103I Furan<2-acctyl-5-rnethyl-> 10.70 1078 C ampheni kne
8.96 1032 ()cirnene<(Z)-F-> 10.1| 10"19 Pyrazine<2-acetyl-3-rnethyl->
8.99 1032 ProPYltiglate 10.12 1079 Allyl hexanoate
9.03 1033 Hexanoicacid <-5-methyl-> 10.76 1080 Artenrisiaalcolrol
9.04 1034 l-avenderr lactone 10.76 1080 Benzene<2-methoxyethyl->
alcolrol 10.78 l()8I Acetyl-2,-5-dirnethyl furan<3->
9.06 1034 Sarrtolina
9.14 I 036 Benzene acetaldehYcle 10.79 l 08l P yrazi ne< 2,3-di ethyl ->
9.11 1037 Roseoxide <cis-dihyclro-> 10.80 l08l Flexenal<(27')->,cliethylacetal
AppcndixII: Conrpounds
l-istedin Orderol-Elution
on DB-5 tf
RT AI Common Name RT Al ColnnronName

l0.tt2 l0ti2 Cymenene<mera-> 11.69 | 104 Fenchocanrphorone<u->
10.8(r1083 Pyrazinc<Fn'arnethyl-> 1 1.72 l l0-5 Veltocitral C <trans->
10.88 1083 Fenclrone | 1.74 1106 Dirnethylplrenol<2,6->
l0.lltt 1083 Fur'lurylpropionatc l l.7-5 I 106 Phcnylethyl alcohol
10.89 10821Linalooloxide <trans->(fLrranoid) | | .71 | | 06 Leaf alcohol,erhyl aceral
10.94 108-5Butyl angelate 11.77 | 106 Mal tol
| 0.94 I 085 Cyclohcxanedit'rnc <3-rnerhyl-1.2-> | 1.77 | 106 R oseoxi de< ci s->
10.94 108-5Mentha-2,4(8)-diene <p-> I 1.80 I 107 Acrolein<(3E)-(2-furyl)->
10.97 1086 Acetyl rhiophene<2-> l | .86 | 108 Menthatriene <1.3,8-p->
10.98 1086 Terpinolene l 1.90 l l 09 B enzal dehyde,di methylacetal
| 1.fi) 1087 Gr-raiacol <o-> I I .9-5 I I 10 Octen-3-ylacetare< l->
| | .0| | 087 Hexenal<diethylaceral<(3E-)-> 11.98 I l l l C anrphenol < 6->
| | .0-31087 Nonanone<2-> | 1.99 I 1 l I Heptenylacerare<(2E)->
I l-0-5 1088 Linalool <dchydro-> 12.00 I I l2 Isopropyl--5-rnethyl-(22)-hexenal <2->
I l.O-5 1088 Nolbornen-2-olacetate<exo--5-> 12.00 | I 12 ThLrlone <trans->
| 1 .07 1088 M c t hy l h e n z o a te 12.02 ll l2 Heptyl acetare
I l.Ott 1089 Pentylbutanoate 12.03 | I l2 Merthylbutanoate,3-rnethyl-3-butenyl <3->
I l.0S 1089 Cymenene<p-> 12.01 | I l3 Octadienol<(2E,4E)->
I l. I I 1090 Hexcnyl nrethylcarbonatc<(37)-> 12.10 1 | l4 Fenchol<endo->
I l.l -l | 090 F,poxyrnyrcene <(r.7-> 12.25 1l l7 Sabinaketone<dehyclro->
I l.l{ l09O Hcxcnal<diethylacetal<(32-)-> 12.27 | l l 8 Isophorone
I l.l-t 1090 Isopropyl-2-rnethoxypyrazine <3-> 12.28 1l I 8 Fenchol<exo->
I l.l5 lO88 Isobutyltiglare 12.29 l l l 8 Menth-2-en-l -ol < ci s-p->
I l-19 1092 Butyl pentanoate 12.30 I l l9 Ethyl lrexanoicacid <2->
I l.2O 1092 Etlryl sorbate 12.32 l l l 9 Myrcenol
Il-22 l{D2 Norholnen-2-olacetate<enclo-S-> 12.33 | I l9 Mentha-2.8-clien-l-ol <rrans-p->
I l-2-3 109-1Pyrazine<nrcthylthio-> 12.33 | I l9 Pinenehydrate<trans->
I f .-lO lO9-5 Hexenyl propionatc<(37,)-> 12.-l -5| 120 Octanolacetate < -1->
| | --ll 1095 Canrphenone<6-> 12.40 l12l Ethyl 3-hydroxyhexanoare
ll--12 l1y75 Linalool 12.45 1122 Roseoxide <trans->
f f --18 1097 Nonenal<(67,)-> 12.45 | 122 U ndecyne< l ->
ll-.t0 1097 Etlryl lreptanoate 12.46 | 122 Canpholenal<u->
I l-^t{) lO97 Nonanol <2-> 12.50 l 123 Methyl ocranoate
I l-.11 l()98 Sabincnehydrate<trans->(IPP vs. OH) l2.-53 | 124 Clrrysanthenone
f l-41 1098 Heprenolacerate<(..17)-> 12.54 l l 24 S temone
I l-{l 1098 Hexenal<(28)->, dierhylacetal 12.-5-5I 124 Norborneol acetate<endo-2->
I l--l-3 1098 Linalool <terrahydro-> 12.59 | l2-5 Norl-rorneolacetate<exo-2->
f f -J-+ 1099 Dinrcthyl styrerlte <2,5-> 12.64 1127 Octyl ftrrnrare
I l--t-5 1099 Pincncoxide <c.-> 12.68 1127 B utyl ti gl ate
I l.J6 | $)9 Naplrthalene' <cis-decahydro-> 12.70 1128 Ocimene<allo->
I l--18 I lfi) ljndecanc <n-> 12.72 | 128 Epoxy-ocimene <(Z)->
l l --19 llf X ) I ps c n o l 12.11 1130 Terpi neol< l ->
ll-{9 | l(X} Isopentyl2-rnethylhutanoate 12.19 1l 30 Cyclohexylpropanoare
| |*50 | |(X) Methyl butyl-2-rrrethylbutyrate<2-> 12.82 113l Linalool<dilrydro->
l l -Y ) ll02 P er ill c n e 12.82 ll3l Myloxide <(Z)->
l l -51 llf X ) Nona n a< l n -> 12.88 | | 32 Lirnoneneoxide <cis->(Mevs IPP)
I ls-f I l0l Hexyl prt4ranoate 12.90 1133 Pyrazine<3-methyl-2-isobutyl->
ll-56 | l0l Heptenylacerat-e <(.27.)-> 12.93 1133 Mentha-2,8-dien-ltl <cis-p->
I l-56 I lOl Thu.ionc<cis-> 12.94 | 134 Benzeneacetonirrile
I l-58 | lO2 Phcnyl propanal<2-> 12.94 1134 Thujanol<iso-3->
ll-59 | 102 C)ctaclienal <(2Ii.4E)-> 12.91 1134 Terpineol<trans-dihydro-B->
I l-60 | 102 Disulllde,dipropyl 12.98 | 134 Cresolacatate<o->
I l-60 | 102 Isopentylisovalerare 12.99 | | 3-5 Pinocarveol<trans->
I l -62 l | 0-1 Octadienal<2,2-dinrcthyl-3.4-> 13.02 | 135 N opi none
I I -6-5 | | 03 Hexenyl plopanoare<(2E)-> 13.04 | 136 Menth-2-en-l-ol<trans-p->
| | .6-5 | | 03 Methyl butyl isovalerate<2-> 13.07 | 1.17 V cl henol< ci s->
| | -66 | 104 Isopropyl-5-methyl-(28)-hexenal <2-> 13.08 I 137 Butanoate<3-methyl-2-butenyl 2-nrerhyl->
by GC/MS
Oil Cornponents
Aclarls:Essential
36
AI CornmtlnNanre RT Al Conmon Name

RT
<(11)-> 14.00 ll58 Cresolac<:tate <meta->
13. 10 l 137 Irpoxy-ocimene
l4'00 | l-58 Pinocamphonectrans-> (=trans-3-pinanone)
1 3 . 10 I 137 Lim on e n eo x i d c< tra n s ->(Me v s .IPP )
| 3.10 I I 37 Sabinol<trans->(OH vs. IPP) 14.02 | 159 Terpineol<trans-B->
1 3 .l- 5 I l38 G ei. ie re n e 14.0,1I159 Nonadiewtl<(2F,67)->
I 3. I 8 t I 39 PinenchYdratc<cis-> 14.05 I l-59 Hexadicnolpt'opanoale<(.28,4E)->
1 3 . 19 | 139 T aget o n e < (B)-> 14.0-5I 159 Mentholuran
< n e o -a l l o -> 14.06 l l 60 C hrysanthenol < ci s->
1 3 . 20 | 140 O c ime n e
13.20 | 140 Terpineol<cis-P-> 14.06 l l 60 l soci tral< (7' )->
1 3 . 2| I 140 ls oc itra<l e x o -> 14.(11l l60 Pinocarvone
13.22 | 140 Vcrbenol<trans-> 14.09 I 160 Terpineol<cis-diltyc'lro-o->
14.12 1l6l l)inrethoxyhenzene < l ,4->
1 3 . 23 ll40 I ps die n o l
13.2.1I140 lsophorone<4-keto-> 14.13 l l 6l Mcnthol< nco->
1 3 .23 I 140 M Y r o x i d e< (E)-> 11.14 | 162 Terpi neol < 6->
1 3 .28 ll4l Car nP h o r l4. l-5 I | (r2 Nonenol<(27)->
13.28 ll4l Veratrole 11.20 | 163 Nonenol<(2ts)->
13.30 ll42 Hexenylisobutanoate <(371-2 14.21 1l (r3 D i methylani l i ne< 2,6->
13.33 | 143 Telpineol<trans-dihydro-u-> 14.21 l l 63 V i ri dcne
1 3. 34 l 143 I s oam Yla n g e l a te 14.22 | l (r3 Melhyl 2-octenoate<(E)->
13.31 | 144 IsoPulegol<neo-> 14.2(t I l(r.l Nonenol <(67)->
13.37 | 144 Necrocltll<trans-o-> 14.26 | 164 Thui anol < 3->
I 3.38 I l44 Heptalactone<T-> 11.21 | 165 Ilenzcne<1,3-dirnethoxy->
l -1.40I 144 Nonen-l-al <(22)-> 14.29 ll6-5 lJonreol
13.43 I 145 CarnPhene hYdrate 14.29 | l(r5 Nonanol<n->
1 3. 43 I 145 ls oP u l e g o l 14.30 I165 Lavancl ul ol
14.32 | 166 Mentha-1,.5-dien-S-ol <p->
1 3. 43 I 14. 5 M Y r c n
e o n e
13..15| l-1-5Menth-3-en-8-ol <p-> 11.32 | l6(r PinocanrPheol
1 3. 47 I lJ 6 E uc a rv o n e 14.35 I 166 C oahui l cnsol
14.35 l l 66 C resolacetate 
1 3 . 47 I l. 16 P hen o l2, -(I Z )l ro p e n y l
13.-50I 147 Hexl'l isobutanoate 14.36 l l67 Angustilirlenone
13 .50 | 147 T huia n o < l n e o i s o -3 -> l4'31 1167 octnnoic acid (=snp1'ylic acid)
13.-5 I I 147 Butanoate<3-rnethyl-2-butenyl 3-methyl-> 14.38 | I67 Isopul egrl< neoi so->
1 3. 54 I 148 T age to n e < (Z )-> 14.38 I 167 U mbcl l ul one
I 3. 55 I | 48 M ent h o n e 14.39 1167 Menthol
14.42 ll68 Methoxy-3-(1-methylpropyl)pyrazine <2->
1 3. - 57ll48 ls oetm Yl ti g l a te
t 1.43 | I 68 Mcthyl (2-lirryl
-.3 )acrolein <(22) ->
l -3 . 58I 148 Cit r o n c l l a l
13.59 l 149 lJthylhexyl acetate<2-> 14.47 | 169 Ethyl benzoate
13.59 I 149 Nonadienol<(38.62)-> 14.48 I169 Artcnrisylacetate
14.48 | 169 N ccrodt' < l ci s-c->
1 3 . 60 I 149 T hul a n o < l n e o -3 ->
l3.62 | 149 IsohutYlhexernoerte 14.50 | 170 FurlurYll-rulanoate
14.52 | 170 Linalooloxide<cis->(pyranoid)
13.64 I 150 Nonadienal<(28,62)->
l -1. 7. 111. 52llc nz c n e 14.54 lll1 SantolinYlacetate
14.57 | 172 Pinocattrphone <cis->(=cis-3-pinanone)
1 3 . 14 1l- 52 None n -l -o l< (3 7 ,)->
13.79 | l-53 Phenyl-tert-butanol 14.(r0| 172 Phenylethyl lbrmate<2->
1 3. 80 I 154 Ner o l o x i d e 14.64 | 173 Linalool oxicle<tlans->(pyranoid)
14.6-5l l 73 R oscl uran eP oxi de
13.82 | 154 Karahanacnone
l 3 . 83 I l- 5; l P inc n eo x i d e 14.66 | 174 Terpincn-4-ol
13.83 I 154 Sabinaketone 14.12 | | 75 IsoamYlacetoacetate
14.12 | 175 Octanc< l ,l -cl i methoxy->
1 3 . 86 I 155 ls oP u l e g o<l i s o ->
<2'-> 14.73 | l7-5 Benzencaceticacid' r-rrethyl ester
l3.87 I l -5-5Hydroxy acetophenone
I3. 87 I 155 ls ob o rn c o l 14.16 | 176 DicthYlsttccinate
13.89 l l-56 Pyrazine<2-acctyl-3-ethyl-> 14.18 l176 Cymen-8-ol<nreta->
11.78 | 176 PinocamPlreol <iso->
| 3.89 I 156 Terpineol<cis-dihydro-p->
14.'18| 176 Verbanol <iso->
1 3. 91 l 156 P en ty lc y c l o h e x a -1 ,3 -d i e n e
14!79 ll11 Dec-1-en-3-ol
1 3. 94 11. 57Non e n -1 -a<l (2 E)->
l-3.9-5I l-57 Lavandulol<tetrahycho-> 14.82 | 177 lsocitral<(E)->
13.96 l 157 llenzyl acetate 14.82 l l 77 S antal one
l -1.99| l-58 Mcrrtlronc<istt-> 14.84 I 178 N aphthal ene
AppendixII: Compounds
t.istedin Orderof Elutionon DB-5
-1 |
RT AI Comnron Name RT Al ColnrnonNalne

14.85 I 178 Ethyt-3(2-furyl)-propanoate l-5.66 I 197 Butanoicacid,2-merhyt-4-methylpenryl
14.8-5I178 Methyl isoborneol<2-> estef
1 4. 86 I 178 A lly l h e p ra n o a re 15.66 I197 Methyl u-cyclogeranare
14.89 | 179 Heptenal<(42)->,diethylacetal l -5.66 I197 V erbanol
14.91 1179 Acetophenone <p-methyl-> 15.67 | 197 Octenolacetare <(22)->
1 4. 91 | 179 Cy m e n -8 -o l f -5.68| 197 Hexenyllacrare<(32)->
14.91 | 179 Menthol<iso-> l -5.691198 S hi sofuran
14.91 1 179 Pyrazine<2-merhoxy-3-(2-methylpropyl-)-> 15.72 | 198 l)ecanol<2->
14.94 1180 Furl'urylacstone 15.73 l l 99 Terpi neol< y->
14.99 1l8l Hexenyl pyruvare<(32)-> 15.14 1199 Decenal<(72)->
1 4. 99 I 181 T hu. j -3 -e n -1 0 -a l 1.5.7-5I 199 Ethyl oct-(22)-enoate
l-5.00 ll82 Pinocarveol<cis-> l -5.7-5I | 99 Menthan-2-one<rrans-p->
l -5. 01I 182 V er ba n o < l n e o -> 15.71 l20O Dodecane<n->
l-5.02 I182 Maple furanone l-5.80 1200 Caranone<cis-4->
l -5. 071183 Cr y pto n e l -5.80 l200 Dihydro carvone<trans->
15.07 I I 83 Cyclopent-2-enone <-5-methylene-2,3,4,4- 1.5.83l20l f)ecanal<n->
tetramethyl-> 15.86 I 202 Butanoate<3-merhylpenryl, 3-rnerhyl->
l -5.07I I 83 Methyl-3(2-furyt)acrotein <(2E)-> 15.86 1202 lilsholtzia kerone
f 5.09 | 184 Hexenyl buranoare<(32)-> 15.90 1202 Hexadienolisoburanoate <(28,4D->
l -5.11 1184 Dill ether 15.90 1202 Norbornene-2-methannl acetate<exo--5->
l -5 . 11ll84 M c nth o l< n e o -i s o -> 15.97 1204 Verbenone
15.12 I 184 lithyl-(411)-ocrenoare 15.98 1204 Cymen-9-ol<p->
l -5 . 16I l8- 5 Dec a n o n e< 3 -> 16.10 1207 H exanol< 3-methyl thi o-l ->
15.19 | | 86 Butyl n-hexanoate <n-> 16.10 l2O7 Piperitol<rans->
15.21 1186 Terpineol<q,-> 16.12 1207 Norbornene-2-rnethanol acetate<endo-5->
15.21 ll 87 Mentha-l(7),8-dien-2-ol <rrans-p-> 16.14 1208 Octenolacerate<(2E,)->
l-5.2-5I 187 Dodecene<l -> 16.23 1210 Methyoxythiophenol <2->
l-5.25 | 187 Verhanol<ncrriso-> 16.24 l2l0 Nonadienal<(2F.,48)->
15.26 | 188 Heptanal,diethylacetal- 16.30 l2l I Octanolacerare
l-5.26 | 188 Heptenal<(4E)->,dierlrylaceral 16.34 1212 Dihydro carveol <iso->
l5-27 | 188 Cresol<2-methoxy-p-> 16.35 l2l3 Pulegol<rrans->
l-5.30 | 189 Prenylangelate 16.39 1214 Dihydro myrcenolacetate
1 5 . 33 l189 P heno < l 2 -a l l y l -> 16..19l 2 l -1 Fragranol
15.3-s| 190 Methylsalicylate 16.42 l2l4 Linalool frrrmate
l-s--38t | 90 Decanone<2-> 16.44 1215 Ctrrveol<trans->
l-5.40 I l9l Hexyl butanoate 16.48 l2l6 Isophorone<4-nrethylene->
l-5.-11I l9l Dihydro carvone<cis-> 16.53 l 2l l C i nnamal dehyde < (Z)->
l-5.4-5l192 Dihydrocarveol 16.55 1217 Cyclocitral <B->
15.-t5l 192 Phenylethyl acerare <l-> l 6.-55 l 2l 7 Elsholtziaketone<a,-clehydro->
l-5.47 I193 Dihydro carveol<neo-> 16.55 1211 Nonadienol<(28,48)->
f-5.48 | 193 Decenal<(42\-> 16.51 l2l8 Fenchylacetate<endo->
l-5--t8 I | 93 Hexenyl buranoare<(2E)-> 16.62 1219 Sabinenehydrateacetate<cis->
l-5.-55| 194 Dihydrocitronellol (cis tbr Ac vs. IPP)
l-5--5-5 I 19.1 Mcnthan-2-one<cis-p-> 16.64 l2l9 Benzofuran<2,3-dimethyl->
l-5.5-5| 194 Myrrenol 16.64 1219 Coahuilensol, merhylerher
l5--56 | l9-5 Myltenal 16.73 1221 Methyl-(2E)-nonenoate
15.-57I l9-5 Anisaldehyde,<meta-> 16.8O1223 Cittonellol
l5--57 | l9-5 Methyl chavicol 16.83 1223 Methyl nonanoare
l5--59 I l9-5 Piperitol<cis-> 16.85 1224 Cumenol<m->
l-5.60 I196 Caranone<trans-4-> 16.86 1224 Prenylcyclopentanone <2->
l-5.60 l196 Decanol<3-> 16.87 f 224 Hydrocinnamylalcohol
l-5.60 | 196 Decenal<(4E)-> 16.93 1226 Dihyclrocarveol<neo-iso->
l-5.60 I196 Methyl heptinecarbonate 16.94 1226 Carveol<cis->
l-5.61 | 196 Cumenol<o-> 16.94 1226 Ocinrenone<(Z)->
15.6-3| 196 Ethyl ocranoate 16.95 1226 Pulegol<cis->
l-5-6+ | 196 Safranal 16.97 1221 Nerol
Adams: RssentialOil Componentsby GC/MS
38
RT AI (lornmon Nanre
RT AI CornmonNantc
17.00 1227 Mcntha-l(7).8-clien-2-ol <cis-p-> 18.24 1255 Decen-I -ol <(47')->
11.02 1228 l)avanone<nor-> 18.29 1257 Benzyl Propanoate
17.01 1229 Hexcnyl 2-nrcthylbtttanoate<(32)-> 18.33 1257 Mcthyl critronellate
17.09 1229 tsenchylacctate<exo-> 18.34 l2-58 Myrtanol<trans->
f 8.38 1259 C i nnamyl al cohol < (Z)->
1 7 .1 5 l23 l Linalo o la c e ta te < te tl a h y d ro ->
17.19 1232 Thynrol,nrcthylether l8.38 12.59 [)ecen-l-ol <(4F])->
17.22 1232 Hexenyl3-rnethylhutanoate <(32)-> 18.42 1259 Carvoneoxide <cis->
11.23 1233 Hexyl 2-rnctlrylbutanoate <n-> 18.44 1260 Decenal<(2E)->
I 8.5I | 261 Chrysanthenyl acetate<cis->
11.23 1233 Thiazole<5-acctyl-2,4-dirnethyl->
11.27 1233 Pulegoue 18.-5 I 126| Guaiacolacetate<o->
11.28 1234 Ascarickrle 18.57 1263 l)ec-9-en-l-ol
11.30 1234 Citronet I it.-58 | 263 Antbersagc
17.3O1234 l)ecen-2-one<(3E)-> | 8.62 l2(r4 Gelanial
11.32 123-5Neral 18.62 1264 Phenol<2-(lE)-propenyl->
11.32 1235 Ocirnenone <(E)-> 18.'71 1266 Ascariclolglycol <trans->
17.33 123-5Chr"ysanthenyl acetate<trans-> 18.12 l2(t6 F,thylsalicylate
11.36 1235 IsobornYl firrnrate 18.73 1266 I)ccanol< n->
18.74 1267 Cinnamaldchyde <(lJ)->
17.41 1238 CurninaldehYcle
11.17 1238 No.iigikuacetate 18.75 l}(fl Thu.ianolacctate<iso-3->
1 7 . . 191238 Hex y l -(2 8 )-b u te n o a l c 18.'771267 lsopropylphenylacetate
1 7 . - 501239 A nis a l d he y d e< o -> 18.71 l2(r7 Nonanoicacid
1 7 .5. 112. 39Calv o n e 18.79 | 268 Lavandukrlacetate<tetrahydro->
I 7.59 I ll 1 Hcxyl isovalerate l 8.80 1268 l )ecen-l -ol < (2E )->
17.60 ll-l 1 Hexenylisovalerate <(22)-> 18.82 1269 Furlirrylpentanoate
1 7 .61 I llI Car v a c ro ln, l c th y le th e r 18.83 1269 P eri l l aal dehY el e
17.69 lJ-1 Benzerreo."1i. ac:id,ethyl ester | 8.84 1269 Tetrahydrojasmone<cis->
<(28)-> l8.87 1270 tithyl chrysanthetnumate <cis->
t] .11 lJ3 Herenvl isovalcrate
18.89 f 270 Nonenal<dimethyl acetal-(32)->
l1 .72 | 2-lJ Carvotanacelone
11.15 l2-l-l Car-3-en-2-one 15.92 l2l1 Citronellyllirrmate
17.17 12-15Perillaketone 18.92 121I McnthYl acetate<neo->
17.80 124-5Ethyl oct-(2E)-enoate 18.99 I 272 Lintrktol acetate<dihydro->
l1 .83 1246 IsoarnYlhexanoate 19.00 1273 Menth-l-en-7-al<P->
17.83 | 246 lsogei.ierenc C 19.02 1273 Carvoneoxide <trans->
11.84 1246 Heptyl isobutanoate 19.04 1273 Thr-rjantllacetate<neo-3->
17.85 1247 Anis aldehYde <P-> 19.05 1214 lsopulegylacctate<neo->
19.05 1274 Plcgei.ierene B
1 1 . 85 1247 Chav i c o l
17.85 | 24J Pirtocarnphone <trans-2-hydroxy-> 19.0-5f 214 Thio tose oxide <cis->
19.10 1275 Hexenylan-qclate <(32)->
11.86 1241 Butyl levtrlinatc
<(2I'',4I1')-> 19.l0 127-5Isopr-rlegyl acetate
11.gl 1248 Hexadienolbutanoate
19. 15 1276 Octalactone <6->
11.93 1248 Thyrnocltrinone
19.18 1277 flthyl chrysanthemutnate <trans->
17.95 1249 ButyroPhenone
11.95 1249 Geraniol 19.19 1271 Nonanal.dirrtethylacetal
17.95 249 PiPeritone 19.22 1278 Allyl octanoate
11.96 1249 Anethole<(7')-> 19.23 1278 N opol
11.96 1249 Mcthyl pentylangelate<3-> 19.24 1278 AnisYIalcohol<P->
l'7.91 l24L) Isoquinoline f 9.28 I 279 Hexenyl valelate<(32)->
19.30 12'19 Ethyl acetophenone <p->
Iu .00 1250 M y r t i rn o<l c i s ->
vs' IPP) 19.31 1280 A ni syl al <
cohol meta->
18.00 l2-50 Piperitoneepoxicle<cis->(epoxide
19.3I 1280 Methyl benzylpropanoate <o->
18.02 12.50 Octalactone <Y->
I 8. | 0 | 252 Piperitone epoxide<trans-> 19.32 1280 Neryl tbrmate
19.32 1280 Octen-3-olbutanoate <l->
18.t2 l2-53 Sabinenehydrateacetate<trans->
(Ac vs. IPP) 19.34 1280 Ethyl menthone<2->
| 8.l6 12-54Linalool acetale 19.34 1280 Methylnerol al e
18.20 125,1Catechol<3-rnethyl-> 19.3-51280 Verbenylacetate<cis->
18.20 l2-54 Phcnylethyl acetate<2-> 19.38 128| Tlrujanolacetate<neoiso-3->
1 8. 21 1255 Cat v e n o n e 19.40 I 282 Ethyl-2-octynoate
18.22 1255 Benzenemcthanol <2-hydloxy-> 19.40 1282 Hcxenylvalerate<(22)->
A|pcntlix I[: Cr)nr|()unds
l,istedin Olclcrof'Iilution on l)B-5 \9
RT AI CuntntonNarno RT AI Cot-nmonNarne
t9.42 1282 Nccrodolacetatc<tl'ans-0-> 20.141298 Carvacrol
r9.431282 A nc t h o l e< (B )-> 20,11 1299 Tcr'1.rinen-4-olacetatc
19.,t.5
I 2133lsopulegylacetttc<iso-> 20.t8 129t) Methyl cinnanrate <(/,)->
19.4612133 Tcrpincn-7-al<u-> 20.18 1299 Nccroclolacctatc<cis-s->
19.4812t33(iogcijerene 20.18 I 299 [Jndec-I 0-en-l-al
r9.48 l2rJ3 lsobornylacclatc 20.19r300 Tridecane<n->
l9.-5
| 1284 Undccanol<6-> 20.20t300 Unclccenal <(8Z1-s
t9.-s2t284 [Jndecanol<-5-> 20.22 1300 Terpinyl acetate<trans-dihyclro-a->
t9.-53t28-5Cyclopcntadicnc carboxylicacid <3,4.-5,5- 20.26 I .r0| Undecanol<2->
tetlanrethyl-
1.3-> 20.29 1.102Elsholtziaketone<p-dehyclro->
t9..s6128.5Saliole 20.29 1302 V ani l l i n< o->
re.57 r28.5Prcgci.jelene 20.3(11303 Cinnarnylalcohol<(Il)->
19.601286 Hydroxy citt-onellal 20.3Cr 1303 Nonadicnolacetate<(28,67,)->
19.(r01286 [Jndc:can-4-ol 20.39l304 Mcnthyl acctate<iso->
19.621287 Bornyl acetate 20.401304 ll utanoicacid.2-ntetlryl-4-nrcthylhexylester
t9.62 t28l Fenchol<2-ethyl-cnclo-> 20.42 1305 Cresolisobutyrate<p->
t9.64 t28l [Icrxenylvaleratc<(2E)-> 20.4.st305 Undecanal
19.641287 l.inakxrloxide acctaLc<trans->(pyranoid) 20.481306 Dilrydrocarvcolacetate
r9.64| 287 Pearlate(=3-octcnql.pfopatloate) 20.48130(rl)ihych'ocarvcolacetatc<neo->
r9.671288Lir-nonen- l0-ol 20.49 l30(r Nonenolltcetate<(2E)->
r9.68t288 Tetraclccatri e'ne <( 37^67^92)-> 20..58t308 Vsrbanolacetate<is<t->
r9.69 t288 Cyc:lopcnt-2-cn- | -one<2-pentyl-> 20.59t309 Guaiacol<p-vinyl->
19.701288 LavanclulylacL:tatLl 20.61t309 Tetlahydro.iasnrone<trans->
r9.71 1289 Thyrrol 20.631309 Carvotanacetone <6-hyclrory->
19.731289 Sabinylacctate<trans->(IPP vs. Acctyl) 20.63t.r09 Vcloutone
t9.14 1289 Butyl heptanoate 20.(14 | 310 Adarrrantanone <2->
t9.14 1289 Cyrlen-7-ol<p-> 20.64l.r| 0 Isclarnylbenzylether
lL).76t290 Acetanisole<o-> 20.68l3tl Pinocarvylacetate<cis->
19.76t290 Inclole 20.69t3l I Nonanyletcctate <n->
19.761290 "[erpincn-7-al<y-> 20.(1913I I Sesarnol
It).11 1290 T lidc c c n c< l -> 20.70t3 | | Unclcc-9E-en- 1-al
19.83 t 29l Vcrl.rcnylacetate<trarls-> 20.131312 l strpul cuylacclal L'< rrcoi so->
19.841292 Prcnylhexanoate 20.14 t312 Cyclohcxanolacetate<trflns-2-tert-butyl->
r 9.8.51292 Cyclohexanolacctate<cis-2-tcrt-hutyl-> 20.75t3t2 Citronc,llicacid
r9.86r292 Dccadienaf <(2h.47) -> 20.79l3t3 Trinrctlrylhenzalclehydc <2,3,4->
t9.90 1293 t]nclccanone <2-> 20.83l.rI4 Cryptone<4-hydroxy->
19.921293 I sorncrrtlrone <2-etlryl-> 20.ri7t 3l5 I)ecadicnaf <(2F^4b)->
19.92t293 Methyl nryrtenate 20.88 I .t1.5 Hexcnyltiglate<(38)->
19.92t293 Undccanol<.1-> 20.90l3l(r Terpinylacctate<6->
t9.93 1294 Carr4rhorquinone 20.9l t3l6 Tcrpinyl acetate<cis-dihydro-u->
19.931294 I\4cnthylacetate 20.93t3t6 Ci tral <clinrethoxy-(Z)->
19.94l2L)4 P er ill aa l c o h o l 20.94 t3t6 Patchcnol<(7,\>
19.941294 Phcnylcthano< | -nitro-2-> 20.96 l3t7 Cycloisolongi lirlenc<diclchydro->
19.951294 Thio roscoxide <trans-> 2t.00 t3t8 Ci nnarrraldehyde <a-rncthyl->
t9.96 1291 Mentlr-|-en-9-ol<p-> 2r.01 l3t8 Pinancdiol<cis-2..1->
r9.981295 Methyl oct.irrccarbonate 21.02 t3l8 Methyl thuiate
t9.e8 129.5Tlru.ianolacctatc<3-> 2 t.04 l3 t9 l)ihydlo citronellolacetate
20.o5 t296 Nonadicnol acetate<(3t',,(tZ)-> 2t.{t41319 I)irnethylphcnethylacctate<o, o->
20.081297 Fenchol<2-ethyl-cxo-> 2 | .0.st.319Verban()lacctalc<nc()->
20.09 1291 13cnzylisobutanoate 2t.07 t3t9 I)ccadicnol<(28,48)->
20.10 1291 Carvacrol,ethyl ether 2t.07 l3l9 Hexenyltiglatc<(32)->
20.ll 1298 Acctophenone <3'-nretlroxy-> 21.t| 1320Flexyl2-nretlryl-3-pcntenoate
20.1 1298 Azulene' 2t.16 t321 Nonyne< l, | -clirnethoxy-2->
20.1t t 298 Gerranyllirrnrate 2l.t1 1322 Unclec-92-cn- l-al
20.1I t29ri Irinocarvylacetate<lrans-> 21.181322Jasnronol<trans.(E)->
20.t2 t298 Carc;ue'iol acctatc 21.191322 Mcthyl geranate
20.| 3 l29tt Octenolpropanoate<(52)-> 21.23132-\Methyl dccan()ate
40 ()il Components
Adams:Essential by GC/MS
AI CommonNar-ne RT AI CornrnonNar-ne
2l.28 1324 Phenylethyl oxyacetaldehyde 22.69 135(r Dihydro carveolacetate<neoiso->
21.29 1324 Myttcnyl acetate 22.70 13-56Ilrgenol
21.30 1325 Mentha-1.4-clien-7-ol <p-> 22.73 l3-57 Nepctalaclone<4au,7a,7aa->
21.36 1326 Dihydro carveolacetate<iso-> 22.74 13-57Mentha-8-thiol-3-one <cis-p->
21.37 1326 Linronencaldehyde 22.14 13-57Undecenal<(2E)->
21.31 1326 Silphiperlbl-.5-ene 22.77 1358 S i l phi perl bl -4.7(14)-di ene
21.39 1327 Hasnrigone <(Z)-> 22.18 1358 Nonalnctone <y->
21.39 1321 Isohutylhenzoate 22.80 1359 lJecenoicacid <9->
21.13 | 328 Jasrnonol<cis,(E)-> 22.81 1359 Neryl acetate
21.11 1328 Menthol<8-hydroxy-neo-> 22.83 13-59Hydroxycitroncllol
2 | ,4-51328 Patchenol<(Ir)-> 22.89 136l l)anrasccnone <(7.)-g->
2 | . 1. 5 1. 128V c r h a n r)la e c l a tc< n c o i s o -) 22.90 136l U ndeccnol< 10->
2 I . 5l 1329 P ipero n a l 22.93 136| Anisalclehyde' <p->, dimethylacetal
II.- 52 1330 A nis y l fo rm a te 23.00 1363 Methyl benzyl butyrate<a->
I L-51 13.30 Hexyl tiglate 23.02 1364 l)ccanoicacid
I | .56 I .1-10Nlenth-1-en-7-al<3-oxo-p-> 2.1,0.5l-j(r4 Mcnlholactone <cis->
I1 . 6. 1 1. 1. 11P ipc ri ttrla c c l a te< c i s -> 2.l.Ott1.1(r5Carvyl acctatc<cis->
I1 .68 l- 13. 1Has n ri g o n<c(E )-> 23.08 1365 Undecenol<(28)->
21.7(l l-1-11Presilphiperlol-7-ene 23.l0 136-5Undecanal<2-nrethyl->
21.72 l-13-l Anthranilatc<rrethyl-> 23.11 1366 llydr"ocinnarnyl acetate
)l .l2 1. 1. 11Nlet h iI o -a n i s a l c 23.12 l-366 Piperitcnone oxide
21.73 1-l-14Linaloolpropanoate 23.15 1366 Iiugenol<dihydro->
21.76 133-5Bcnzenemcthanol <4-hydroxy-> 23.16 l3fi7 Furfirrylhexanoatc
21.71 1335 Elemene<6-> 23.19 1367 U ndecanol < n->
2 | .80 | 336 Phenylpentan-3-onc 23.23 l3(r8 Olcinol
21.82 l33fi Isosaflole<(Z\-> 23.25 1.369 Cyclosativcne
2 l .85 1337 E v ocl o n e 23.32 1370 Carvact'olacetate
21.90 1338 Citral <climethoxy-(E)-> 23.33 1371 Methyl p-anisate
2 1.9O 1. 1. 18I ndir n o<l .5 -> 23.35 137| Mentholactome <tl'ans->
21.92 1339 Benzencmethanol(3-hydroxy-> 23.36 l31 l Mcnlha-8-thiol-3-one <trans-p->
21.92 1339 Octancdiol<2.4-> 23.37 l3ll Longicyclene
21.95 1339 Butanone<3-hydroxy-4-phenyl-2-> 23.37 l3l I Menth-6-en-2,8-diol <trans-p->
21.95 | 339 Cart yl acatate<tfans-> 23.38 1312 Angustione
21.96 1310 Me ntho thiophene 23.12 1373 Benzencacetonitlile<3-rnethoxy->
2 |' . 97 1340 l) ihy d to i s o i a s n to n c 23.43 1373 Linaloolisobutanoate
2 l . 98 l3z l0 P ipe ri te n o n e 23.43 1373 Ylangene<0->
22.00 1340 Verbanolacctate 23.45 1373 Isosall'ole<(E)->
22.09 1342 Nicotine 23.48 1314 lsolsclcne
22.10 1343 Piperitolacetate<trans-> 23.49 1374 Copaene<0->
2 2. 13 1343 B enzy lb u ta n o a te 23.51 1375 B i phcnyl
2 2. 18 13, 15S ilph i n e n e 23.52 137-5l)ec,ane <l .l-dimethoxy->
22.20 134.5Silphiperlbl-.5-ene <7-epi-> 23.55 1316 lJthyl cinnantarc<(1.)->
22.24 1346 Phenol<2,(r-dinrertlroxy-> 23.-5-5l37Cr lonol <a-(E)->
22.26 1346 Terpinyl ercetate <tr-> 23.-581376 Methyl cinnantate <(E)->
22.30 1347 Acetophenone <4'-nrcthoxy-> 23.61 1377 Silphipellbl-6-ene
22.30 1347 Carvon'renthyl acctate<neoiso-> 23.65 1378 Allyl nonanoate
2 2. 31 1347 T r iace ti n 23.65 1378 Hexenyllrcxanoate <(37)->
22.33 134-5Cubebcne<c-> 23.66 1378 Counrarin<3,4-dihydro->
22.38 1349 Thymol acetatc 23.67 1378 .Iasrnone<dihydro->
22.41 1350 Citronellylacetate 23.69 1379 Dictarnnol<8-epi->
22.11 13-50Longipinenc<G-> 23.70 13"19 Geranylacetate
22.41 l35l Phenylethyl propanoate <2-> 23.10 1379 Patchoulene <B->
22.48 135l lrthyl nerolate 23.13 | 380 Nonadienal <cliethyltrcetal-(2F',62)->
22.51 1352 Trimethylhenzaldchyde <2,3,6-> 23.74 1380 Anisole<p-bur( lE)-enyl->
22.57 1353 llutyl butyryl lactate 23.14 1380 Daucene
22.64 13"5-5 Danrascone <(Z)-0-> 23.15 1380 Anisyl methylkekrne
22.65 13-5-5Hydroxybenzaldehycle <4-> 23.7-51380 Ethyl-(4Ir)-decenoate
I- tIT
Appcnclixll: CompoundsI-istcdin Ordel ol'Hlutionon I)B-5 4l
RT AI Common Nanre RT AI CornnronName

23.7-sl3rJ0Funebrenc<2-epi-n-> 24.84 1405 ltalicene
23.7.5t.180Thu.iicacid 24.81 140.5S csqui rhui cne
23.771380 Phcnyl-4-nretlryl-pentan-3-one < | -> 24.86 140-5Methyl anthranilate <methyl-n->
23.78t38l IJthyl2-nonynoate 24.90 1406 Cycloseychellene
23.78l-r8l Panirsinsene <B-> 24'.90 1406 Isoeugcnol<{7)->
23.80t38| Angustionc<clchydro-> 24.92 1407 Barhatene<cr->
23.81138| S k a to l e 24.92 1407 Longilblene
23.83r 382 Hexyl hc'xanoate 24.93 1407 Acora-3,7(l4)-cliene
23.83t3n2 Modheph-2-enc 24.94 1407 l)ecyl acerare
23.8(r1383 Hexenyl-(3Z)-hexenoate<(32) -> 24.94 1407 Isocornene<B->
23.87t383 l)arnascenone <( It )-B-> 24.95 1408 Caryophyllcrrc <(Z)->
23.881383 lsobornylpropanoats 24.95 1408 l)odcrcanal
23.97t38.5Myrtanol acetate<trans-> 24.96 1408 l)ec,enylacerate<(2E)->
23.9n138.5Nonalactonc<6-> 2-5.001409 Gur.iunene <c->
23.99t38.5Hexenyl caproate<( 2E)-> 25.01 1409 Citronellyloxy-aceraldehyde
24.(il l3Ufi f )arnascone<(7)-fl-> 2-5.06l4l0 Cedrene <cr->
24.(X)l3ft(r Ncpetalactone <4 aa,1u.7 ap-> 25.06 1410 Thu.iaplicin <u->
24.0I 1386 Isol-rLrtyl phcnylace.tate 25.l O l 4 | | B crgatn()l cnc < cr-ci s->
24.031386 Octcnolbutanotrte <(2H)-> 25.l 0 141| l ononc< cl i hycl ro-o->
24.04 t38l Cubebene<p-> 25.11 1411 Funehrcne < 2-cpi -p->
2.+.0-5 t3tt7 Bourbonenc<B-> 2-5.l 3 l 4l 2 A ni syl acetate < p->
24.0-s1387 lsocorncnc<u'-> 2-5.15l 4l 2 l onol < p->
24.07 13s7 |)upre'zianonc<u.-> 2.5.1.5 l l | 2 N el onc< ci s->
2,1.09t.rn8 Mettryldcg'yll(etonc(=2-cloclecanone) 25.11 l 4l 3 I)arnasconc < (l r)-B ->
24.t0 t3[r8 Cinnanrylacetate<(Z)-> 2.5.l 9 l 4 | .1 H thyll rl ,dl otl ui none
24.10t.r88 Tetradecene < l-> 25.19 l 4l 3 Funebl ene 
24.12 1.188Jasrnonc<iso-> 25.23 1414 Antlrranilare <erhyl->
24.1.1l3tt9 Longilillcnc<iso-> 25.23 l414 l)avanalirran<cis.threro->
2.1.t-5 | 389 l)oclccanone <3-> 25.26 l415 Caryophyllane <4,8-o,-epoxy->
24.t-5 l3tt9 I.rlenrene <P-> 25.21 1415 Anrbrinol<trans-o.->
24.lri t390 Thiazoleethanolacetatc<4-rnethyl-5-> 25.28 14l-5 Unclecadienal <(28,4E)->
24.t9 1390 .lasrnone <(H)-> 25.31 1116 S antal ene< c->
2.1.t9 1390 Sesc; uithu.iene <7-cpi-> 25.33 1417 Dicyclohexylanrinc
21.211390 S a ti v e n c 25.33 l4l7 lithyl-(2li){ecenoatc
21.24 t39l Nepetalactone <4 aa,7$,7aa-> 25.36 l4l7 Caryophyllene <(E)->
24.2(t1392 .fasrnone<(7,)-> 25.42 l4l9 Ceclrene <p->
24.281392 l)arnasconc<(E)-s-> 25.43 l4l9 Ylangenc<B->
2.+.30 1.192Mcthyl ;-rcrillate 25.45 1419 Trinrcnal<(E)->
24.3I r3e3 Phcnylethyl isobutanoatc 25.48 1420 Carvyl plopanoate<cis->
24..121393 V a n i l l i n 25.51 l42l Cymen-7-olacetate<p->
21.37t394 Benzcne< l,3-clirnet I -rnethylethyI)-
hoxy--5-( 25.51 1121 Duprezianene <B->
21.311394 Ethyl gcranate 25.51 l42l Lavandulylisobutanoate
24.'t0 139.5Iithyl clccanoate 25.53 l42l l,inal<xrlbutanoare
)4.44 1396 Charrripirrcne <c,-> 25.53 l 42l Mcnth-l -en-9-olacerate < p->
t1..5| t397 Jl"imenal<(7.)-> 25.54 1422 Carvonehydlate
11..54|]9ri Cypercnc 25.58 1423 P hcnylhcxan-3-one < l ->
1t..5.5t.198Jasr.nonyl acetate<(li)-> 25.59 1423 Caryoplryllane <4,8p-epoxy->
2-+..s71399 l)cccnylacclate<9-> 25.59 1423 lsohutylsalicylate
21.57t399 Gcosrnin 25.60 1423 Mefranal
l-1.(r
I l4(X) llcxenyl 2-rlethyl-2-pentenoate <(37,)-> 25.61 1423 Allyl cyclohexylpropanoare
l-1.(r
I l4(X) Tctraclecane <n-> 25.65 1424 Nopyl acctate
2-1.621400 Sibirerrre 25.66 1124 Cynrene<2,-5-dirnethoxy-p->
li.(r4 l4(X) Longipincrrc<B-> 25.66 1424 Mcthyl unclccanoate
11.(19l40l I t a l i c c n c 25.19 1428 l)ictarnnol
2+.1| 1402 Funcbrene<0-> 25.81 1428 l onone< (l r)-u->
l+.7-5t403 Methyl eugenol 25.86 1429 Thujopscne<cis->
21.16 1403 Crcsol acetatt:<nlethyl-> 2-5.881430 lsoarnyl3-(2-turan)propionare
Adams:Essential
Oil Components
bv GC/MS
RT AI ConrnronNarle RT Al CornmonNarne
25.90 l'430 Copaene<p-> 26.80 1452 Cinnarnicacicl<(E)->
25.94 l43l Xanthostemone 26.80 1452 Ckrvene<0-ne0->
25.95 143| Gulitrnene<p-> 26.81 1452 Arbozol <exo->
25.95 l43l Isot"rornylisobutanoate 2(t.82 1452 Hunrulene<q,->
25.91 1432 Coumarin 26.83 1452 Neryl propanoate
25.99 1432 Berganrotene<o-trans-> 26.83 1452 Vanillin <ethyl->
26.00 l,433 Arbozol <endo-> 26.84 1152 Jasmonylacetate<(Z)->
26.03 1433 Isoanrylbenzoate 26.8-5l4-53 Gcranylacetone
2(t.06 1434 Neryl acetone 26.85 1453 K husi nrene
2(r.08 1434 H,lernene <y-> 26.90 1454 Car"vylpropanoate<trans->
26.08 1434 Ionone<dihydro-B-> 26.92 1454 Ferrnescne <(I1)-0->
2 6 .1 2 1435 Nez uko n e 26.92 1454 Patchoulene <u->
26.15 1436 Lavandulylacetate<hydroxydihydro-> 26.9() 1456 l\,lnl11rlpropionatc
2 6 .1 6 1436 Hur r r u l e n<eB -> 27.04 1457 Crowencin
2 6 .1 6 |436 ls ubazz a n c n c 27.04 1451 Prenyllimonene<tlans->
26.19 1431 HyacinthRody #3 27.05 1457 Decenal<(47.)->,diethylacetal
2 6 .2 0 l43l G uaie n e< s -> 27.05 1451 Rotunclcnc
26.24 1438 Methyl butyl benzoate<2-> 27.05 1451 Santalene <p->
26.24 1438 Phenylpropyl isobutanoate <2-> 27.05 1451 Sesquisabinene
16.25 l:138 Nerone<trans-> 27.01 1458 Aronradendrene <allo->
1 6 .16 lJ 19 A nr hr i n o <l c i s -c -> 27.08 1458 lonol <a-isonrcthyl-(E)->
16.17 l-139 Aromaciendrene 21.10 1459 Cyclamenalclehycle
16.17 l-l-19 Phenylethyl butanoate <2-> 21.10 1459 l )i furfurylsul fi dc
16.-ll l-l-10 Barbatene <B-> 2l .16 1460 Arornaclendrane <clehyclro->
26.31 lll0 Phenolacetate<2,(r-climethoxy-> 21.18 l46l Ageratochrorrrcne <6-demethoxy->
2 6 .11 l- l- 10 P inoni ca c i d 2l .18 l 46l C acl i na- < ci s->
l (6),4-di ene
26.-l-i l+10 Farnesene <(Z)-$-> 21.23 1462 Cabreuvaoxide B
2 6 .37 l44l Cedr a n e 27.32 1464 Acoladiene<u->
26.39 1442 Cuaiadiene<6,9-> 27.33 1464 Caryophyllene <9-epi-(Ir)->
26.42 1442 Isoarnyloctanoate 21.33 1461 l)oclecenal <(211)->
26.44 1443 Prenyllintonene<cis-> 21.35 1465 l)ecalactone<y->
26.4(t 1443 Cinnarnylacctate<(E)-> 21.35 1465 Ishwarane
2 6 .4 6 1443 llidola c to n e < l ra rrsc. i s -> 27.35 1465 Muurola-4(l4).-5-clicne <cis->
26.41 1444 Aoetylacetophenonc <p-> 27.37 1465 lithyl cinnarnate <(li)->
26.47 1444 Rakerol 21.38 1465 Thuiopsacliene <cis->
26.47 1441 Citronellylplopanoate 21.42 1466 Furfurylhcptanoate
26.47 1444 Naphthalcne <l-nretlroxy-> 27.43 1466 CabreuvaoxicleC
26.48 1444 Prezizaene 27.43 1466 Linalool isovalerate
26.49 1444 Vestitenone 21.44 1467 Menthyl lactate<neo->
26.50 1444 Acora-Z.4( 1.5)-diene 27.45 | 467 F,thyl-(28,47.)-decadienoafe
26.50 1444 CabreuvaoxideA 27.50 1468 Pinchoteneac:etate
26.50 1444 Seychellene 27.52 1469 Acoradicne<p->
26.51 1445 l)odccadien-l-al <(22,68)-> 27.52 1469 l)odecanol<n->
26.51 1445 Santalene <epi-p-> 27.54 1469 Salicylicacicl,butyl ester
2 6 .51 1145 V anilly l a l c o h o l 27.54 1169 Sesquicineole <clehydro->
2 6 .53 1445 M y lt ay l -4 (1 2 )-e n e 27.55 | 469 Dodecen-l -ol <(2E)->
26.53 1445 Naphthalene <2-rnethoxy-> 21.56 1410 .lasmonelactone<(3iZ)-2
26.62 1447 Ccdlanc<cpi-> 27.57 1470 Cunracrenc
26.(t2 1447 Hexyl 2-furoate 27.59 1470 Macrocarpene <0->
26.61 | 148 Muurola-3.-5-diene <cis-> 27.60 147| l)auca--5.8-diene
26.61 1448 Isoeugenol<(E)-> 27.60 l4l I Massoialactone
26.68 1449 Himachalene <u-> 2'1.62 l4l I SesqLricineole <7-epi-1,2-dehydro->
26.69 1449 Spirolepe.chincne 21.62 141| Terpinyl isol'rutanoate <s->
26.11 1449 Aniorpha-4.lI -diene 21.63 l41l Aristolochene <4,-5-di-epi->
26.13 1450 l)avana.bis-ether 27.72 1413 Isobornyln-butanoate
26.78 l45l Methyl isoeugcnol<(Z)-> 27.73 1414 Acortrdiene <10-epi-p->
26.18 l45l Muurola-3.-5-dicne <trans-> 27.73 1474 l)ecenal <(411)->,diethyl acetal
Appendixll: CompoundsListedin Older of Elution on Dtl-5
43
RT AI ConrmonNarne RT AI CcunmonNanre
21.131474 Undecanal,dimethylacetal 28.53 1493 Vetispirene<B->
21.75 1474 Neocallitropsene<0,-> 28.53 1493 Zingiberene<o->
21.71 t4l5 Cadina-| (6),4-diene<trans-> 28..5.51493 Cubebol<epi->
21.78t475 Methyl vanillin 28.-551493 l)ecalactone<6->
27.791475 Thujaplicin<B-> 28.-5-51493 Raspberryketone,methyl ether
27.801415 Curiunene<y-> 28.58 1494 Maltyl isoburyrare
27.821476 Charnigrene<B-> 28.62 1495 Asaricin
27.821476 Gerarryl propanoate 28.62 1495 Cadina-l .4-diene<cis->
27.841476 Allyl decanoate 28.63 1495 Amorphene<y->
27.841416 Pentyl benzoate 28.64 1495 Tridecanone<2->
27,89 1477 Pyran-2-one<6-nonyl--5,6-d i hydro-2H-> 28.65 1495 Coumarin<3-rnethyl->
21.911478 Anrorphane<ttans-4,I 0-epoxy-> 28,66 1496 Valencene
27.91t4t8 Muurolene<1-> 28.68 1496 Viridillorene
21.921418 Ionone <isomethyl-o,-(E)-> 28.69 1496 Irrdipone
27.941419 Cabreuvaoxide D 28.70 1497 Methyt p-telt-butylphenylacerare
27.96l4l9 Curcunrene<ar-> 28.11 1497 I3enzyltiglate
27.961419 Ionol <methyl-B-(E)-> 28,72 1497 Sandalorc
27.97t4t9 Amorpha-4,7(| | )-diene 28.14 1498 Selinene<a->
28.00r480 Ionone <mcthyl-T-> 28.75 1498 Alaskenc<B->
28.021480 Cyclogeranylacetate<0-> 28.75 1498 Pseudowiddrene
28.0.rt48l Wicldra-2.4(| 4)-diene 28.76 1498 Undecenolacetate<10->
28.04t48| Curcumene<y-> 28.71 1498 Apofarnesal<(Z)-dihydro->
28.0-5l48t Amorphane<cis-4,I O-epoxy-> 28.79 1499 Culzerene
28.0-5l48l Himachalene<y-> 28.80 1499 Dihydroagarofuran<4-epi-cis->
28.0.sl48l M en th y ll a c ta te 28.81 1499 Macrocarpene<B->
28.05 t 48| Vanillone,aceto- 28.82 l -500 Pentadecane <n->
18.071482 Citronellolisobutanoate 28.82 1-500Himachalenc<p->
It.08 t482 Decalactone<y-metlryl-y-> 28.83 l-500 Bicyclogerrnacrene
18.091482 Tof uene<2,4,6-trinethoxy-> 28.83 l -500 Isodaucene
28.| 2 148.3Phenylpropyl butanoate<2-> 28.83 l-500 Muurolene<u->
28.121.183Thujaplicin<y-> 28.88 l50l Epizonarene
l8.t,j 1483 Anrorphenc<c-> 28.89 l-501 Aciphyltene
t8.14 t483 Jasmonelactone<(3E)-> 28.89 l-501 Allyl anthranilate
28.1-51484 GernracreneD 28.89 l-501 Decyl propanoare
28.t9 1485 Prenyl benzoate 28.91 1502 Patchoulene<y->
28.20 t48-5Himachala-1,4-diene <l I sH-> 28.92 1502 Cyckrtkydsgsnone
18.24 r486 Benzyl acetylacetate 28.92 l5t)2 Gulritrrc<tlans-B->
28.2-5t486 Phenyletlryl 2-nretlrylbutanoate 28.9-5l-503 Dihydro agaroluran<B->
:8.28 t487 Aristolochene 28.9-5 1503 Pipelonyl acetate
18.30 t487 Ionone <(tr)-B-> 28.96 l -503 Chamigrene<o->
18.-jl t487 Jasmolactone <(7\-> 29.00 l -504 Cuparene
:8.-1.1l-188 Butylatedhydroxyanisole 29.00 l-504 Unclecenolacetate<(28)->
t8.-15t488 Methyl biphenyl <4-> 29.03 l-50-5 Cuprenene<c->
1E.36t489 Eudesrrra-6, I I -diene<cis-> 29.03 l -50-5Farnescne<(E.E)-a->
18.-17t.189 Selinene<p-> 29.04 1-505 Ilisabolene<13->
18.-181489 Vetispirene<o-> 29.0-5l-505 PremnasPirocliene
lE.-1.3l.+90 Neryl isobutanoate 29.09 l-506 Bisabolene<(Z\-a->
f8.{-r t{90 Phenylethyl 3-methylbutanoate 29.12 1507 Silphiperfolan-6-0,-ol
l8.J-i l.tgl Drirn-8(l2)-ene 29.18 1508 Farenal
18.-r-5t49l .lasmolactone<(L,)-> 29.l8 l -508 GermacreneA
:8.{7 l-tgl Calamenene <10,I I-epoxy-> 29.19 1509 Lavandulylisovalerate
18.{7 l49l Methyl isoeugenol<(E)-> 29.20 1509 Bulnesene<a->
:8-{9 t492 Menthyl lactate<iso-> 29.20 1509 Thuiaplicinol<u->
]8-+9 t.t92 Selinene<6-> 29.22 1509 Tridccanal
tE..st l-t.92 Guaiene<c,is-F-> 29.23 1510 Quinoline<6-isopropyl->
lE5-3 l{9-l Capillene 29.26 1510 Anisyl propanoat.e
t8_5-1t-193 Muurola-4(l 4),-5-diene <trans-> 29.26 l5l0 Cameroonan-7u-ol
Adarns:Esscntial by GC/MS
Oil Components
RT Conrmon Nanrc RT Al ComnronName

29.27l5t1 Lavanclulyl2-nrcthylbutanoale 30.09 l 53l V eti venene < y->
29.29l5tl Arnorphene<6-> .30.| | 1.528C al anrcncnc < ci s->
29.31l5l2 Alaskcne<s-> 30.l 4 1532 C uprenene< y->
29.31t5l2 Macrocarpene <(7.)-y-> 30.l4 l-532 Hydroxycitronellal<cliethylacctzrl->
29.3.st.sl3 Cadinenc<y-> 30.18 1533 C adi na-1,4-cl i enc < trans->
29.3.5t-513Cycloisolongi lbl--5-ol<trans-> 30.19 l -533 C ubebol< 10-epi ->
29..1.5
l-5|3 Modhephen-8p-ol 30.22 1534 Artedouglasia oxide A
29.401514 Bisabolene<(Z-)-y-> 30.23 1534 Silphipertbl-5-en-3-ol ll
29.40l5l4 Italiceneepoxide<iso-> 30.24 1531 Liguloxide
29.4t 1514 Cuhcbol 30.2-51535 Isopentylsalicylate
29.411514 Geranylisohutanoate 30.30 l-536 l-iugenolacetate<dihydro->
29.42l5l4 Curcurnene<p-> 30.30 1536 l tal i ceneether
29.43l5l1 Br.rtylatedhyclroxytoluene 30.-321536 Thu.iaplicinol <B->
29.44t5t5 Sescpricineole 30.33 | 537 Cadinene<o->
29.45l5t5 Italicenecther 30.34 1537 lonol acetate<B-@)->
29.4815t6 Hinrachalene<c-dehyclrcl-ar-> 30.39 1538 Furopclargone A
29.50t5 t6 Menthylisovalerate 30.40 1538 Veltonal<(7.)->
29.53l5l7 Nootkatene 30.43 1539 C opaen-11-ol < o->
29.54t5 l7 Myristicin 30.4.51540 Dracunculitbliol<1O-epi-cis->
29..56t-5|8 I)odecadienal <(211,4E)-> 30.1.6l-540 Carpacin<(Z)->
rl a n -6 8 -o<l 7 -e p i ->
29.57t5 | 8 S ilphi p e rft 30.41 1540 LaciniatafuranoneE
29..s9t.5I 8 Bourbonanol<enclo-| -> 30.-50l-541 Cleclranoxide <8, l4->
29.601.5 | 9 | )ihydroagarofuran<cis-> 30.-50I -54| l)racunculifoliol<cis->
29.60 1519 Myrac aldelryde 30.54 1542 Cuprenene<6->
29.62t5t9 lSazzanene <p-> 30.56 1542 Sesquisabinene hydrate<cis->
29.621519 Silphiperlblan-78-ol 30.-591543 Isoamylnonanoate
29.65 t520 Apolirrncsal<(Ir)-dihyclro-> 30.62 1544 Calacorene<c->
29.65 1520 Ionone<6-mcthyl-u-> 30.66 1.545S el i na-3,7( I l )-di ene
29.67 1520 Selinene<7-epi-o-> 30.(t7 1545 Raspbelryketone
29.69t52l Calamcnene <trans-> 30.69 l -54-5Flavesone
29.10l52l E,ugcnolacetate 30.70 154(r Silphiperlblan-6p-ol
29.10t52l Isohornylisovalerate 30.12 1546 l{eclycaryol
29.70 l52l Sesquiphel landrenc<p-> 30.14 1547 ftaliceneepoxicle
29.721522 Cadinene<6-> 30.75 1541 l)ecanediol<l, l0->
29.74 1522 Arteclou-el asia oxidc C 30.78 1548 Allyl cinnanrate <(E)->
2L).161523 Isoburnyl2-rncthylbutanitate 30.78 1548 E l emol
29.77 1523 | )odecadicnol <(2Fi,4Fl) -> 30.79 l -548 Agarofirran<c->
29.80t.524Chavibetolacetate 30.80 l-548 LaciniatafuranoneH
29.82t521 Methyl dodecanoate 30.86 l-5-50Muurol-5-en-48-ol <cis->
29.83t.52.1Phenylheptan-3-one 30.86 1.5.50Silphiperfol-.5-en-3-one B
29.851.52.5 Vanillin acetate 30.88 l-5-50Occidentalol
29.881526 Macrocarpcne<ar-> 30.89 1.5.50Li ppi fol i -l (6)-en-5-one
29.92 1527 Maclocarpenc<(E)-y-> 30.94 l-5-52Cadineneether<cis->
29.93 1527 Lilial 30.98 l-5-53Coumarin<6-methyl->
2L).931521 Methoxycinnamaldehyde <(E)-o-> 30.98 l-5-53Isocroweacin <(E)->
29.96 1528 Bi saholene<(E)-iso-y-> 30.99 l -553 Thymohydroquinone
29.96 1528 LaciniataluranoneG 3 I .00 l-553 Norpatclroule nol
29.91 1528 Octenylcyclopentarrone <(lt)-> 3l .02 l5-54 Velivenene<B->
29.97 1528 Zonarene 31.07 1555 Veltonal<(Il)->
30.02 1529 Kessane 3 | .08 1.5-5-5lonol acetatc<(Z)-s-isomcthyl->
30.031.529Bisabolene<(E)-y-> 3 | .09 l-5-5-5liernicin
30.03 l-529 Nopsan-4-ol 3l .l I l 5-56 D auca-4(ll ),7-di ene< trans->
30.0.5t.530 Citronellylbutanoate 31.14 1551 C adi ne' ne cther< trans->
30.0.5l530 Dar-rca-4( l l ),8-diene 3l .18 l -5.57S i l phi perfol -.5-en-3-olA
30.08l530 Himachalene <'y-dehydro-ar-> 3 | .22 l-5-58Artedouglasia oxidel)
30.09 l-531 Laciniata lutanone F 31.22 1558 Erenrophilaketone
30.091.53 | Nerolidol <(Z)-> 31.24 1559 GermacreneB
--l
Appcnclix
II: Compourrds
l,istedin Ordclol'lrlutionon DB--5 A<
RT AI Corlnrou Name RT AI ConrmonNanre

3 | .24 l-559 Muulol,-5-en-4a-ol <cis-> 32.31 1581 l)avanone
31. 32 l- 561 B o u rb o u a n o trc < l -rro r-> 32.31 1587 Hcxenylbenzoatc<(2I1)->
.1| .32 | 56l Ncrolidol <(E)-> 32.44 l-588 Flcxadecene < l->
3 1.-15l-562 Longicarnphenylone 32.44 1.588Thr"rlopsan-2p-ol
3 I .3-5 l-562 Longipinanol<epi-> 32.45 l-589 Allo-cedrol
31. 36 1" 5( r 2G c ra n y lh u ta n o a te 32.45 1.589 Allo-heclycaryol
3 1.38 1,5(r2Clinnanraldehydc <(li)-p-rncthoxy-> 32.45 1589 Irlemenonc<cis-p->
3 | .4.1 l-5(r4 C-alacorene <B-> 32.49 1590 Copaen-4u-ol <B->
31. 44 1564 B o rn y l a n g e l a tc :32.50l-590 Dicthyl phthalarc(plastizcr)
3 1.44 l-564 Carvotanacetone <8-acetoxy-> 32.-50l-590 Gkrbulol
3 | .46 l -5(r4 l)ar,anonc[l 32.-521590 Apolirrnesol<(Ir)-dihyclro->
31.41 | 5(r-5 l)odccanoicacid 32.-58l-592 Hc.lilirlen-12-al A <syn-anri-anti>
31.48 f -56-5Hexenylbenzoare <(.37.)-> 32.-58l -592 Helilirlen-l2-al B <anti-anti-anti->
3 | .219l-5(r-5lonone<clintethyl-> 32..58l-592 Viriclillorol
3 | .-5I 1-5(r(rIsoeugenolacetate<(.2)-> 32.62 1593 Unclecalactone <6->
3l .-5| l -56(r .Iasmolarctone, extra C <(/,\-> 32.63 l-593 Carpacin<(ll)->
3 L-52 1566 Furlirlyl octanoate 32.(t6 1594 Salvial-4(l4)-en-| -one
3 l. - 53 1- 5( 16 Maaliol 32.(tl 1594 Carotol
3 | .-5-5l -5(r7Tridecen-I -al <(28)-> 32.68 l-594 lJthyldoclccanoate
3 1. - 56l- 567 P a l u s tro l 32.70 l -59.5Cubelrarr- I l-ol
3l .-571.567 lonol acetatc<(E)-u-isomcthyl-> 32.70 159-5 lJemicin <6-nrc'rhoxy->
3l .-5tJl -5(r7Lorrgipinanol 32.10 159-5Mayurone<cis-dihydro->
3 l .62 l -568 lsoelcrnicin<(I1)-> 32.70 1595 Tulrnerone<ar-dihydro->
3 1. 62 l- 568 I s o c l e rn i c i<n (' /,\-> 32.73 1596 Fokiernol
3 | .62 l -568 Tlidecenol<(2I1)-> 32.8-5l -599 I-on-eiborneol (=Juniperol)
3 | .65 l -569 tlndecalactone <y-> 32.85 1.s99 W i ddrol
3 | .68 l -570 Tridecanol<n-> 32.88 l -599 Clinnamaldehyde <hydro->
-l | . ( r 9 1. 570l) c rrd rtrl a s i n 32.89 1600 Hexaclecane <n->
31.70 1510 Amorph-4-ene<1a.,1Oo-epoxy-> 32.89 1600 R osi l bl i ol
31. 70 l- 570 Ca ry o p h y l l e n yall c o h o l 32.91 1600 Cedrol
3l.72 157| Apoliu'ncsol<(Z)-clihydro-> 32.92 1600 Guaiol
3 1.73 l -571 Caryolan-8-ol 32.93 '1601 Gcranyl 2-methyl lrultrnoate
3 1. 18 1572 A s a ro n c < y -> 32.94 l(t01 Guaia-3,| 0( l4)-cliene<9, I l-epoxy->
31.84 1574 Cedrcncepoxidc<a-> 32.95 l fi l l B i sabol atri en-7-ol< 1,3.-5->
3l .tt4 1574 Silphiperlirl-.5-en-3-one A 32.99 160I Elemcnone<trans-p->
3l .8-5l -574 Ccnnacrene[)-4-ol 32.99 16O2 Leclol
3 1. 8- 5l- 574 P en ty ls a l i c y l a te 33.00 1602 Isoarnylnerolare
3l .86 l -574 Zieronc .1.1.(Xl (r02
) Tl i prtrqri oni n
3 | .91 l-57-5Prcnopsan-8-ol 33.0,11603 Isobornylisohutanoatc <-5-oxy-)
31. 92 1516 S an ta l e n o n e 33.0-51604 Khusintont:
31. 96 l57l S pa th u l c n o l 33.08 1(r04 Sescluithuril-erol
31.99 l5ll Sescluisabinenc hyclrate<trans-> 33.1I 160-5Curzercnone
(lPP vs. OI{) 33.l-5 I (106 Geranylisovalerale
32.0I l-578 Hinrachalcnc epoxide 33.16 1607 S esqui l avancl ul<ol (Z)->
32.02 1518 .Iasnrolactone, extraC <(E)-> 33.11 160l l)odecyl acetare
32.05 l-579 Hcxyl benzoate<n-> 33.17 l60l lluclesmol<-5-epi-7-epi-o->
32.12 l58l Altcdouglasiaoxidc ll 33.11 l(r07 Oplopenonc<B->
32. l2 l- 581 f I c x y l o c ta n o a tc 33.| 8 1607 B i otone
32. l4 l. 5t It P y g n ra e i n 33.l 8 1607 H i l l one
32.16 1582 Caryophyllene oxide 33.l 9 1607 P l atyphyl l ol
32.17 1582 Trn'rnerol<ar-> 33.20 1608 A tl antol
32.l8 l -582 Neryl isovalerate 33.20 1608 l)odccenyl acerare<(2b)->
32.25 1584 Oc:tancdioic acicl.diethylester 33.20 1608 HunrulencepoxidelI
32.25 1584 Phenylethyl tiglate<2-> 33.22 | 608 Naphthalene <2-acetyl->
32..30I 58.5 Ptesilphiperlblan-Sol 33.3-5l6l I Tertradecanal
3 2. 33 1. 586G le e n o l 33.37 16l2 Isolongif<rlanone <cis->
32.34 1586 Thuiopsan-2s-ol 33.39 1612 B i otol 
Adams:Esscntial bv GC/MS
Oil Comnonents
RT Al CornrnonNaurc RT A[ CornmonNante
.1.1.42l613 Ethyl chrornone<2-> 31.42 1639 I)uprezianen-3-one <2-epi-B->
33.,12l6l3 Styrene<2.4,6-trirnethoxy-> 34.45 1640 Flinesol
33.46 l(rl4 Isoeugenolacctate<(ll)-> .14.46l 64O Muurokrl< epi -a->
3 3 .47 1615 I ) av an o l l )l (i s o rn e 'l r) 34.46 164(l Phenylethyl hexanoate
33.48 l6l-5 Hinrachalene oxide <B-> 34.47 164l l )aucol
3 3 .- 52l6l6 I s om y r i s ti c i n 34.48 l64l Thuiopsanone <3-iso->
33.-531(rlfi Asarone<(l)-> 34.53 | 642 Styrene<2,3,4,6-tarramethoxy->
3 3 .56 l6l7 B ut y l a n th ra n i l a te 34.54 1642 S el i na-3.1 l -di cn-64+ l
33..59l6 | 8 Cedrol<epi-> 34.56 164.1 Isobolnylisobutanoate <6-hyclroxy->
3 3 .- 59l6l8 ls olon g i tb l a n -7 u -o l 34.58 1643 Cec'lren-3-otre <2-epi-p->
33.60 l6l8 Bisaboladien-4-ol <2,(77.)-> 34.61 1644 Muurolol <u.->(=Torreyol)
3 3 .60 1618 Cuhen o< l 1 ,1 0 -d i -c p i -> 34.(t3 1645 Cubcnol
3 3 .61 l6l8 J uneno l 34.68 l6z16 Desmethoxyencccalin
3 3 .6 4 16l9 Helilbl e n -1 2 -aCl < a n ti -s y n -s y n -> 34.(t9 164(t Agarospirol
3 3 .64 l6l9 Helilir l e n -1 2 -a I)l < s y n -s y n -s y n -> 34.11 1647 Khusilal
-13.6-5 l (rl9 Linakrol <(Z)-8-hydroxy-> 34.72 1647 Butyl phthalide<3->
3 -1 .661620 I ) ill ap i o l e 34.73 |(t4l Arnyl cinnatualdehyde <(.7.)->
3 3 .7 2 162l Cedr en ec p o x i d e< B-> 34.74 1648 Mcthyl.jasmonate <(Z)->
33.72 162l Leptospernrone <istt-> 34.15 1648 Guaia-3,9-dien- l | -ol <cis->
-3-3.75 1622 Corocalcne<0.-> 34.19 1649 Euclesrnol <B->
3 3 .11 1622 E udesmo<l 1 0 -e p i -y -> 34.81 1649 V ul garoncB
3 3 .80 1623 ls ohuty cl i n n a ma tc 34.83 l6.s0 Cedr-8(l -5)-en-9s-ol
33.82 1624 Citronellylpentanoate 34.8-516.50C edr-8(1-5)-en-10-ol
33.83 1624 Silphiperlbl-6-en--5-one 34.85 16.50 Isoamylgclanate
33.tt8 l(r2-5 Isolongitblanonc <trans-> 34.87 l6-5| Dihyclroagarolui'an <4u-hydroxy->
3 3 .90 1626 Cedr en -3 -o n e < 2 -e p i -u -> 34.89 I65| P ogostol
33.9| 1626 Hexyl phenylacetate 34.91 1652 Hudesrnol <0->
33.92 | 626 llenzophenone 31.91 1652 I'lirnachalol
33.93 1627 Isornenthonc<2-(3-oxobutyl)-> 34.93 1652 C adi nol < u->
3 3 .95 1621 Cuben o< l l -c p i -> 34.94 l (r-53I)inretlroxy,.5-vinyl- <4,6->
I ,2-benzodioxide
33.95 1627 l)avanolI)2 (isorner2) 34.9-5l6-53 Thujopsanone <3->
34.(X)1628 Ccclranone <-5-> 34.91 1654 Linalool<I.2-dihyclro-8-hydroxy-(2lr)->
-11.011629 Leptospermone 34.99 1654 Methyl dihydro.jasmonatc <cis->
3-1.011629 Erenroligenol 35.01 l6-5-5Exalatac:in
-]J.0-sl6-30 Cedrcn-9-one <0-> 3-5.02l6-5-5Gcranylvalerate
.1i.06 16.10 N,luurola-4.10( l4)-dien-I F<rl 35.04 l6-55 Syringaldehycle
-11.08l6-10 Iiudesrnol<y-> 3.5.06l6-56 Citronellyltiglate<(7,)->
-3J.l0 l6-l I Gynrnonritrone 3.5.07l6-56 Valerianol
. 163l S c s qui l a v a n d u l<o(E
3 '1I0 l )-> 35.08 1656 R i sabol ol oxi deB < u->
3-1.l3 l6-12 Acorenol<tr-> 3.5.08l6-56 Isoholnylisobutanoate <-5-hydroxy->
34.14 1632 Isoborneol<8-isobutylyloxy-> 3.5.08l6-56 Patchoulialcohol
34.1.51632 Phthalide<3-butylhcxahydro-> 3-5.091657 Atractylone
3 4 .1 . 51632 S elinal-,3 ,7 (l | )-tri c n -8 -o n e 3-5.141658 S cl i n-ll -en-4c-ol
34.16 1632 Hexenylphenylacetate<(32)-> 3-5.1-51658 lnternrcdeol <neo->
34.20 1634 Carnphoricacicl 3-5.161658 Agcratoclrromene
34.24 1635 Hexenylphenylacetats<(2ti)-> 3-5.16 l6-58 (iyrnnonritlol
34.25 1635 Cadin-4-en-7-ol <cis-> 3-5.201660 Calarncncn-10-ol <cis->
34.28 |636 Gossonorol 3-5.2-5l66l Allohirrrachalol
3 4 .30 1636 A c or en o < l B-> 35.2-5l(16l Euclesmol <dihydro->
3 4 .3. 516. 17Capilli n 35.29 1662 lludesmol<7-cpi-a->
34.38 1638 Cadinol<epi-u-> 35.38 1664 Juni cedranone
3 4 .40 1639 Car y op h y l l a -4 (l 2 ),8 (I3 )-c l i e n --5 u - ol 3.5.411665 Lyral
3 4 .40 | 639 Car y op h y l l a -41 (2 ).8 l(3 )-d i e n -5 B-o l 3-5.421665 lnternredcol
34.41 1639 Hepttrn-2+ne<6-methyl-6- 3-5.45l(166 Caryophyllene <14-hydroxy-(7,)->
(3-nrethylphcnyl)-> 3.5.46l(r(rfi Citronellyltiglate<(ll)->
34.42 1639 Aromadendrene <e.poxicle-allo-> 35.41 1667 Il i sabol -l l -ol < E ->
34.42 1639 Cedrenal <1.7-diepi-u-> 35.47 1667 Phloroacekrphenone <2,4-dimethyletlrer->
-t-}
AppendixII: Compounds
l-istedin Or.der.of
Elutionon I)B--5 47
RT AI CornnronNamc RT AI ComnronNarne
3-5.4ttl6(17 Arnyl cinnanraldehyde <(lr)-> 36.32 1689 Davanolacetate
35.48 l6(17 Conil'crylalcohol<U,)-> 3(r.33 1689 Aprirone<(Z)->
35.49 1667 Pcntadecen-2-onc <((rZ)-> 36.-141689 Borrydiol
-3-5.-5 | l(168 Calanrcnen- l0-ol <trans-> 36.37 l(r90 Ber-uanrorol <(Z)-a-rrans->
3-5.-5 I l(r(r8 Hexenylsalicylare<(.3Z)-> 36.44 1692 .funiceclranol
.l-5.-5 I I (168 Turnterone<ar.-> 36.4-5l(r92 Acorenone
3-5..521668 l)ihycL'oarlanrone <(I1)-10.l l-> -j(t.45 1692 Cuprenen-l-ol<4->
3-5.-53 1668 Atlanronc<B-> 36.48 | 693 Gcrntacrone
-35.-53| 668 Caryophyllone <14-hydroxy-9-epi-(E)-> .36..5
I 1694 Arlanrone<(Z)-y->
3. 5. . 54I 6( r t l' / . it u n o n c< c p i -> 36.-5(rI69-5 Cypcrotunclone
-l-5.(r01670 Bisaholol<epi-B-> 36.-591696 Ge.r.anyl ti-elate
-l-5.(r01(r70 Bulnesol 36.63 1697 T,izanal
-1.5.(r4 167I Tctradccanol<n-> 36.64 1697 AcorenoneB
3-5.(r-5 167| Buryliclene-phrhalide <(.37.)-> 36.64 1697 Pcntaclecalrorrc <2->
3,5.68I672 Cedmnol<-5-iso-> 36.(18I (r98 l)eodarone
35.14 1674 Bisabolol<B-> 36.(r8 1698 Farncsol<(27.,62)->
35.71 l614 FlelilirlenolA 3(r.69 1698 Agglonerone
-l-s.741674 San{alol<(7).u-> 36.12 1699 H i rnachal -4-en-18-ol < l l aH ->
-3-5.74 I (r74 Valelanone 36.72 1699 Noorkarol<epi->
35.7-51674 Hycl'oxycliphenyl mcrhane<2-> 36.73 1699 Sine.nsal <D->
35.15 1614 lsobornylisohutanoatc <8-hyclroxy-> 36.74 1700 lruclesrn-7(l l)-en-4-ol
-35.7-5 l(r74 Salicylicacicl.hexyl esrer 3(t.14 1700 Heptaclecane <n->
-1-5.77| 67,1 Caclalene <8,9-cpoxide> 36.71 1100 Amorpha-4.9-dicrr-2-ol
3-5.79167-5Asarone<(E)-> 36.71 1700 Merhoxycinnarnicacid <(4lr)->
-l-5.80l(r7-5 Andro encecalinol 36.79 1101 Caryophyllene acetate
-l-5.80l(r7-5 Caclalene 36.80 | 70 | Acetophenonc <2.4.(r-trirnethyoxy-
.15.80l(r7-5 Khusilol 3-nrethyl->
-l-5.83l(176 Musrakone 36.81 170| S esqui ci neol -2-one
-3 - s . li4167( r G ua i a -3 ,1 0 (1 4 )-c l i eln-o-ll 36.82 1702 Calanrencn-10-one <1O-n<x->
-3-5.8-5 1676 l)odecalactone <y-> 36.84 1702 S antal ol< (Z)-epi -F->
-l5.li-51676 Neroliclylacerare <(Z)-> 36.tt-5f 703 Tridecenolacctare<(28)->
-15.8-5l(176 Occiclenol 36.91 1704 A nrorpha-4,9-di en-14-al
3. s . 87l( r 77 A pi o l e 36.9| l704 Dodecalacrone <6->
.1 5. 87l( r 77 l, r r c :n i c u l i n 36.98 170(r Atlantone<(E)-y->
3 - 5. 89l( r 77 Hel i l i rl e n oB l 36.98 | 70(r Caryophyllene < 14-hydroxy-4,-5-dihyclro->
.l-5.9 | f (r78 Methyl epi-jasmonate <(Z)-> 36.98 170(r Mel al eucol
3-5.9-5 lfi79 Khusinol 36.98 1706 Propylchr.omone <2->
-l-5.97I (rf30 lllcrrlrl acetate 36.99 1706 Apodophylene
16.00 l(r80 Islrrvaronc 37.04 1708 Aprironel<(E)->
.16.02168I Occidcntalolacerate 37.06 1708 Thui opsenal < ci s->
-l(r.0-l| 6ttI FlclilblenolC 37.09 1709 Mayurone
-l(r.03 l(r8| t{clilblcnol I) 31.21 11I 2 Curcunre-n- l -5-al<ar->
.3(r.0-5 l (r82 Mcthyl clihyclr.o.iasrnonatc <trans-> 37.22 17l3 Calanrenene <.5-lrydroxy-cis->
-3(r.0(r1682 Alnyl cinnantylalcohol<a-> 3l .22 11l3 Farnesal<(2F.67.)->
.1( ) . 1Il( r i{ . 1B is l l ro h rl< c p i -u -> 31.23 17| 3 Cedroxyde
-16.l-l l(r,34 Farnosal<(27.,62)-> 37.24 | 7 l3 Hunrulene< l4-hydroxy-o->
-36.l4 l(rli4 BisabokrneoxicleA <n-> 31.25 171.1 l 1y11qi l i l l 1yI
-16.l4 l(rll4 Ccclranol<-5-neo-> 37.25 l1l3 Nucil'cral<(Z)->
-l(r.I6 l6u4 Lon_siborncol acctate(=.luniperolacetate) 31.21 ll 14 Farnesol<(2E,62)->
3 (t . 17 i' 68- 5B is a h rl o l< a -> 37.28 l 7l 4 N ootkatol
3(r.I 8 | (r8-5Gcrrnacra-4( l-5).-5,l0( l4)-rrien-l n-ol 37.28 | 7l 4 P henerhyl 2-l uroare
-lCr.20 | (rfi.5 Massoia dodccalactot.lc 37.31 17f-5 F-arnesal <Q7^6E'\->
36.27 | (r87 lruclcsnra-4( | 5).7-dien-I [3-ol( inrpure) 37.:11 | 71.5 N i rani n
-l(r.-10l(rtt8 Ccdrcn-l3-ol <tl-> 37.31 | 71.5 S antal ol< (7t-[]->
3 ( r . 311( r 88 l; ar n es o l < 2 ,3 -d i h y d ro -> 37.35 17l 6 N crol i dylaccrare < (E )->
36.-l| | (r[38 Muurol--5-cn-4-onc <cis-l4-nor-> 37.38 l 7l 7 C tn' cuphenol
-l(r.-lI l(r88 Shvobunol 37.39 l 7l 7 A tl antone< (/,)-a->
by GC/MS
Oil Components
Adams:Essential
48
RT A[ CornmonNatne RT AI Corrtnon Nanre

3 7.3 9 l' 7l7 Rut y lide n e p h th a l i d e< (3 ts )-> 38.98 l76l liupattx"iochromene
3l .40 1718 Methyl eudesmate 39.0t 1162 Aristolone
31.41 l7l8 Davanone-2-ol <B-> 39.03 1762 Acoraclienol <B->
3 1.4 5 1719 S edane n o l i d e 39.15 1766 C ostol
31.48 1120 Hepta-I ,3,-5-triyne < l -phenyl-> 39.16 17(t(t Drirnenol
37.-5-5 1722 Celestolide 39. I 6 | 76(r Sescluici rreole< | 2-lty droxy-(Z)->
31.55 1722 Ncocniclilicls 39.19 l l 66 C urcurncn-15-al < Y ->
31.51 1722 Methyl tetradecanoate 39.21 1767 Ceclryl acetate
37.-581722 liarnesol<(27.(tE)-> ?9.22 1767 Muurolene<14-oxY-u->
31.62 1724 Clyptomcrionc 3L).221167 Valenccne
37.63 1724 Nucil'erol<(Z)-> 39.26 1768 lJancroliinone
31.68 1125 Guaiolacetate 39.26 1768 Bisabolenal <P->
3 1.1 0 1126 T as m a n o n c 39.31 1770 Squatnttlosone
?7.15 | 727 Nucil'eral<(Il)-> 39.42 1713 Cinnamaldehyde<2-hexyl-(Z)->
37.78 | 728 Cinnarnaldhyde <4-hydroxy-3-nlefhoxy-> 39.42 l1l3 Costol<a->
37.80 | 728 Culcumen-I 2-ol <y-(Z)-> 39.12 1773 Pentadectrnol <n->
39.48 1774 C ycl octrl orettone< cpi ->
-1 7 .801728 Longilo l o l
39.49 1775 Arnorphir-4,7( 1 | )-diene<2u-hydroxy->
-3 7 .841730 V et is el i n e n o l
3 7 .8 7 1730 Clr at na z u l e n e 39.-50 177-5 Ceclrylnrethylketone
37.92 1132 Sesquilavandulyl acetate<(Z)-> 39.56 1777 Cresolttctauoate <P->
37.94 1732 Zerutnbone 39.-581777 lsobaeckeol methylether
37.9-51733 Curcr-rrrenol 39.59 1771 Atlantone<(E)-o->
37.95 1733 Isobicyclogcrmacrenal 39.59 1117 Santalolacctate<(Z)-a->
37.98 1733 Conit'erylalcohol<(I1)-> 39.64 1179 Muurolene<14-hydroxy-u->
38.02 1734 Ercnrophilone 39.66 1779 Guaiazulene
38.02 1734 Ligustilide<(Z)-> 39.79 1'183 Hinesol acetate
3 8 .1 . 51738 S ant al o<l (E )-B-> 39.79 1183 Methyt tarnesoate<(2E,6Ir)->
38.17 1739 f)ploPanone 39.19 1783 Nerolidyl isobutyrate<(Z)->
3tt.l9 1739 Sesqtrilavanclulyl acetate<(E)-> 39.80 1783 Eudesnrolacetate<y->
39.89 1786 h,lerrra-1,3-dien-8-ol <7-acctoxy->
38.21 1740 Isoarnylcinnamate<(t1)->
38.21 1740 Mint sulllde 39.92 1186 llutyl doclecanoate
38.22 1140 Farnesal<(ZE,(tP')-> 39.94 l78l Pttpuanone
38.21 1140 Bisabolone<6R,7R-> 39.97 1788 C edren-13-ol acetate< 8->
isobutyrate <(E)-> 40.01 1789 B i sabol enol 
-38.2417,10 Pseudoisoeugenyl
l5)-en-9u-ol, acelate 40.02 1789 Octadecene <l->
-38.26l74l Cedr-8(
4O.ll 1792 lludesmol acetate<B->
-1 8 .1 61741 K hus in ro l
.1t3..10 1742 Farnesol<(2E,6E)-> 40.12 1192 l)rirrtcnone
40.14 1192 Acctoxyelemol<84->
-lu."l0 174-5Costol<y->
38.,1.11746 Elemodiol<8o-11-> 40.1-51793 Isovalencenol<(E)->
e pnoex i d e 40.16 1793 ltpoxy-pscudoisocugenyl isobutyrate
3 8 .1 6 1146 S elina -1 ,3 ,1 (1 1 )-tri c n -8 -o
3 8 .- 501748 llis abo l o l o x i d eA 40.20 1794 Bergan.rotol acetate<(Z)-u-trans->
38.5| 1748 Cinnarnaldehyde <2-hexyl-(lr)-> 40.21 1794 lludesntolacetatc<o->
38.-521748 Bisabolotre <6S,7R-> 40.22 1795 Coumalin <4iydroxy->
3 8 .64 l75l Cupar e n a l 40.25 1795 lrtltyl tetradecanoate
38.64 l7-5l Xanthorrhizol 40.28 1196 Ligustilide<(E)->
38,70 1753 Isobaeokeol 40.33 1798 Bisabololacetate<o->
3S.75 l7.54 Curcumen-12-ol<P-(7')-> 40.40 1800 Octadecane<n->
38.75 1754 Nucil-erol<(E)-> 40.42 1800 Isotorquatone
38.7S l7-5-5Anrorpha-4,9-diene <7'14-anhydlo-> 40.48 1802 Risabololacetate<epi-o->
 40.4() | 802 Pyran--5 <rne <2,2-di methyl-7-sec-butyl-
3 8 .78 1755 S inens a l
38.80 l7-56 lJrenrophilone <8-hydroxy-dihydro-> 2H.5H,PYrano [4,3-bl>
3 8 .8 1 1756 A r nbr o x i d e 40.52 1803 Cadinene<14-hydroxy-6->
38.82 1756 Cinnamylacetate<o-amyl-> 40..52l 803 C al l i tri n
38.90 l7-59 Benzylbenzoate 40.53 1803 l l enzoi n
38.92 1759 Cyclocolorcnonc 40.59 I 80-5 Arnorpha-4,7(I I )-diene<2cr-acctoxy->
38.94 1760 Lanceol<(Z)-> 40.60 180-5Conglomerone
38.95 1760 Bisaboladien -12-ol<2,7(14)-> 40.60 1805 Santtrlolacetale<(Z)-epi-B->
Appenclixll: Compoundsl,istctlin Orclcro{'},.lutionon l)B--5
49
RT AI CurnmonNarue RT AI CornmonName
40.62 180(t Nrxrtkatonc 42.84 l8(r9 Flourcnsacliol
40.65l807 $nligylate,2-ethylhcxyl- 42.93 1871 Homoisobucckeol nethyl ether
40.70trJ08Euclesrn-| | -en-4s.6a-cliol 43.03 1874 Hexaclccanol <n->
40.74 1809 Pyran-5-one<2.2-climethyl-7-isobutyl- 43.l -5 | 878 Cubitene
2H,.5H-pyrano[4,3-b] -> .13.l9 I 879 Spiroether<(Z)->
40,80|8tI Chcnopodiol<B-> 43.20 1879 Laurenene
40.80l8l I Vetivenicacid 43.22 1880 Cyclohexylanthranilate
40.831812 Acor'<lnc<iso-> 43.25 1880 Hcxenylcinnamare<(37.)->
40.8(rl8l3 Cryptonrcridiol .1.1..14188-1A l krevodi onc
40.94I 8 t5 Torcluatone 43.45 1886 Farnesylacerone<(58,92)->
40.97I 8 l6 Butyl chrornone<2-> 43.47 1887 Oplopanonylacerare
40.98| 816 F'arnest'ricracid <(2 E.6E)-> 43.-541889 C edrane-cl i<ol8S ,14->
4t.0-5t8l8 Santalolacetate<(7,)-F-> 43.-5-5I8t39 Falncsyl acetone<(.57,.98)->
.l t.06 l8 | 8 Trihyclroxybcnzaldehyde <2,4.6-> ,13.56I 889 Isobornylisobutanoatc <8-isobutyryloxy->
,11 .09 l8l9 Acorone J.1.581890 C l tcrropocl i ol -6-acctate< 0->
4t.09 l8t9 Longilblol acetatc<iso-> 43..59 I t390 Spirocther"
<(E)->
.11.131820 Hcxenylanthranilate <(3/.)-> 43.68 I 893 Dihydroangelicin <2',3',3'-tirnethyl-2',3'->
.ll.t6 l82l Farnesylacetate<{22,6F,)-> 43.71 l89zl Catalponone
1t.20 t822 Vctivone<p-> 43.75 1895 lrpoxy-pseucloisoeugenyl 2-rnethylburyrate
+ I .21 t823 Khusinolacetirte 43.79 1896 Rinruene
-+I ..1{)182.sDisulllcle,diphcnyl 43.tt3 | 897 C edrane-di ol < 8S ,l 3->
-l| .30 182-sNeroliclyl isobr.rtyratc <(E)-> 43.92 1900 Nonaclecane <n->
-ll.-12182(rAvocadynolirran 4-1.9-5I 900 Columellarin<dihydro->
+ | .-17t827 IJcnzcneacctic acid,3-tnethylphenyl ester 43.91 1901 Laurcncne<cpi->
l r .-121828 Isopropyl tetl'adecan0ate 44.0ti 190.+ Evodione
-ll.-t7 t830 Nuci t'erolacetate<(.7,)-> 44.11 1905 Isopi rnara-9(l l ),1.5-di ene
r r.56 | tt32 CycIopcntaclecanoI ide 44.33 1912 Kudrdiol
-ll.6u l13.16 Occidol 44.31 l913 Farnesylacetone<(-5E,98)->
-lt.69 r836 Coumarin<7-hydroxy-> 44.38 l 9l 3 P henyl crhylphcnylacerare' <2- >
-+t.72 | 837 Hillyl acetate 44.40 1914 V al encene < l I,l 2-di hydroxy- >
-1l.ttO1839 Eudesrn-7( | | )-en-4-ol.acerare 44.64 l92l Methyl hexadecanoate
+r.rJ01839 Honroisobaeckcol 44.68 1922 Totarcne
+ | .82 1840 Pipitzol<o-mcthyl,a-> 41.84 1926 Carissone
-rt.8.5| 8.11Caf'lbine 44.92 1929 Musk anrbrertc
r l.tr.5184| Pseudoisoeugenyl 2-nrethyll-rur.yrate
<(E)-> 41.97 1930 l)ictarrine
I I .89 18.+2Vctivone<c-> 44.98 l 93l B eyercne
-rr.96 1844 Istltorquatonc<clenrethyl-> 44.98 193l P l oceri n
+ t.97 1844 Bisabolatrien- | -ol-4-one<2,1( | 4),10-> 45.02 1932 Cr-rparenic acid
+ t.97 18.+4Isoarnyldodccanoate 4-5.05l 933 Isohibacne
+ r.97 t 844 Ternine<(7.\> 45.06 1933 R osa--5,l S -di ene < ent-)
+r.0| I 845 Farne.sylacctate<(2E,6H)-> 4-5.071933 Cyclohexadccanolide
+1.0,1t846 Phenylethyl octanoate 45.21 1937 Cembrene
-11.0-s l84a) Ercmophilone<8-hydroxy-> 45.24 1938 Acetoxyeudesrnan-zla-ol <l l->
{1.r0 | 8+8 Oxofulanoerenrophilane < l . | 0B-epoxy-6-> 45.34 l94l Callitrisin
-ll..1g1g-53Pipitzol<o-metlryl,B-> 45.31 l91l l)rinrenin
-[.-3] l8.s4 Lanccolacctate<(Z)-> 45.37 1942 Phyrol
Jt.-16tS.s.sChcnopodiol<a-> 45.52 194(r Isophytol
Jt.-5-+t860 Farnesylacctone<(7^7,)-> 4-5.-5.51947 CcrnhreneA <(3E)->
+1.-5,5 I 861 Amorl.rlra-4,7-clienc <2a-acctoxy- 45.-59l948 Pimaradiene
I I-methoxy-> 15.7O1952 C ol rrrncl l ari n
-ll.-5S1361 Baeckeol 45.1)2l9-58 Gcranylhcnzoare
Jt.6-5l863 T h u i o p s c rriacc i d< c i s -> 4-5.9-5 l9-59 Hcxadecanoic acid
-11.68t86.1 Benzylsalicylatc 4-5.9-5l9-59 Nootkarin
rl .7-1l ti(rfi M u s k ry l o l 4.5.981960 Geranyll i nal ool< (2,7)->
:t.7-i t866 E,ncecalin 45.99 1960 Chenopodiol-(r-acerate <o.->
Jl.:-5 l8(1 6 Torquatone<denrethyl->
'1-5.991960 Rirrrucne <tetrahydro->
rl.-9 | 8(r7 Santalolacetate<(E)-p-> 46.16 196-5CemhreneA <(32)->
50 Adams:Essential bv GC/l\4S
Oil Cornponents
RT AI CornrnonNarne RT Al CornrnonName
46.181966 Isophyllocladcne -50.332095 Mcthyl linolcate
4(r.2.51968 Callitrisin <dihydro-> 50.47 2100 Heneicosane <n->
46.26 1968 Sandalacopinrara-8( | 4), l -5-diene -50.952l l-5 Isoprenylc'rxycoumarin <7->
46.30t969 Jensenone -50.96 2l l-5 Laurenan-2-one
46.34t9t0 lsoprenylcinnamate<(Z)-methyl-> 51.23 2124 Methyl octaclecanoate
46.421973 I)olabradiene 51.24 212-5 Isoeugenylbenzylether<(E)->
46.45t914 FerulalactoneI 51.28 2126 Phenylethyl anthranilate <2->
46.451974 Sclalcne 51.47 2132 Li nol ei caci d
.16..5
I 197.5Occidolacetate 51.47 2132 N ezukol
16.561911 R illoratriene 5l.12 2140 Osthole
46.69198| Counrarin<7-lryclroxy-4-methyl-> 51.75 2l 4l Ol ei caci d
46.80198:1Musk ketone -51.9821,19 A bi enol
46.841985 Ar.rrorpha-4,7( I I )-clien-8-one<2c-acetoxy-> 52.08 2152 Oloselone
46,89l9U7 Manool oxidc 52.12 21.53 A bi eta-(8(14),13(l -5)-di ene
46.901987 Geranyllinalool<(E,Z)-> 52.26 2l-58 lncensole
.16.92t987 Eicosene< | -> 52.76 2171 Grandillorene
-16.93t 988 Pseudophytol<(62, l0Z)-> 52.90 2179 Phcnethylcinnamate
.16.941988 Catalponol<cpi-> 52.93 2180 Citronellylanthranilate
47.061992 Stilbcne<4-n.rcthoxy-> -53.0-52184 Incensoleacetate
41.091992 Iithyl hexaclecauoate .5.1.062 | [J4 Sanclaracopir.narinal
47.25 1991 Kaur'-l-5-ene 53.22 2189 l)ocosene< l->
41.21t998 S es elin 53.43 2196 Ethyl octadecanoate
41.29 t998 Geranyllinalool<(7.E)-> -53.502198 U gancl ensi di al
47.33 2000 Ilicosane<n-> -53.-532 199 Catalpalactone
47.35200t) l)olahracliene 53.54 2200 l)ocosane<n->
47.,1.5200,1Heradecyl acetate 53.65 2203 Santonine<o->
.17.6-12009 M anoo lo x i d e< l 3 -e p i -> -53.782208 Totarol<cis->,methylcther
-+7.7-s2013 Counrarin <7-hydroxy-4,8-dirnethyl-> 53.82 2209 Octaclecranol acetate
17.81201.5Ethl'lenebrassylate 53.83 2209 Plryllocladanol
+7.8.5 2016 Poll,grxlial 53.96 2214 Retene
47.8620t6 Phylkrcladene 54.02 2216 Manool oxide <2-keto->
47.9020| 8 J uv ibio n c 54.01 2217 Geranylanthranilate
41.912018 Psetrdoph1'tol<(61r.l 0Z)-> 54.07 2218 Phytolacetatc<(E)->
48.032022 A hiet a -8 .l2 -d i e n e 54.15 2220 Methyl eperuate
48.08202,3Catalponol 54.21 2222 Sclareol
48.082023 Warburganal 54.47 2231 Mcthylcommunate<(Z)->
48.092024 Isopropylhexadecanoate 54.49 2232 Stilbene<3.-5-dintethyoxy->
48.162026 Geranyllinalool<(11,E)-> 54.632237 Isopi nrpi nel l i n
48.292030 Pseuclophytol<(62,l 0R)-> 54.63 2231 Manool <7u-hydroxy->
48.39203:l Bergaptene<iso-> 54.63 2237 Totarol<trans->.nrethylether
48.442035 Falcarinol<(7,'\> 54.65 2237 Methyl pimerrate
48.65 2012 Stilbene<4-hydroxy-> 54.75 2241 l)ecyl anthranilate
48.662042 Kaurenc 54.76 2241 Isoeugenylphenylacctate <(Z)->
48.152045 Canell a l 55.19 225(t Methyl sandaracopintarate
49.0820-55Abietatricnc 55.22 2257 Mcthyl comrnunate <(E)->
49.102056 13crgaptene 55.47 2265 Larixol
49.n 2056 Manool 55.58 2269 Sanclaracopitnarinol
49.162058 Pseuclo phytol<(68, l 0E)-> 55.74 2214 Abietal,dehydro
49.202059 M anoo l< 1 3 -e p i -> 55.88 2219 Incensoleoxide
49.402065 Isoprcnylcinnatnate<(E)-methyl-> 55.98 2282 Sernpcrvirol
49.402065 Sclareolicle 56.24 2291 Labd-7,13-di en-15-ol
49.6u2072 Isoeugenylbenzyl ether<(Z)-> 56.41 2297 Manool <3u-hydroxy->
49.162077 Octaclscanol<n-> 56.42 221)7 Isoc,ugenylphenylacetate <(ll)->
50.002085 Juvibione<dchyclro-> 56.42 2297 Mcthyl isopit-n:rrate
.s0.082087 Abietaclienc 5(t.11 2298 Abietal <4-cpi->
l0 2088 Nootkatinol
.50. -56.482300 Tricosane<n->
50.222092 Benzylcinnamatc 56.66 2306 Methyl levopinrarate
AppendixII: Corlpounds
l.istcdin Orcler"of
lllutionon DB-5 5l
RT Al ColnnronNante
56.11 2310 Isopirnarol
5 6. 8- 52312 A bi e ta -7 ,1 3 -d i e n c -3 o n c
.56. t i72313 A bi e ta l
-56.U823 l4 Totarol <tl'ans->
56.92 2315 Felluginol <6,7-dehyclro->
57. 11 2324 A bi e ta c l i e n -1 8 -o
< 8l ,1 3 ->
51.39 2331 Ferruginol<trans->
57.39 233l Mcthyl claniellare
57.55 2331 Manool oxide <3s- 14.15-dihydro->
51.65 2341 Methyl dehydroabietate
57.72 2343 Abietol <4-epi->
51.76 2344 Libocedrol
-58.I8 23-59 Manool <3c-acetoxy->
58.21 2360 Peucenin,7-methylethcr
-58.2I 2360 Torulosol
-58.282363 Ferluginol acetate<trans->
5ft.3-5236-5 Conmunic acicl
58.42 2368 Ahierol, dehydr-o
-58.-50 2370 Fcrluginol<cis->
58.80 2381 Mcthyl labdanolate
58.9| 2.18-5Merhyl ahietare
-58.962387 Methyl nidoresedare
58.96 2387 Mcthyl srricrare
-59.0.52-390 Heyderiol
59.12 231)2 Labd-7,13-dien-1-5-ol, acerare
59.33 2400 Teh'acosane <n->
59.37 2401 Abietol
59.63 2411 Ferruginolacetate<cis->
59.92 2422 Labd-13tr-8,1.5-diol
(fr.10 2428 Totarol acetate<trans->
(ff-28 2435 Taxodione<6-dcoxy->
60.48 2443 Methyl neoabierare
(fr .55 2445 Totarol <7c-hydroxy-trans->
(fr.84 2456 Fen'uginol<6-keto->
61.15 2468 Abietol <neo->
62.00 2-500 Pentacosane <n->
62.05 2501 Methyl-7,13,1-5-abierarrienoare
63.10 2542 Totarolone
63.30 2549 Hinokione
63.-502-5-57Hinokienone
61.33 2.589 Hinokiol
&-61 2600 Hexacosane
65.36 2629 Sugiol
67.12 2700 Heptacosane
67.83 2729 Resveratrol
69.-5-52800 Octacosane
71.78 2900 Nonacosane
74.16 3000 Triaconrane
76.3-5-1100 Unlriaconta'e
78.48 -1200 Dorriacontane
79.26 32?7 Stigmast-4-en-3-one
EO--55-3300 Tritriacontane
E2.80 3400 Tetratriacontane
Appendix III: Mass Spectra
53
AppendixIII
MASS SPECTRAAND STRUCTURESOF COMPOUNDS

LISTED IN ORDER OF THEIR RETENTION TIME/ARITHMETIC INDEX ON DB.s
RT: 1.63 AI: 529 KI: 540 EthYl ether

CAS#:60-29-1 MF: C4 HlO O trW:74 MSD LIB#: 1-561
CN: ethylether
Synonyms:diethyl ether
Source:VWR Scientific
AoA
RT: 1.80 AI: 606 KI: 609 EthYl acetate

CAS#: 14l-78-6 MF:C4 H8 ()2 FW: 88 MSD LIB#: 186-5
CN: aceticacid, ethyl ester
Synonyms:aceticether;acetidin;ethyl ethanoate
Source:VWR Scientific; 57.39VoCanangaodorata, Sepu.6: 1I ( I 988); 6.40VoBouea macrophylla;
3.797oBrassicaiuncea (seed)
100
80
60
40
20
RT: 1.88 Al:623 Kl:632 Hexane <n'>

CAS#: I 10-54-3 MF: C6 Hl4 FW: 86 MSD LIB#: 1430
CN: n-hexane
Synonyms:none
Source:SigmaChem.; 2.60VoThymus vulg aris, B iofl avour 87:327( I 988);
0.127aArtemisiaannua;A.l}VoApium graveolens
cH3(cH2)4cH3
J)
RT: L93 AI:634 KI: 64.5 Methyl propanoate

CAS#:554-12-l MF: C4 H8 ()2 FW: 88 MSD LIB#: ll t0
CN: propanoicacid,methylester
Synonylns:Inethylplopionale
Source:AldrichChem.
^r"\
RT: 1.99 AI: 647 KI: 658 Dichloroethane

<1,2->
CAS#:107-06-2 MF: C2 H4Clz FW: 98 MSD LIB#: -591
CN: ethane,1,2-dichloro-
Synonyms:none
Source:Matheson-Coleman Co.
I_
I
cH2cl
80
RT:2.00 AI:6-50 KI:660 Cyclobutanone

CAS#:I l9l-9-s-3 M F :C 4 H 6 O F IM :70 MSD LIB#; 2014
CN: cyclobutanone
Synonyms: none
Source:Aldrich Chem. ex.IJ Brophy
56 Adams:EssentialOil Components
by GC/MS
RT:2.00 AI: 650 KI: 660 Isobutanol

CAS#:78-83-l MF: C4 H10O FW:74 MSD LIB#: 1609
CN: 1-propanol, 2-methyl-
Synonyms:isoburyl alcohol
Source: Aldrich Chem.
E
F 4l
F
F
il
60
RT:2.02 AI:654 KI:664 Butanal<2-methyl->

CAS#:96-17-3 MF: C5 HlO O FW: 86 MSD LIB#: 1703
CN: butanal,2-methyl-
Synonyms: none
Source:Aldrich Chem.
100i,l
80
60
40
20
RT:2.(X AI:658 KI: 668 Isovaleraldehvde

CN: hrtanal,3-methyl-
Synonynrs:isovaleral, isopentanal,butanal <3-methyl->
Soucs Aldrich Chem.
\az'
AppcndixIll: MassSpcctra
57
RT : 2. 10 A I : 6 7 1 K I: 6 7 9 Methyl-2-butanol<3->
CIAS#:-598-7.5-4 MF: C-5H l 2 O F W: 88 MS D LIB #: 1(r39
CN: 2-butanol,3-rncthyl-
Synonyrns: sec-Isoanrylalcolrol
Source:Aldlich Chenr.
100
80
60
40
X"
20
RT: 2. 14 AI: 680 KI: 686 Isobutyl formate

CA S #:542- 5. 5 -2 MF : C 5 H l 0 0 2 F W : t02 MS D LIII#: t613
CN: lirrnticacid,2-nrethylpropyl cster
S1'tton1,1119;
i s1tbutylrncrthanoatc
Sorrrce:AlclrichChem.;0.06VrOcirttuntbasillicum,FFJ 6:225(199l)
)"'-.-""\o
R T : 2. 1- 5 A I : 6 8 2 K I: 6 8 7 P e n ta n o n e< 2 ->
C A S #: 107- 87-9 M F : C .5H l O O F W: 86 MS I) LtB #: 1.571
CN: 2-pentanone
Synonynrs:n<'rnc
Srrtrrce: Afdrich Cherrr.;9.llVa Psidiutnguajat,ct, FIr.l6:143(1991);
|.85VoZizt'phusju juba;0.307aHedl,otisdilJilsa
r00
8r)
60
40
20
RT: 2.1-5 AI: 682 KI: 687 PYruvicacid

CAS#:127-17-3 MF: C3 H4 03 FW: 88 MSD LIB#: 2059
CN: propanoicacid,2-oxo-
Synonyms: pyroacemicacid;acetylformicacid
Source:BedoukianRes.
t00
tl
80 /\'2"
60 I
OH
40
20
R T:2 .16 A I : 684 KI:6 8 9 Pe n te n ' 3 ' o l< l ' >

CAS#: 616-25-1 MF: C-5HlO O FW: 86 MSD LIB#: l7l0
CN: l-penten-3-ol
Synonyms:ethyl vinyl carbinol
Source:Aldrich Chem.;0.36VoComptoniaperegrina,FFJ3:65(1988);
0. | 37o Chlo r anthus sp i catus; 0.05VoTi lia co rdata
OH
80
I
-\./\Z
60
40
20
RT: 2.18 AI: 689 KI:692 Pentanol<2'>

CAS#:6032-29-7 MF: C5 Hl2 O FW;88 MSDLIB#: 1813
CN:2-pentanol
Synonyms:sec-pentanol, pentyl alcohol <2->
Source:alcoholsmix (2-OHs) ex K-H Kubeczka;7.007oPsidiumguaiava, FFJ 6:143(1991);
0.857oM ichelia fi g o ; 0. | 07oN qrc issus tazetta
100 OH
80
I
-/\-,A-
60
40
20
AppendixIII: MassSpcctla 59
RT:2.23 AI:700 KI:700 Heptane

CAS#:142-82-5 Ml"-:C7 Hl6 FW: 100 MSDLIB#:101
CN: heptane
Synonyms:skcllysolveC
Source:afkancsrnix. Alltech Assoc.;3.217oCt,mbiditmt .sinense,p. I 10,
in: AromaticPlants& EssentialConstituents, PeaceBook Co., Hong Kong(1993);
1.799/o (seed);O.50VoCarlina accntlish.<t<tt)
Elettaria carclantonranr
+J
r00
cH3(cH2)scH3
80
60
40
RT: 2.23 AI: 700 KI: 700 Pentandione<2,3->

CA S #: 600- 14- 6 M F : C .5H 8 0 2 F W: 100 MS D LIII#: t247
CN: 2,3-perntanedi<'rne
Synonyrns: acctylpropionyl
Sou'ce:Aldrich Chenr.
r 00
80
ar^-^"
60
40
20
RT: 2.25 AI:102 KI: 703 Ethyl furan <2->

CAS#: 3208-l(r-0 MF: C6 H8 O F'W:96 MSI) LtB#; 2071
C N: lur an. 2- et h y l -
Synonyrns:none
Sotrlce: liedoukianRes.;0.0.57., Mentltapiperita..ChinrikaChr.onika9:13(1980);
0.02VaOt:i rn unt basi| i cunt; 0.0 | oLtCit n ts med i ca (leal)
t00
80
60
40
20
60 by GC/MS
RT:2.27 AI 104 KI:706 Pentanal

CN: pentanal
Synonyms: valeraldehyde
flower),FFJ l:-57(1986);
Source:AfdrichChem.;2.257oTilia cordata(blossorn
2.0O7oMenthaarvensis;1.02Vo
Gardenia iasminoides
100
80
,/\./-\r'"
60
40
20
RT: 2.33 AI: 71I KI: 71-5 Ethoxyethanol<2'>

CAS#:110-80--5 MF: C4 Hl} OZ FW: 90 MSD LIB#: 1748
CN: ethanol,2-ethoxy-
Synonyms: ethylglycol
cellusolve,
Source:BakerChem.
Vo*o"
R T:2. 34 A I : 71l KI:7 1 6 E th y l p ro p a n o a t e

CAS#: l0-s-37-3 MF: C5 HlO ()2 F-!V: 102 MSD LIB#: 75
CN: propanoicacid, ethyl ester
Synonyms:ethyl propionate
Source:Afdrich Chem.;0.377oArtabotrys hexape.talus, p. 90, in: Aromatic Plants& Essential
Constituents,PeaceBook Co., Hong Kong(1993)
:-,-o\aa-
tl
o
Appendix llI: Mass Spectra
6l
RT: 2.43 Al:721 KI: 728 Methyl butanoate

CAS#:623-42-l MF: C5 HlO ()2 FW: 102 MSD LIB#: 7l
CN: butanoicacid,nrethylestcr
Synonyms: methylbutyrate
Source:AldrichChem.
r00
RT: 2.4-5 Al:723 KI: 73| Buten-l-ot <3-meflryl-3->

CN: 3-buten- I -ol, 3-methyl-
Synonyms: 3-isopentyl alcohol;isobutenylcarbinol
Source:ref. cpd.ex E. Von Rudloff
NT:2.46 AI:724 KI 732 Methyt-l-butanol<2->

CAS#: 137-32-6 MF: C5 Hl2 O FW:88 MSD LIB#: 1638
CN: l-butanol, 2-methyl-
Synnyms: sec-butylcarbinol
Sornce: Aldrich Chern.
-.--1.-.,-",
RT: 2.-50 Al:728 Kl:737 Methyl-2-pentanone <4->

CAS#:108-10-1 MF: C6 HlzO FW: 100 MSD LIB#: 1707
4-methyl-
CN: 2-pentanone,
Synonyms: hexon;methylisobutylketone;MIBK
isopropylacetone;
Source:AldrichChem.
Yr"
C AS#: 498- 66- 8 MF: C7 Hl0 FW: 94 MSD LIB#: I186

CN: bicyclo(2.2. | )hept-2-ene
Synonyms:norcamphene;norfenchene
Source:ref. cpd. ex E. von Rudloff
100
80
60
40
20
RT: 2.53 AI: 731 KI: 740 Isopentyl alcohol

CAS#: 123-51-3 MF: C5 Hl2O FW:88 MSD LIB#: 1431
CN: l-butanol, 3-methyl-
Synonyms:isoamyl alcohol
r
I Appendixlll: Mass Spectra
RT: 2.-54 AI:732 KI: 742 Thiazote

63
CAS#:288-47-1 MF: C3 H3 N S FW: 85 MSD LIB#:67

CN: thiazole
Synonyrns:none
Source:AlclrichChem.
fr
RT: 2.58 AI:737 KI:746 Tiglic aldehyde
CAS#: 497-03-0 MF: C-5H8 O FW: 84 MSD LIB#: 1959
CN: 2-butenal,2-merhyl-,(E)-
Synonyrns:tigalclehyde;crotonaldehyde,2-methyl-,(E)-
Sonrce:BedoLrkian Res.ex.I.IBrophy
100
80 at?
60
40
20
6U 80 t00 120
RT: 2.61 AIl.l4O KI:7.50 Methyt cyclohexene

CAS#: 591-47-9 MF;C7 Hl2 FW:96 MSDLIB#:20i2
CN: cyclolrcxene,4-methyl-
Synonyrns:none
80
60
40
20
RT:2.6.5 Al 144 KI:154 Penten-l-al<(2E)->

CAS#:1.s76-87-0 MF: C-5H8 O FW: 84 MSD LIB#: 1967
(2E)-
CN: 2-pentenal,
Synonyms:T-methylcrotonalclehyde
Source:BedoukianRes.ex.lJtsrophy
o\An
100
RT:2.66 AI 745 KI:755 Pentanol<4'methyl'2'>

CAS#:108-ll-2 MF: C6 Hl4 O F'W:102 MSDLIB#:2017
4-rnethyl-
CN: 2-pentanol,
Synonyms: 3-MIC;metilarnilalcohol;isobutylmethylcarbinol
Brophy
Soulce:ref.cpd.ex.T.I
-r^("'
RT: l.8l AI: 760 KI: 770 Cyclohexadiene<2-methyl-1'3->

CAS#: l-+89--s7-2 MF: C7 Hl0 FW:94 MSDLIB#:2199
2-methyl-
CN: 1.3-cyclohexadiene,
S1'nonyms:dihydrotoluene,3,4-
Appendix Ill: Mass Spectra
65
RT: 2.81 Al: 761 Kl: 7'70 Isobutylacetate

CAS#:I 10-19-0 MF: C6 Hl2 02 FW: I 16 MSD LIB#: 1607
CN: aceticacid,2-rnethylpropyl
ester
Synonyms: isobutylethanoate
Source:AldrichChem.;0.017o Anthemisnobilis,Proc.
I lth Intl.Cong.Ess.Oils,
NewDelhi,India4:207(1989)
)--A
RT:2.82 AI:762 KI:771 Pentanol

CAS#:71-41-0 M l r: C 5 H l z O F W:88MS D LIB #: 1248
CN: 1-pentanol
Synonyms:arnyl alcohol
Source:Aldrich Chem.ex Art Tucker; 0.607oBrassicajuncerz,Nippon Noge.,
Kaishi 54(#2):99(1980);0.507ocoridotothymuscapitatrls 0.50vopsidium guajav,a
A)
l00r'i
80 /\../o'
60
40
20
RT:2.83 Al:163 KL772 Butanoic acid

CAS#:107-92-6 MF: C4 HB 02 FW: 88 MSD LIB#:2069
CN: butanoicacid
Synonyms: butyricacid
Source:lledoukianRes.
r00
80
60
40
-----4",
20
R T:2 .85 A l: 765 Kl:113 Buten-1-ol<3-methYl'2->

CAS#: .556-82-l MF: C-5Hl0 O FW: 86 MSD LIB#: 325
CN: 2-buten-1-ol, 3-methyl-
Synonyms:dimethylallyl alcohol;prenol; 3-methylcrotylalcohol;prenyl alcohol
Source:ref. cpds.ex R. von Rudloff
RT: 2.8-5 AI: 76-5 Kl:713 Pentenol <(22)'>

CAS#: 1576-95-0 MF: C-5HlO O FW: 86 MSD LIB#: 12'50
CN: 2-penten-l -ol, (Z)'
Synonyms:none
Source:Alclrich Chem.ex Art Tucker; 1.077oSpondiascytherea,FF.I l0:37-5(1994);
0 .307oLawson i a inermis; 0.307oAng eI ica ar chang elica (seed)
t00
80
60
40
20
RT:2.88 Al:769 KI 776 Buten-2'olacetate<2'methyl-3'>

CAS#:24-509-88-4 MF: C7 Hl2 02 FW: 128 MSD LIB#: 324
CN: 3-buten-2-ol,2-methyl-,acetate
Synonyms: dimethylallylacetate( acetate
I , I ); dimethylvinylcarbinyl
Source:acetylation 2-methyl-3-(-5
of buten-2-ol, 8 I 5)
O-Ac
I
I
Appenclix
lll: MassSpectra 67
RT: 2.88 Al: 769 Kl:776 Hexen-3-ol<l->

CAS#: 4198-44-l Ml,: C6 H12 O FW: 100 MSI) LIB#: 1948
CN: l -hexen-3-ol
Synonynrs: pr<lpylvi
nylcatbinol
Sotrlce:BedoukianRes.ex J.IBrophy;6.07%,Psidiumgua.java,
. in: ArornaticPlants& Essc-rrtial
trt.221 corrstituentq, PcaceBook co., Hong Kong(1993);
4.001;hA momum p tychoI ir'tlatut tti l, | 7a/oJ asnriru rm olfic i nal e
RT: 2.90 Al:711 KI: 778 Cyctohexadiene<l-methyl-1,3->

CAS#: 1489-.56-l MF: C7 HlO FW: 94 MSI) LIB#: 2200
CN: 1.3-cyclohexaclicne,| -rrretlryl-
Synonyrns:dihyct'otol
ucne,2,3-
Source:BcdoukianRes.
r00
80
60
40
20
RT: 2.97 AI: 778 KI: 784 Methyt-2-butenal <3->

CAS#:107-8(r-8 MF':C-5H8 O FW: 84 MSD LIB#: 1640
CN:2-hutenal.3-rnctltyl-
Synonynrs:Sececi
aldehyde, crotonaldehycle<3-mct.hyl->,
prenal
Source:AldrichChcnr.
Y-'
RT:3.03 AI:78.5 KI:789 Butanediol<2,3->

CAS#:-51 3-85-9 MF: C4 H l0 02 FW: 90 MSD LIB#: 322
CN: 2.3-hutanediol
Synonyms: 2,3-butylene glycol
glycol;dimethylethylene
ffi.cinale(absolute),
Source:Flukaex Art Tucker;O.}lVoJa,sminum
l 98-5)
J. Agric.FoodChem.3 I :5-58(
,oX*
RT: 3.03 AI:78-5 KI: 789 <3-methylene'>

Cyclohexene
CAS#: 1888-90-0 MF: C7 H10 F'W:94 MSD LIB#: 2201
CN: cyclohexene,3-methylene- =::
ti
Synonyms:methylenecyclohexene,3- l:
Source:BedoukianRes. xlr
qI
ilI
,=l
::!
::i1,
.::l
,::l
,::1.
,l:l
:::
RT: 3.04 AI: 786 KI:790 Cyclopentanol

CAS#:96-41-3 MF: C5 HlO O FIM:86 MSD LIB#: 539
CN: cyclopentanol
Synonyms: hydrocyclopentane
Source:FlukaChem.ex Art Tucker
100
80
60
Appendixlll: MassSpectr.a
69
R T : 3. 05 A I : 1 8 7 K I: 7 9 0 Butanethiol, 2-nrethyl-
C A S #: 1878- 18 -8 M F : C .5H l 2 S F ' W : 104 MS D LIB #: 1702
CN: I -butancthiol, 2,metlryl-
Synonyms:none
Source:AlclriclrChem.
l/\
RT: 3.0(r Al: 788 KI: 791 Dimethyl-3-pentanone<2,4->

CAS#: .5(r-5-80-0 MF: C7 I-l14 O FW: I t4 MSD LtIt#: 2007
CiN:3-pcntanonc,2.4-clintcthyl-
Synonyrrrs:
isobutylone:isopropylkckrne;clisopropylkctone
Soulcc:Alch'ichChern.ex.lJ Brqthy
..--Jt--
tl
RT: -1.0(r AI: 788 Kl: 791 Isopentylformate

CAS#: I 10-45-2 MF: C(r Hl2 02 FW: I 16 MSD LIB#: 872
CN: | -btrtanol,3-ntcthyl-.lirrntatc
S-r,nonynrs:isoarnyllirrntate;isoantylnrethanoate;
isopentylntclhanoate
Source:Alcl'iclrChcm.
l(.xl
fJo
-l-^-"o\y'o
6(
+(
20
70 Adams:EssentialOil Componentsby GCMS
RT:3.06 AI;788 Kl : 7 9 1 Oc te n e< l ->

CAS#:I I l-66-0 MF: C8 H16 FW: 112 MSD LIB#; 1213
CN: octene (1-)
Synonyms: caprylene
Artemi.siaabsinthura,Z. Naturforsch.36c:369(198l)
Source:ref. cpd. ex E. von Rudloff; O.20Vo
CHr=cHlsHt)5cHt
RT: 3.08 AI: 790 KI: 793 Isopropyl isobutyrate

CAS#: 617-50-.5 MF: C7 Hl4 OZ FW: 130 MSD LIB#: 1621
CN: propanoicacid, 2-methyl-, l-methylethyl ester
Synonyms:isobutyricacid, isopropylester
Source:Aldrich Chern.t0.29VoPa,ssifloraedulis,p.220, in: Aromatic Plants& Essential
Constituents,FeaceBook Co., Hong Kong(1993);0'027oRuta chalapensis
Y"IA
RT:3.f0 AI:792 KI:794 Hexenal<(3E)'>

CAS#:69112-21-6 MF:C6 HlO O FW: 98 MSD LIB#: 1975
(3E)-
CN:3-hexenal,
Synonyms:
trans-3-hexenal
Source:
Bedoukian Psidiumguajava,
Res.ex JJBrophy;0.437o FFJ6:143(1991);
0.}lVo Salvia fficinalis
\4z,\.:o
AppcndixIll: MassSpcctra
7l
RT: 3. l4 Al::196 KI: 797 Hexanol <2->

CAS#: 626-93-7 MF: C6 Hl4 O FW: t02 MS D LIl l #: l 8l 4
CN: 2-hexanol
Synonyrns:sec-hexylalcolrol
Source:alcolrolsmix (2-OHs)ex K-H Kubeczka
r00
80
60
40
2A
RT:3.1.5 Al:197 KI:798 Hexenat <(3Zi)->

CAS#:6789-80-6 MF: C6 HlO O FW: 98 MSD LIB#:20-57
CN: 3-hexenal.(37,)-
Slrronynrs:
hexenal,
cis-3-
Source:Becloukian psiditt.tl
Res.;0.83%,Boueamacroplqlta,JEOR8:99(1996);0.307ct guajat,a
looi'l
80
60
RT:3.17 AI: 800 KI: 800 Hexanedione<3,4->

CAS#: 4431-51-8 MF: C6 HlO ()2 FW: I 14 MSD LIB#: 800
CN: 3.4ltexaneclione
Svnonynrs:bipropionyl
Source:Aldrich Cheut.ex Arl Tucker
72 Oil Componentsby GC/MS
Adams:F,ssential
RT:3.17 AI:800 KI: 800 Octane<n->

CAS#:I l1-65-9 MF:C8 Hl8 trW:114 MSD LIB#: 87
CN: octane
Synonyms: none
Source:ref. cpd. ex E. von Rudlolf =!
=I
,iii
ill
il
cH3(cH2)6cH3
n
'ff1
lEli
RT:3.19 Al:801 KI: 801 Hexanal

CAS#:66-25-l
CN: hexanal
*l
Synonyms:caproaldehyde
Source:ref. cpd. ex E. von Rudloff; 14.887oPyrus serotina(Asian),JEOR 4:645(1992);
3.377o Spondiascytherea; 2.977oPsidium guajava
I
I
I
RT:3.20 AI:801 KI: 802 Octene<(48)->

CAS#:14850-23-8 M F : C 8 H l 6 FW: 112 MSD LIB#: 1209
(E)-
CN:4-octene,
Svnonvms:none
=--
Appendix
III: MassSpcctla I -'\
RT:3.22 AI: 802 KI: 804 Ethyl butanoate

CAS#: 10-5-.54-4 MF: C6 Hl2 02 F'W: t 16 MSI) LIB#: 77
CN: hutanoicacicl,ethyl ester
Synonyrns:ethyl butyrate
Source:Aldrich Cherr.r.
100
Bt)
60
,10
2Q
RT: 3.2-5 AI: 804 KI: 80(r Methyl-1,4-cyclohexadiene

CAS#: 4313-57-9 MF: C7 HlO FW:94 MSD LIB#: t70-5
CN: 1,4-cyckrhexadiene, | -nrcrtlryl-
Synonynrs:clihydrotoluene<2,5->
Source:Aldrich Chelrr.
RT: 3.30 AI: 807 KI: 810 Norbornene<5-methylene-2->

C A S #: 694- 91- 7 MF : C 8 H l O F W: 106 MS D LIB #: I 183
CN: bicyclo(2.2.l')hept-2-ene. -5-merhylcnc-
Synonyms:none
Source:rel'.cpd. cx 8,. von Rudlol'l
RT: 3.31 AI: 807 KI: 811 Butyl acetate

CAS#:123-86-4 MF: C6HlzOZ FW: l16 MSD LIB#: 23
CN: aceticacid,butylester
Synonyms: butylethanoate
Source:alcoholsmix ex E. von Rudloff; 53.067aMichelia figo (flower),
p. 17,in: AromaticPlants& EssentialConstituents, PeaceBook Co., Hong Kong(1993);
t
22.24VoArta.bot rys hexape a lu s (fl ower) ; 9 .087oM andra I o ra ffi cin ar um
.A..Vorc
RT: 3.32 AI: 808 KI: 8ll Octene<(22)->

CAS#:7642-04-8 MF: C8 Hl6 FW: 112 MSD LIB#; 1207
CN:2-octene, (Z)-
Synonyms: none
Source:ref.cpd.ex E. vonRudloff
V(cH2)4-cH3
80
60
40
20
RT:3.42 AI: 814 KI: 819 Thiazole <4-methyl->

CAS#:693-95-8 MF: C4 H5 N S FW: 99 MSD LIB#: 59
4-methyl-
CN: thiazole,
Synonyms: none
Sourge:AldrichChem.
tr
AppendixIII: N,lass
Spectra 75
RT : 3. 4- 5 A l: 8 1 5 K l : 8 2 1 Oc te n e< (2 E )->
CA S #: 13389- 4 2 -9 MF : C 8 H l 6 F W: 112 MSI) LIB#: 1208
CN: 2-rrctcne. (11)-
Syrronynts: none
Source:rcf. cpd. cx E. von Rucllol'l'
4l
RT : 3. . 52 A I : 8 1 9 Kl : 8 2 6 Pyrazine <nretlryl->
CAS#: 109-08-0 MF: C-5H6 N2 FW: 94 MSD LIB#: -57
CN: pyrazine,. ntcthyl-
Syrronyrns: none
Soulce' : AlclrichChcrn.
t 00
80
60
(,,4
/.\
40
20
RT: 3.5-5 AI: tt2l Kl: 828 Methyl pentanoate

CAS#: 624-24-8 MF: C6 Hlz 02 FW: I 16 MSI) LIB#: l 106
CN: pcntanoicacicl.ntcthylester
Synonynts:ntethylvalcratc
Soulce:CTC Chcm.ex Art Tucker;0.22%: (llower),
Agtaia dttpen.eana
p.7.5,in: AronraticPlants& Esscntialconstitucnts,PcaceBook Co., Hong Kong(1993);
O.O| %:S1tartiuntjutt c:eunt
r00
80
60
40
20
RT:3.60 Al:824 KI:831 Cyclohexene<3,3,5-trimethyl'>

CAS#: 503-45-7 MF: C9 Hl6 FW: 124 MSD LIB#:2202
3,3,5-trimethyl-
CN: cyclohexene,
epsilon-
Synonyms:cyclogeraniolene,
RT: 3.62 AI: 82.5 KI: 832 Prenyl formate

CAS#:68480-28-4 MF: C6 HlO 02 Flff: I 14 MSD LIB#: 20.50
CN: 2-buten-I -ol, 3-methyl-,formate
Synonyms:none
t00-.,1l
I
80 I
60
10
20
RT: 3.66 Al:821 KI: 83-5 Isovaleric acid

CAS#: 503-74-2 MF: C5 HlO ()2 FW: 102 MS D LIB #: l 53l
CN: butanoicacid, 3-methyl-
Synonyms:isopentanoicacid; 3-methylbutanoicacid
Source:Valeriana fficinalis root oil ex Art Tucker
w
7',|
RT: 3.67 AI: 828 KI: 836 Furfural

CAS#:98-01-l MF: C5 H4 02 FW: 96 MSD LIB#: 725
CN: 2-f'urancarboxaldehyde
Synonyms:a-furole; artitrcial ant oil; 2-formylfuran
Source:Aldrich Chem.; I 2.397oTamarindusindica,JEOR 2; I 97( I 990);
19.107oAverrhoa hilimbi (fruit); 5.307oZizypltusjujuba (flruit)
c)^"
r00 96
80
60
40
RT: 3.70 AI: 830 KI: 838 Pentanol<4-methyl->

CAS#:1320-98-.5 MF: C6 Hl4 O FW: 102 MSD LIB#: 1249
CN: pentanol,4-methyl-
Synonynrs:none
Source:AldrichChem.ex Art Tucker
t00
80
60
40
20
4u b0 80 100
RT: 3.72 AI: 831 KI: 839 Pentanone<4-hydroxy-4-rnethyl-2->

CAS#:123-42-2 MF: C6 HlzC2 FIV: I t6 MSD LIB#: 17-50
CN: 2-pentanone,
4-hydroxy-4-methyl-
Synonyms: diacetone
Source:AlddchChem.
A^
78 Adams: Essential Oil Components by GC/MS
RT: 3.74 AI: 832 KI: 840 Cyclohexene <3,5,5'trimethyl'>

CAS#:933-12-0 MF: C9 H16 FW:124 MSD LIB#:2203
CN: cyclohexene,3,5,-5-trimethyl-
Synonyms 6-
: cyclogeraniolene,
RT: 3.75 Al:8t2 KI: 841 Butanoicacid <2'methyl'>

CAS#:I 16-53-0 MF: C5 Hl} OZ FW: 102 MSD LIB#: 1966
CN: butanoic acid, 2-methyl-
Synonyms:2-methylbutyric acid
Source:BedoukianRes.ex JJ BroPhY
74
100
RT: 3.76 AI: 833 KI: 841 Pentanol<3-methyl'>

CAS#:589-35-5 MF: C6 H14 O FW: 102 MSD LIB#: 1987
CN: I -pentanol,3-methyl-
$ynonyms:2-ethyl4-butanol
Source:BedoukianRes.ex JJBroPhY
._(_"
Appcndixlll: MassSpectra 79
RT: 3.81 AI: 836 KI: 844 Isopropyl butanoate

(- - A S #:638- l l- 9MF: C7 Hl4 02 F W : 130 MS D LIB #: 335
CN: br-rtanoic
acid, l-nrethylcthylesrer
Synonynrs:isopropyl[rul.yrate
Source:Aldrich Chenr.
100
Y'l-
100
RT: 3.96 AI: 844 KI: 853 Hexenol <(3E)-y

CAS#: 928-91-2 MF: C6 Hl2 O FW: 100 MSD LIB#: 806
CN: 3Jrcxen-| -ol. (lr)-
Synonynrs:trans-3-hcxenol
Strttrce:rel'.cpcl.ex E,.von Rudlofl';5.12c/o Lav'sorriainermis.p. 44, in: Aromatic
PIanls& EssentialConstituents, PeaceBook Co., Hong Kong(1993);
0.85% Psi d i tun guajava ; 0. | }ah N a rt:i sstt,\ tazetta ( absolute)
r00i,l
\\.A?'^\\v/'oH
80
60
t00
Rl': -3.99 Al: 846 Kl: 855 Hexenal<(2E)->

CAS#: 6128-26-3 MF: C6 HlO O FW: 98 MSD LIB#: 802
CN: 2- hc x enal. ( E )-
Svnonyrns: tlans-2-hexenal; lcal'alclehyde
Srrurce:Aldrich Clrem.cx Art Tucker';33.1l7aSpondiascytherea,FF'Jl0:375(1995);
| 9.5(l% Contp t otri a p ereg r irta; | 0.007oCanrelli a sh rctrsi,s
Io0
80
6t)
80 Adams: EssentialOil Cornponentsby GC/MS
RT:4.01 AI: 847 KI: 8-56 Salvene<(Zl->

CAS#:33146-70-2 MF: C9 Hl6 FW: 124 MSD LIB#: 1374
CN: 2-heptene,6-methyl-5-rnethylene-, (Z)-
Synonyms: cis-salvene
Salviafficinalis oil ex Art Tucker;0.757o
S<rurce: Salviafficinalis,.IEOR2:139(1990);
0.24VoArtemisiaabsintlrunt
100
80
60
40
20
RT:4.04 AI: 849 KI: 8.58 Ethvl isovalerate

CAS#:108-64-.5 MF: C7 H14OZ FW: 130 MSD LIB#: 67.5
CN: butanoicacid, 3-methyl-,ethyl ester
Synonyms:ethyl isopentanoate; ethyl 3-methylbutnoate
Source:ref. cpd. ex Z. Fleisher;0.867o Artemisiajudaica,IEOR2:27l(1990);
0. | 27oChantomilla r ecutit a'.0 .017o Cal amintha n ep eta
----"A-(
RT: -1.06 AI: 8.50 KI: 859 Hexenol <(32)->

CAS#: 928-96-l MF: C6 Hl2 O FW: 100 MSD LIB#: 80-5
CN: hex-3-en-l -ol, (Z)-
S1'nonyms:cis-3-hexenol;leal'alcohol
Source:ref. cpd. ex E. von RudlolT; 13.007oLawsonia inermis (flower),.IfiOR 7:42-5(199-5);
10.M%oConvallaria maialis: 10.397oNicotiana rustica (flower)
t0 0 {l
/t",9-'.-.2""
80
60
t00
r00
Appendixlll: MassSpectra 8l
RT: 4.l3 AI: 8-54 KI: ,962 Hexenol <(2E)->

C A S #: 928- 9. 5-0 Ml ,:C 6 H l 2 O F W: l (X ) MS D LIB #: 1947
C N: ( 2E ) - hc x en -l -o l
Synonyrns: hexenol,ttans-2-
S < r ur c e: B edou k i a n R e s .c x J .l B ro p7h.8
y l6 c /o S pondi al ;cytherea,FFJ
l 0:37-5(1995);
6. | 0(/t: Tltymus rt tIgori us; 3.22% Lau,.s rn i a i trcnn i,s
r00
80
60
40
20
t00
RT:4.20 AI: 8-58 Kl: 8(16 Pentenoicacid <4->

CA S #: . s 91- 80- 0 MF : C -5H g 0 2 F W: 100 MS t) LIII#: t969
CN: 4-pcntenoicacicl
Synonyllls;.l-pcntenoicacicl
Srrttrcc:BedoukianRcs.cx .l.ll3lophy;0.817..GardenirL.jo,sntinoicle.r.
.ll1OR8:24I ( 1996)
55
100
8(
fi)
40
/.\
RT: 4.20 AI: u-58 KI: 8(16 Salvene<(E)->

C A S #: . l37Ll6- ( r9 -9 Ml ,;C 9 H t6 Ij W : 124 MS I) LIB #: 137-5
CN : 2-hcptcnc,(r-nrethyl --5-rrrcthylcne-,(lJ)-
Synonylns:tlans-salvcnc
So111'cc' Solviao.fJicirtalls
oil ex Art Tucker:O.35a/aSah'iao.fticinalis,
f )cut. A1roth.'/.tg.|27:2513(I987t:0.|0%,Tlntja occiclentoli.s
tt()
60
.10
4
Y
20
Adams: Essential Oil Components by GC/MS
RT:4.22 AI: 859 KI: 867 Hexenol<(22)'>

CAS#:g28-94-g MF: C6 HlzO FW: 100 MSD LIB#: 194'5
CN: 2-hexen-l-ol,(Z)-
Synonyms:none
Sturce:BedoukianRes.ex J.IBrophy;0.l}VoLawsoniainermis,JEoR 7:425(1995);
0.017oDaphnegenkwa; 0.01VoCalaminthanep eta
RT:4.28 AI: 863 KI: 870 Hexanol<n'>

CAS#:111-27-3 MF: C6 H14O FW: 102 MSD LIB#: 1429
CN: hexan-l-ol
Synonyms:none
56
cH3(cH2)s-OH
RT: 4.28 AI: 863 KI: 870 MethYl tiglate

CAS #: 6622- 76- 0 MF :C 6 H l O 0 2 FW: l14 MS D LIB #:41
CN: 2-butenoic acid, 2-methyl-, methyl ester
Synonyms:crotonic acid, 2-methyl,methyl ester
EssentialConstituents,
Slurce: Aldrich Chem.;3.297aGardeniajasminoides,p.90, in: Aromatic Plants&
PeaceBook Co., Hong Kong(1993);0.127oChanromillarecutita
AppendixllI: MassSpectra 83
RT: 4.40 AI: 869 KI: 876 Isopentylacetate

CAS#:123-92-2 MF: C7 IIl4 02 FW: 130 MSt) LIB#: 1866
CN: I -butanol.
3-rrrethyl-.
acetate
Synonyms: banana oil, isoarnyl
acetate,
pearoil, isopentyl
ethanoate
Source: AldrichChcm.
t00
80
60
40
20
RT: 4.40 AI: 869 KI: 876 Methyl-(32)-hexen-2-one

<5->
CAS#:1669-43-8 MF; C7 H l2 O F'W:1l2 MSD LtIr,#:2025
CN: 3-lrcxen-2-one, (37,)-
-5-methyl-
Synonynrs:none
Source:Bedor-rkian
Res.ex .IJBronhv
43
RT:4.42 AI: 871 KI: 877 Hexenol<(42)->

CAS#; 928-91-6 MF: C6 Hl2 O FW: 100 MSD LIB#: 2047
CN: 4-hexcn-1 -ol, (47.)-
Synonyms:none
Source:BedoLrkian Res.
r00
fit"'rt-"-.zo'
80
60
40
20
84 Adarns:EssentialOil Componentsby GC/MS
RT: 4.42 AI: 871 Kl: 871 Methyl pentanoate<2-methyl'>

CAS#:2171-17-1 MF: C7 Hl4 02 F-W:130 MSD LIB#: 1970
CN: pentanoic methylester
acid,2-methyl-,
Synonyms:Valericacid,2-methyl,methylester
Source:BedoukianRes.ex.TJBrophy
tl
vv\o-l
I
40 60 80 100 t20
RT: 4.-50 AI: 87-5 KI: 881 Methyl butyl acetate<2->

CAS#:624-41-9 MF: C7 H14OZ FW: 130 MSD LIB#: 1088
CN: l-butanol,2-methyl,acetate
Synonyms: acetate;
sec-pentyl acetate
sec-amyl
Source:AldrichChem.;4.247o Plants& Essential
Micheliafigo,p.lT, in: Arornatic
PeaceBookCo.,Hong
Oil Constituents, Kong(1993);2.80% balansae;
Micheli.a
0.627oAnthemisnobilis
-Y^
RT:4.59 AI: 880 KI: 885 Buten-l-ol acetate<3'methyl'3->

CAS#: 5205-0'7-2 MF: C7 HI2O2 FW: 128 MSD LIB#: 320
CN: -ol,
3-buten-1 3-methyl,acetate
Synonyms:3-methyl-3-blrtenylacetate
Source:acetylationof 3-me-l -buten-l-ol(6284)
100
80
60
-,-l\..^"^"
40
20
Appendix
III: MassSpectra
85
RT:4.59 AI: 880 KI: 885 Isopropyl-2-methyl butyrate

CN: butanoicacid,2-methyl-,l-methylethyl
ester
Synonyms: none
Source:Alctjch Chern.
3r
-^.-'.\ I
RT:4.60 AI:881 KI:88-5 Altytburanoate

CAS#:2051-78-7 MF: C7 HtZor2 FW: 128 MSD LIB#: 72
CN: butanoicacid,2-propenyl
ester
Synonyms:2-propenylbutyrate
Source:AldrichChem.
y'"zo)--
RT: 4.60 AI: 881 KI: 885 Butenoicacid <3-methyl-2->

CN: 2-butenoicacid,3-methyl-
Synonyms: Crotonicacid<3-methyl->,senecioic
aci<l
Source:AldrichChem.
Adams: EssentialOil Componentsby GC/MS
86
RT:4.6-5 AI: 884 KI: 888 Ethyl pent-4-enoate

CAS#:1968-40-7MF:C7H12OZFW:l28MSDLIB#:678
acid,ethYlester
CN: 4-pentenoic
Synonyms: I -ene
4-ethoxycarbonylbut-
Source:BedoukianRes'ex Art Tucker
RT:4.66 AI: 884 KI: 888 Santene

CAS#:529-16-8 MF: C9 Hl4 FW:122 MSD LIB#: I
CN: bicycfo(2.2.1)hept-2-ene,2,3-dimethyl-
Synonyms:none
source: Abiessiberica oil ex E. von Ru<lloft;6.107oBupleurumlineo.rifolium,
5.{)\VoAbies atba;3.46VaPseudotsLtga menziesii
PakisranJ. Sci. Ind. F(es.22:325(1979);
19
100
80
60
40
40 60 bu
RT:4.68 AI: 885 KI: 889 HePtanol<4'>

CAS#:589-.5.5-9 MF: C7 Hl6 O FW: I 16 MSD LIll#: 782
CN:4-heptanol
Synonyms:dipropylcarbinol
Source:Pfaltz& Bauerex Art Tucker
OH
II
*
87
RT:4.70 AI: 886 KI: 890 Pentanal<S-hydroxy->

CAS#:4221-03-8 MF: C.5HlO ()2 FW: 102 MSD LIB#: 1246
CN: pentanal. -5-hydroxy-
Synonyrrrs:
valeraldehyde. -5Jrydroxy-
Source:ref'.cpd.ex E. von Rudlol'f'
RT:4.74 AI: 889 KI: 892 Heptanone<2->

CAS#:I 10-43-0 MF: C7 Hl4 O FW: I t4 MSI) LIB#: 786
CN:2-heptanone
Synonyms:methylamylketone;arnyl methyl ketone;pentyl methyl ketone;methyl pentyl ketone;
Source:Aldrich Chem.;0.30VoSclentostriatimrx(rhizome),.IEOR8:-59(1996);
O.| 07o Zi ng ih er ffi cinale ; 0.057oBo Icleafra g rans (leat)
cH3(cH2)4-c(=o)cHS
RT:4.80 AI: 892 KI: 894 Methyl-(3E)-hexen-2-one<S->

CAS#: l82l-29-0 MF: C7 Hl2 O FW: I t2 MSD LIII#: 2024
CN: 3-hcxen-2-{tne,-5-methyl-,(3E)-
Syronyms; none
&xrrce: BedoukianRes.ex JJ Brophy
88 Adams: EssentialC)il Componentsby GC/MS
RT:4.82 AI: 893 KI: 89.5 Heptenal <(42)->

CAS#:6728-31-0 MF : C 7 H l 2 O F W: 1 1 2 M' S DLIB #: 1985
(Z)-
CN: 4-heptenal,
Synonyms:none
Source:BedoukianRes.ex J.l Brophy
t00
80
60
40
20
RT: 4.84 AI: 894 KI: 896 Heptanol <2->

CAS#:543-49-1 MF : C 7 H 1 6 0 FW: I 16 MSDLIB#: l8l-5
CN: 2-heptanol
Synonyrns:sec-heptylalcohol
Source:alcoholsmix (2-OHs) ex K-H Kubeczka;0.807oCurcumaaromatica,
JEOR 8:633(1996):0.1\VoLawsoniainermis (flower); 0.607oAJiamomttntmelegueta
t0 0 .._r-.._,-Y""
80
60
40
20
RT: 4.86 AI: 896 KI: 897 Pyrazine <2-methoxy->

CAS#: 3149-28-8 MF: C5 H6 N2 O FW: I l0 MSD LIB#:58
CN: pyrazine,methoxy-
Synonyms:none
(:)-"-
AppendixllI: MassSlrcctra
89
RT: 4.9 | Al: 898 KI: 899 propyl butanoate

CAS#; 10-5-66-8 MF: C7 Ht1.o2 FW: t30 MSD LIB#: 336
CN: butanoicacid,propyl ester
Synonyrns:propyl lrutryatc;butyricacid.propyl ester
Source:Aldrich Chern.
r00
80
60 -^-Ao*
-10
20
RT: 4.93 AI: 900 KI: 900 Nonane <n->

C A S #: lll- 81- 2 MF ' :C 9 H 2 0 F W: t28 MS D LIII#: u8
CN: nonane
Svnonynrs: none
Source:rel'.cpcl.ex H. von Rucllol'l';42.00vopittosportutttobira, p.
-57.in:
Prog.in h,ss.Oil Rcsearch, E,.-.LBrunkeIicl.,Gruyterpubl., Ucrli;(t9g6);
9.707c H yp er i cuttt p erfo ratunt; | .ZBVoCo r i antl nun sat ir.,
unt
43
cH3(cH2)7cH3
I 6U I(D 120
RT : - 1. 96 A I : 9 0 1 KI:9 0 t Eth y l p e n ta n oate

CAS#: 539-82-2 MF: C7 Hl4 02 FW: t30 MSD LIB#: 78
CN: pentan<tic acicl.ethyl ester
S-rnon)'nts:ethyl valerratc
Srrulss'Afdriclrchem.; 1.38% P1,rus .terotitxtt (Asian),JEoR zl;64-5(1992);
O-10%Tapetesninuta.
r00
80
60 -")(-
RT:4.97 AI; 901 KI:901 Propanal<3-methylthio'>

CAS#;3268-49-3 MF: C4 H8 OS FW: 104 MSD LIB#: 1709
CN: | -propanal,
3-(methylthio)-
Synonyms: thiapentanal
methional, <4->
Source:AldrichChem.
?5"/
RT: 4.98 AI: 901 Kl:902 Heptanal

CAS#: lll-71-7 MF: C7 Hl4 O FIil: l14 MSD LIB#: 779
CN: heptanal
Synonyms:enanthaldehyde; enanthole;oennathal
Source:Pfaltz & Bauer ex Art Tucker; 11.077oMichelia champaca,
p. 16, in: Aromatic Plants& EssentialConstituents,PeaceBook Co., Hong Kong(1993);
14.857oNarcissustazettai 1.80%Tilia cordata
100
*o
40
20
RT: 5.03 AI: 903 KI: 904 Ethoxyethyl acetate<2'>

CAS#:lll-15-9 MF:C6Hl2()3 FW:132 MSDLIB#:1749
CN: 2-ethoxyethyl
acetate
Synonyms:cellusolve ethylglycolacetate
acetate,
Source:BakerChem,
Y"\-^oA
Appcrrclix
III: MassSpectra 9l
RT: -5.05 Al: 904 KI: 90-5 Hydroxybrrtanoicacid lactone<4->

CAS#: 96-48-0 MF: C4 H6 02 FW: 86 MSD LIB#: t-596
CN: 2(31-l dihydro-
)-lin'an()nc.
Syttonynts
: 4-butanolicler,
butyryl lactone,butyr.ic,
acid Iactonc
Soulcc:Alch'ichChern.
8(
fi
40
20
"5
RT: -5.12 AI: 90(r Kl: 908 Santolinatriene
C A S #: 2153- 66 -4 MF : C l 0 H l 6 F W : 136 MSD LItl#: 226
CN: l .-l-hcxaclicnc. 3-ethcnyl-2.5-cli nrcthvl-
Svnonytrrs: rrone
Strttrce:Artetni.siatridentata,SLC. Utah" RP Adarns#5511',1.40c/c, Santolinar:honnecvl.tari.sstts,
Sci. Plrarrrr.
55:2(:7(|981 );0.407oOrmcnisnti.uta:0.361h Artemisiat,e,ttita
|(x)
80
Yl
60
-t0 \-V-
l0
RT : - 5. 1. 1 A I : 9 0 7 KI:9 0 9 B u ty l p ro p a n oate
C . \ S #: 590- 01- 2 MF: C7 Hl4 02 F W: 130 MS I) LIU #: 33 t
CN: propanoicacicl,butyl estcr
S r nt ' r nY ntUN
s: l9l4
Source:Af dlich Chern.: 0.1J aL;Ci t rus sinensi.s,.IEOR7 : 10-5(199-5 );
(t.() | (ic ln vencler artg ust ifo I i a; 0.{\| (k Sp art i un. lul cew n
.j
/Yo-\/'-\//
92 Adams: EssentialOil Comnonentsbv GC/MS
RT: -5.14 AI:907 KI:909 Hexadienal<(28'48)->

CAS#: 142-83-6 MF:C6 H8 O FW:96 MSDLIB#:798
CN: 2,4-hexadienal,(E,E)-
Synonyms: sorbaldehyde ; tr ans-2,trans-4-hexadienal
"w
RT:5.18 AI: 908 KI: 911 Isobutylisobutyrate

CAS#:97-85-8 MF:C8Hl6(o2 FW: 144 MSDLIB#: 1615
CN: propanoicacid, 2-methyl-,2-methylpt'opylester
Synonyms:isobutyricacid, isobutylester
Source:Aldrich Chem.;26.897oArtabotrys hexapetalus,p,21 , in: Aromatic Plants& Essential
Constituents,PeaceBook Co., Hong Kong(1993); l4.0O7oEriocephaluspunctualis;
| 2.707oAnthemisnob il i s
,---"yJ--
RT:5.18 AI: 908 KI: 9l I Pyrazine<2,5-dimethyl->

CAS#:123-32-0 MF: C6 H8 N2 FW: 108 MSD LIB#: 6l
CN: pyrazine,2,5-dimethyl-
Synonyms; none
Source:AldrichChem.
.(.^^y
AppcndixIll: MassSpecrla 93
RT : - 5. 19 A l: 9 0 9 KI:9 1 2 Ac e ty l fu ra n< 2->

CAS#: ll92-(t2-1 MF: C6 H6 02 FW: I t0 MSD LIII#: 47
CN: cthanone,I -(2-l'uranyl)-
Synonyurs: a-acetylluran,
2-turyl rncthylkctone
Sourcc:Af drich Cherr.;0.J2VoTamarindu:;indi.ca..ftiOR 2:l9j(99{iD:
0.531, Daplmegenkwa;0.|\cl, Garclenict jastnirnides
dl-"
RT: .5.20 AI: 909 Kl: L)12 Tiglic acid

CAS#; 80--59-l MF':C.5H8 (]2 FW: 100 MSI) LIII#: 2061
CIN:2-butenoicacicl.2-rnethyl-(2E)-
Synonyrns:crotonicacicl.trans-2-mcthyl-;
ccvaclicacid
Soulcc:BcckrukianRes.
RT: -5.2| AI: 909 KI: 9 | 2 Pyrazine <2,6-dinrethyl->

C A S #: 108- . 50 -9 MF : C 6 I{ 8 N 2 F W: 108 MS D LtB #: 62
CN; pyrazine.2.6-clirnethyl-
Synonynts:n<lnc
Sourcc:Aldlich Chern.
RT: -5.2.5 AI: 911 Kl:914 AmYIacetate

CAS#:628-63-7 MF: C7 Hl4 02 FW: 130 MSD LIB#: 128
CN: aceticacid,pentYlester
Synonyms: pentylacetatel pearoil
bananaoil; birnenoel;
Source:localdry cleanerstore
CHs(cH2)4-o-Ac
RT: 5.29 Al:912 KI: 916 Hexadienol<(28,48)'>

CAS#: 17t02-64-6 MF: C6 HlO O FW: 98 MSD LIB#: 2098
-ol, (2F,4ts')'
CN: 2,4-hexadien-I
Synonyms:sorbicalcohol;sorbinolltrans-trans-2,4-hexadienol
z v
RT: -5.29 Al:912 KI: 916 Pyrazine<2-ethyl'>

CAS#:13925-00-3 MF: C6 H8 N2 FW: 108 MSD LIB#:-54
CN: pyrazine,ethyl-
Synonyms: ethylpyrazine
Source:AldrichChem.
r-F-
Appendixlll: Mass Specrra
v.\
RT: -5.29 Ar: 912 KI: 9l6 Tetrahydrofuran<2,5-criethenyr-2-nrethyr->

CAS#:l0,ll88-15-0 MF: C9 Hl4 O FW: 138 MSt)LtB#:228
CN: lirran.2,5-diethenylrctrahydro-2-methyl-
Synonyms: none
Sr)1r1'cs;
Artenti,sia
trident(lto,SLC.Utah,Rp Aclams
#-5-577
100
80
60
'ts
40
20
RT:-s..32 Af:913 KI:917 Anisole

C.\S#:100-66-3 MF: C7 H8 O FW: t08 MS D LIII#: l 7l
CN: benzene.ntetlroxy-
Sr.non)'ms:phenyl rrethyl ctlrer-;phenoxymcthane
Source:Aldrich Chent.;0.60Vc, Trrbetmelanr,t,rltonrnr, .IEOR I :2gl ( l9g9):
{t.26%,4c1
ui Ia r i a ag al Iaclto ; O.Z27oGa rd enia i asnthto ide,g
d
ou u0 100
RT: -5.-12 AI: 9 | 3 KI 917 Hexenyl formate <(32)->

C.\.S#:33167-73-1 MF': C7 Hl2 02 FW: t28 MSD LIB#: t.5u6
Clti: -l-hexen-I-ol. fbrrnate.(Z)-
Sr non\,nrs: cis-3-hexenyl forrrate
S.'urce:Af drich Chem.; |.207oViola odorota.phytochent.3l:-571(l()92):
(,t-ll'i Citnts retir:ulatal0.1l% Hya<:inthns
orientcLli,s
acetate
RT: 5.35 AI: 914 KI: 919 Buten'l-o|,3'methyl'2-'
CAS#:l19l-16-8 MF: C7 HIzOZ FW: 128 MSDLIB#: 1712
acetate
I -ol, 3-methyl-,
CN: 2-buten-
Synonyms: prenylacetate, acetate
dimethylallyl
Source:AldrichChem.
100
80
60
40
20
RT: 5.38 AI: 91-5 KI: 920 Pyrazine<2,3'dimethyl->

CAS#:5910-89-4 MF:C6 H8 N2 FW: 108 MSD LIB#: 60
CN: pyrazine,2,3-dimethyl-
Synonyms: none
Source:AldrichChem.
RT: 5.46 AI: 918 KI:923 Heptanone<2-methyl-4'>

CAS#:626-33-5 MF: C8 H16 O trW: 128 MSD LIB#:783
CN: 4-heptanone, 2-methyl-
Synonyms: isobutylpropylketone
Source:ref. cpd.ex CA McDaniel
- lr -
)
l
l
!
Appendixlll: MassSpectra 97
RT: -5.46 AI: 918 Kl 923 Heptanone <3-methyl-4-> (impure)

CN: 4-heptanonc.3-nrethyl-
Synonyms:none
Source:ref. cpcl.ex CA Mcf)aniel
o
tl
+
I
40 60 80 100 120
RT: 5.46 AI: 918 KI:923 Hexenylformate<(28)->

CAS#:.53398-78-0 MF: C7 Hl2 02 FW: 128 MSD LIB#: 1984
CN: 2-hcxen- (28)-
l -ol, tirrnrate,
Synonynrs:
trans-2-hexenyl fcrrmtrte
Source:Bedoukian Res.ex.I.IBrophy
r00
80
60
40
20
RT: .5.46 AI: 918 Kl:923 Isocitronellene

CAS#: 85006-04-8 MF: Cl0 Hl8 FW: 138 MSD LIB#:861
CN: 1,6-octadiene,
5,7-dimethyl-
Synonyms:none
RT:.5.48 AI:919 Kl:924 Acetonylacetone

CAS#:I l0-13-4 MF: C6 HlO ()2 FW: 114 MSD LIB#: 8
CN: 2,-5-hexanedione
Synonyms: none ,
Source:Fluka Chem,ex Art Tucker
43
RT: 5.53 AI:921 Kl:926 Ethyl 2'methyl-4'pentenoate

CAS#: 53399-81-8 MF: C8 H14 OZ FW: 142 MSD LIB#: 2147
CN: 4-pentenoicacid, 2-methyl-,ethyl ester
Synonyms:none
4I
//\o)'\/\/
RT: -5.53 AI:921 KI:926 Tricyclene

CAS#:508-32-7 MF: C10Hl6 FW: 136 MSD LtB#: 913
1,7,7-trimethyl-
CN: tricycIo(2.2.| .02.6)heptane,
Synonyms:cyclone
Source:luniperus monticolaf . compactaleaf oil, RP Adams #2580;
57.907oCordiq cylindrostachya,JEOR 2:209(1990);6.767oTsugacanadensis(conifer);
2.91VoAnaphalis marg aritacea
r00
80
60
40
20
RT: -5.-54 Al 921 KI:927 Methyl hexanoate

CAS#: l0(t-70-7 MF: C7 Hl4 02 FW: 130 MSD LIB#: 1099
CN: lrexanoicacid,nrethylester
Synonynrs: methylcaproatc
Af drich Chem.; 6.04% Cha ewnneles,speci oso..IEOR(r:8 1( 1994);
Srrrrrce:
2.00VcMagtolia grortdilloral 1.03/t:Michelia al.ba(tlower absolute)
40 60 80 100 120
RT: -5.59 AI: 923 KI: 929 Pentenoicacid <2-methyl-4->

CA S #: 1575- 14 -2 M F : C 6 H l O ()2 F W: I 14 MS D LIB #: 1968
CN: 4-pentenoicacid,2-rlethyl-
Synt'rnyrns:
mcthyl-zl-pcntenoic ac:id.2-
Source:Be,doukianRes.ex .I.IIlrophy
RT: -5.61 Al:923 Kl:929 Artenrisiatriene

CAS#:18383-70-5 MF-:ClOI{16 FW: t3(r MSI)LIB#:213
CN: 1,3.6-heptatriene,
2,5,-5-trirnethyl-,(tr)-
Syn<lnynrs: nonc
S<rurce: Artetnisictlter,sr-iaoil cx P. Weyerstahl;|.4011Atteuril;iaabaen.ri.s,
p. 272, in: ArornaticPlants& Irssentialconstituents,Peacellook Co., Hong Kong(1993);
0.64(ft,Artetni.siaocL'iclerftali,s-siclmttnen.sis:0.15(k;
Artemisia iudoica
I 00
80
100 EssentialOil Componentsby GC/MS
RT: .5.62 AI:924 KI: 930 Thujene <a->

CAS#: 2867-05-2 MF: Cl0 Hl6 FW: 136 MSDLIB#:911
CN: bicyclo(3.1.0)hex-2-ene, 2-methyl--5-(1 -methylethyl)-
Synonyms:origanene
Source:Jtmiperusmonticolaf. compacta.leafoil, RP Adams #2-580;
6 | .36VoB oswellia serrata, FFJ 2:99( I 987); 8.237oOcimum g ratissimum;
7 .75VoCinnatnomutnburnrannii
I
o
A
40 60 80
RT: 5.63 Al:924 KI: 930 Cumene

CAS#:98-82-8 MF: C9 H12 FW: 120 MSD LIB#: 502
CN: benzene,( I -methylethyl)-
Synonyms:cumol; 2-phenylpropane; isopropylbenzene
Source:Hopkins-Williarns, UK ex Keith Harkiss;0.727oThuia occidentali,s,
J. Wood Chem. Technol.8:-561(1988);0.017o Apium grat'eolens
O
-f--
CAS#:6137- ll- 7 MF : C 8 H 1 6 O FW: 128 MSDLIR#:20l2

CN: 3-heptanone, 4-methyl-
Synonyms:none
Source:Aldrich Chem.ex J.IBrophy
Appendix III: Mass Spectla
l0l
RT: 5.71 AI: 921 KI: 933 Hepten-2-one<(38)->

CAS#:5609-09-6 MF: C7 Hl2 O FW: 112 MSD LIB#: 2019
CN: 3-hepten-2-one.
(38)-
Synonyms: trans-3-hepten-2-one
Source:Bedoukian Res.ex JJ Brophy
80
60
40
W
20
RT: -5.71 AI:921 KI: 933 Pentanoic acid <2-methvl->

CAS#:97-61-0 MF; C6 H1202 FrM:I 16 MSD LIB#: 1971
CN: pentanoicacid, 2-methyl-
Synonyms:Valeric acid, 2-nrethyl
Source:BedoukianRes.ex JJ Brophy
RT: 5.72 AI:927 KI: 934 Methyt-(3E)-hexenoate

CAS#:13894-61-6 MF: C7 Hlz02 FW: t28 MSD LIB#: 2046
CN: 3-hexenoic
acid,methylester,(3E)-
Synonyms:none
Source:Bedoukian
Res.
4l
r00
80
68 74
60
40
t02 Adams: EssentialOil Componentsby GC/MS
RT:-5.7.5AI:928 KI:93.5 Thiazole <4,5-dimethyl->

CAS#:3.581-91-7 MF:C5 H7 N S FW: I l3 MSD LIB#: 63
4,5-dimethyl-
CN: thiazole,
Synonyms: none
Source:AldrichChem.
q
RT: 5.78 Al:929 KI: 936 Ethyl tiglate
CAS#:5837-78--5 MF:C7Hlz02 F]il: 128 MSD LIB#: 1960
acid,2-methyl-,ethylester,(E)-
CN: 2-butenoic
Synonyms:tiglic acid, ethyl ester;cortonic acid, 2-methyl-,ethyl ester'(E)-
Source:BedoukianRes.ex J.IBrophy; 0.087oGardeniaiasminoides,
p. 90, in: Aromatic Plants& EssentialConstituents,PeaceBook Co', Hong Kong(1993);
0.017oSpondiascytherea
100
80 o\,/
60
40
RT: 5.80 AI: 930 Kl 937 Citronellene<tetrahydro->

CAS#:20-51-30-l MF: Cl0 H22 FW: 142 MSD LIB#:454
CN: octane,2,6-dimethyl-
Synonyms: none
Source:FlukaChem.
I
ar
)
IE
AppcntlixIll: N4ass
Spectra
103
RT: -5.130 AI: 930 KI: 937 Oxazole<2_ethyl_4,5-clinrethyl_>

CA S #: . 53833 -3 0 -0 M F : C 7 H t I N O F W: 12.5 MS t) LIB #: t229
CN: 2-cthyl-4.-5-clirrrctlryl
oxazulc
Synonyrtrs: nonc
Serul'ce;BccloukiarrRcs.ex Art Tucker
y)' I
RT: -5.81 AI: 930 KI: 937 Ethyl 2-rnettrylpentanoate

c A S #: 392- 5- 5 -3 2 -8 M F : C 8 H r6 .u a F W: t.14 MS I) LIB #: 2r48
CN: ltcntanoicacricl, 2-nrcthyl-.clhyl ester
Synony11l5; cthyl 2-nrethylvalerate
Soulcs' Bcckrukian Res.
l ( x)
80 ll
60 ,-\.)\a-\r.
i0 I
20
R T : - 5. 82 A I : 9 3 1 KI: 9 3 g A l l y l i s o v a l e rate
C,,\S#:283.5-39-,1 MF-:C8 hltl 62 F.W:142 MSI) LIII#: I t2
CN: bulartoicacicl.3-rnethyl-,2_pr.opernyl estcr
Sl n.nynrs:allyl 3-ntethylbutan.ate: 2_propenyt 3_r'ethylbutanoate
So111sg' AlclrichChcrl.
l 0(
80
N.Y\.
60
-10
nt
1l
l
104 by GC/MS
RT: -5.83 AI: 931 KI: 938 Cyclopentene<3,5-dimethylene'l'4,4-trimethyl->

CAS#:000-00-0 MF: C10H14 FW: 134 MSD LIB#: 2091
<3,5-dimethylene-
CN: cyclopentene 1,4,4-trimethyl->
Synonyms: none
Source:Lqvandulaluisierioil ex NicolasBaldovini
CAS#: 106928-44-3 MF: C7 HlO O FW: 110 MSD LIB#: I178

-en-2-ol, ( 1R-endo)-
CN : bi cyclo(2.2.1)hept-5
Synonyms:none
Source:ref. cpd. ex E. von Rudlotf
0r.'
RT: 5.85 AI:932 KI: 939 Pinene<c->
CAS#:80-56-8 MF: Cl0 Hl6 FW: 136 MSDLIB#:912
CN: bicycfo(3. I . I )hept-3-ene,2,6,6-trimethyl-
Synonyms:2-pinene
Source:Juniperushtcayanaleaf oil, RP Adams #2863;88.137oPinus kesiya,
The ChemicalCompositionof Pinus kesiya oil from Yunnan,.I-L Lo, in: Flav. & Frag.:
A World Perspective,Lawrence,etal.,(eds.),Proc. 1OthIntl. Cong. Ess' Oils', Wash' DC(1996);
87.407oSequoiadendron g i ganteum; 7 8.617oP i stqcia Ienticus
-
AppendixIII: MassSpectra t 05
RT: -5.89 AI: 933 KI: 940 Pentanoicacid <4-methyl->

CAS#: 646-07-l MF: C6 Hl2 02 FW: I 16 MSD LIB#: 1986
CN: pcntanoicacicl,4-rncthyl-
Synonyms:valericacid,4-rnethyl-:isocaproicacid
Source:BecloukianRes.ex.l.fBrophy
100
80
60
40
Y^-t"
20
RT:-5.9-5 AI: 935 KI: 943 Cyclohexanol<3-rnethyl->

CA S #: . 591- 23 -l MF: C7 H14 O F - W :l 14 MS D LIl l #:2011
CN: cyclohexanol, 3-mcthyl-
Synonynrs: none
Source:Fluka Chem.ex JJ Brorrlry
100
80 ./-"-'./o'
60
40
V
CA S #:. 54l- 8- 5 -5 MF: C8 H l6 o FW: 128 MSD LIB#: 78-5
CN: heptanone, -5-methyl-3-
Synonyrrrs: 3-rnethylbutylethyl ketone
Sourcc:Aldlich Chem.
A1
r00
80
6(
4(
20
RT: 6.00 AI:937 Kl:944 Fruitaleur

acid,2-methyl-,
CN: 3-pentenoic ethylester
Synonyms:ethyl2-methyl-3-pentenoate
/\o
RT: 6.0-5 AI: 939 KI: 946 Norbornen-2-ol<exo-S'>

CAS#:71030-14-3 MF:C7Hl0O FW:110 MSDLIB#:ll8l
( I S-exo)-
CN: bicyclo(2,2,| )hept-5-en-2-<>1,
Synonyms; none
Source:ref. cpd.ex E. von Rudloff
o--
RT: 6.05 AI: 939 Kl:946 Valeric acid <3-methyl'>
CAS#: 105-43-l MF: C6 H12O2 FW: I 16 MSD LIB#: 1-532
CN: pentanoicacid, 3-methyl-
Synonyms:3-methylpentanoicacid
Source:acetoxyhexane,2-ex JJ Brophy
Appendixlll: I\4ass
Spectra to7
RT: 6. l0 Al: 941 KI: 948 Acetoxyhexane<2->

CA S #:59. 53- 4 9 -l M F : C 8 H l 6 ()2 F W : 144 MS D LIB #: 2016
CN: 2hexanol. acetate
Synonyrrrs:hcx-2ylethanoate
Sou'cc: acetoxyhexan e, 2- ex.I.l Brophy
80
60
40
)lr
RT: (r.l0 AI: 9,Xl Kl: 948 Valerolactone<T->

CAS#: 108-29-2 MF: C.5H8 02 FW: 100 MSD LIB#: 1690
CN: 2(3H)-luranone,dihydro-5-nrethyl-
Synonyms:y-pentalactone
1001,1
80
60
40
120
RT: 6. | 5 Al:912 KI: 950 Citronellene<p->

CAS#: 2436-90-0 MF: Cl0 Hl8 FW: 138 MSD LII]#: 453
CN: 1.6-octadiene,
3,7-dirnethyl-
Synonyrns:dihydro myrcene
Source:F'lukaChem.ex K. Harkiss
60
40
20
tffi Adams: EssentialOil Comoonentsbv GC/MS
RT: 6.21 AI: 94-5 Kl:952 Cyclohexanone<3-methyl-> (impure)

CAS#:591-24-2 MF: C7 H12O FW: I l2 MSDLIB#:532
CN: cyctohexanone,3-methyl-
Synonyms:none
Source:ref. cpd. ex Art Tucker
100
80
60
40
RT: 6.21 AI: 945 KI:952 Methyl pent-2-enolide <4-> (impure)

CN: 2(5H)-furanone,
-5,5-dinrethyl-
Synonyms:4,4-dimethyl-2-butenolide
Source:Armoisea davanone oil ex GuyCollirr
100
80
60
40
20
RT:6.22 AI: 94-5 KI: 9-52 Fenchene<o->

CAS#:471-84-1 MF: ClO Hl6 FW: 136 MSD LIB#: 895
CN: bicycfo(2,2,l)heptane,7,7-dimethyl-2-methylene-
Synonyms:none
Source:Juniperusangosturanleaf oil, RP Adams #2665; 4.107oJuniperusintermedia,
FFJ l0:25(1995);3.70Vo Artemisiavelotionrm;3.307oJunipenr.s
communis
AppcndixIII: N{assSpcctr.a
r09
RT: (r.2(r AI: 946 KI: 9-54 Canrphelre

CAS#:19-92-5 MF:Cl0 Hl6 FW: 136 MSDLtB#:914
CIN:2.2-di mcthyl-3-nrcthylencbicyckr-(2.2.I )hcptane
Synonylns:none
S<ru'ce'
Jurtiperusluc'ay,x6ex RP Adants#2863;co'''on in conil'ers:
7o.50%,Ettcalt'ptus kirtonicuta,.f
lloR 7:215(1995);32.05(/o
valericurao.ffici1ctlis:
29.97% Ab ies,si biri ca
t(x) 93
80
60
4(
RT: (r.27 Al:941 KI: 9-54 Heptenal <(2E)->

C A S #: 18829- . 5 5 --5 MF : C 7 H l 2 0 F -W:I l 2 MS I) LIB #: 1942
C N: 2- hc pt c r r a(H
l , )-
Synonynrs: butylaclolein,3-; hcptanal.tt.ans-2-
Sourcc:BctloukianRes.cx J.fBrophy
l(x)
u0
60
40
20
RT : ( r . 28 A I : 9 4 1 KI:9 .5 4 Heptenol <(32)->

C A S #: 1708- 8l -2 M l -: C 7 H l 4 () F W ; l 14 MSD LIB#: 2076
C N: . l- hc P t c rl-r -o l . (.l Z )-
Synonynts:nonc
t00
,OG
80
60
40
20
ll0 Adams: EssentialOil Componentsby GC/MS
RT: 6.34 AI:949 KI: 956 Ethyl 3-methylpentanoate

CN: pentanoic ethylester
acid,3-methyl-,
Synonyms:ethyl3-methylvalerate
100
80
60 --AA.A
40
20
RT:6.35 AI: 950 KI: 9-57 GlYcerol

CAS#:56-81-5 MF: C3 H8 ()3 FW: 92 MSD LIB#: 1904
CN: 1,2,3-propanetriol
Synonyms: glycerin,glycylalcohol
Source:SismaChem.
RT: 6.35 AI: 950 KI: 957 Mercaptopropanoic acid <2'>

CAS#:79-42-5 MF: C3 H6OZ S F\M:106 MSD LIB#: 165l
CN: 2-mercaptopropanoic acid
Synonyms: thiolacticacid,propionicacid<2-mercapto->
Source:AldrichChem.
-
Appcndixlll: MassSpectra
lll
RT : 6. 38 A l: 9 -5 1 KI: 9 5 8 Thiazole <2-etlroxy->

CA S #: l- 5679-1 9 -3 M F : C 5 H7 N O S FW: 129 MSI) LIB#: .5.5
CN: thiazole,2-cthoxy,
Synonyrns: none
Sour"ce: AlclrichChenr.
100
Y)
RT:(r.43 AI:9-52 Kl:960 Benzaldehyde
CAS#:l(t0-52-7 MF: C7 H6 O FW: 106 MSDLIB#:310
CN: bcnzaldchyde
Svnonynrs: artil'icialhlackherry:artillcialalmoncl
.Sourcc: artiflcialhlackhelryllavor,LorannInc.; 95.00%,prunrr,scrulcis, p. (tl .
in: Dic nntttel'liclren
und kuenstilchcnArcrrne n. Dr. Alll'eclVerlagPubl.,He.iclelherg(
1982);
95.007oPnutus arnteniaca(kernel); |0.07a/(, Derdntbium chrysatoxumfilower-)
,Y
ra>
\2
RT: (r.4'1 AI: 9.53 Kl: 960 Thuja-2,4(10)-diene

CAS#; 36262-09-6 MF-:Cl0 H14 FW: t34 MSD LIB#: 361
CN: bicyclo(3.| .0)hcx-2-cnc,
4-mcthylenc-l-( l-rnetlrylcthyl)-
Svnonyrns: none
Srrurce'can'ot ex A chaintettu;0.107apinussibirica.
seecloil ex Ne-stle
.fBoR 8:549(199(r); 0.30%Junipentsri.qida(Kolca): 0.05%Juniperusrigicln(.Iapan)
112 Adams: EssentialOil Comoonentsbv GC/MS
RT: 6.49 Al: 9-54 Kl:962 Cyclohexyl formate

CAS#: 4?51-54-6 MF: C7 H12 02 FW: 128 MSD LIB#: 533
CN: formic acid, cyclohexylester
Synonyrns:cyclohexanolforrnate
Source:BedoukianRes.ex Art Tucker
67
100
80
60
4{)
RT: 6.56 AI: 957 KI:964 Furfural <S-methvl->

CAS#: 620-02-0 MF: C6 H6 Oz FW: I l0 MSD LIB#: 1460
CN: 2-furancarboxaldehyde, -5-methyl-
Synonyms: -5-rrethyl-2-lurl-uraldehyde
Source:distilled comm. tarnalind(Laxmi Brand, India) RP Adams #6440
xF"
RT: 6.58 AI: 958 KI: 965 Heptan-2-ol<6-methyl->
CAS#:4730-22-'l MF: C8 H18O FW: 130 MSD LIB#: 778
CN: 2-heptanol,
6-methyl-
Synonyms: none
Source:ref.cpd.ex P. Weyerstahl
.:::
,=:
,=:1
=!!
=:!
=!:
,r!!
=!:
:l:
n:
::::
=!:
:::i
E
=
Appendix III: Mass Spectra l13
RT: 6.-58 AI: 9-58 KI: 96-5 Hepten-l-ol<(2E)->

CAS#:33467-16-4 MF: C7 Hl4 O FW: I 14 MSD LIB#: t93-5
CN: 2-hepten-l
-ol,(E)-
Synonyms: none
Source:Bedoukian Chem.ex.I.T
Brophy
100
80
Wo,
60
40
20
RT: 6.59 AI: 958 KI: 965 Octen-S-yne

<(2-methyt-(3E)->
CAS#:850309-57-8 MF: C9 Hl4 FW:122 MSDLIB#: 1909
CN: 3-octen--5-yne,
2-methyl-,(3E)-
Synonyms:none
Source:Lom&tiumdissectumroot oil ex Vasu Dev
RT: 6.63 AI: 959 KI: 966 Heptanol <n->

C A S #: lll- 1A - 6 MF : C 7 H l 6 O F W: I l 6 MSD LIB#: 33
CN: | -heptanol
Synonyms:gentanol,enanthicalcohol
Source:alcoholsmix ex E. von Rudloff
4l
cH3(cH2)6-oH
lt4 Adams: Essential Oil Components by GC/MS
RT: 6.63 AI:9-59 KI: 966 Hepten'l'ol <(42)'>

CAS#:619l-71-5 MF: C7 Hl4 O FW: 114 MSD LIB#: 787
-l -ol,(Z)-
CN: 4-hepten
Synonyms:cis-hept-4-enol
41
100 woH
80
60
40
20
RT: 6.64 AI: 960 KI: 966 Isoamylpropionate

CAS#:10-5-68-0 MF: C8 Hl6 02 FW: 144 MSD LIB#: 1606
CN: propionicacid,isopentylester
Synonyms:isoamylpropionate,isopentylpropanoate
Source:AldrichChem.
Ir
RT: 6.67 AI: 961 Kl:967 Verbenene

CAS#:4080-46-0 MF: ClO H14 FW: 134 MSD LIB#: 906
CN: bicyclo(3.1. 1)hept-2-ene,6,6-dimethyl-4-methylene-
Synonyms:2( I 0),3-pinadiene
Source:Iuniperusflaccida vat. martinezii leaf oil, RP Adams #5974;
Identified bv R. Larent, Robertet, France
Appcnclix
III: MassSpcctra I t-5
RT: 6.84 A1:961 Kl: 973 Hexanoicacid

CA S #: 142- 62-l MF :C 6 H 1 2 O 2 F W: l 16 MSI) LIB#: 2067
CN: lrcxanoicacid
Synonyrns: caploicacid
Srrurcc:BecfoukianRcs.;(r.l7qo Zinipltus.iu.iuboliuit, JIIOR 8:323(1996);
3.35% Passillorq edulis h'uit 2.10(n)P,Eicliumguajava I'ruit
RT: 6.8-5 Al:967 Kl: 97.1 Pyrazine <2-metlroxy-3-methyl->

CAS#: 2847-30--s MF': C6 H8 N2 O FW: 124 MSD LIU#: (16
CN : pyrazinc.2-rlcthoxy-3-mct
hyl-
S y nony r r r none
s:
Sourcc:AlchichCherrr.
lrY"'"
\,/\
RT: 6.90 AI: 969 KI: 97.5 Nlethvl 2-furoate

CA S #:( r ll- 13- 2 M F :C 6 H 6 0 3 FW: 126 MSD l-lll#: 20(16
CN: 2-lirlancalboxylicacicl,mcthylostcr
Synonynts:l.rylontucic
acridrrrethylestcr;Iuroic acicl,2-
Sourcc:IJcdoukianRes.
I00
tl
80 tl
fi) 1o\Ao,"
40
\_/
20
l16 Adams: EssentialOil Componentsby GC/MS
RT: 6.90 AI: 969 KI: 97-5 Propanol <3-methyltltio->

CAS#: 505- 10- 2 MF : C 4 H 1 0 O S FW: 106 MS D LIB #: 1708
CN: I -propanol,3-(methylthio)-
Synonyms:methionol
RT: 6.91 AI: 969 KI: 97-5 Pinane<trans'>

CAS#:33626-25-4 MF: Cl0 Hl8 F'\il:138 MSD LIB#: 1296
I u,2c,5a)-
2,6,6-timethyl-,(
CN: bicyclo(3.I . | )heptane,
Synonyms: none
Source:SCMChems. ex H. Hills
5
140
RT: 6.91 AI:969 Kl975 Sabinene

CAS#:3387- 41- 5 MF : C l 0 H l 6 F W: 1 3 6 MS D LIB #: 304
CN: bicyclo(3.I .0)hexane,4-methylene-I -( I -methylethyl)-
Synonyms:4( I O)-thu.iene
Source:<listillationof black pepper, RP Adams#5448;82.907oJuni.perussabina,
.I. Chromatog.396:416(1987);62.367oLitsea cubeba(flower); 61.917oCitrus paradi.si
tl
o
A
m
-
Appendix Ill: Mass Spcctra
il7
RT: 6.93 AI: 970 KI: 976 Isopropyttigtate

CAS#:1733-25-l MF: C8 H14OZ FW: 142 MSD LIB#:42
CN: 2-butenoic acid,2-methyl-,l -nrethylethyl
ester(E)-
Synonyms: tiglic acidisopropylester
Source:AldrichChem.
+u (r0 ttO 100 120

-A"A
RT: 6.93 AI: 970 KI:976 Norborneol<exo-2->
CAS#:497-31-0 MF: C7 Hl2 O FW: I 12 MSD LIB#: 1187
CN: bicyclo(2.2.l)heptan-2-ol,
exo-
Synonyrns:none
Source:ref. cpd.ex E. vonRudlolT
t00
80
60
40
€r"'
20
RT: 6.96 Al: 911 Kl 976 Artemiseole

CAS#: ff48.5-46-3 MF: Cl0 Ht6 O F'W: l-52 MSDLIB#:222
CN: 3-oxabicylo(3. I .0)hexane,6-erlrenyl-
l ,4,4-tr-imethyt-,(
| R-( lu,-5a,6a11-
Synonyms:arthole
SnuLce:Aftenisia tridentata,SLC, UT ex RP Adams #5577
80 /'/tQtr
,
60
40
RT: 6.98 Al:972 KL:977 Octen-3'one<l'>

CAS#:4312-99-6 MF: C8 H14 O FW: 126 MSD LIB#: 20-58
CN: I -octen-3-one
Synonyms: amylvinyl ketone;pentylvinyl ketone
Source:Bedoukian Res.
*
'tl
tl
o
RT: 7.00 AI:912 KI: 978 Octen'2'ol<{d.2)->

CAS#:69668-89-9 MF: C8 Hl6 O FIV: 128 MSD LIB#: 2021
(32)-
CN: 3-octen-2-ol,
Synonyms:trans-3-octen-2-ol
Source:BedoukianRes.ex JJBroPhY
80
60
40
20
RT: 7.01 AI:9'73 KI: 978 Hexanal, dimethyl acetal

CAS#: l5gg-4'7-g MF: C8 Hl8 02 FTV:146 MSD LIB#: 2112
CN: hexane,I,l -dimethoxy-
Synonyms:caproaldehydedimethyl acetal
=-,-
I
Appendix Ill: Mass Spectr.a

l 19
RT: 7.02 AI:973 KI: 978 Dimethyl-4-heptanone

<3,5->
CAS#:19549-84-9 MF: C9 Hl8 O FW:142 MSD LIB#: 1997
CN: 4-heptanone,3,-5-dimethyl-
Synonynrs:di-sec-butyl
ketone
Source:AldrichClrenr.ex JJBrophy
RT: 7.03 AI: 973 KI:91.9 Vlenthane<trans-p->

CAS#:1678-82-6 MF: ClO H20 FW: 140 MSD LIB#: t075
CN: cyclohexane, | -methyl-4-(
I -rnethylethyl)-,trans-
Synonyms: none
Source:ret-.cpd.ex E. vonRudlofT
RT: 7.04 Al:914 Kl:979 Octen-3-ol<1->

CN: octen-3-ol<l->
Synonyms:none
Source:Jwtipents bemtudiqnaleaf oil, Rp Atlarns#2-5-54
*'l
I
OH
:
RT: 7.04 Al:974 KI:919 Pinene<p'>

CAS#:127-91-3 MF :C l O H l6 FW: 136 MSD LIB#: 305
L t
CN: bicyclo(3. )heptane. 6,6-dirnethyl-2-methylene-
Synonyms:nopinene;telebenthene;pseudopinene
Strurce:clistillationof black pepper,RP Adams #5448; 59.90VoFerula galbaniflua,
.I.Food Sci. 27:4-5-5(1962);58.527o MyristicaJTagrarts
Amunum villosum;55.107o
RT: 7.18 AI:919 KI: 983 <trans'rneta'>

Mentha'2,8'diene
CAS#: 5208-52-6 MF: Cl0 Hl6 FW: 136 MSDLIB#:1067
CN: m-mentha-4,8-dien, ( I R,3S)-
Synonyms:none
Source:ref. cpd. ex K. Gollnick
RT: 7.19 AI 979 KI: 983 Octanone<3->

CAS#:106-68-3 MF: C8 Hl6 O F\V: 128 MSDLIB#: 987
CN: 3-octanone
Synonyms:ethyl pentyl ketone;arnyl ethyl ketone
Source:Laven<Jer oil ex Firmenischex AF Thomas;6.157oRosm.arinus fficinalis,
IHOR 7 :219( | 995) : 2.407oE Isho ttzia c il i atai 2.277oLavendula ang ustifo Ii a
Appendixlll: MassSpect!'a t2l
RT:1 .22 AI: 980 KI: 984 Isolirnonene<trans->

C A S #: . 5113- 8 7 -l MF: ClOHl6 F W: l 3(r MS D LTB #: 867
CN: cyc,lohcxcnc, 3-mellryl-6-(
| -rrrethylethenyl)-,
(3R,trans)-
Synonyurs: none
Source:Fluka Chenr.
=
00
80 ill
rl
(r0
./\
RT: 7.2-5 Al: 98l KI: 98-5 Hepten-2-one<6-methyl-5->

C A S #: l 10- 9. 1-0 MF :C 8 H l 4 O F W : 126 MS t) LIB #:789
CN: nrcthyl-5-hepten-2-one (6-)
Svnonyrns:2-rncthyl -6-oxo-2-hcptcne
Soln'gs'rcf. cpcl.ex TheresaChanrblee, CocaCola Co.
RT: 7.26 Al::982 KI: 985 Norborneol <errdo-2->

CA S #: 491- 3( t - 9 M l .' :C 7 H I2 O F W: I12 MS D LIII#: II88
CN: bic t c lo( 2. 2I.)h e p ta n -2 -ocl n
. clo-
Sr nont'rns:none
Srturce:rel'.cpd. cx h,. von Ruclloff
122 by GC/MS
:
PiT:7 .27 AI: 982 KI: 986 Pinane <cis->
CAS#: 6876-13-7 MF; ClO Hl8 FW: 138 MSD LIB#: 1297
CN: bicyclo(3.1. I )heptane,2,6,6-trimethyl-,( I tt,28,5ct)-
Synonyms:none
Source:SCM Chems.ex H. Hills
4l ):)
100
80
60
40
20
'u'"
RT: 7.28 AI:982 KI:986 Octen-2-ol<(3tr1-v
CN: 3-octen-2-ol,(3E)-
Synonyms: ffans-3-octen-2-ol
Source:Bedoukian Res.ex.IJBrophy
RT: 7.30 AI: 983 KI: 987 Hexenoicacid <(3E)->

CN: 3-hexenoicacid,(E)-
trans-3-hexenoic
Synonyrns: acid
Source:Bedoukian Res.ex JJ Brophy
AppendixIll: MassSpectr.a
I l-1
RT: 7.31 AI: 983 KI: 987 Mentha-2,8-rliene<cis-meta->

CAS#: 5208-.51-.5 MF: ClO Hl6 FtM: 136 MSD LIB#: 1068
CN: m-mentlra-4,8-diene, ( I S,3S)-
Synonyms:none
Sourcc:rel'.cpcl.ex K. Gollnick
100
80
60
40
r 6u t00 120
RT: 7.3l AI: 983 KI: 987 l\Iethyl pentanoate<2-hydroxy-4-methyt->

CAS#:40348-12-9 MF: C7 Hl4 ()3 FW; 146 MSD LIB#: I107
CN: pentanoicacid,2-hydroxy-4-methyl,
rnethylester
Synonyms: none
Source;ref.cpd.ex KC Wong,Malaysia
RT:7.32 AI: 984 KI: 987 Menthene<3-p->

CAS#:.500-00--5 MF: Cl0 Hl8 FW: t38 MSD LIB#: 1077
CN: cyclohexene, 4-merhyl-1-(I -methylerhyl)-
Synonyms: rnenthomenthene; isopropyl-4-methylcyclohexene
Source:ref, cpd.ex E. vonRudlol'f
o
,-
I
t2 4 Adams:EssentialOil Componentsby GC/MS
RT: 7.34 AI: 984 KI: 988 Pentyl furan <2->

CN: furan,2-pentyl-
Synonyms:2-amylfuran
Source:BedoukianRes.ex JJ Brophy; 1.0O7o Spartiumjunceum, Rivista Ital. EPPOS325(1992);
0.60VoApium graveolens;0.25VoRhus coriaria
6
RT:7.39 AI: 986 KI: 989 Decene<l'>
CAS#: 872-05-9 MF: ClO H20 FW: 140 MSDLIB#: 1219
CN: decene(l-)
Svnonvms:none
Source:Olefins stock mix, Aldrich and SigmaChem.;6.207oNicotianq rustica,
JEOR 7:265(1995);0.307oMachilus bomb)tcina'0.207oMinthostachysspicata
CHr=ct11sl1r)7Cnt
RT:7.42 AI: 987 KI: 990 Furfuryl acetate

acetate
CN: 2-furanmethanol,
Synonyms:aceticacid furfuryl ester;NSC -5585
O^*'
= -t -
Appenclixlll: Mass Spectra
t25
RT:7.43 AI:988 Kl:990 Myrcene

CAS#:123-35-3 MF:ClOHl6 trW:136 MSD LIB#: 9l-5
CN: 1,6-octadiene,
7-methyl-3-rnethvlene-
Synonyms:none
Source:Juniperuslucava.n.a leaf oil, RP Adams #2863;94.5\vo Alpinia galanga (root),
JIIOR 4:8 | (1992); l2.25VoPistacictlenticus(ripe fruit); 68.007oCanella winterana Oeaf\
41
RT:1.44 AI: 988 KI: 991 Octanot<3->

CAS#:-589-98-0 MF: C8 Hl8 O FW: 130 MSD LIB#: 1257
CN: octan-3-ol
Synonyms:none
Source:Pcpperrnintoil, McCornrick Co.; l0.30VoMentha x gentilis,
Phytochem.1l:2639(1972);3.957oPerillafrutescens;3.60ToTeucritutthrterophyllum
t00
80 cHscH2cH(oHxcH2)4cH3
60
40
t20 140
RT: 7.4-5 AI: 988 KI: 991 Cineole <dehydro-1,8->

CAS#: 66113-06-2 MF: Cl0 Hl6 O FW; 152 MSD LIB#: 227
CN: 2-oxabicyclo(2.2.2)ocr--5-ene,1,3,3-trimethyl-
Synonyms:none
Source:Artenxisiatridentata,RP Adams #5s77, sLC, Utah; 5.20vaArtemi.siacampestris,
FFJ l0:2-5(1995); 1.107oArtemisia velotiorum)0.i\Vc Artemisiapersica
Q
RT: 7.4-5 AI: 988 KI: 991 Octanone<2->

CAS#:lll-13-'1 MF; C8 H16O FW: 128 MSD LIB#: 1205
CN:2-octanone
Synonyms:methyl hexyl ketone
Snurce:ChemicalServicesinc. ex H. Hills; 0.407oRutagraveolens,Sci' Pharm-56:l2l(1988);
0. | 7 VoZizyp hus i uiuba; 0. | 07oDracocephalum kotschyi
cH.c(:o)(sl'lz)scHr
RT:7 .47 AI: 989 Kl: 991 Hepten-2'ol <6'methyl'5->

CAS#: l56g-6(t-4 MF: C8 Hl6 O FIM: 128 MSD LIB#: 788
CN: -5-hepten-2-ol,6-methYl-
Synonyms:none
Source:ref. cpd. ex E. von RudlolT
4l o<
RT: 7.48 AI: 989 KI 992 Heptanol <2'6'dimethyl-2'>

CAS#: 13254-34-'7 MF: C9 H20 O FW: 144 MSD LIB#: 781
CN: 2-heptanol,2,6-dimethYl-
freesiol
Synonyn.rs:
Source:H & R Chem.ex Art Tucker
f
-m
Appendix
III: MassSpectra r27
RT: 7.48 AI: 989 KI:992 Methyl pentanoate<2-hyclroxy-3-methyl->

CN: pentanoic acid,2-hydroxy-3-methyl-,
merhylester
Synonyms: none
Source:ref. cpd.ex KC Wong,Malaysia
4tJ 60 80 t00 120
RT: 7.-52 AI: 991 KI: 993 Linalool oxide<dehydroxy-trans->

CAS#:-547.50-70-8MF: Cl0 Hl6 O FW: 1.52 MSD LIB#: l0l I
CN: fulan,2-ethenyltetrahydro-2-methyl--5-(
I -nrethylethcnyl)-,
trans-
Synonyms: none
0
,-\
40 60 80 100 120 t4
RT: 7.58 AI: 993 KI: 994 Butyl butanoate

CAS#:109-21-7 MF: C8 Hl6 02 FW; 144 MSD LIB#: 323
CN: butanoicacid,butylestcr
Synonyrns:br.rtylbutyrate
Soutce:AldrichChem.
Arlams: EssentialOil Componentsby GC/MS
128
RT: 7.60 AI:994 KI; 995 Octanol <2'>

CAS#: 123-96-6 MF': C8 H18 O FW: 130 MSDLIB#:32
CN: 2-octanol
Synonyms:capryl alcohol
Stu,.ce:ref. cpd.ex E. von Rudloff;0.01VoThymusvulgare,Bioflavour87:327(1988)
RT: 7.61 Al 994 KI: 99.5 MesitYlene

CAS#:108-67-8 MF: C9 H12 FW: 120 MSD LIB#:202
CN:benzene, 1,3,5-trimethyl-
Synonyms: trimethylbenzene < 1,3,-5->
Source:Artemisiaiu.dicaoil ex Z' Fleisher
100
80
60
40
60 6u I t't' t L'
40
RT:7 .62 AI: 994 KI: 995 Isobutyl-(2E)'butenoate

CA S #: 589- 66- 2 M F :C 8 H 1 4 O 2 F W :1 4 2 MS D Ll B #:16l l
CN: 2-butenoicacid, 2-methylpropylester
Synonyms:isobutYlcrotonate
*'f| -=-/
--
AppendixIIII MassSpectra t29
I.lT:7.62 AI:994 KI: 995 Thiazole <2,4,5-trimethyl->

CAS#: 13623-11-5 MF: C6 H9 N S FW: 127 MSD LIB#: 70
CN: thiazole,2,4,5-trirnethyl-
Synonyn.rs:
none
Y,_{-
RT: 7.71 AI:997 KI: 998 Ethyl hexanoate

CAS#: 123-66-0 MF: C8 H16 02 FW: 144 MSD LIB#: 79
CN: hexanoicacid, ethyl ester
Synonyms:ethyl caproate
Source:Alclrich Chem.; 61.017oMi.cheliabalansae,p. l-5,in: Aromatic plants & Essential
Constituenl.s,
PeaceBook Co., Hong Kong(1993);9.587oMicheliaJigo;
7.907oPynts serotino(Asian)
-")i-
RT:7.72 AI: 998 KI: 998 Octanal<n->

CN: I -octanal
Synonyms:caprylaldehyde
Source:r.ef.cpd. ex E. von Rudloff; 16.707oCarurncarvi,FFJ 2:83(1987);
| 4. | 7 7o Cit rus sinensi s; 8.7O7oZantho xylum avi cerutae
4l
ow
CAS#: 1438-91-l MF: C6 H8 0 S FW: 128 MSD LIB#: 726

CN: fumn, 2-((methylthio)methyl)-
Synonyms:none
Source:Aldrich Chem.ex Art Tucker
80
60
O^"'"
40
20
RT: 7.75 AI: 999 KI: 999 Yomogialcohol

CAS#:26127-98-0 MF: C10Hl8 O FW: 154 MSDLIB#:231
(E)-
2,5,5-trirnethyl-,
CN: 3,6-heptadien-2-ol,
Synonyms:none
Source:Aftemisia vestitaoil ex P. Weyerstahl;4.707oArtemisiapersica,
.TEOR4: 1( 19 92); 3.007oArtemisia judaica; 3.007oArtenilsia annua
80
60
40
20
P.T:7.77 AI: 1000 KI: 1000 Decane<n'>

CAS#: 124-18-5 MF: C10H22 FW: 142 MSD LIB#: 89
CN: decane
Synonyms:none
Source:Alkanesmix, Alltech Assoc.; 10.507oAcacia praecox (flower),
FFJ I I :3( I 996); 2.08VoCymbidiumsinense(flower); 1.307oNarcissustLzettq
cH3(cH2)8cH3
1l-F
Appendix III: Mass Spectla l3l
RT:1.71 AI: 1000 KI: 1000 Pyrazine<2,3,5-trimethyl->

CAS#:14667-55-l MF: C7 HlO N2 FW: 122 MSD LIB#:68
CN:pyrazinc.
trirncthyl-
Synonyms:none
Source:
AldrichChem.
XX
RT: 7.79 AI: 1000 KI: 1000 Mentha-1(7),8-diene <meta->
CAS#:13837-9-5-1MF:Cl0 Hl6 FW: 136 MSDLIB#: 106-5
CN: cyclohexane,I -methylene-3-(
I -methylethenyl)-
Synonyms: none
Source:ref.cpd.ex K. Gollnick
RT: 7.84 AI: 1001 KI: 1002 Carene<6-2->

CAS#:.5-54-61-0 MF: Cl0 Hl6 FW: 136 MSD LIB#: 3-5.5
CN: bicyclo(4.| .O)hept-2-
ene,3,7,7-trimethyl-
Synonyms: none
Source:AldrichChem.
100
80
60
40
20
r32 Adams: Essential Oil Components by GC/MS
RT: 7.84 AI: l00l KJ: 1002 Hexenyl acetate<(38)->

CAS#: 3681-82-1 MF: C8 Hl4 02 F'W: 142 MSD LIB#: 807
CN: 3-hexen-1-ol,acetate,(E)-
Synonyms:trans-3-hexenolacetate
Source:acetylationof (E)-3-hexenol(6345);0.55% Psidiumguaiava, FF.I6:143(1991);
0. 107oAnthri scus cer efoI ium; 0.027oRuta g r aveolens
/Y2-........... o.o"
RT: 7.85 AI: 1002 KI: 1002 Phellandrene <o'>

CAS#: 99-83-2 MF; C10 Hl6 trW: 136 MSD LIB#: 159
CN: methyl-S-(I -methylethyl)-I ,3-cyclohexadiene <2->
Synonyms:menthadiene;pjmentha-1,5-diene;1,3-cyclohexadiene
Source:distillation of black pepper,RP Adams #5452;58007o Anethurugraveolens(herb),
JEOR 7: | 1( I 995); 55.427oSchinttsntolle; 48.807oMonodora myristica
Q
RT:7.85 AI: 1002 KI: 1002 Pyrazine<2'ethyl-3'methyl'>
CAS#:15707-23-0 MF:C7HlON2 FW:122 MSDLIB#:64
CN: pyrazine,2-ethyl-3-methyl-
Synonyms: none
(:r
Appendixlll: MassSpectla r33
RT: 7.89 AI: 1003 Kl: 1004 l\Ientha-1(7),8-diene <p->

CA S #: 499- 97 -8 MF : C l O H 1 6 F W : 136 MS D LtB #:796
CN: cyclohexane,| -methylene-4-( I -nrethylethcnyl)-
Synonyms:pseudolimoncne
Source:HeteropyxisncLtalensis oil ex P. Weyerstahl
100 93
80
60
40
2(
RT: 7.91 AI: 1003 KI: 1004 Ethyl-(38)-trexenoate

CAS#:2.196-8.1-0 MF: C8 Lll4 02 FW: 142 MSI) LtU#: l9zt.l
CN: 3-hcxenoic
acicl.ethylestcr-,(3E,)-
Synonyrns:
none
Sourcc:RedoLrkian
Res.ex.l.lBrophy
4l
t00
80
6C)
4o
RT: 7.9-l AI: 1004 KI: 1005 Hexenyl acetate<(32)->

C A S #: 3681- 71 -8 MF : C 8 l l l 1 (o 2 F W : t,l 2 MS D LIII#: 808
CN: 3-hcxcn-|-ol, acctatc,(Z)-
Synonynrs: cis-3-hexcnyl acetate
S r r r r r c e: ac et yl a tiool 'n(Z )-3 -h c x c n o l (6 3 4 -5
| 1);. 007oP si di untguoj avcL,
FF.I6:| 43(| 991);
8.|2% VaIericurct oflicinelis; 7.82% Cortva.Ilariantajolis
l( x)
po-ac
ti0
fi)
40
20
RT: 7.96 AI: 100-5 KI: 1006 Cresol methyl ether <o'>
CAS#:578-58-5 MF: C8 HlO O FW:122 MSDLIB#: 1664
CN: benzene,I -nrethoxY-2-methyl-
Synonyms:o-methyltoluene,o-methylanisole
ChirnikaChronikal0:l 19(1988);
Pistacial,entic:us.
Source:Al<lrichChem.l0.44a/o
0.177oBoswelliacarterii
O-Me
80
I
60
(/
40
20
RT:7.99 AI: 100-5 KI: 1007 Heptadienal<(28'48)->

C AS#: 4313- 03- 5 MF : C 7 H l O O FlV: I l0 MS D LIB #: 2060
(28,48)-
CN: 2,4-heptadienal,
Synonyms:trans,trans-2,4-heptadienal
Source:BcdoukianRes.;0.607oMelis,gafficinalis, Lebensm.-Wisc. U.-Technol.19:482(1986);
0.107oNarcissus (absolute);
tazetta. 0.107oRhuscoriaria
RT:7.99 AI: 100.5 KI: 1007 Hexenoicacid <(2E)'>

CAS #; 13419- 69- 7 MF :C 6 H 1 0 ()2 F W :I1 4 MS D LIB #:2062
CN: 2-hexenoicacid, (2E-)
Synonyms:none
source:BedoukianRes.; 0. 107oGartleniai asnrinoid.e s,.IEOR 8:241( I 996);
o/o p
0.03 S ar t i untj unc eu m; 0.0 | 7o Zi 4, p lt us j uj u ba f r uit
r-1F
Appendix lll: Mass Spectra
r35
RT: 7.99 AI: 1005 KI: 1007 Pentylproparroate

CAS#:624-54-4 MF: C8 Hl6 02 F'W:t44 MSD LIB#: l2-51
CN: propanoicacid,pentylester
Synonyms: amylpropionate;pentylpropionate
Source:Pfaltz& Bauerex Art Tucker
RT: 8.01 AI: 1006 KI: 1008 Linalool oxide<dehydroxy-cis->

CAS#:54750-69-5 MF: Cl0 Hl6 O FTV:l-52 MSD LIB#: 1012
CN: furan,2-ethenyltetrahydro-2-methyl-_5-(
I -methylethenyl)-,cis-
Synonyms: none
o
:
- 'q 'H
l
RT: 8.03 AI: 1007 KI: 1008 Sylvestrene<iso->

CAS#: 499-03-6 MF: ClO Hl6 FW: 136 MSD LIB#: 1066
CN: cyclohexene,| -methyl-3-(| -methylethenyl)-
Synonyms:nr-mentha- 1,8-diene
Source:rel'.cpd. ex K. Gollnick
136 Adaurs:EssentialOil Componentsby GC/MS
RT: 8.0.5 Al: 1007 KI: 1009 Hexyl acetate

CAS#: 142-92-'7 MF: C8 Hl6 02 FW: 144 MSD LIB#: l8-5
CN: aceticacid, hexyl ester
Svnonvms:none
Source:clistillationof red delici<lusapples,RP Adams #5756;6.94VoMandragora o.fficin.arum,
JIIOR 4: 187(1992);5.007o Rosa cltittensis
Anthemisnobilisl 3.95o/o
RT:8.0.5 AI: 1007 KI; 1009 Isoamylisobutyrate

CAS#: 20-50-0l-3 MF: C9 H | 8 02 FW: 158 MSD LIB#: 1603
CN: propanoicacid, 2-methyl-,3-methylbutylester
Synonyms:isopentylisotrutyrate
Aldrich Chem.;3.607oEriocephalus
Scrtpce: ArornaticPlants:Basic & Applied'
puncttLalls,
N. Margaris,etal.,ecls.,MartinusNiihofl'Publ',The Netlrerlands(l982);
2.227oAnthemis nob ilis: 0. 107oPt er onia incana
I
)--""Y-
RT: 8.10 AI: 1008 KI: l0l I Carene<6'3->

CAS#:13466-78-9 MF: Cl0 Hl6 FW: 136 MSDLIB#:1655
CN: trimethylbioyclo(4. -ene<3,7.7->
I .0)hept-3
Synonyms:none
Source:Juniperu,sg,amboanaex RP Adirr.ns#2514'.common in corril'ers;black pepper;
65.3OVc, Robiniapse'udoacacio;
Pistacialentictts,FtsI6:229(.1991):54'60Vo
44.00Vo Abies semenovii
i
Appendix
Ill: MassSpeclra 137
RT: 8.17 AI: l0l0 KI: l0l3 Hexenyl acetate<(28)->

CAS#: 2491-18-9 MF: C8 Hl4 02 FW: 142 MSD LIB#: 2048
CN: 2iexen-| <rl, acetate,(2Ii)-
Synonyms:none
Source:BedoukianRes.; | .80%tValerianao.fficinalis,DragocoRept. 3:3l(ll1992);
0.29VoLa vt's
onia inermis'.0.24VoSpondias cytlrcrea
RT : 8. 18 A I : l 0 l I K I: l 0 l 3 D i c h l o ro b e nzene4,4->
CAS#: 106-46-7 MF: C6 H4 Clz FW: 146 MSD LIB#: 590
CN: benzene.1.4-clichloro-
Svnonylns:p-clicholorobenzenel paracide;parazene;para crystals
Source:ENOZ Inc., rnothballs
+
cl
RT:8.22 AI: l012 KI: 1014 Cineole<1,4->

CAS#:470-67-7 MF : C l 0 H l 8 O F W : l -54 MS D LIB #: l 00l
CN: 7-oxabicyclc>(Z.2.1) heptane,1-methyl-4-(I -methylethyl)-
Synonyms:p-menthane, 1,4-epoxy-
Source:West lndian lime oil ex Lorann Co; l.7A7oCitrusaurantifolia,p.325,
in: Flav. & Frag : A World Persp.,Lawrence,etal.,Proc. lOth Intl. Cong.of EssOil,
Elsevier,Amsterdarr(1988); | .O6VoTerminalia bentzoe; 0.80akEucdlyptusglobulus
Q
138 Adams: EssentialOil Componentshy GC/MS
RT: 8.24 AI: 1012 KI: 1015 Isopropyl-4'methylthiazole<2'>

CAS#:15679-13-7 MF: C7 Hl I N S FW: 141 MSD LIB#: 1624
I -methylethyl)-
CN: thiazole,4-methyl-2-(
Synonyms : thiazole<2-isopropyl-4-methyl->
Source:AldrichChem.
Y
,4"
\_/
<(28,48)'>
RT:8.27 AI: 1013 KI: 1016 Heptadienol
CAS#:33467-'79-7 MF: C7 HlzO FW: 112 MSD LIB#: 2103
I -ol,
CN: 2,4-heptadien- (2F'48)-
Synonyms:none
S*
RT: 8.30 AI: 1014 KI: l0l7 Terpinene<u'>

CAS#:99-86-5 MF: C10Hl6 FW: 136 MSD LIB#: 900
I -methyl-4-(1-methylethyl)-
CN: 1,3-cyclohexadiene,
Synonyms: p-mentha-1,3-diene;terpilene
Source:Juniperuscoahuilensisleaf oil, RP Adams #2121; 16.837oColeusaromaticus,
J. Ethnopharmacol.32:57(1991);ll.gOVoMelaleucaalternfolia: lO.TOVoCitrusparadisi
Appendix
III: MassSpectra 139
RT : 8. 32 A I : l 0 l 4 K t: 1 0 1 8 T h i a z o l e< 2 -acetyl ->

CAS#: 24295-03-2 MF: C-5H-5N O S FW: 127 MSD LIB#: -52
CN: elhanone,l-(2,thiazolyl)-
Synrrnylns:ketone,methyl 2-thiazolyl
C,Y-
RT : 8. 34 A I : l 0 l -5 K I: l 0 l 8 An i s o l e

CA S #: f 04- 93 -8 MF: C8 H l0 O tsW : 122 MS D LIB #: t 72
CN: benzene,I -nrethoxy-4-methyl-
Synonynrs: p-nrcthoxytoluene; p-nlethylanisole; cresol,rnethylether<p->
Source:Alcf ich Chem.
r 00 t22
tt0
60
4(
20
RT: 8.41 AI: l0l7 KI: 1020 Ethyl2-methyl-2-pentenoate<(E)->

CA S #: 1617- 4 0 -9 M F : C 8 H 1 4O2 F W: 142 MS D LIB #: 2144
CN: 2-pctltcnoictrcid.2-methyl-,cthyl estcr,(2ti-)
Synonynrs:none
Source:BccloukianRes.
4l
o
tl
/\./y_z\/ ln
I
:
l
RT: 8.41 AI: l0l7 KI: 1020 Pyrazine<2'acetyl->

CAS#:22047-25-2 MF: C6 H6 N2 O FW:122 MSD LIB#:50
CN: ethanone,l-pyrazinyl-
Synonyms: ketone,methylPYrazinYl
Source:AldrichChem.
(x-
RT: 8.43 <3'methyl'I,2->
AI: 1017 KI: 1021 Cyclopentanedione
CAS#:765-70-8 MF: C6 H8 ()2 FW:112 MSDLIB#:169l
3-methyl-
CN: 1,2-cyclopentanedione,
Synonyms: methyl cYcloPentanone
il
(\<.
\/
RT: 8.5| <(Z)'>

AI: 1019 KI: 1023 Ethyl 2'methyl'2-pentenoate
CAS#: 1617-39-6 MF: C8 Hl4 02 FW 142 MSD LIB#: 2145
acid,
CN: 2-pentenoic ethyl
2-methyl-, (22-)
ester,
AppendixIII: MassSpectra
141
RT: 8.53 Al: 1020 Kl 1024 Cymene <p->

CAS#:99-81-6 MF : C l O H l 4 F IM : 134 MS D LIB #;306
CN: benzene,l -methyl-4-(l -rnethylcthyl)-
Synonyms:p-isopropyltoluene;p-cymol; carnphogen
Source:Bf ack pepperdistillationex Shilling Co.;83,757ooriganum saccatunx,
.IEOR7: 175( 1995); 53.07VoOriganum soll,nticunt;44.13VoThymusvul,saris
I
I
/\
lt l
i4
l
J---_-_.T
140
RT: 8.-57 AI: l02l Kl: 102.5Attyl tigtare

CAS#:7493-71-2 MF: C8 Ht2(o2 FW: 140 MSDLIB#:43
CN: 2-butenoic acid,2-methyl-,2-propenyl
ester,(E)-
Synonyms: tiglic acid,allyl ester
Source:AldrichChern.
tl
.Ga-o/v
I
RT: 8.57 AI: l02l KI: 1025 Methyl heptanoate

CAS#: 106-73-0 MF: C8 Hl6 ()2 FtM: 144 MSD LIB#: 1098
CN: heptanoicacid, methyl ester
Synonyms:methyl enanthate
source: Aldrich Chem.;0.377oHwnulus lupulus (Neomexicanuscurtivarl,
Z. Naturforsch.37a:565( 1982\
142 Adams:Essential by GC/MS
Oil Components
RT: 8.57 AI: 1021 KI: 102-5 Trimethyl benzene<I,2,4'>

CAS#:95-63-6 MF : C 9 H 1 2 FW: 120 MSD LIB#: 203
CN: benzene,1,2,4-trimethYl-
Synonyms:pseudocumene; methyl-p-xylene;psi.-cumene
Source:Artemisia juclica oil ex Z Fleisher;0.687oArtemisiaiudaica, JEOR 2:27l(1990);
0. l\Vo Law soni a in ermi s ; 0'0 | 7oM u rray a koenig i i
RT: 8.-58 AI: 1021 KI: 1026 Menthene<l-p'>

CAS#:5502-88--5 MF: ClO Hl8 FW: 138 MSD LIB#: 1076
CN: cyclohexene,l -methyl-4-(1-methylethyl)-
Synonyms: carvomenthene; I -methylcyclohexene
4-isopropyl-
Source:ref.cpd.ex E. vonRudloff
Q
RT: 8.59 AI:1022 KI: 1026 CYmene<o->
C A S #: 527- 84- 4 MF :C l OH 1 4 F W:134 MS D LIB #:1529
CN: benzene, I -methyl-2-(1-methylethyl)-
Synonyms:none
Source:Vafencia ofangeleaf oil ex MG Moshonas,USDA; 2.20VaAchillea colina,
Rasrir.Resur2 I :69(I 985); 0.507oBoswellia carterii; 0.467oP erseapodadenia(leaf
?
-
Appenclix
lll: MassSpectra 143
RT: 8.69 AI:1024 KI: 1029 Limonene

CAS#: | 38-86-3 MF: C l0 H l6 FW: I 36 MSD LIB#: 164
CN: nrethyl-4-( l-methylethenyl)cyclolrexe
nc 
Synonynrs: crajeputene; cinene;kautschin;ncsol; p-mentha- 1,8-cliene:
dipentene
Sottrcc:clistiflationol-sweetanisleaves.Calif., RP Aclarns#5452:96.497oCitnrssinensis,
Zhiwu. X uebao,30:623(l 988 ) : 96.41a/aCit r us auranti uttri 95.007oCi t n ts d eli c iosa
RT: 8.70 AI: 102-5Kl:1029 Phellandrene

<p->
CA S #:- 55. 5- 10 -2 MF : C 1 0 H l 6 FW: 136 MSDLIB#:16l
CN: mcthyl-6-(| -methylethyl)cyclohexene <3->
Synonyrns: p-menth-1 (7),2-diene
S<rtttce:distillationol sweetanisleaves(Calil'.),
RP Adanrs#5452;63.057oLet,istictutt
o.fficinale
641,in: F-lav.& Fra-{.:A WorlclPersp.,Lawrence,etal..ElsevierSciencePublishers,
1->.
Arrrstcrclanr(
1988);6l .007oAngelir:aarch.angelico;21.007oLat'andtilapintnta
t00
d
80
60
40
20
A
RT: 8.73 AI: 1025 KI: 1030 Sylvestrene
CAS#:1461-21-4 MF: ClOH16 FW: 136 MSD LIB#: 1453
CN; cyclohexene, I -nrethyl-5-(
l-nrcthylethenyl)-
Synonynrs:rn-mentha- I (6),8-diene
Sourcc:ref. cpd.ex H,.vonRudlolT
Adanrs:E ssentialOil ComponentsbY CCiMS
t44
RT: 8.76 Al: 1026 KI: 1031 Cineole<1,8->

CAS#:470-82-6 MF;Cl0 Hl8 O trW: 154 MSDLIII#: 160
l, 3,3-trimethyl-
CN : 2-oxabicylco(.2.2.2)<tctane,
Synonyms: cajeputol, 1,8-epoxy-p-menthane; eucalyptol;z'edoaryoil; eucapur;trepan
globultts,
Sour.": F oenicuhtmrtulgare(Calif. anis) leaf rtil; 95.137oEucalS'ptus
p. 52, in: Aronra{icPlants& EssentialConstitucnts, PeaceBook Co'' Hong Kong(1993);
70.007oMelaleuca firidiflora; 69.00VoEucalltptuscitrerea
/\
I
(/,
tl
-\
RT: 8.77 AI: 1026 KI: 1031 Benzyl alcohol

CAS#: 100-51-6 MF: C7 H8 O FW: 108 MSD LIB#: 288
CN: benzenemethanol
Synonyms:phenylmethanol; o-hydroxytoluene
benzenecarbinol;
: Jasminabsolute ex A.F.Thornas;35.207oConvallari a ntaial i s,
Scrurc,e
()9(t);35.087o
Daphnetangutit:a;21.007aNcrcisslspoeticus
I)ragocoRep.5:21(l/l
OH
I
(/
RT: 8.80 Al:1021 KI: 1032 Hexanoic acid <2'ruethyl'>

CA S #: 453( t - 23- 6 M F :C 7 H 1 4 O 2 F W :I3 0 MS D LIB #:1974
CN: hexanoicacicl,2-methYl-
Synonyms:2-methYlcaProicacid
-f-
i
Appendix
RT: 8.83 AI: 1028 KI: 1033 Acetylpyridine<2->

CAS#:1122-62-9 MF: C7 H7 N O FW: 121 MSD LIB#:49
CN: ethanone,I -(2-pyridinyl)-
Synonyms: 2-pyridylmethylketone
Source:AldrichChern.
(>^"
RT:8.89 AI: 1030 KI: 103-5Thiazole<2-isobutyt->
CAS#: 18640-'74-9 MF: C7 Hl I N S FW: l4l MSD LIB#: -56
CN: tlriazole,2-(2-nethylpropyl)-
Synonyms: 2-isobutylthiazole
Source:AldrichChem.
OT
RT: 8.90 AI: 1030 KI: 1035 Octen-2-one

<(3E)->
CAS#:18402-82-9 MF: C8 Hl4 O FW: 126 MSD LIB#: l94l
(3Et-
CN:3-octen-2-one
Synonyms:none
Source:BedoLrkian
Res.ex J.IBrophy
t46 Adams: Essential Oil Components by GC/MS
!
RT: 8.9-5 AI: 1031 KI: 1037 Furan <2'acetyl'5'methyl->

CAS#:llg3-79-g MF:C7 H8 02 FW:124 MSD LIB#:724
CN: 2-acetyl-5-methylfuran
Synonyms: 2-methyl-5-acetylfuran; I -(-5-methyl-2-furanyl)-
ethanone,
Source:AldrichChem.
RT: 8.96 AI: t032 KI: 1037 Ocimene <(Z)'F >

CAS#: 3338-55-4 MF:C10 Hl6 FW: 136 MSD LIB#: 165
CN: 1,3,6-octatriene, 3,7-dimethyl-, (32)-
Synonyms:cis-ocimene
Source:distillation of sweetanis leaves,Calif., RP Adams #5452;42307o Tagetesminuta,
Ti thon ia div er sifu lia; 32.237o CIor anthus sp i catus
Perf. Fl av. 10 :73( 1985) ; 40.ZOVo
RT: 8.99 AI: 1032 KI: 1038 Propyl tiglate

CAS#:61692-83-9 MF: C8 Hl4 OZ FW: 142 MSD LIB#: 44
CN: 2-butenoicacid, propyl
Z-methyl-, (E)-
ester'
Synonyms: none
Source:AldrichChem.
100
80
o/\./
60
40
147
RT: 9.03 AI: 1033 KI: 1039 Hexanoic acid <S-rnethvl->

CAS#: 628-46-6 MF: C7 Hl4 02 FW: 130 MSD LIB#; 2063
CN: lrcxanoicacid, -5-methyl-
Synonynrs:caproicacid,-5-methyl-;
isoenanthic
acid
RT:9.04 AI: 1034 KI: 1039 Lavenderlactone

CA S #: 1073- 11 -6 MF :C 7 H l O ()2 F W : t26 MS D LIB #: t95
CN: 2(3H)-f'uranone,-5-ethenylclihydro--5-methyl-
Synonyms:methyl hex-5-enolicle<4->; y-vinyl-y-valerolactone
Source:Armoisea davanoneoil ex Guy Collin
RT: 9.06 AI: 1034 KI: 1040 Santolina alcohol

CAS#: 35671-15-9 MF: ClO H18 O FW: 1.54 MSD LIB#: 232
CN: 4-hexen-2-ol,3-ethenyl-2,-5-dirnethyl-,(S)-
Synonyms:none
source:Artemisia vestita oil ex P. weyerstahl.,3.20voorruenis mixta,parfums cosmet.
Aromes 60:6-5(| 984); 3.147oArtentisia vestita:0.209oArtemisiajudaica
RT: 9.14 AI: 1036 KI 1042 Benzeneacetaldehyde

CAS#:122-18-1 MF: C8 H8 O FTV:120 MSD LIB#: 272
CN: benzeneacetaldehyde
Synonyms:o-tolualdehyde;phenylcthanal;phenylacetaldehyde
Source:ref. cpd.ex J.P.Vidal, France
RT:9.17 AI: 1037 KI: 1043 Roseoxide<cis-dihydro'>

CAS#:1666-5-10-4 MF: Cl0 H20O trW: 1.56 MSD LIB#: 136-5
CN: 2H-pyran,tetrahydro- (2R'4R)-
4-meLltyl-2-(2-methylpropyl)-,
Synonyms: none
Source:rel. cpd.ex P. Weyerstahl
I
|,-o!
)
0 -A-.
RT:9.19 AI: 1038 KI: 1043 Heptyl acetate<2->

CAS#: 5921-82-4 MF: C9 Hl8 O2 FW: l-58 MSD LIB#: 143
CN: 2-heptanol"arcetate
Synonyms:hept-2-ylethanoate
Source:Aml,yisdiatrypa oil, Dom. Rep. ex Tom Zanoni; 3.307oAfrantomumntelegueta,
FFJ 6 : 183( I 99 | ); 0. 10%,Zing iber ofli cinale; 0.06VoRuta angustifoli a
O-Ac
- - t- r
Appendix III: Mass Spectra 149
RT: 9.20 AI: 1038 KI: 1044 Ethyl hex-(2E)-enoate

CN: 2-hexenoic
acid,ethylester,(E)-
Synonyms:ethyltrans-2-hexenoate
tl
*o'7l'\
40 60 80 t0
RT: 9.23 AI: 1039 KI: 1044 Salicylalclehyde

CAS#:90-02-8 MF: C7 H6 02 I:W: 122 MSD LIB#: 1370
CN: benzaldchyde,2-hyclroxy-
Synonyms:2-lolrnylphenol
Source:rel. cpcl.ex Keith Halkiss;2.507oTagetesminuta,IndianPerf. 19l.29(1975):
l.J5VoCintrcmomumcassiai0.487oCinnamomumzeylanicunl
40 60
RT: 9.33 AI:1O42 KI: 1047 Hexalactone <y->

CAS#:695-06-1 MF : C 6 H l O C )2 F W: 114 MS D LIB #: 1977
CN: 2(3H)-furanone,-5-ethyldihydro-
Synonynrs: y-caprolactone; hexanolide-1,4; tonkalide
Source:BedoukianRes.ex .I.lBrophy; 0.23VoZiz,t'phus .jujuba fruit, JEOR 8:323(1996i);
0. | 57oPsi dirun guaj ava truit 0.02VoM and rag o ra qffici narunr
10 0
80
60
40
20
:
150 Adams: Essential Oil Components by GC/lr4S
RT:9.42 AI: 1044 KI: 10-50Ocimene<(E)'P'>

CAS#:3779-61-l MF: ClO Hl6 FW: 136 MSD LIB#: 894
(3E)-
3,7-dimethyl-,
CN: 1,3,6-octatriene,
Synonyms: trans-ocimene
Source:Juniperusbarbadensisleaf oil RP Adams #5400; 94.80VoAstroni.umfraxinfolium,
JEOR 8:177(1996);75.0O7oNarci.ssus Bouea macrophylla
pseudonarcissus;68.597o
RT: 9.45 AI: 1045 KI: 10-51 Isobutyl angelate

CN: 2-butenoicacid, 2-methyl-,2-methylpropylester(Z)-
Synonyms:angelicacid, isobutyl ester,crotonic acid, cis-2-methyl-2-butenoate
Source:Aldrich Chem.;37.417oAnthemisnobilis (Italy), in: Atlas of EssentialOils, Srinivas,
Publ.,Bronx, NY(1986); 35.927oAnthemisn,obilis(Japan);0.207oHelichrysumitalicum
100
.-.--.-"M
ll
<3->
RT: 9.50 AI: 1046 KI: l0-52 Methyl'2'cyclohexen'1-one
CAS#:I193-18-6 MF: C7HlO O FW: 110 MSDLIB#: 1693
I -one,3-methyl-
CN: 2-cyclohexen-
Synonyms: pseudenone,MCH
Source:AldrichChem.
b
RT:9.51 AI: 1046 KI: 1052 Arbusculone <cis->

CN: ethanone,
I -(5-ethenyltetrahydro--5-merhyl-2-furanyl)-,
cis-
Synonyms: none
Source:Artemi.sia
tridentata,SLC,UT ex RPAdams #5577
100
80 ^"%O)<\
60
40
20
1 00 140
RT: 9..51 AI: 1046 KI: 10.52 Tagetone <dihydro->

CAS#:1879-00-l MF: Cl0 Hl8 O trW: l-54 MSD LIB#: 14.58
CN: 7-octen-
4-one,2,6-dimethyl-
Synonyms: dihydrotagetone
Source:Tagetesmitxutaoil ex E. Hethelyi,Hungary
RT: 9.52 AI: 1047 KI: 10-52 Octen-l-ol<(32)->

CAS#:20125-84-2 MF: C8 Hl6 O FW: 128 MSD LIB#: 217-5
(Z)-
CN: 3-octen-1-ol,
Synonyms:octenol,
cis-3-;
Source:Bedoukian
Res.ex.JJBrophy
152 Adams: EssentialOil Componentsby GC/MS i
RT:9.-57 Al: 1048 KI: 1054 Prenylisobutyrate

CAS#:76649-23-5 MF':C9 HI6OZ FW: 1.56 MSD LIB#: 1982
ester
CN: isohutyricacid,3-methyl-2-butenyl
Synonyms:none
Source:Bedoukian Res.ex .TJBrophy;0.167o nobilis,Proc.1l th Intl.
Anthemis
Cong.olEss.Oils,NewDelhi,India, 4:207(1989)
r"lA
RT:9.-59 AI: 1049 KI: 10.54 Octen-l-al <(28)->
CAS#: 2-548-87-0 MF: C8 Hl4 O F'W: 126 MSD LIB#: 1938
CN: 2-octenal,(E)-
Synonyms;octenal,trans-2-
Source:BedoukianRes.ex J.IBrophy;0.707oRltuscoriaria,p. 81, in: DragocoBericht(1993);
0.06VoSp ondias cytherea; 0.0 | 7oD aplute g enktva
RT: 9.62 AI: 1049 KI: l0-55 Pentyl isobutanoate

CAS#: 2445-72-9 MF: C9 Hl8 ()2 FW: l-58 MSD LIB#: 3ll
CN: propanoicacid, 2-methyl, pentyl ester
Synonyms:amyl isobutyrale;pentyl isobutyrate
Source:artificial blackberrvflavor. Lorann Oils
-l mt
Appendix III: Mass Spectla r53
RT: 9.64 AI; 1050 KI: 1056 Ethyl levulinate

CAS#:-539-88-8 MF: C7 Hl2 (]3 FW: 144 MSD LIB#: 218-5
CN: pentanoic
acid,4-oxo-,ethylester
Synonyms:ethyllaevulinate;
ethyl4-oxovalerate
r00
80 o\,/
60
40
20
40
RT:9.6.5 AI: 1050 KI: 10.56 Cresol<o->

CAS#:95-48-7 MF: C7 H8 O FW: 108 MSD LIB#: I192
CN: phenol. 2- me th y l -
Synonyms:2-methylphenol;2-hydroxytoluene;o-tolulol
Pfaltz & Bauer; 0.287oJasminumfficinale, Univ. Cairo Bull. Fac. pharm,
Scrtrrce:
l3:183(1974);0.05Vo Atractylodeslancea;0.057o Spartiumjuncean (absolute)
108
OH
I
/Y
w
RT:9.67 AI: 10.51 KI: 1056 Bergamal
CAS#: 106-72-9 MF; C9 H16 O FW: 140 MSDLIB#:790
CN: -5-heptenal,2,6-dimethyl-
Synonyms:melonal;heptenal,2,6-dimethyl-5-
Source:ref. cpd. ex E. von RudlofT
154 Adams:EssentialOil Componentstry GC/MS
RT:9.12 AI: l0-52 KI: 1058 Isopentylbutanoate

CAS#:106-27-4 MF: C9 Hl8 ()2 FW: l-58 MSD LIB#: 312
CN: butanoicacid,3-methylbutyl ester
Synonyms: isoamyln-butyrate; isopentylbutyrate
flavor,LorannOils
Source:artificialblackberry
100
RT: 9.17 AI: 10-53 KI: l0-59 Naphthalene <trans-decahydro'>

CAS#: 493-02-7 MF: C10 H18 FIM: 138 MSD LIII#: 566
CN: naphthalene,decahydro-,trans-
Synonyms:trans-decalin;trans-perhydronaphthalene
RT: 9.78 AI: 10-54 KI: 10.59 Terpinene<y'>

C AS#: 99- 8. 5- 4 MF: ClO Hl6 FW: 136 MS D LIB #: 994
CN: l ,4-cyclohexadiene,I -methyl-4-(1-methylethyl)-
Synonyms:crithrnene; moslene;p-rnentha-1,4-diene
Source:Lemonoil, LorannOils;-58.507o HRC & CC -5:182(1982);
Satureiahortensis,.f.
35.307oCitrus unsltiu 32.007oCitrus medica
I
A
Y
-A-.
t- m
AppendixIll: MassSpectra r55
RT:9.79 AI: 10.54 KI: 1060 Acetylpyrrote

<2->
CAS#:1072-83-9 MF: C6 H7 N O F'W:109 MSD LIII#:48
CN: ethantine,
l-( l Hlyrrol-2-yl)-
Synonyrns:2-pyrolylethanone
Source:Alchichkit #2
r00
i
./"\./0"
\_/
RT: 9.84 AI: l0-55 KI: l06l Nlethyl cyclohexylcarboxylate

CN: cyclohexanecarboxylic
acid,nrcthylester
Synonynrs:methylcyclohexanoate
Soulcc:Aldrich Chenr.
Y"
(,
RT : 9. 88 A l: 1 0 5 6 K I: 1 0 6 2 Arte n ri s i ak e tone
CAS#: 54(t-49-6 MF: C10 Hl(r O FW: 1.52 MSD LIB#: 223
CN: 1,5-hcptaclien-4-onc, 3,3,6-trinrethyl-
Synonyrns:nonc
Sourcc:Artenti,sicr trirlentata.SLC. tlT ex RP Aclanrs#5511:64.00% Artemisia an.nua,
Tolev ac t al.pape r# l 1 7 .V l th In tl . C o n g .o f E s s .Oi l s.S anFranci sco(1974);
46.O(Y/o Artenisicrltotttit:a;45.00%Santolinachatttoecl,ltari,s,stt,s
100
80
60
40
20
r56 Adams:Essential by GC/MS
Oil Components
RT: 9.89 AI: 10-57 KI: 1062 Thiophene<2'butyl'>

CAS#:1455-20-5 MF: C8 H12S FW: 140 MSD LIB#: 1480
CN: thiophene, 2-butyl-
Synonyms: none
Source:ref. cpd.ex Art Tucker
o^--
RT:9.92 AI: 10-57 KI: 1063 Benzenemethanol <c-methyl'>
CAS#:98-85-l MF: C8 HlO O FW:122 MSD LIB#: 274
CN: benzenemethanol,o-methyl-
Synonyms:c-phenethyl alcohol; phenylmethylcarbinol; styralyl alcohol
Source:Aldrich Chem. ex Art Tucker
d'
r00
80
60
40 80 r0 0
RT:9.95 AI: l0-58 KI: 1064 Norbornene-2'methanol <exo-S->

CAS#: 67671-05-0 MF: C8 H12O FW:124 MSD LIB#: l184
( 1R-exo)-
CN: bicycfo(2,2,1)hept-5-ene-2-methanol,
Synonyms:none
Source:ref. cpd. ex E. von RudlolT
r00
80
60
40
Appendix III: Mass Spectra t57
RT:9.99 AI: 1059 KI: 106.5 Acetophenone

CN: phenylethanone
Synonyms:phenyl methyl ketone;acetylbenzene; hypnone;phenylethanone
Source:Englemannspruceleaf oil ex E. von Rudlolt 20.007aPltiladelphuscoronarius,
p. 57, in: Progressin EssentialC)ilResearch(Proc. Intern. Syrnp.on Ess.Oils),
E.-.T.Brunke, Ed., GruyterPubl., Bcrlin(1986); 2.407oTrifolium pratense(red flower);
2.20a/aCistus ladaniferus (leaf)
105
80
60
40
20
100 120
RT: 10.00 AI: 1060 KI: 106-5 Isobutylacetoacetate

CAS#:1779-75-1 MF: C8 Hl4 (]3 FW; l-58 MSD LIB#: 1608
CN: butanoicacid,3-oxo-,2-methylpropyl
ester
Synonyms: none
Source:AldrichChem.
43
I
2-'-{-'<"
ill
ol
8-5
57 r0 3
r00 120
RT: 10.02 AI: 1060 KI: 1065 Hexenyl oxy-acetaldehyde<(32)->

CAS#: 68133-72-2 MF: C8 H14 02 I:W:142 MSD LIB#: 2124
CN: acetaldehyde,
((32)-3-hexenyloxy)-
Synonyms:none
4l
55
80
60
82
40
20
;
I
158 Adams:EssentialOil Componentsby CC/MS
RT: 10.03 AI: 1060 KI: 1066 Octen-l-ol<(28)'>

CAS#:18409-17-l MF: C8 H16 O FW: 128 MSD LIB#: 1939
(E)-
CN:2-octen-l-ol,
Synonyms:octenol,trans-2-
Source:BedoukianRes.ex JJBrophy
"offi
RT: 10.09 Al:1062 KI: 1067 Tolualdehyde<o'>

2-methyl-
CN: benzaldehyde,
Synonyms:2-methylbenzaldehyde
Source:FlukaChem.
100
H
I
60 4rA"
ttl
40 \,/\
20
80 100 120
RT: 10.11 AI: 1063 KI: 1068 Hexadienolacetate<(28'48)'>

CAS#:57006-69-6 MF: C8 Hl2O2 FTV:140 MSD LIB#: 2099
CN: 2,4-hexadien-1 (28,48)-
-ol, acetate,
Synonyms:sorbylacetate
43
79
t40
;l
t
Appendix III: Mass Spectla t 59
RT: l0.ll AI:1063 KI:1068 Octanolcn->

CAS#:I I l-87-.5 MF: C8 H18O FW: 130 MSD LIB#: 34
CN: l-octanol
Synonyrns:caprylic alcohol
Source:ref. cpd. ex E. von RudlofT; 14.407cCitus sinensi.s, Nippon Noge.
Kaislri -58 :691( 19 84); 12.707oBo,sv'ell i a carteri i.,2.007oAlp in ia kat,s
untqdai
41
100 cH3(cH2)7oH
80
60
40
40 60 80 100 t20
RT: 10.12 AI: 1063 KI: 1068 Hexenyloxy-acetaldehyde<(3E)->

CAS#:000-00-0 MF: C8 Hl4 02 hW:142 MSD LIB#:212.5
((3E)-3-hexenyloxy)-
CN: acetaldehyde,
Synonyms:none
Soutce:Bedoukian Res.
4l
100 .5.5
80
60
82
40
40 100 t20
RT: 10.1-5 AI: 1064 KI: 1069 Tolualdehyde<meta->

CN: benzaldehyde,3-rnethyl-
Synonyms:3-methylbenzldehyde
Source:Fluka Chern.
9l
l t9
65
t60 Adams: EssentialOil ComponentsbY GCiMS
RT: t0.20 AI: l0(r.5 KI: 1070 Octenol<(52)'>

CAS#:(t4215-73-6 MF: C8 Hl6 O FW: 128 MSD LIB#: 2055
1-ol,(52)-
CN: -5-octen-
Synonyms: none
RT: 10.20 AI: 106-5 KI: 1070 Sabinenehydrate <cis'> (IPP vs. OH)
CAS #: 17699- 16- 0 MF :C l 0 H l 8 O F W : 1 -5 4 MS D LIU #: 1438
CN: bicyclo(3.1.0)hexan-2-o|,2-methyl-5-(l-rnethylethyl)-,(la'2o,-5o)-
Synonyms:trans-4-thujanol;trans-sabinene hydrate(transfor Me vs. lPP, old narne)
Source:Strobilanthesoil ex P. Weyerstahl;25.007oMa.ioranalnrtensis, FF.T2:5-5(1987);
2 | .537oOriganum rotundifolium; 10.8|a/oOriganum nicranthum
RT: 10.22 AI: 1066 KI: 1070 Arbusculone <trans->

trans-
I -(5-ethenyltetrahydto--5-methyl-2-furanyl)-,
CN: ethanone,
Synonyms: none
Source: tridentata.SLC,UT ex RP Adams#5-577
Artemi.sia
^'$\
--ll-l'
t 6l
RT: 10.23 AI: 1066 KI: l07l Octanone<5-hyctroxy_4->

CAS#:496-77-5 MF; C8 H1602 FW: 144 MSD LIB#: 159',7
CN: -5Jrydroxy-4-octanone
Synonyms: butyroin,-5-octanot-4*one
Source:AldrichChem.
80
60
40
20
102
40 60 80 r0 0 120
RT: 10.29 AI: 1067 KI: 1072 Linalool oxide<cis->(furanoid)

CAS#:.5989-33-3 MF:Ct0 Hl8 02 FtV: t70 MSI) LIB#:988
CN: 2-furanmethanol,5-ethenyltetrahydro-u..a,5_tt.imethyl_,
cis_
Synonyms: linalooloxideB
Source;Lavenderoil ex Firmenischex AF Thornas;1i.r7vc Magnoliapurpureila
p.204.
in: AromaticPlants& Essentialco'stituents,peaceB..k co., fiong Kong(1993)
14.607oOsmanthusfragrans; I l.50VaCinnarnonlr,r,canrDhor"a
59
=
:
fl0
(:0 -\-
I btl
94 t / tl
40 -v
lll
t2l 1.55 -+r
t37tqt - t\
OH
40 60 80 r00 t20 140
RT: 10.30 AI: f 068 Kl: l0l2 Mentha-3,8-diene <p->

CAS#:586-67-4 MF -:C l 0 H l 6 FW: 136 MSD LIB#:.587
CN: cyclohexene,
4-merhyl-I -( I -methylethenyl)-
Synonylns;p-nrcntha-3.8-disne
Source:Dicerandrafnftescensoil ex Mark Deyrup, F-L
79
60
93
40 l 07
12l
RT: 10.30 AI: 1068 KI:1012 Norbornene-2-methanol <endo-S->

CAS#: 67671-06-l MF: C8 Hl2 O FW: 124 MSD LIB#: 118-5
( I R-endo)-
CN: bicyclo(2.2.1)hept-5-ene-2-methanol,
Synonyms:none
Source:ref. cpd. ex P. Weyerstahl
100
80
60
ID
40
20
100
RT: 10.31 AI: 1068 KI: 1073 Roseoxide<trans-dihydro->

CAS#:140238-19-5 MF: ClO H20 O FW: 156 MSD LIB#: 1366
CN: 2H-pyran,tetrahydro- (2S,4R)-
4 -methyl-2-(2-methylpropyl)-,
Synonyms:none
Source:IFF ex Jian-QinCu,Kunming
=
100
?
80
tftl
60 t/\
\ I
40 I
20
RT: 10.35 AI: 1069 KI: 1074 Dihydro myrcenol

CAS#:18479-58-8 MF: ClO H20 O FW: l-56 MSDLIB#;606
CN: 7-octen-Z-ol, 2,6-dimethyl-
Synonyms:none
Source:IFF ex Jian-QinCu,Kunrning
II
r00 I
80
60 I tl
40 Ion
20
Appendix III: Mass Spectla r63
RT; 10.43 AI: 1071 KI: 1076 Benzylformate

CN: formicacid,phenylmethyl cster
Synonyms: benzylmethanoate
Source:K & K ex H. Hills;1.20VaAcsciapraicox(flower),FFJI l:3(1996);
0.187oOcimumbasilicum;0.llVo Micheliaalba(flower)
t00
80
40 60 80 r0 0 120
RT: 10.43 AI: l07l KI: 1076 Cresol<p->

CN: phenol,4-methyl-
Synonyms:p-oxytoluene;
p-tolulol
Source:.Iasminabsoluteex Firmenischex AF Thomas:2l ,60VoJasminum , Dragoco
Repolt ll1996, 5-21;3.767oJasmirutmfficinale (absolute);2.867oJasminum /e (headspace)
t07
5t
60
63
77
80
90
r00
+
RT: 10.4-5 Al:1072 KI: 1076 Cresol <meta->
CN: phenol,3-mcthyl-
Synonyms:m-methylphenol; nr-oxytoluene;3Jrydroxytoluene;m-tolulol
Source:FisherSci.;2.33VoJqsninuntsanrbac,F'F-JI | :57(1996);2.017o
Narcisstt
0.457oNarcis sttsj onEtilla
t00 r0 8 OH
I
r-
\-.
79
RT: 10.52 AI: 1074 KI: 1078 Heptanal,dimethylacetal

CAS#:10032-05-0 MF: C9 H20 OZ FW: 160 MSD LIB#: 2l 13
1,1-dimethoxy-
CN: heptane,
Synonyms:none
RT: 10.61 AI: 1076 KI: 1080 Vertocitral C <cis->

CAS#:65405-78-9 MF:C9 Hl4 O FW: 138 MSD LIB#: 1552
CN: 3-cyclohexene-1
-carboxaldehyde, cis-
3,-5-dimethyl-,
Synonyms:dimethylcyclohexenecarboxaldehyde
Source:H & R Chem.ex Jian-QinCu,Kunming
100
80
60
40 60 80 100 t20
RT: 10.66 Al: lO77 KI: 1081 Tolualdehyde<p->

CAS#:104-87-0 MF: C8 H8 O FW: 120 MSD LIB#: l-510
4-methyl-
CN: benzaldehyde,
Synonyms: 4-methylbenzaldehyde
Source:FlukaChem.
91
r19 H
I
6.5
-V^rA"
l:
Appcndix lll: Mass Spectra t 65
RT: 10.70 AI: 1078 KI: 1082 Camphenilone

CAS#:13211-15-9 MF':C9 Hl4 O FW: 138 MSD LIB#: 820
CN: bicyclo(2.2.1)heptan-2-one,3.3-dimethyl-
Synonyn.rs:2-norbornanone, 3,3-dimethyl-
Source:Spmcelcal'oil ex E. von RudlolTandL. Hogge;0.llVo Micromeriacarminea,
JEOR 7 :4-57( 1995 ) ; 0. | }Vo A rtemi si a alba ; 0.077o Ci tronella ceyIon
RT: 10.71 AI: 1079 KI: 1082 Pyrazine<2-acetyl-3-methyl->

CAS#:23787-80-6 MF: C7 H8 N2 O FIV: 136 MSD LIB#: t3-52
CN: ethanone,
I -(3-methylpyrazinyl)-
Synonyrns:
none
Source:Pyrazinespecialties
ex Art Tucker
(:X
40 60 80
RT: 10.72 AI: 1079 KI: 1082 Allylhexanoate

CAS#:123-68-2 MF: C9 HI6OZ FW: 1.56 MS D LIB #; l l l
CN: hexanoicacid, 2-propenylester
Synonyms:allyl caproate
Source:H&R ex.Iian-Qin Cu, Kunming
t00
80
y'".,2")a*
60
40
20
RT: 10.76 AI: 1080 KI: 1083 Artemisia alcohol

CAS#: 51590-19-9 MF: Cl0 Hl8 O trW: 154 MSDLIB#:224
CN: l.-5-hcptadien-4-ol,
3,3,6-trinrethyl-
Synonyms:none
(Hungary),
Source:Arteni.siatridentata,SLC, UT ex RP Adanrs#5571;24.00VoArtemisia a.nn.ua
.IEOR7:4.5(| 995);1 .507. Artemisiajudaica
100
lo H
80 tl
60 %
40
20
RT: 10.76 AI: 1080 KI: 1083 Benzene<2-methoxyethyl->

CAS#: 3.5.58-60-9 MF: C9 Hl2 O FW: 136 MSD LIB#: 276
CN: benzene,( 2-methoxyethyl)-
Synonyrrs:pandanol,rnethylphenyl ethyl ether
Source:ref. cpd.ex.Iian-QinCu, Kunrning
RT: 10.78 AI: 1081 KI: 1084 Acetyl-2,5-dirnethyl

furan <3->
CAS#:10599-70-9 MF':C8 HlO ()2 FW: 138 MSD LIB#: 12
CN: acetyl-2,-5-dimethyl
luran<3->
Synonyms: none
43
0()
8()
6(I
40
--t-r
Appendix III: Mass Spectt'a 167
RT: 10.79 AI: l08l KI: 1084 Pyrazine<2,3-diethyl->

CAS#:15707-24-l MF: C8 H12N2 FW: 135 MSD LIB#: -53
CN: pyraxine,2,3-dicthyl-
Synonyns:none
Source:AldrichChem.
l 2l
RT: 10.80 AI: 1081 KI: 1084 Hexenal <(22)->, diethyl acetal
CAS#: 87383-46-8 MF: ClO H20 02 FW: 112 MSD LIB#: 804
CN: 2-hexene,I,l -diethoxy,(Z)-
Synonyrns:l, I -diethoxy-22-hexene
RT: 10.82 AI: 1082 KI: 1085 Cymenene<rrreta->

CAS#:1124-20-5 MF: Cl0 Hl2 F'W:132 MSD LIB#: 42(r
CN: benzene,I -rnethyl-3-(|-methylethenyl)-
Synonyrns:a-3-dinrethylstyrene;2-nr-tolylplopene;m-isopropenyltoluene
Sotrrce:Chatna.ecyparisnootkatenri.lleaf oil ex E,.von Rr.rdlolf;Identificationby
R. Laurent.Robertet.Fiance
t00
80
60
40
20
r68 Adarns:EssentialOil Componentsby GC/MS
r
RT: 10.86 AI: 1083 KI: 1086 Pyrazine<tetramethyl->

CAS#:Il24-11-4 MF: C8 Hl2 N2 FW: 136 MSD LlIl#: 69
CN: pyrazine,tetrarnethyl-
Synonyms: Iigustrazine
Source:AldrichChem.
100
80
60
40
20
RT: 10. 88 A I : 108 3 K I: 1 0 8 6 F e n c h o n e

CAS#: ll95- 79- 5 MF : C l O H l 6 O F W : 1 .52 MS D LIB #: 162
CN: bicylco(2.2.1)hepran-2-one.1,3,3-trimethyl-
Synonyms:2-norhornanone, 1,3,3-trimethyl-; 1,3,3-trimethylnorcamphor
Scrurce:SweetAnis leaves(Foeniculumvul7are) distilled, RP Adams #5452:
42.107o Lat,andulastoechas,I lth tntl. Cong.o['ljss.Oils, Frag.& Flav.,New Delhi,
India 4:l-5(1989125.107o Alninia katsunmdai(stem);24.30%Foeniculurttvulgare
RT: 10.88 Al: 1083 KI: 1086 Furfuryl propionoate

CAS#:623-19-8 MF: C8 H1003 FW: l-54 MSDLIB#:8l
CN: 2-furanmethanol,propanoate
Synonynts:llrfuryl alcohol,propionate
--:l -F
169
RT: 10.89 AI: 1084 KI: 1086 Linalooloxide<trans->(furanoid)

CAS#: 34995-77-2 MF: CtO Ht8 ()2 FW: | 70 MSD LIB#: 989
CN: 2-furanmethanol,5-ethenyltetrahydro-o,,o,-5
_trimethyl_,trans_
Synonyms:linalooloxide A
sotrrce:Lavencleroif ex Firmenischex AF Thomas;2r.10Toosmanthus
Jra.grans,
Rastit.Resur.22:243(1986);l0.80voCinnanrcmumcamphora;7,g9vo
Ma.giolia purpurella
r00
=
80 .:
60
( / tl
40 :
=
tl7As I
OH
4u ou E0 100 120
RT; 10.94 AI: 108.5 KI: 1088 Butyl angelate

CAS#:7785-64-0 MF: C9 Hl6 ()2 FW: 156 MSD LIB#: 1992
CN: 2-butenoic
acid,2-methyl-,butylestcr(22)-
Synonyms:none
Source:BedoukianRes.ex.I.J. Brophy; 34.907oAntlrcmisnobilis, Plantamed. 57:231(1991\
100 r00
80
60
40
RT: 10.94 AI: 108-5 KI: 1088 Cyclohexanedione<3,methyl-1,2->

CAS#: 3008-43-3 MF: C7 HlO ()2 FW: 126 MSD LIB#: 1687
CN: 1,2-cyclohexanedione,3-methyl-
Synonynrs:none
o
tl
\-,
l'10 Adams:EssentialOil Componentsby GC/MS
RT: 10.94 AI: 108.5 KI: 1088 Mentha-2'4(8)-diene<p->

CAS#:586-63-0 MF : C l 0 H l 6 F-W:136 MSD LIB#: 586
3-methyl-6-(1
CN: cyclohexene, -methylethylidene)-
Synonyms:p-mcntha-2,4(8)-diene; isoterpinolene
Source: oil
Dicerandra.frutescetxs ex Mark Deyrup,FL
Q
<2->
RT: 10.97 AI: 1086 KI: 1088 Acetylthiophene
CAS#:88-15-3 MF: C6 H6 O S FW: 126 MSD LIB#:-51
CN: ethanone,I -(2-thienyl)-
Synonyms: ketone,methyl2-thienYl
Source:Aldrich
O---
RT: 10.98 AI: 1086 KI: 1088 Terpinolene

CAS#: 586-62-9 MF: C l0 H l6 FW: 1-16 MSD LIB#: 9l6
CN: cyclohexene, 1-methyl-4-(l -methylethyliclene)-
Synonynrs:p-mentha-1,4(8)-diene, isoterpincne
Jun,iperushrcayan.aleal-oil, RP Aclanrs#2863; 49 ]07a Vepriselliotii, .fEOR 7 :441(1995);
Sor.rrce:
40.287oProtiturtheptaphy-llum(stem); 18.917oPistacia r,'erc(fruit hull)
-rm
Appcnclixlll: MassSpectra
t 7l
RT: I l.(X) AI: 1087 KI : 1089 G uaiac ot < o- >

CAS#: 90-0.5- | MF: C7 H8 ()2 FW: 124 MSD LIB#: 7.5.5
(-N: phc nol.2- lr rc tl ro x y -
Synonyrrrs:anastil;gLraiastil: o-hych.oxyanisolc:
o-ntctlrylcatcchol;pyroguaiacaci

CAS#: .5I 79.5-7.5-6 MF: C l0 H20 02 F'W: 172 MSt) LIU#: 2 | 19
CN: 3- hex c ne.I , l -d i e th o x y -,(3 1 1 )-
Synonynts:none
Source:RedoukianRes.
I 00
80 o\-r'-
60
40
20
RT: | | .03 AI: 1087 KI: 1090 Nonanone<2->

CA S #: 821- - 55- 6 MF: C9 Hl8 O FW: 142 MSDLIB#: l167
CN: nonanonc(2-)
Synonyrrrs: metlrylheptylketone
S or u' c e:
K & K c h c n r.c -xH . Il i l l s ; 2 4 1 0 % R u tagraveol en,r,
S ci . P harrn.56:l 2l (l 9gg)l
| 6.21X Rrrta cItaIepc tt.ti,t
o
r00
80
ll
,n,.,-,r,u-.r.
60
40
)a l
172 by GC/MS
EssentialOil Components
RT: 11.0.5AI: 1088 KI: 1090 Linalool <dehydro->

CAS#:000-00-0 MF: ClOHl6 O FW: 152 MSDLIB#: 1013
CN: not assigned
Synonyms: none
100-.,11
80 a\,
60 (ill
40
A
RT: 11.0-5 AI: 1088 KI: 1090 Norbornen-2'olacetate<exo'S'>
CAS#:5257-37-4 MF: C9 Hlz 02 FW: 152 MSD LIB#: 1182
-en-2-ol,acetate,exo-
CN: bicyclo(2.2.1)hept-5
Synonyms:none
of norbornen-2-ol<exo-5->(6288)
Source:acetylation
RT: 11.07 AI: 1088 KI: 1090 Methyl benzoate

CN: benzoic acid, methyl ester
Synonyms:noibeoil; clorius
Source:Jasminabsoluteex Firmenischex AF Thomas; 4l.217oPolianthestuberosa,
p. 109,in: Aromatic Plants& EssentialConstituents,PeaceBook Co', Hong Kong(1993);
32.347oGardenia j asminoi d es; 23.407oN ar cissus i onquiI la
RT: 11.08 AI: 1089 KI: l09l Pentvlbutanoate

CAS#:-540-18-l MF:C9 Hl8 ()2 FW: 158 MSD LIB#:313
CN: butanoicacid, pentyl ester
Synonyn.rs: arnyl butyratelpentyl butyrate
Source:artiljcial blackberryflavor, Lorann Oils; 0.03VaOsmanthusfragrans,
Rastit.Resur.22:243(1986); 0.01VaSpartiumjunceunx(absolute);
0.0 | %;Spartium j unceum (headspace)
//t'\./t\r/")a-
RT: | 1.09 Al: 1089 KI: l09l Cymenene

<p->
CAS#;1195-32-0 MF: ClOHl2 FW: 132 MSDLIB#:427
CN: benzene,1-melhyl-4-(l -methylethenyl)-
Synonyms:a-p-dimethylstyrene; dehydro-p-cymene; 4-isopropenyltoluene
Source:Clmmaecyparisn.ootkatensis leaf oil ex E. von Rudloff
'i' .,\
| [)
IY
rl -\
, f , , lll,
140
RT: | 1. I I AI: 1090 KI: l09l Hexenyl methyl carbonate <(32)->

CAS#: 67633-96-9 MF: C8 Hl4 ()3 FTV: l-58 MSD LIB#: 204-5
CN: carbonicacid, (32)-3-hexenylrnethylester
Synonyms:none
Soutcc:BedrrukianRes.
\,-7\."\A OMe
6
RT: 11.14 AI: 1090 KI: 1092 Epoxymyrcene<6,7->

CAS#:29414-55-9 MF: ClO H16O FW: 152 MSD LIB#: l02l
CN: oxirane.2,2-dimethyl-3-(3-methylene-4-pentenyl)-
Synonyms: mlrceneepoxide
Source:Lippia multitlora oil ex C. Menut & G. Lamaty;7030Vo Lippia rnultiflora (leaf),
FFJ10:7-5(1995)
RT: 11.14 AI: 1090 KI: 1092 Hexenal<diethylacetal'(32)'>

CAS#:73545-18-3 MF:ClOH20o2 FW 172 MSDLIB#:2121
CN: 3-hexene, (Z)-
1,1-diethoxy-,
Synonyms:none
o .
\€-,J-OA
<3->
RT: I l.14 AI: 1090 KI: 1092 Isopropyl'2'methoxypyrazine
CAS#:25773-40-4 MF:C8 H12 N2 O FW: 152 MSD LIB#: 1622
CN: pyrazine,2-methoxy-3-(
I -methylethyl)-
Synonyms: none
100
80
60
40
20
Appendix III: Mass Spectla 175
RT: | |.l5 AI: 1088 KI: 1090 Isobutyltiglate

CAS#:(t1692-84-O MF: C9 H1602 FW: 156 MSD LIB#: 860
CN: 2-butenoic cster,(E)-
acid,2-methyl-,2-methylpropyl
Synonyms: none
Source: AldrichChem.ex Art Tucker;0.347o nobilis(Japan),
Anthenris Koryol6 | :93(1989);
0.037o Arfthemis nobilisflndia)
80
60
4t)
20
RT: 1l.l9 Al:1092 KI: 1093 Butyl pentanoate

CAS#:-591-68-4 MF:C9 Hl8 02 FW: 1.58 MSDLIB#:330
CN: pentanoicacid, butyl ester
Synonyms:butyl valerate;valeric acid. butyl ester
Source;Aldrich Chem.;0.017aSpaniumjwtcewn, Rivista Ital. EPPOS325-343(1992)
:-,,'\.t.4-ol\--\
tl
RT: | 1.20 Al: 1092 KI: 1093 Ethyl sorbate

CAS#:2396-84-l MF: C8 Hl2 02 F-!V:140 MSD LIB#: 2149
acid,ethylester,(2E,48)-
CN: 2,4-hexadienoic
Synonyrns:sorbicacid,ethylester
Source:Bedoukian Res,
r00
80
60
40
20
l',l6 Adams: Essential Oil Components by GC/MS
RT: 11.22 AI: 1092 KI: 1094 Norbornen-2-olacetate<endo-S->

CAS#:99295-40-6 MF: C9 Hl2o2 FW: l-52 MSD LIB#: 1179
CN: bicyclo(2.2.| )hept-S-en-2-ol,acetate,endo-
Synonyms: none
Source:acetylation of norbornen-2-olcendo-5 ->(6294)
100
80
60 @N*
40
20
RT: | 1.23 AI: 1093 KI: 1094 Pyrazine<methylthio->

CAS#:21948-70-9 MF: C5 H6 N2 S FW: 126 MSD LIB#: 1354
CN: pyrazine,(methylthio)-
Synonyms: none
Source:PyrazineSpecialtiesex Art Tucker
RT: I t.30 AI: 1095 KI: 1096 Hexenyl propionate <(32)->

CAS#: 33467-74-2 MF: C9 Hl6 OZ F'\M:l-56 MSD LIts#: 1946
CN: (3Z)-hexen-1-ol, propanoate
Synonyms:hexenylpropionate,cis-3-
Source:BedoukianRes.ex.I.TBrophy; 0.377oChamomillarecutifa,DragocoRept.
3-3 | (l 992); 0. | 6VoLi q ui damber fo tmosana; 0. | }VoArt emisi a annua
Appendixlll: Mass Spectra
t 77
RT: I I .32 AI: 109-5KI: 1096 Carnphenone <6->

CAS#:.53803-33-l MF':Cl0 Hl4 O F-W:l-50 MSI)LIB#:617
CN: bicyclo(2.2,1 5.-5-dirnerhyl-6-rncthylcne-
)hcptan-2-one,
Sytronyrns:none
Soulce:Diltlotaeniacachrl,difttlioe
erxK. Harkiss
100
80
60
40
20
RT: | 1.32 AI: 109.5KI: 1096 Linalool

CAS#:78-10-6 MF:Cl0 Hl8 O FW: 1.54 MSDLIB#:307
CIN: di rnethyl-| -6-octadien-3-ol<3.7->
Synonyrns: none
Soulcc: distiflation of black pepper,RP Adants#-5448;94.90o/r,
Cirutanutnuurtcanrlthoro.,
JIroR 4:l6l(1992); 94.2()a/o Cirmamonn.m pertlrcno$,ltnt:89.00vaMichelictalba
40 60
RT: I l.3ti AI: 1097 KI: 1097 Nonenal <(62;)->

CAS#:2271-19-2 M F : C 9 H l (r 0 F W : 140 MS D LIB #:2131
CN: 6-ntrnen al,(67,)-
Synonyrrs: nonc
Source: tscdoukian Res.
178 bv GC/MS
RT: 11.40 AI: 1097 KI: 1098 Ethyl heptanoate

CN: heptanoicacid,ethylester
Synonyms:ethylenanthate,ethylheptylate,enanthicether
Source:AldrichChem.;0.l5VoCitrusreticulata(leaf),JEOR2:331(1990);
0.107oNarcissustazetta(absolute);
0.lU%oCitrusmedica(leaf)
\,-
tl
o
RT:11.40 AI: 1097 KI: 1098 Nonanol<2->

CAS#:628-99-9 MF: C9 H20 O FW:144 MSDLIB#:1816
CN: 2-nonanol
Synonyms:sec-nonyl
alcohol
Source:alcoholsmix (2-OHs) ex K-H Kubeczka;2.007oCurcumaheyneana,
FFJ 7: l9( 1992); 1.407oCurcumaaeruginosa;| .30VoPsidium guajava
RT: 11.41 AI: 1098 KI: 1098 Sabinenehydrate <trans-> (IPP vs. OH)
CAS#: 15826-82-l MF: C10 Hl8 O FW: 1-54 MSD LIB#: 1439
(1o,2B,-5cr)-
CN: bicyclo(3.1.0)hexan-2-o1,2-methyl-5-(1-methylethyl)-,
Synonyms:cis-4-thujanol;cis-sabinenehydrate(IPP vs. Me, old name)
Source:Strobilanthesoil ex P. Weyerstahl;85.307oMentha candi,cans,Ag. Biol.
Chem.42:433(1978);26.207oLippia ukambemsis;10.007oThymuspinewood
43
Appcndixlll: MassSpcctra 179
RT: 11.42 AI: 1098 KI: 1098 Heptenol acetate<(32)->

CAS#: 1516-78-9 MF: C9 Hl6 02 FW: 1.56 MSD LIR#: 2077
CN: 3-lrcpten-
I -ol. acetate(32-)
Synonyms:none
Sourcc:lledoukianRes.
RT: l 1.42 AI: 1098 Kl: 1098 Hexenal <(2E)->,diethyl acetal

CAS#: 67146-30-9 MF: ClO H20 02 FW: 172 MSD LIB#: 803
C N: 2lr ex ene,l. l -d i c th o x y -,(E )-
Synonyrns: (E)-I . l -diethoxy-2-hexene
Sclurcc:tsedoukianRes.ex Art Tucker
80
60
4(
20
RT: I I .4-l Al: 1098 KI: | 098 Linalool <tetrahvdro->

CAS#: 78-(r9-3 MF : C l O H 2 2 O F -W :l -58 MS D LIB #: 1475
CN: 3-octanol.3,7-dinrethyl-
Synonyrns: 2.6-climetlryl-(r-oc:tanol
SoLrrce: SCM Chcnr.ex H. Hills
RT: 11.44 AI: 1099 KI: 1099 Dimethylstyrene<2,5->

CAS#:27576-03-0 MF: ClO Hl2 FW: 132 MSD LIB#: 612
CN: benzene, ethenyl-,dimethylderiv.
Synonyms: dimethylstyrol
RT: I 1.45 AI: 1099 KI: 1099 Pineneoxide<a->

CAS#:1686-14-2 MF:ClO Hl6 O FW: 152 MSD LIB#: 1302
CN: 3-oxatricy clo(4.| . | .02,4)octane,2,7,7-trimethyl-
Synonyms: 2,3-epoxypinane
Source:ref.cpd.ex Tom Phillips,FSU
RT: 11.46 AI: 1099 KI: 1099 Naphthalene <cis-decahydro'>

CAS#: 493-0l-6 MF: ClO Hl8 FW: 138 MSD LIB#: 567
CN: naphthalene,decahydro-,cis-
Synonyms:cis-decalin; cis-perhydronaphthalene
80
60
40
20
I
AppcndixllI: Mass Spectla

181
RT: | 1.48 AI: I 100 KI: I 100 Undecane<n->

CAS#: 1120-21-4 MF: Cll H24 FW: 1.56 MSD LIB#: 90
CN: undecane
Synonyrns:hendecane
Source:Alltech Assoc.; 13.307oAcacia praecox,FFJ I I :3( 1996);7 .50vopittosporum tobira;
6.157o Cymlsidium sinense
cH3(cH2)scH3
4u 6U 80 100 120 14
RT: I L49 AI: I100 KI: I 100 Ipsenol

CAS#:35628-0-5-8 MF: C10Hl8 O FW: 1.54 MSD LIB#: 849
CN: 7-octen-4-ol,2-methyl-6-methylene-
Synonyms: none
Source:ref'.cpd.ex Tom Phillips,FSU
RT: 11.49 AI: I100 KI: I100 Isopentyl2-methyt butanoate

CAS#:27625-35-0 MF':ClO H20OZ FW:172 MSD LIB#: 871
CN: butanoicacid,2-methyl,3-methylbutyl
ester
Synonyms: isoamyl2-methylbutanoare;
isopentyl2-methylbutyrate
r00
80
60
40
t8 2 Adams: EssentialOil Comnonentsbv GCiMS
RT: I 1.50 AI: I 100 KI: I 100 Methyl butyl-2'methyl butyrate <2->
CAS#: 2445-18-5 MF: Cl0 H20 02 l:W: 172 MSD Ltll#: 1698
CN: butanoicacid,2-methyl-,2-tnethylhutyl ester
Synonynrs: none
Source:Aldrich Clrenr.;12.007aAnthenisnobilis,EssenzeI)eriv. Agrum.93:107(1913);
0.547oMyrtus t:onuntrnis(unripe l'ruit):0.407oAchillea willtelmsii (Egypt)
----l--'-"/---
RT:11.50 AI: ll02 KI: 1103 Perillene

CAS#:.539-.52-6 M F ' :C l 0 H l 4 O Flil: 150 MS D LIB #: 362
CN: tLrran,3-(4-rnethyl-3-pentenyl)-
Synonyms:none
Snurce:carrot seecloil ex Nestleex A Chainteau:2.'107o Erigeron canadensis,
(
JEOR4 :227 |992): 0.12VoRosa d ama scenai 0.40Va Ab i es hoIop h -t'
I Ia
RT: 11. . 51 A I : l100 K I: l l 0 0 N o n a n a l< n ->

CAS #: 124- 19- 6 M F :C 9 H l 8 O h W:1 4 2 MS D Ll Il #:39
CN: l-nonanal
Synonyrns; pelargonaldchyde
Sgurce:re'f.cpd.ex R. von Rudloff; 16.637o Frag,ariax Qnanosst(lea|, .TIIOR-5:10-5(1993);
7.29VaListtstrum sinense(flower); 4.907o Canmr carvi
oV.(cHz)z-CHa
l(
80
60
40
)al
100
-rrtr-FFr
Appendix
III: MassSpectla 183
RT: 1 l.-53 AI: I l0l KI: I 101 Hexyt propanoate

CAS#: 2445-76-3 MF': C9 HIS 02 trW: l-58 MSD LIB#: 16-59
CN: Propanoicacid. hexyl ester
Synonyrrs:Hexyl propionate
Sonrce:Alclrich Chern.;0.207aHibisats abelmo,schrus, FF.I 7:65(1992);
0. | 7 7o CIrontonti lla recut i ta ; 0.06VoLat'anclulo x ht b ri da
80
--Y"\--^v1-,/
60
40
20
4u. 60 E0 100 120 l4
RT: ll.-56 AI: I l0l KI: I 102 Heptenyl acetate<(22)->

CAS#: 83540-70-9 MF: C9 Hl6 02 FW: 1.56 MSD LIB#: 794
CN: 2-hcpten-l-ol, acetatc,(Z)-
Synonyrns: none
Soutcc;IledoukianRes.ex Art Tucker
r00
80
60
40
20
RT: I l.-5(r AI: l l0l KI: I 102 Thujone <cis->

CAS#:-546-80-5 MF : C l 0 H l 6 0 F IM: l -52 MS D LIB #: 1497
CN : 4-rnethyl-I -(methylethyl)bicyc lo(3.I .0)-hexane-3-one
Synonyrns:a-thujone
Source:ref. cpd. ex E. von Rudlol'l'
=
:
H,.
qL',(./ ;- -o
Y-
l \l
t\ I
l\ |
:
=
184 by GC/MS
Adams:EssentialOil Cornponents
RT: 1l.-58 AI: I 102 KI: 1102 Phenylpropanal<2->

CN: benzeneacetaldehyde, cr-methyl-
Synonyms: phenylpropionaldehyde, o-; cumenealdehyde;hyacinthal;hydrotropicaldehyde
Source:Givaudan ex H. Hills
RT: 11.59 AI: 1102 KI: 1103 Octadienal<(2E,,48)'>

CAS#:30361-28-5 MF:C8 Hl2 O FW:124 MSD LIB#: 2153
CN: 2,4-octadienal,(2F,,48)
-
Synonyms: trans,trans-octadienal
RT:11.60 AI:1102 KI: 1103 Disulfide'dipropyl

CN: disulfide,dipropyl
Synonyms: propyl sulfide,dipropylsulfide
100 .-*zt-rA/
80
60
40
20
185
RT: I I .60 AI: 1102 KI: I 103 Isopentyl isovalerate

CAS#: 6-59-70-l MF: Cl0 H2OOZ hW 172 MSt) LIB#: 922
CN: isopentyl-3-methylbutanoic acid
Synonyms:isoarnylisovalerate
Source:Jwiperus monticola f . compactaleaf oil, Rp Adams #2-580
-r---"lT
RT: IL62 AI: I103 KI: I103 Octadienal<2,2-dimethyl-3,4->

C A S #: 590- 71- 6 MF: ClO Hl6 O F W : 152 MS D LIB #: 1203
CN : 3,4-octadienal,2,2-dimethyl-
Synonyr-ns: none
Source:rcf'.cpd. ex E. Von RudlofT
100
80
60
40
20
RT: I 1.6-5 AI: I 103 KI: l 104 Hexenyl propanoate<(28)->

CAS#: -53398-80-4 MF: C9 Hl602 FW: l-56 MSD LIB#: 19-53
CN: 2-hexen-l-ol, prclpanoate,(E)-
Synonyms:none
Source:Iledoukian Res.ex .I.TBrophy
186 Adams: EssentialOil Componentsbv GC/MS
RT: I L6.5 AI: I 103 KI: 1104 Methyl butyl isovalerate<2'>

CAS#:2445-77-4 MF: C10H20 OZ FW: 172 MSD LIB#: 1689
ester
CN: butanoicacid,3-methyl-,2-methylbutyl
Synonyms: ester
isovalericacid,2-methylbutyl
Source: AldrichChem.
I
I
\-/\,,-o\,.\,/
ttl
r8
<2->
RT: 11.66 AI: 1104 KI: 1104 Isopropyl-5-methyl'(2E)-hexenal
CAS#:69104-96-7 MF:ClO H18O FW: 154 MSD LIB#: 1626
5-rnethyl-2-(
CN: 2-hexenal, (2E)-
I -rnethylethyl)-,
Synonyms: aldehyde
isodihydrolavandulyl
Source:AldrichChem.
43
RT: 11.69 AI: I 104 KI: 1105 Fenchocamphorone <a->

CAS#:40550-41-2 MF: C9 Hl4 O FW: 138 MSD LIB#:711
CN: bicyclo(2.2.l)heptan-2-one, -, ( I R,4R)-
7,7-dimethyl
Synonyms: none
Source:ref. cpd.ex Y. Yuasa,.Iapan
r87
RT:11.72 AI: 110-5KI: 1106 VertocitralC <trans->

CAS#:65405-19-0 MF: C9 Hl4 O FW: 138 MSD LIB#: 1.5.53
CN: 3-cyclohexene-
I -carboxaldehyde,
3,5-dirnethyl-,
trans-
Synonyms: dimethylcyclohexene
carboxaldehyde
Source:H & R Chem.ex Jian-QinCu,Kunming
r00 67
80
60
40
R T : 11. 74 A I : l 1 0 6 KI: l l 0 7 D i me th y l p henol< 2,6->

CAS#: 576-26-l MF: C8 HtO O FW:122 MSD LIB#: 750
CN: phenol,2,6-dimethyl-
Synonyms:2,6-xylenol
Source:Grob mixttrrefor GC, Alltech Assoc.;0.28VoOsmanthus.fragrans,
Rastit.Resur. 22:243(l 986)
OH
I
\r,^.
\)
RT: I 1.7.5AI: I106 KI: I 107 Phenytethytatcohol

CAS#:60-12-8 MF: C8 Hl0 O FW:122 MSDLIB#: 1362
CN: benzeneethanol
Synonyms:benzyl ethanol
Source:Roseoil ex Firmenischex AF Thomas
r00
80
60
40
20
r8 8 Adams: EssentialOil Componentsby GC/MS
RT: I 1.77 AI: 1106 KI: 1 108 Leaf alcohol <ethyl acetal->
CAS#: 28069-14-l MF: ClO H20 OZ FW 172 MSD LIB#: 2116
CN: 3-hexene,l-(l -ethoxyethoxy)-,(32)-
Synonyms:leaf acetal
RT: 11.77 AI: 1106 KI: 1108 Maltol

CN: 4H-pyran-4-one,3-hydroxy-2-methyl-
Synonyms:larixic acid; palatone;veltol
Source:ref. cpd. ex Guy Collin; 8.207oTrifolium pratense,J. Ag. Food Chern.
44 : | 827( | 996) ; 5 .307oTr ifoli um r ep ens; 0.447oAb i es bal samea
fi"
126
RT: | 1.77 AI: I 106 KI: I108 Rose oxide <cis->

CAS#: 4610-11-1 MF: ClO Hl8 O FW: 154 MSD LIB#: 729
CN : 2H-pyran, tetrahydro-4 -methyl-2-(2-methyl- 1-propenyl)-, (2R,4S)-
Synonyms:rose oxide levo
Source:Geraniumabsoluteex Firmenischex AF Thomas;2.397aPelargoniumgraveolens,
Acta Pharm.Sinica 24:336(1989);7.347oCitrus sinensis(leaf);0.507oCistusladaniferus
AppcndixIII: MassSpcctra
r89
RT : 11. 80 A l: I 1 0 7 KI: I 1 0 8 Ac ro l e i n < (3 E )-(2-furyl )->

CAS#: .19-5| l-08--5 MF: C7 H6 02 t-W: 122 MSI) LII]#: 2030
CN: 21'opcnal, 3-(2-luranyl)-,(2IJ)-
Synonyrrrs:nonc'
Sourcc:lJecloukianRes.e,x.l.IBrophy
t 00
tt0
60
40
20
+u ()(, u (l I(x) 120 140
RT : I 1. 8( r A l: I 1 0 8 K I: I I l 0 rv -Ie n th a tri erre

< 1,3,g-p->
CA S #: 183( r 8- 9 .5 -l MF : C l O H l 4 F W: t3zt MS I) LIB #: t236
CN: 1.3-cyclohexacliene, I -nrcthyl-4-(l-r-nethylethgryl)-
Synonl,ltrs: none
Sotrrce:clistillationof ll'cshparsley.RP Aclarrrs #-5440;64.10(n,petro.selimtm cri,slttun,
J. Ag. Fo.d clrcrnr.3(r:467(1988); 24.64%petnt.sclitutnt,sati,urn (hcr.b);
2.30()(,
Api urn g raveolerts
t 00 9l
80
60
40 d
-\
R' l- :ll. 9t ) A l: l l 0 9 K l : l l l l B e n z a l d e h yde,cl i methyl acetal

C A S #: | 12. 5- 8 ti -8 MF : C 9 H l 2 0 2 trW : t.52 MS t) LIB #: 268
(lN : lrcnzcno,(clinrcthoxylrre(hyl )-
,Synonyrrrs: plrcnyldinrertlroxyl-rrcthans; clin.rcthoxyphenylntethane
Soul'c'g; Bccloukian Rcs.cx Art Tuckcr
?
Me-oAo-Me
190 Adams:EssentialOil Componentshv GC/MS
RT: | 1.9.5 AI: | | l0 KI: 1112 Octen-3-ylacetate<1->

CAS#: 2442-10-6 MF: C l0 H I 8 ()2 F'W: I 70 MSD LIR#: I 206
CN: l-octen-3-ol.acetate
Synonyms:octen-3-olacetate,| -
(NanaAlha),
Source:re[. cpd. ex Art Tucker; 3.007oLavandulaangr.tstifoli.a
Perf. & Ftav. 9:49(1984):1.607o Lavandulaangustfolia (Twickel Purple);
O.63VoLepeclrin i o urbani i
z+J
# I
O-Ac
RT: 11.98 AI:1111 KI:1113 Camphenol<6->

CAS#:3570-04-.5 MF: Cl0 Hl6 O FW: 1.52 MSD LIB#: 618
5,-5-dimethyl-6-rnethylene-
| )heptan-2t1,
CN: hicyclo(2.2.
Synonyms: nojigikuol;6-hydroxycamphene
ex K. Harkiss
Source:Diplotaeniacaclu,-difoliae
""-o\
R T: 1 1. 99 A I : llll KI:1 1 1 3 H e p te n y l a c e ta te< (28)->
CAS#: 16939-13-4 MF: C9 Hl6O2 FW: 156 MSD LIB#:793
CN: 2-hepten-l-ol,acetate, (E)-
Synonyms:trans-2-heptenyl acetate
Source: Bedoukian Res.ex Art Tucker
43
o" o*
- l i ;F -
I
Appendix III: Mass Spectla t 91
RT: 12.00 AI: l l l2 KI: 1114 Isopropyl-5-methyl-(22)-hexenal

<2->
CAS#:69104-97-8 MF: ClO Hl8 O FW: 154 MSD LIII#: 1627
CN: 2-hexenal.
-5-rnethyl-2-( yl)-,(Z)-
I -rnethylerh
Synonyms: none
Source:AldrichChem.
100
80
60
40
20
40 60 80 100 120
RT: 12.00 Al: ll12 KI: I I l4 Thujone<trans->

CAS#:471-1.5-8 MF: ClOHl6 O FW: 1-52 MSDLIB#:1496
CN: bicyclo(3.l .O)hexan-3-one, I -( 1-methylethyl)-,
4-nrethyl- ( l S-(lo,4B,5c)-
Synonyms: B-thujone
Source:ref. cpd.ex E. vonRudloff
RT: 12.02 AI: I I 12 KI: I l 14 Heptyl acetate

CAS#: 112-06-l MF: C9 Hl8 ()2 FW: l-58 MSD LIB#: 780
CN: aceticacid, heptyl ester
Synonyrns:heptylethanoate
Sottrce:acetylationof heptanol(6209);0.|07o poeticrts(absolute),
Narcissu.s
FF.I9:l-59(1994);0.097o Zingiberofficinale;0.03%Heraclewnplatytaenium
t92 Adanrs:EssentialOil Componentsby GC/MS
RT: 12.03 AI: 1112 KI: I I l4 Nlethyl butanoate,3'methyl-3-butenyl<3'>

CAS#: 54410-94'5 MF: ClO Hl8 ()2 FW: 170 MSD LIB#: 144
CN: butanoicacid, 3-rnethyl-, ester
3-methyl-3-butenyl
Synonyms:none
Source:Amyris cliatrypaoil, Dom. Rep. ex Tom Zanoni
)"--..-"rL-|-
R T: 1 2. 07 A I : 1ll3 KI: 1 l 1 6 O c ta d i e n o l< QE ,4 E )->

CAS#: 18409-20-6 MF: C8 Hl4 O FW: 126 MSD LtB#: 2104
CN: 2,4-octadien- 1-ol, (28,4E)-
Synonyms:none
R T: 1 2. l0 A I : I I 14 KI: I | 1 6 F e n c h o l< e n d o ' >

C AS #: 14575- 74- 7 MF :C l 0 H l 8 O FW: 154 MSDLIB#:712
CN : bicycfo(2.2.1)heptan-2-ol,1,3,3-trinrethyl-, endo-
Synonyms:s-fenchol
Source:K & K Chem.ex H. Hills
'- ou
i - I- .[-
AppendixIll: MassSpectra
193
RT: 12.2-5 AI: I I 17 KI: 1 120 Sabina ketone <dehydro->

CAS#: 36262-12-l MF: C9 HlzO FW: 136 MSD LIB#:214
CN: bicyclo(3.1.0)hex-3-en-2-one, 5-(l -rnethylethyl)-
Synorrynrs:lebaicone
Scrurce:
Artemisiaperscia oil ex P. Weyerstahl
otl
P.T 12.21 AI: I ll8 KI: I l2l Isophorone

CAS#:78-.59-l MF: C9 Hl4 O FW: 138 MSD LIB#: 968
CN: 2-cyclohexen- I -one,3,-5,5-trirnethyl-
Synonynrs:isoacetophorone
Source:ref. cpd.ex Z. Fleisher
r00 82
\-^-l
80
lr >
60 Ytl
40 o
RT: 12,28 AI: I I 18 KI: I 12l Fenchol <exo->

CAS#: 22627-95-8 MF: C10 Hl8 O FW: l-54 MSD LIB#: 713
CN: bicyclo(2,2,l')heptan-2-ol,1,3,3-rrimerhyl-,exo-
Synonyms:B-l'enchol
t94 Adams:EssentialOil Componentsby GC/MS
R T:12. 29 A I : 1118 KI: l 1 2 1 Me n th -2 -e n -l -o l<ci s-p->

CAS#: 29803-82-5 MF: Cl0 Hl8 O FW: 1-54 MSD LIB#: 10-5fi
CN: 2-cyclohexen- I -nrethylethyl)-,
I -ol, I -ntethyl-4-( cis-
Synonyrns: none
Source:distillation of Marjorarn leaves(Schilling),RP Adams#-542-5
t00
80
60
40
20
RT: 12.30 AI: 1I 19 Kl 1122 Ethyl hexanoicacid <2->

CAS#:149-57-5 MF:C8Hl6()2 FW: 144 MSDLIB#:7-51
CN: hexanoicacid,2-ethyl-
Synonyms:2-ethylcaproicacid;butyl ethyl aceticacid
Scrurce:Grob rr.rixture tirr G, Alltech Assoc.;0.107oLa',vsoniainennis (flower), JEOR 7:42-5(199-5);
0 .02VoH ed vch i unt co r onar i urn; 0.0 17oM alus anr.oId i ana
OH
I
R T 12. 32 A I : l119 K l : l I2 2 M y rc e n o l
CAS#: 543- 39- 5 MF :C l OH l 8 0 F W :1 5 4 MS D LIB #: l l 18
CN: 7-octen-2-ol,2-methyl-6-rnethylene-
Synonyms:none
Source:IFF'ex SuzanneKral; I .407oEl,sholtz.ia blanda,Proc.lntl. Cong.of Ess.Oils,
New Delhi, India 4:49(1989); 1,127o Hyssopus fficinalis:0.70% Viburnunrorientale(leaf)
r60
t
-IF-r
Appcnclix
Ill: MassSpectla t 95
RT: f 2.33 AI: I I l9 Kl: | 122 1\{entha-2,8-dien-l-ol <trans-p->

CA S #: 7212- 40 -0 MF: Cl0 Hl6 O F W: l -52 MS I) LIB #: t069
CIN:2-cyclohcxen- | -ol, | -rnethyl-4-(
I -rncthylerhcnyl)-,
rrans-
Synonynrs: none
Sout c e:r c l. c pd .c x G u y C o l l i n
(x)
80
60 N
A
RT : 12. 33 A I : I I l 9 K l : l l 2 2 P i n e n el ry d r ate< trans->
CAS#: 4948-29-2 MF': C l0 H l8 O FW: l-5zt MSI) LIB#: 1.100
CN: bicycfo(3.| .l )hcptan-2-o1,2.6.6-trinrcthyl-. ( ls.2F.5c)-
Synonyms:pinan-2-ol<trarls->
Source:rcl'. ct-rcl.
ex li. von Rudlol'l'
i)
|(x)
80
60
,+0
,$
2(
RT : I 2. 35 A t : I 1 2 0 K I: I 1 2 3 O c ta n o la c e tate< 3->
C A S #:48( 14-l-63 MF: C l0 H20 02 F W : | 72 MS D LIB #: 12-54
CN: 3-octanol.acetate
Synonynrs:none
Sourcc: acctylationo1'pcppermint oiI (-5498.t
I 00
u0
60
't()
20
196 hy CC/MS
Adams:EssentialOil Compcrrrenls
RT: f 2.40 Al 1121 Kl:1124 Ethyl3-hydroxyhexanoate

CAS#:2305-25-l MF: C8 H16()3 FW: 160 MSD LlIl#: 2146
ethylester
CN: hexanoicacid,3-hyclroxy-,
Synonyms: caproicacid,p-hyclroxy-,
ethylestcr
Source:Bedoukiau Res.
OH
..,^__.rl_.__\-\
RT: | 2.4-5 Al 1122 KI: I 125 Roseoxide <trarrs->

CAS #: 5258- 11- 1 MF : C 1 0 H l 8 O F W; l -54 MS D LIB #:727
CN: 2H-pyran-,tetrahydro-4-methyl-2-(2-methyl-I -propenyl)-,(2R-trans)-
Synonyms:none
Source:Geraniumabsoluteex Firmenischex AF Thomas;3.547oPelargoniumgraveolens,
p.317. in: Flav. & Frag.:AWorld Persp..Lawrence,etal.,Ploc. 1OthIntl. Cong.of lrss.Oils'
Elsevier,Arnsterdam(I 988):0.82qoCistusparadisi;0.207oCitrus sirrcnsi's
<l->
RT: | 2.45 AI 1122 KI: I 125 Undecyne
CAS#:2243-98-3 MF: Cl I H20 FW: 1.52 MSD LIB#: l-526
CN: l-undecyne
Synonyms: none
Soulce:Pfaltz& Bauerex Art Tucker
AppendixIII: MassSpectra 197
flT:12.46 AI: ll22 KI: 1126 Campholenal<u->

CAS#: 4-501-.58-0 MF: Cl0 Hl6 O FW: 152 MSD LIB#: 903
CN : 3-cyclopentene-I -acetaldehyde, 2,2,3 -trimethyl-
Synonyms:u-campholenaldehyde
Source:Jwdpents gamboanaex RP Adams #2574; common in Juniperusspecies
and other conifers
4rJ 60 80 100
RT: 12.-50 Al:1123 KI:1127 Methyl octanoate

C A S #: lllll- 5 MF: C9 Hl8 t)2 FTV:158 MSD LIB#: I105
CN: octanoicacid, methyl ester
Synonyrns:methyl caprylate
Source:Af drich Chem.: 2.817oPsiditunguajava, p.221 , in: Aromaric planti and
EssentialConstituents, PeaceBook Co., Htxg Kong(1993);2.177oSchinusnrolle(berry);
1.78VaM agnoI i a grand ifl o ra
RT: 12..53 AI: ll24 Kl1127 Chrysanthenone

CN: bicyclcr(3.1
.1)hept-2-en-6-one,
2,7,7 -trimethyl-
Synonyms:2-pinen-7-one
Source:Artenisia vestitaex P. Weyelstahl:6.847oArtemisi.ajudalca (Egypt),
IEOR 2:271(1990); 6.307oArtemisia j udaica (lsrael);4.207oArtemisia herba
RT:12.54 AI:1124 KI: ll28 Stemone

CAS#:22457-23-4 MF: C8 Hl7 N O FW: 143 MSD LIB#: 1434
oxime
5-methyl*,
CN: 3-heptanone,
Synonyms: oxime
-5-methyl-3-heptanone
ex Jian-QinCu,Kunming
Source:Givaudan
RT: 12.55 AI:1124 KI: 1128 Norborneolacetate<endo-2->

CN: bicyclo(2.2.l)heptan-2-ol,acetate,endo-
Synonyms: none
Source:acetylationof norborneol,<endo-2->(6300)
80
60
40
20
100 140
RT: 12.59 AI ll25 KI:1129 Norborneol acetate <exo'2'>

CN: bicyclo(2.2.1)heptan-2-ol, acetate,exo'
Synonyms:none
Source: acetylation of norborneol (6277)
Appcndix III: Mass Spectra 199
RT: f 2.64 Al: ll2l KI: I | 30 Octyl forrnate j
CAS#: 112-32-3 MF: C9 Hl8 ()2 FW: l-58 MS D LIB #: l 2l 0

i
CN: fornric acid, octyl ester'
I
I Synonyms:none
Sottrce:Pfaltz & Bauer ex Att Tucker; 0.8lVa Dendranthetnavestitr,ltt(flower absolute),
p. 9-5,in: AronraticPlants& L,sscnt.ial
Constitucnts, PeaceBook Co., Hong Kong(1993)
o(cH2hcH3
100
80
60
40
20
40 60 80 t00 l2{)
RT: 12.68 AI: | 127 KI: l 13I Butyl tiglate

CAS#:7785-66-2 MF: C9 Hl6O2 FW: l-56 MSDLIB#:2143
CN: 2-butenoicacid. 2-methyl,butyl ester,(2H)-
Synonyms:butyl o,-methylcrotonate
Source:BedoukianRes.;0. l57o Lc;andula x h:-brida,p. 36-5,in: Lavendeet fl-avandin,
R. Nael Rivistaltal. EPPOS(1992);0.127o Antltemi,s
nobilis;0.llVa Anthemisangustifolia
o
tl
/>:a\
I
R T : 12. 70 A I : I 1 2 8 Kl : l l 3 2 Oc i n re n e< a l l o->

C A S #:1216- 56 -0 MF : C 1 0 H l 6 F W : 136 MS D LIB #: I199
CN: 2,4,6-octatriene, 2,6-cli methyl-,(8,7)-
Synonyms:allocinrene,4-trans,6-cis-; allocirnene,(48,62)-
Source:Fluka Chem.
200 Adams: EssentialOil Comrronentsbv GCiMS
RT 12.72 Al: I128 KI: 1132 Epoxy-ocimene<(Z)->

CAS#:33281-83-3 MF: Cl0 Hl6 () FW: 152 MSDLIB#: 1756
-methyl-2,-penladienyll-
CN: oxirane,2,2-dimethyl-3-U.2Z)-3
Synonyms: epoxy-ocitnctte<cis->
Source:Wornrwoodcv. PowisCastle,CalililrniaGardensNursery
79
P.T:12.77 AI: I 130 KI: 1133 Terpineol<l->

CAS#: -586-82-3 MF : C l 0 H l 8 O F W: 1 .54 MSDLIB#: 1002
CN: I -methyl-4-(l -nrethylethyl)-3-cyclolrexen-1-ol
Synonyrns:p-menth-3-en- I -ol; 3-terpinen-I -ol
Source:West Indianlime oil, LorannOils
100
80
60
40
20
propanoate
RT: 12.79 AI: I130 KI: 1134 Cyclohexyl
CAS#:6222-35-l MF: C9 Hl6 02 FW: l-56 MSD LIts#:534
CN: propanoic
acid,cyclohexylester
Synonyms:cyclohexylpropionate
Appendix
Ill: MassSpectra 201
RT : 12. 82 A I : l l 3 l KI: I l 3 -5 L i n a l o o l < d i hydro-> i

CA S #: 18479- . 5 1 -l MF : C l 0 H 2 0 O F W: l -56 MS I)LIB #: l 0l 5r
CN: 6-octen-3-ol. 3,7-climethyl- |
Synonynrs:dihydrolinalool
Source:SCM Chem.ex Il. von Ruclloffl| .507oCitrus,tinensis..IEOR 7: l0-5(199-5):
0.597oAntomtuttsubu.l,atunt; 0 JATo Eucalyptus globulus
il
100
RT: 12.82 AI: I l3l Kt: I l3-5 l\lyroxide<(Z)->

CAS#:94601-48-4 MF: C10Hl6 0 FW: 1.52 MSD LIB#:I l19
CN: crxiranc,
2,2-dinethyl-3,(3-rnethyl-2,4-pentadienyl)-,(Z)- ,
Synonynrs:ocimene epoxide.B-
Source:Firmcnisch ex.fian-QinCu,Kunnting
RT: 12.88 AI: I 132 KI: I l3(r Limonene oxide <cis->(Me vs. IPP)
C A S #: 13831- 1 5 -l M F : C 1 0 H l 6 O F ' W: 152 MS D LIB #: 1007
CN: 7-oxal"ricyclo(4. l .0)hcptane.I -rnethyl-4-(| -rncthylethe.nyl)-,(
I o,4u.6a)-
Synonynrs: p-nrentl.r-8-ene,1,2-epoxy-,cis-;1,2-epoxydipentene
Source:Aldrich Chcnr.
t00 a2-
80 a)
tl
II
60
40 i
')(\
-\
j
202 Adams: EssentialOil Comoonentsbv GCiMS i
RT: 12.90 AI: I 133 KI: I 137 Pyrazine<3-methyl-2-isobutyl->

CAS#:13925-06-9 MF: C9 Hl4 N2 FW: 1.50 MSD LIB#: 1353
CN: pyrazine,2-methyl-3-(2-methylpropyl)-
Synonyms:none
Source:PyrazineSpecialtiesex Art Tucker
(:r.
RT: 12.93 AI: I 133 KI: I 137 Mentha-2,8-dien-1-ol <cis'p->
CAS#:3886-78-0 MF: ClOHl6 O FW: 152 MSDLIB#: 1070
CN: 2-cyclohexen-l-ol, I -methyl-4-11 cis-
-rnethylethenyl)-,
Synonynrs:none
Source:ref.cpd.ex GuyCollin
t00
80
60
40
20
RT: | 2.94 AI: I | 34 KI: I 138 Benzeneacetonitrile

CAS#:140-29-4 MF: C8 H7 N F\M:l17 MSDLIB#:1797
CN: benzeneacetonitrile
Synonyms:phenylacetonitrile,benzyl cyanide,u-tolunitrile
Source:Mace oil ex Mario Tellez
RT: l2.94 AI: I 134 KI: 1138 Thujanol<iso-3->

CAS#:1112-79-0 MF: Cl0 H18O FW: 1.54 MSD LIII#: 1488
CN: bicyclo(3.I .0)hexan-3-ol,
4-methyl-I -(I -merhylethyl)-,(
| S-(I a,3c,4B,-5a))-
Synonynrs: isothu.jol
Source:rcf. cpd.ex E. vonRudlolT
'.,o
I
RT:12.97 AI: 1134 KI: I138 Terpineol<trans-dihydro-ft->

CAS#:3901-93-1 MF: ClO H20O FW: 156 MSD LIII#: 1470
CN: cyclohexanol,
I -rnetl'ryl-4-(
| -methylethyl)-,
trans-
Synonynrs:
p-nrenthan-I -ol,lrans-
Soulce:SCMChems. ex H Hills
RT: l2.98 AI: I 134 KI: l 139 Cresol acetate<o->

C A S #:. 533- 18-6 MF: C9 HlO 02 H W: 1-50 MS D LIB #: 482
CN: aceticacid, 2-rnethylphcnylester
Synonyms:2-acetoxytoluene; 2-ntethylphenylacetateto-tolyl acetato
Source:acetylationof o-cresol(6446)
RT:1 2 . 99 A I ; 113- 5 K I:1 1 3 9 P i n o c a rv e o l c tra ns-> ,

CAS#: 547-61-5 MF: Cl0 Hl6 O FW: 1.52 MSD LIB#: 1309
CN: bicyclo(3.1. t )heptan-3-ol,6,6-dirnethyl-2-methylene-, ( I S-(I ct,3o,5o))-
Synonyms:2( l0)-pinen-3-ol,( | S,3R,5S)-
Source:ref. cpd. ex B. von Rudloff; 26.707oChenopodium. ambrosioides,.IEOR 7:221(1995);
7 .507aLavanduladentata;7.007oEucall,ptuskirtoniana
4l
100
RT:13.02 AI:113.5 KI; 1140 Nopinone

CAS#:386-51-65-9MF: C9 Hl4 O FW: 138 MSDLIB#: 1173
CN: bicyclo(3. 6,6-dimethyl-
1.I )heptan-2-one,
Synonyms: none
Source:AldrichChem.;0.08Vo Hyssopus fficinalis,.IEOR7:39(1995);
p
0.037aSantoIina chamaec1t arissus; O.0
| 7o Pinus p inaster
40 60 80 luu tzu
RT: 13.04 AI; 1136 KI: 1140 Menth-2-en-l-ol <trans-p->

CN: 2-cyclohexen-l -ol, I -methyl-4-(I -methylethyl)-,trans-
Synonyms:none
Source:distilled from Marioram leaves(Schilling),RP Adams #5425;
22.807oCymbopogon jwarancusa,p.317,in: Flav. & Frag.:A World Persp.,
Lawrence,etal.,Proc. 1OthIntl. Cong. of Ess.Oils, Elsevier,Amsterdanr(1988);
| .7O7oZin g ib er casswnunqr ; 1. | 07oArte misia moo r cr oft i ana
43
Appendix
R T : 13. 07 A I : I 1 3 7 KI: I l 4 l Ve rb e n o l< c is->

CAS#: | 84.5-30-3 MF: C l0 H l6 O FW: l -52 MSD LlIl#: 15-5I
CN: bicyclo(3.l . | )hept-3-en-2-ol, 4,6,6-trinretlryl-, ( t u.28,.5u)-
Sy nony r ns2-: pin c n -4 -ocl .i s -
Sourcc:ret'.cpcl.ex Rocky MountainForestServiceStation,Ft. Collins,C();
1.35ok Cl eon.ia lusi tan i ca,.IEOR 3 :441( 199 1); 0.807aLavand ula t'i.ridi s;
030% J u tti.perus fl acc icla
100
80
60
40
€,"
20
RT: 13.08 AI: I137 KI: I l4l Butanoate<3-methyl-2-[rutenyl2-methl->

CAS#:842-54-80-8 MF: ClO Hl8 02 FW: 170 MSD LIB#: 1.579
CN: butanoicacid,2-methyl-,
3-methyl-2-butenyl
ester
Synonyms:
Source:Clrcrtopodiutn
bot\',rex VasuDev
RT: 13.10 AI: l137 KI: 1142 Epoxy-ocimene <(E)->

CAS#:28977-57-3 MF: Cl0 Hl6 O FW: l-52 MSD LIB#: 17-57
CN: oxirane,
2,2-dimethyl-3-[(2E)-3-rnethyl-2,4-pentadienyll-
Synonyrns:
epoxy-ocimene<tt'ans->
Source:Wormwoodcv. PowisCastleex CalilbrniaGardensNursery
R T: 1 3. 10 A I : 1137 K l : l l 4 2 L i m o n e n eo x i d e<trans' > (Me vs.IP P )

CAS#: 4959-35-7 MF: C10 Hl6 O FIM: 1.52 MSD LIB#: 1008
CN: 7-oxabicycto(4.1 .0)heptane, l-methyl-4-(I -methylethenyl)-, ( I o,4p,6o)-
Synonyms:1,2-epoxy-trans-p-menth-3-ene
=_
i
-t9,
-\
RT: 13.10 AI: ll37 Kl 1142 Sabinol <trans-> (trans for OH vs.IPP)
CAS#: 29606-16-6 MF: Cl0 Hl6 O FW: 152 MSD LIB#: 1367
CN: bicyclo(3.1 .0)hexan-3-ol, 4-methylene- ( 1S,3R,-5S)-
l -( I -methylethyl)-,
Synonyms:4( I O)-thujen-3-ol, cis-
Source:ref. cpd. ex P. Weyerstahl;14.137oArtemi,siakawakamii,p.279 ' in; Aromatic
Plants& EssentialConstituents, PeaceBook Co., Hong Kong(1993);
A rtentisia ersica; 3.2 | VoArt entisia absinthunt
J .00a/a p
RT: 13.1-5Al: I138 KI: 1143 Geijerene

CAS #: 6902- 13- 4 MF : C l 2 H l 8 F.W:162 MSDLIB#:149
CN: cyclohexene,4-ethenyl-4-rne'thyl-3-(I -methylethenyl)-,(3S-trans-)-
Synonyms:o-nentha-3,8-diene, I -vinyl-(I S,2S)-
Source:Anq\risdiatr1,6Dorn. Rep. ex Tom Zanoni 14.607oWiedentanniaorientalis,
JEOR tt:-543(1996);5.00qoSkimmialqureol,a;3.627aPimpinella anisunt
I
lr^
v\-,=
RT: 13.l8 AI: | 139 KI: l 143 Pinenehydrate <cis->

CAS#: 4948-28-l MF: Cl0 Hl8 O FW: l-54 MSD LIB#: l30t
CN: bicyclo(3.I . I )heptan-2-ol,2,6,6-trirnerhyl-.
( I a,2o,-5
a)-
S y nr r ny nr pi
s :nan -2 -o l .c i s
Source:ret. cpd. ex E. von RudlofT
R T : 13. 19 A I : 1 1 3 9 K l : I1 4 4 T a g e to n e< (E )->

C A S #:6752- 80 -.1 M F -:C l 0 H l 6 0 F W : 152 MS D LIB #: 14-56
CN: -5,7-octadien-4-one, 2,6-dimethyl-,(E)-
Synonyn.rs: trans-tagetone
Sotrtce:Tagete,s nilnutctoil ex E,.Hcthelyi, Hungary 40.297oTagetesriojana,
JIIOR 7:319(l99-5);25.405(,Tagetesten.ufolia;l6.l0Vo Tageteslemntonii
4
RT: 13.20 AI: | 140 KI: 1144 Ocimene<neo-allo->
C A S #: 3016-| 9- | MF: C l0 H l6 F W: 136 MS D LIB #: I l 98
CN: 2,4.6-octatriene, (E,E)-
2,6-dinrethyl-,
Synonyrns: allocirncneB; allocitncnc,(4E,6I1)-
Sourcc':Fluka Chcm.
ll
ffi
i
208 Adams: EssentialC)il Conrponentsby GC/MS I
I
RT: 13.20 AI: | 140 KI: 1 144 Terpineol <cis-p->

CAS#: 7299- 41- 4 MF: Cl0Hl8 O F W : l -5 4 MS D LIB #: 1003
CN: cyclohexanol,1-methyl-4-(| -nrethylethenyl)-, cis-
Synonyms:none
Source:West Indianlime oil, LorannOils; 6.987oCitrttsparadlsi,JEOR 7: l0-5(1995);
0.907oVitex agnus-cdstus; 0.85% M aj o ratm lrort ensi s
RT: 13. 21 A l: 1140 K l : l 1 4 4 Is o c i tra l< e x o ->

CAS#: - 550. 50- 40- 3 M F :C l 0 H l 6 O F l i l : 1 .52 MSD LIB#: 1726
CN: 6-octenal,7-methyl-3-methylene-
Synonyms:none
Scrurce:Backltou,siacitriodora oil ex. Ian Southwell
RT: | 3.22 AI: I 140 Kf : I 144 Verbenol <trans->

CAS#: 1820- 09- 3 M F ' :C l 0 H l 6 O trW : 1 5 2 MS D LIB #: 1539
CN: bicyclo(3.1. l )hept-3-en-2-ol, 4,6,6-trimethyl-,( I 4,2u,-5u)-
Synonyms:2-pinen-4-ol,trans-
Source:rel'.cpd. ex Rocky Mountain F-orestSelvice Station,Ft. Collins, C0;
7.607oArtemisi.averl.otiorum.l:tsJ l0:2-5(1995);7.00%Anentisiavul,g,aris;
2.747o M i crtnneri a carrnitrea
.-][-Tr
Appendixlll: Mass Spectra 209
RT : 13. 23 A l: l l 4 0 K I: l 1 4 5 l p s d i e n o l
CA S #: 3. 5628-0 0 -3 MF : C l 0 H l 6 O F W : l -52 MS D LIB #: 848
CN: 2,7-octadien-4-ol. 2-rnethyl-6-rmcthylene-
Synonynrs: none
Source:r'ef-.cpd. ex H. Hills
100
RT: 13.23 AI: 1140 KI: ll45 Isoplrorone <4-keto->

CAS#:1125-21-9 MF: C9 Hlz OZ FW: l-52 MSD LIB#: 969
CN: 2-cyclohexener-1,4-dione,2,6,6-trirnethyl-
Synonyms: ketoisophorone; oxophorone; oxoplrolone
Source:rel'.cpd.ex Z. Fleisher
100
80
60
40
RT: 13.2.1AI: I 140 KI: | 14.5 Myroxide<(E)->

CAS#:94607-47-3 MF: Cl0 Hl6 0 FW: 1.52 MSDLIB#: 1120
CN: oxirane,
2,2-dimcthyl-3-(3-mcthyl-2,41entaclicnyl)-,(tr)-
Synonynrs:ocimene epoxide,(E)-B-
Source:Firmcnischex .fian-QinCu,Kunrning
j
210 Adams: Essential Oil Componentsby GC/MS
R T:13. 28 A I : 1141 K I: 1 1 4 6 C a mp h o r
CAS#:76-22-2 MF: ClO H16O FW: 152 MSD LIB#: 896
e <l ,7,7->
CN: trimethylbicyclo(2.2.1)heptan-2-on
Synonyms:bornanone,2-
Source:Juniperus bermudiana ex RP Adams #2554; common in conifers;
86.66VoCinnamomumparthenoxylum,p.31, in: Aromatic Plants& Essential
PeaceBook Co., Hong Kong(I993); 83.87VoCinnamomumcamphora;53.46Vo
80
60
40
20
40 60 80 100 120
RT:13.28 AI: ll41 KI:1146 Veratrole

CAS#:9l-16-7 MF:C8 H1002 FW: 138 MSD LIB#: 1-538
CN: benzene,1,2-dimethoxy-
Synonyms:catechol dimethyl ether; o-methoxyanisole;pyrocatechol dimethyl
95
80 77
60
65
40
40 60 80 100 120
RT: 13.30 AI: 1142 KI: 1146 Hexenylisobutanoate <(32)->

CAS#:41519-23-7 MF: C10Hl8 02 FW: 170 MSD LIB#: 811
CN: propanoicacid,2-methyl-,3-hexenylester,(Z)-
Synonyms:hexenylisobutyrate<32->
67
100
Appcnclixlll: MassSpectta 2ll
RT: 13.33 Al: 1143 Kl:1147 Terpineol <trans-dihydr.o-o->

CA S #:- 51l4- 00- l MF : C l 0 H 2 0 O F W: l -56 MS D LIB #: 1472
CN: cyclolrcxanclnethanol, o,a,4-trirnethyl-,
trans-
Syntlnynrs: p-ntenthan-8-ol, tt"ans-
Source:rcl'. cpcl.ex B. von Rucllol'f
=
:
tl
tl
tl
|
-oH
RT: I3.34 AI: I 143 Kl: 1147 Isoamyl angelate

CAS#: 10482--5-5-0 MF: C l0 H | 8 ()2 lrW: | 70 MSI) LIII#: t 989
CN: 2-butenoicacid,2-urethyl-,3-methylbutylester(Z)-
Synonyms:none
Sotrrce:Bedor-rkian
Res.ex .IJ Brophy; l'7.907oAnthenis nobilis (Italy), .I. HRC & CC -5:182(19821
11.38%Antlrcnr,isnobilis (England);8.397oAnthemisnobilis (llgypt)
)-^-")4
RT: 13.37 Al 1144 KI: | 148 Isopulegol<neo->
CAS#: -59905--53-2 MF: C l0 H l 8 O FW: 154 MSD LIB#: 880
CN: cyclohexanol, ( I a, 28,-5cr)-
-methylethenyl)-,
-5-methyl-2-(l
Synonyrns:none
Soulce:Aldrich Chem.
100
212 Adams: EssentialOil Conrponentsby GC/MS
!
RT: 13.37 AI: I144 KI: 1148 Necrodol<trans-c->
CAS#:104104-38-3MF: Cl0Hl8 O FW: l-54 MSDLIB#:2094
I -methanol,
CN: 2-cyclopentene- ( I R-trans-)
3,4,5,-5-tetramethyl-,
none
Synonynrs:
Source:Lavandulaluisieri.ex NicolasBaldovini
!'no"'\oH
RT: 13.38 AI: 1144 KI: 1148 Heptalactone<T->

CAS#:105-21--5 MF: C7 H1202 FW: 128 MSDLIB#: 191.5
CN: 2(3H)-furanone,dihydro-51ropyl-
Synonyms:4-heptanol ide
Source:ref. cpd. ex.lJ Rrophy 0.157aZiry'phusittitrha (t'tuit),JEOR 8:323-326(1996);
0.04% Citrus bergamia
80
60
40
2A
100
40 t00
RT: f 3.40 Al ll44 KI: | 1,19 Nonen-l-al <(22)->

CAS#:60784-31-8 MF: C9 Hl6 O FIV: 140 MSD LIB#: l 169
CN: 2-nonenal,(Z)-
Synonyms: none
Source:BedoukianRes.ex Art Tucker; 0.247aMicromeria canninea,JEOR 7:457(1995);
Pistaciavet? (liuit hull)
0.Il7o Sideritisdicltotoma:0.017o
I
i
Appendix
III: MassSpectra
i 213
RT: 13.43 Al: I14.5 KI: I149 Camphene hydrate

CAS#:64474-11-9 MF: Cl0 Hl8 O FW: t-54 MSD LIB#: 904
CN: bicyclo(2.2.
I )heptan-2-ol.
2,3,3-trimerhyl-,(
I R-endo)-
Synonyms: 3-methylcamphenilanol;
3-methylcamphenilol
Source:Jmiperus flaccida var.poblana ex Rp Aclams#25l8 common in
2.3lVoArtemisiaan,nua(leal).JEOR 3:33 (1991);2.l0VoCurcumaa
2.097oArtemisia anruta (flower)
43
100
80
60
40
20
80
R T ; 13. 43 A I : 1 1 4 .5 K I: l l 4 9 Is o p u l e g o l
CAS#: t21468-66-4 MF: ClO Hl8 O FW: 154 MSD LIB#: 879
CN: cyclohexanol, -5-rnethyl-2-(l -methylethenyl)-, (1a,2u,581-
Synonyms:none
Source:Aldrich Chern.;1 1.207oSature.jagitliesii,JEOR 8: I 83( I 996);
| 0.33VoEucalltptuscitriodora; 4.907oCitrus hystrix
4l
-:
80
67 tl
60
40
8l
121 \-1.
20
40 60 80 100
RT:13.43 AI:1145 KI: ll49 Myrcenone

CAS#:-539-70-8 MF: Cl0 Hl4 O FW: t-50 MSD LIB#: 1020
CN: 2,7-octadien-4-one, 2-methyl-6-methylene-
Synonyms:ipsdienone
Source:Liltpia javanica oil ex JW Mwangi, Kenya; l4.B5ToHyptis mtttabilis, EOR7:81(199-5)
83
100
80
60 55
4{)
=
214 Adams: EssentialC)il Comnonentsbv GC/MS
RT: 13.4.5 Al: I l4-5 KI: 11.50 Menth-3-en-8-ol<p->

CAS#: 24302-23-6 MF: C l0 H I 8 O Flil: 154 MSD LIII#: 588
CN: l-cyclohexene-l -methanol,c,o,4-trimethyl-
Synonyms:p-rnenth-3-cn-8-ol
Source:Dicerandrafi'utescennoil ex Mark Deyrup, FL
t00
80
60
40
20
RT: 13.47 Al: I146 KI: 11.50Eucarvone

CAS#:.503-93--5 MF: Cl0 Hl4 O FW: l-50 MSD LIB#: 1793
I -one,2,6,6-trimethyl-
CN: 2,4-cycloheptadien-
Synonyms:none
Source:ref. cpd. ex lan Southwcll'.1."70o/oMeli,ssafficinalis, in: FlavorlrCornposition
olLemon Balm, I. Nykaenen,etal.,l,ebensm.-Wisc. U-Technol.,19:482(1986);
g
Ang eIica a r chang eli ca: 0.367oRibes n.i
0.40a/o runr
RT: 13.47 AI: I146 KI: 11.50Phenol<2112)-propenyl->

CAS#:23.508-99-8 MF: C9 H10O F'W:134 MSD LIB#: l27l
CN: phenol,2-(lZ)-1-propenyl-
Synonyms:none
AldrichChem.
Sourcc:
-ilt:flnF'
i
RT: 13.50 AI 1147 KI: I l -51 Hexyl isobutanoate

CAS#: 2349-07-7 MF: Cl0 H20 02 FW: t12 MSD LIB#: 817
CN: propanoicacid, 2-methyl-,hexyl ester
Synonyms:hexyl isobutyrate
Source:Pfaltz & Bauer ex Art Tucker
\.4=4=."t|
60
40
20
40 60 80 100
RT: 13.-50AI:1147 KI: I l5l Thujanol<neoiso-3->

CAS#;21653-19-0 MF: ClO Hl8 O FW: l-54 MSD LIB#: 1490
CN: bicyclo(3.L0)hexan-3-ol,4-methyl-I -( I -methylethyl)-,( I S-(I o,i
Synonyms:neoisothujol
Source:ref. cpd. ex E. von RudlofT
+-)
93
t2l
40 60 80
RT: 13.51 AI: ll47 KI: I151 Butanoate<3-methvl-2-butenvl

CAS#:89026-29-9 MF: ClO Hl8 C)2 FW: 170 MSD LtB#: 1580
CN: butanoicacid, 3-methyl-,3-methyl-2-butenylester
Synonyms:none
Source: Chenopoditunbotrys ex Vasu Dev
4l
69
8-5
216 Adan.rs:EssentialOil Componentsby GC/MS
RT: 13,54 AI: 1148 KI: 11.52Tagetone <(Z)->

CAS#:3.588-18-9 MF: Cl0 Hl6 O FW: l-52 MSDLIB#: 1455
ien-4-one,2,6- dimethyl
CN: -5,7-octad -, (Z)'
Synonyms: cis-tagctone
Scrurce:
Tagetes mirultaoil ex E. Hethelyi,Hungary;68.20VoTagetesterniflora,
JEOR-5:679( 1993);27.157.Tagetes minuta;| 1.007o Lippiadattensis
R T: 1 3. - 5- 5A I : 1148 K I: 1 1 .5 2 Me n th o n e
C AS#: 89- 80- 5 MF : C l 0 H l 8 O F T V :l -5 4 MS D LIB #: 126l
CN: cyclohexanone,5-methyl-2-(I -methylcthyl)-,trans-
Synonyms:p-menthan-3-one, trans-
Source:Peppermintoil, McCormick Co.; 60.007oMentlw longifolia'
Par.f.,Cosm.,Arolres 64:83(t985); 57.207oMenthaspicata;54.Il7o Satureiaboliviana
t00
80
A
60 (-(
40 :
20
RT: 13.-57 AI: I 148 KI: 11-53 Isoamyl tiglate

CAS#: 41. 519- 18- 0 M F : C 1 0 H l 8 O 2 F \M : 1 7 0 MS D LIB #: 1990
CN: 2-butenoicacid, 2-methyl-,3-methylbutyl ester (2E)-
Synonyms:none
Source:Bedcrukian Res.ex .I.IBrophy;0.447oAn.thenisnobilis(.Tapan), Kolyo 161:93(1989)
100
80
60
-t^"\o-
40
AppcndixIII: MassSpectra 217
RT : 13. . 58A I : l l 4 8 K I: l l -5 3 C i tro n e l l a l

CAS#: 106-23-0 MF-:ClO Hl8 () FW: 154 MSD LIB#: 923
CN: c1imcthyl-6-octcnal <:1,7->
Synonynrs: 2,3-dihydrocitral ; rhodinal;3.7-dimethyl-6-octenal
Strttrce:Jttnipenrsmonticola f. conrpat:taleaves.RP Aclams#2580; 86,22 &tcatl,ptuscitriodora,
p. 50, in: AromaticPlants& Essenrialconstituents,PeaceBook co.. Hong Kong(1993);
16.55 % Li t,sea cuIteba : 65.40a/aCit rus h vs n-ix
RT: 13..59 AI: | 149 KI: I l-53 Ethyt hexyl acetate<2->

CAS#: 103-09-3 MF: ClO H20 02 FW 172 MSD LIB#: 673
CN: aceticacicl,2-ethylhexylester
Synonynrs:2-ethylhexyl ethanoate l
S<rurce:Afdrich Chern.:l.l0% Alpinia katsumadai(seed),JEOR 2:259(1990);
0.107t,Al p ini a chine rtsi s ( fl ower)
-"Y'A
RT: 13.59 AI: 1149 KI; 11.53Nonadienol

<(38,62)->
CAS#:56805-23-3 Ml;: C9 Hl6 O FW: 140 MSDLIB#:2129
I -ol,(3b,62)-
CN: 3,6-nonadien-
Synonyms: none
Source:IledoLrkian
Res.
RT: 13.60 A7 ll49 KI: 1153 Thujanol<neo-3'>

CAS#:21653-lS-9 MF: Cl0 Hl8 O FW: 154 MSD LIB#: 1491
(1S-(14,3p,44,5cl))-
CN:bicyclo(3.1.0)hexan-3-o1,4-methyl-1-(l-methylethyl)-,
Synonyms: neothujol
Source:ref. cpd.ex E. von Rudloff;0.267oArtemisiamoorcroftiana,
p.26, in: Newer Trendsin Ess.Oils & Flav., P. Weyerstahl,New Delhi, India(l
43
=
?./'.'*/""
V z
:
60 80
RT: 13.62 AI: ll49 KI; 1 154 Isobutyl hexanoate

CN: hexanoic acid, 2-methylpropyl ester
Synonyms: i sobutyl caproate
Source:Afdrich Chem.; |.327oMichelia balansae,p. 15, in: Aromatic Plants&
Constituents;PeaceBook Co., Hong Kong(l993); 0.237oMicheliafigo (flower)
99
tr7
129 t42
4A 60 120 140
RT:13.64 AI: 1150 KI: 11-54 Nonadienal<(28,62)->

CAS#:557-48-2 MF: C9 H14O FW: 138 MSD LIB#: 1162
CN: 2,6-nonadienal,(E,Z)-
Synonyms:cucumberaldehyde;nonadienal,trans-2,cis-6-;violet leafaldehyde
Source:Aldrich Chem. ex Art Tucker; l3.O07aViola odorata, Pytochemistry 31 t(tee?):
0. 1OVoN ar ci ssus p oet icus; 0.077oAc aci a farn esi ana
to0'.,1l
80
60 70
Appendix lll: Mass Spectra 219
RT: 13.73 AI: ll52 KI: I156 Benzene

<pentyl->
CAS#:.538-6U-l M F : C l I H 1 6 FW: 148 MSDLIB#:422
CN: benzene,pentyl-
Synonyms:amylbenzene;phenylpentane;pentylbenzene
Source:Celery seecloil (distilled in lab), RP Adams #5434
100
80
60
40
20
RT : 13. 74 A I : l 1 -5 2 KI: l l -5 7 N o n e n -l -o l < (.3Z,)->

CAS#: 10340-23-5 MF: C9 Hl8 O FIM: 142 MSD LIB#: l t70
CN: 3- nr r nen
- l -o l .\L )-
Synonynrs; noue
Source:Afdrich Chem.;0.727oAcaciafaruesiana(blossornabsolute), J. Ag.
F oodChenr 3l:. I 1 6 7 (1 9 8 3 )
RT: 13.79 AI: l1.53 KI: I l-58 Phenvl-tert-butanol

CAS#:100-86-7 MF: Cl0 Hl4 O FW: 150 MSDLIB#: 1284
CN: benzenecthanol,cr,o-dimcthyl-
Synonyms:2-benz,yl-2-plopanol
; benzyldimcthylcarbinol
Soutce:K & K Chem. ex Art Tucker
r00
80
60
40
20
Adams:RssentialOil ComPonentsbY GC/MS
220
RT: 13.80 AI: I t.54 KI: I l -58 Nerol oxide

CAS #: 1786- 08- 9 MF: C10H l6 O FW: l'52 MS D LIB #: I 139
l -propenyl)-
CN: 2H-pyran,3,6-clihydro-4-rnethyl-2-(2-rnethyl-
Synonyms:none
Stu..": Firnrenisch ex .Tian-Qin Cu, Kunming;0.157nZantho*lum nitidwt,
p. 7-5,in: NewerTrcn<lsin Ess.Oils & Flav',P' Weyerstahl'New Delhi' lndia(1993);
i)I }qo D, o, or:ep halunt nto Idavi ca; 0.097oRosa d amascenct
A
A
RT: 13. 82 A I : | 15 4 KI: I1 5 9 Ka ra h a n a e n o n e
C AS #: 19822' 67- 4 MF : C l 0 I{ 1 6 O FW: 152 MS D LIB #: 516
CN: 4-cyclohepten-l -one,2,2,-5-trirnethyl-
Synonyms:none
Source;cupressus,sargentiioil ex Larry Cool;0.70% crytressu,s senxpentrens'
composition of cypressoil, J. Garnero,etal,
in: Contributionto the study ol'the chenrical
Paper# I I 2, Cong.Ess.Oils, Kyoto( l 977)
4l
t\
x,
R T: 13. 83 A I : 11.5 4 KI: 1 l -5 9 P i n e n eo x i d e< p' >
C A S #: 6931- . 54- 0 MF :C 1 0 H l 6 O F ' W:l ' 5 2 MS IIL IB #:1303
CN: spiro(bicyclo(3. I . | )heptane-2,2'-oxirane), 6,6-dimethyl-
Synonyrns:pinane,2, I 0-ePoxY-
(leaf), 'TEOR2:61(.1990);
Source:Alclrich Chem.ex H. i{ills; 0.207oJttrtiperus.foetidissima
0.20%J trniperus tilo rl i n (zi i
4l
:[lJt-.
RT: 13.83 AI: I 154 KI: l l -59 Sabina ketone

CAS#;513-20-2 MF: C9 H14O F'W:138 MSDLIB#:212
CN: bicyclo(3.I .0)hexan-2one, -5-(I -merhylerhyl)-
Synonyms:none
Source:Artemisiaperscia oil ex P. Weyerstahl;3.OO7o Artemisia roxburghiana,
.TEOR6 :34-5( 1994); 1.107oA rt eni si a p er si ca; l .53VoArt emisi a gmel in i
8l o
r00
80
60
4{)
138
0
A
r40
RT: | 3.86 AI: l 15.5 Kl: I 1.59 Isopulegol<iso->

CAS#: .5990-5-.54-3 MF: Cl0 Hl8 O FW: 1.54 MSI) LlIl#: 878
CN: cyclohexanol, S-rncthyl-2-( ( I a,2p,-5B)-
l-methylethenyl)-,
Synonyms:none
r00
80
60
40
)n
RT: f 3.87 AI: I l5-5 KI: 1160 Hydroxy acetophenone<2'->

CAS#:I l8-93-4 MF: C8 H8 ()2 FW: 136 MSD LIB#: l-593
CN: ethanone,| -(2-hydroxyphenyl)-
Synonyms:o-acetophenol
S nur c e:A ldr ic hC h e m.;0 .0 1 7 al ri s fl o re n ti n aRi
, vi stai tal i anaE P P OS63:l 4l (1981)
:
222 Adams: EssentialOil Componentsby GC/MS !
j
RT: 13.87 AI: 115-5KI: 1160 fsoborneol

CAS#:124-76-5 MF:ClO Hl8 O FW: 154 MSD LIB#: 1441
CN : bi cycIo(2.2. I)heptan-z- o1,1,7,7-trimethyl-, exo-
Synonyms:none
Source: Strobilanthus auriculatus oil ex P. Weyerstahl; 22.90VoCurcuma (rhizome),
JEOR 7 :26 I ( 1995); 19.207oStrobilmtthes auriculatus
100
80
60
40
$r"'
t2l
40 t20
RT: 13.89 AI: 1156 KI: 1160 Pyrazine<2'acetyl'3-ethyl'>

CAS#:32974-92-8 MF: C8 H10 N2 O trW: 150 MSD LIB#: l35l
CN: ethanone,1-(3-ethylpyrazinyl)-
Synonyms:none
ex Art Tucker
Source:PyrazineSpecialties
43 107
80 132
40 100
RT: 13.89 AI: 1156 KI: 1160 Terpineol<cis'dihydro'p'>

CAS#:3901-9-5-9 MF: C10H20O FW: 156 MSD LIB#: 1469
1-methyl-4-(
CN: cyclohexanol, cis-
I -methylethyl)-,
Synonyms:p-menthan-1
-ol, cis-
Source:SCMChems.ex H Hills
7l
100
80
60
40
8l t41
223
RT: I 3.9 | AI: l 156 KI; I l60 Pentyt cyclohexa-1,3-diene

CA S #:- 56318 -8 4 -4 MF : C l l H l 8 FIM: 1.50 MSI)LIB#: l8l
CN: 1.3-cyclohexadiene, -5-peutyt-
Svnonvrns: none
Source:clistillationof celery seed(I)ur.keeSpiceCo.), Rp Aclams#5534;
3.30%ApirLntgraveolens(seecl),Parf. Cosm.Aronres90:8-5(1989);
3.007oApium graveolens(flower); 0.537oLevisticturrfficinale
40
20
160
RT; 13.94 AI; I1,57 KI: l161 Nonen-l-al<(Zf,\->

CAS#:ltt829-.56-6 MF; C9 H t6 O F'W:140 MSD LIB#: I I
(E)-
CN: 2-nonenal,
Synonyms:none
Source:BecloukianRes.ex Art Tucker; 1.00,/oRltuscoriaria,
I)r'agcrcoRcports3 :8 1( | 993); 0.307oCoriandrum satit'unt: 0.22VoCi.trus
4l
r00
80 5.5
70
83
RT; 13.9-5 AI: ll57 KI: I l6l Lavandulol <tetrahydro->

CA S #: 41884- 2 8 -0 MF : C l 0 In 2 2 O F W: 1-58 MS D LIB #: 984
CN: 1-hcxanol,-5-methyl-2-( l -nrethylethyl)-
Synonynrs:none
Sourcc:ref. cpcl.ex E. von Rudloff
f",
'r', ll Adams:EssentialOil Componentsbv GC/MS
RT: 13.96 AI: I l-57 KI: 1 162 Benzyl acetate

CAS#:140-ll-4 Ml.':C9 HlO ()2 FW: 1.50 MSD LIB#: 289
CN: aceticacid,phenylnrethyl ester
Synonyms:benzylethanoate; o-acetoxytoluene
Oil 84.807oNarc:issu.s
Source:.Iasminabsoluteex A.F. fhor.nas;CanangaOtl; Ylang t'l.an.g ta?.etto,
p. 108,in: ArornaticPlants& EsscntialConstituents, PeaceBook Co', Hong Kong(1993);
7 | .00%,J asnrirttunfficinale; 25.10%'Ylangylang
OAc
d
40 60 ttO luu tzu l4tr lou
RT: 13. 99 A I : I 1. 58 KI: 1 1 6 2 N l e n th o n e

CAS#: 491-01-6 MF: C l0 H | 8 O FW: l -54 MSD LIB#: l2-55
CN: cyclohexanone, 5-methyl-2-( cis-
I -methylethyl)-,
Syn ony r nsp-
: nr c nt h a n -.3 -ocni cs .-
Source:Peppermintoil, McConnickCo.; 51.62%Menthospicata,Perl'.Flav. l9:41(1995);
35.00% A g atlrcsnm betulina; 25.007oM entlm p ip er ita
A
t"
RT: 14.00 Al: l1-58 KI:1162 Cresol acetate<neta->
CAS#:122-46-3 MF: C9 HlO ()2 FW: 1.50 MSD LIB#:483
CN: accticacid,3-methylphcnyl estcr
Synonynrs:3-acetoxytoluene:3-tolyl acetate;cresatin
Source:acetylationof m-cresol(5828)
nnEEufl[r-i'
RT: 14.00 AI: ll58 KI: ll62 Pinocamphone <trans-> I

CAS#:541-60-4 MF : C 1 0 H l 6 O F W : 1.52 MS D LIB #: t3rG
CN: bicyclo(3.I . l)heptan-3-one,2,6,6-trimethyl-,
( I a,2u,.5a)-
Synonyms:trans-3-pinanone
Sonrce:ref. cpd. ex P. Weyerstahl
RT: 14.02 AI: I 159 KI: I 163 Terpineol <trans-p->

CAS#: 7299-40-3 MF: C10 Hl8 O FW: 1.54 MSD LIB#: 1004r
CN: cyclohexanol,l-methyl-4-(l-rnethylctl.renyl)-,
trans- i
Synonyms:p-rnenth-8-en-I -ol, isomer
Source:West Indianlime oil. LorannOits; 1.807oCitrusjunos,.L Chromato$.268:336(1983);
1.257oMajorana hortensis;0.347oPistacia lentisctts i
r00
'l
80
60
40
20
40 60 80 t00 120 l40i

i
RT: 14.04 AI: 1159 KI: 1163 Nonadienol <(28,62)->

CAS#:28069-12-9 MF: C9 H16O FW: 140 MSD LIB#:2126r
CN: 2,6-ncuatlien-l-ol,(2F,,62)- t
Synonyms: none :
Srrnrce:IJcdoukianRes.;0.01VoViolaodorata,I)ragoco Rept.5-21(1996);i
0.0| 7oRibes sanguinemn;0.017oJasnin e poIyanthtnn
RT: 14.0-5 AI: I l-59 KI: I l(r4 Hexadienol propanoate <(28,48)->

CAS#: 95994-92-6 MF: C9 H14 02 FW: 154 MSD Llts#: 2100
CN: 2,4-hexadien- I -ol, propanoate,(2}-,4F,)
-
Synonyms:solbyl acetate
RT: 14.0-5AI: l1-59 KI: 1164 Menthofuran

CAS#:494-90-6 MF':Cl0Hl4 O FW: 150 MSDLIB#:701
CN : benzolur an,4,5,6,7-tetrahydro-3,6-dimethyl-
Synonyms:p-mentha-3,8-cliene, 3,9-eprxy-
Peppermintoil, (McCormickCo.); 58.-507o
SrruLce: Menthaaquatica,p' l4l in: Flav' & Ftag':
'
A World Persp.,Lawrence,etal.,lOthIntl. Cong.of Ess.Oils, Elsevicr,Amsterdam(1988);
54.007oE uodi a hort ensi s: 38.969oM entha d enti.culata
RT: 14.06 AI: l160 KI: l164 Chrysanthenol<cis->

CAS#: 55122-60-6 MF: Cl0 Hl6 O FW: 152 MSD LIB#: 199
CN: bicycfo(3.I .l )hept-2-en-6-ol,2,7,7-trimeLhyl-,( I a,5u,6tt)-
Synonyms:none
Source:Artemi.siaabsinthiumex A. Carnot; 1.407oArtemisia moorcro.ftiana,
p.26, in: NewerTrendsin Ess.Oils & Flav.,P. Weyerstahl, New Delhi, India(1993);
0.507oArt emisi a anruta: Ar
0.387o t emi si a vest i t a
100
80
60
40
20
227
RT: 14.06 AI: l160 KI: I164 Isocitral<(Z)-> i
CAS#:12203-91-5 MF: Cl0 Hl6 O FW: 1.52 MSD LIB#: 1727

CN: 3.6-octaclicnal,
3,7-dimethyl-,(32)-
Synonyms:isoneral
Source:Backlrcusia
citriodoraoil ex. Ian Southwell
4l
t00
80
60
40
RT: 14.07 AI: I 160 KI: I 164 Pinocarvone

CA S #: 16812- 4 0 -l M F : C l 0 H l 4 O F W : I.50 MS D LIB #: 410
CN: bicyclo[3.L l ]heptan,3-one,6.6-dirnerhyl-2-merhylene-
(9CI)
Synonyms:3-nopinenone;2( I O)-pinen-3-one
Sou"ce:ref'.cpd. ex B. Rodriguez,Spain; 25.757oHyssopusrfficinalis,
J. Ag. Food chem. 42:776(1994);4.707o Artemisiaargentea;3.59vo
Anthemisnobilis
RT : 14. 09 A I : 1 1 6 0 K I:1 1 6 4 T e rp i n e o l cci s-di hydro-a->

CAS#: 7322-63-6 MF: Cl0 H20 O FW: 156 MSD LIB#: l47l:
CN: cyclolrexanernethanol, o,o,4-trimetl'tyl-,cis-
Synonyrns: p-menthan-8-ol, cis-
100
80
60
40
20
4,4->
RT: 14.12 AI: 1161 KI: ll6-5 Dimetlroxybenzene
CAS#:l-50-78-7 MF: C8 HlO 02 FW: 138 MSDLIB#:613
Synonyms:hydroquinonedimethyl ether;quinol dimethyl ether;p-rnethoxyanisole
Source:Aldlich Chern,:52.30%, Svringavulgaris,p.415, in: Flav. & Frag.:A World Persp,,
Amsterdanl(1988);
Lawrence,etal.,lOth Intl. Cong.of Ess.Oils, H'lsevier,
17.00a/oViola odora.ta;3.307aLv-castearomatica
O-Me
100
80 J-
60 lil
40
20
Y O-Me
RT: 14.13 AI: l161 KI: 116.5N{enthol <neo->

CAS#:491-01-0 MF: Cl0 H200 FnV:1.56 MSDLIB#: 1256
5-methyl-2-(l
CN: cyclohexanol, (1a,2u,5$)-
-methylethyl)-,
menthol,trans-| ,3, trans-I ,4-
Synonyrns:
Source:Peppermintoil, McCormickCo.
I
o i
3
,,rrtt4OH
RT: 14. 14 A I 1162 K I: I1 6 6 T e rp i n e o l< 5 ->

CAS#: 7299-42-5 MF: C l0 H I 8 0 FW: 1.54 MSD LIB#: 148
CN: cyclohexanemethanol, a,o,-dimethyl-4-methylene-
Synonyms:p-menth-I (7)-en-8-ol
Source:Amyris diatrypa.(Dom, Rep.) oil ex Tonr Zanoni,identifiedby Teris van Beek;
13.027oP i staci a l enti sr:us,.IEOR 4 :663( 1992); 03.677oM el itt i s meli.ssop lrylhun;
2.107oRosmarinusffici.nalis
RT: 14.15 Al:1162 KI: I166 Nonenol<(22)->

CAS#: 41453-56-9 MF: C9 Hl8 O FW:142 MSD LIB#: 2081
CN: 2-ntrnen- | -ol, (2Zi)-
Synonyms:none
Ho/-V(cH2)5-cH3
60
40
20
40 60 80
RT: 14.20 AI: I163 KI: I167 Nonenol<(28)->

CAS#:31502-14-4 MF: C9 Hl8 O FW:142 MSD LIB#: 2082
l-ol,(2H)-
CN: 2-nonen-
Svnonvnts:
none
Source:Becloukian
Res.0.l5% Ruta angustifolia,JEOR 3:355(1991);
0.04%oGeum ntonteturnl
57
68 82
95
t42
60 80 t00 t20 r40
RT: 14.21 AI: I163 KI: I167 Dimethvlaniline<2.6->

CAS#:87-62-7 MF: C8 Hl l N FIV: 121 MSD LIts#:7-52
CN: benzenamine,2,6-dirnethyl-
Synonyms : 2,6-xylidine;o-xylidine;2,6-clirnethylbenzenamine
Sont'ce:Grob mixture for GC, Alltech Assoc
t06 NH2
71
)0r-
230 Adams: EssentialC)il Componentsbv GC/MS
R T: 14. 21 A I : l163 KI: 1 1 6 7 Vi ri d e n e

C AS #: 83327- 43- 9 MF :C l l H l 6 F W: 1 48 MSD LIll#: | 8l I
CN: 1,3-cyclohexadiene, 1-(2E)-2lentenyl-
Synonyms:none
Source:Mewn athamantit:umoil ex K-H Kubeczka
100
80
60
40
2(l
100 t20
< (E )' >

R T 14. 22 A I : ll63 K I: 1 1 6 7 M e th y l 2 -o c te l ro ate
CAS#: 1367- 81- 9 MF :C 9 H 1 6 O Z F W : 1 56 MS D LIB #:2160
CN: 2-octenoicacid,nrethylester,(2E)-
Synonyms:none
il
r"o%
<(62)->
RT: 14.26 AI: 1164 KI: I168 Nonenol
CAS#:358.54-86--5MF: C9 Hl8 O I'-!V:142 MSDLIB#:2128
CN:(r-nonen-
| -ol,167;-
Synonyms:none
Source:
Bedoukian Res.
100
80
-oH
60
40
20
Appendix Ill: Mass Spectra 231
RT:14.26 AI: I164 KI: 1168 Thujanol<3-> :

CAS#:21653-20-3 MF: C10Hl8 O FW: l-54 MSD LIB#: 1489
CN: bicyclo(3,1.0)hexan-3-ol,
4-rnethyl-
l-( l -merhylerhyl)-,(
| S-(I o,3u,4o,5cr))-
Synonyms: thujol
Source:ref. cpd.ex E. vonRudlotT
43
Harr,....r\......ttoH
,/\
/\
P.T:14.27 AI: ll6-5 Kl: I168 Benzene<1,3-dimethoxy->

CA S #: 15l- 10- 0 MF : C 8 H l O ()2 F W : 138 MS D LIB #: 27-5
Synonyms:resorcinoldimethyl ether;m-methoxyanisole
Source:H&R ex Jian-QinCu, Kunming
Me-O
R T : 14. 29 A I : 1 1 6 -5 K I: I1 6 9 Bo rn e o l
CAS#: 501-70-0 MF: C l0 H I 8 O FW: l -54 MSD LIB#: 31-5
CN: trimcthylhicyclo(2.2. | )heptan-2-ol<endo- l ,7,7->
Synonynrs:camphol
Source:Rosm.arinus uil, Firmenischex A.F. Thomas,'Juniperusleal'oils;
8l .187oCinrtarnomuru carnpltora,p. 26, in: ArornaticPlants& EssentialConstituents,
Peace
Btrok Co., Hong Kong( 1993);-5l.56VoCinnanlonurnlbunnannii;38.40'Vo Artemisia awllta
100
232 Adarns:EssentialOil Cornponentsby GC/MS
RT: 14.29 Al: 116.5K I: 1 1 6 9 N o n a n o l< n ->

CAS#:1,13-08-8 MF: C9 H20 O FW: 144 MSD LIB#: 35
CN: l -nonanol
Synonyms:pelargonicalcolrol
Source:ref. cpd.ex Il. von Rudlol'f':2.02o/o jambltiri, Scoria,RW et al. p. 441,In: Proc.
Citru,s
l969); | .937oNicotianaforgetiana; | .607oCitru,slinton (leafi
First Intl. Citrus Syrnposiurn(
cH3(cH2)8oH
R T: 14. 30 A I : 116-5 KI: l l (r9 L a v a n d u l o l

C AS#: 498- 16- 8 MF -:C l 0 H l 8 O F W: 1 .5 4 MSD LIB#: 1928
CN: 4-hexen-I -ol,-5-methyl-2-( I -methylcthenyl)-
Sl,nonyms:none
Scrurce:Diltlotaenia cachryclifolaeroot oil ex K' Harkiss],29'1lo/aLat'andula lanata,
IEORl:219( 1995);7.527,,Lavandulaangu,stifolia;1.650/o Valeriana fficinalis
t
41 69
100
80
6()
l0
t0
RT: 14. 32 A I : 1166 K l : 1 1 7 0 N fe n th a -1 ,5 -d i en-8' < olp->

CAS#: 1686- 20- 0 M F :C l 0 H l 6 O F W: 1 .52 MS D LIts#:901
CN: 2,4-cyclohexadiene- I -mcthanol,o,o,4-trimethyl-
Synonyms:o-phellandlen-8-ol
Source:Juniperuscommunisv. depressaoil (MA, USA) RP Adams #6052;0.427oCymbopogonju'orattctt,tar
l Othl ntl .C ong.E ssOi l s,E l sevi er,A msterdarrr(1988) ;
p .3 17, in: F lav . & F r a g .: A Wo rl tl P e rs p .,L a w re n c e,etal .,P roc.
0.347oRibes n ig rum; 0.307oAchi llea w ilhe lms i r
i
I
Ap1--ndir
lll: MassSpectra z-)-)
R T : 14. 32 A I : | 1 6 6 KI: l l 7 0 Pi n o c a mp h eol

CAS#: 2.546.5-95-6 MF: C l0 H I lJO FW: 1.54 MSD LtB#: I 304
C N: bic y c lo( 3.l. | ;h c p ta n -3 -o2l ..6 ,6 -rri n re rh yl
(l -a,2u,3B ,5a)-
Syntxynrs:pintrnol.3-
Source:r'cf.cpcl.0x E. von Rudlol'f
r00
80
60
10
20
RT : 14. 3- 5 A I : l l 6 6 K I: I1 7 0 C o a h u i l e n s ol
CAS#: 21489(t-23-8 MF: C9 HlO O FW: 134 MSD Llll#: 2088
CN: phcnol,2-ethenyl-3-ltrethyl-
Synrxyms:none
Sotrce:Jrtrtiperus coalmilen.,si.s
v. ariKtni.caoil, RP Adams#7637,
identifie{bv NMR. VasuDcv
80
60
A.'=
\z(.H
40
20
RT : 14. 35 A I : | 1 6 6 Kl : I 1 7 0 C re s o la c e ta te< p->

CAS#: | 40-39-6 MF: C9 H l 0 02 FW: I .50 MSD LIB#: 123l
CN: aceticacid,4-nrethylphcnyl ester'
Synonynrs:cresyl acetate
Source: Pfaltz,& Bauer ex H. Hills
O-Ac
+
:
R T: 1 4, 36 A I : 1167 KI: I1 7 0 A n g u s ti fo l e n o n e
CAS#: 122221-94-7 MF-:Cl I HlS O FW: l6fi MSDLIB#: 263
CN: 2-cycIolrexen-I -one, 2-ethyl-4,6,6-trinrethy r-
Synonyms:none
Source:Backhousiaangu,stifoliaex J..I.Brophy
I00
80
60
4{)
20
acid
RT: 14.37 AI 1161 Kl: I171 Octanoic
CAS#:124-07-2 MF: C8 Hl6 OZ FW: 144 MSD LIB#: 2068
CN: octanoic acid
Synonyrns:caprylic acid
Source:BedoukianRes.;4.00Scleriastriatinux(rhizorrre),
JIIOR 8:-59(1996);
jujuba;
2.297oZizypltus 1.107oPsidiuntg,uaiava
RT: 14, 38 A I : I 167 K l : 1 1 7 1 Is o p u l e g o<l n e o i so' >

CAS#: 21290-09-5 MF: ClO Hl8 O FW: 1.54 MSD LIB#: 881
CN: cyclohexanol, 5-methyl-2-(l-nrethylethenyl)-, ( Is,2ct,-5s)-
Synonyms:none
f",
41
100
80
60
40
AppcndixIII: Mass Spectla
235
R T : 14. 38 A I : I1 6 7 KI: I l 7 l U m b e l tu to ne
C A S #: 24. s 4- 5 -tl l -l MF : C l 0 H l ,l O F W: 1.50 MS D LtB #: l -518
CN: bicyclo(ll.L0)hex-3-en-2-one, 4-nrethyl-| -( t -nrcrhylethyl)-
Synonynrs: 3-tlrujen-2-one
S<rttrcc'UnrbelluloriacoliJontica(Calitirrniabay), RP Aclams#5432; | .B(to/c TorracetumvulgcLre,
.llroR -5:629( 1993);0.60%Euc'al.tptrts globulus;0.31./o Arterni,sia
ctksaietrsrs
h
-l-
R T : 14. 39 A l: 1 1 6 l K l : tl T l N l e n th o l
C A S #: l- 53. 56- 6 0 -2 MF ' :C l 0 H 2 0 O l .W : 1.56 MS D LIB #: 1258
CN: cyclohexanol,-5-rncthyl-2-( I -nrcrlrylc.thyl )-. ( | u,2$.5a1-
Synonynrs: pcpltcrntintcamphor';Incnthacantph(x.
Srrrrrcc: pcrppcrnrint oil, Mccor.nrickCo.; 95.00%Mentha an,ensi,t. p. 21. in: Stuclieson the
Alt er at ionol- lis s c rn tioaill C o rl p o s i ti o nS.
. O n o ,9thl ntl . C ong.ol l rss. Oi l s,S i ngap< x.e(1983):
ll .61(/,,Mentlta hoplocaly.r;69.76,/,,MetrtltcL x t'crticillota
=
:
tl
tl
Y."r,o*
I
2( l
4L) 60 ttO I0 0 | 20 | 40
RT: 14.42 AI: ll68 Kl 1172 Methoxy-3-(1-methylpropyl)pyrazine

<2->
CAS#: 24168-70-5 MF: C9 H l.t N2 O FW: I (16 MSD LIII#: t646
CN: Pyrazine.2-rnctlroxy-3-(
| -rrrclhylpropyl)-
S y nony r nsnonc
:
Soulco:Aldrich Clrcln.
|00
RT: f 4.43 AI: ll68 Kl: lll2 Methyl-3(2-furyl)acrolein<(22)'>

CAS#:000-00-0 MF: C8 H8 ()2 FW: 136 MSD LIR#:2023
CN : 2-propenal, 3-(2- llran yl')-2-meLhyl-, (22) -
Synonyms:none
Source:BedoukianRes.ex.IJ Brophy
79
o/X"
RT: 14.47 AI: 1 169 KI: I 173 Ethyl benzoate
CAS#: 93-89-0 MF: C9 HlO ()2 FW: 150 MSD Ltts#: 664
CN: benzoicacid, ethyl ester
Synonyms:benzylethylether
Source:Aldrich Chem.; 12.50%Liliu.mcandidum;p 415. in: Flav. & Frag.:A World Pemp.,
Lawrsnce.etal.,lOth Intl. Cong.ol'Ess.Oils, Elsevier,Arnsterclanl(1988);
1.007oArtemisia nronospennai| .00VoAcacia praecox (llower)
X
-El
RT: 14. 48 A t : 116 9 K I: 1 1 7 3 A rte m i s y la c e tate

CAS#: 34(r5-88-l MF: Cl2 H20 02 FW: 196 MSD LIB#: 22-5
3,3,6-trimethyl-,acetate,
CN: l,-5-hc'ptadien-4-ol. (S)-
Synonyms:arternisia acetate<B->
Source:Artenrisiatridentota,SLC, UT ex P. Weyerstahl;3.007oArtentisia.vestita.Ptoc.
1I th Intf. Cong.o1'Ess.Oils 4: 127(1989),New Delhi, India; L707oArtenisiapersicai
1.507oArtenrisiaiudaica
AppendixIII: Mass Spectra 23'7
RT : 14. 48 A l: l 1 6 9 Kl : I1 7 3 N e c ro d o l< c i s-o->

CA S #: 187663-9 l t-5 MF : C l 0 H l 8 0 F W: l -54 MS D LIB #:2096
CN: 2-cyclopentene-I -mcthanol,3,4,5,5-tetrantethyl-, cis-
Synonyms:none
Sorrrce:Lovardul.aI.ui.sieri. ex NicolasBalclovini
t00
8C)
60
40
20
RT: 1,1.50At: 1170 KI: ll73 Furfurylbutanoate

CAS#:623-21-2 MF: C9 Hl2 ()3 FW: 168 MSD LIB#:82
CN: butanoicacid,2-firranylmethyl
ester
Synonyrrrs:
furl'urylbutyrate
Source:AlclrichChern.
100 o
^ll
tl
1"\r'\o-'\-"\
\_/
RT: 14.-52 AI: ll70 Kl:1174 Linalool oxide <cis->(pyranoid)

CA S #: 14009- 7 1 -3 MF : C l 0 H l 8 0 2 F W: 170 MS D LIII#: 1010
CN: 2H-pyran-3-ol.6-ethenyl tetrahycho-2.2,6-trimethyl-,cis-
Synonyms:(Z)-pyranoidlinalooloxide;linalooloxiclel)
Source:Clarkia breweri llower oil ex RA Raguso,Ariz.(ex Flath. USI)A)
100
:
RT: 14. - 54 A I : ll71 K I:1 1 7 4 S a n to l i n y la c e ta te

CAS#: 79.s07-88-3 MF: Cl2 H20 02 FW: 196 MSD LIB#: 2.13
CN: 4lrexen-2-ol,3-ethenyl-2,-5-dinrethyl-, acetate,(S)-
Synonyms:none
Source:Artemesiavestitaoil ex P. Weyerstahl
ff
-f.-
O-Ac
RT: 14.-57 ltl:1172 KI: 1175 Pinocamphone<cis'>

C AS#: 1. 53. 58- 88 -0 M F : C l O H l 6 O F W: 1 .52 MS D LIB #: 1306
CN: bicyclo(3.L I )heptan-3<tne,2,6,6-trimethyl-(l o,28,-5o)-
Synonyms:isopinocamphone
Source:rel'.cpd. ex P. Weyerstahl
5-5
t00 41
80
6t)
40
20
RT: 14.60 A[ | 172 KI: I 176 Phenyl ethyl formate <2->

CAS#: 104-62-l MF: C9 HlO ()2 FW: 150 MSD LIB#: 1278
CN: lbrmic acid, 2-phenylethylester
Synonyms:benzylcarbinyllbrrnate
Source:ICN Chem.ex Art Tucker;0.93% Gardeniajasmi.noides(absolute),
JEOR 8:281(1996):0.1{)% tazetta(absolute);
Narcissr.ts 0.107cHyacinthusorientalis
AppendixIII: MassSpecrra
239
RT: 14.64 AI: I 173 KI: | 176 Linalool oxide <trans-> (pyranoicl)
C A S #: 41720- 62 -l M F : C l 0 H l 8 (t2 F W : 170 MS D LII]#:462
CN: 2H-pyran-3-ol.6-ethenyltetrahydro-2.2,6-trirncthyl-, (3R-trans)-
Synonyrrs:linalooloxide C
Sou'ce:clarkio ltren:eriflower oil ex RA Ragus<t; l2.2lTo Magnoliapurpurella.L-F .zhu
ctal.,p. 204 in AtornaticPlantsand EssentialConstituents, PeaceBook Co. Hong Kong ( 1993);
2.00(/aLavenclulaangustiJblia;| .667oClerodendnunfragrans
RT: 14.6-5 Al: I 173 KI: | 171 Rosefuranepoxide

CAS#: 92356-06-4 MF: ClO H14 02 FW: t66 MSD LIII#: 6.57
CN: luran,2-[(3,-3-dimethyloxrianyt)rnethyl ]-3-rnerhyl-
Synonyrns: none
source:El,sltoltziadensa oil ex vasu Dev',0.407oAloysia triphylla,JEOR g:5gl(1996);
0.05 VoA g astache r ug osa (lcal'); 0.037aB o uea nu c r op hyIIa
RT: 14.66 AI:1114 KI:1171 Terpinen-4-ol

CA S #: 562- 14- 3 M F :C 1 0 H l 8 O F W:154 MS D LIB #:910
CN: 3-cyclohexen- l-ol, 4-rnethyl-l-( I -methylethyl)-
Synonyms:4-terpineol;p-nrenth- I -en-4-ol;4-carvomenthenol
Source:Juniperuslur:aranaleaFoil, RP Aclarns#2863; 46.l\vo MelLileucapa.ntiflora,
.TEOR6:419(1994);45.657o Melaleucaalternifolia:3(t.30vaMaioranahortensis
P.T:14.72 AI: 117-5 KI: 1178 Isoamylacetoacetate

CAS#:2308-18-l MF: C9 H1603 FW:172 MSD LIB#: 1599
CN: butanoicacid,isopentylester
Synonyms:isopentylacetoacetate
t20 140
R.T:14.72 AI: 1175 KI: 1178 Octane<1,1-dimethoxy->

CAS#:10022-28-3 MF: C10H2202 FW: 174 MSD LIB#: 1201
CN: octane,l,l -dimethoxy-
Synonyms: octane,dimethylacetal
75
143
40 t00 120 140
RT: 14.73 AI: 1175 KI: 1178 Benzeneacetic acid, methyl ester
CAS#: l0l-41-7 MF: C9 HlO 02 FW: 150 MSD LIB#: 271
CN: benzeneacetic acid, methyl ester
Synonyms:methyl phenylacetate;methylo-toluate
Source:Pfaltz & Bauer ex H. Hills
9l
AppendixIll: MassSpecrra
241
RT:1 4.7 6 AI: I l7( r KI : ll79 Diet hy l s uc c i r r a t e

CAS#:123-25-l MF':C8 H 1404 FW: 174 MSD LIB#:321
CN: lrutancdioicacicl,clictlrylester
Synonyrns:succinicacid.diethylcster:clietlrylhutanedioate
Source:P|altz.& [Jauerex Arl.Tucker;0.30%,courortpitagttaianerr,ri.r
(llowcr),
.lIrOR7:22.5(
l99.5)
o
rl
-\-,-"\rr-\--\o/,,1
ll
40 60 80 100 t20 l .xO t60 | 80
R T : 14. 78 A T : l l 7 6 K I: l l 7 9 C y n re n -S -o<l nreta->

CAS#: 520U-37-7 MF-:C l0 Fll:1.O tjW: 1.50 MSD LIB#: 9.12
CN: bcnzenemethanol, u,o.,3-trinrctlryl-
Synonynrs:21 3 -tolyl)-2-1'rr.opanol
Sotrrce:Jrtrtipentsprocera lcal'.RP Aclarns#-5530:0.267oRibersnigrurr,
p. -j7-5'in: l'lav. & l'rag.:A Wol'lclPets;.r.. Lawlencc.etal (ecls.),Proc. lOth lntl. Cong.Ess.Oils,
Elscvier,Arttstcrclam; 0.23(/oArtgelir:aarchangelic:o:0.211, Cl,nfuopogort.jrrarartt'tL,s'a
R T : 14. 78 A I : ll 7 6 K I: l l 7 9 P i n o c a rn p h e ol 

C A S #: 21179- 29 -9 MF : C l 0 H l 8 O F W : t-54 MS D LIB #: t30.5
C N: hic y c lo( 3.I . l )h e p ta n -3 -o2l ,,6 ,6 -rr.i rn e rh yl
( l a.2P
-, ,3s,-5n)-
Sy nor r y r ns
n<: lnc
Strtttcc'rcl'.cpcl.cx li. von RLrdlol'l'; 0.50ckJunipentsmartinez.ii..lllOR 2:9969901:
0.50%,J utri1tcnrs .fl at't'icla ; 0.35 1, H ysso1ttt,stt,ffici ncL Ii s
R T: 14. 78 A l: 1176 KI: I1 7 9 Ve rb a n o l 

C AS#:94480- 80- . 5 M F : C l O H l 8 O F W: 1 54 MS D LIB #: 1544
-,( | u,2a,4$,5u)-
CN : bicycfo(3.I . I )heptan-2-ol, 4,(:,6-trimethyl
Synonyms:none
Source:ref. cpd. ex E. von Rudlotf
RT: 14.79 Al 1177 KI: I 180 Dec-l-en-3-ol

CAS#:.5| 100--54-0 MF: C10H20O trW: 156 MSD LIB#: 2052
CN: I -decen-3-ol
Synonyms: none
Sottrce 07oAlpinia katsumqdai,.IEOR2:2-5
Res.; 2.-5
: Bedoukian 9(l 990)
60
40
20
R T: 14. 82 A l: 117 7 K I: 1 1 8 0 Is o c i tra l< (E )->

CAS#: 55122- 59- 3 M F :C l 0 H l 6 O F W: 1 52 MSDLIB#: 1728
CN: 3,6-octadienal, 3,7-dirnethyl-, (3tr)-
Synonyrns:none
Source:Backlrousiat:itrioclorqoil ex. lan Southwell
, ..,. 41
Appendix
lll: MassSpcctra 243
RT : 14. 82 A l l l 1 l K I: l l 8 0 S a n ta l o n e
CA S #: . 59300- .5 1 -.5M F :C l l H l 6 O F W : 164 MS D LIII#: 1396
CN: cthanone.I -(2,3-dirnethylrricyclo(2 .2.1.02,6)hept-3-yl)-
Synonyms:none
Soutce:acetylertion ol'sanclalwood oil (5491)
d
R T : 14. 84 A I : l l 7 8 K I: 118 1 N a p h th a l e n e
C A S #: 9l- 20- - l MF: ClO H8 F W : 128 MSDLIB#:91
CN: ntrplrthalenc
Synonyrns: nrothllakes.tar canrphor'
Source:SigmaChcrtr.a2.30%Pluneria rubra, p.89, in: ArolnaticPlants& EssentialConstitr.renrs,
Peacellook Co., Hong K<lng11993); |.52VaArtenrisiaatrovirens; | .007oRlntscoriarict.
4(
R T : 14. 8- 5A l: l l 7 8 KI: l l Sl E th y l -3 (2 -fu ryl )-propanoate

CA S #: 10031- 9 0 -0 MF : C 9 H l 2 0 3 F W : l 6tt MS I) LIB #:686
CN: 2-luranpropanoic acid.ethyl ester
S y nr r ny r r rcst:hy l B -lu ry l p l rrp i 6 rp n l s
Source:BedoukianRes.ex Alt Tucker
RT: 1 4. 8- 5A I : 1178 K I: I1 8 1 Me th y l i s o b o rn eol< 2->

CAS#: 2311-42-8 MF: Cl I H20 O FW; 168 MSD LtB#: 1769
(
CN: bicycfo(2.2.I)heptan-2-ol,1,2,7,1-tetrarnethyl-,1R,2R,4R)
Synonyms: 2-norbornanol,1,2,7,1-tetramethyl-
Sourc:e:SupelcoInc.
100
80
60
40
20
R T: 14. 86 A I : 1178 KI: I l 8 l Al l y l h e p ta n o a te

C AS#: 142- 19- 8 MF : C l O H l 8 ()2 FW: 170 MS D LIB #: I l 0
CN: heptanoicacid,2-plopenyl ester
Synonyms:allyl enanthate; 2-propenylheptanoate
Sourcc:Aldrich Clrern.
R T: 14. 89 A I : I 179 Kl : 1 1 8 2 H e p te n a l< (.4 2 )- > ,di ethylacetal

CAS#: 18492-65-4 MF: Cll I H22 02 FW: 186 MSD Llts#: 791
CN: 3-heptene,7,7-diethoxy -, (Z)-
Synonyms:none
Souroe:BedoukianRes.ex Art Tucker
41
AppenclixIII: MassSpectra aA<
RT: 14.91 AI: I l79 KI: I I ft2 Acetophenone <p-methyl->

CAS#: 122-00-9 MF: C9 H l0 O FIV: I 34 MSD LIB#: 9
CN: ctlranonc,| -(4-ntcthylphcnyl)-
Synonynrs:norte
Sourcc:ICN Cherrr.ex Art Tr.rcker'
Q
RT : 14. 91 A I : ll 7 9 K I: I 1 8 2 C y me n -8 -o <p-> l
C A S #: 1197- 01 -9 MF : C l 0 H 1 4 O F W : 1-50 MS D LIB #: .548
CN: trenzencrnethanol, o,,a,4-trimctlryl-
Synonyms:8{ydroxy-p-cyntcne
Scrtrrce:Roule flertrandex H. Hills; 4. l07oAbiesholophylle,p.l l4; in: Aromatic
PIants& EssentialConstituents, PeaceBook Co., Hong Kong(1993);
3.66a/oTltyntus ntortg o l i c us; 2.00% Tr iphasi a t r ifo Ii a
r00
8()
60
40
20
r6 0
Q
RT: 14.91 AI: l 179 KI: I I 82 Merrthol <iso->
CAS#: 490-99-3 MF: ClO H20 O F-W:1.5(r MSD LIB#: 1259
CN: cyclohexanol, l
-5-nrcthyl-2-(-rlethylethyl)-,(
| a,2B,-5B)-
Synonyrns:menthol,trans-l,3,cis-1,4-
Source:Pcppennintoil, McCormick Co.
Q,".
246 Adams:EssentialOil Cornnonentsbv GC/MS
RT: 14.91 AI: l179 KI: 1182 Pyrazine<2-methoxy-3-(2'methylpropyl-)->

CAS#:24683-00-9 MF: C9 Hl4 N2 O FW: 166 MSD Llts#:6-5
CN: pyrazi
ne,2-methoxy-3-(2-nrcthylpropyl)-
Synonynrs:2-isobutyl-3-rnethoxypyrazine
Source:AldrichChcm.
124
(.nr
40
RT: 14.94 AI: 1180 KI: 1183 Furfuryl acetone

CAS#:623-15-4 MF: C8 H8 ()2 FIV: 136 MSD LIII#: 206-5
CN: 3-buten-2-one, -(2-furanyl)-
Synonyms:buten-2-one,4-(2-luryl)-3-; ftrrfurylidenacetonc
Source:BedoukianRt:s.
RT: 1.1.99 AI: I l8l KI: | 184 Hexenyl pyruvate <(32)->

CAS#: 68133-76-6 MF: C9 Hl4 ()3 FW: 170 MSD LIB#: 2043
CN : propanoicacid, 2- oxo-,(32) ester
-3-hexenyl
Synonyms:none
r/
)Y,,\
Appendixlll: MassSpectra ', l1
RT: 14.99 AI: I 181 KI: I I 84 Thuj-3-en-10-at i

CA S #: 57129- 5 4 -l M F : C l 0 H l 4 O F W : 150 MS D LIB # 2t5
CN:bicyclo(3.1.0)hex-2-ene-2-carboxaldehyde.-5-(l-methylethyl)- r
Synonyms:thuienal
Sottt'ce:Artemisiaperscia oil ex P. Weyerstahl;0.867oArtemisiapersic'a,.lEOR4: l(lgg2)
f
RT : l- 5. 00 A I : l1 8 2 KI: I1 8 4 P i n o c a rv e o <
l ci s->
CAS#: 19889-99-7 MF: C l0 H 16 O FIM: 1.52 MSD LIB#: I 308 i
CN: bicyclo(3.1. I )heptan-3-ol, 6,6-climerhyl-2-methylcne-, ( l S-(to,3B,5n)-
Synonyms:pinen-3-ol,2(10)-,( I S,3S,.5S)-
soutce: ref'.cpd. ex E,.von Rutllotr; 1.007oCyperus st:ariosus, Proc. I lth Intl.icong. of Ess.oils,
New Defhi, lnclia4: 16| ( 1989);0.01%,Pinuspinaster;0.017o Artentisiaroxbutphiana
t00
80
60
40 -€(
20
RT : l- 5. 01 A I : ll 8 2 KI: 1 1 8 4 Ve rb a n o l < n e o->

CAS#: 94180-82-7 MF: C l0 H t 8 O FW: 154 MSD LIB#: l-54.5
CN : bicyclo(3.l . I )heptan-2-ol, 4,6,6-Irirnethyl -,( I a,2$,4a,5u)-
Synonyms:none
Sourcc:rel'.cpd.ex E. von RudlolT
-{y OH
248 Adarns:EssentialOil Cornoonentsbv GC/MS
RT: 1.5.02AI: 1182 KI: I184 Maplefuranone

CAS#:698-10-2 MF: C7 H10()3 FW: 142 MSD LIB#: 2040
5-ethyl-3-hydroxy-4-n.rethyl-
CN: 2(5H)-furanone,
Synonyms:abhexone
100
8(
60
4A
20
R T: 1 5. 07 A I : ll83 KI:1 1 8 .5 C ry p to n e
CAS#: 500-02-1 MF: C9 Hl4 O FW: 138 MSD LIB#: l4l8
CN: 2-cyclohexen-I -one,4-( I -methylethyl)-
Synonyms:none
Source:Solidagogran,inifolia ex P. Weyerstahl 9.227oEuca.ll'ptttstorelliana,
.IEOR9: | 1 I ( 1996);8.507oEucall,ptusdealbata:8.107oEucalvptusltolltanrltrutot
0
A
RT: 15.07 AI: l183 KI: I185 Cyclopent-2-enone <5'methylene'2,3,4,4'tettamethyl'>
CAS#: 000-00-0 MF: Cl0 Hl4 O FW: l-50 MSD LIB#: 2092
CN: cycfopent-2-enone<5-methylene -2,3,4, -tetramethyl->
Synonyms:none
Source:Lavandulaluisieri oil ex Nicolas Baldovini
RT: 1.5.07 AI: l183 KI; I18.5 Methyl-3(2-furyl)acrolein<(2E)-> i

CAS#: 108576-21-2 MF: C8 H8 C)2 FW: 136 MSD LIB#: 2022
CN : 2-propenal, 3-(2-furanyl)-2-methyl-,(2E)-
Synonyms:none
Source:BedoukianRes.ex J.I Brophy
t00
80
60
40
20
RT: l-5.09 AI: I184 KI: 1186 Hexenylbutanoate<(32)->

CAS#:16491-36-4 MF: ClO H18()2 FW; 170 MSD LIB#: 334
CN: butanoicacid,3-hexenyl ester,(Z)-
Synonyrns:cis-hexenyl buty'ate
Source:ref. cpd.ex H. DePooter
100
60
40
RT: l5.l I AI: l I 84 KI: I 186 Dill ether

CAS#: 74410-10-9 MF: Cl0 Hl6 O FW: l-52 MSD Lllt#: 607
CN: benzofuran,2,3,3a,4,-5,7a-hexahydro-3,6-dimethyl-(3S-(3a,3aa,lao.))-
Synonyms:anethollran
Scrurce:Dilf weecloil ex Lorann Oils;36.70VoAnethumgrar:eolens(Finland),
FIJ 3 : I 2 I ( | 988); 2-5.007o
Anetlnnngrat,eolens (Iruropa);
23.007oAnetluungraveolens(U.S.A.)
RT: l-5.1I AI: I | 84 KI; 1186 l\fenthol <neoiso->

CAS#:491-02-1 MF: Cl0lt20 O F'W:l-56 MSDLIB#: 1080
5-methyl-2-(
CN: cyclohexanol, I c'2o'-5o)-
I -nrethylethyl)-,(
Synonynrs:menlhol,cis-l,3,cis-1,4-
oil, McCormickCo.
Source:Pepperrnint
A
r"'
RT: 15.12 Al: I184 KI: I186 Ethyl'(4E)-octenoate
CAS#:18989-37-4 MF: Cl0 Hl8 02 FW: 170 MSD LIB#: 688
acicl,ethylester,(E)-
CN:4-oct.enoic
Synonyms:none
-5-5
tl
,,o%
RT: l- 5. 16 A I : l185 K I: I1 8 7 D e c a n o n e< 3 ->

CAS#: 928-80-3 MF: ClO H20 O FW: l-56 MSD LIB#: 574
CN: -l-decanone
Synonyms:ethylheptylketone
Source:Pfhltz & Bauer
00
80
AppcndixIll: MassSpectlir 251
RT : l- 5. l9 A l: I 1 8 6 K I: I 1 8 8 B u ty l n -h e xanoate< n->
CAS#: 626-82-,1 MF: C l0 I{20 O2 l-W 112 MSI) LIB#: | 86
CN: hcxanoicacicl,l'rutylcstcr
Synonynrs: l)utylcaproate
Soulcc:distiIlcclred cleliciousapplcs
RT : 1. 5. 21 A I : I l 8 (r K I: | 1 8 8 T e rp i n e o l< o ->
CA S #:98- . s . s - .5 M F : C l 0 H IU O F W : l -54 MS D LIB #: l -5l 7
CN : 3-cyclohcxcne-| -nrcthanol,o.cr.zl-trinrelhyl-
Synonynrs: p-rnenth- l -en-8-ol
Srrurce:Urnbel.lularia colilbnrit'aoil. RP Adarns#-5.132
Q
RT : l- 5. 24 A l: 1 1 8 7 K l : l l 8 9 N l e n th a -l (7 ),8-di en-2-ol
< trans-p->
CA S #: 21391- 8 4 -4 MF : C l O H l 6 O F W: l -52 MS I) Ll l l #: l 07l
CN: cyclohcxanol.2-methylcne--5-1 l-methylethcnyl)-, trans-
Synonyrns: trans-isocarveol
Source:rcl'.cpd. ex Guy Collin
r 00
./\t/
tl OH
80
60
tl
\-/
40 :
20
252 Adams: EssentialOil Comtronentsby GC/MS
RT: 15.2-5AI: I 187 KI: l l 8 9 D o d e c e n e < l ->

CAS#:112-41-4 MF: C12H24 FW: 168 MSDLIB#:l2l4
CN: dodecene(1-)
Synonyms:none
Source:Olelinsmix ex Aldrich and SigrnaChem.;0.537oHedychiumcorottarium,
Hibiscnsabelnnschus
Vitexaglrtts-r:astusi0.307o
lrF) 6:217(1991);0.40a/a
. -,^ 4 1
H2c=cH(cH2)9cH,
RT: l-5.25AI: 1187 KI: 1189 Verbanol<neoiso->

CAS#:94480-8 l-6 MF: C l0 H I 8 0 F'W:l -54 MSD LIB#: 1546
CN: bicyclo(3.I . l )heptan-2<tl, I o,2B,a
4,6,6-trinrethyl-( u)-
B,-5
Synonyms: none
Source:ref-.cpd.ex E. von Rudlol'f
-,ru,"z
OH
R T: 15. 26 A I : I 188 KI: I1 8 9 Heptanal, diethyl acetal-

C AS#: 688- 82- 4 MF: Cl I H24OZ F W: 1 8 8 MS D LIB #:2117
CN: heptane,I,l -diethoxy-
Synonyms:none
Source:Bcdor"rkian Res.
oA
Appendix
RT: 15.26 AI: ll88 KI: l189 Heptenal <(48)->,diethyl acetal

C A S #: 18492- 6 6 -5 MF :C l l H 2 2 0 2 F W : 186 MS D LIB #:792
CN: 3Jreptene, 7,7-diethoxy-, (3ti)-
Synonyrns:3-heptene, 7,7-diethoxy-
Sourcc:BedoukianRes.ex Art Tucker
r00
80
ffio"
60 I
oEr
40
20
RT: 1.5.27AI: I188 KI: l190 Cresol<2-methoxy-p->

CAS#:93-.51-6 MF':C8 H l0 02 FW: 138 MSD LIB#:481
CN: phenol,2-nrethoxy-4-methyl-
Synonyms: creosol
; 4-methylguaicol
Source:rel-.cpd.ex ll. vonRucllolT
.d-
RT: 1-5.30 AI: I 189 KI: I 190 Prenyl angelate
C A S #: 83783- 8 2 -8 M F : C l 0 H l 6 0 2 F W: | 68 MS D LIB #: l 99l
CN: 2-butcnoicacid.2-rnethyl-,3-nrethyl-2-butcnyl ester,(22)-
Synonyrns:3-methyl-2-butenyl angelate
Soutce:BcdoukianRes.ex .l.lBrophy;0.137oArt.tlrcmis nobilis, I lth Intl. Cong.oiEss. Oils,
N c w l) elhi,I nc li a4 ;2 0 7 (1 9 8 9 )
-U-"ry
RT: 1 5. 33 A I : 118 9 K I: 1 l 9 l Ph e n o l< 2 -a l l y l - >

CAS #: 174. s - 81- 9 MF :C 9 H l O o FW: 134 MSDLIB#: 1268
CN: phenol(2-allyl)-
Synonyms:phcnol,(2-(2-propenyl-))
RT: 15.3-5 AI: l 190 KI: I l9l Nlethyl salicylate

CAS#: ll9- 36- 8 MF: C8 HB()3 FW: 1.52 MSI) LIB#: 1400
CN: benzoicacid,2-hydroxy-,Inetltylester
Synonyms:salicylicacid,rnethylester:wintergleenoil: 2-carbonlethoxyplrenol
Artitlcial sassaliasflavor,Loran Oils;99.40Vo
S<rurce: Betulaalnoides,JEOR 7:565(1995);
90.00a/a
Gaultheria procumbens; 47 .48'/oAcal:iafantesiana
l00
80
60
40
20
R T: 15. 38 A l: 119 0 Kl : I 1 9 2 D e c a n o n e< 2 ->

CAS#: 693-54-9 MF: ClO H20 O FW: 1.56 MSD LIB#: 57-5
CN: 2-clecanone
Synonyrns: nethyl octyl kctone
Squrce:ref'.opd.ex E. von Ruclloif:2.80a/n Sci. Pharrn.56:12l(1988);
Rutagravettlens,
ensis; l .54VoRhanterium epappo,swn
Ruta clml.elt
| .5(:a/a
:
R T : l- 5. 40 A I : l l 9 l K I: l l 9 2 H e x y l b u ta noate
CAS#: 2639-63-6 MF: Cl0 H20 02 FW: 112 MSD LIB#: 73
i CN: butanoicacid, hexyl ester
Synonyrns:hexyl butyrate
RT: l-5.41 AI: I l9l KI: I192 Dihydro carvone <cis->

CAS#: 7764-50-3 MF: ClO Hl6 O FfM: 1.52 MSD LIB#: 609
CN: cyclohexanone,2-rnethyl-5-(1-methylclhenyl)-
Synonyms: p-menth-8-en-2-one:5-isopropenyl-2-rnethylcyclohexanone
Source:Dill seedoil, Schilling;26.167aSphaeranthus cyathuloides,
JEOR 1:177(1995);
| 1.387aH1:ptismutabilis; 5.20VoAnethunxsowa
f
100
80
60
40
20
40 60 80 100 t20 t40 t60

!
RT: 1.5.4.5AI: 1192 KI: I I93 Dihydro carveol
CAS#: 38049-26-2 MF: C l0 H I 8 O FW: 1.54 MSD LIB#: 602
CN: cyclohexanol, 2-methyl--5-( (l cr,2B,-5o)-
l -nrethylethenyl)-,
Synonyms:revisedname,old name= neoiso-clihydrocarveol
Source:ref. cpd., S. Geribaldi,France;7 .l l%oMentlta suaveoleils,in: De vluehtigeolie van
enkeleclrernotypenvan Mentln suave.olens L,hrh.E,nvan hybridenmet Men, H. Hendricks,
Ph.D. thesis,U. Riiksuniversiteit, Groningen(1974); 5.947oMenthaspicata;3.517o Menthalongfolia
r00
80
60
40
20
.=
RT: l-5.4-5 AI: 1192 KI: I 193 Phenyl etlryl acetate<l->

CAS#:93-92-5 MF: Cl0 Hl2 02 FW: l(r4 MSD LIts#:1275
o-mctlryl-,acelate
CN: bcnzenenrethanol,
Synonyrns: phenylethylacetate,u-; gardenol;stytalylacetate
JEOR 8:241(1996)
Source: Pfaltz& Bauerex A. Tucker; 1.227oGardeniaiasminoide.s,
Y
Y"
r\
\2
RT: l-5.47 Al: I 193 KI: l 194 Dilrydro carveol <neo->

CAS#: I 867.5-33-7 MF: C l0 H | 8 O FW: 154 MSD Llll#: 600
CN: cycfohexanol,2-rnethyl--5-( (1u,2u,
I -nrethylethenyl)-, 5B)'
Synonynrs: revisednanre.old classical natrle= iso-dihydrocarveol
Source:ref. opd., S, Geribaldi,France
=
.nr*ot
tt
tt
./\
RT: f -5.48 AI: | 193 KI: | 194 Decenal<(42)->

CAS#: 21662-09-9 MF: Cl0 Hl8 O FW: 154 MSD LIB#: .581
CN:4- dec enal,(Z)-
Synonynrs: cis-4-decenal
Source:BcdoukianRes.crxArt Tucker; 2.1001, .IIIOR 2:259(1990);
Alpinia ka.tsuntadai,
1.10%Carunt carvi; (1.307oCoriandrurtrsativtutt
4l o
.
RT: 15.48 AI: 1193 KI: 1194 Hexenylbutanoate<(28)->

CAS#:-53398-83-7 NIF:Cl0 Hl8 02 FW: 170 MSD LIB#:3.13
CN: butanoicacid,2-hexenyl ester
Synonyrns:trans-2-hexerrylbutyrate
Source:ref'.cpd.ex H. I)ePooter
128 141
40 60 100 120 140
RT: 1.5..5.5
AI: ll94 KI: 1195 Dihydro citronellol
CAS#:106-21-8 MF : C l 0 H 2 2 O F W: 1.58 MS D LIB #: 604
CN: l-octanol,3.7-dimethyl-
Synonyms: tetrahydrogeraniol; per"hydlogeraniol
Source:SCM Chems.ex H. Hills
A)
+-)
56
70
60
tr.l
80
97
100
112
120 160
f..
RT: 15.55 AI: 1194 KI: 119-5 Menthan-2-one<cis-p->
CA S #:3901- 91 -5 M F ' :C l 0 H l 8 O F W; l -54 MS D LIB #: 1073
CN: cyclohexanone,2-rnethyl--5-( I -methylethyl)-,cis-
Synonyms:carvomenthane;isocarvomenthane
55
ilt )-'
60
40
20
69 X
258 Adams: EssentialOil Cornponentsbv CC/MS
RT: 1 5. . 5. 5A I : 1194 K l : 1 1 9 .5 M y rte n o l

CAS#:.51.5-00-4 MF:ClOH16O FW: 1.52 MSDLIB#: 1124
6,6-dimethyl-
CN: bicyclo(3.L l )hept-2-ene-2-rnethanol,
Synonyms:2-pinen-I 0-ol
Source:ref. cpd. ex E. von Rudloff; 27.107oLippia multiflora (leaf , .
.fEOR 7:33l( 199-5);Myrtus communis(maturefruit); 3.80%Artentisiaalba .
100
i
80
60
40
20
6
RT: 1 . 5. . 56A l: 119.5 KI: I1 9 .5 My rte n a l
CAS#: 564-94-3 MF: C10 Hl4 O FW: 1-50 MSD LIB#: 1125
CN: bicyclo(3.l. I )hept-2-ene-2-carboxalclehyde, 6,6-dimethyl-
Synonyms: none
Source:ret'.cpd. ex E. von Rudlofl; 21.027oLedumpalustre,p.8O,
in: AromaticPlants& EssentialConstituents, PeaceBook Co., Hong Kong(1993);
5.00VaAn themisnob ilis: 3.807oArtemisi.aalba
6
RT: 15.-57AI: ll95 <meta->
KI: I196 Anisaldehyde
CAS#:-591-31-l MF: C8 H8 02 FW: 136 MSD LIB#: 167
CN: benzaldehyde,3-methoxy-
Synonyms:3-anisaldehyde
Source:Atdrich Chem.;0.747oKaempferiagalanga(rhizome),p.103,
in: AromaticPlants& Hssential PeaceBook Co., Hong Kong(1993);
Constituents,
().587 A rtenti.si o v'altotri i
1,16,/o
i
AppendixIII: Mass Spectra 259
RT: I 5.57 AI: I I 95 KI: I I 96 Methyl chavicol

CAS#: 140-67-0 MF: ClOHl2 O FW: 148 MSDLIB#: 169
CN: ntethoxy-4-(2-propenyl)benzene
Synonynrs:estragole;esdragol;chavicol methyl ether
Sor.rce:clistillationof'basilleavesex McConnick Co., RP Adams#5427
96.7\a/aAgastaclrcfoeniculum, JEOR 4:295(1992):93.20VoAntonrumlhtgnifonne;
93.10o/oClausena dunniana
RT: 1.5..59AI: I l9-5 KI; l 196 Piperitol <cis->

C A S #: 34350- 53 -3 M F : C l 0 H l 8 O F W : 1.54 MS D LIB #: 1327
CN: 2-cyclohexen-l -ol, 3-methyl-6-(1 -methylethyl)-, (lR-cis)-
Synonyrns: p-menth-l-en-3-ol.(3R,4S)-
Source:ret'.cpd. ex E. von Rudlofi; #2509;26.42Vo Citrussinensis,.IEOR7:10-5(199-5);
| 5 .2()%, C),mbop og on j wa ra ncusa; 0.807oM 1-r i st i ca fr ag r ans
RT : l- 5. 60 A I : I 1 9 6 KI: l l 9 6 C a ra n o n e< tr ans-4->

CAS#: 4176-04-9 MF: Cl0 H l6 0 FW: 1.52 MSD LIB#: 17-5-5
CN: bicycfo(4.L0)heptan-3-<>ne, 4,1,7-trimethyl-,( l R, 45, 65)-
Synonyms:none
Source:Litruloplila cltinensi.s ex Art Tucker
RT: 1.5.60 AI: I 196 KI: | 196 Decanol<3->

CAS#: 1565- 81- 7 MF: Cl0 H22O F W: 1 58 MSD LIB#: -573
CN: 3-decanol
Synonyms:3-hydroxydecane
Source:Pl'altz& Bauer
RT: l- 5, 60 A I : 119 6 K I: 1 1 9 6 D e c e n a l< (4 E)->

CAS #: 6. 540- 5- 70 -l MF : C l 0 H l 8 O FW: 154 MSD LIB#: 582
CN:4-decenal.(E)-
Synonyms:trans-4-decenal
Source:BedoukianRes.ex Alt Tucker
RT: 1.5.60 AI: | 196 KI: 1196 Methyl heptinecarbonate

CAS#: lll- 12- 6 MF:C9 H1402 FW: 154 MSDLIB#:215|
CN: 2-octynoicacid,methylester
Synonyms:flolionelVert de vilette, artificial;
.^ ^ 41 qi
RT:1 .5.6 1 AI: l 196 KI : ll96 Cum enol< o- >

CAS#:88-69-7 MF: C9 Hl2 O FW: 136 MSD LIB#: 162-5
CN: phenol,2-(l -methylethyl)-
Synonynrs:phenol<o-isopropyl->
I
a\YoH
\-/
40 60
RT: 1.5.63AI: 1196 KI: I197 Ethyl octanoate

CAS#:106-32-l MF: Cl0 H20 OZ FW: 172 MSD LIB#: 76
CN: octanoicacid, ethyl ester
Synonyms:ethyl caprylate
Source:Afdrich Chem.l 6.667oBuddleia asiatica,in: Aromatic Plants& Essential
Constituents,New Sourcesof EssentialOils in China,PeacetsookCo., Hong Kong(1993);
5 .627oCha enomeIes sp ec i osa; 2.247oM andrag o ra ffi cina ru nt (fr uit)
ll
AoA(cH2)6-cH3
RT : l- 5. 64 A I : I1 9 7 K I: l 1 9 6 S a fra n a l
CAS#:ll6-26-7 MF: Cl0 H14O FW: 1-50 MSDLIB#: 1369
CN: 1,3-cyclohexadiene- y de,2,6,6-trimethyl-
| -carboxaldeh
Synonyms:salldon:safi'ani ne
of High
Soutce:rel'.cpd. ex P. Weyerstahl;60,30% Crocus satitttts,.Tourn.
Resof.Chromot.l4:771(1991):0.lUVo Narcissustazetta(absolute);0.05VaTllia cordata
t07
80
60
40
20
262 Adarns:EssentialC)ilComponents
by GC/MS
RT: l-5.66 Al: ll9l KI: 1 197 Butanoic acid,2-methyl-4-methylpentylester

CAS#: 3.5852-40-.5 Ml.: C l l H22 02 FW: 186 MSD LIII#: l 9l0
CN: butanoicacid,2-mcthyl.4-methylpentyl ester
Synonyms:lsohexyl2-rrre'thylbutyrate
Source:Lornatiurud.issectuntroot oil ex Vasu l)ev
100
80
60
40
20
RT: 1.5.66 AI: l197 Kl: l197 Nlethyl o-cyclogeranate

C AS#:28043- 10- 9 M F : C l I H l 8 ()2 F IM : 1 8 2 MS D Ll l l #: 1087
CN: 2-cyclohcxene- 1-carboxylicacid,2,6,6-trimethyl-, methylester
Synonyms:none
Source:ref. cpd. ex P. Weycrstahl
r00
80
60
40
20
100 120 r6 0
R T: 1 5. 66 A l: ll97 K I: 1 1 9 7 V e rb a n o l
C AS#: 94480- 83- 8 MF :C l OH l 8 O FW: 154 MS D LIB #: 1.547
CN: bicyclo(3.I . l )heptan-2-<tl, 4,6,6-trirnethyl-( I a,2a,4cr,-5a)-
Synonynrs: nonc
Source:ref'.cpcl.ex E. von Rudlofl; 1.12a/o Daucuscarota..Ind.Alirn. Ag. 108:3-57(199 1);
0 .90 7o Cinnank)mLtnl ap p eli an.unq 0 .50 a/oP i,st at:i a l erft i sc us
r0 0
80
60
40
20
Appendix
RT: 15.67 AI: 1197 KI: I198 Octenolacetate<(22)->

CAS#:26806-12-2 MF: ClO Hl8 ()2 FW: 170 MSD LIB#:2079
CN: 2-octen-
l-ol, acetate(ZZ-)
Synonyms: none
40
20
RT: l-5.(r8AI: l197 KI: I198 Hexenyllactate<(32)->

CAS#:61931-81-.5MF:C9Hl6 ()3 l:W:112 MSDLIB#:I587
CN: propanoicacid,2Jrydroxy-,(32)-3-hexenyl
ester
Synonyms:none
4.5
100
80
60
40
2(l
R T : l- 5. 69 A I : ll 9 8 KI: I198 Shisofuran

CAS#: 235742-95-7 MF :C l 0 H l z O F W : 148 MS D LIB #: l 4l 3
CN: shisofuran
Synonyms:none
r00
80
60
40
:
!
264 Adams: EssentialOil Comoonentsbv GC/MS
R T: 1 . 5. 72 A I : 1198 K I: I1 9 9 D e c a tro <

l 2 ->
CAS#: 1120- 06- 5 MF: ClO H22O F W: l -5 8 MS D LIB #: l 8l 7
CN: 2-decanol
Synonyms:sec-decylalcohol
Source:alcoholsnix (2-OHs) ex K-H Kubeczka
80 Y(cHrrcH3
OH
6(
40
20
120 140 t60
RT: l-5.73AI: 1199 Kl: 1199 Terpineol <y->

CAS#;.586-8l-2 MF: C l0 H I 8 O FW: 1.54 MSD LIB#: 1527
1-methylethyllidene)-
I -methyl-4-(
CN: cyclohexanol,
Synonyms: none
Source;Unipine90 ex AllenGanser & Assoc.
A'
X
40
RT: f .5.74 AI: I199 KI: I 199 Decenal<(72)->

CAS#: 21661-97-2 MF: Cl0 Hl8 O FW: 1.54 MSD LIB#: 2132
CN: 7-decenal, (72)-
Synonyms:none
Source:BedoukianRes,
100
80
60
40
20
RT: 15.7.5 AI: I199 KI: | 199 F;thyloct-(22)-enoate

CAS#: 42178-93-8 MF: Cl0 Hl8 02 FW: 170 MSD LIB#: 684
CN; 2-octenoicacid, ethyl ester,(Z)-
Synonynrs:none
40 60 80 100 120 I
R T : 1- 5. 75A I : I1 9 9 KI: I1 9 9 M e n th a n -2 - one< trans-p->

CAS#:499-70-1 MF:Cl0 Hl8 O FW: 1.54 MSD LII]#: 1074
CN: cyclohexanone,2-methyl--5-(
I -nterhylethyl)-,trans-
Synonyms:carvornenthone:tetrahyclrocarvone
RT: l-5.77 Al: 1200 KI: 1200 Dodecane

<n->
CAS#: ll2-40-3 Mts:C12H26 trW: 170 MSD LIB#: 92
CN: tlodccane
Synclnynrs:none
Sotrrce:Alkanesnrix, Alltech Assoc.;3.507oAcocictprae(:ox(llower).FF-JI l:3(1996);
1.094/aValerianafficinalisl 1.00VoVite.r.an.gus-castus
(]eal)
57
t00
cH3(cH2)1ocHs
80
60
40
2(
141
140
266 Adarns:EssentialOil Componerrtsby GCiMS
RT: 15.80 AI: 1200 KI: 1200 Caranone<cis-4->

C AS#: 4116- 01- 6 MF : C l 0 H l 6 O F W: 1 .52 MS D LIB #: 17.54
CN: bicycfo(4.| .0)hcptan-3-one, ( I R,4R,6S)-
4,7,7-trinrethyl-,
Synonyrns: nonc
Sonrce:Litnnophilachinensi.s ex Art Tucker
RT: 15.80 Al: 1200 Kl: l200 Dihydro carvone <trans->

CAS#:. s 948- 04- 9 MF: Cl0 Hl6 O F ' W: 1 .5 2 MS I) LIB #: 610
CN: cyckrhexanone, 2-methyl-5-( | -methylethenyl)-, trans-
Synonynrs: p-menth-8-en-2-one, trans-
Source:Dif l seedoil, SchillingCo.;67.437oSphaeratttluts .TEOR7:177(1995');
cyathuloides,
yp 2 1
32.9| 7aH ti s nurtabiI i s; .60% T anacetttm','ulI a r e ( 1l
ower)
r00
80
60
.10
It)
+0 60
R T: l - 5. 83 A I : l2}l KI: l20l Decanal<n->

CAS#: 112-31-2 MF ' :C l 0 H 2 0 O FW: 156 MS D LIB #:40
CN: decanal
Synonyms:caprinicaldehyde
Source:Alclehycle mix, Aldrich Chenr.;26.60VoPolygonummirms,.IEOR2:167(1990);
17 .00% Ci t rus sinertsi s; 13.70o/oCo ri atrdn rnr.sat itttutt
cH3(cH2)8cHo
267
RT: f 5.86 AI:1202 KI: 1202 Butanoate<3-methylpentyt,3-methyl->l

cAS#: 83783-89-5 MF: Cl l H:2202 FW: 186 MSD LIB#: 1584i
CN: butanoicacid, 2-methyl-,3-methylpenrylester
Synonyms:none
Source:Lomatium dissectumex Vasu Dev
. ^. . 4l
"T
RT: l-5.86 Al:1202 KI:1202 Elshottziaketone

CAS#:488-0-5-1 MF: ClO H1402 FW: 166 MSD LIB#:654
CN; | -butanone,
3-methyl- I -(3-methyl-2-luranyl)-
Synonyms: elsholtzione
Source:Elslnltziacristcrta
ex O. Vostrowsky,PlantaMed.3;268fl9g7)
RT: l-5.90 AI: 1202 KI: 1203 Hexadienol isobutanoate <(28,4E)->

CAS#: 000-00-0 MF: Cl0 Hl6 ()2 F-W:168 MSD LIB#: 2l0l
CN: 2.4-hexadien-I -ol, isobutyrate,(28,48)-
Synonyms:none
la
RTr 15.90 AI: 1202 KI: 1203 Norbornene-2-methanol acetate <exo-S->

CAS#: 128435-13-2 MF: Cl0 Hl4 OZ F-W:166 MSD LIB#: I176
acetate,exo-
CN: bicyclo(2.2.l)hept-5-ene-2-nrelhanol,
Synonyms:none
Source:acetylationof norborene-2-methanol(62.59)
..$t\ o-L
RT: 15.97 Al:1204 KI: 120.5Verbenone

CAS#:80-57-9 MF:C10Hl4 O FW: 150 MSDLIB#: l-5.50
CN: 4,6.6-trimethyl bicyclo-(3.I. I )hept-3-en-2-one
Synonyms:2-pinen-4-one
Source:ref. cpd. ex Tom Philtips,UF; l-5.587o Rosntarinus fficinalis,
Gida Sanyii l:20( 1988); 10.217o Magnolia grandiflora;8.857o Micronteria congesta
t00
80
60
'+0
20
A
<p->
RT: 1.5.98AI 1204 Kl: 1205 Cymen-9-ol
CAS#:4371-.50-0 MF: Cl0 H14O FW: 1.50 MSD LIB#: 547
CN: benzencethanol.B,4-dimethyl-
Synonyms: | -ol
2-p-tolylpropan-
Source:RoureBertrandex H. Hills
+-1
100
8(
f,,
60
4t)
20
AppentlixIII: N4ass
Spectra 269
RT: l6.10 Al:1201 KI: 1208 Hexanol <3-rrrethylthio-l->

CAS#: 5 I 7-5.5-6(r-9 MF: C7 H l6 O S FW: | 48 MSt) LIB#: 80l
CN: | - hc x ano l3, -(m e th y l rh i o )-
Synonyltrs: none
Source:Aldrich Chcrn.ex ArLTucker
l( x) 4l
80
60 *oH
40
20
40 60 80 t(n 120 t40
RT : 16.l0 A l l 2 0 l KI: 1 2 0 8 P i p e ri to l< trans->

CA S #: l( t 721-3 9 -4 MF ' :C l O H l 8 O F W: 1.54 MS t) LIU #: 1328
CN: 2-cyclohcxern- | -ol. 3-rnclhyl-6-(
I -lnctlrylethyl)-,tr.ans-
Synonynts:p-ntcnth-| -crr-3-ol,tlans-
Sottrce : rcl-.cpcl.cx E. von Rucllol'l'; 8.30%,Cvnbopogou.jtroran(:usa.
p. 317.in: F lav.& F l a g .:A Wo r' l cPc etal .(ccl s.).
l l s p ..L a rvrcnce.
Prrrc.f {)thIntf. corrg.ol'Ilss.oils. lilscvier.Arnsterdanr(1988); Citnts paradi.si,.
7.u10%
0.J0(/t,Zi tt ei lter ca..\'s
ltrn.t
l tto r
t(x)
tt0
60
A
40 \-\""
2Q
i
RT: f (r.f 2 Al: 1201 KI: 1208 Norbornene-2-methanolacetate<enclo-S->

CA S #: 160- 53 -0 6 -8 M F : C l 0 H 1 4 0 2 F W: 16(r MS I) LIB #: I t77
CN: hicyclo(2.2.| )hcpt--5-enc-2-nrethauol, acctate.cnckr-
Synttnl,ttts:ttt'tt'tc
Soulcc:acctylaliorr ol' noLborenc-2-ntethanol(62-59)
t ( x)
8()
6(
2't0 Adams: EssentialOil Componentsby GC/MS
RT: 16.14 AI: 1208 KI: 1209 Octenolacetate<(2E)'>

CAS#:39t3-80-2 MF:Cl0 Hl8 ()2 FW: 170 MSDLIB#:2078
(2E)-
acetate
CN: 2-octen-l-ol,
Synonyms:none
o"o%
RT: 16.23 AI: l2l0 KI: l2l I N{ethyoxythiophenol<2->

CAS#: '7217-59-6 MF: C7 H8 O S FW: 140 MSD LIB#: 1652
CN: 2-methoxybenzenethiol
<o-mcthoxy->
benzenethiol
Synonyms:thitlguaiacol,
100
t^
80
6{)
10
el-"--
RT: 16.24 AI; 1210 Kl 1212 Nonadienal<(28,48)->
C AS#:- 5910- 87- 2 M F : C 9 H l 4 O F W: 1 38 MS D LtB #: l 16l
CN: 2,4-nonadienal, (E,tl)-
Synonyms:nonadienal, trans-2,trans-4-
Srrurce:AfclrichClrern.ex Art Tucker;0.257oRhuscoriaria,I)ragocoBericht3:81(1993);
0.017oJuniperuscomnturtis (leafl
tl
8( ,W
60
40
20
RT: 1 6.3 0 AI: l21l KL1213 O c t anol ac e t a t e

CAS#:ll2-14-l MF: ClO H2O02 FW: 112 MSD LIB#: 1204
CN: aceticacid, octyl ester
Synonyms:octyl acetate;capryl acetate
Source:acetylationo1'octanol(62t 0)
RT: | 6.34 Al: l2l2 Kl l2l4 Dihydro carveol <iso->

CAS#: l8675-3.5-9 MF: C l0 Hl 8 O FW: 1-54 MSD LIB#: 60l .
CN:cyclohexanol,2-methyl-5-(l-methylerhenyt)-,(la,2B,-5B)- i
Synonyms:p-menth-8-en-2-ol
Sorrrce:ret'.cpd.,S. Geribaldi,France;0.59VnHyptismutabilis,.IEOR7:81(1995);
0 .207oAn etlm m g rav eo Iens: 0. | 0 VaSanto I ina n.eapo Ii tana
100
80
60
40
20
RT: 16.3-5 Al: l2l3 KI:1214 Pulegol<trans->

CAS#: 22472-79-3 MF: ClO Hl8 O FW: l-54 MSD LIB#; -589 r
CN: cyclohexanol.-5-methyl-2-( (
| -rnethylethylidene)-,I S-trans-.)-
Synonyms:p-menth-4(8)-en-3-ol
Source:Dicerandrafrutescensoil ex Mark Deyrup, FL
?
272 hy GC/MS
Adams:EssentialOil Comporrents
RT: 16.39 AI:1214 KI: 121-5 Dihydro rnyrcetrolacetate

C AS#: 53167- 93- 4 M F :C l 2 H 2 2 OZ F W: 1 9 8 MS D LIB #:-593
2,6-climethyl-,
CN: 7-octen-2-ol, acclate
Synonyms:uone
Source:acelylationof dihydromyrcenol(6547)
100
8r)
60
40
20
R T: 16. 39 A l 1214 K I: 1 2 1 .5 F ra g ra n o l
CAS#: 10864.5-.56-3MF: C l0 H l 8 O FW: 154 MSD LIB#: 234
CN: cyclobr.rtane ethanol, l -methyl-2-(I -methylethenyl)-,trans-
Synonyms:none
Scrurce: Artemisia ve.stitoex P. Weyerstahl|-9.10'7o Achillea willtelmsii,
p .8 -5,in: P r og.in E s s .Oi l R e s e a rc hE, .-.I'B ru n k e ,trd .,GruyterP ubl .'B erl i n(1986);
0.5| 7t Artentisia ve,stita
.A
-Fo'
R T:16. 42 A l: 1214 K l : 1 2 1 6 L i n a l o o l fo rm a te
CAS#: I 15- 99- 1 MF : C l I H l 8 0 2 FW: 182 MS D LIB #: 1009
CN: 1,6-octadien-3-ol,3,7-dinrethyl-. lr rmate
Synonyms:vetiverol
Sourcc:recd. as vetiverol from Arf Tucker, identified as Linalool formateby P. Weyerstahl;
0.447oCitnrs sinensis,JEOR7:10-5(199-5)
o-,'y'o
80
60
4()
20
AppcntlixIll: MassSpcctra z t -)
RT : l( r . 44 A I : l 2 l -5 K I: l 2 l (r C a rv e o l< trans->
CA S #: ll9l- 07-5 MF ' :C l 0 H t6 O F W : 1.52 MS D LtB #: 370
CN: 2-cyclohcxen- l -ol. 2-rncthyl--5-( l-nrethylcrhenyl)-,rrans-
Synonyrns: p-tnentha-(r.l3-d icn-2-ol.trans-
Srr111'sg' Jtttriperu,s.flnccido v. poltlatra. RP Aclarns#2578,3.70% At,ttilteamillefctlitmr,
l.F.l I l:265(1996):2.307o Fokienioltodgirr.sii:2.28%, Cltenopodinttr
antbro,sioicles
OH
RT : 16. 48 A l: l 2 l 6 Kl : l 2 l 7 l s o p h o ro n e< 4-methyl ene->

CAS#: 20.5.18-(n-9 MF': Cl0 Hl4 O I;W: 1.50 MSD I-IU#: 967
CN : cylcohcx-2-enone, 4-ntethylene-3,.5,-5-tli methyl-
Synonyms:none
Source:kcto tabac+ rtrethylene clcriv.ex P. Weyerstahl
ll,
Y-J--
Y
o
RT : 16. - 53 A l:1 2 1 7 Kl : l 2 l 9 C i n n a m a l d ehyde< (Z)->

CAS#: 57191-69-l MF: Cl9H8 O FW: | 32 MSD LIB#: 443
CN: phenyl-2-propenal <3->
Synonynrs: phenylaclolein, cinnamal
Source:Plaltz & llauer ex H. Hills; Cinnartron Oil; CinnamicAldehvde:
Phenvlacrolein : Cinnamal
a1 tl Adams: EssentialOil Componentsby GC/MS
RT: 16.55 Al: l2l7 Kl: 1219 Cyclocitral <p->

CAS#:432'25-'7MF:ClOHl6OFW:I52MSDLIB#:1654
CN: 1-cyclohexene- aldeh
| -carbox y de,2,6.6-trimethyl-
Synonyms: none
S.,urce:Afclrichchenr.;5.827oFragariax ananassa (leaf),.lEoR-5:109(l993);
0.409oPonulus deltoides',0.197oAcaciafa mes i ana
5e"
RT: 16.55 Al: l2l7 Kl:1219 Elsholtziaketone <u'dehydro->
CAS#: 78173- 38- 3 M F :C l 0 H 1 2 (o 2 F W :l 6 4 M SD LIB #:6-55
CN: 3-buten-l -one, 3-metlryl-I -(3-rncthyl-2-llranyl)-
Synonyrns:elsholtzione<o-clehydro->
Source:Elsholtz.iacrista7qex o. vgstrowsky,PlantaMed. 3:268(1987)
100
80
60
4t)
20
RT: 16.-55 Al:1211 Kl:1219 Nonadienol<QE,4E)->

I -ol, (28,48)-
CN: 2,4-nonadien-
Synonyms;none
Sourcc:BedoukianRes.
41
100
*o
8(
6t)
40
AppcndixIII: MassSpectra 275
RT: 16.-57 AI: l2l 8 KI: 1220 Fenchyl acetate<enclo->

CN: bicyclo(2.2.1)heptan-2+|,|,3,3+rin'lerhyl-,
acerare,
endo-
Synonyms:a-l'enchylacetate
Source:Abiessibericcleaf oil ex E. von RucllofT
-^
-O-Ac
v--J-
/ll
RT; 16.(12 Al: l2l9 KI: 1221 Sabinenehydrate acetate<cis->(Ac vs. Ipp)
C A S #; 17318- 4 8 -0 MF : C l 2 H 2 0 (o 2 F -W :196 MS D LtB #: -517
CN: bicyclo(3.I .0)hexan-2-ol. 2-rnethyl--5-( l -nrcthylcthyl)-,
acetate,(
lcr,2s,5o)-
Synonyms:cis-4-thujanol ac:etate
Strrrrce:Cuprel;su,s,sorgentiileaf oil ex l,atly Cool; 3.007oMa jorana hortensis.
F'FJ2:-5-5(1981): 0.09o/aCitrus bersamia
r00
80
60
40
20
RT: 16.64 AI: l2l9 KL l22l Benzofuran <2,-3-dimetlryl->

CAS#: .1782-00-l MF: Cl0 HlO O FW: 146 MSD LIB#: 281
CN: hcnzoluran,2,3-dirnetlryl-
Synonynrs:rtone
Source:Aldlich Chern.
%
RT: 16.64 AI: 1219 Kl1221 Coahuilensol,methyl ether

CAS#: 72473-09-7 MF: C l0 H | 2 O FW: l48 MSD LIB#: 2089
CN: benzene,2-ethenyl- l -nrethoxy-3-methyl-
Synonyms:nonc
v. arizonica oil, RP Adarns#7637,
Source:Jwtilterus coah.uilensi.s
Identifrcationby NMR, Vasu [)ev
100
80
60
40
20
120
RT: | 6.73 AI: l22l Kl: 1224 Methyl-(2E)-nonenoate

CAS#:14952-06-8 MF: Cl0 Hl8 02 FIil: 170 MSD LIB#: 2182
CN: 2-nonenoic (2E)-
acid,methylestcr,
Synonyms: rnethyltrans-2-nonenoate
Source: Bedoukian Res.
100
80 tl
,"-o/tVt} (cH2)5cH3
60
.10
20
RT: 16.80 AI 1223 Kl: 1225 Citronellol

CAS#: 106-22-9 MF: ClO H20 O FW: 156 MSD LIB#: 136-l
CN: dirnethyl-6-octen- I -ol <3,7->
Synonyrns: rodinol;ceplrrol.p-citronellol
Sotrrce:Roseoil (absolute)ex Firrnenisch ex AF Thornas;59.987oRosarugosct,FFJ -5:219(1990);
0.
-5 80% P elar g o n it nr g ra t,
e ol ens; 50.007o a da ntascene
R o's
f",
Appendixlll: MassSpectra 2'77
RT: 16.83 Al:1223 KI:1226 Methyl nonanoate i

CAS#: 113l-84-6 MF: Ct0 H20 02 FW 112 MSD LIB#: I103
CN: nonanoicacid, methyl ester
Synonyms:methyl pelargonate ;
Source:Afdrich Chenr.;0.44VoHumuluslupulus,, p.59, in: Aromatic
Plants& EssentialConstituents, PeaceBook Co., Hong Kong(1993);
O.097o Osnrantltusfra g r ans; 0.05 VoSchinus mo ll e
RT: 16.85 AI:1224 Kl:1227 Cumenol<rn->

CAS#:618-4.5-l MF: C9 HlzO F'W:136 MSDLIB#: 1628
CN: phenol,3-( | -nrethylethyl)-
Synonyms:phenol <nt-isopropyl->,
<Y",
VI
RT: 16.86 AI:1224 Kl:1227 Prenyl cyclopentanone<2->

CAS#: 2520-60-7 MF: ClO Hl6 O FW: l-52 MSD LIB#: 213-5
CN: cyclopentanone,
2-(3-methyl-2-butenyl)-
Synonyms:nonc
Source:BecloukianRes.
t00
80
60
40
20
i
I
RT: 16.87 Al:1224 Kl:1227 Hydrocinnalnyl alcohol

CAS#: 122-91-4 MF: C9 Hl2 O FW: | 36 MSD LIB#: 1696
CN: benzenepropanol
Synonyms:hydrocinnamicalcohol,3-phenylpropanol,3-be'nzenepropanol
Source:Aldlich Chem.
RT: 16.93 NI 1226 KI: 1228 Dihydro carveol <neoiso->

CAS#: 18675-34-8 MF: C 10 H I 8 O FIV: 154 MSD LIB#: 603
CN: cyclohexanol, 2-nrethyl--5-( ( Ict.2o,-5s)-
I -methylethenyl)-,
Synonyms:none
Source:ref'.cpd.,S. Geribaldi,France
-.,.. 4 l
60
*
l0 f-
RT: | 6.9-1 Al: 1226 Kl: 1229 Carveol <cis->
CAS#: 1197-06-4 MF: ClO Hl6 O FW: l-52 MSD LIB#: 372
CN: 2-cyclohexen- 1-ol,2-methyl--5-(| -methylethenyl)-, cis-
Synonyms:p-mcntha-6,8-dien-2-ol, cis-
Source:SCM Cherricalsex H. Hills; 5.007oAr:ltilleomillefolium,FFJ l I :265(1996);
4.9 17o Chenop odium ambr osi oidesl | .357o Cyntbop og on nnrtini
I
o*'
/\
i
Appcndixlll: Mass Spectra 279
RT: 16.94 Al:1226 Kl:1229 Ocimenone ;

<(Z)->
CAS#:33146-11-3 MF-:Cl0 H14O FW: l-50 MSD LIB#: 14-59
CN: 2,5,7-octatrien-4-one,
2,6-dinethyl-, (Z)-
Synonyms: cis-ocimenone
Source:Tagetes minutaoil ex E. Hethelyi,Hungary;45.59a/o Togetes argentina,
JI1OR-5:851| 993);32.407oLipp ia .jat,ani <:a; 23.| 8./oTagetes ri ojarn
t00 t3-5
80
60
A
20
RT: 16.9-5 AI:1226 Kl:1229 Pulegol<cis->

CAS#: 22472-80-(t MF: Cl0 Hl8 O FW: 154 MSD LIB#: l3-50
CN: cyclohexanol, ( 1R-cis)-
I -methylethylidene)-,
-5-rnethyl-2-(
Synonyms:p-menth-4(8)-en-3-ol. ( I R,3R)-
Scrurce:pulegols ftom Mentlm ex J. IJamoso,Poltugal
RT: 16.97 Al:1221 Kl:1229 Nerol

CAS#:106-25-2 MF: ClO Hl8 O FW: 154 MSDLIB#: I138
+1, (Z)-
CN: 3,7-dimethyl-2,6-octadien-I
Synonyms:geraniol.( Z)-
Soutce:Lavenderoil ex Firmenischex AF Thomas;21.107oRosadamascena,
FFJ 7: l9-5(1992);14.76VoC),mbopogonmartini; 14.267oRosa centi.folia
<cis-p->
RT: 17.00 Al 1227 KI: 1230 Mentha-l(7),8-dien-2-ol
CAS#:22626-43-3 MF: Cl0 Hl6 O FW: 1.52 MSD Lll]#: 1072
2-methylene--5-(
CN: cyclohexanol, cis-
I -rrethylethenyl)-,
Synonyrns:
none
ref.cpd.ex GuyCollin
Source:
A*,
tt
\-/
i
RT: 17.02 Al 1228 KI: l23l Davanone<nor'>

CAS#: 549?3-91-4 MF: C l I H 18 ()2 I'-W: 182 MSD LIB#: 196
CN: 2-butanone,3-(5-ethenyltetrahydro--5-methyl-2-furanyl)-'(2S-(24(R1')'-5s))-
Synonyms:norclavanone
Armoisea clavanone
Scrurce: ex Guy Collin; 1.5OVo pallens,
Artenr.isia
30:-549(
Phytochenr. 199l);0.107aArtemisia judait'a
=
:
''.(j-:(
120 140 160 180 200
RT: | 7.07 Al: 1229 KI: 1232 Hexenyl 2-methyl butanoate <(32\'>
CAS#: .53398-85-9 MF: Cl 1 H20 02 F.W:184 MSD LIB#: 1588
(32)-3-hexenyl
CN: butanoicacid,2-methyl-, ester
Synonyms:none
4l
--/'-.,,-"
AppcndixllI: MassSpectra 281
RT: f 7.09 AI: 1229 KI: 1232 Fenchyl acetate <exo->

CAS#: 56282-46-3 MF': C12 H20 02 FW: 196 MSD LIB#: 163
CN: bicyclo(2.2.| )heptan-2-ol,1,3,3-tr'i
methyl-,acetare,exo-
Synonyms:B-l'enchylacetate
Source:Sweetanis(Foeniculttntvulgare) leaves,distilled RP Adarls #-5452
A1
RT: | 7. | 5 AI: 123| Kl: 1234 l-inalool acetate <tetrahydro->

CAS#: 20180-48-7 MF': Cl2 H24 02 FW: 200 MSD LIII#: 1014
CN: 3-octanol,3,7-dimethvl-,acetate
Synonynrs: none
Source: acetylati on of tetrahyclroIinalool(5893)
t00
80
(',0
40
20
100 120
RT: 17.19 AI:1232 KI: 123-5 Thymol, metlryl etlrer

C A S #: 1076- - 5 6 -8 M F : C l l H l 6 0 F W: 164 MS D LIB #: 1506 r
CN: benzcnc.2-nrctlroxy-4-methyl- 1-( I -rnethylcthyl)-
Synonynrs: anisole,2-isopropyl-5-methyl-; 3-rrrethoxy-p-cymcne
Source:clistillationof thyrneleaves(SchillingCo.),RP Adarrrs#-5426
100
80
60
40
20
!
RT: 11.22 AI 1232 KI: 1235 Hexenyl3-methyl butanoate<(32)'>

CAS#:35154-45-1 MF: Cl 1 H2002 FW: 184 MSD LIB#: l-589
acid,3-methyl-,
CN: trutanoic ester,(Z)-
3-hexenyl
Synonyms: Isovalcric ester,(Z)-
acid,3-hexenyl
Source:AldrichChem.
RT: 17.23 AI: 1233 Kl: 1236 Hexyl2'methyl butanoate<n->

C AS#: 10032- 15- 2 M F : C l I H 2 2 0 2 F W: 1 8 6 MS D LIB #: 187
CN: butanoicacid,2-methyl-,hexyl ester
Synonyms:none
Source:clistillationof recldeliciousapples,RP Adams #5756 0.30'/aAlolt5iq triphylla'
JEOR6:-523( 1994);0.12ok Lavandulax hybrida;0.067aLavandulalatifolia
I
o(cH2)scH3
\-Ar,
tl
RT: 17.23 AI: 1233 Kl: 1236 Thiazole <5-acetyl-2,4-dimethyl->

CAS#: 38205-60-6 MF: C7 H9 N O S FW: l-55 MSD LIB#: 1477
CN: cthanone,I -(2,4-dirnethyl-.5-thiazolyl)-
Synonyms:none
Source:Aldrich Chcm. ex Art Tucker
XX
-- 43
RT 17.27 AI: 1233 Kl: 1231 Pulegone

CAS#:89-82-1 MF ' :C l 0 H l 6 O F W: 1.52 MSD LIB#: 1260:
CN: methyl-2-(l-methylethylidiene)cyclohexanone<5->
Synonyms:p-menth-4(8)-2en-3-one
Source:Peppermintoil ex Lorann Orls;96.907oAcinos suaveolens, I
PlantaMedica 54:340(1988);86.67Vo Ziziplnra tenuior: 8l.5O7oMentha arfiensis
f
r00
80
60
40
20
140 I
RT: 17.28 Al:1234 KI 1237 Ascaridole

CAS#:.512-85-6 MF : C l 0 H l 6 ()2 F W; 168 MS D LIB #: l 86l
CN: 2,3-dioxabicyclo(2.2.2)oct--5-ene,
I -methyl-4-(I -methylethyl)-
Synonyms:none
Source:Chenopodiumoil ex TheresaChamblee;62.l2VaArtemisia molinierfr"
JEOR 4:635( 1992); 16.107oBotdea.fragrans;16.007oArtemisia abrotanumt
RT: 17.30 AI:1234 KI:1231 Citronet

CAS#:69929-16-4 MF; C12H24 O FW: 184 MSD LIB#: 2197
CN: 2-octene,
8-ethoxy-2,6-dimethyl-
Synonyms:none
Source:Bedoukian
Res.
RT: 17.30 1t1:1234 KI:1237 Decen-2-one<(3E)'>

CAS#: 10519- 33- 2 MF : C l 0 H l 8 O F W: 1 .5 4 MS D LIB #: 1940
CN: 3-de'cen-2-one (E)-
Synonyms:none
Source:BedoukianChem.ex .IJ Brophy; 0.88o/o Acronltchiapedunculata(China),
PeaceBook Co., Hong Kong(1993)
p. 63, in: AromaticPlants& EssentialConstituents,
80
)(x"(cH2)5-cH3
6(
40
20
RT: 17.32 AI:1235 KI: 1238 Neral

CAS#: 10(t-26-3 MF: ClO Hl6 O trW: 1.52 MSD LIB#: 991
CN: 2,6-octadienal.3,7-dimethyl-,(Z)-
Synonyms:citral bl Z-citral
PAITAI l0:23(1988);
Source:Lemon oil, Lorann Oils;39.257aMelissaqfficinali's,
39.15%Elsltohz.iaeriostaclTta:31 .807oLitsea cubeba
t20 140
RT: 17.32 AI: 123.5 KI: 1238 Ocimenone<(E)->

CN: 2,-5,7-octatrien-4-one, 2,(r-dimethyl-,(E)-
Synonyms:trans-ocimenone
Source:Tagetesntinuta oil ex E,.Hethelyi,Hungary; 40.387oTagetesargentina,
.IEOR -5:8-5( | 993); 33.807aTag etes tenufol ia; 26.007aTag eres mi n uta
100
80
60
40
RT: 17.33 AI: | 23-5 KI: 1238 Chrysantlrenylacetate<trans->

CA S #:. 50764--5 5 -l MF : C l 2 H l 8 0 2 F W: 194 MS D LIB #: l 46l
CN: lricyclo(3.1.l )hept-2-en-6-ol, 2,7,1-trinethyl-,acetate,(.1S-(
I o,-5o,6B))-
Synonyrns: none
Tartacetumparthenhnr oil ex H. DcPooter
Scrrrr-ce:
-"::-}
RT: 17.36 AI: 1235 Kl: 1239 Isobornyl formate

CAS#: 1200-67-5 MF: C I I fI I 8 02 FW: | 82 MSD LIB#: 1442
CN: bicycfo(2.2.I )heptan-2-<>1 1,7,'7-tritnethyl-,formate,exo,
Synonynrs:isoborneollbrmate i
Sottrce.'Strobilantltusauriailatus oil ex P. Weyerstahl;0.207oStrobilanthe.sauriutlatus,
p. -567,in: F'lav& Flag.:A WorlclPcrsp.,Lawrence,etal.(eds.),Proc. lOth Intl.
Cong.of L,ss.Oils, Elsevier,Amstcldam(1988)
RT: 11.47 AI: 1238 KI: 1241 Cumin aldehyde

CAS#: 122-03-2 MF; ClO Hl2O FW: 148 MSD LIB#: 1338'
CN: benzaldehyde, 4-( l -methylethyl)-
Synonyms:cunrinal;benzaldehydc, p-isopropyl-
Source:Polvlophium in.volucraturtt ex JJC Schel'l'er;43,487oCLuninumcvninunl,(China),
p. 139.in: AromaticPlants& EssentialConstituents, PeaceBook Co., Hong Kong(1993);
13.SOVo Arteni.siaalba;4.70 VoArtemisia catnltestris
f
RT: l'7.47 AI: 1238 KIl. 1241 Nojigiku acetate

CN: bicyclo(2.2.|)heptan2-ol, acetate'(IS-exo)-
-5,-5-dimethyl-6-methylene-,
Synonyms:camphenol acetate<6->
Source:Diplotaenia cachrydifoliaeoil ex K. Harkiss,UK
^"*A
RT: 17.49 AI: 1238 KI 1242 Hexyl(2E)'butanoate
CAS#:19089-92-0 MF: ClO Hl8 02 FW: 170 MSD LtB#: 1590
CN: 2-butenoicacid,hexylester
Synonyms: crotonicacid,hexylester,hexylcrotonate
Source:Aldlich Chem.
RT: 17.-50 Al 1239 KI:1242 Anisaldehyde <o'>

CAS#: 135-02-4 MF: C8 H8 ()2 FW: 136 MSD LIB#: 158
2-methoxY-
CN: benzaldehyde,
Synonyms: o-methoxybenzaldehyde; methylether
salicylaldehyde
Source:AldrichChem.
Appendixlll: MassSpectra 28',7
RT: 17.53 Al:1239 Kl:1243 Carvone

CAS#:99-49-0 MF: C10Hl4 O F'W:1-5Cl MSD LIts#:371
CN: methyl--5-( I -methylethenyl)-2-cyclol.rexenc-
I -one<2->
Synonyms: p-mentha-6,8-dicn-2-one
Source:Spearmint oil, LorannCo.:80.lTVoCqrumcan,i.Seif-en-Oele-Ferrr-Wachse
1| 2:1I ( 1986): 76.547oM etrtha spi cata; 70.007oM enthaIongifoIia
t00
I
(Y"
X
RT: | 7.-59 Al: 1241 Kl 1244 Hexyl isovalerate
C A S #: f 0032- 1 3 -0 MF : C l l H 2 2 0 2 F W: 186 MS D LIB #:816
CN: l-rutanoic acid,3-methyl-,hexyl ester
Synonyrns: hexyl 3-methylbutanoate; hexyl isopentanoate
Source:K & K Chem.ex Art Tucker
41
o(cH2)5cH5
-n-
r00 120 t40 r6 0 180
RT: f 7.(r0 Al l24l KI 1244 Hexenvl isovalerate<(22)->

CA S #: 54675- 7 1 -3 MF : C l 1 H 2 0 OZ F W: 184 MS D LIB #: 813
CN: frutanoicacid,3-methyl-,2Jrexenylester,(Z)-
Synonynrs: cis-3Jrexcnylisopentanoate; hexenylisopentanoate
<22->
Sourco:Rerckrukian Res.ex Alt Tuckel
100
80
60
40
2{j
l
RT: 17.61 AI1241 Kl:1244 Carvacrol, methyl ether

CAS#: 6379-73-3 MF: Cl I Hl6 O F'W: 164 MSD LIB#: l-503
CN: benzene,2-methoxy- | I
-nrethyl-4-( -methylethyl)-
Synonyms:anisole,-5-isopropyl-2-nrethyl-: 2-methoxy-p-cyrnol
Source:distilledlionr SchillingThynreherbs
RT: 17.69 Al: 1243 Kl: 1246 Benzeneacetic acid, ethyl ester
CAS#: 101- 97- 3 M F :C l O H 1 2 o .2 F Ii l : 1 6 4 MS D LIB #: 270
CN: benzeneaceticacid, ethyl ester
Synonyms:cthyl phcnylacetate; ethyl o-toluate
o\./
RT: 17.71 Al: 1243 Kl: 1241 Hexenyl isovalerate <(28)'>

CAS#: 68698--59-9 MF: C I 1 H20 02 FW: 184 MSD LIB#: 812
CN: butanoicacid, 3-rncthyl-,2-hexenylester,(E)-
Synonyms:none
RT: 17.72 Al: 1244 KI: 1247 Carvotanacetone

CAS#:499-11-8 MF:ClOHl6 O FW: l-52 MSD LIB#:377
CN: 2-cyclohexen-l-one, 2-rrethyl--5-(l-rnethylerhyl)-, (S)-
Synonyrns:p-rnentha-6-en-2-one, (S)-
Source:ref. cpd. ex Il. von Rudlofl'; 1.207aArtenrisi.aabsinthu.nr,
in: Cont. al studio
de l<rsaceitesesencialesE,spanoles, Aceite esencialde Artemisia absinthumL..
M. Mugica, etal.,Madrid(1974);0.507aCisttrsladaniferus;0.24VoEucalyptwsglobulus
I
I
I
^l
tl
tl
\-,-
:
RT: 17.75 Al:1244 KI: 1248 Car-3-en-2-one

CAS#:.5358.5-45-8 MF: C10Hl4 O FW: l-50 MSD LIB#: 1796,
CN: bicyclo(4.1.0)hepr3-en-2-one, ( I R)-
3,7,7-trimethyl-,
Synonyrns:none
Source:ref. cpd.ex Ian Southwell
RT: 17.77 Al: 1245 KI: 1248 Perilla ketone

CAS#: .5.53-84-4 MF: ClO Hl4 02 FW: 166 MSD LIB#: 1266
CN: I -pentanone,I -(3-furanyl)-4-methyl-
Synonyms:none
Scrurce:rcf. cpd. ex G. Hondo,.Tapan;3.507oCurcuma(tromatica,JEOR 8:633(1996);
0.02VoPogostemoncablin;0.017oCitnrs linnn (leafl
r00
80
60
40
20
RT: 17.80 Al:1245 KI 1249 Ethyl oct-(2E)-enoate

CAS#:23.51-90-8 MF:C10Hl8 ()2 FIV:170 MSDLIB#:683
acid,ethylester,(E)-
CN: 2-octenoic
Synonyms:none
Source:BedoukianRes,ex Tucker
100
80
60
40
20
RT: 17.83 AI 1246 Kl 1249 Isoamyl hexanoate

CAS#: 2198- 61- 0 M F :C l l H 2 2 0 2 FW: 186 MS D LIB #: 1602
CN: hexanoicacid,3-methylbutylester
Synonynrs:isoan.rylcaproate,isopentylhexanoate
Srrurce:AfclrichChem.;0.877nPistacia lentisr:tts(leat), JIIOR 4:66?(1992);
0.477o Cymbop og otr martin i ; 0.4 | VaPi stacia lentist:us \fruil)
+-l
80
60
40
20
RT: 17.83 Al:1246 KI:1249 IsogeijereneC

C AS#: 106494- 41-l M F : C l 2 H l 8 F ' W: 1 6 2 MSDLIB#:150
C
CN: isogei-lerene
Synonyms:nonc
Source:Amyri,sdiatrya leaf oil ex Tom 7'anoni
UNKNOWN
STRUCTURE
t20 t62
t20 160
Appendix
lll: MassSpectra 291
RT: 17.84 Al: 1246 KI: l2-50 Heptyl isobutanoate

CAS#: 2349-13-5 MF: C | 1 H22 02 F-W: 186 MSD LIB#: 79-5
CN: propanoicacid,2-rtrcthyl-.hcptylester
Synonyms:heptyl isobr-rtyrate
Source:ref. cpcl.ex Art Tucker
100
80
60
40
20
RT: 17.8-5Al 1247 KI: l2-50 Anis aldehyde<p->

CAS#:123-11-5 MF:C8H8 ()2 FW: 136 MSD LIB#:166
CN: benzaldchyde.
4-methoxy-
Synonyms:anisicalclchyde;
crategine;
aubcpine;
p-fonnylanisole:
obepin
Sourcc:
AldrichChem.
100
80
60
R T : 17. 85 A l: 1 2 4 7 KI: 1 2 5 0 C h a v i c o l
C A S #:. 501- 92 -8 MF: C9 Hl0 O F W: 134 MS D LIB #: 129-5.
CN: phenol,4-(2-propenyl)-
Synonynrs: 4-allyl phenol;p-allylphenol
Source:Pimentctoil, F'irmenischex AF Thorrras;21.607oPimenta recenTosa,
FocrdChem.2:19(1977);6.007o Ocintuntgratissimtrm;3.27o/o Alpinia conchigera
292 Adarns:EssentialOil Componentsby GCiMS
RT: 17.85 Al: 1247 KI: 12-50 Pinocamphone <trans-2'hydroxy->

CAS#: 84236-t)4-4 MF:Cl0 Hl6 ()2 Flil: 168 MSD LIII#: 1307
CN: bicyclo(3.1. I )heptan-3-one, ( l u'2o,-5u)-
2-hydroxy-2,6,6-trirnethyl-
Synonyms:none
Source:rel. cpd.ex P. Weyerstahl
RT: 17.86 AI 1241 KI: l2-50 Butyl levulinate

CAS#:2052-15-5 MF: C9 Hl(r 03 tsW:172 MSD LIB#: 218fi
CN: pentanoic butylester
acid,4-oxo-,
butyl4-oxovalerate
butyllaevulinate;
Synonyrns:
Bedoukian
Soulce: Res.
l00r i
tl
60
tl
40
20
RT: 17.91 AI: 1248 KI: l25l Hexadienolbutanoate<(28,48)->

CN: 2,4-hexadien-l-ol, butyrate,(28,48)-
Synonyms:none
Source:IledoukianRes.
100
80
60
40
20
RT: 17.93 Al:1248 Kl:1252 Thymoquinone

CAS#:490-91-5 MF; Cl0 Hlz|o2 trW: 164 MSDLIB#: I1.58
CN: 2,5-cyclohexadiene-1.4-dione, 2-rnethyl--5-(
I -methylethyl)-
Synonynrs: p-mentha-3,6-diene-2,-5-dione;p-cymen-2,5-dione
Source:Nigellasativaseedoil ex EA Aboutable;24.50Vo Nigeltasatvia,p. 49,
in: Proc.in Ess.Oil Research,E.-J.Brunke,Ed,Gruyterr Publ.,Berlin(1986);r
0.| 7% San reja montcuxa;0.0| o/oTlqtmus vuIgari,s
100
80
40
20
RT: f 7.9-5 Al 1249 KI:1252 Butyrophenone

CAS#:495-40-9 MF: ClO Hl2O F'W:148 MSD LIB#: 337
CN: l-hutanone, l-phenyl-
Synonynrs: phenylpropylketone;propylphenylketone
Soutce:Aldric,hChern.
o
ill
\2
RT: 17.9.5AI:1249 KI:1252 Geraniol

CAS#: 106-24-1 MF:C10Hl8 O FW: 154 MSDLIB#:728
CN: dinrethyl-2.6+ctadicn-1 -ol <3,7->
Synonyms:lernonol;guaniol
Sotrrce:Roseoil ex Firnrenischex AF Thontas:93.l5VaMorrarda.fistulo,ra.
p. 68, in: Ess.Oifs. Allured Publ.,Whcaton(l981);88.82okOcimumgratissitiunt(leafi;
114.01VaCy mbop og ut rnartini
=-
RT: 17.9.5 l:'l:1249 KI:1252 Piperitone

CAS#:89-8| -6 MF: C 10H | 6 O FW: 152 MSD LIB#: 905
CN: 2-cyclohexen- 1-one,3-methyl-6-(l -methylethyl)-
Synonyms:3-carvonrcnthenone; p-mcntl.r-| -en-3-onc
Source:Jun.iperus.floccitla v. poblana leal'oil, RP Adams #2578:-13.427o C.tmbopogon jv'arancu.sa,
p. 3 I 7, in: Flav.& Frag.:A World Persp.. Lawrence, etal.(eds.),
Proc. lOth Intl. Cong.of Ess.Oils,
Efscvier,Amsterdarn( 1988); 70.00% Mentha pulegiunr;66.107cMentha rotundifrtlia
100
A
,\
r00 120 140
RT: 17.96 Al: 1249 Kl:1252 Anethole <(Z)->

CAS#: 25619-28-l MF: ClO Hlz O FW: 148 MSD LIB#: 168
CN: bcnzene, 1-methoxy-4-(I -propenyl)-,(7,)'
Synonynrs: cis-p-rncthoxy-B-methylstyrene
cis-p-anethole;
Sourcc:Foeniculwttvulgareoil (sweetanisoil) ex RP Adams#5421:
3.417oFoeniculumvul,gare Pimpinellaoniswtr;
(sweet),FF.l8:l l5(1993);2.29a/o
|.J5o/oFoeniculwntulgare (bitter)seedIing
120 t40
RT: 17.96 Al:1249 Kl:1252 Methyl pentyl angelate<3'>

C.\S#: 53082-.58-9 MF: C I I H20 02 FW: I 84 MSD LIB#: 1988
CN: 2-butenoicacid. 2-nrethyl-,3-nrethylpentylestet(27')'
3-nrethylarrylangelate
S1'nony'ms:
Source:BedoukianRes.ex J.IBrophy; 20.337n Anthemisnohili,s(Italy),Atlas of
EssentialOils, S.R.SrinivasPress,NY ( 1986); l8.32VoAnthemi.gttobilis(Egypt);
| 6.227oAntltemis nobilis (England)
120 l40 r6 0 180

1
I

295
RT: 17.97 Al:1249 KI: 1253 Isoquinoline

CAS#:119-6.5-3 MF: C9 H7 N FW: 129 MSD LIB#: 1630
CN: isoquinoline
Synonyms:benzopyridine,leucoline,isochinolin,2-azanaphthalene
Source:Aldrich Chem.;0.03VoSpartiumjunceum(absolute), p.325,
in: RivistaItal. EPPOS(1992)
RT: 18.00 AI: 1250 KI: 1253 Myrtanol<cis->

CAS#:15358-92-6 MF: C10Hl8 O FW: 154 MSDLIB#: I 122
CN: bicyclo(3.L I )heptane-2-methanol,
6,6-dimethyl-,(la,2g,5u)-
Synonyms: none
Source:AldrichChern.ex Tom Phillips,FS[I; I .267oGeummontanum(root)j
.IEOR7:l 11(1995); l.l97oRosmariruts
fficinalis i:
.^ ^ 4l i
{
RT: 18.00 AI: l2-50 KI: 1254 Piperitoneepoxide<cis->(epoxidevs.f*)
CAS#:4713-37-5 MF: ClO H16OZ FW: 168 MSD LIB#: 1329 i
CN: 7-oxabicyclo(4.1.0)heptan-2-one,
6-merhyl-3-(l-methyterhyl)-,( I R,3R,6*.)-
Synonyms:none i
Source:ref-.cpd. ex P. Weyerstahl
296 Adarrs: EssentialOil Componentsbv GC/MS
RT: 18.02 AI: 12-50 KI: 1254 Octalactone<1->

CAS#: 104--50-7 MF: C8 Hl4 02 FW: 142 MSD LIB#: 1944
CN: 2(3H)-luranone,5-butyldihyclt'o-
Synonyms:octanoliclc-1,4-;bu{.ylhutyrolactone(y-)
Source:Becloukian Res.cx J.IBrophy;0.15% Rltuscori.aria,DragocoBericht8l-9-5(1993);
0.06% Zizyphusju.juba;0.04a/nRibesnigrunt
100
100 120 140
RT: 18.10 AI 1252 KI: l2-56 Piperitoneepoxide<trans-> (epoxidevs.IPP)

C AS#:- 57130- 28- 6 M F : C l 0 H 1 6 0 2 HW: 168 MS D LIB #: 1330
CN: 7-oxabicyclo(4. I .O)heptan-2-onc. 6-methyl-3-( ( | R,3S,6R)-
I -methylethyl)-,
Synonynrs: none
Source:ref. cpcl.ex P. Weyerstahl
tl
tl
tl
\.'\.
a
100 t20 t40 t60 180
RT: 18.l2 AI: l2-53 KI: l2-56 Sabinenehydrate acetate<tratrs'> (Ac vs. IPP)
CAS#: 77318-47-9 MF: C12 II20 02 FW: 196 MSD LIB#: 1058
CN: bicyclo(3.1.0)hcxan-2-ol.2-rnethyl--5-( lo'2B'-5c)-
l-methylethyl)-,acetate'(
Synonyms:cis-sabinene hydrateacetate(cis lbr Me vs. IPP, old namo); ac:etate
trans-4-tlru.ianol
Source:distillationof sweetmatioram leaves, RP Aclams #-5922
O-Ac
tl
V
=
120 140 160 t80

Appcndixlll: MassSpcctla 297
RT: 18. | 6 Al: 1254 KI 1257 Linalool acetate

CA S #: ll. 5- 9- 5 -7 MF':Cl2 H2002 FW; 196 MSD LIB#: l-50.5
CN: 1,6-octadien-3-ol, 3,7-dirncthyl-,acetate
Synonyurs: linaloolacetate;hcrgarniol
Source:Thynrcoil distilleclliom comm. leavcs(Schilling),RP Adams#5426;
I1.507oSkirn.nia Laureola,Glossarry
of IntlianMedicinalPlants,CSIR Pubt.,New Dclhi(1956);
69.9341t Salvi asclo rea', 56.807aCitrus aurantiunr
+-')
RT: | 8.20 Al: 1254 KI: l2-58 Catechol<3-methvl->

CAS#:488-17--5 M F : C 7 H 8 ()2 l ;W :124 MS D LIB #: 20l O
CN: I .2-benzenecliol,
3-methyl-
Synonyrns: pyrocatechol,
3-methyl-;2,3-dihydroxytoluene
Source:Toky<lKasai ex.l.TBrophy
)+ \-/
RT: 18.20 AI: 1254 KI: l2-58 Phenvl ethvl acetate <2->
CAS#: 103-45-1 MF: C10H12OZ Ffil: 164 MSD LIB#: 1274
CN: aceticacid,2-phcnylether ester
Synonyrns:benzylcarbinylacetate
Source:K & K Chem.ex Art Tucker; 21.007oCoronilla enterus,
p. 57, in: Prog.in Ess.Oil Research,E.J-.Brunke,
Ed, GruyterPubl.,Berlin(1986);
7 .l6VoMinrttsopselerryi;3.38%Nercissustazetta
r00
80
60
40
20
=
RT: 1 8. 21 A I : l2- 55 K I: 1 2 5 8 C a rv e n o n e
CAS#:499- 14- l M F :C l 0 H l 6 .O F W: 1 5 2 MSI) LIB#: 367
CN: 2-cyclohexen- | -one,6-nrethyl-.3-( l -methylethyl)-
Synonyrns: p-tnenth-3-en-2-one
Source:Roth Chem.ex Keith Harkiss;0.027oCrotoneluteria,FFJ 6: l93(199l)
f
RT: 18.22 AI: l2-5-5 KI: l2-58 Benzenemethanol <2-hydroxy->
CAS#:90- 01- 7 M F :C 7 H 8 ()2 ts W :1 2 4 MS I) LIB #:2006
CN: benzenemethanol, 2-hydroxy-
Synonyms:salicylalcohol;diathesin;saligcnin;saligenol;2-methylphenol
Source:Aldrioh Chern.ex.IJ Ilrophy
RT: 18.24 AI: 12.5.5KI: 1259 Decen-l-ol <(42)'>

CAS#: 57074-31-0 MF': Cl0 tt20 O FW: 156 MSDLIB#: .577
CN: 4-decen-l<ll, (Z)-
cis-4-decenol
Synonyrns:
Source:BedoLrkianRes.ex Art Tucker
..... 4l
,o
Appendix
lll: MassSpectta 299
RT: | 8.29 Al: l25l KI: 1260 Benzyl propanoate

CA S #: 122- 63 -4 M F :C l O H l 2 O 2 F W : 164 MS D LIB #: 292
CN: propanoicacicl,phenyhnethyl cstcr
Synonynrs: benzylpropionate
soulce: ICN Cherns.ex Art Trlckeyo.0l(/o Tmracefiunportlrcnium,F'F.II l:367(1996)
RT: 18.3.1 Al: 1251 Kl: 1261 N{ethyl citronellate

CAS#: 2270-60-2 MF: Cl I H20 02 FW: 184 MSI) LIB#: 908
CN: (r<rctcnoic acid,3,7-dirrethyl-,methylester
Synonyns:none
Srrurce:Juniperusltrcat'an.a lcal'oil. RP Adarns#286-3:4.907oMalissoofticinal.is,
l)eut. Apcrtlr.Ztg. 129:l-5-5(
1989);2.00a/o Baccltorisdracunt:ulifolia; | .607oJunipentssaLtina
I 00
80
60
40
)o
RT : 18. 34 A l: l 2 -5 8 K I: l 2 (rl My rta n o l < t rans->

CA S #: 15. 1. 58 -9
-.51 M F : C l 0 H l tt O F W : 154 MS I) LtB #: l l 23
CN: hicyclo(3.I . I )heptane-2-nrcthernol, 6,6-dirnethyl-.( 1u,2s,-5a)
Synunyr-ns: nonc
Af drich Clrcm.ex Tom Phillips,FSU; 3.637oGeuntntontanure(root),
S<rttrc:c:
.IHOR7: I l7( 199-5); 2.327oRosmarirur.s o.fJir:irtale:0.20(/r,
Ptcroniairrcutrr
.. 4l A1
300 Adarns:EssentialOil Cornponentsby GC/MS
RT: 18.38 AI: 12.59 KI:1262 Cinnamylalcohol <(Z)->

CAS#: 4510- 34- 3 MF : C 9 H l 0 O F IV : 1 3 4 MS D Ll Il #: 450
CN: 3-propen-l -ol, 3-phenyl-,(Z)-
Synonyms;cis-cinnanryl alcohol
Source:Aldrich Chent. H. Hills
ex
100
80
60
40
20
RT: 18.38 AI 1259 Kl:1262 Decen'l-ol<(48)->

CAS#:10339-62-5 MF: Cl0 H20O FW: 156 MSDLIB#: 578
(E)-
CN:4-decen-l-ol.
Synonyms:trans-4-decenol
,o
RT: 18.42 AI: l2-59 KI: 1263 Carvone oxide <cis->

CAS#: 18383-49-8 MF': Cl0 Hl4 OZ FIM: 166 MSD LIB#: 376
lS-( | u,4p,6ct))-
.0)heptan-2{ne,I -methyl-4-(I -methylethenyl)-,(
cN: 7-oxahicyclo(4.1
Synonyms:p-mentha-8-en-2-one,1,6-epoxy-, ( 1S,4R,6S)-
Source:Carvoneoxicle.PPF'#010959,ex H. Hills; 0.l\Vo Mentha'spicata,Perf.Flav.-5:6(1980)
Appcndix lll: Mass Spectra 301
RT: 18.44 AI: 1260 KI:1263 Decenal<(2E)->

CAS#:3913-81-3 MF: C10Hl8 O FW: l-54 MSDLIB#:472
(E)-
CN: 2-decenal.
Synonyms:trans-2-decenal
Source:Corianderoil ex GuyCollin; 46.107o
Coriandrunr sativum(leal),Agric.FoodClrent.
38:2054(1990);8.25Vo Canrmcarvi: 8.A0VaRhuscoriaria
RT: 18.-51 AI: 1261 KI: 1265 Chrysanthenylacetate<cis->

CAS#: 67999-48-8 MF-:Cl2 Hl8 ()2 FW: 194 MSD LIB#: 23.5
CN: bicyclo(3.I .1)hept-2-en-6-ol,2,1,7-trimethyl-,acetate,( 1o,5o,60)-
Synonyms:none
Sottrce:Artentisia vestitaex P. Weyerstahl 56.607oDucrosia qnethifolia,PakistaniJ. Sci.
Ind. Res.22:252(1979);l.l97o Artemisiavestita;0.707o Angelicaarchangelica(root)
80
60
40
20
RT: 18.5I Al: 1261 KI: 1265 Guaiacol acetate<o->

CAS#:613-?0-7 MF: C9 H10 03 F-W: 16(r MSD LIB#: 7-56
CN: phenol,2-methoxy-,acetate
Synonyms:eucol, o-acetoxyanisole;2-methoxyphenyl acetate
Source:acetylationof o-guaiacol(625I )
302 Adarns:EssentialOil Comnonentsbv GC/MS
RT: f 8.57 Al: 1263 KI: 126(r Dec-9-en-1-ol

CAS#: 13019-22-2 MF: ClO H20 O FW: 1.56 MSD LIB#: .561
CN: 9-tlecen-1-ol
Synonyms:decylenicalcohol
Sourcc:lF'Fex.lian-QinCu, Kunming
100 120 r4 0
RT: 18..58AI: 126.1KI 1266 Ambersage

CAS#:-s3338-0.5-9 MF: Cl I H20OZ FW: l84 MSD LIB#: I 15
4,7-dihydro-2-methyl-2-(3-methylbutyl)-
CN: 1,3-dioxepin,
Synonyms:nonc
Source:
Givaudan
43
t60 180
RT: 18.62 Al: 1264 Kl 1261 Geranial

C AS#: l1l- 21- 5 MF: Cl0 H16 O F W: 1 .5 2 MSD LIB#: 992
CN: 2.6-octaclienal,3,7-dimethyl,(E)-
Svnonvms:citral a: E-citral
Source:L-emonoil, Lorann Oils: -53.607o Cymhopogon. r:ittattts,FFJ I I :289(1996);
52.55 VoELsholtzia er io st achya; M
45.00V,, e a
lis,s ffi c i nali,s
100
80
60
40
20
AppenclixIll: N4ass
Spectra 303
RT: 18.62 AI: 1264 Kl: 1261 Phenol <2-(1E)-propenyl->

CAS#: 23(t19-59-2 MF: C9 HlO O FW: 134 MSD LIB#: | 272i
C-N:phenol,2-( | lr)- I -propenyl-
Synonynrs: none
Solrlqs;AlclrichChenr.
100
80
60
40
ry:
20
t00 120
RT: 18.71 Al: 1266 KI: 1269 Ascaridol glycol <trans->

CAS#: 21413-37-0 MF-:C l0 H | 8 C)2 FW: 170 MSD LIB#: 1419i
CN: 2-cyclohcxenc-
1,4-diol,1-methyl-4-( l-methylethyl)-,( l R,4S)-
Synonyrns: p-
rnenth-2-en-1,4-cliol, l
Source:Solidagograminifiilia.ex P. Weyerstahl
RT: 18.72 AI:1266 KI: 1269 Ethyl salicylate

CAS#:ll8-(rl-6 MF:C9 HlO ()3 FW: 166 MSDLIB#: 1401|
CN: benzoicacicl,2-hydroxy-,ethyl ester ,
Synonynrs: salicylicacid,ethylester
Source:Artillcial Sassafras flavor,LorannOils; 5.507cColeusaromatictts,PakistanJ. Sci.
Res.28: l0( 198-5);l.l07o Ac&ciaprqe(:ox(llorver); 0.407oLilitutt csndiclwn(picke<lflower)
=
RT: 18.73 Al:1266 KI: 1269 Decanol<tr'>

CAS#: 112-30-1 MF: ClO H22 O FW: 158 MSD LIB#: 36
CN: l-decanol
Synonyms:capricalcohol:decylalcohol
1973);
Source:ref. cpcl.ex LawrenceHogge:9.907oMenthax gentillis,Riv. Ital. Ess.-5-5:-565(
9 .20VoOsnruntlrus.frag,r ans; 6.80%Al 1t i ti a katsunmda i (seed)
41
t00 cH3(cH2)8cH20H
80
6(
RT: | 8.74 AI 1267 Kl: 1210 Cinnamaldehyde <(E)'>

CAS#: 14371- 10- 9 M F :C 9 H 8 O F W: 1 3 2 MS D LIB #:444
CN: 2-propenal,3-phenyl-,(E)-
Synonynrs: trans-3-phcnylpropenal
Source:Plnltz & Bauerex H. Hills; CinnamonOil
100
80
60
40
20
RT: f 8.7-5 AI 1267 Kl: 1270 Thujanol acetate<iso-3'>

CAS#: 62181-90-2 MF: Cl2 H20 02 W: 196 MSD LIB#: 1484
4-rnethyl-I -( I -nrcthylethyl)-,
CN: bicyclo(3.| .0)hexan-3-ol, I a'3u'4p'-5o)-
acetate'(
Synonyms:thu.ianylacelale,3-
Source:acetylationof thuianolrrixture(642l)
',$"*^.
RT : 18. 77 A I : 1 2 6 1 K I: 1 2 7 0 Isopropyl phenylacetate

CA S #: 4861- 85 -2 M F : C l I H l 4 (o 2 F W : 178 MS D LIB #:1629
CN: isopropylphcnylacctate
Synonynrs: none
Source:Alch'ichChern.
|00
tt0
60
.10
20
100 t20
RT: l8.77 Al: 1267 Kll. 1210 Nonanoicacicl

CA S #: l 12- 0. 5 -0 MF :C 9 H l 8 C )2 F W: l -58 MS I) LIB #: | 166
CN: nonanoicacicl
Synonyrns: pelargonicacid
S<rurce'rcl'. cpd. ex E. von Rudlol'f';2.387o Sideritisarna,siaca,.TEOR 7:699(199-5);
2.0O(
/o H i bi sttr s a belmo:tchus: | .7O%A ver rl n a It il i mbi
t00
80
60
fr"'
40
20
RT: f 8.79 AI: 1268 Kl 127I Lavandulol acetate<tetrahydro->

CAS#: 40853-.5.5-2 MF: C l2 H24 02 FW: 200 MSI) LtB#: 98-5
CN: | -lrexanol,5-mcthyl-2-(I-rncthvlcthvl)-.acetatc
Synonyrrrs: 2-isopropyl--5
-rtrcthylhexylelcertate
Sourcc:rcl'.cpd. ex E. von Rudlcllf
00
A1
I
80
^
306 Adanrs:EssentialOil Cornnonentsbv GC/MS
RT: 18.80 AI: 1268 KI: 127| Decen-l-ol<(28)->

CAS#:18409-t8-2 MF: ClOH20O FW: 156 MSDLIB#:.576
(E)-
CN:2-decen-l-ol,
Synonyms:trans-2-decenol
RT: 18.82 AI 1269 KI: 1271 Furfuryl pentanoate

CAS#:36101-01-6 MF: Cl0 Hl4 03 FW: 182 MSD LIB#: 83
CN: pentanoic ester
acid,2-luranylmethyl
Synonyms: furfurylvalerate
Source:AldrichChem.
n
tl
100
,/o\,,t^t.-
")\/\/
80
\_/
60
40
20
RT: 18.83 AI 1269 Kl 1211 Perilla aldehyde

CAS#: 2l11- 75- 3 MF : C l 0 H l 4 (l FW: 150 MS D LIB #: 1264
CN: l -cyclohexene- I -carboxalclehyde, 4-( I -methylethenyl)-
Synonyms:p-mentha- 1,8-dien-7-al; perillal
Source:Perilla oil ex IFF ex R. Trenkle',93.067oPerill.a.frutescen.s,
p. 177,in: AromaticPlants& EssentialConstituents. PeaceBook Co., Hong Kong(1993);
70.747oPectisprostrata (leaf);43.407oPerilla acu.ta
100 z'
80
60 A
40
20 V
,'\
Appendix
lll: MassSpectra 30'l
RT: 18.84 Al: 1269 Kl: 1272 Tetrahydro jasmine <cis->

CAS#: 71535-28-9 MF: Cl I H20 O FW: 168 MSD LtB#: 195.5
CN: cyclopentanone,
3-nrethyl-2-pentyl-,
cis-
Synonyms:none
Source:BedoukianRes.ex .IJBrophy
t00
80
60
40
RT: 18.87 AI: 1210 Kl: 1212 Ethyl chrysanthernumate <cis->

CAS#:41641-26-3 MF':Cl2 H20 02 FlM: 196 MSD LIB#: 66-5 |
CN: cyclopropanecarboxylic
acid,2,2-dimcthyl-3-(2-methyl- esrer,(l R,3s)-
| -propcnyl)-,ethyl
Synonyms: none
r00
80
60
40
20
RT: 18.89 Al: 1270 Kl: 1273 Nonenal <dimethyt acetal-(32)->

CAS#: 68-555--53-3 MF: Cl I H2202 FW: 186 MSD LIB#: 2122
CN: 3-nonene,9,9-dimethoxy,
(Z)-
Synonyrns:none
I
308 Adarns:EssentialOil Componentsby CC/MS
RT: 18.92 A1: l21l Kl 1273 Citronellyl formate

CAS#: 105- 85- l MF: Cl 1 H2002 F ' W :1 8 4 MS D LIB #; 730
CN: (r-octen-I -ol, 3,7-dinrethyl-,lbrnrate
Synonynrs: none
Source:Gcraniuntabsolute,Firmenischex AF Tlronras 12.80%Pelargon.iumgratteolens(Australia),
Southwell,etal,Perl'.Flav. 20:I l( 1995);1239akPelargoniumgraveolens(bourbon),
41
100
80
60
40
RT: I 8.92 Al: 1211 KI: 1273 Menthyl acetate<neo'>

CAS#: 223t)-87-7 MF: C 12 H22 02 FW: l98 MSD LIB#: 1262
CN: cyclohcxanol. |
-5-methyl-2-( -methylethyl)-, I
acetatc,(o,2o,-58)-
Synonyrns:menthol,acetate,tlans-l,3,trans-1,4-
Source:acetylationoI peppermintoil (-5498);
I
80
6{)
-+0
20
o, =
O-Ac
RT: 18.99 AI 1272 Kl: 127-5 Linalool acetate<dihydro'>

CAS#: 108-597-90-6 MF: C l2 H22 02 FW: 198 MSD LIII#: | 0l6
acctate
CN: 3,7-dimethyl-6-octen-3-ol.
Synonyrns:none
Source:acetylationof dihydro-linalool(6280)
Appendixlll: Mass Spectra 309
RT: 19.00 Al: 1273 Kl: 1275 Menth-l-en-7-al <p->

CAS#:2 l39l-98-0 MF:C l0 H l6 0 FW: 1.52 MSDLIB#: 1420
CN: I -cyclohexene-
l -carboxaldehycle,
4-(l -ntethylethyl)-
Synonyrns: phclIandranal
Sonrce:Solidagogrcninfolia oil ex P. Weyerst.ahl
4l
t00
80
60
4(i
f
RT: 19.02 Al:. 1213 Kl:: 1216 Carvone oxide <trans->
CAS#: 39903-97-4 MF: Cl0 H14 02 FW: l(16 MSD LIB#: 375 ,
CN: 7-oxabicyclo(4.1 .O)heptan-2-one
, l -rncthyl-4-(
I -rretlrylerhenyl)-,(
I S-(| a;4s,6a))-
Synonynrs: | .6-epoxyisoclihydrocarvone
Sr.rurcc:
rcl'. cpd. ex H. Hills
RT: 19.04 AI: 1273 KI1276 Thujanol acetate<neo-3->

CAS#:000-00-0 MF: Cl2 H20 02 FIV: 196 MSD LIB#: t48-5
CN: not assignecl
Synonyrns:isothu.ianyl acetate.3-
Source:trcetylationof thujanolrrrixture(642| )
l0c)
80
60
40
20
RT: 19.0-5 Al:1274 Kl:1276 Isopulegylacetate<neo->

CAS#: 109010- 10- 8 MF : C t2 H 2 0 0 2 F n V :1 9 6 MS D LIB #: 883
CN: cyclohexanol, I
-5-methyl-2-( -methlyethenyl)-, ( lu,2B'-5ct)-
acetate,
Synonyrns:none
\r/'4', O-Ac
t-
RT: 19.0.5 Al: 1274 KI: 1216 PregeijereneB

CAS#: 5-56799-96-3 MF': C l2 H l8 FW: 162 MSDLIB#:17.58
1,7-dimethyl-,(lE,4E,7E)-
CN: 1.4,7-cyclodecatriene,
Synonyrns:crcct()lal.cne
Source:Jw1i.perusere(lopaten,tleaf oil, Cool & RP Adams,Phytochem.63: 105(2003)
RT: 19.0.5Al 1214 KI 1276 Thio rose oxide <cis->

CAS#:000-00-0 MF : C l O H 1 8 S FW: 170 MS D LIB #: 1478
CN: notassigned
none
Synonynrs:
ref.cpd.ex P. Weyerstahl
Source:
4l
Appendixlll: MassSpectra 3t l
RT: 19.10 Al 1275 Kl: 1277 Hexenyl angelate<(32)->

CA S #: 84060- 8 0 -0 M F : C l I H l 8 ()2 F W: 182 MS D LIB #: 1993
CN: 2-butenoicacid,2-merthyl-, (32)-3-hexenylestcr,(22)-
Synonyrrrs:cis-hexenylangelate
Source:IJedoukianRes.ex JJ llrophy
RT: 19.l0 AI: I 27.5 Kl: 1277 Isopulegylacetate

CAS#: | 09010-I 2-0 MF: C I 2 H20 02 l--W:196 MSD LIB#: 884
CN: cyclohexanol, | -nrethylcthenyl)-,
-5-methyl-2-( acetatc,( | u,2a,5B)-
Synonyrns:none
Sourcc:AlclrichCherrr.
I(
8t)
I
60 tl
'::U'/"",rto
Ac
40 :
=
20
-t\
RT : l9. l- 5 A l: 1 2 7 6 KI: 1 2 7 8 Oc ta l a c to n e< 6->

CA S #: 698- 76- 0 MF : C 8 H 1 4 0 2 F W: 142 MS D LIB #:21.50
CN: 2Hlyran-2-unc, tetrahydro-(r-1.rropyl-
S y nony m soc: t an o l i c l e
-5. -:
Sorrce:BcdoukianRcs.;0.0,{%Hedychiumt:oronaritutt, FF.I(r:217(199
l):
0.02c/r,
Ribesnigruttr
t)
l
3 t2 Adarns:EssentialOil Comnonentsbv GC/MS
RT: I9.l 8 Al: 1217 KI: 1219 Ethyl chrysanthemunate<trans->

acicl,2,2-dimcthyl-3-(2-methyl-
CN: cyclopropanecarboxylic ester,( l R,3R)-
1-propenyl)-,ethyl
Synonyms:none
RT: 19.19 Al 1277 KI:1279 Nonanal <dimethyl acetal->

CAS#: 18824-63-0 MF':C l I H24 OZ FW: 188 MSD LIB#: I 16.5
CN: nonane,l, | -dimethoxy-
Synonyms:pelargonaldehyde dimcthylacefal
/-)
100
8(
60
,l
2t) to,
RT: 19.22 Al:1218 KI: 1280 Allyl octanoate

CAS#: 4230-91-l MF: Cl I H20 02 FW: 184 MSD LIB#: I 14
CN: octanoicacid,2-propenylester
Synonyms:allyl caprylate
41
t00
80
60
40
20
Appcnclix
III: N4ass
Spcctra 3l-l
RT : 19. 2. 1 A I : 1 2 7 8 K I: 1 2 8 0 N o p o l
CA S #: 128- . 50 -7 M F :C l 1 H l 8 O F W: l 6(r MS D Ll Il #: 117-5
CN: bic:yclo(3. L l )hept-2-cnc-2-ethanol. 6.6-dirncttryl-
Synonynrs: hornomyrtenol
Sout'cc:SCM Chenrs.ex H. Hills
t00 OH
80
60 /
40
20
|0o 120
O
RT: 19.24 AI: 1278 KI: 1280 Anisylalcohol<p->
CAS#:10.5-| 3-.5 MF: C8 H l0 ()2 FW: | 38 MSD LIB#: | 7-5
CN: bcnzenemcthanol,4-rnethoxy-
S),nonynrs:
p-anisylalcohol
Soulce:AldrichClrern.
Ma-O
80 I (X)
R'I: 19.28 Al: 1279 KT: l28l Hexenyl valerate<(32)->

C A S #:358. 52-4 6 -l MF : C l l H 2 0 O2 F W : 184 MS I) LIB #: 1973
CN: pentarnoic acid,3-hcxenylester,(Z)-
Synonynrs: valcricacid,cis-3hcxc'nylester
Source:BcdoukianRes.ex.IJ Brophy
I00
tt(
60
40
20
31,+ Adanrs:llssentialOil Componentsbv GC/MS
RT: 19.30 AI 1279 Kl: l28l Ethyl acetophenone<p->

CAS#:937-30-4 MF : C 1 0 H l 2 O FW: 148 MS I) LIB #:663
CN: I -(4-ethylphenyl)-ethanone
Synonyms:p-acetylethylbenzene
Source:Aldrich Chem.;1.42(/nContpttntia peregrirra,FFJ 3:65(1988);
0.507aCyn* i d i mt sinense ( tlower); 0.017oSp art ittttt.iun ceum
t00
80
60
40
20
RT: 19.31 AI: 1280 KI: 1282 Anisyl alcohol <meta'>

CAS#: 6971- 51- 3 MF : C 8 H l O ()2 FW: 138 MS D LIB #: 174
3-methoxy-
CN: benzenenrethanol,
Synonyrns:none
100 Me-O,
u0
60
40
20
RT: 19.31 AI: 1280 KI:1282 Methyl benzylpropanoate<u->

CAS#:120-4.s-6 MF: Cf I tl14 02 FW: 178 MSDLIB#: 16.50
CN: benzenemethanol, u-rnctltyl-,pt'opanoatc
propionate
Slnonl,ms:styralylpropionate,I -phenylethyl
Y)-
r\.
\2
A pp en dixlll: Ma ssS pec t la 315
RT: 19.32 AI: 1280 Kl:1282 Neryl formate

CAS#: 2142-94-l MF: Cl I Hl8 ()2 FW: 182 MSD LIB#: I146
CN: 2,6-octadien-l -ol, 3,7-dimethyl-,formate,(Z)-
Synonyns: none
Scrurce:BedoukianRes.ex Art Tucker; |.59VoCiutts jamhhiri,
I st Intl. CitrusSyrnp.l:441(1969),U.Calif. Press,Riverside,CA;
1.007aCitnts liruon (leaf;0.757o Cymbopogotrmartini
f,\
100
60
40
20
RT: 19.32 Al: 1280 KI: 1282 Octen-3-olbutanoate<1->

CAS#: 16491-54-6 MF: Cl2 H2202 FW: 198 MSD LIB#:20-54
CN: butanoicacid. l-ethenylhexylester
Synonyrns: pcntylalylbutyrate
Source:Ilcdoukian Res.
80
60
40
142 155
140
RT: 19.34 AI: 1280 Kl: 1282 Ethyl menthone<2->

CAS#:169209-96-5 MF: Cl2 H22O FW: 182 MSD LIB#:676
CN: cyclohexanone,2-ethyl-3-rnethyl-6-(l-rnethylethyl)-,
(2R-(2a,3B,6c))-
Synonyms:none
Souroe:
P"[. s:pcl.
ex LarryCool
100.11
80
60 97 lll
40
20
3 t6 Adams: EssentialOil Componentshy CC/MS
RT: 19.34 AI: 1280 KI: 1282 Methyl nerolate

CAS#: 1862-61-9 MF: Cl I H l8 ()2 F'W: 182 MSD LIB#: 1097
acid,3,7-dimethyl-,
CN: 2,6-octadienoic methylester,(Z)-
Synonynrs:cis-geranicacid,methylestcr;rnethylneratc
Source:FinnenischChem.
t40 tfl) t80
RT: 19.3-5 AI: 1280 KI: 1282 Verbenyl acetate<cis'>

C AS#: 29135- 27- l M F : C l 2 H 1 8 t)2 F W: 1 9 4 MS D LIB #: 1549
acetate,(lR-(lo,2ll,5ct))-
CN: bicyclo(3.1.1)hept-3-en-2-o1,4,6,6-trimethyl-,
Synonyms:2-pinen-4-olacctate,( lR,4R,5R)-
Source:acetylationof verbenols(5-531)
43
.,1fr......\\o.Ac
Y
RT: 19.38 AI: 128| KI: 1283 Thujanol acetate<neoiso-3'>
C AS#:62181- 91- 3 MF : C l 2 H 2 0 OZ F W : 1 9 6 MS D Ll l l #: 1486
acetate'
C N:bic y c lo( 3. 1. 0) h e x a n -3 -o 1 .4 -m e th y l -l -(l -m e thyl ethyl )-, (1u' 3p' 4p' 5u)-
Synonyms:neothujanylacetate,3-
Source:acetylationol thuianolmixture(6421 )
t00
I o"
'ro,,',/\/o
V :
=
12t) 140 160 180

RT: 19.40 Al: 1282 KI: 1283 Ethyl 2-octynoate

CAS#: 10519-20-7 Mt-: Cl0 Hl6 02 FW: 168 MSD LIB#: 681
CN; 2<rctynoicacid, ethyl estcr
Synonyms:ethyl heptynecarbonate
67
RT: 19.40 A1 1282 KI: 1283 Hexenylvalerate<(22)->

CAS#:56922-78-2 MF: Cl 1 H20 02 FW: 184 MSD LIB#; 1934
CN: pentanoic
acid,2-hexcnylester,(Z)-2-hexenyl
valerate
Synonynrs
: pentanoicacicl,2Z-hexenyl
ester
Source:BedoukianRes,ex J.lBrophy
RT: 19.42 AI 1282 KI: 1284 Necrodol acetate<trans-u->

CAS#: 1.560-53-83-7MF: Cl2 H20 02 FW: 196 MSD LIB#: 209-5
CN: 2-cyclopentene-l-methanol, acetate,(lR-trans)-
3,4,5,-5-tetramethyl-,
Synonyms:none
Source:La,,,andulaluisieri. ex Nicolas Baldovini
t2l
.nntttt\o-A.
Adams: EssentialOil Cornponentsby GC/MS
3 t8
RT: 19. 43 A l 1282 K I:1 2 8 4 A n e th o l e < (E )->

C AS#: 4180- 23- 8M F :C l 0 H l 2 O F l i l :l 4 3 MS D L l B#:170
CN: methoxy-4-(I -propenyl)bcnzene<1 ->, (t1)-
Synonynts:trans-4-(1-propenyl)anisolc; trans-p-methoxy-B-nrcthylsty'enc
Source:Star Anis oil ex Brian Lawrence;98.20%Clausenqltepaphyllaleaf ,
RivistaItal .56:683( 1974);96.1O7oPintpinellaanisunr(Spain);
94.73ahP i nrpin ella anisunt(Turkcy)
RT: 19.4-5 AI: 1283 KI: 128-5 Isopulegylacetate<iso->

CAS#: 1090t 0- ll- 9 MF : C l 2 H 2 0 0 2 F ' W: l 9 (r MS D LIU #: 88-5
CN: cyclohexanol, I -mcthylelhenyl)-, ( 1o'2ll'50)-
acetate,
-5-methyl-2-(
Synonyms:none
Sourcc:Aldrich Chem'
A
Xr^"
RT: 19.46 AI: 1283 KI: 1285 Terpinen-7'al <u'>
CAS#:1197-15--5MF:ClOH14OFW:I50MSDLIB#;1339
1-carboxaldehyde,
CN: I ,3-cyclohexadiene- 4-(I -rrrethylethyl)-
Synonyms: p-rnentha-1,3-dien-7-al
Scrurce: oil ex 'T'ICSchel'fer
Poll'lophiuminvolucrcttwn
{
AppendixIII: MassSpectra 3t 9
RT: 19.48 AI: 128.1 KI: 128.5 Cogeijerene

CA S #: 5988- 83-0 MF : C l 2 H l 8 F W: 162 MSD LIB#: 1832 ,
i
CN: naplrthalene,2,3,4,4a.5,6Jrexahydro-l,4a-dinrethyl-
Synonynrs:none
Source:ref. cpd. ex Ian Southwell
RT: 19.48 AI: 1283 KI: 1285 Isobornyl acetate

CAS#: 125-12-2 MF: Cl2 H20 02 FW: 196 MSD LIB#: 8.56
CN: bicycfo(2.2. I )heptan-2-ol,1,7,1-trirnethyl-,acetate,exo-
Synonyms:isoborneolacetate
Source:ref'.cpd. ex Brian Lawrence; l8.8o7oCurcumapierreana, JEOR 7:
1 | .40VoInula viscosa:3.397oSalvia officinalis
r00 =
^\
80
-
> (\tt II
60 Y.-
40
20
RT: 19.-5
I AI: 1284 KI: I 286 Undecanol<6->
CAS#: 23708-56-7 MF: Cll H24 O FW: 172 MSD LIB#: 1996
CN:6-undecanol
Synonyms:diamyl carbinol
Source:Tokyo Kasai ex J.TBrophy
80
60
40
20
320 by GC/MS
RT: 19.-52AI 1284 KI: 128(r Undecanol<5->

CAS#:31493-10-z MF: Cf I H24 O FW: 172 MSD LIB#: 2000
CN: 5-undecanol
Synonyms:none
Source:Tokyo Kasai ex J.IBrophy
RT: l9.-53 AI: 128-5 KI: 1286 Cyclopentadienecarboxylic acid <3,4,5,5-tetrametlryl-1,3->

CAS#:000-00-0 MF: Cl0 Hl4 02 FW: 166 MSD LIIJ#:2093
f frl; qyclopentadiene - 1,3->
carboxylic acid, <3,4,-5,-5-tetramethyl
Synonyms:none
Source:Lat,andulaluisierioil ex NicolasBaldovini
ff".
RT: 19.-56 Al: 128.5 Kl:1281 Safrole
CAS#:94-59-7 MF':Cl0 Hl0 ()2 FW: 162 MSDLIB#:917
CN: benzodioxole<-5-(2-propenyl)- I .3->
Synonyms:shikirnol; rhyunooil: allylcatechol ether,4-allyl-1.2-Methylenedioxybenzene;
rnethylene
Allydioxybenzene MethyleneEther;m-Allylpyrocatechin Methylenelither
Source:Jtm.ipems angosturanleai oil, RP Adams#2665;91.667oCinnamomumnilcrantlunn,
p. 29, in: AronraticPlants& Constituents, PeaceBook Co., Hong Kong(1993);
92.907oSassafrasalhi.dum;90.30% Cinrmmomumparthenoxylon
100
80
€
RT: 19.57 AI: l28-5 KI: 1287 Pregeijerene

CAS#: 20082-11-l MF: C12Hl8 FW: 162 MS D LIB #: l 5l
CN ; 1,3.7-cycIodecatriene, 1,7-climcthyl-, (Z,E.E)-
Synonynts:none
S<rttrce:Ainyrisdiatnta oil, Dom. Rep. ex Tom Zanoni: 12.907aWiedennnniaori.entalis,
JEOR 8 :543(1996): l 2.7\Vo P irrrpi n ella anisunt; 12.30%,Skinunia l aureola
8t)
60
40
20
RT: 19.6) AI: 1286 KI: 1288 Hydroxycitronellal

CAS#:101-15-5 Ml.: Cl0 H20(r2 hW: 172 MSD LIB#: 824
CN: octanal,
7-hydroxy-3.7-cli
nrethyl-
Synonyrns:
lilyl alclehyele
; lixol;cyclalia; phixia
cyclosia;
S<rurce:
ref.cpd.ex BrianLawrence ; 0.12(kAmonrum FFJ ll j(1996)
subulaturr.
RT: 19.60 AI: 1286 KI: 1288 Undecan-4-ol

CAS#:4272-06-4 MF: Cl I H24 O FW: 172 MSD LIII#: 2013
CN:4-unclccanol
Synonynrs:
none
Sclurcc:
Toky<lKasaiex .lJ Brophy
122 Adams: EssentialOil Comoonentsbv GC/lr'lS
RT: 19.62 Al: 1287 KI: 1288 Bornyl acetate

CAS#: 76-49-3 MF': Cl2 H20 02 FW: 196 MSD LIB#: 314
2.1)heptan-2-ol
CN: trirnethylhicyclo(2. <1,7,7-> acetate
Synonyms:none
Source:Aldrich Chenr.ex T, Phillips,Juni.perusleaf oils; 16.00%Abies.fragesii,
p. 4, in: AromaticPlantsand llssentialConstituents,PeaceBook Co., Hong Kong(1993);
66.57VoAmotttutrtvillosumi 59.00%Juniperus rigida
100
80
RT: 19.62 AI: 1287 KI: 1288 Fenchol<2-ethyl'endo->

CAS#: 137255-07-3 MF: CI2 H22 O FW: 182 MSD LIB#: 7l-5
(
1,3,3-trinethyl-,
2-ethyl-
CN: bicyclo(2.2.I )heptan-2-ol, 1R-endo)-
Synonyms:none
Sonrce:BedoukianRes.ex Art Tucker
RT: f 9.64 AI: 1281 KI: 1288 Hexenyl valerate <(28)'>

CAS#: 56922-74-8 MF: Cll H20 02 F'W: 184 MSD LIB#: 1933
CN: pentanoicacid,2-hexenylester,(2F,)-
Synonyms:pentanoicacid, 2ll-hexenylester
t00
80
60
40
20
RT: | 9.64 Al: 1287 KI: 1288 Linalool oxideacetate<trans->(pyranoi{;

CAS#:56752-50-2 MF: C12H20()3 FW:212 MSD LIB#: 2-51 |
CN: 2H-pyran-3-ol,
6-ethenyltetlahydro-2,2,6-trimethyl-,acetate,
trans- :
Synonyms:none
Source:Artemisia vestitaoil ex P. Weyerstahl
-r"N\
^c-o/-\,)
r3 6
RT: 19.64 Al:1287 KI: 1288 Pearlate

CAS#:94134-03-9 MF: Cl 1H20OZ FW: 184 MSD LIB#: 20.53
CN: 3-octen-
I -ol, propano
ate,(32)-
Synonyms:none
RT: 19.67 AI: 1288 KI: 1289 Limonen-l0-ol

CAS#: 3269-90-l MF: ClO Hl6 O FW: l-52 MSD LIB#: 100-5
CN: 3-cyclohexene-1-ethanol, 4-methyl-B-methylene-
Synonyrns:p-mentha-I ,8( l0)-dien-9-ol
100
80
40
20
324 Adams:EssentialOil Componentshy GC/MS
RT: f 9.68 AI: l288 KI: 1289 Tetradecatriene<(32,,62,92)->

C IAS#:I 34896- 10- 9 M F ; C l 4 H 2 4 F W: 1 9 2 MS D LIB #: 1908
(2,2,7)-
CN: 3,6,9-tetradecatriene,
Synonyms:none
Source:Lontatiwn rigidum oil ex VasrrDev
100
80
60
40
20
100 160 180
<2'pentyl'>
RT: 19.69 AI: 1288 Kt: 1289 Cyclopent-2-en-1-one
CAS#:25564-22-l MF:ClOHl6 o F'W:152 MSDLIB#:537
-one,2-pentyl-
CN: 2-cyclopenten-l
none
Synonynrs:
100
80
60
40
20
t00 140 160
RT: l9. 70 A I : 1288 K I: 1 2 9 0 L a v a n d u l y la c e tate

CAS#: 20711-39-3 MF: C 12 H20 02 FW: 196 MSD LIII#: l 1.5l
CN: 4-hexen-I -ol, 5-methyl-2-( l -nrcthylethenyl)-, acetate
Synonyms:Iavandulylacetate
Source:Nidorella resediftiliaex P. Weyerstahl:29.287oLet,andulaangustiJitlia(Graves),
Perf.& Frag.9:49(1984);2-5.-5 l%, Lav'andulaangustifulio(Locldonpink);
21.5|VoLct,,,andula angustiJb|ia (.IeanI)avis)
t
43
T
325
RT: 19.73 AI: 1289 KI: 1290 Sabinylacetate<trans->(IPP vs.Acetyt)

CAS#:-53833-8.5--5MF: C | 2 H | 8 02 FrM:194 MSD LIB#: 1368
CN: bicyclo(3.1.O)hexan-3-ol,4-methylene-
I -( I -methylethyl)-,
acetate,(
I S-(I 3p,.5a))-
Synonyms:cis-sabinylacetate(IPP vs. Me gp., traditionalname)
Souroe:ref. cpd. ex E. von Rudloff
r00
80
b(,
40
20
RT: 19.74 AI: 1289 KI: 1290 Butyl heptanoate

CAS#:5454-28-4 MF: Cl I H2202 FW: 186 MSD LIB#: 329
CN: heptanoic
acid,butylester
Synonyms:none
RT: 19.74 AI: 1289 Kl: 1290 Cymen-7-ol<p->

CAS#:. 536- 60- 7 MF: Cl0 H14 O F W: l -5 0 MSD LIB#: 546
CN: benzenemethanol, 4-( I -methylethyl)-
Synonyms:cumin alcohol,curninol
Source:ref. cpd.ex E. von Rudloli
OH
o
(
A
RT: 19. 76 A I : 1290 K I: 1 2 9 1 A c e ta n i s o l e< o ->
CAS#: 579-14-8 MF: C9 H10 ()2 FW: 150 MSD LIts#: 7
CN: o-rnethoxyacetophenone
Synonyms:
Source:Aldrich
RT: 19.76 AI: 1290 KI: 1291 Indole

CAS#:120-72-9 MF: C8 H7 N FW: l 17 MSD LIB#: 840
CN: 1H-indole
Synonyms:| -araindene:| -benzazole; ketole;2.3-henzopyrrole
Source:MCB Chern.ex H. Hills; 25.617oOen.otltera odorata,
p.46, in: AromaticPlants& ltssentialConstituents, PealceBook Co., Hong Kong(1993);
19.307oLill i um candidutn: 17 .507oCo roni l la.eme nts
AppcndixIll: MassSpcctra -11 I
R T : 19. 76 A l: 1 2 9 0 K I: l 2 9 l T e rp i n e n -7 -al< y->

C A S #: 22. 580- 9 0 -l MF : C l 0 H 1 4 O F ' W: 1.50 MS I)LtB #: 1340
CN: 1.4-cyclohcxadien-|-ctrrboxaldchydc,,l-( I-nrethylcthyl)-
Synonyrns:I.4-p-nrenthadien-7-al
Source:Prtlylopliwn irtvolucratumoil ex JCC Schellbr
Q
RT : 19. 77 A l: 1 2 9 0 KI: l 2 9 l T ri d e c e n e< l ->
CA S #: 2437- 56 -l M F -:C l 3 H 2 6 F W: 182 MS I) l -l B #: 899
CN: l-triclcccnc
Synonyrns: nonc
S<rurce: r'el'.cpcl.cx Il. von RLrcllol'l': 2.00%Pectiselongata,JITOR7:63(199-5);
0.80(ft Vitis 't'ittifera(llower)
. . . . 4l
HrC=CH(CHz)
r ocHs
RT : 19. 83 A l l 2 9 l K l : 1 2 9 2 V e rb e n y la cetate< trans->

CA S #: 1203- 2l-0 N 4 FC : l 2 H l 8 ()2 l ,W : l 94 MS D LIB #: t-548
CN: bic y c l6ll. I . 1)h e p t-3 -e n -2 -o4l.6
. .(r-tl i rn c t hyl -.
acctatcr.(
| a,2o.-5u)-
Synonynrs: 2-pincn-4-olacelatc.trans-
Srrtrrcc:
acctylationol'vcrhenols(55.1 l) 0.9()%Junipent.s rnaftine:.ii.
JIIOR 2:99(1990);
0.461, A rtg,eI i ca o rcltong cI i ca: 0. | 0%:Achi I Iett v,i Ilt eImsi i
|{x)
ft0
60
40
2( 59 65
fi)
I
j
328 Adants:EssentialOil Componentshy CC/MS I
RT: 19.84 Al 1292 KI:1292 Prenyl hexanoate

CAS#: 76649-22-4 MF: Cl I H20 OZ FW: l84 MSD LIB#; 20.51
ester
CN: hexanoicacid.3-methvl-2-hutenvl
Synonyms:none
martini, I I th Int. Cong.of Ess.Oils, 3:89(1989),
Strurce:BedoukianRes.;0.20% Cl,ntboltogort
New Delhi, India
68
4(
2(
128 t42
140 200
RT: 19.8-5 AI: 1292 KI: 1293 Cyclohexanol acetate <cis-2-tert-butyl->

CAS#: 20298-69-5 MF: Cl2 H22 02 FW: 198 MSD LIB#: .541
CN: cyclohexanol, 2-(1,| acetate,
-climethylethyl)-, cis-
Synonyms:none
Source:rel'.cpd. ex Art Tucker
t0 0
80
f'0
40
20
RT: f 9.86 Al:1292 Kl 1293 Decadienal <QE,4Z)->

CAS#: 25152-83-4 MF: C l0 H l6 O FW: 1.52 MSD LIB#: -563
CN: 2,4-dccadienal, (E,Z)-
Synonyms:2-trans,4-cis-decadienal
Source:ref. cpd. ex Art Tucker; 1.327oNicotianafitrgetiana (llower), .lIrOR 1:265(1995);
1,007oRhuscoria.riai0.40%,Hibiscus abelmoscha^s(seed)
100
80
60
40
20
AppendixllI: MassSpectra 329
RT: 19.90 AI 1293 Kl:1294 Undecanone<2-> j

CA S #; ll2- 12- 9 MF ' ;C l I H 2 2 O F W: 170 MS D LIB #: l -525
CN: 2-undecanone
Synonyms:2-henclecanone
Source:ref. cpcl.ex Art Tucker:90.427o Ruta graveolens,p.255,in: EssentialtOil
Analysis Capillary Gas Chromatography& Carbon-l3 NMR Spectroscopy,
J. Wifey & SonsPubl.,Chichester(1982);6.90VoPistacialenticus(tiuit); 4.80VoJunilterusrigida
cHJC(=oxcH2)8cHJ
RT: 19.92 AI: 1293 KI:1294 Isonrenthone<2-ethyl->

CAS#: 000-00-0 MF: Cl2 H22O trW: 182 MSD LIB#: .50-5
CN: not assigned
Synonyms:none
Source:Cupressusbakeri oil fraction ex Larry Cool
,, 41
RT: 19.92 AI: 1293 Kl 1294 Methyl myrtenate

CAS#:30649-97-9 MF: Cl I Hl6 ()2 FW: 180 MSD LIB#: 1666
CN: bicylco(3.1
.1)hept-2-ene-2-carboxylicacid,6,6-dimethyl-,
merhylesrer
Synonyms: myrtenicacidnrethylester
Source:Dar\viniacitriodoraoil ex Ian Southwell
o
\l l
+,.T\il.'\o,"
<)
-330 Adams: EssentialOil Componentsby GC/MS
RT: 19.92 Al:1293 Kl: 1293 Undecanol <3->

CAS#:6929-08-4 MF':Cl I H24 O FW: 172 MSD LIll#: 2004
CN: 3-unclecanol
Synonyms: none
Source: TokyoKasaiex.lJBrophy;0.947o 8:413(1996);
Rutachalepensis,.IEOR
g g (
0.5| % F i ssiti mashan tz,eensellowerextract)
6(
RT: 19.93 Al:1294 KI 1294 Camphorquinone

CAS#: 10373- 78- 1 M F ' :C l 0 H l 4 (o 2 FW: 166 MSD LIB#: 1994
CN: bicyclo(2.2.l )heptane-2,3-dione, 1,7,7-trimethyl-
Synonynrs:none
Source:Aldrich Chem.ex.I.TBrophy
M
100 120 140
RT: 19.93 AI: 1,294 KI: 129-5 Menthyl acetate

CAS#: 89-48-.5 MF: Cll2 H22 02 FTV:198 MSD LIB#: l08l
CN: rnenthyl-2-( acetate
I -methylethyl)cyclohexanol<-5->
Synonyms:menthol,acetate, | ,4-
cis-| ,3,trans-
Source:SCM Chem.ex H. Hills
A
\Aoo.
:
Appendix
llI: MassSpectra 331
RT: 19.94 AI: 1294 KI: 129.5 Perilla alcohol

CAS#: 536-59-4 MF: C10 H16 O FW: 1.52 MSD LIB#: 1265
CN: | -cyclohcxcne-| -methanol,4-(l -nrethylethcnyl)-
Synonyms:p-rnentha- 1,8-dien-7-ol
Source:Perilla oil ex IFF'ex R. Trenkle
OH
O
A
RT: 19.94 AI:1294 KI: 129-5 Phenyl ethane<1-nitro-2->
C A S #:6125- 24 -2 MF : C 8 H 9 N 0 2 F W : l .5l MS D LIII#: l 160
CN: bcnzcne,(2-nitroethyl)-
Synonyms:none
Sotrrce:An.i.biacanellial oil cx P. Richomnte
a T
o
RT: | 9.9-5 Al: 1294 K[ 1295 Thio roseoxide<trans->
CAS#:000-00-0 MF: ClO Hl8 S FW: 170 MSD LIB#: 1479
CN: not assigned
Synonyrns: none
Source:ref'.cpd.ex P. Weyerstahl
100
80
60
40
20
l
-)-)I Adams: EssentialOil Componentsbv GC/MS
RT: 19.96 AI: 1294 KI: 129.5 Menth-l-en-9-ol <p->

C AS#: 18479- 68- 0 MF : C l 0 H l 8 O FW: 154 MS D LIB #: 1061
CN: 3-cyclohexene- I -etlrernol.
B.4-dimethyl-
Synonynrs: none
Strurce:ref'.g:pd.ex E. von Rucllol'1':
O.0l7oCitrus l:tergomia,
Seifen-Oele-Fette-Wachse l07:363(l98l ): 0.0l % Citus deliciosa
f".
RT: 19.98 AI: 129.5 KI: | 295 l\{ethyl octine carbonate
C AS#: I I l- 80- 8 MF : C l O H 1 6 O Z F W; 1 6 8 MS D LIB #: 2152
CN: 2-nonynoicacid,methylester
Synonynrs: none
100 (cH2)5'cH3
80
60
40
20
RT: 19.98 Al 1295 KI: l295 Thujanol acetate<3->

C AS#:12747- 24- l MF: Cl2H20 02 F IM: 1 9 6 MS D LIB #: 1487
acetate,(l
C N:bic y c l< . r ( 3. 1. O )h e x a n -3 -o 1 ,4 -m e th y l -l -(l - methyl ethyl )-, s,3s,4s,5s)-
Synonyms:neoisothuianyl acetate,3-
Source:acetylationof thu.lanol mixture(6421 )
100 =
:
"'Z..,rt\..n$t"
80
NI
t\ |
60 L\ )
40 :
:
:
20 /\_/\
AppendixIl[: MassSpectra
-1-fJ
RT: 20.05 AI:1296 Kl 1297 Nonadienol acetate <(38,62\->

CAS#: 211323-05-6 MF': Cl 1 Hl8 ()2 F'W: 182 MSD LIB#: 2134
CN: 3,6-nonadien-1
-ol, acetate,(3li.(rZ)-
Synonyms:none
RT: 20.08 AI: 1297 Kl: 1297 Fenchol<2-ethyl-exo->

CAS#:13'7255-11-9 MF: Cl2 H22O FW: 182 MSDLIB#:7t4
CN: bicyclo(2.2.1)heptan-2-ol,
2 -ethyl-1,3,3-rrimethyl
-, ( l R-exo)-
Synonyms: none
Source:Bedoukian Res.ex Art Tucker
t00
80
60
40
20
RT: 20.09 AI: 1297 KI: 1297 Benzyl isobutanoate

C A S #: 103- 28-6 MF : C l I H l 4 0 2 F W : 178 MS D LIB #: 291
CN: propanoicacid,2-nrethyl-,phcnylmcthylcster
Synonynrs: benzylisohutyrate
Source:Aldrich Chent.
o
tl
80 /'\a"\
60
4(:)
ur
tn
334 Adams:EssentialOil Componentsbv GC/MS
RT: 20.10 Al:1297 KI: 1298 Carvacrol, ethyl ether

CAS#: 4732- 13- 2 MF: C12Hl8 O F W: 1 7 8 MS D LIB #: 366
| -methylethyl)-
CN: benzene,2-ethoxy-l-nrethyl-4-(
Synonyms:carvacrylethyl ether;phenetrole.-5-isopropyl-2-methyl-
Source;ref. cpd. ex Art Tucker
t00
8t)
60
40
20
fov'//
RT: 20.1I AI: 1298 KI: 1298 Acetophenone <3'-methoxy'>
CAS#:586-37-8 MF: C9 HlO 02 F W : 1 .5 0 MS D LIB #: I I
CN: ethanone,I -(3-methoxyphenyl)-
Synclnyms: meta-
acetanisole,
q"-
RT: 20.I I AI: 1298 KI: 1298 Azulene
CAS#:215-51-4 MF:ClOH8 FW; 128 MSDLIB#:262
CN: cyclopentacycloheptene
Synonyms:none
Source:Alclrich Chem.ex H. Hills; 2.J57oDendrobiumchrl'sato-turu(tlower),
p. 1I I , in: AromaticPlants& EssentialConstituents, PeaceBook Co., Hong Kong(1993);
0.917oArt emisia macrocep hala; 0.457oM i cheI i a y wtnne sis (llower)
AppcndixIll: MassSpectla 33-5
RT: 20.I l AI: 1298 KI: 1298 Geranyl formate

CA S #: 10. 5- 86 -2 MF ' :C l l H l S 0 2 F W : 182 MSDLIB#:732
CN: 2,6-octadicn- | -ol. 3.7-clinrethyl-, (H)-
frrrnrate,
Synonynrs:gcrarriollirrmate
Scrrrrce:Filnrenischex AF Thonras:9.65a/c, Pelargoniwngraveolens,.f
ltOR 2:73(1990);
5 .00a/aCv nbop og on ntartini; 4.207oCynrbotrtog on nard us
f""
RT: 20.I I AI; 1298 Kl: | 298 Pinocarvyl acetate<trans->
CA S #: l6t t 6- 1.5 -3 M F :C l 2 H 1 8 .o 2 F W :194 MS D LIB #: l 3l l
CN: bicyclo(3.I .1)heptan-3-ol, 6,6-dirnetlryl-2-nrethylene-,
ircetare,(
1a,3u,-5u)-
Synonynrs: 21I O)-pinen-3-ol, acetate.trans-
S<rurce: re[. cpd.cx E. von RucllolT;49.007oE,qletes tiscosa...IEOR4:639(| 992):
| .00% Euca I1,p tus bot ryo i d e,s'.
0.24VaA co nrs cal antus
RT : 20. l2 A I : 1 2 9 8 K t: 1 2 9 8 C a rq u e j o la cetate
CA S #:3215l- 09 -0 MF: C l2 H l6 02 trW : 192 MS I) LIB #: I 290
CN: 2-cyclohexen- | -ol, -5-rrrethylene-6-(l -mcthylcthenyl)-,
acctate.(I S-cis)-
Synonynrs: o-mentha-l(7).4.8-trien-3-ol. acetate(2R,3S)-
Scrtrrcc:Plutebeoil ex P. Weyerstahl;42.82%,Bat:clmrisporosa, FFJ 9:119(.1994);
2.107oPhoe.be Dorosa
l0t) 120 140 | (r0 180

RT: 20.l3 AI: 1298 KI: 1298 Octenol propanoate<(52)->

C AS#: 196109- 18-9 M F :C 1 l H 2 0 (o 2 FW: 184 MS D LIl l #: 2056
l-ol, propanoare,
CN: -5-octen- (52)-
Synonyms:none
100
82 fl
%
fJ0
60
40
20
R T: 2 0. 14 A I : 1298 KI: 1 2 9 9 C a rv a c ro l
CAS#:499-15-2 MF:Cl0 Hl4 O FIV: 1.50 MSDLIB#: 1.507
CN: 2-methyl--5-( phenol
I -rnethylethyl)
Synonyms:p-cymen-2-ol;antioxine,isothymol;2-hydroxy-p-cymene, isopropyl-o-cresol
Strurce:distilled f}om Thynte leaves,RP Adams #5426 ex Schilling; Oreganum;Marjorant;
86.337oCo r idothynrus capi tatus,.lllOR 4 :4 17(1992); 1 8.857oM aj o rana hortensis;
1 1.407oThymbra spicata
f."
100
80
60
40
20
100 t20 t40
RT: 20.17 AI:1299 Kl 1299 Terpinen-4-olacetate

CAS#: 4821-04-9 MF: Cl2 H20 02 FW: 196 MSD LIB#: 1.560
l -ol, 4-nrcthyl-l-( | -melhylcthyl)-,acetate
CN: 3-cyclohexen-
Synonyms:p-nrentlr-| -en-4-olacetate
lusitanicaoil, Portugal,RP Adams#7123
Source:Cupre,ssus
43 .r 1
AppcndixIll: MassSpectra 33'7
RT: 20.18 AI: 1299 KI: 1299 Methyl cinnanrate<(Z)->

CA S #: 1971. \ -1 3 -6 MF : C l 0 H l 0 O2 F W: 162 MS D LIB #: 266
CN: 2lroperroic acid,3-phenyl-,nrethylester,(Z)-
Syn<lnyr.ns: cis-cinnanricacid,mcthylesterr
Soulcc:distillationol'basilleavesex McCormickCo., RP Adams#-543-5:
9.40o/r:Ot'itnumbasil.it:ttnt,
l Fl l :-53(198(r);0.78%,Ocimuntbasilicum(CO2-extract);
0.4| a/oArtemisia.judaica
40 60 80 t00 r20 140
RT: 20.| 8 Al 1299 KI: l299 Necrodol acetate <cis-cr->

CAS#: 70X)26-15-3 MF: C I 2 H20 02 FW: l96 MSD LIB#: 2097
CN: 2-cyclopcntene- 1-methanol,3,4.-5,-5-tetrantethyl-,
acetate,cis-
Synonynrs: none
Sorrrce:Lovardula luisieri.cx NicolasIlaldovini
.*..ttt\o_o.
RT: 20.18 Al: 1299 KI: 1299 Undec-l0-en-l-al

CA S #: I 12- 4. 5 -8 MF : C l I H 2 0 O F W: 168 MS D LIB #: 1519
CIN:10-Lrndecenal
Synonyrns: none
Sourc,e: Givaudanex .Iian-QinCu, Kunrningl'0.10a/o
Coriandrmnsativum,
.I. Ag. FooclChern.38:20.54(1990)
HrC=CH-(CH2)s-CHO
:
j
338 Adams: lissentialOil Comrronentsbv GC/MS l
i
RT: 20.19 AI: 1300 KI: 1300 Tridecane<n->

CAS#: 629-.50-.5 MF: C 13 H28 FW: 184 MSD LIB#: 93
CN: tlidecane
Synonynrs:none
Source:AflteclrAssoc.;0.7}VoBrassica.juncea(flower),Nippon NogeikagakuKaishi54:99(1980);
050% Hypetit:tun perforatum;0.50(/c
Brassicajwrcea (leavcs& stem)
1cHs
cHs(cH2)1
60
40
20
<(8ZJ->
RT: 20.20 AI: 1300 KI: 1300 Undecenal
CAS#:147159-49-7MF: Cl I H20O FW: 168 MSD LIB#: 2133
(82)-
CN: 8-undecenal,
Synonyms:none
t00
80
60
40
20
P.T: 20.22 AI: 1300 KI: l300 Terpinyl acetate<trans-dihyclro-o->

CAS#: 20177-41-7 MF: C 12 H22 02 FW: | 98 MSD LIli#: I 468
CN: cyclohexanemethanol, acetate,
o,u,4-trimcthyl-, trans-
Synonyms:p-menthan-8-ol acetate,trans-
Source:acetylationof cis-dihydlo-o-terpineol(6269)
t80 200
Appcndix lll: MassSpectra 339
P'T: 20.26 AI: 1301 KI: 1301 Undecanol<2->

CA S #: 16- 53- 30 -l MF : C l l H 2 4 O F W 172 MS D LIB #: 1818
CN: 2-undecanol
Synonyms:sec-undecylalcohol
Source:alcoholsmix (2-OHs) ex K-H Kubeczka;0.807oRuta graveolens,
Sci. Pharnr.56: I 2 I ( 1988); O.5l7o Rosarugosa;0.3O7oCurcwna aerLtginosa
(cH2)8-cH3
RT: 20.29 AI: 1302 KI: 1302 Elsholtziaketone<p-dehydro->

CAS#:6138-88-l MF: Cl0 Hl2(.J2 FW: 164 MSD LIB#: 6-56
CN; 2-buten-
I -one,3-methyl-1-(3-rnethyl-2-f
uranyl)-
Synonyms: naginataketone:elsholtzione,
dehydro-
Sc'rurce:
Elsholtzi.a
cristataex O. Vostrowskv.PlantaMed.3:268(1987)
100
80
60
40
20
RT: 20.29 Al: 1302 KI: 1302 Vanillin <o->

CAS#:148--53-8 MF: C8 H8 ()3 F'W:l-52 MSDLIB#: I193
CN: benzaldehyde,2-hydroxy-3-rnethoxy-
Syrronyms:rn-anisaldehyde,
2-hydroxy-;6-formylguaiacol
Source:Plaltz& IJauerex H Hills
r00
80
60
40
20
g
I
RT: 20.36 AI: 1303 Kl: | 304 Cinnamyl alcohol <(E)->
CAS#: 4401-36-7 MF: C9 HlO O FW: 134 MSD LIB#:449
CN: 2-propen-l-ol, 3-phenyl-,(H)-
Synonyrns:trans-cinnamylalcohol
Source:Aldrich Chem.ex H. Hills
RT: 20.-16 AI: 1303 KI: 1304 Nonadienolacetate<(28,62)->

CAS#: 68.55.5-6.5-7 MF: C | | H l8 02 FW: 182 MSD LIB#:2127
CN: 2,6-nonadien-I -ol,acetate(B,Z)-
Synonynrs:none
RT:20.39 AI: 1304 Kl: 1305 Menthyl acetate<iso->

C AS#: 20177- 45- l MF : C l 2 l l 2 2 0 2 F W: 1 9 8 MS D LIB #: 1263
CN: cyclohexanol,-5-methyl-2-(I -methylethyl)-, I
acetate,( o,2B,-5B)-
Synonyrns:none
Source:Acetylationo1'pepperrnintoi| (-5498)
=
:
i
^ ^-
-/\-/"-^"
tl
tl
tl
i
RT: 20.40 AI: 1304 KI: 130-5 Butanoicacid,2-methyl-4-methylhexyl

CAS#:850309-46-5 MF: Cl2 H2402 IiW: 200 MSD LIB#: 2163
CN: butanoicacid,2-methyl,4-methylhexylester
Synonyms:none
Source:Lomatiumdissectumroot oil ex VasuDev
RT:20.42 AI: 1305 KI: 1305 Cresylisobutyrate<p->

CAS#:103-93--5 MF: Cl l Hl4 02 FW: 178 MSD LIB#: 2l8l
CN: propanoicacid,2-nrethyl-,
4-methylphenyl
ester
Synonyms: p-;
tolyl isobutyrate,
a,
I
100 I
I
80
60
40
20 178
180
RT: 20.4.5 AI: 1305 KI: 1306 Undecanal

CAS#: ll2-44-7 MF: Cl I H22 O FW: 170 MSD LIB#: 1-523
CN: undecanal
Synonyms:hendecanal
Source:Aldrich Chem. ex Art Tucker.:5.007oMachilus bombycina,JEOR 7:1 199-5);
3.047oCoriandrum sativumt2.087oNarcisslrstazettet
. ^^ 4l
cH3(cH2)ecHo
_
a
342 Adarns:EssentialOil Componentsby GC/l\4S
RT: 20.48 AI: 1306 KI: 1307 Dihydro carveol acetate<neo'>

CN: cyclohexanol,2-methyl--5-(l-rnethylethenyl)-,acetate,( I R-( I o,2u,-5B))-
Synonyms:none
Source:rel'.cpd.,E von Rudlolf
=
-A-.."
RT: 20.48 Al: 1306 KI: 1307 Dihydro carveol acetate

CAS#: 7.5684-65-0 MF: Cl2H20 02 FW: 196 MSD LIB#: 597
CN: cyclohexanol,2-methyl-5-(1-rnethylethcnyl)-,acetate,(| 4,2B,-54)-
Synonyrns:dihyclrocarvylacetate
Source:ref. cpd. ex E. volt Rudloff
100 =
80
tl
60
40
t-
20 ,/\
RT: 20.49 AI: l306 KI: l307 Nonenol acetate<(2E)->

CAS#: 30418-89-4 MF: C I I H20 02 FW: l84 MSD LIB#: 2083
(28)'
CN: 2-nonen-l-ol,acetate,
Synonyms:none
A"O
RT: 20.-5ft AI: 1308 Kl; 1309 Verbanol acetate<iso->

CA S #: 13366- ll -1 M F :C l 2 H 2 0 0 2 F W: 196 MS D LIB #: l -541
CN: hicycfo(.j.I . l)heptan-2-ol, 4,6,6-trirncthyl-,
accrrate,(
1u.2a,4fi,5a)-
Synorryrns:none
Soulce:acelylationof verbanols(63 | 4)
f*-
RT: 20.-59 AI: 1309 KI: 1309 Guaiacol<p-vinyl->
C A S #: 1186- 61 -0 MF: C9 Hl0 02 F W : 1.50 MS D LIB #: 1662
CN: 2-rnethoxy-4-vi nylphenol
Synonyrns: p-vinylguaiacol,plrenol<2-nrethoxy-4-vi
nyl->
Sourcg:AlclrichChern.
I 00
u0
60
40
20
RT: 20.61 AI: 1309 KI: l3 l0 Tetrahydro .iasmone<trans->

CA S #: 71. 535- 2 9 -0 M F : C l I H 2 0 O F W: t68 MS D LIB #: 19-56
CN: cyclopcntanone, 3-nrethyl-2-pentyl-, tl'ans-
Synonynrs: none
Source:BcclilukianRes.ex .I.TBrophy
RT: 20.63 AI: 1309 KI: 1310 Carvotanacetone<6'hydroxy->

CAS#: 131486-99-2 MF: Cl0 Hl6 02 FIV: 168 MSD LIIJ#: 974
1-nrethylethyl)-
CN: 2-cyclohexen-l-one, 6-hydroxy-2-methyl-5-(
Synonyms:none
Lagg.eraalata orl ex.T.ISchefl'er
ScruLce:
100
80
60
40
l 28 140 1.50
t40
RT;20.63 AI: 1309 KI: l3l0 Veloutone

CAS#:65443-14-3 MF: Cl3 H24O FTV:196 MSD LIB#: 1537
2,2,5-trimethyl--5-pentyl-
CN: cyclopentanone,
Synonyms: none
Source:Firmenisch Cu,Kunming
ex Jian-Qin
RT: 20.64 AI: 1310 KI: l 31l Adamantanone<2->

CAS#:700-58-3 MF: Cl0 Hl4 O FW: 150 MSDLIB#: 1995
l. I 3,7)decanone
CN: tricyclo(3.3.
Synonyms: 2-oxoadamantane
Source:Aldrich Chem.ex JJ Brophy
t00
80
60
40
Appendix
RT: 20.64 AI: l3l0 KI: l3l I Isoamylbenzylether

CAS#:122-13-6 MF: Cl2 Hl8 O FW: 178 MSDLIB#:851
CN: benzene,((3-nrethylbutoxy)rnethyl)-
Synonyms: isopentylbenzylether
Source:Ptaltz& Bauerex Art Tucker
er'T
RT: 20.68 AI: l3l I KI: 1312 Pinocarvyl acetate<cis->
CAS#: 13366-18-4 MF: Cl2 Hl8 02 Flil: 194 MSD LIB#: l3l2
CN: bicyclo(3.| . l )heptan-3-ol,6,6-dimethyl-2-methylene-,
acetate,(I o,3B,5o)-
Synonyms:none
t00 120 140
R T : 20. 69 A I : l3 1 l K l : l 3 1 2 N o n a n y l a c e tate< n->

C A S #: 143- 13- 5 M F : C 1 l H 2 2 OZ F W : 186 MS D LIB #:
CN: aceticacid, nonyl ester
Synonyms:pelargonylacetate
43
100 CHg(CH2)6o-Ac
80
60
40
20
R T: 2 0. 69 A I : l3l I K I: 1 3 1 2 S e s a mo l
CAS#:533-3l-3 MF: C7 H6 03 F'W:138 MSD LIB#: 1405
CN: 1,3-benzodioxol-5-ol
Synonyms:phenol,3,4-(nrethylenedioxy)-
Source:ref. cpd. ex E. von Ruclloif
100
80
60
40
RT:20.70 AI: 1311 KI: 1312 Undec'(98)-en'1-al

CAS#:143-14-6 MF:Cll H20O FW: 168 MSDLIB#: 1-520
CN: 9-undecenal
Synonyms:9-hendecenal
Source:Givaudan Cu,Kurrming
ex Jian-Qin
100 Hc(=o1
lsxr)7-ctt=cttcH,
80
60
40
20
10 6t)
RT: 20.73 Al 1312 KI: l3l3 Isopulegylacetate<neoiso->

CAS#:000-00-0 MF: Cl2 H20 02 F'W: 196 MSD LIB#: 882
CN: not assigned
Synonyms: none
Source:AldrichChem.
RT:20.74 AI:1312 KI: 1313 Cvclohexanol

acetate<t
CAS#: 20298-10-8 MF: Cl2 H22OZ FIM: 198 MSD LIB#: -542
CN: cyclohexanol,2-(1,I -dirnethylethyl)-,acetate,trans-
Synonyms:none
Source:ref. cpd. ex Art Tucker
60
40
20
RT: 20.7.5AI: 1312 KI: l313 Citronellicacid

CAS#:502-47-6 MF: ClO Hl8 ()2 FW: 170 MSD LIB#: 1717
CN: 6-octenoic
acid,3,7-dimethyl-
Synonyms:none
Source:ref. cpd. ex E. von Rudloff; 4.107oEucalyptuscitriodora, JEOR 4:
0.52VoCitrus hystrix (twig); O.4lok Citrusparadisi (leaf)
4l
100 t20 140
RT: 20.79 AI: l3l3 KI: l3l4 Trimethyl benzaldehyde<2,3,4->

CAS#: 34341-28-l MF: Cl0 Hl2 O FW: 148 MSD LIB#:660
CN: benzaldehyde,2,3,4-trimethyl-
Synonyms:none
Source:Erl,ngiu*Tontidum oil ex KC Wong, Malaysia
I 19
9l
348 Adams:EsscntialOil Componcntshy GC/MS l
RT: 20.83 AI: l3l4 KI: 1315 Cryptone< 'hydroxy'>
CAS#:39125-34-3 MF: C9 H1402 FW: 154 MSD LIB#: l42l
CN: 2-cyclohexene-| <rne,4Jrydroxy-4-(1 -mcthylethyl)-
Synonyms:2-cyclohexen- | -methylethyl)-
I -onc,4-hydroxy-4-(
Source:Solidagograninifolia oil ex P. Weyerstahl
100
80
6t)
40
20
R T: 20. 87 A I : 131 5 KI: l 3 l 6 D e c a d i e n a l < (2 8,48)' >

CAS#: 25152-84-5 MF: ClO Hl6 O FW: 152 MSD LIB#: 564
CN: 2,4-decaclienal, (E.ll)-
Synonyms:2-trans,4-trans-clccadienal
Source:ref. cpcl.ex Art Tuckel2.65Vo Nicotiano.forgetiana(flower)'
.IITOR7 :26-5( | 995 ): 2.00% RIus cctr i ari a; 0.837aSi d erit i s amasiaca
RT: 20.88 AI: 131.5 KI: l3 | 7 Hexenyl tiglate <(38)->

CA S #: 120603- 00 -1 M F :C l I H l 8 ()2 F W: 182 MS D LIB #: 1937
CN: 2$utenoic acicl,2-nretlryl-,(38)-3-hexenylcster,(2E)-
Synonyms:hexenyltiglate<trans-3->
Source:BedoukianRcs. ex .lJ Brttphy
Appenclixlll: MassSpectra 349
RT: 20.90 AI: 1316 KI: l3l7 Terpinylacetate <6->

CAS#:93836-.s0-l MF: Cl2 H2O02 FW: 196 MSD LIB#: 1562
CN: cyckrhexancntctlranol,
c,a-dirnethyl-4-rncthylene-,
acetate
Synonyms:none
Source:Drasocoex NorbertBraum
A
V
L__o-o"
RT: 20.91 AI: I 3 | 6 KI: 1317 Terpinyl acetate<cis-clihydro-u->

CAS#: 20171-40-6 MF: Cl2 H22(o2 I,W: 198 MSD LIB#: 1467
CN: cyclohexanerncthanol, o.o,4-tritnethyl-,
acctate,cis-
Synonyms:p-nlenthan-8-ol acetaLe,cis-
S<lurce:Dragocoex Norbcrt Braurn
r00
A
x^"
n0
60
40
20
t40 160 180
RT: 20.93 AI: l316 KI: l3l8 Citral <dinrcthoxy-(Z)->

CAS#: 15128-91-1 MF': Cl2 H22 02 FW: 198 MSD LIB#: 451
CN: 2.fr-octadicne
, l ,I -elirnethoxy-3,7-climethyl-,
(Z)-
Synonynrs:dirnethoxynelol
Sonlcc:Aldrich Chenr.ex H. Hills
4l
100
8(
60
t1.4l 4l f, *,
t98
200
RT:20. 94 A I : 131 6 KI: l 3 l 8 Pa tc h e n o l < (Z )->

CAS #: 58431- 72- 2 MF : C l l H l 8 O F W: 1 66 MS D LIB #: 1237
CN: ethanol,2-(3,3-dirnethylbicyclo(2.2. (27)-
I )hept-2-yildene)-,
Synonyms:camphenernethanol, 8-
100
80
60
40
20
RT: 20.96 AI: I 317 KI: 1319 Cycloisolongifolene <didehydro'>

CAS#: 74842-33-4 MF: Cl5 H22 FW: 202 MSD LIB#: -536
CN: 2,3b-methano-3bH-cyclopentn( , | ,2,3,3a,4'5-hexahydro-
I ,3)cyclopropa(I ,2)benzene
| ,l .4,4-tetramethyl-
Synonyms:none
Source:ref. cpcl.ex P. Weyerstahl
100
80
60
-+0
20
RT: 2l .00 AI: I 3 l8 Kl: l3 l9 Cinnamaldehyde<c'methyl->

C AS#: l0l- 39- 3 M F : C l 0 H l 0 () F W: 1 46 MS D LIB #: 1686
CN: 2-propenal,2-methyl-3-phenyl-
Synonyms:o-rnethylcinnimal,2-methyl-3-phenylacrolein
/--
d
RT: 21.01 AI: l3l8 KI: 1320 Pinanediol<cis-2,3->

CAS#: I 8680-27-8 MF: C l0 H l8 ()2 FW: I 70 MSD LIB#: 1299
CN: bicyclo(3.1.l )heptane-2,3-diol, ( lR-( lo,2a,3a,-5c))-
2,6,6-trimethyl-,
Synonyrns:pineneglycol,cis-u-
100
80
60
40
20
RT:2l .02 AI: 1318 KI: 1320 Methylthujate

CAS#:.54-598-10-6 MF: Cl1H14ao2 FW: 178 MSD LIB#: 1864
CN: I ,3,6-cyclohcptatriene-
l -carboxylicacid,5,-5-dimethyl-,methyl
ester
Synonynts: thujicacid,methylester;
Sonrce:QuestIntl. ex RobinClery
100
\J \ ,o.Me
80 /\:^\
60
40
20
80 r00 t20 140 t60
RT: 21.04 AI: l3 | 9 KI: 1320 Dihydro citronellol acetate

CAS#: 20180-49-8 MF: Cl2 H24 02 FW: 200 MSD LIB#: -592
CN: l -octanol,3,7-dimethyl-,acetate
Synonynrs:dihydro citronellyl acetate;tetrahych'o
geranylacetate
t00
80
60
40
20 f.-
i
RT: 2l .04 AI: l319 Kl: | 320 Dirnethylphenethylacetate(o,o')

C AS#: 1. 51- 05- 3 MF : C l 2 H l 6 0 2 F W: 1 9 2 MS D LIB #: 6l I
CN: benzeneethanol,u,u, dimethyl-,acetate
Synonyrns: dinrethylbenzylcarbinol acetate
Source: Aldrich Chem.
u1
f\2<"Y
\ 2b
l2{) 140 t60 t80
RT: 2l .0-5 AI: 13l9 KI: 1321 Verbanol acetate<neo->

C AS#:73366- 10- 6 MF : C l 2 H 2 0 0 2 F W: I9 6 MS D LIB #: l -542
l
acetate,(
1,6,6-Irirnethyl-,
CN: bicyclo(3.| .1)heptan-2-ol, o,2B,4u,-5u)-
Synonyms:none
Source:acetylationol'verbanols(63| 4)
RT: 2 | . 07 A I : 1319 K I: 1 3 2 l D e c a d i e n o<l (2 E ,4 E )->

CAS#: 18. 109- 21 -7 MF : C l 0 H l 8 O F -W :1 .5 4 MS D LIB #: 2106
CN: 2.4-decadien- l -ol, (28,48)-
Synonyrns: none
100 HO
80
60
40
20
RT: 2 | .07 AI: l319 KI: l321 Hexenyl tiglate <(32)->

CAS#: 67883-79-8 MF: C I I H 18 ()2 FW: I 82 MSD LIB#: 1936
CN: hexenyltiglate <-32->
Synonynrs: hexenyltiglate<cis-3->
Strtrrce:BedoukianRes.ex JJ Brophy; 20.30VaGardenia.jasminoides,
p.90,in: AromaticPlants& EssentialConstituents, PeaceBook Co,, Hong Knng(1993);
3.107o Lorticera j aponica; OA0% Hy aci nthus o r i entali s
RT: 21. I I AI: l320 Kl: 1322 Hexyl 2-methyl-3-pentenoate

C A S #: - 5862- 5 -9 4 -8 MF :C l 2 H 2 2 0 2 F W: 198 MS D LIB #:2196
CN: 3-pentenoic acid,2-methyl-,hexyl ester,(Z)-
Synonyms:none
100
80
60
40
20
RT:21.16 AI: l32l KI: 1323 Nonyne <1,1-dimethoxy-2->

CAS#:13257-44-8 MF:Cl I HZO02 FW: 184 MSD LIB#: 2l l-5
CN: 2-nonyne,
I,1-dimethoxy-
Syntuyms:none
H3C-(HrC)5--#
\o-"u
3.54 Adams: EssentialOil Componentshv GC/MS
RT: 21.17 Al 1322 KI 1324 Undec-(92)-en-1-al

CAS#:390745-03-6 MF: Cl I H20O FW: 168 MSD LIB#: 1.521
(97)-
CN: 9-undccena,l.
Synonyms:none
Source:Givaudan Cu,Kuntning
ex.Iian-Qin
A'""'Fo
60
40
20
RT: 21.18 AI: 1322 Kl l?24 Jasmonol<trans'(E)->

CAS#:l-5631(r-87-9MF: C I I H20O FW: | 68 MSD LIB#; 2026
( I R.2S)-
2-(lE)-l -hexenyl-,
CN: cyclopentanol,
Synonynrs:none
Source:IledoukianRes.ex .I.lBrophy
100
ti0
60
RT: 2l .19 Al: 1322 KI: 1324 Methyl geranate

C AS#: 2349- 14- 6 M F :C l l H l 8 0 2 F ri l : 1 8 2 MS D LIB #: l l 33
CN: 2.6-octadienoic acicl,3,7-dirnethyl-, rnethyl ester
Svn o ny p5;r nc t hy gc
l ra n i a l c
Source:Neor:allotropispon.cherioil ex P. Raharivelomanana; 0.807oLtruru,snobilis,
Acta Bot. Sinica32:878(1990);0.707oAbysia triphylla' 0.667oRosadqnnscena
100
8t)
60
40
20
t40 160 180

App cn dixlll: Ma s sSpec t r a 355
RT: 2l .23 AI: 1323 KI: I 32.5 Methyl decanoate i

C A S #: ll0- 42- 9 MF : C l l H 2 2 O2 F W : 186 MS D LIB #: l 09l i
CN: decanoicacid,methylester i
Synonyms;methylcaprate;capricacid,methylester
Sottrce:rel'.cpd. ex Il. von RudlofT;4.107oAnrontuntptycholinratum.,
p.333, '
in: Flav. & Flag.:A World Pelsp.,Lawrence,etal.(eds.),Proc. 1OthInt. Con$.Ess.Oils,
Irlsevier,Amsterdarn(1988):3.497oMagnolia grandifloral 2.5|tk Hurnuhtslupttlus
Me-o-C(=Q)-(cH2)8-cHJ
40 60 80 100 120 t40 r6 0 r8 0
R T : 2l' 28A |: |32 4 K | :1 3 2 6 Pl re n y | e th y | o x y a ceta| dehyde

CAS#: 4 | 847-88--5 MF: C 10 Hl2 02 FW: I (r4 MSD LIB#: 1289
CN: acetaldehyde, (2-phenylethoxy)-
Synonynts;none
l0-5
100
80
60
40
20
40 60 8t) l0t) t20 140 t60
RT:21.29 Al 1324 Kl: 1326 Nlyrtenyl acetate I

C A S #: l0l9- 01-2 M F :C l 2 H l 8 0 2 F W : 194 MS D LIB #: Il 21 ,
CN: bicyclo(3.I .l )hept-2-ene-2-rnethanol, 6,6-dirnethyl-,
acetate,(
lS)
S y nony nr s : 21i n e n -1 0 -oa lc, e ta te i
Scrurcc;ercetylation of myrtenol (6 | 1.5);35.907oM),rtuscomnruris(leaf),
.IEOR3:ll3(1991);33.007oMyrtu,scontnmnis(unripefiuit);6.-507o Egletesviscosa
6-
j
356 Adams:IlssentialOil Componentsby GC/MS
< p->
RT:2 1 . 30 A I : 132- 5 K l :1 3 2 7 Me n th a -I,4 -d i e n -7-ol
CAS#: 22539-72-6 MF: Cl0 Hl6 O FW: 1.52 MSD LIII#: 2180
CN: 1,,1-cyclohcxadiene-l -methanol,4-(l -methylethyl)-
Synonyms:none
Source:Rh.odiolaru.raroots ex. Jan Karlsen,Norway; 0.707oHedltotisdi.ffusa,
JEOR 7:537(1995);0.387a Citms sinensis;0.19a/o Dauctrscorota
o
A
I
l2{) t40 r6 0
RT: 21.36 AI: 1326 KI: 1329 Dilrydro carveol acetate<iso->

CAS#: 160868--58-6 MF: C l2 H20 02 FW: 196 MSI) LIB#: -598
CN: cychexanol,2-mcthyl--5-( (l
acetate,
I -nethylcthenyl)-, u,213,-50)-
Synonyms:none
Sonrce:ref. cpd. ex E. von Rudlol'l'
A*-
t00
80
60
-+0
l0 \
t40
RT: 21.37 Al 1326 KI: 1328 Limonene aldehyde

CAS#: 6784- 13- 0 Ml ' :C l l H l 8 O FW: 166 MS D LIB #: 1006
-propanal,p,4-clirnethyl-
CN: 3-cyclohexene-1
Synonyms:p-rnenth-I -ene-9-carboxaldehyde
Source:Takita Chem.ex Art Tucker
100
80
fl)
dH
40
20 A-\"
Appendix II[: Mass Spectra 357
RT:21.37 AI:1326 KI: 1328 Silphiperfol-S-ene

CAS#:138752-24-6 MF: Cl5 H24 F'W:204 MSD LIB#:63.5
CN: cyclopenta(c)pentalen
e, 1,3a,4,5,5a,6,7,8-octahydro-1,2,3a,6-tetramethyl-,(
I S,3aS,5aS,6R.8aR)-
Synonyrns:
silphiperfol--5-ene
B
Source:Echinoposgiganteus oil ex P. Weyerstahl
RT:21.39 Al:1327 KI:1329 Hasmigone <(Z)->

CAS#:000-00-0 MF:Cll Hl8O FW: 166 MSDLIB#:76-5
2-(2{exenyl)-, (22)-
CN: cyclopentanone,
Synonyms:none
Source:Bedoukian
Chem.ex Art Tucker
RT: 21.39 AI: 1321 Kl: 1329 Isotrutyl benzoate

CAS#: f 20-.50-3 MF': Cl I Hl4 02 I.W: 178 MSD LIB#: 858
CN: benzoicacid, 2-rnethylpropylester
Synclnyms:none
Soutce:Afdrich Chenr.;l.l5o/oCltenopodium ambro.sioicles,.IEOR 7:221(1995);
030% Enrpleunmr, 0.0 1a/oSpartiwrtj unceurn( absolute)
fragrans;
o
tl
ra=4"'Y
\2
3.58 by GC/MS
Adams:EssentialOil Cornponents
RT:2l .43 AI: 1328 KI: 1330 Jasmonol <cis,(E)->

CAS#:1.56316-90-4 MF: Cl l H20O FW: 168 MSDLIU#:2027
( I R,2R)-
2-(I E)-hexenyl-,
CN: cyclopentanol,
Synonyrns:none
Source:BedoukianRes.ex.I.I}3rophy
80
60
4(l
2(
RT: 2l .44 AI: l328 KI: 1330 lVlenthol<8-hydroxy-neo->

CAS#: 3564-95-2 MF: Cl0 H20 02 tsW: 172 MSD LIB#: 2015
CN: cyclohexanelne'thirnttl, I R'2S'4R)-
2-hydroxy-cr,u,4-trimethyl-,(
Synonynrs: neonrenthoglycol; PMD -38;
Source:ref. cpd. ex .l.IBrophy
80
6(
40
20
RT: 2 l . 45 A I : 1328 Kl : 1 3 3 0 P a tc h e n o <

l (E)->
CAS#:. 58437- 71- l M F :C l l H l fl O FW: 166 MS D LIts#: 1238
CN: ethanol,2-(3,3-dinrethylbicyclo(2.2' (28)-
l )hept-2-yidiene)-'
Synonyrns: none
100
80
60
40
20
Appendix
RT: 2l .4-5 AI: 1328 KI: 1330 Verbanol acetate<neoiso->

CA S #: 73366- 12 -8 MF : C l 2 H 2 0 0 2 F W: 196 MS D LIB #: 1.543
CN: bicyclo(3.l.l )heptan-2-ol,4,6,6-trirrrerhyl-,acetate,(lct,2B,4p,5u)-
Synonyms:none
Source:acetylationof verbanols(63| 4)
q"-
43
RT: 2l .51 AI: 1329 KI: 1332 Piperonal

CAS#:120-51-0 MF: C8 H6 C)3 FW: l-50 MSDLIB#: 1331
CN: 1,3-benzodioxole-5-carboxaldehyde
Synonyms:heliotropin;geliotropin i
Source:Aldrich Chem. ex H. Hills; 1.4A7oEucal;,-ptus
lelmtqnni,FFl s : 9 1 (1 9 q 0 );
J
0.247oCinnamomttm micranthum;O.1O7oP ip er n ig r um I
lt4s
80
60
40
"Yry)
20
RT: 21.52 AI: 1330 Kl 1332 Anisyl formate

CAS#:122-91-8 MF: C9 HlO ()3 FW: 166 MSD LIB#: 176
CN: benzenemethanol,
4-methoxy-,
fbrmate
Synonyms: none
Source:AldrichChem.
100
oAo
80
60
40
20
RT:21..54AI: 1330 KI: 1332 Hexyltiglate

CAS#:16930-96-4 MF: Cl l H2002 F-W:184 MSD LIB#:45
CN: 2-butenoic lrexylester,(Ii)-
acitl,2-ntethyl-,
Synonyrns:crotonicacid,2-nrethyl-,hcxylester(E)-
Source:AfdrichChem.;0.46Vo Lat,andulaangustilolia,Perf. & Flav.9:49(.1984);
0.387oLav'andulax hy'brida; 0.207oCltantonilla recutita
100
ti0
60
40
20
RT:2l.-5(rAI: 1330 KI: 1333 Menth-l-en-7-al <3'oxo-p->

CAS#:160152-34-l MF: Cl0 Hl4 02 FW: 166 MSDLIB#:1422
I -carboxaldchyde,
CN: l -cyclohexene- 4-(I -rnethylethyl)-3-oxo-
Synonyrns:none
Source:Solidagograntinifoliaoil ex P. Weyerstahl
f
RT: 21.63 AI: 1332 Kl: 1334 Piperitol acetate<cis->
CAS#: | 12028-22-5 MF: C I 2 H20 02 FW: I 96 MSD LIB#: I 32.5
CN: 2-cyclohexen-| -ol, I
3-methyl-6-( -methylethyl)-, cis-
acetate,
Synonyms:none
Source:acetylationof cis-piperitol(6433)
r+-)
100
I
80
60
40
.>
\-/
,,rrlt\O
AC
:
120 r40 t60 180

AppendixIll: MassSpectra 361
RT: 2l .68 AI: 1333 KI: l -136 Hasmigone<(E)->

CAS#: 000-00-0 MF: Cl I Hl8 O FW: 166 MSD LIB#: 766
CN: cyclopentanone, (E)-
2-(2-hexenyl)-,
Synonyms:none
r00
80
60
4(
20
137 t48
RT: 21.70 AI: 1334 KI: 1336 Presilphiperfol-7-ene

CAS#:8093l-09-.5 MF: C 1.5H24 FW: 204 MSD LIB#:636 i
CN: lH-cyclopent(cd)indene,2.2a,3,4,4a.-5,6,7<rctahydro-1,1,2a,5-tetramerhyN-,
(2aS,4aS,5R)-
Synonyms:none
Source:Echinoposgiganteusoil ex P. Weyerstahl
tit)
60
40
20
RT:21.12 AI: 1334 KI: 1337 Anthranilate<methyl->

CAS#:134-20-3 MF: C8 H9 N 02 FTV:l-51 MSD LIB#: 179
CN: bcrnzoic
ac.icl,2-arnino-,
ntethylester
Synonynrs:
2-carbornethoxyaniline;
rnethyl2-aminobenzoate
Source:Neroiloil cx AlanF. Thonras
r00
80
60
40
20
P.T:21.72 AI: 1334 KI: 1337 Methyl o-anisate

CAS#:606-45-l MF: C9 HlO ()3 FW: 166 MSD LtB#: 1692
rnethylester
CN: benzoicacid,2-methoxy-,
dimethylsalicylate
Synonynrs:
Source:
AldrichChem.
r00
80
60
40
20
140
RT: 2 l . 73 A I : 1334 K l : 1 3 3 7 L i n a l o o l p ro p a n o ate

CAS#: 144- 39- 8 M F : C l .l H 2 2 0 2 F W:2 1 0 MS D LII]#: 1634
CN: I ,6-octadien-3-ol. 3,7-dimethyl-, pr opanoate
Synonynrs:1,6-octadien-3-ol <3.7-dirrcthyl,propionate>
Scrurce:Aldrich Chem.; 4.96Vc Artentil;iaafra. Pharmazie49:935(1994);
0.367oCit rus limon; 0.127o Lat,antlula artgustifoI i a
120 l4t) t60 180 200 220
< 4-hydroxy' >

RT:2 1 . 76 A I : 1335 K I: 1 3 3 7 B e n z e u e me th a nol
CAS#: 623-05-2 MF: C7 Hti ()2 FW: 124 MSD LIB#: 1998
CN : henzeneutethanol, 4-hydroxy-
Synonyms:gastrodigenin I p-mcthylolphcn<ll ; o-hydroxy-p-cresol
Sourcc:Aldrich Chcm.ex J.l Brophy
100
80
60
Appendix III: Mass Spectl.a
RT 21.77 AI: 133-5 KI: 1338 Elemene<6->

CAS#:20301-84-0 MF: C1-5H24 FW:204 MSD LIB#: 308
CN: cyclolrexene,4-ethenyl-4-methyl-3-( I -methylethcnyl)-l -( l -methylethyl)- 3R+rans-)
Synonyms:p-menth-3-ene,2-isopropenyl-| -vinyl, trans-
Source:Black pepperdistillation; 28.797oConuniphoramyrrha, gth Int. of Ess.Oils,
Paper#400, Singapore( I 983); 6.40%o B accharisdracunculifulia; 5.277o cerifera (leaf)
r00
80
60
40
20
RT: 21.80 AI: 1336 KI: 1338 Phenylpentan-3-one <L->

CAS#:20195-51-1 MF: Cl I H14 O FW: 162 MSD LIB#: 119
CN: 3-pentanone,l-phenyl-
Synonyms:ethylphenethyl ketone
Source:Amorttyrtusmeli oll ex P. Weyerstahl
9l t0-5
57
r3 3
100 t20 r40
RT: 21.82 AI: 1336 Kl: 1339 Isosafrole

<(Z\->
CAS#:17627-76-8 MF: ClO HlO ()2 FW: 162 MSD LIB#: 886
CN: benzodioxole
<5-(1Z-propenyl)-
1,3->
Synonyms: none
Source:AldrichChem.
104
j
364 Adams: EssentialOil Componentsby GCiMS
RT:2 1 . 8- 5 A l: 1337 K l : 1 3 4 0 Ev o d o n e
CAS#: 30.5.57-66--5 MF: ClO Hl2 02 FW: 164 MSD LIB#: 702
CN : 4(-5H)-benzoluranone, 6,7-clihydro-3,6-dimethyl-
Synonyms:p-nrentha-4,8-clicn-3-one, -5,9-epoxy-
S<rurce: hrodia horten,sisoil ex .lJ Broplty; 44.007cEuodia ltorten,sis(flower),
FF.l | : t 7( 1985);25.00VoEuodia hortensi,s(lcaf); 0.80% DracoceplrclLr m kotst:ltyi
120 t.10
RT: 2 | .90 AI: 1338 KI: l34l Citral <dinrethoxy'(E)->

CAS#:75128-98-2 MF:C12H2202 FW: 198 MSDLIB#:4-52
CN: 2,6-octadiene, (E)-
l, I -dimethyoxy-3,7-dirnethyl-,
Synonyms: dirnethoxy geraniol
Source:AldrichChem.ex Art Tucker
ff"
t00
t4t) 160 180
RT: 2 1. 90 A I : 1338 K I: 1 3 4 1 In d a n o l < 5 ->

C AS#: 1470- 94- 6 MF ' :C 9 H 1 0 O F ' W: 1 3 4 MS D LIB #: 838
2.3-dihydro-
CN: I H-inclen--5-ol.
Synonyms:-5-hydroxyi ndane
Source:Aldrich Chcm.
t00
RT:21.92 Al: 1339 KI: l34l Benzenenrethanol<3-hydroxy->

CAS#: 620-24-6 MF: C7 H8 C)2 I"W: 124 MSD LtB#: 2001
CN: lrcnzcnemethanol,
3Jrydroxy-
Synonyrns:hydroxybenzylalcohol,3-
Source:AlclrichChent.ex.lJ Broplry
40
6
RT:21.92 AI: 1339 KI: l34l Octanediol<2,4->
CAS#:629-41-4 MF -:C 8 H l 8 0 2 F W : 146 MS D LIB #:2008
CN: 1,8-octanediol
Synonyms:none
Source:Pl'altz& Bauer ex J.I Brophy
RT: 21.9,5AI: 1339 Kl: 1342 Butanone<3-hydroxy-4-phenyl-2->

CAS#:53.5.5-63-.5MF: ClOHlz02 F-W:164 MSD LIB#: 1112
CN: 2-butanone,
3-hydroxy-4-phenyl-
Synonyms: none
Source:Minursopselengiex KC Wong,Malaysia
l
366 Adams:EssentialOil Componentsbv GC/MS
RT: 21.95 AI: 1339 Kl 1342 Carvyl acetate<trans->

CAS#: I 134-9.5-8 Ml'-:C l2 H l 8 ()2 FW: 194 MSD LIB#: 368
CN: 2-cyclohexen-l-ol,2-rnethyl--5-(l-rnethylethenyl)-,acetate,trans-
Synonyms:p-rnentha-6,8-disn-2-ol, trans-
acLrtate,
Strurce:SCM Cherns.ex H. Hills; 5.90%Mentha,spir:ata. FFJ 1:10-5(1986);
0.997oMentlta aquatica x viridisi 0.847o Hltlttisnmtabilis
I
O-Ac
*
\-,
i
,,\
RT: 2f .96 AI: 1340 KI 1342 Menthothiophene

CAS#:103215-89-4MF:ClOHl4 S FW: 166 MSDLIB#:2193
4,5,6,'7
CN: lrenzo(b)thiophene, rnethyl-
-tetraltydro-3,6-di
Synonyms: none
cq
RT:21.97 AI: 1340 Kl 1342 Dihydroisojasmone
CAS#: 13014-65-2 MF: Cl I H20 O FW: 168 MSD LIB#: 2138
2-hcxyl-
CN: cyclopentanone,
Synonyms:jasmatone
RT: 2l .98 AI: 1340 KI: 1343 Piperitenone

CAS#:49l-09-8 MF: Cl0 Hl4 O F W : 1.50 MS D LIB #: 1064
CN: 2-cyclohexen-I -one, 3-methyl-6-(I -methylethylidcne)- t
Synonyms:pulespenone;3-terpinolenone
Source:Men.thavertic:illataoil ex M. Maffei. ltaly 40.407cCalantinflmnepeta'
JEOR 3 :7( I 99 | ); 34.00VoM entlm cervina; 14.707aZizip In ra h i sp ani ca
t07
r00
80
60
40
20
RT: 22.00 Al: 1340 KI: 1343 Verbanolacetate

CAS#:73366-09-3 MF; Cl2 H2002 FW: 196 MSD LIB#: 1.540
CN:bicyclo(3.1.1)heptan-2-<t1,4,6,6-trinrethyl-,
acetate,(1a,2u,4u,-5u)-
Synonyms:none
Source:acetylation
of verbanols(63
I 4)
l0t)
.,-.ttto-O'
80
60 €
=
40
20
RT: 22.09 AI:1342 KI: 134.5 Nicotine

CAS#:-54-11-5 M F :C l 0 H l 4 N 2 F W: 162 MS D LIB #:11.50 I
(S)-
CN: pyridine,3-(I-methyl-2-pyrrolidinyl)-,
Sy nony m snone
:
Source:Aldrich Chern.;25.927aNicotiana rustica (l'lower),.IEOR7:26-5(1995)
100
80
60
40
20
368 Adarrs:EssentialOil Comnonentsbv GC/MS
RT: 22.10 AI: 1343 Kl: 1346 Piperitol acetate<trans->

1.5-8 MF: C 12 H20 02
CAS#: 9 | 1.59- FW: 196 MSD LIB#: I 326
CN: 2-cyclohexen- | -methylethyl)-,
I -ol, 3-methyl-6-( acetate,trans-
Synonyms:none
Source:acetylationol' trans-piperitol(6433)
5,^"
t00
80
60
40
20
140 l6t) 180 200
RT: 22.| 3 AI: l343 KI: 1346 Benzyl butanoate

CAS#: 103-37-7 MF: Cl I H14 OZ FW: 178 MSD LIB#: 74
CN: butanoicacicl,phenylmethylester
Synonyms:henzylbutyrate
tl
ot'\'-\
ill
\/
RT: 2 2. 18 A I : 134. 5 K I: l -1 4 7 S i l p h i n e n e
CAS#: 74281- 51- 4 M F : C 1 5 H 2 4 F W :2 0 4 MS D LIB #:2167
CN: cyclopenta(c)pentalene,l .2,3,3a,4,5,-5a,6-octahydro-1
,4,4,5a-tetramethyl-,
| | R -(| a. . iaa. 5aF . 8a R + )l -
Synonyms:none
Source:Artemisia anna rcots,Vietnam ex HJ Woerdenbag
100
80
60
40
20
100 120 140 160 180

{
I
1
AppendixIII: MassSpectra i 369

I
RT: 22.20 AI: 1345 KI: 1348 Silphiperfol-S-ene
i
<7-epi-> |
CAS#: 138'752-23-5MF: Cl5 H24 FW: 204 MSD LIB#: 637 |
CN: cyclopenta(c)pentalene,
1,3a,4,5,5a,6,7,8-octahydro-1 ,(l R,3aS,-5aS,6R,8aR)-
,2,3a,6-tetramethylf
Synonyms:none I
Source:Echinoposgiganteus
oil ex P. Weyerstahl i
i
l o o4191!
ll' | -^ _ i r
*nl| ,f, ,To 294
| | 'i? rJ3 r7.s
P.T:22.24 AI: 1346 KI: 1349 Phenol<2.6-dimethoxy->

CAS#:91-10-l MF: C8 Hl0 03 FW: 154 MSD LIB#: 1269
CN: phenol,2.6-dimethoxy-
Synonyms:syringol
40 60 80 t00
RT:22,26 AI: 1346 KI: 1349 Terpinyl acetate<tr->

CAS#:80-26-2 MF: Cl2 H2002 FW: 196 MSD LIB#: 948
CN: 3-cyclohexene-l-methanol,cr,a,4-trimethyl-,
acetate
Synonyms:p-menth-I -en-8-ol,acetate
Source:Jwiperus squ.amata,India,oil ex P. Weyerstahl;43.007oElettaria
Phytochern.10:177(197l); 3O,507oEucalyptusdiversicolor;26.907o x hybrida
_^ 59
:')-, I
RT: 22.30 Al: 1341 Kl: l3-50 Acetophenone<4'-methoxy'>

CAS#:100-06-1 MF:C9 Hl0 02 FW: 1.50 MSDLIII#: l0
CN: ethanone,I -(4-rnethoxyphenyl)-
Synonyms:4-acetylanisole; p-
linarodin;acetanisole,
RT: 22.30 Al: 1341 KI: 13-50 Carvotnenthyl acetate <neoiso->

CAS#: 2077'7-43-9 MF: C 12 H22 02 Fril': | 98 MSI) LIB#: 373
CN: cyclohexirnol,2-rnethyl-5-( acetate,( I u,2u,-5o)-
I -methylethyl)-,
Synonyms : p-rncnthan-2-ol,acetate
Source:ref. cpd.,ex E. von RudlofT
=
=
..t\O'Ac
\-.rr"
t -\
r-a
tl
tl
\-/
!
=
RT: 22.31 A1:1341 KI: 1.1.50Triacetin

CAS#: 102-1(t-l M F :C 9 H l 4 0 6 F fi l :2 1 8 MS D LIB #: 1700
CN: 1,2,3-propanetriol,
triacctate
S1'nonyms;glyccroltriacetate,vanay,Kodallextliacetin
RT: 22.33 AI: 1345 KI: 1348 Cubebene

<u->
CAS#:11699-14-8 MF: Cl.5H24 FW: 204 MSD LIB#: 826
CN: I H-cycloperrta( I ,3)cyclopropa(
1,2)benzene, 3a,3b,4,-5.6,7-hexahydro-3,
-dimethyl-
4-( I -methyfethyl)-, (3aS-(3aa,3bp,4p,7cr,7aS't))-
Synonyms:none
Scrurce:Hltnenaea oil ex .Tean Langenlreim#5439:22.507aHeterothecainul
FF'.II I :49(1996);8.00o/a Cedrelaodorata:7 .10VoPiper cuheba
10.5
r 00
80
RT: 22.38 AI: 1349 Kl:1352 Thyrnolacetate

CAS#:528-19-0 MF: Cl2Hl6 02 FlV: 192 MSD LIB#: 1227
CN: phenol,-5-methyl-2-(
1-methylethyl)-,
acetare
Synonyms:none
Source:acetylation
of oreganooil(-5430)
80
60
40
20 +"-
F.T:22.41 AI: 1350 KI: 1352 Citronellylacetate
CAS#:150-84-5 MF: Cl2 H22OZ FW: 198 MSD LIB#: 1364
CN; 6-octen-1
-ol. 3.7-dimethvl-.
acetate
Svnonvms: none
Source:Rcrsecril(acetylated)ex Firmenischex AF Thomas; 64.877aTermi bentToe,
.IIIOR 6:-533(1994);44.457o
Dracaena rqflexa; 18.0O7o
Ducrosia anethifolia
4,3
100..,
f.-
69 8l
i
PtT:22. 41 A I : 13. 5 0 KI: 1 3 5 2 L o n g i p i n e n e

C AS#:5989- 08- 2 M F :C l -5 H 2 4 FW: 204 MSD LIII#: 1032
CN: r'icyclo(5.4.0.02.8)undec-9-ene,2,6,6,9-tetramethyl-, stereoisonrer
Synonyms:none
Source:Fluka Chern.;1.347oSannlina chamaecl'parisstts, Dragoctl Rept. 39: l5l(1992);
0.907oP i tttts sib i r i ca: 0.65% Scltinu,s\entisr:ifoliu s
RT:22.47 Al: 13.51 KI: 13.54Phenylethylpropanoate

<2->
CAS#:122-70-3 MF:Cl1H14 02 FW: 178 MSDLIB#: 1280
CN: propanoicacid,2-phenylethyl ester
Synonyms:benzylcarbinylpt'opionate
Source:Aldlich Chenr.ex H. Hills: O.l27oMicheliaalba, p'14; in: Aromatic
Plants& EssentialConstituents, PeaceBook Co., Hong Kong(| 993);
g
0.0 | %,Pelar oniu n1graveo lens; 0.0 | 7oSp art ium j utl cemtt
/t\a'\'-":J-
\)6
RT: 22.48 AI: l35l KI: 1354 Ethyl nerolate

CAS#:32659-20-4 MF: Cl2 H2002 FW: 196 MSD LIB#:670
ethylester(Z)-
acid,3,7-dinrethyl-,
CN: 2,6-octtrdienoic
Synonyms:cthyl (Z)-geranate
Source:Bedoukian Res.cx Art Tucker
l0l 1j
Appendix
RT: 22.-5
| AI: 1352 KI: 1355 Trimethyl benzaldehyde
<2,3,6->
CAS#:34341-29-2 MF: Cl0 Hl2 O FW: 148 MSD LIB#: 661
CN: benzafdehyde,2,3,6-trimethyl-
Synonyms: none
Source:Erygiuntfoetidumotl ex KC Wong,Malaysia
RT 22.57 AI: 1353 KI: l3-56 Butyl butyryl lactate

CAS#:7492-70-8 MF: Cl 1H20 04 FW: 216 MSD LIB#: 2184
CN: butanoicacid,2-butoxy-1
-methyl-2-oxoethyl
ester
Synonynrs:
lacticacid,butylester,butyrate
RT:22.64 AI:1355 KI:1358 Damascone <(Z\-u->

CAS#:57549-93-6 MF: Cl3 H20O FW: 192 MSD LIB#:-555
CN: 2-buten- l-yl)-, (Z)-
| -one,I -(2,6,6-trimethyl-2-cyclohexen-
Synonyms: none
Solu'ce:
Finnenischex Jian-QinCu,Kunnring
374 Adarns:EssentialC)il Componentsby GC/MS
RT:22.6-5 AI: 13-5-5KI: l3-58 Hydroxybenzaldehyde<4->

CAS#: 123-08-0 MF: C7 H6 02 FW: 122 MSD LIII#: 1594
CN; henzaldehycle,
4-hytlroxy-
Synonyms:p-fornrylphenol.benzaldchycle, p-hydroxy-
Source:Aldrich Chem.;8.50o/o Flav. Food Addit. 7:272(1976)
Vanilla.fragrans,Int.
t00
80
60
40
20
RT: 22.69 Al: l3-56 KI: 13-59 Dihydro carveol acetate<neoiso->

CAS#: 256332-36-2 MF: Cl2H20 02 FW: 196 MSI) LIB#: 599
CN: cyclohexanol, 2-nrethyl-5-( (
1-nethylcthyl)-,acetale, R,2S.-5R)-
I
St'nonyns:none
Source;ref. cpd.ex E. von Rudlofl'
100
o-Ac
..ttt
80
60
40
20
RT:11.70 AI: 13.56Kl: 13.59Eugenol

CAS#:97-53-0 Mtr:C10Hl2(]2 FW: 164 MSDLIB#: 109.5
C\: nrethoxy-4-(2-propenyl)phenyl<2->
Sr nonvnrs:rl-allylguaiacol
Source:K & K Chenr.ex H. Hills; 95.007oEugeniacaryolthylhr (leafi.
PartunrCosmet.Aromes.89:81(1989);92.507oEugeniacaryophyllus(stem);
87.00% Pitnetrtadioic:q
100
8t)
60
40
20
Appendix III: Mass Spectla 375
RT:22.73 AI: 1357 KI: 1360 Nepetalactone <4aa,7u,7au->

CAS#:21651-62-7 MF: ClO H1402 FW: 166 MSD LIB#: I134
CN: cyfcopenta(c)pyran-
I (4aH)-one, 5,6,7,7a-tetrahydro-4,7-dirnerhyl-,(4aS-(
7a,7au))-
Synonyms: nepetalaclone.
cis.l"rans-
Source:Nepeta caesareaoil ex Husnu Baser
4l
1001l' 8l
80
60
40
20
40 60 80 r00
RT:22.74 AI: 1357 KI: 1360 Mentha-8-thiol-3-one<cis-p->

CAS#:33284-96-7 MF: ClOHl8 O S FW: 186 MSDLIB#:1636
CN: cyclohexanone,
2-(l -mercapto-
l -rnethylethyl)-5-methyl-,
cis-
Synonyms:none
100-.,11 6s
109
758t
153
t23
60 120
RT:22.74 AI: 1357 KI: 1360 Undecenal<(2E)->

CAS#:53448-07-0 MF: Cl I H20 O FW: 168 MSD LIB#: 2130
(2E)-
CN: 2-undecenal,
Svnonvms:none
Source:BedoukianRes.;5.607oCoriandrum sativum(leat), J. Ag. Food 38:20-54(
l990);
4.80VoCoriandrum sativum(plant); 0.20VoSideritiscondensata
.^ ^ 4I
t00 (cH2)7-cH3
376 Adanrs:EssentialOil Componentshy GC/MS
RT 22.77 AI: 13.58 KI: 1360 Silphiperfol-4,7(l4)-diene

CAS#: 210637-49-3 MF: Cl5 H22 FW: 202 MSD LIB#: 638
I ,3a,4,5,-5a,6,7,8-octahydro-2,3a,6-trimethyl-,
CN: cyclopenta(c)pentarlene, (3aS,-5aS,6R,8aS)-
| -methylene-,
Synonyms:silphipertbl-4,7(14)-dienc in Weyerstahlct al., Eur..I. Org. Chem. 1998,1205-1212.
Source:Echinopsgiganteusvar. le\'i, Weyerstahlet al' J' Org' Clrem', 1205-1212(1998)
t40 160 180
RT: 22.78 AI: l3-58 KI: 1361 Nonalactone<y'>

CAS#: l 04-61-0 MF: C9 H16 02 FW: I 56 MSD Llts#: l I 63
CN: 2(3H)-1uranone,dihdyro--5-pentyl-
Synonyms:apricolin;cocosaldehyde:prr-lnolide
Polianthestuberosa,.IEOR6;6-53(1994);
Sourcre:Pl'altz& Bauer ex Art Tucker; | .(107c
O.25VoZizspltus jujuba ll'uit; 0.097oO,smanthusJi'agratxs
RT: 22. 80 A I : l3- 59 Kl : l 3 6 l D e c e n o i ca c i d < 9 - >

CAS#: 14436-32-9 MF: Cl0 H18 02 FW: 170 MSDLIB#: 2070
CN: 9-decenoicacid
Synonyms:caproleicacid
AppendixIll: MassSpectra 377
RT: 22.81 AI: 1359 KI: l36l Neryl acetate

CA S #: l4l- 12- 8 MF : C l 2 H 2 0 0 2 F W : 196 MS D LIB #:996
CN: 2,6-octadien- l-ol, 3,7-dinrethyl-, acetate,(Z)-
Synonyrns:nolol acetate
S<rurce: Lemon oil, Lot'annOils; l -5.807o Alpinia chinensis,p. 333, in: Flav. & Fras.:
A World Persp.,Lawrcnceetal.(ecls.), Proc. lOth Inr..Cong.Ilss. Oils, Elsevi{, Amsterdam(1988);
7 .5A%,Cyn.bopogut cit ratus;'7.447oCitrus lirtton
69
80
60
40
20
RT: 22.83 AI: 1359 KI: 1362 Hvdroxvcitronellol

CAS#:107-14-4 MF: Cl0 H2202 FW: 174 MSDLIB#:825
CN: 1,7-octanediol,3,7-dimethyl-
Synonyrns:2.6-tlirnethyl-2,8-octanediol
80
60
4{)
20
t4l 159
f00 t20 140 t60i
I
t
i
RT: 22.89 AI: l3(rl KI: 1364 Damascenone <(Z)-F->

CAS#:-59739-63-8 MF: Cl3 Hl8 O FW: 190 MSDLIB#:-5-51
CN: 2-buten-
| -one,l -(2,6,6-trimethyl | -yl)-,(22)-
- 1,3-cyclohexadien-
Synonyrns:none
Source:Firmenischex.Iian-Qin Cu,Kunming
69
378 Adarrs: EssentialOil Componentsby GC/MS
RT:22.90 AI: l36l KI: 1363 Undecenol<10->

CAS#:l12-43-6 MF: Cl I H22 O FW: 170 MSD LIB#: 2074
CN: lO-unclecen-l-ol
Synonyms:none
Source:lledoukianRes.
RT: 22.93 AI: 1361 Kl: l364 Anisaldehyde<dirnethylacetal'p->

CAS#: 2186-92-1 MF: Cl0 Hl4 ()3 FW: 182 MSD LIts#: 1929
CN: benzene,| -(dimethoxynrethyl)-4-nrethoxy-
Synonyms:none
r00
80
60
40
20
100 120 140 160 r8 0
RT: 2-3.00 AI: 1363 KI: 1365 Methyl benzyl trutyrate <u'>
CAS#: 3.160-44-4 MF: Cl2 Hl6 02 FW: 192 MSD LIB#: 1663
CN: butanoicacid, I -phenylethylester
Synonyms:none
Source:Alclrich Chem.
Y)r-
o.
r00
80
60
40
RT: 23.02 AI: 1364 KI: 1366 Decanoic acid

CAS#:334-48-5 MF: Cf 0 H:2002 tsW:172 MSD LIB#: 2041
CN: decanoicacicl
Synonyms:capric acid; caprinic acid
OH
I
/\\(cH ,\B -cH 3
RT: 23.0-5 AI: 1364 KI: 1367 Mentholactone<cis->

CAS#: 68330-68-7 MF: ClO Hl8 ()2 FW: 170 MSD LIB#: 1078
CN: 2-oxepanone,4-methyl-7-(I -methylethyl)-,(4R, cis)-
Synonyms:none
Source:ret'.cpd. ex P. Weyerstahl
69 8l
r00
80
60
40
140 160 180
RT: 23.08 AI: 136-5 KI: 1367 Carvyl acetate<cis->

CAS#: 1205-42-l MF: C l 2 H I 8 C)2 FW: 194 MSD LIB#: 369
CN: 2-cyclohcxen-I -ol, 2-methyl-5-(I -rncthylethenyl)-,acetate,cis-
Synonyms: p-rnentha-6r, 8-dien-2-ol,ac:etate, ci s-
S<rurce:
SCM Chem.ex H. Hills; 2.007oMentha,spicata, Perf.Flav.-5:6(1980);
0.877oA bi es ernest i i; 0.507oCi st us lad aniferus
=
380 Adanrs:EssentialOil Componentsby GC/MS
RT:23.08 AI: 136.5KI: 1367 Undecenol <(28)->

CAS#:7.s039-84-8 MF: Cl I H22 O FW: l70 MSD Llll#: 2084
CN: 2-undecen-l
ll, (2E)-
Synonyms:none
t00 ,o/V(cH2)7-cH3
80
60
40
20
CAS#:110-41-8 MF: Cl2 H24O FW: 184 MSD LIB#: l-524

CN: undecanal, 2-methyl-
Synonyms:none
cHJ(cH2)BcH(cHu)c(=o)H
126 142
60 100 120 140
RT: 23.1I Al: 1366 KI: 13(r8 Hvdrocinnamvl acetate

CAS#:122-72-5 MF: Cl 1 Hl4 02 FW: 178 MSD LIB#: 445
CN: benzenepropanol,
acctate
S1'nonynrs:
3-phenylpropylacetate
Source:Cinnamonleaf oil. GreatAmericanHerb Co.
RT: 23.12 AI: 1366 KI: 1368 Piperitenone oxide r

CAS#:35178-.55-3 MF: ClO H1402 FW: 166 MSD LIB#: 1063i
CN: 7-oxabicyclo(4.
I.0)heptan-2one, 6-methyl-3-(1 -methylethylidene)-
Synonyms:p-menth-4(8)-en-3-one, 1,2-epoxy-
Source:Mentlmverticillata
oil ex M. Mafl-ei,ltaly;77.43a/o
Menthalongifolia,
FFJ3:23(1988);75.837oMenthasuaveolens; 37.25%Menthaspicata
RT: 23,1-5AI: 1366 Kl: 1369 Eugenol<dihydro->

CAS#:2785-87-1 MF: ClO Hl4 02 FW: 166 MSD LIB#: 697
CN: phenol,2-rnethoxy-4-propyl-
Synonyms: 4-propylguaiacol;
cerulignol;
coerulignol
Source:ref,cpd.ex E. vonRudlolT
A-
Y
O-Me
I
40 60 80 100 t20 140
RT:23.16 AI: 1367 KI: 1369 Furfuryl hexanoate

CAS#:39252-02-3 MF: Cl I Hl6 ()3 FTV:196 MSD LIB#: 84
CN: hexanoicacid,2-furanylmethyl
ester
Synonyms: none
Source:AldrichChem.
RT:23.19 AI: 1367 KI: 1370 Undecanol<n->

CAS#:l12-42-5 MF: Cl 1 H:24O I'W: 172 MSD LIB#: 28
CN: 1-undecanol
Synonyms:hendecanol
Source:rel'.cpcl.ex E. von Rudlofl'
cHs(cH2)1ooH
CAS#:-504-15-4 MF: C7 H8 02 FW: 124 MSDLIB#: 1226

CN: l,3-benzenediol, 5-methyl-
Synonyms:resc'rrcinol, 5-methyl-
100
80
60
40
\7 OH
20
40 60 80 r0 0
RT: 23.25 AI: 1369 KI: l37l Cyclosativene

CAS#:22469-52-9 MF:C1.5H24 FW: 204 MSD LIB#: .540
CN: l ,2,4-metheno- lH-indene,octahydro- I -rnethylethyl)-'
1,7a-dimethyl--5-(
( | S-(lo.2a,3ap,4u,5u,7ap,8S*))-
Synonyms:none
Source:ref. cpd. ex Larry Cool;0.797oPlutebeporosa,FFI 9:179(1994);
0.537oCroton elLrteriq
10t)
80
60
40
2(
RT: 23.32 AI: 1370 Kl: 1372 Carvacrolacetate

CAS#:6380-28-.5 MF: Cl2 Hl6 02 FIV: 192 MSD [.IB#: 36-5
CN: phenol,2-rnethyl-5-(
| -methylethyl)-,
acetate
Synonynrs:carvacrylacetate
Source:ref.cpd.ex GuyCollin
t00
80
60
40
20
r00 t20 t40 160
RT:23.33 AI: l37l KI: 1373 Methylp-anisate

CAS#:121-98-2 MF: C9 HlO ()3 F'W:166 MSD LIB#: 143
CN: bcnzoicacicl,4-nrethoxy-,
methylester
Synonynrs:
4-(rnethoxycarbonyl)anisole
Sourcc:
Staranisseedoil cx.Tian-QinCu
l 3.5
100
80
60
40
77
43 sp
100 120
RT: 23.3-5 AI: l37l KI: 1373 Mentholactone<trans->

CAS#:133267-3'7-5MF: Cl0 Hl8 C)2 FW; 170 MSD LIB#: I
CN: octanoicacid, 6Jrydroxy-3-methyl-7-methyl-,.epsilon.-lactone,
trans-
Synonyms:none
Source:ref. cpd. ex Weyerstahl
8t
121
=
RT:23.36 AI: 1371 KI: 1373 Mentha-8-thiol-3-one<trans-p->

C AS#: 3. 51l7- 8. 5- 2 M F :C l 0 H l 8 O S F IV: 1 8 6 MS D LIII#: 1637
CN: cyclohcxanone, 2-( l -rnercapto- (2S-tLans-)
l-methylethyl)--5-rncthyl-,
Synonyms:none
100
80
60
40
20
180
RT:23.37 AI: 1371 Kl: 1374 Longicyclene

C AS#: ll37- 12- 8 MF : C 1 .5H 2 4 F W:2 0 4 MS D LIR #: 1026
CN: | ,2,4-rnethenoazulene, decahydro- I S-(1u,2u,3aB,4u,8trp,0R"1r-
| ,-5,5,8a-tetramethyl-,(
Synonynrs: none
Source:FlukaChem.;0.65a/o Chamaect,parisus Ag. Biol. Chern.4-5:1497(1981);
obfitsa,.T.
0.427oPhoebe p o r osa; 0.01% Angeli ca a rchang elica
RT: 23.37 AI: l37l KI: 1374 Menth-6-en-2'8-tliol<trans-p'>

CAS#: 42370-11-2 MF: ClO Hl8 02 FW: 170 MSt) LIB#: 2009
| R,5S)-
| -methanol,-5-hyclroxy-u,o,4{rimcthyl-,(
CN: .3-cyclohcxcne-
Synonyms:soberol,trans-;trans-(r-hydroxy-a-terpineol
Source:Aldrich Chenr.ex JJ llrophy
RT: 23.38 Al:1372 KI:1374 Angustione

CAS#:641-ll-2 MF: Cl l Hl6 03 FW: 196 MSD LIB#: 264
CN: 1,3-cyclohexanedione,
2-acetyl-4,4,6-trimethyl-
Synonyms:none
Source:Backltousiaangustifuliaex.TJBrophy
98
40 60 t00 r60
RT:23.42 AI: 1373 KI: 1375 Benzeneacetonitrile<3-methoxy->

CAS#:19924-43-7 MF: C9 H9 N O FW: 147 MSD LIB#: 1798
CN: benzeneacetonitrile,
3-methoxy-
Synonyrns:
3-methylphenylacetonitrile,
3-methylbenzyl
cyanide
Source:Maceoil ex MarioTellez
Me-O
77
5l l 16
63 90 104
40 60 80 r00 t20
RT: 23.43 AI:1373 KI: 1375 Linalool isotrutanoate

CAS#:78-3-5-3 MF: Cl4 H24 02 FW:224 MSD LIB#:
CN: propanoicacid, 2-methyl-, l -ethenyl-l,-5-dimethyl-4-hexenyl
ester
Synonyms:linalool isobutyrate;linalyl isobutyrate
Source;K & K Chem.ex Art Tucker
93
69 80
121
224
180 200 220
386 Adams:l'.sscntial hy CC/MS
Oil Cornportetrts
R T:23. 43 A I : 1373 KI: 1 3 7 -5 Yl a trg e n e < a ' >

CAS#: 14912-44-8 MF: Cl-5 H24 FW: 204 MSD LIB#: 404
CN: tricyclo(4.4.0.02,7)dec-3-ene, I ,3-climethyl-8-( l -nrethylethyl)-'
stereoisomer
Synonyrns: NOT= o-copaene as listcdin somesources!
(leaD,
Ssurce:Cedrelaodorota oil ex l)ragoco ex E-.f. Brunke; 7.83%,Psidiutn.fiieclricltthali.an.um
JHOR7:187(1995):6.20%Artemisiaamrua;3.32% Canella wirtterarn
RT: 23.45 Al: 1373 KI: 1375 Isosafrole <(E)->

CAS#:4043-71-4 MF: Cl0 Hl0 O2 FW: 162 MSDLIB#: 887
(E)-
-5-(l-propenyl)-,
CN: 1.3-henzodioxole,
Synonyms: none
Sourse:AldrichChem.
q
160
R T: 23. - 18 A l: 1314 KI: 1 3 7 6 Is o l e d e n e

CAS#: 95910--16-4 MF: Cl5 H2't trW: 204 MSD LIB#: 866
CN: lH-cycl<4rrop(e)azulene, 1a,2.3,4.5.6,7,7b-octahydro-l'1,4,7-tetrarnethyl-,
( I aR-(I au,4a.7a,7bs))-
Synonyms:none
Source:FlukaChcm.
RT: 23.49 AI: 1374 KI: 1376 Copaene

<u->
CAS#:38-56-2.5-5 MF: Cl5 H24 FW: 204 MSD LIB#: 828
CN:tricyclo(4.4.0.02,7)dec-3-ene, 1,3-dimethyl-8-(l-rnethylethyl)-,
srereoisonrer
Synonynrs:aglaiene
Source:H),menaeaoil ex.IeanLangenheim:20.737oCopaiferafficinalis, :
Journalof High ResolutionChromatographyl8:54(1995); 15.607oCedrelao&trata;
| 5 .507oD acry odes ig agang a (frvtt)
r00 !l
80
(Y>"$"\
60
40
20
CAS#:92-52-4 MF :C l 2 H l O F W : 154 MSD LIB#: 295

CN: l, l' - bipheny l
Synonyms:bibenzene; diphenyl;phenylbenzene
t00
8(
60
40
r3 9
140
RT: 23.52 AI: 137-5 Kl1371 Decane<1,1-dimethoxy->

CAS#: 7779-41-l MF': Cl2 H2602 FW:202 MSD LIts#: -570
CN: decanal,l,l,dimethoxy-
Synonyms:dimethyl acetalclecanal
388 Aclarns:EssentialOil Cornponentsby GC/MS
RT: 23.55 Al: 1316 Kl 13'77 Ethyl cinnamate <(Z)->

CAS#: 4610-69-9 MF: Cl I Hl2 02 FW: l7(r MSD LII]#: 201
CN: 2-propenoicacid,3-phenyl-,ethyl ester, (Z)-
Synonyn.rs:
ethyl cis-cinnanrate
Source:Artemisiajudlca oil ex Z. Fleisher;'7.807oArtemisiajudaica (Israel),
.IEOR2:271(1990);4.44%Artentisia.iudaica(Egypt);0.3Jo/oElaeagnusangustffitlia
RT: 23.5.5AI: 1376 KI: 1371 Ionol <u-(E)->

CAS#:25312-34-9 MF: Cl3 H22O FW: 194 MSD LIII#: 1957
l -yl)-,(38)-
1-(2,6,(t-trimethyl-2-cyclohcxen-
CN: 3-buten-2-ol,
Synonynrs:none
Source:Bedoukian Brophy
Res.ex.I.T
t40 160
RT: 23.-58 AI: 1376 KI: | 378 Methyl cinnamate<(E)'>

CAS#: 1151-62-7 MF: ClO Hl(l 02 FW: 162 MSD LIB#: 267
CN: 2-propenoicacid,3-phenyl-,nrethylester,(L')-
Synonynrs: trans-cinnamic acid,rnetlrylester
Source:distillationof basil leavesex McCttrmickCo., RP Adams#-543-5;
66.50a/oOci mum basiIi c'um, FFJ I :53( I 986); 45.50'k L1't'asre o romat i ca;
7 .80VoNarcissusjonquilla
100
80
60
40
20
q
Appcntlixlll: MassSpectra 389
RT : 23. 61 A I : 1 3 7 7 Kl : 1 .1 7 9 Si l p h i p e rfo l-6-ene

CAS#: 71284-56-3 MF: Cl.5 H24 FW: 204 MSI) LB#: 639
CN: c1'clopenta(c);rcntalcne, I.2,3,3a,4,"5.-5a,(r-octahydro-3,-5a,7.8-tetramcrhyl-,(3R.3aS.-5aS,8aS)-
Synonyrns:silplrilrcrlirlene
Source:Ecltinoltosgiganteusoil cx P. Wcyclstahl
l( x)
80
60
40
20
R'f : 23.(r-5 Al: | 378 Kl: | -lflO Allvl nonanoate

CAS#: 1493-72-3 MF: C I 2 lI22 02 FW: 198 MSI) LIB#: l l-3
CN: nonarroicacicl.2-propernyl estcr"
Synorrynrs: allyl pelargonatc
Source:AlclrichChent.ex Alt Tucker
(cHrrc H3
y'.,,-/"\\y,,,,
8( tl
o
60
40
20
RT: 23.(15 AI: 1378 KI: 1380 Hexenyl hexanoate<(32)->

CA S #: . 11. 501-l l -8 MF : C l 2 H 2 2 0 2 F W: 198 MS I) Ll tt#:2042
CN: hc x anoicaci d .(3 2 )-3 -h e x e n ycls tc r
Syrronyurs: cis-3Jrcxenylcapro.rtc:
Sotrcc: BcrloukianRes.:(r.(r-57o Pa.s.si.fl.ora
edttli.r,p.2l9, in: ArontaticPlants& Essential
Cltrnstitttcrtts.PeaceBook Co., Hon-uKong(| 99.1);0.10(1,Nort:isstt.s (absolute):
ltoetic:rt.s
O.I O'/a rl verrln o bi Ii nrbi ( l'r"uitt
o
tl
-\,,/7-\.,'-\o 1cu,1o.*r.
E_
RT: 23.66 AI: 1378 KI: 1380 Cournarin <3'4-dihydro->

CAS#: I 19- 84- 6 M F : C 9 H 8 ()2 FW: 148 MS D LIR #:475
CN: 2H- | -benzopyran-2-one, 3,4-dihydro-
Synonyms:2-chrontanone; rnelitotin(counrarin);
nrelilotol
Source:Alclrich Chem.
t00
80
60
4t)
t20
RT: 23.67 AI: 1378 Kl: 1380 Jasmone<dihydro->

CAS#: I 128- 08- l M F ' :C l I H l 8 O F W: 1 6 6 MS D I-l B #: 19.58
gfrf; l-cyclt)penten-| -one, 3-methyl-2-pentyl-
S1'nonynrs: none
Source:BedoukianRes.ex.I.TBrophy
il
r6 0
R T: 23. 69 A I : 1379 K I: 1 3 8 0 D i c ta mn o l< 8 -e p i ->

CAS#: 195259- 16- 2 M F :C l 2 H l 8 O F W: 1 7 8 MS D LIB #: l 4fi
CN: I -azufenol, 1,2,3,3a,4,-5,6,8a-octahyclro-l -methyl-4-methylene-,( lR,3aR'8aS)
S1'nonyrns: none
Source:Antyrisdiatrl,;ta leaves,ex Tom Zanoni, Dom. Rep.
RT: 23.70 Al: 1379 KI: l38l Geranylacetate

CAS#:10-5-87-3 MF: C12H2O02 FW: 196 MSD LIB#: 990
CN: 2,6-octadien- (E)-
I -ol, 3,7-dimethyl-,acetate,
Synonyms: geraniol acetate
Source:Neroiloil ex Firmenisch ex AF Thomas;7 | .38Vo
Elsholtz.ia
blanda,
JEOR4: I 2 1( 1992);7.807oDracocephalum moldavica, 36.407oS&lviasclare
RT: 23.70 AI:1379 KI: 1381 Patchoulene<p->

i
{
CAS#: 514-51-2 MF: Cl5 H24 F-!V:204 MSD LIB#: 1240 |
CN: 4,7-methanoazulene, ,8-octahydro-I ,4,9,9-tetramethyl-,(
| ,2,3,4,5,6,7 I S-(! o ,4a,7u))-
S y nony m snone
: i
Source:Patchoulioil ex Firmenischex AF Thomas; 13.007oPogostemoncabflin,
Atlas of EssentialOils, S. Srinivas(1986);4.207oPsiadia viscosq.:, I
0J07o Nardostacltl'sjatantansi ;
t00
80
60
40
20
RT: 23.73 AI: 1380 KI: 1381 Nonadienal<diethylacetal-(28,62)->

CAS#:67674-36-6 MF:Cl3 H2402 FW:212 MSDLIB#:2ll8
CN: 2,6-nonadiene,l, I -diethoxy-(28,62)-
Synonyms:none
Source:BedoukianRes,
r3J13
R T:2 3 . 74 A I : 1380 K I: 1 3 8 1 An i s o l e

CAS#: 186. 57- 09- . 5 MF :C l l H l 4 O F W: 1 6 2 MS D LIB #: l 8-59
CN: henzene, l-(1E)-1-butcnyl-4 nrcthoxy-
Synonyms:Anisole.p- l -butenyl-,(E)-
ScruLce: Amonutntuliginosumex .T.lBrophy
(ff
vl.tl.V
RT:2 3 . 74 A I : 1380 K I: l 3 8 l D a u c e n e
CAS#: I 6661- 00- 0 M F : C l 5 H 2 4 F W:2 0 4 MS D LIB #;363
CN: azulene,I ,2,4,-5,8,8a-hexahydro-6,8a-dinrethyl-3-( I -methylethyl)-
Synonynrs: none
Sourc.e: Carrotseedoil ex A. Chainteau, Nestle;3.507oDaucu,scarota (leaf),
Proc. 1 lth lntl. Cong.of liss. Oils, FFJ.4:173(19t19); 1.007nDatr<'uscarcta (seed)
100
80
60
10
20
t60 t80
RT:23.7.5AI: 1380 KI: 1382 Anisylmethylketone

CAS#:122-84-9 MF: ClO H1202 trW: 164 MSD LIB#: 1649
CN: 2-propanone,l-(4-nrcthoxyphcnyl)-
S1'nonyms:anisketone,
anisalacatone, 1-(4-methoxyphenyl)->
2-propanone<
Sonrce:AldrichClrem.
100
8{)
60
A
A
Y
4tl
20
./o
RT: 23.7.5AI: 1380 KI: 1382 Ethyl-(48)-decenoate

CN: 4-dccenoicacid, ethyl ester,(R)-
Synonynrs:ethyl trans-4-decenoate
Source:BedoukianRes.ex Art Tucker'
4l
I
(cH2)4-cH3
t2 3 ' i. 1 0 ,
RT: 23.75 AI: 1380 KI: 1382 Funebrene

<2-epi-a->
CAS#:6-53-54-33-8MF: Cl-5H24 FW: 204 MSD LIB#: 1927
CN: lH-3a,7-methanoazulene,2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-
(3R-(3o,3aB,7F,8aF))-
Synonyms:none
Source:Lomatium rigidunt ex Vasu Dev
RT:23.7-5AI: 1380 KI: 1382 Thujic acid

CAS#:499-89-8 MF: C l0 Hlz 02 FW: 164 MSD LIB#: 18-50
CN: 1,3,6-cycloheptatriene-l-carboxylic
acid,5,-5-dimethyl-
Synonyms: none
Source:Thujaplicatawoodoil, SeattleLbr. Co.,RP Adams#8012
t49
C=
t00
80
60
40
51 59
E
391 by GC/MS
RT:23.11 Al: l38l KI: 1382 Phenyl-4-methyl-pentan-3-one <l'>

CAS#: 40463-09-0 MF: C 12 H l6 O FW: 176 MSD LIB#: l20
CN: 3-pentanone,4-nrcthyl-| -phenyl-
Synonynrs:2-rnethyl--5-pcntyl-3-pentanone
Source:Amontyrtusnre.lioil ex P. Weyerstahl
tl
ry
v
RT:23.78 Al: 1381 KI: 1382 Ethyl2-nonynoate
CAS#:10031-92-2 MF: Cll Hl8 02 FW: 182 MSD LIB#: 662
CN: 2-nonynoic
acid,ethylester'
ethyloctinecarbonate
Synonyrns:
(cH2)5-cH3
R T: 2- 1. 78 A I : 138 1 KI: 1 3 8 2 Pa n a s i n s e n<ep - >

CAS #: . 56684- 97- 0 M F : C l -5H 2 4 F W:2 04 MS D LIB #: 1232
CN: cyckrbut(c)inclene, decahydro-2,2,4a-tlinrethyl-8-rnethylene-,(2aS,4aR,8aR)-
S1'nonynrs: none
Source;ref. cpd.ex P. Weyerstahl;8.007oPanaxginseng;Bull. Chem.Soc..Tapan 48:2078(197-5)
4l
l00r r'
)\*'
40
20
(Ai =
t20 140 160 180

Appendixlll: MassSpectra .JYJ
RT:23.80 AI: 1381 KI: 1383 Angustione <dehydro->

CAS#:4717-6'7-3 MF: Cl1H14()3 F-W:194 MSDLIB#:265
CN: 4-cyclolrexene-
1,3-dione,
2-acetyl-4,6,6-trirnethyl-
Synonyms: none
Strurce:
Backhousi.a
angustfoliaex JJBrophy
60
40
L\
RT:23.81 AI: l38l KI: 1383 Skatole

CAS#:83-34-l MF-:C9 H9 N FW: l3l MSD LIB#: 1416
CN: I H-inclolc,
3-rnetlryl-
Synonynrs:3-rnethyl
indole
Source:AldrichChem.ex H Hills
t0(
8(
60
4(
20
RT: 2.3.83 AI: l3U2 KI: 1383 Hexyl hexanoate

CAS#: 6378-6-5-0 MF': Cl2H24 02 FW: 200 MSD LIB#: 188
CN: hcxanoicacid,hexyl ester
Synonynrs:hcxyl caproate
Sotrrce
: clistillationo1'reddelicioustrpples,RP Adams#5756; l6.69VoPassiflrtraedulis,
p.219, in: At'otnaticPlants& EssentialConstitucnts, PeaceIJookCo., Hong Kong(1993);
0.25% H erat:leunl p Iatytct.en
i um; 0.227oM arrd rag o ra r1fficin aru nt
r 00 cHJ(cH2)s-o-c(=gxsx2)acnt
80
60
40
20
396 Adams:EssentialC)il Componentsby GC/MS
j
RT: 23.83 AI: 1382 KI: 1383 Nlodheph-2-ene
CAS#: 68269-87-4 MF:Cl5 H24 FW: 204 MSD LIII#: 64t)
CN: I H,4H-3a,6a-propanopentalene, l
-5'6-dihydrO-, 1,3,4-tetramethyl-.(3aR'4R,6aS)-
Synonynrs:modhcphene
Source:Echino;tosgiganteusoil ex P. Weyerstahl
<(32)->
RT: 23.86 AI: 1383 Kl: 1384 Hexenyl-(32)-hexenoate
CN: 3-hexenoicacid,(32)-3-hexenylester,(32)-
Synonynrs:none
RT: 2-1.87Al: 1383 KI: 1384 Damascenone <(E)-p'>

CAS#:?3126-93-4 MF: Cl3 Hl8 O FW: 190 MSDLIB#:552
CN: 2-butcn-l-one,I -(2,6.6-trirnethyl- l-yl)-' (E)-
1,3-cyclohexadien-
Synonyms: trans-B-darnasccnonc
Source: ex.lian-Qin
F-irmenisch Cu,Kunming
69
,2, ff
RT: 23.88 AI: 1383 KI: 1384 Isotrornylpropanoate

CAS#:2756-56-1 MF':C13H2202 FW: 210 MSD LIB#: 1443 ,
CN: bicyclo(2.2.l)heptan-2-ol,1,7,1-trimethyI-, propanoare,exo-
Synonyms: propionate
isoborneol
Source:Strobil,anthus auriculott.ts
oil ex P. Weyerstahl;0.70Vo Strobilanthes
auriculotus,
p. 5(:7, in: Flav.& Frag.:A WorldPersp,, Lawrence, etal.,Elsevier
Amsterdam(1988);
0.307oOnnenis mixta;0.067oChenopodi um anrhrosioides
'Y''6-
Ii.T:23.97 AI: 1385 KI: 1386 Myrtanol acetate <trans->
CAS#: 90934-53-5 MF; Cl2 H20 02 FW: 196 MSD LIB#: I126
CN: bicyclo(3.| .l )lieptane-2-methanol,
6,6-dimethyl-,acetate,(I S-(| o,2a,5u))-
Synonyms:uone
Source:acetylationof myrtanol (6428);
O-Ac
)=t
RT: 23.98 AI: 1385 KI: 1386 Nonalactone<6->
CAS#: 3301-94-8 MF: C9 Hl6 02 FW: 1-56 MSD LIB#: | 164
CN: 2H-pyran-2-one,6-butyltetrahydro-
Synonyms:nonan-l,-5-olicle
Scrurce:ref. cpd. ex P. Weyerstahl;0.0 | VoJasmhntntpolyanrT'rru,r,
DragocoRept. 5-2 | ( | 996)
.=
:t
I
398 by GC/MS
Adarns:EssentialOil Components -
RT: 23.99 AI: 138-5 KI: 1387 Hexenyl caproate<(28)->

CAS #:. 53398- 86- 0 MF : C l 2 H 2 2 0 2 FW: 198 MS D LIB #: 2031
CN: hexanoicacid,(2E)-2-hexenyl ester
Synonynrs:none
RT: 24.00 AI: 1386 KI: 1387 Darnascone <(Z)-F->

CAS#:23126-92-3 MF: C 13 H20 O FW: 192 MSD LIB#: .5.53
CN: 2-buten-
I -one,1 l
-(2,6,6-trimethyl- | -yl)-,(Z)-
-cyclohexen-
Synonyrns:none
Source: ex.Tian-Qin
Firn'renisch Cu,Kunming
100 120
RT: 24.00 AI: 1386 KI: 1387 Nepetalactone<4au,7a,7aP->

CAS#: 000-00-0 MF: Cl0 Hl4 02 FIM: 166 MSD LIB#: | 136
CN: not assigned
Synonyms:nonc
Source:Nepetacqesareaoil ex Husnu Baser
4l
100
80
60
4{')
20
Appcndix lll: Mass Spectra 399
RT: 24.01 AI: 1386 KI: 1387 Isobutylphenylacetate

CAS#:102-13-6 MF: Cl2 Hl6OZ FW: 192 MSD LIB#: 1616
CN: benzeneaceticacid,2-methylpropyl
ester
Synonyms: isobutyls.-toluate
A"
o
RT: 24.03 AI: 1386 KI: 1388 Octenolbutanoate<(2E)->
CAS#:84642-60-4 MF: Cl2 H2202 F'W:198 MSD LIB#: 2080
CN: butanoicacid,(2E)-2-octenylester
Synonyms:none
Source:BetloukianRes.
j
\
RT: 24.04 AI: 1387 KI: 1388 Cubebene <p-> i
CAS#:13744-15-5 MF: Cl-5H24 FW: 204 MSD LIB#:468 i
CN: I H-cyclopenta(
I ,3)cyclopropa(
1,2)henzene,
octahydro-7-methyl-3-methfene-4-(
I-
(3aS-(3ao,3bB,4B,7a,7aS*))-
nrcthylethyl)-, t
Synonyms: none i
Source:Copaihaoil ex Natl.Geo.Soc.expedition;39.007a
Melissafficinalisl
FFJ3:167(1988);32.0OVo Lippiacarviodoravar.
minor;14.8O7oLippiaukampensis
-
RT: 24.05 AI: 1387 KI: 1388 Bourbonene <p->

CAS#:5208-.59-3 MF:Ct.5 f{24 F'W:204 MSD LIll#: 653
CN: cyclobuta(l decahydro-3a-methyl-6-rnethylene-1-(l-rnethylethyl)-,
,2:3,4ltlicyclopentene,
( | S-(| u,3au,3hp,6ap.6bu))-
Synonyms: nrue
Source:Elsholtz.ia cristataex I)r. Vostr"owsky Origanumvulgare,
Jurtipentsl.ucs1y6n6;4.30o/a
FlavourInd.,4;481(1973);3.647a Menthalongifolia;3.507o laeviSatt,utr
Origanurtt
t00
80
60
40
120 t40 160 t80
RT: 24.0-5AI: 1387 KI: 1388 Isocomene <u->

I ,2,3,3,5A,6,7,8-octahydlo-
CN: cyclopenta(c)pentalene, | R-(I a,3au,5aB,8aR*))-
I ,3a,4,-5a-tetranrelhyl-,(
Synonyms:bcrkheyaradulene
Artemisiaarlrutatooloil ex HJ Woerdenbag
Scrurce:
t00 t20 140 160 180
RT: 24.07 AI: 1387 KI: 1388 Duprezianene<o->

CAS#: 79801-29-9 MF: Cl.5 H24 FW: 204 MSD LIB#: 960
e, | ,2,3,6,7
CN: 3a.6-ethano-3aH-inden (3R,3aS,65,7aS)-
,Ja-hexahydro-3,-5,7,7-tetramethyl-,
Synonyms:none
Source:Jurtiperusthurifera wood oil, Junicedrcllfraction,AF Barrero,Spain
100
80
60
40
20
t60 180
RT: 24.09 AI: 1388 KI: 1389 Methyl decyl ketone (=2-dodecanone)
CAS#: 6175-49-l MF: Cl2 H24 O FW: 184 MSD LIB#: 2192
CN: 2-dodecanone
Synonyms:dodecanone,2-
41 o
l00r
80
i-
tl
,,n,"*r,n-.r.
60
4
20
RT: 24.10 AI: 1388 KI: 1389 Cinnamylacetate<(Z)->

CAS#:77134-01-l MF':Cl I Hl2 02 FW: 176 MSD LIB#:446
CN: 2-prcrpcn- (Z)-
l-ol, 3-phenyl-,acetate,
Synonyms:cis-cinnamylacetate
Source:Pfaltz & Bauer ex H. Hills
41
l0 0 r I
100 t20
RT : 24. 10 A I : 1 3 8 8 KI: 1 3 8 9 T e tra d e c e n e<1->

CA S #: 1120- 36- l MF : C l 4 H 2 8 F W: 196 MS D LIB #:
CN: tctradecene (l -)
Svnonvms:none
Source:Olelinsmix ex Aldrich & SismaChem.
100.11
HrC=CH(CH2)1
1cn,
80
60
40
20
140 tS4 168
OFESSTNTIAL
IDENTIFICATION OILCOMPONTNTS
ByGASCH RAPHY/II,IASS
RoMAToG SPtCTRot'Jl
ETRY
4THEDITION
Thisisthefourthedition 0nmoss ondrelenlion

speclro limesofcommon componenls
inplonlessenliol fromfte previous
oils.lt differs editions
inseverolimporfonl
oreos:
600compounds hovebeen odded,thesources
oforiginolionforeochcompoundore
listed,
themossspeclro orelorger lo reod,oc(urren(e
ondeosier nolureinformolion
is
nowincluded,ondoll2,205compounds hoveheenonolyzed fromtheiroriginol
sour(es
ononHP597l MSD mosspeclromeler HP(hem$olion
using softwore.
Inoddilion,
thelibrory(including
relenlion limes)isnowovoilobleforlhemo$(ommon moss
speclromeler/compuler syslems.
The lhirdedition
ofDrAdomt book presents
overyusefulcompilolion ofover
I 600mosspeclro oflerpenes,oliphoilc hydrocorbons,
eslers, oromolicsondother
compounds encounleredinnolurolproducfs
chemislry,
especiolly
fte chemistry
of
oils.Nolonlyorelhemoss
essenliol given
speclro bullhecompoundt Refenlion
Index onlhecommonly used
DB-5 glccolumnoreincluded.There ofthe
oreindices
RelenlionIndexorronged ondinRelenlion
botholphobeficolly Index moking
order,
il overyproclicol
foolforuseinnolurolproducbreseorch.I hovefound thiswork
extremely inmyworkinnolural
useful producfs
chemislry.
- J.J.Brophy, Universify
ofNew SoulhWoles.

Identification Essential Oil by Gc-Ms - Robert Adam1

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Identification Essential Oil by Gc-Ms - Robert Adam1

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Copyright:

IDEI{TTFICATION OF

Dr. ROBERT P. ADAMS

Allured Putrlishing Corporation

Copyright2007- All RightsReserved

PART A GAS CHROMATOGRAPH/MASS SPECTROSCOPY

L AlphabeticalListing of Compoundswith rheir Retention

This is the foLrrtheditionon rllassspectraatrdretentiorrtirnesof corlrnon cornponents in plarrt

Changesirt technologyallorvus to tttaketlrisavailablertorv. For instance. rvherrI beganresearch orr

This book is an outgror,vth of the previousbooks(lclentitication of EssentialOils by lon Trap Mass

I orvea specialdebtof thanksto colleagues rvho Lrnselfishly

Finally, I would like to tlrarrkmy wife, Janice,for her patienceand encouragement.

Thc utilization ol'thc essctttial ttils ol'plants is rviclesprcacl,ran-cin-glxrrn

, E 1 lstcincta|'.l9 76 ) u' ' it lr it s nt ln_|r c r r c l_t ir . t

phlsi<lltrg ica litna ly s c s t ll. s eas t lt lalalr c |c c |a1lhic |i l c t <l r . s i n c o n l t t t c r c i a l s 1 r i c e a n t | e s s e n t i a l c t . r l p s ) n t a y

' e\\cntia l oils.

.nr llatch(o llatch(.| c llnin. es . l9871. G il' c nr epr . oc lt r c i l l l c t . c t c t l t i t l t t t i n l c s 't | r c

' ll1|1()llclllsisptrss it r |elr y t . c t c r r t it lnt ilr t c / t r r as s Sp e c t t . o l l l c t f y / c t l t r l 1 l u l c r s c a l . c h i n g

Even moreconl'usingfbr (E)-caryophyllene ("p-caryophyllcne"):The cloublebond in the a positionresultsin the nameof

III. MASS SPECTROMETRY CONSIDERATIONS

A. Obtaining Quality Spectra for Identification

talgettune,with targettttnevaluesof M69 - lOOVol

!*tl r0s 5[r

Oxyg en attclr,r'ater c anSeVc l. c |y af f . ec t t hel} laSS S l ] e C t | . ( ) n t c t c r . l r t r t h i n t I r c c 1 u a | i t y ( ) l - s p e ( ] t f a t r b t i r i n e c l a t r t l i tl p e l l l a l l cl l l

lirrairan c|wa [cl'.Be c lt t Sc c v c llt |r c ht lndc d1r has c 1r t r | a r . c t r | t t l t t n s a r c t | e g l . a d c c |

B. Tlre Role of Retention Tinres in Library Searches

B ccitttscttncc1 triv oc ir |ic |c r r 1i|ic t r t it r nt t |' s t lt lt c t e t . p c n r l i t | s c a | r | 1 0 t b y r r r a c l c t r n {h c b i r s i s r r l . t l r e l i

.i. 62thtricnc<Cx'->).Thus . 5' ( l2is t hc r c t c nt it r nt int c in l t t i t r t r n D B . 5 . . ] ( ) l l l . t c | l 1 l ) c | . a t t t f c l l ( ) g | l l l ] ] l l ]

tr.nErillE'-'f 5 :iil tf 5.E41ilrirr..LElllli5l ri t' {-)

F i.ctrrc2 'Lib r.arys c ar c hlilr . a- lht r jc nc ll. t lt lt lc lt r t ln r l i | ( t t l p ') \ 's . t I - l h l , c n e

' ' r llre HP Cltcln s t at it lr r ( Hewlc t t - Pac k alc l.

Avef age ol 8.657to 8.8F5min.:LE['1I154S7.8

Figure 3. Libraty searchfor unknown and lnatch to library litnonene

IV. OPERATING CONDITIONS USED FOR SPECTRA ACQUISITION

V. CONIPATII}II-TY WITH NIASSSPECTRONIETER DA'I'A SYSTENIS

3B?9448:17 fl lrrl il Lr,llJrf I lt l:t td., 5,:dnlllT lZirlS) ff r'l:,ti2:r_r5,r'fl

Figure4. MassFildersearchpageshowingthe iilentificationof E-cadinene: the middlesectionclisplaysthe previotrs,cuffent,

VI. EXPLANATIONS OF FORMATS USED IN APPENDICES

Both AI anclKI inclicesare presentcdfof eachcompounclin Appendix III.

RT..............AI......KI..... Common name............

AI: = A r it hlnet icin c l e xo rrD B --5i n r.e l ' c r.e nto

C tr nr t r r on|la|lle= C tl tl tl n tl n n a trtc .tc n c l .a | | ),ttset| (rl | .ctl ttrsc.

CAS# = ChcrrricalAbstractsScrvicc rcl'et'cncc

NISD Libr# = HP MSD libr.arycnrry nunrtrcr(the librrry is ar,ailal"rlc

CN = Chcrnicalor syslglltalicnar.ncuscd lry ChcrDicalAl'rstracts

SYNONYN{S = S)'trtlnylllslill thc cotllttl()ttnatttc. Sotttc ol'thcse arc various pernru(ations

lcr. 1lin ctll.c,l.r-/rlttlt . l. - s abinc nc hy c |r . at es . L] t c . ) . A s | r r r a s p o s s i h | e . t h o C A S S y s t e n l i s l o | l o r l . c c | a n t l n o t o t l

SOURCE = Sorttcc of the cotttpottnclttsccllil'thc analysis. plus othcl natural s()pr.cec

A;tp cn dir IV lisls all lhc s Ynony llr slt nd c r os s - r c l c 'r c n c c s( h c s y l r o n y n r s( o l l r c

A tIattts.R.P.l97 ().Seas t lt t alr . ar . iat it lt t t r l. t c r 1lc r lt li c | c t r t l s t i t u c n t s

de Planta,sdo Nordeste,EdicoesUFC, Fortalez'a,Btazil

ALPHABETICAL LISTING OF COMPOUNDSWITH

CommonName RT Conrmon Name RT AI

CornmonNatte RT Conrmon Narne RT AI ru

C otttttto ltNulu c RT AI Comrnon Nirnre RT AI

Ctlmntcrn Name RT AI Common Name RT Al

Conrnron Naue RT AI Connron Naure RT AI

Comnron Nanre RT Comrnon Narue RT

(lonrnou Narnc RT AI Cotnr.rron Narne RT AI

CornrnonName RT Al Cornmon Narne RT AI

Clonrrlon Nanrc RT AI CumrnonNanre RT AI

Cont nro n N l r n e RT Conrrnon Name RT Al

(lrnrntrn Nanrc RT Al ContnronNarrrc RT AI

ConrrnonNanre RT Al Conrnron Nanre RlI Al

Conrnron Nanrc RT AI Common Nalne RT AI

Cornrrlrn Narne RT ConrnronNanre RT Al

ComrnonName RT AI Common Namc RT AI