CALCULO DE LA PRESION DE VAPOR PARA SUSTANCIAS PURAS

ECUACION DE ANTOINE

log10 Pvap = A - [B / (T °C + C)] bar

T= 50 °C <---- Ingrese temperatura

No. = 33 <---- Ingrese No. de Sustancia

Sustancia = Estireno C8H8

A B C
Constantes =

Valor Calculado: Pvap = ND bar

BASE DE DATOS
Ref: POLING, BRUCE; PRAUSNITZ, JOHN & O'CONNELL, JOHN.
"The Properties of Gases and Liquids". 5th edition. McGraw Hill. New York. 2001

No. SUSTANCIA FORMULA A B C

1 Metano CH4 3.76870 395.744 266.681
2 Etano C2H6 3.95405 663.720 256.681
3 Propano C3H8 3.92828 803.997 247.040
4 n-Butano C4H10 3.93266 935.773 238.789
5 n-Pentano C5H12 3.97786 1064.840 232.014
6 n-Hexano C6H14 4.00139 1170.875 224.317
7 n-Heptano C7H16 4.02023 1263.909 216.432
8 n-Octano C8H18 4.05075 1356.360 209.635
9 n-Nonano C9H20 4.07356 1438.030 202.694
10 Isobutano C4H10 4.00272 947.540 248.870
11 Isoctano C8H18 4.03877 1335.220 213.415
12 Ciclopentano C5H10 4.06783 1152.574 234.510
13 Ciclohexano C6H12 3.93002 1182.774 220.618
14 Metilciclopentano C6H12 4.18199 1295.543 238.390
15 Metilciclohexano C7H14 3.98232 1290.968 223.701
16 Etileno C2H4 3.91382 596.526 256.370
17 Propileno C3H6 3.95606 789.624 247.580
18 1-Buteno C4H8 3.91780 908.800 238.540
19 cis-2-Buteno C4H8 4.00958 967.320 237.873
20 trans-2-Buteno C4H8 4.00827 967.500 240.840
21 1-Hexeno C6H12 4.18199 1295.543 238.390
22 Isobutileno C4H8 3.80956 866.250 234.640
23 1,3-Butadieno C4H6 3.96640 927.210 238.630
24 Ciclohexeno C6H10
25 Acetileno C2H2 3.67374 528.670 228.790
26 Benceno C6H6 3.98523 1184.240 217.572
27 Tolueno C7H8 4.05004 1327.620 217.625
28 Etilbenceno C8H10 4.06861 1415.770 212.300
29 Cumeno C9H12 4.06112 1460.766 207.830
30 o-Xileno C8H10 4.09789 1458.706 212.041
31 m-Xileno C8H10 4.14051 1468.703 216.120
32 p-Xileno C8H10 4.10494 1446.832 214.627
33 Estireno C8H8
34 Naftaleno C10H8 4.13555 1733.710 201.859
35 Bifenilo C12H10 4.18870 1841.480 185.150
36 Formaldehido CH20
37 Acetaldehido C2H40
38 Acetato de Metilo C3H6O2 4.18621 1156.430 219.690
39 Acetato de Etilo C4H8O2 4.13361 1195.130 212.470
40 Acetona C3H6O 4.21840 1197.010 228.060
41 Metil Etil Cetona C4H8O 4.13860 1232.630 218.690
42 Eter dietílico C4H10O 4.10962 1090.640 231.200
43 Eter metil t-butílico C5H12O 3.83648 1052.470 210.880
44 Metanol CH4O 5.20277 1580.080 239.500
45 Etanol C2H6O 5.33675 1648.220 230.918
46 1-Propanol C3H8O 4.99991 1512.940 205.807
47 1-Butanol C4H10O 4.64930 1395.140 182.739
48 1-Hexanol C6H14O 4.18948 1295.590 152.510
49 2-Propanol C3H8O 5.24268 1580.920 219.610
50 Fenol C6H6O 4.26960 1523.420 175.400
51 Etilenglicol C2H6O2
52 Acido Acético C2H4O2 4.54456 1555.120 224.650
53 Acido n-butírico C4H8O2 4.82340 1731.708 195.955
54 Acido Benzoico C7H6O2
55 Acetonitrilo C2H3N
56 Metilamina CH5N 4.54420 1050.660 237.830
57 Etilamina C2H7N 4.43400 1102.880 232.450
58 Nitrometano CH3NO2
59 Tetracloruro de carbono CCl4 4.10445 1265.632 232.148
60 Cloroformo CHCl3 3.96288 1106.904 218.552
61 Diclorometano CH2Cl2 4.07622 1070.070 223.240
62 Cloruro de metilo CH3Cl 4.16533 920.860 245.580
63 Cloruro de etilo C2H5Cl 4.09088 1020.630 237.570
64 Clorobenceno C6H5Cl 4.02012 1378.790 211.700
65 Argón Ar 3.74141 304.227 267.320
66 Kriptón Kr 3.75560 416.380 264.450
67 Xenón Xe 3.76779 566.282 258.660
68 Helio 4 He 1.68360 8.155 273.710
69 Hidrógeno H2 2.94928 67.508 275.700
70 Oxígeno O2 3.81634 319.013 266.700
71 Nitrógeno N2 3.61947 255.680 266.550
72 Cloro Cl2 4.06280 861.340 246.330
73 Monóxido de carbono CO 3.81912 291.743 267.996
74 Dióxido de carbono CO2
75 Disulfuro de carbono CS2
76 Sulfuro de hidrógeno H2S 4.22882 806.933 251.390
77 Dióxido de Azufre SO2 4.40720 999.900 237.190
78 Trióxido de Azufre SO3 6.17575 1735.310 236.500
79 Oxido Nítrico NO 5.86790 682.939 268.270
80 Oxido Nitroso N2O 4.12884 654.260 247.160
81 Cloruro de hidrógeno HCl 4.29490 745.780 258.880
82 Cianuro de hidrógeno CNH
83 Agua H2O 5.11564 1687.537 230.170
84 Amoníaco NH3 4.48540 926.132 240.170
85 Acido Nítrico HNO3
86 Acido Sulfurico H2SO4
 MODELO SIMÉTRICO: CONSTANTES PARA MEZCLAS BINARIAS
Rango de
Temperatura
Componente 1 Componente 2 [°C] B
Benceno 56.1 - 80.1 0.405
Metanol 56.1 – 64.0 0.56
Acetona Etil Eter 34.6 - 56.1 0.741
Metanol 55.5 - 64.6 0.56
Benceno Ciclohexano 80 0.335
Tetracloruro de Cloroformo 40 0.154
carbono Ciclohexano 50 0.094
2-Butanona n-Hexano 50 - 70 1.22
Tolueno 76.4 - 110.7 1.757
Etanol Acetato de Etilo 71.7 - 78.3 0.896
o-Xileno 136 - 144 0.0081
m-Xileno 136 - 139 0.0083
Etilbenceno p-Xileno 136 - 138 0.0071
Acetato de Etilo 62.1 - 77.1 1.16
Acetato de Metilo 53.7 - 64.6 1.064
Tricloroetileno 65 - 87 1.946
Metanol 2-Propanol 65 - 82 -0.0754
Fuente: SANDLER, STANLEY. (1989). Chemical and Engineering Thermodynamics. John Wiley &
Sons. New York.

O`CONNELL, J. & HAILE, J.M. (2004). Thermodynamics: Fundamentals for

Applications. Cambridge University Press. Cambridge.

MODELO MARGULES: CONSTANTES PARA MEZCLAS BINARIAS

Temperatura
Componente 1 Componente 2 [°C] A12 A21
Benceno 57.7 – 76.5 0.316 0.461

Tetracloruro de carbono 56 – 70.8 0.764 0.918

Cloroformo 57.5 – 64.4 -0.561 -0.84
Acetona Metanol 55.3 – 64.6 0.579 0.618

Tetracloruro de carbono 76.6 – 79.9 0.0855 0.121

Cloroformo 62 – 79.2 -0.167 -0.236
Metanol 58 – 78.6 1.71 2.293
Benceno n-Hexano 68.6 – 77.9 0.516 0.365
2-Butanona Cloroformo 62.9 – 79.7 -0.686 -0.85
Benceno 67.9 – 76.9 1.472 1.836
Ciclohexano 65 - 74 1.726 2.473
n-Hexano 58.1 – 78.3 1.94 2.705
Etanol Tolueno 77 – 110.6 1.571 1.648
Metanol Cloroformo 53.5 - 63 0.832 1.736
n-Octano Etilbenceno 125.7 – 136.2 0.201 0.188
 Benceno 77 – 97.2 1.336 1.596
Etilbenceno 97 – 118.9 1.33 1.239
n-Hexano 66.2 – 89.6 1.867 1.536
1-Propanol Acetato de etilo 78 - 96 0.519 0.641
Acetona 56.8 – 79.8 0.514 0.632
Benceno 71.8 – 82.4 1.269 1.52
2-Propanol Acetato de etilo 75.9 – 80.3 0.517 0.476
Tolueno Fenol 110.5 – 172.7 1.034 0.714
Fuente: O`Connell, John and J. Haille. (2004). Thermodynamics: Fundamentals for applications. Cambridge.

MODELO DE VAN LAAR: CONSTANTES PARA MEZCLAS BINARIAS

Temperatura B12 B21
Componente 1 Componente 2
[°C]

Acetaldehido Agua 19.8 - 100 1.59 1.8

Acetona Agua 25 1.89 1.66
Acetona Agua 56.1 - 100 2.05 1.5
Acetona Metanol 56.1 - 64.6 0.58 0.56
Agua Fenol 100 - 181 0.83 3.22
Benceno Isopropanol 71.9 - 82.3 1.36 1.95
Bisulfuro de
Acetona 39.5 - 56.1 1.28 1.79
Carbono
Bisulfuro de Tetracloruro de
46.3 - 76.7 0.23 0.16
Carbono Carbono
Etanol Agua 25 1.54 0.97
Etanol Benceno 67.0 - 80.1 1.946 1.61
Etanol Ciclohexano 66.3 - 80.8 2.102 1.729
Etil Acetato Benceno 71.1- 80.2 1.15 0.92
Etil Acetato Tolueno 77.2 - 110.7 0.09 0.58
Etil Eter Etanol 34.6 - 78.3 0.97 1.27
Isobutano Furfural 37.8 2.62 3.02
Isobutano Furfural 51.7 2.51 2.83
Isopropanol Agua 82.3 - 100 2.4 1.13
Metanol Agua 25 0.58 0.46
Metanol Agua 64.6 - 100 0.83 0.51
Metil Acetato Agua 57.0 - 100 2.99 1.89
n-Hexano Etanol 59.3 - 78.3 1.57 2.58
n-Propanol Agua 88.0 - 100 2.53 1.13
Tetracloruro de
Benceno 76.4 - 80.2 0.12 0.11
Carbono
Fuente: SANDLER, STANLEY.(1989). Chemical and Engineering Thermodynamics. John Wiley & Sons. New York.
 ECUACIÓN DE WILSON: CONSTANTES PARA MEZCLAS BINARIAS
VOLUMEN MOLAR PARÁMETROS
SISTEMA [cm3/mol] a12 [cal/mol] a21 [cal/mol]
Acetona (1) 74.05
1 Agua (2) 18.07 291.27 1,448.01
Metanol (1) 40.73
2 Agua (2) 18.07 107.38 469.55
1-Propanol (1) 75.14
3 Agua (2) 18.07 775.48 1,351.90
Agua (1) 18.07
4 1,4-Dioxano (2) 85.71 1,696.98 -219.39
Metanol (1) 40.73
5 Acetonitrilo (2) 66.3 504.31 196.75
Acetona (1) 74.05
6 Metanol (2) 40.73 -161.88 583.11
Metil acetato (1) 79.84
7 Metanol (2) 40.73 -31.19 813.18
Metanol (1) 40.73
8 Benceno (2) 89.41 1,734.42 183.04
Etanol (1) 58.68
9 Tolueno (2) 106.85 1,556.45 210.52
Metanol (1) 40.73
10 Etanol (2) 58.68 -326.819 678.595
Metanol (1) 40.73
11 1-Propanol (2) 75.14 1846.612 -987.209
Etanol (1) 58.68
12 1-Propanol (2) 75.14 3108.881 -829.156
Ref.:

Smith, J.M.; Van Ness,H.C. & Abbott,M.M. 2001. Introduction to Chemical Engineering Thermodynamics. 6th edition.

Skouras, Stathis. En: http://www.nt.ntnu.no/users/skoge/distillation/nonideal_skouras/ternary/wilson.m. July 2001

ECUACIÓN NRTL: CONSTANTES PARA MEZCLAS BINARIAS

VOLUMEN MOLAR PARÁMETROS NRTL
SISTEMA
[cm3/mol] b12 [cal/mol] b21 [cal/mol] α
Acetona (1) 74.05
1 631.05 1,197.41 0.5343
Agua (2) 18.07
Metanol (1) 40.73
2 -253.88 845.21 0.2994
Agua (2) 18.07
1-Propanol (1) 75.14
3 500.4 1,636.57 0.5081
Agua (2) 18.07
Agua (1) 18.07
4 715.96 548.9 0.292
 4 715.96 548.9 0.292
1,4-Dioxano (2) 85.71
Metanol (1) 40.73
5 343.7 314.59 0.2981
Acetonitrilo (2) 66.3
Acetona (1) 74.05
6 184.7 222.64 0.3084
Metanol (2) 40.73
Metil acetato (1) 79.84
7 381.46 346.54 0.2965
Metanol (2) 40.73
Metanol (1) 40.73
8 730.09 1,175.41 0.4743
Benceno (2) 89.41
Etanol (1) 58.68
9 713.57 1,147.86 0.5292
Tolueno (2) 106.85
Ref.: Smith, J.M.; Van Ness,H.C. & Abbott,M.M. (2001). Introduction to Chemical Engineering Thermodynamics. 6th edition.